Diatomic metasurfaces designed for interferometric mechanisms possess significant potential for the multidimensional manipulation of electromagnetic waves,including control over amplitude,phase,frequency,and polarizat...Diatomic metasurfaces designed for interferometric mechanisms possess significant potential for the multidimensional manipulation of electromagnetic waves,including control over amplitude,phase,frequency,and polarization.Geometric phase profiles with spin-selective properties are commonly associated with wavefront modulation,allowing the implementation of conjugate strategies within orthogonal circularly polarized channels.Simultaneous control of these characteristics in a single-layered diatomic metasurface will be an apparent technological extension.Here,spin-selective modulation of terahertz(THz)beams is realized by assembling a pair of meta-atoms with birefringent effects.The distinct modulation functions arise from geometric phase profiles characterized by multiple rotational properties,which introduce independent parametric factors that elucidate their physical significance.By arranging the key parameters,the proposed design strategy can be employed to realize independent amplitude and phase manipulation.A series of THz metasurface samples with specific modulation functions are characterized,experimentally demonstrating the accuracy of on-demand manipulation.This research paves the way for all-silicon meta-optics that may have great potential in imaging,sensing and detection.展开更多
High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,inclu...High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments.展开更多
The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches...The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches between the parameters of the received amplitude modulation(AM) signals and the system's linear workspace and demodulation operating points can cause severe distortion in the demodulated signals. To address this, the article proposes a method for determining the operational parameters based on the mean square error(MSE) and total harmonic distortion(THD) assessments and presents strategies for optimizing the system's operational parameters focusing on linear response characteristics(LRC) and linear dynamic range(LDR). Specifically, we employ a method that minimizes the MSE to define the system's linear workspace, thereby ensuring the system has a good LRC while maximizing the LDR. To ensure that the signal always operates within the linear workspace, an appropriate carrier amplitude is set as the demodulation operating point. By calculating the THD at different operating points, the LRC performance within different regions of the linear workspace is evaluated, and corresponding optimization strategies based on the range of signal strengths are proposed. Moreover, to more accurately restore the baseband signal, we establish a mapping relationship between the carrier Rabi frequency and the transmitted power of the probe light, and optimize the slope of the linear demodulation function to reduce the MSE to less than 0.8×10^(-4). Finally, based on these methods for determining the operational parameters, we explore the effects of different laser Rabi frequencies on the system performance, and provide optimization recommendations. This research provides robust support for the design of high-performance Rydberg atom-based AM receivers.展开更多
The development of solid frustrated Lewis pairs(FLPs)catalysts with porous structures is a promising strategy for advancing green hydrogenation technologies and has garnered significant attention.Leveraging the divers...The development of solid frustrated Lewis pairs(FLPs)catalysts with porous structures is a promising strategy for advancing green hydrogenation technologies and has garnered significant attention.Leveraging the diverse oxidation states and structural tunability of cerium-based metal-organic frameworks(Ce-MOFs),this study employed a competitive coordination strategy utilizing a single carboxylate functional group ligand to construct a series of MOF-808-X(X=-NH_(2),-OH,-Br,and-NO_(2))featuring rich solid-state FLPs for hydrogenation of unsaturated olefins.The-X functional group serves as a microenvironment,enhancing hydrogenation activity by modulating the electronic properties and acid-base characteristics of the FLP sites.The unique redox properties of elemental cerium facilitate the exposure of unsaturated Ce sites(Ce-CUS,Lewis acid(LA))and adjacent Ce-OH(Lewis base(LB))sites within the MOFs,generating abundant solid-state FLP(Ce-CUS/Ce-OH)sites.Experimental results demonstrate that Ce-CUS and Ce-OH interact with theσandσ^(*)orbitals of H-H,and this"push-pull"synergy promotes heterolytic cleavage of the H-H bond.The lone pair electrons of the electron-donating functional group are transmitted through the molecular backbone to the LB site,thereby increasing its strength and reducing the activation energy required for H_(2)heterolytic cleavage.Notably,at 100℃and 2 MPa H_(2),MOF-808-NH_(2)achieves complete conversion of styrene and dicyclopentadiene,significantly outperforming MOF-808.Based on in-situ analysis and density functional theory calculations,a plausible reaction mechanism is proposed.This research enriches the theoretical framework for unsaturated olefin hydrogenation catalysts and contributes to the development of efficient catalytic systems.展开更多
Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show t...Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show that the scattering angle of SRS in a longitudinally inhomogeneous plasma can be significantly affected by transverse density modulation.Under transverse density modulation conditions,the laser focuses into underdense regions,owing to the transversely modulated refractive index.The angle of LA-SRS,neither a purely 90° angle side scattering nor purely backscattering,is almost consistent with the specific angle at which the density inhomogeneity vanishes.In modulated plasmas,the nonuniform distribution of laser intensity shifts the regions of scattering and gain compared with those in uniform plasmas,ultimately affecting the laser transmission.SRS is suppressed in weakly modulated regimes,whereas it is enhanced under strong modulation conditions,and a theoretical criterion distinguishing between strong and weak modulation is established.展开更多
Neuromorphic devices,inspired by the intricate architecture of the human brain,have garnered recognition for their prodigious computational speed and sophisticated parallel computing capabilities.Vision,the primary mo...Neuromorphic devices,inspired by the intricate architecture of the human brain,have garnered recognition for their prodigious computational speed and sophisticated parallel computing capabilities.Vision,the primary mode of external information acquisition in living organisms,has garnered substantial scholarly interest.Notwithstanding numerous studies simulating the retina through optical synapses,their applications remain circumscribed to single-mode perception.Moreover,the pivotal role of temperature,a fundamental regulator of biological activities,has regrettably been relegated to the periphery.To address these limitations,we proffer a neuromorphic device endowed with multimodal perception,grounded in the principles of light-modulated semiconductors.This device seamlessly accomplishes dynamic hybrid visual and thermal multimodal perception,featuring temperature-dependent paired pulse facilitation properties and adaptive storage.Crucially,our meticulous examination of transfer curves,capacitance–voltage(C–V)tests,and noise measurements provides insights into interface and bulk defects,elucidating the physical mechanisms underlying adaptive storage and other functionalities.Additionally,the device demonstrates a variety of synaptic functionalities,including filtering properties,Ebbinghaus curves,and memory applications in image recognition.Surprisingly,the digital recognition rate achieves a remarkable value of 98.8%.展开更多
The control of adiabatic dynamics is essential for quantum manipulation.We investigate the effects of both periodic modulating field and linear sweeping field on adiabatic dynamics based on a non-reciprocal Landau-Zen...The control of adiabatic dynamics is essential for quantum manipulation.We investigate the effects of both periodic modulating field and linear sweeping field on adiabatic dynamics based on a non-reciprocal Landau-Zener model with periodic modulation.We obtain adiabatic phase diagrams in the(ω,δ)parameter space,where the adiabatic region is bounded by the modulating frequencyωgreater than a critical valueω_(c) and the non-reciprocal parameterδless than one.The results show that the adiabaticity of the system is not sensitive to the modulating amplitude.We find that the critical modulating frequency can be expressed as a power function of the modulating period number or the sweeping rate.Our findings suggest that one can change the adiabatic region or improve the adiabaticity by adjusting the parameters of both the modulating and the sweeping fields,which provides an effective means to flexibly control the adiabatic dynamics of non-reciprocal systems.展开更多
The utilization of millimeter-wave frequencies and cognitive radio(CR)are promising ways to increase the spectral efficiency of wireless communication systems.However,conventional CR spectrum sensing techniques entail...The utilization of millimeter-wave frequencies and cognitive radio(CR)are promising ways to increase the spectral efficiency of wireless communication systems.However,conventional CR spectrum sensing techniques entail sampling the received signal at a Nyquist rate,and they are not viable for wideband signals due to their high cost.This paper expounds on how sub-Nyquist sampling in conjunction with deep learning can be leveraged to remove this limitation.To this end,we propose a multi-task learning(MTL)framework using convolutional neural networks for the joint inference of the underlying narrowband signal number,their modulation scheme,and their location in a wideband spectrum.We demonstrate the effectiveness of the proposed framework for real-world millimeter-wave wideband signals collected by physical devices,exhibiting a 91.7% accuracy in the joint inference task when considering up to two narrowband signals over a wideband spectrum.Ultimately,the proposed data-driven approach enables on-the-fly wideband spectrum sensing,combining accuracy,and computational efficiency,which are indispensable for CR and opportunistic networking.展开更多
Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involv...Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.展开更多
Difficulty in extracting nonlinear sparse impulse features due to variable speed conditions and redundant noise interference leads to challenges in diagnosing variable speed faults.Therefore,an improved spectral amplit...Difficulty in extracting nonlinear sparse impulse features due to variable speed conditions and redundant noise interference leads to challenges in diagnosing variable speed faults.Therefore,an improved spectral amplitude modulation(ISAM)based on sparse feature adaptive convolution(SFAC)is proposed to enhance the fault features under variable speed conditions.First,an optimal bi-damped wavelet construction method is proposed to learn signal impulse features,which selects the optimal bi-damped wavelet parameters with correlation criterion and particle swarm optimization.Second,a convolutional basis pursuit denoising model based on an optimal bi-damped wavelet is proposed for resolving sparse impulses.A model regularization parameter selection method based on weighted fault characteristic amplitude ratio assistance is proposed.Then,an ISAM method based on kurtosis threshold is proposed to further enhance the fault information of sparse signal.Finally,the type of variable speed faults is determined by order spectrum analysis.Various experimental results,such as spectral amplitude modulation and Morlet wavelet matching,verify the effectiveness and advantages of the ISAM-SFAC method.展开更多
Background:The nuclear receptor coactivator(NCOA)family,including NCOA1,NCOA2,and NCOA3,is critical in regulating gene expression through interactions with nuclear receptors and other transcription factors.These coact...Background:The nuclear receptor coactivator(NCOA)family,including NCOA1,NCOA2,and NCOA3,is critical in regulating gene expression through interactions with nuclear receptors and other transcription factors.These coactivators are implicated in various cancers,but their comprehensive roles across different cancer types remain poorly understood.Methods:We performed a pan-cancer bioinformatics analysis using data from The Cancer Genome Atlas and the Genotype-Tissue Expression project.We assessed the differential expression,copy number variations,mutations,methylation status,tumor mutation burden,microsatellite instability,and immune cell infiltration associated with NCOA family members across various cancers.Differential expression analysis was conducted using the DESeq2 package.Methylation data were analyzed using the ChAMP package,and immune cell infiltration was estimated using the CIBERSORT algorithm.Results:NCOA1 and NCOA2 were predominantly downregulated in multiple cancers,suggesting potential tumor suppressor roles,whereas NCOA3 was largely upregulated,indicating a consistent oncogenic function.These expression patterns significantly correlated with patient prognosis.Frequent copy number variations,particularly gains,and high mutation rates were observed in NCOA2.NCOA3 demonstrated consistent hypomethylation in tumors,which was associated with increased gene expression.Significant correlations were found between NCOA expression and tumor mutation burden,microsatellite instability,and immune cell infiltration,indicating their involvement in genomic instability and immune modulation.Conclusion:This comprehensive analysis reveals significant alterations in the expression,genomic,and epigenetic profiles of NCOA family members across various cancers.The findings highlight the multifaceted roles of NCOA1,NCOA2,and NCOA3 in tumorigenesis and their potential as biomarkers and therapeutic targets.Future research should focus on elucidating the mechanisms underlying the associations between NCOA expression,genomic alterations,and immune modulation to develop targeted cancer therapies.展开更多
This paper designs a high-frequency stable wireless amplitude modulation(AM)system based on a Pierce circuit.The system utilizes an oscillator and comparator to generate a 20 kHz square wave with an adjustable duty cy...This paper designs a high-frequency stable wireless amplitude modulation(AM)system based on a Pierce circuit.The system utilizes an oscillator and comparator to generate a 20 kHz square wave with an adjustable duty cycle,combined with a 41 MHz carrier wave produced by a passive crystal oscillator Pierce circuit.A 100% modulation index amplitude modulation is achieved through the AD835 multiplier.The modulated signal is amplified by a power amplifier circuit and transmitted wirelessly via the transmitter antenna.Upon reception,the signal undergoes two-stage highfrequency amplification before passing through a Schottky diode envelope detector.The NE5532 shaping circuit then restores the square wave.Experimental results demonstrate reliable 11-meter transmission with carrier frequency deviation<0.75% and demodulation error<1%.展开更多
The reasonable development and design of high-efficiency and low-cost electrocatalysts for hydrogen evolution reaction(HER)under industrial current densities are imperative for achieving carbon neutrality,while also p...The reasonable development and design of high-efficiency and low-cost electrocatalysts for hydrogen evolution reaction(HER)under industrial current densities are imperative for achieving carbon neutrality,while also posing challenges.In this study,an efficient electrocatalyst is successfully constructed through electrodeposition methods,which consists of monodispersed Pt loaded on amorphous/crystalline nickel–iron layered double hydroxide(Pt-SAs/ac-NiFe LDH).The Pt-SAs/ac-NiFe LDH demonstrates an elevated mass activity of 17.66 A mg_(Pt)^(−1)and a significant turnover frequency of 17.90 s^(−1)for HER in alkaline conditions under the overpotential of 100 mV.Meanwhile,for alkaline freshwater and seawater,Pt-SAs/ac-NiFe LDH exhibits ultra-low overpotentials of 141 and 138 mV to reach 1000 mA cm^(−2),respectively.Remarkably,it maintains stable operation for 100 h at 500 mA cm^(−2),showcasing its robustness and reliability.In situ Raman spectra reveal that Pt single atoms(Pt-SAs)accelerate interfacial water dissociation,thereby enhancing the HER kinetics in Pt-SAs/ac-NiFe LDH.Furthermore,theoretical calculation results show significant electronic interaction between the Pt-SAs and the ac-NiFe LDH support.The interaction significantly enhances water adsorption and dissociation,and balances the adsorption/desorption of hydrogen intermediates,ultimately improving HER performance.This research provides a viable method for designing efficient HER catalysts for water electrolysis in alkaline freshwater and seawater under industrial current densities.展开更多
The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus...The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus,the ability to manipulate its degrees of freedom is highly desirable.In this paper,the full-domain polarization modulation of BlVVB within a hot atomic ensemble has been investigated.We begin with the theoretical analysis of the resonant magneto-optical effect of atoms with a horizontal linear-polarized beam and experimentally demonstrate precise manipulation of the polarization state across the entire domain of the BlVVB,achieving an error margin of less than 3°at various cross-sectional points.Our study provides a novel approach for the modulation of BlVVB based on atomic media,which holds potential applications in sensitive vector magnetometers,optical communications,and signal processing.展开更多
Single-wavelength interferometry achieves high resolution for smooth surfaces but struggles with rough industrially relevant ones due to limited unambiguous measuring range and speckle effects.Multiwavelength interfer...Single-wavelength interferometry achieves high resolution for smooth surfaces but struggles with rough industrially relevant ones due to limited unambiguous measuring range and speckle effects.Multiwavelength interferometry addresses these challenges using synthetic wavelengths,enabling a balance between extended measurement range and resolution by combining several synthetic wavelengths.This approach holds immense potential for diverse industrial applications,yet it remains largely untapped due to the lack of suitable light sources.Existing solutions are constrained by limited flexibility in synthetic-wavelength generation and slow switching speeds.We demonstrate a light source for multiwavelength interferometry based on electro-optic single-sideband modulation.It reliably generates synthetic wavelengths with arbitrary values from centimeters to meters and switching time below 30 ms.This breakthrough paves the way for dynamic reconfigurable multiwavelength interferometry capable of adapting to complex surfaces and operating efficiently even outside laboratory settings.These capabilities unlock the full potential of multiwavelength interferometry,offering unprecedented flexibility and speed for industrial and technological applications.展开更多
In this paper,Index Modulation(IM)aided Generalized Space-Time Block Coding(GSTBC)is proposed,which intrinsically exploits the benefits of IM concept,diversity gain and spatial multiplexing gain.Specifically,the infor...In this paper,Index Modulation(IM)aided Generalized Space-Time Block Coding(GSTBC)is proposed,which intrinsically exploits the benefits of IM concept,diversity gain and spatial multiplexing gain.Specifically,the information bits are partitioned into U groups,with each being modulated by IM symbols(i.e.Spatial Modulation(SM),Quadrature SM(QSM),etc).Next,the structure of GSTBC is invoked for each K IM symbol,and a total ofμ=U/K GSTBC codes are transmitted via T time slots.A Block Expectation Propagation(B-EP)detector is designed for the proposed IM-GSTBC structure.Moreover,the theoretical Average Bit Error Probability(ABEP)is derived for our IM-GSTBC system,which is confirmed by the simulation results and helpful for performance evaluation.Simulation results show that our proposed IM-GSTBC system is capable of striking an efficient trade-off between spatial multiplexing gain,spatial diversity gain as well as implementation cost imposed for both small-scale and large-scale MIMO antenna configurations.展开更多
Hyperlipidemia is a major risk factor for erectile dysfunction(ED).Oxidative stress and phenotypic modulation of corpus cavernosum smooth muscle cells(CcSMCs)are the key pathological factors of ED.N-acetylcysteine(NAC...Hyperlipidemia is a major risk factor for erectile dysfunction(ED).Oxidative stress and phenotypic modulation of corpus cavernosum smooth muscle cells(CcSMCs)are the key pathological factors of ED.N-acetylcysteine(NAC)can inhibit oxidative stress;however,whether NAc can alleviate pathological variations in the corpus cavernosum and promote erectile function recovery in hyperlipidemic rats remains unclear.A hyperlipidemia model was established using 27 eight-week-old male Sprague-Dawley(SD)rats fed a high-fat and high-cholesterol diet(hyperlipidemic rats,HR).In addition,9 male SD rats were fed a normal diet to serve as controls(NC).HR rats were divided into three groups:HR,HR+normal saline(NS),and HR+NAC(n=9 for each group;NS or NAc intraperitoneal injections were administered daily for 16 weeks).Subsequently,the lipid profiles,erectile function,oxidative stress,phenotypic modulation markers of ccsMCs,and tissue histology were analyzed.The experimental results revealed that erectile function was significantly impaired in the HR and HR+NS groups,but enhanced in the HR+NAC group.Abnormal lipid levels,over-activated oxidative stress,and multi-organ lesions observed in the HR and HR+NS groups were improved in the HR+NAC group.Moreover,the HR group showed significant phenotypic modulation of CCSMCs,which was also inhibited by NAC treatment.This report focuses on the therapeutic effect of NAc in restoring erectile function using a hyperlipidemic rat model by preventing CcSMC phenotypic modulationand attenuating oxidativestress.展开更多
We have investigated homoepitaxy of AlN films grown by molecular beam epitaxy on AlN/sapphire templates byadopting both the continuous growth method and the Al modulation epitaxy(AME)growth method.The continuous growt...We have investigated homoepitaxy of AlN films grown by molecular beam epitaxy on AlN/sapphire templates byadopting both the continuous growth method and the Al modulation epitaxy(AME)growth method.The continuous growthmethod encounters significant challenges in controlling the growth mode.As the precise Al/N=1.0 ratio is difficult toachieve,either the excessive Al-rich or N-rich growth mode occurs.In contrast,by adopting the AME growth method,sucha difficulty has been effectively overcome.By manipulating the supply time of the Al and nitrogen sources,we were able toproduce AlN films with much improved surface morphology.The first step of the AME method,only supplying Al atoms,is important to wet the surface and the Al adatoms can act as a surfactant.Optimization of the initial Al supply time caneffectively reduce the pit density on the grown AlN surface.The pits density dropped from 12 pits/μm^(2)to 1 pit/μm^(2)andthe surface roughness reduced from 0.72 nm to 0.3 nm in a 2×2μm^(2)area for the AME AlN film homoepitaxially grownon an AlN template.展开更多
基金supports from National Key Research and Development Program of China(2021YFB2800703)Sichuan Province Science and Technology Support Program(25QNJJ2419)+1 种基金National Natural Science Foundation of China(U22A2008,12404484)Laoshan Laboratory Science and Technology Innovation Project(LSKJ202200801).
文摘Diatomic metasurfaces designed for interferometric mechanisms possess significant potential for the multidimensional manipulation of electromagnetic waves,including control over amplitude,phase,frequency,and polarization.Geometric phase profiles with spin-selective properties are commonly associated with wavefront modulation,allowing the implementation of conjugate strategies within orthogonal circularly polarized channels.Simultaneous control of these characteristics in a single-layered diatomic metasurface will be an apparent technological extension.Here,spin-selective modulation of terahertz(THz)beams is realized by assembling a pair of meta-atoms with birefringent effects.The distinct modulation functions arise from geometric phase profiles characterized by multiple rotational properties,which introduce independent parametric factors that elucidate their physical significance.By arranging the key parameters,the proposed design strategy can be employed to realize independent amplitude and phase manipulation.A series of THz metasurface samples with specific modulation functions are characterized,experimentally demonstrating the accuracy of on-demand manipulation.This research paves the way for all-silicon meta-optics that may have great potential in imaging,sensing and detection.
基金supported by the National Natural Science Foundation of China(Grant Nos.52272103 and 52072010)Beijing Natural Science Foundation(Grant Nos.2242029 and JL23004).
文摘High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments.
基金Project supported by the National Natural Science Foundation of China (Grant No. U22B2095)the Civil Aerospace Technology Research Project (Grant No. D010103)。
文摘The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches between the parameters of the received amplitude modulation(AM) signals and the system's linear workspace and demodulation operating points can cause severe distortion in the demodulated signals. To address this, the article proposes a method for determining the operational parameters based on the mean square error(MSE) and total harmonic distortion(THD) assessments and presents strategies for optimizing the system's operational parameters focusing on linear response characteristics(LRC) and linear dynamic range(LDR). Specifically, we employ a method that minimizes the MSE to define the system's linear workspace, thereby ensuring the system has a good LRC while maximizing the LDR. To ensure that the signal always operates within the linear workspace, an appropriate carrier amplitude is set as the demodulation operating point. By calculating the THD at different operating points, the LRC performance within different regions of the linear workspace is evaluated, and corresponding optimization strategies based on the range of signal strengths are proposed. Moreover, to more accurately restore the baseband signal, we establish a mapping relationship between the carrier Rabi frequency and the transmitted power of the probe light, and optimize the slope of the linear demodulation function to reduce the MSE to less than 0.8×10^(-4). Finally, based on these methods for determining the operational parameters, we explore the effects of different laser Rabi frequencies on the system performance, and provide optimization recommendations. This research provides robust support for the design of high-performance Rydberg atom-based AM receivers.
文摘The development of solid frustrated Lewis pairs(FLPs)catalysts with porous structures is a promising strategy for advancing green hydrogenation technologies and has garnered significant attention.Leveraging the diverse oxidation states and structural tunability of cerium-based metal-organic frameworks(Ce-MOFs),this study employed a competitive coordination strategy utilizing a single carboxylate functional group ligand to construct a series of MOF-808-X(X=-NH_(2),-OH,-Br,and-NO_(2))featuring rich solid-state FLPs for hydrogenation of unsaturated olefins.The-X functional group serves as a microenvironment,enhancing hydrogenation activity by modulating the electronic properties and acid-base characteristics of the FLP sites.The unique redox properties of elemental cerium facilitate the exposure of unsaturated Ce sites(Ce-CUS,Lewis acid(LA))and adjacent Ce-OH(Lewis base(LB))sites within the MOFs,generating abundant solid-state FLP(Ce-CUS/Ce-OH)sites.Experimental results demonstrate that Ce-CUS and Ce-OH interact with theσandσ^(*)orbitals of H-H,and this"push-pull"synergy promotes heterolytic cleavage of the H-H bond.The lone pair electrons of the electron-donating functional group are transmitted through the molecular backbone to the LB site,thereby increasing its strength and reducing the activation energy required for H_(2)heterolytic cleavage.Notably,at 100℃and 2 MPa H_(2),MOF-808-NH_(2)achieves complete conversion of styrene and dicyclopentadiene,significantly outperforming MOF-808.Based on in-situ analysis and density functional theory calculations,a plausible reaction mechanism is proposed.This research enriches the theoretical framework for unsaturated olefin hydrogenation catalysts and contributes to the development of efficient catalytic systems.
基金supported by the National Natural Science Foundation of China under Grant Nos.U2430207,12035002,and 12305258by the CAEP Foundation under Grant No.YZJJZQ2023020.
文摘Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show that the scattering angle of SRS in a longitudinally inhomogeneous plasma can be significantly affected by transverse density modulation.Under transverse density modulation conditions,the laser focuses into underdense regions,owing to the transversely modulated refractive index.The angle of LA-SRS,neither a purely 90° angle side scattering nor purely backscattering,is almost consistent with the specific angle at which the density inhomogeneity vanishes.In modulated plasmas,the nonuniform distribution of laser intensity shifts the regions of scattering and gain compared with those in uniform plasmas,ultimately affecting the laser transmission.SRS is suppressed in weakly modulated regimes,whereas it is enhanced under strong modulation conditions,and a theoretical criterion distinguishing between strong and weak modulation is established.
基金the financial support given by National Natural Science Foundation of China(52227808,62202285)the National Science Foundation for Distinguished Young Scholars of China(51725505)+1 种基金the Development Fund for Shanghai Talents(No.2021003)Shanghai Collaborative Innovation Center of Intelligent Perception Chip Technology。
文摘Neuromorphic devices,inspired by the intricate architecture of the human brain,have garnered recognition for their prodigious computational speed and sophisticated parallel computing capabilities.Vision,the primary mode of external information acquisition in living organisms,has garnered substantial scholarly interest.Notwithstanding numerous studies simulating the retina through optical synapses,their applications remain circumscribed to single-mode perception.Moreover,the pivotal role of temperature,a fundamental regulator of biological activities,has regrettably been relegated to the periphery.To address these limitations,we proffer a neuromorphic device endowed with multimodal perception,grounded in the principles of light-modulated semiconductors.This device seamlessly accomplishes dynamic hybrid visual and thermal multimodal perception,featuring temperature-dependent paired pulse facilitation properties and adaptive storage.Crucially,our meticulous examination of transfer curves,capacitance–voltage(C–V)tests,and noise measurements provides insights into interface and bulk defects,elucidating the physical mechanisms underlying adaptive storage and other functionalities.Additionally,the device demonstrates a variety of synaptic functionalities,including filtering properties,Ebbinghaus curves,and memory applications in image recognition.Surprisingly,the digital recognition rate achieves a remarkable value of 98.8%.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12375019 and 11974273)。
文摘The control of adiabatic dynamics is essential for quantum manipulation.We investigate the effects of both periodic modulating field and linear sweeping field on adiabatic dynamics based on a non-reciprocal Landau-Zener model with periodic modulation.We obtain adiabatic phase diagrams in the(ω,δ)parameter space,where the adiabatic region is bounded by the modulating frequencyωgreater than a critical valueω_(c) and the non-reciprocal parameterδless than one.The results show that the adiabaticity of the system is not sensitive to the modulating amplitude.We find that the critical modulating frequency can be expressed as a power function of the modulating period number or the sweeping rate.Our findings suggest that one can change the adiabatic region or improve the adiabaticity by adjusting the parameters of both the modulating and the sweeping fields,which provides an effective means to flexibly control the adiabatic dynamics of non-reciprocal systems.
文摘The utilization of millimeter-wave frequencies and cognitive radio(CR)are promising ways to increase the spectral efficiency of wireless communication systems.However,conventional CR spectrum sensing techniques entail sampling the received signal at a Nyquist rate,and they are not viable for wideband signals due to their high cost.This paper expounds on how sub-Nyquist sampling in conjunction with deep learning can be leveraged to remove this limitation.To this end,we propose a multi-task learning(MTL)framework using convolutional neural networks for the joint inference of the underlying narrowband signal number,their modulation scheme,and their location in a wideband spectrum.We demonstrate the effectiveness of the proposed framework for real-world millimeter-wave wideband signals collected by physical devices,exhibiting a 91.7% accuracy in the joint inference task when considering up to two narrowband signals over a wideband spectrum.Ultimately,the proposed data-driven approach enables on-the-fly wideband spectrum sensing,combining accuracy,and computational efficiency,which are indispensable for CR and opportunistic networking.
基金supported by the National Natural Science Foundation of China(No.22375021,22235003,22261132516&22205021)the BIT Research and Innovation 265 Promoting Project(Grant No.2023YCXZ017)。
文摘Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense oxidizers.In this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive performance.Utilizing this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic compounds.Notably,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),respectively.Additionally,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and stability.This work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.
基金funded by the National Natural Science Foundation of China(grant nos.52475084 and 52375076)the Postdoctoral Fellowship Program of CPSF(grant no.GZC20230202).
文摘Difficulty in extracting nonlinear sparse impulse features due to variable speed conditions and redundant noise interference leads to challenges in diagnosing variable speed faults.Therefore,an improved spectral amplitude modulation(ISAM)based on sparse feature adaptive convolution(SFAC)is proposed to enhance the fault features under variable speed conditions.First,an optimal bi-damped wavelet construction method is proposed to learn signal impulse features,which selects the optimal bi-damped wavelet parameters with correlation criterion and particle swarm optimization.Second,a convolutional basis pursuit denoising model based on an optimal bi-damped wavelet is proposed for resolving sparse impulses.A model regularization parameter selection method based on weighted fault characteristic amplitude ratio assistance is proposed.Then,an ISAM method based on kurtosis threshold is proposed to further enhance the fault information of sparse signal.Finally,the type of variable speed faults is determined by order spectrum analysis.Various experimental results,such as spectral amplitude modulation and Morlet wavelet matching,verify the effectiveness and advantages of the ISAM-SFAC method.
基金supported by grants from the Tianjin Health Technology Project(Grant No.2022QN106).
文摘Background:The nuclear receptor coactivator(NCOA)family,including NCOA1,NCOA2,and NCOA3,is critical in regulating gene expression through interactions with nuclear receptors and other transcription factors.These coactivators are implicated in various cancers,but their comprehensive roles across different cancer types remain poorly understood.Methods:We performed a pan-cancer bioinformatics analysis using data from The Cancer Genome Atlas and the Genotype-Tissue Expression project.We assessed the differential expression,copy number variations,mutations,methylation status,tumor mutation burden,microsatellite instability,and immune cell infiltration associated with NCOA family members across various cancers.Differential expression analysis was conducted using the DESeq2 package.Methylation data were analyzed using the ChAMP package,and immune cell infiltration was estimated using the CIBERSORT algorithm.Results:NCOA1 and NCOA2 were predominantly downregulated in multiple cancers,suggesting potential tumor suppressor roles,whereas NCOA3 was largely upregulated,indicating a consistent oncogenic function.These expression patterns significantly correlated with patient prognosis.Frequent copy number variations,particularly gains,and high mutation rates were observed in NCOA2.NCOA3 demonstrated consistent hypomethylation in tumors,which was associated with increased gene expression.Significant correlations were found between NCOA expression and tumor mutation burden,microsatellite instability,and immune cell infiltration,indicating their involvement in genomic instability and immune modulation.Conclusion:This comprehensive analysis reveals significant alterations in the expression,genomic,and epigenetic profiles of NCOA family members across various cancers.The findings highlight the multifaceted roles of NCOA1,NCOA2,and NCOA3 in tumorigenesis and their potential as biomarkers and therapeutic targets.Future research should focus on elucidating the mechanisms underlying the associations between NCOA expression,genomic alterations,and immune modulation to develop targeted cancer therapies.
文摘This paper designs a high-frequency stable wireless amplitude modulation(AM)system based on a Pierce circuit.The system utilizes an oscillator and comparator to generate a 20 kHz square wave with an adjustable duty cycle,combined with a 41 MHz carrier wave produced by a passive crystal oscillator Pierce circuit.A 100% modulation index amplitude modulation is achieved through the AD835 multiplier.The modulated signal is amplified by a power amplifier circuit and transmitted wirelessly via the transmitter antenna.Upon reception,the signal undergoes two-stage highfrequency amplification before passing through a Schottky diode envelope detector.The NE5532 shaping circuit then restores the square wave.Experimental results demonstrate reliable 11-meter transmission with carrier frequency deviation<0.75% and demodulation error<1%.
基金funded by the National Key Research and Development Program of China(2022YFB3803600)the National Natural Science Foundation of China(22368050,22378346)+4 种基金the Key Research and Development Program of Yunnan Province(202302AF080002)Yunnan Basic Applied Research Project(202401AT070460,202401AU070229)Xingdian Talent Support Program Project in Yunnan Province,the Scientific Research Fund Project of Yunnan Education Department(2024J0014,2024J0013)the Open Project of Yunnan Precious Metals Laboratory Co.,Ltd(YPML-2023050259,YPML-2023050260,YPML-20240502008)the Scientific Research and Innovation Project of Postgraduate Students in the Academic Degree of Yunnan University.
文摘The reasonable development and design of high-efficiency and low-cost electrocatalysts for hydrogen evolution reaction(HER)under industrial current densities are imperative for achieving carbon neutrality,while also posing challenges.In this study,an efficient electrocatalyst is successfully constructed through electrodeposition methods,which consists of monodispersed Pt loaded on amorphous/crystalline nickel–iron layered double hydroxide(Pt-SAs/ac-NiFe LDH).The Pt-SAs/ac-NiFe LDH demonstrates an elevated mass activity of 17.66 A mg_(Pt)^(−1)and a significant turnover frequency of 17.90 s^(−1)for HER in alkaline conditions under the overpotential of 100 mV.Meanwhile,for alkaline freshwater and seawater,Pt-SAs/ac-NiFe LDH exhibits ultra-low overpotentials of 141 and 138 mV to reach 1000 mA cm^(−2),respectively.Remarkably,it maintains stable operation for 100 h at 500 mA cm^(−2),showcasing its robustness and reliability.In situ Raman spectra reveal that Pt single atoms(Pt-SAs)accelerate interfacial water dissociation,thereby enhancing the HER kinetics in Pt-SAs/ac-NiFe LDH.Furthermore,theoretical calculation results show significant electronic interaction between the Pt-SAs and the ac-NiFe LDH support.The interaction significantly enhances water adsorption and dissociation,and balances the adsorption/desorption of hydrogen intermediates,ultimately improving HER performance.This research provides a viable method for designing efficient HER catalysts for water electrolysis in alkaline freshwater and seawater under industrial current densities.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12033007,61801458,12103058,12203058,12074309,and 61875205)the Key Project of Frontier Science Research of the Chinese Academy of Sciences(Grant No.QYZDB-SSW-SLH007)+2 种基金the Strategic Priority Research Program of CAS(Grant No.XDC07020200)the Youth Innovation Promotion Association,CAS(Grant Nos.2021408,2022413,and 2023425)the Research on Highly Sensitive Long-Wave Receiver Based on Rydberg Atoms(Grant No.1P2024000059)。
文摘The Bessel-like vector vortex beam(BlVVB)has gained increasing significance across numerous applications.However,its practical application is restricted by manufacturing difficulties and polarization manipulation.Thus,the ability to manipulate its degrees of freedom is highly desirable.In this paper,the full-domain polarization modulation of BlVVB within a hot atomic ensemble has been investigated.We begin with the theoretical analysis of the resonant magneto-optical effect of atoms with a horizontal linear-polarized beam and experimentally demonstrate precise manipulation of the polarization state across the entire domain of the BlVVB,achieving an error margin of less than 3°at various cross-sectional points.Our study provides a novel approach for the modulation of BlVVB based on atomic media,which holds potential applications in sensitive vector magnetometers,optical communications,and signal processing.
基金supported by the German Federal Ministry of Education and Research,Research Program Quantum Systems(Grant No.13N16774).
文摘Single-wavelength interferometry achieves high resolution for smooth surfaces but struggles with rough industrially relevant ones due to limited unambiguous measuring range and speckle effects.Multiwavelength interferometry addresses these challenges using synthetic wavelengths,enabling a balance between extended measurement range and resolution by combining several synthetic wavelengths.This approach holds immense potential for diverse industrial applications,yet it remains largely untapped due to the lack of suitable light sources.Existing solutions are constrained by limited flexibility in synthetic-wavelength generation and slow switching speeds.We demonstrate a light source for multiwavelength interferometry based on electro-optic single-sideband modulation.It reliably generates synthetic wavelengths with arbitrary values from centimeters to meters and switching time below 30 ms.This breakthrough paves the way for dynamic reconfigurable multiwavelength interferometry capable of adapting to complex surfaces and operating efficiently even outside laboratory settings.These capabilities unlock the full potential of multiwavelength interferometry,offering unprecedented flexibility and speed for industrial and technological applications.
基金supported in part by the National Key Research and Development Program of China under Grant 2021YFB2900500in part by the National Science Foundation of China under Grant 62001179+1 种基金in part by the Fundamental Research Funds for the Central Universities under Grant 2020kfyXJJS111。
文摘In this paper,Index Modulation(IM)aided Generalized Space-Time Block Coding(GSTBC)is proposed,which intrinsically exploits the benefits of IM concept,diversity gain and spatial multiplexing gain.Specifically,the information bits are partitioned into U groups,with each being modulated by IM symbols(i.e.Spatial Modulation(SM),Quadrature SM(QSM),etc).Next,the structure of GSTBC is invoked for each K IM symbol,and a total ofμ=U/K GSTBC codes are transmitted via T time slots.A Block Expectation Propagation(B-EP)detector is designed for the proposed IM-GSTBC structure.Moreover,the theoretical Average Bit Error Probability(ABEP)is derived for our IM-GSTBC system,which is confirmed by the simulation results and helpful for performance evaluation.Simulation results show that our proposed IM-GSTBC system is capable of striking an efficient trade-off between spatial multiplexing gain,spatial diversity gain as well as implementation cost imposed for both small-scale and large-scale MIMO antenna configurations.
基金This work is supported by a grant from the National Natural Science Foundation of China(No.82060809)the Natural Science Foundation of Guangdong Province(No.2017A030313453 and No.2018A030313638)Guangzhou Basic and Applied Basic Research Foundation(No.202102020417).
文摘Hyperlipidemia is a major risk factor for erectile dysfunction(ED).Oxidative stress and phenotypic modulation of corpus cavernosum smooth muscle cells(CcSMCs)are the key pathological factors of ED.N-acetylcysteine(NAC)can inhibit oxidative stress;however,whether NAc can alleviate pathological variations in the corpus cavernosum and promote erectile function recovery in hyperlipidemic rats remains unclear.A hyperlipidemia model was established using 27 eight-week-old male Sprague-Dawley(SD)rats fed a high-fat and high-cholesterol diet(hyperlipidemic rats,HR).In addition,9 male SD rats were fed a normal diet to serve as controls(NC).HR rats were divided into three groups:HR,HR+normal saline(NS),and HR+NAC(n=9 for each group;NS or NAc intraperitoneal injections were administered daily for 16 weeks).Subsequently,the lipid profiles,erectile function,oxidative stress,phenotypic modulation markers of ccsMCs,and tissue histology were analyzed.The experimental results revealed that erectile function was significantly impaired in the HR and HR+NS groups,but enhanced in the HR+NAC group.Abnormal lipid levels,over-activated oxidative stress,and multi-organ lesions observed in the HR and HR+NS groups were improved in the HR+NAC group.Moreover,the HR group showed significant phenotypic modulation of CCSMCs,which was also inhibited by NAC treatment.This report focuses on the therapeutic effect of NAc in restoring erectile function using a hyperlipidemic rat model by preventing CcSMC phenotypic modulationand attenuating oxidativestress.
基金supported by the Innovation Program for Quantum Science and Technology(Grant No.2021ZD0303400)the National Key R&D Program of China(Grant No.2022YFB3605602)+2 种基金the Key R&D Program of Jiangsu Province(Grant Nos.BE2020004-3 and BE2021026)the National Naturaal Science Foundation of China(Grant No.61974065)Jiangsu Special Professorship,Collaborative Innovation Center of Solid-State Lighting and Energysaving Electronics.
文摘We have investigated homoepitaxy of AlN films grown by molecular beam epitaxy on AlN/sapphire templates byadopting both the continuous growth method and the Al modulation epitaxy(AME)growth method.The continuous growthmethod encounters significant challenges in controlling the growth mode.As the precise Al/N=1.0 ratio is difficult toachieve,either the excessive Al-rich or N-rich growth mode occurs.In contrast,by adopting the AME growth method,sucha difficulty has been effectively overcome.By manipulating the supply time of the Al and nitrogen sources,we were able toproduce AlN films with much improved surface morphology.The first step of the AME method,only supplying Al atoms,is important to wet the surface and the Al adatoms can act as a surfactant.Optimization of the initial Al supply time caneffectively reduce the pit density on the grown AlN surface.The pits density dropped from 12 pits/μm^(2)to 1 pit/μm^(2)andthe surface roughness reduced from 0.72 nm to 0.3 nm in a 2×2μm^(2)area for the AME AlN film homoepitaxially grownon an AlN template.
