Two novel tetrahedral manganese(II)complexes,(N-methylpiperidinium)MnCl_(4)(1)and(N-methylpyrrolidinium)MnCl_(4)(2),with clearly distinct fluorescence characteristics were synthesized through organic cation modulation...Two novel tetrahedral manganese(II)complexes,(N-methylpiperidinium)MnCl_(4)(1)and(N-methylpyrrolidinium)MnCl_(4)(2),with clearly distinct fluorescence characteristics were synthesized through organic cation modulation.Compound 1 exhibits prominent green luminescence with a high quantum yield of 79.37%and 2 emits unusual red emission at 611 nm.展开更多
基金supported by the National Key Research and Development Program of China(Grant 2017YFA0204800)the National Natural Science Foundation of China(21522101)the Fundamental Research Funds for the Central Universities(Grant 2242017K41027).
文摘Two novel tetrahedral manganese(II)complexes,(N-methylpiperidinium)MnCl_(4)(1)and(N-methylpyrrolidinium)MnCl_(4)(2),with clearly distinct fluorescence characteristics were synthesized through organic cation modulation.Compound 1 exhibits prominent green luminescence with a high quantum yield of 79.37%and 2 emits unusual red emission at 611 nm.
