In this paper, we have evaluated a bidirectional wavelength division multiplexing passive optical network(WDM-PON) employing intensity modulated/direct detection optical orthogonal frequency division multiplexing(IM/D...In this paper, we have evaluated a bidirectional wavelength division multiplexing passive optical network(WDM-PON) employing intensity modulated/direct detection optical orthogonal frequency division multiplexing(IM/DD-OFDM). The proposed system employs 100 Gbit/s 16 quadrature amplitude modulation(16-QAM) downstream and 5 Gbit/s on-off keying(OOK) upstream wavelengths, respectively. The proposed system is considered low-cost as non-coherent IM/DD OFDM technology and a simple reflective semiconductor optical amplifier(RSOA) colorless transmitter are employed and no dispersion compensating fiber(DCF) is needed. Based on the bit error rate(BER) results of WDM signals, the proposed WDM-PON system can achieve up to 1.6 Tbit/s(100 Gbit/s/λ × 16 wavelengths) downstream transmission over a 30 km single mode fiber(SMF).展开更多
The 200 Gbit/s passive optical network(PON)is most likely to be the next-generation scheme following 50G PON.The costeffective direct detection(DD)system is the economical choice.However,larger-capacity DD systems wil...The 200 Gbit/s passive optical network(PON)is most likely to be the next-generation scheme following 50G PON.The costeffective direct detection(DD)system is the economical choice.However,larger-capacity DD systems will face much more serious power fading caused by chromatic dispersion(CD)combined with square-law DD and thereby significantly increases the complexity of equalization algorithms.In this paper,a 200 Gbit/s Nyquist 4-level pulse amplitude modulation(PAM4)single side-band(SSB)modulation-DD downlink scheme is designed,and a low complexity quadratic-nonlinear equalizer is proposed for this system.The computational complexity of the quadratic nonlinear equalizer is about 28%of that of the conventional Volterra nonlinear equalizer,while still exhibiting excellent nonlinear equalization ability.Simulation results for the 200 Gbit/s system with 20 km fiber transmission show that it can achieve a power budget of 29 dB,while a 30.4 dB power budget is obtained in the 50 Gbit/s experimental transmission.展开更多
The suppression of ablative Rayleigh–Taylor instability(ARTI)by a spatially modulated laser in inertial confinement fusion(ICF)is studied through numerical simulations.The results show that in the acceleration phase ...The suppression of ablative Rayleigh–Taylor instability(ARTI)by a spatially modulated laser in inertial confinement fusion(ICF)is studied through numerical simulations.The results show that in the acceleration phase of ICF implosion,the growth of ARTI can be suppressed by using a short-wavelength spatially modulated laser.The ARTI growth rate decreases as the wavelength of the spatially modulated laser decreases,and ARTI is completely suppressed after a certain wavelength has been reached.A spatially uniform laser is introduced to keep the state of motion of the implosion fluid consistent,and it is found that the proportion of the spatially modulated laser required for complete suppression of ARTI decreases as the wavelength continues to decrease.We also optimize the spatial intensity distribution of the spatially modulated laser.In addition,as the duration of the spatially modulated laser decreases,the proportion required for completely suppressing ARTI increases,but the required energy decreases.When the perturbation wavenumber decreases,the wavelength of the spatially modulated laser required for complete suppression of ARTI becomes longer.In the case of multimode perturbation,ARTI can also be significantly suppressed by a spatially modulated laser,and the perturbation amplitude can be reduced to less than 10% of that without a spatially modulated laser.We believe that the conclusions drawn from our simulations can provide the basis for new approaches to control ARTI in ICF.展开更多
Peroxymonosulfate(PMS)-based advanced oxidation technology has been proven to be a viable option for the decontamination of organic pollutants from water bodies.Advanced catalyst design is essential to this technology...Peroxymonosulfate(PMS)-based advanced oxidation technology has been proven to be a viable option for the decontamination of organic pollutants from water bodies.Advanced catalyst design is essential to this technology.Herein,a vanadium-doped LaFeO_(3) perovskite(LFO-V)featuring asymmetric Fe-O-V sites was rationally designed.Thanks to orbital electron interaction between Fe and V atoms,the modified electronic structure elevated electron density near the Fermi energy level while reducing the energy barrier toward effective PMS activation.This facilitated concurrent PMS reduction at the Fe sites to generate SO_(4)^(·-)and·OH(57.7%),and PMS oxidation at V sites to produce ^(1)O_(2)(42.3%).The LFO-V/PMS system demonstrated excellent tetracycline(TC)degradation performance with a 2-fold enhancement in rate constant compared to that of pristine LFO.Further,the LFO-V maintained long-term stability,and the toxicity of degradation intermediates was evaluated through microbial metabolomics.This work establishes an effective route to regulate the PMS activation pathways through precise electronic structure modulation,advancing the rational design of advanced Fenton-like catalysts.展开更多
We used hydrodynamic simulations and shock wave propagation theories to analyze the behavior of shock waves within Ti/Pt periodically modulated graded structures and their integration layers.The effects of the total n...We used hydrodynamic simulations and shock wave propagation theories to analyze the behavior of shock waves within Ti/Pt periodically modulated graded structures and their integration layers.The effects of the total number of periodic layers,the total thickness of graded materials and loading velocity on the integration layer thickness and behavior of pressure-strain rate were systematically investigated.The results reveal that,by adjusting the total number of periodically modulated layers,the total thickness of graded materials and loading velocity the pressure amplitudes of the reflected compressive and rarefaction waves at different interfaces of Ti/Pt periodically modulated graded materials can be precisely controlled.Furthermore,empirical structural design criteria for Ti/Pt periodically modulated graded materials are established.The thickness ratio variation between adjacent Ti/Pt layers in the periodic structure must exceed 0.32.After the collaborative design of the integration layer,Ti/Pt periodically modulated graded materials can achieve a controllable loading function with pressures ranging from 1.4 to 144 GPa and strain rates from 3.8×10^(4) to 1.7×10^(7) s^(–1).The outcomes of this research provide a theoretical and simulation basis for the optimized design of periodically modulated graded materials to be utilized in ramp compression experiments.展开更多
The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ...The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ simulations with varied protocols to evaluate the effectiveness of different descriptors in predicting mechanical properties across both low-and high-pressure regimes.Our findings demonstrate that conventional structural and configurational descriptors fail to correlate with the mechanical response following pressure release,whereas the activation energy descriptor exhibits robust linearity with shear modulus after correcting for pressure effects.Notably,the soft mode parameter emerges as an ideal and computationally efficient alternative for capturing this mechanical behavior.These findings provide critical insights into the influence of pressure on glassy properties,integrating the distinct features of compressed glasses into a unified theoretical framework.展开更多
The classical-quantum analogue offers a new platform for exploring extreme dynamic control of mechanical systems.In this work,the concept of the stimulated adiabatic passage of quantum states is extended to mechanical...The classical-quantum analogue offers a new platform for exploring extreme dynamic control of mechanical systems.In this work,the concept of the stimulated adiabatic passage of quantum states is extended to mechanical systems for achieving unidirectional energy transportation.The mechanical analog of stimulated adiabatic passage is realized in three mechanical resonators coupled with the time-varying stiffness,which are delicately modulated to mimic the selective population of quantum states.Based on the tight-binding approximation,an analytical model for the classical-quantum analogue of the adiabatic passage effect is established to realize the one-way energy transfer control.Numerical results demonstrate that the vibration energy acquired from an initially excited resonator can be transferred to the target one via an intermediate resonator,while flow in the reverse direction is prohibited due to energy localization in the intermediate resonator.The model holds application potentials in energy suppression and harvesting,and offers promising prospects for unidirectional wave and vibration control.展开更多
In this study,we explored a one-step direct synthesis of NH3 under mild experimental conditions utilizing pulse-modulated microwave plasma technology at atmospheric pressure.At a substantial gas flow rate,a microwave ...In this study,we explored a one-step direct synthesis of NH3 under mild experimental conditions utilizing pulse-modulated microwave plasma technology at atmospheric pressure.At a substantial gas flow rate,a microwave plasma jet was formed and the microwave-assisted ammonia synthesis can be realized.Impacts of various parameters including the gas flow rate,gas component,microwave absorbed power,pulse modulation frequency,and pulse duty cycle on ammonia synthesis were systematically investigated.To indicate the reaction path of ammonia synthesis,the distributions of both the gas temperature and active species were also studied using optical emission spectra technology.It is found that a considerable amount of ammonia was directly synthesized without involvement of any catalysts,the highest ammonia production rate and energy efficiency(EE),up to 2.93μmol·min^(-1) and 6.64×10^(-2)g·(k W·h)^(-1),respectively,were achieved under low microwave power of 84.42 W.The duty cycle has obvious influences on the synthesis efficiency,compared to a duty cycle of 80%,the ammonia synthesis rate,EE and nitrogen conversion decreased by about 22%at a duty cycle of 100%.This finding underscores the significance of incorporating pulse modulation in the microwave discharge process for ammonia synthesis.Furthermore,it was found that vibrational excitation of microwave plasma has a significant driving effect on ammonia synthesis.展开更多
The 4-level pulse amplitude modulation(PAM4)based on an 23 GHz ultrabroadband directly modulated laser(DML)was proposed.We have experimentally demonstrated that based on intensity modulation and direct detection(IMDD)...The 4-level pulse amplitude modulation(PAM4)based on an 23 GHz ultrabroadband directly modulated laser(DML)was proposed.We have experimentally demonstrated that based on intensity modulation and direct detection(IMDD)56 Gbps per wavelength PAM4 signals transferred over 35 km standard single mode fiber(SSMF)without any optical amplification and we have achieved the bit error rate(BER)of the PAM4 transmission was under 2.9×10–4 by using feed forward equalization(FFE).展开更多
It is very attractive to apply a directly modulated laser(DML)-based intensity-modulation and direct-detection(IM/DD)system in future data centers and 5G fronthaul networks due to the advantages of low cost,low system...It is very attractive to apply a directly modulated laser(DML)-based intensity-modulation and direct-detection(IM/DD)system in future data centers and 5G fronthaul networks due to the advantages of low cost,low system complexity,and high energy efficiency,which perfectly match the application scenarios of the data centers and 5G fronthaul networks,in which a large number of high-speed optical interconnections are needed.However,as the data traffic in the data centers and 5G fronthaul networks continues to grow exponentially,the future requirements for data rates beyond 100 Gbaud are challenging the existing DML-based IM/DD system,and the main bottleneck is the modulation bandwidth of the DML.In this paper,the data rate demands and technical standards of the data centers and 5G fronthaul networks are reviewed in detail.With the modulation bandwidth requirements,the technical routes and achievements of recent DMLs are reviewed and discussed.In this way,the prospects,challenges,and future development of DMLs in the applications of future data centers and 5G fronthaul networks are comprehensively explored.展开更多
We investigate a wavelength-division-multiplexing passive optical network(WDM-PON) with centralized lightwave and direct detection. The system is demonstrated for symmetric 10 Gbit/s differential phase-shift keying(DP...We investigate a wavelength-division-multiplexing passive optical network(WDM-PON) with centralized lightwave and direct detection. The system is demonstrated for symmetric 10 Gbit/s differential phase-shift keying(DPSK) downstream signals and on-off keying(OOK) upstream signals,respectively. A wavelength reused scheme is employed to carry the upstream data by using a reflective semiconductor optical amplifier(RSOA) as an intensity modulator at the optical network unit(ONU). The constant-intensity property of the DPSK modulation format can keep high extinction ratio(ER) of downstream signal and reduce the crosstalk to the upstream signal. The bit error rate(BER) performance of our scheme shows that the proposed 10 Gbit/s symmetric WDM-PON can achieve error free transmission over 25-km-long fiber transmission with low power penalty.展开更多
In this paper,a novel directional modulation(DM)network utilizing the distributed active intelligent reflecting surface(IRS)to enhance the secrecy sum-rate(SSR)performance is established,with each unmanned aerial vehi...In this paper,a novel directional modulation(DM)network utilizing the distributed active intelligent reflecting surface(IRS)to enhance the secrecy sum-rate(SSR)performance is established,with each unmanned aerial vehicle(UAV)hanging an IRS.The degree of freedom(DoF)is only two in the single-IRS-aided DM network,which will seriously limit its rate performance.Multiple active IRSs will create more DoFs for DM network and dramatically enhance its rate.Three IRS-user matching methods,path loss coefficient(PLC)matching,distance matching,and signal-to-interference-plus-noise ratio(SINR)matching,are proposed to enhance the SSR performance,where all IRSs are equipartitioned into two parts,one part is matched to Bob and the other part to Eve.The double layer leakage(DLL)and minimum-mean square error(MMSE)rules,called DLL-MMSE,are adopted to construct beamforming at transmitter,IRS and receiver,respectively.The double layer null-space projection(DLNSP),Rayleigh ratio(RR)and MMSE schemes,called DLNSP-RR-MMSE,are used to acquire the transmit beamforming vector,phase shift matrix(PSM)and receive beamforming vector,respectively.Simulation results show that the proposed SINR matching scheme outperforms the remaining two ones in terms of SSR.It is also verified that a significant SSR enhancement over single IRS is achieved by using multiple distributed IRSs.展开更多
In this paper,the covert age of information(CAoI),which characterizes the timeliness and covertness performance of communication,is first investigated in the short-packet covert communication with time modulated retro...In this paper,the covert age of information(CAoI),which characterizes the timeliness and covertness performance of communication,is first investigated in the short-packet covert communication with time modulated retrodirective array(TMRDA).Specifically,the TMRDA is designed to maximize the antenna gain in the target direction while the side lobe is sufficiently suppressed.On this basis,the covertness constraint and CAoI are derived in closed form.To facilitate the covert transmission design,the transmit power and block-length are jointly optimized to minimize the CAoI,which demonstrates the trade-off between covertness and timelessness.Our results illustrate that there exists an optimal block-length that yields the minimum CAoI,and the presented optimization results can achieve enhanced performance compared with the fixed block-length case.Additionally,we observe that smaller beam pointing error at Bob leads to improvements in CAoI.展开更多
Direct ethanol fuel cells(DEFCs)are a promising alternative to conventional energy sources,offering high energy density,environmental sustainability,and operational safety.Compared to methanol fuel cells,DEFCs exhibit...Direct ethanol fuel cells(DEFCs)are a promising alternative to conventional energy sources,offering high energy density,environmental sustainability,and operational safety.Compared to methanol fuel cells,DEFCs exhibit lower toxicity and a more mature preparation process.Unlike hydrogen fuel cells,DEFCs provide superior storage and transport feasibility,as well as cost-effectiveness,significantly enhancing their commercial viability.However,the stable C-C bond in ethanol creates a high activation energy barrier,often resulting in incomplete electrooxidation.Current commercial platinum(Pt)-and palladium(Pd)-based catalysts demonstrate low C-C bond cleavage efficiency(<7.5%),severely limiting DEFC energy output and power density.Furthermore,high catalyst costs and insufficient activity impede large-scale commercialization.Recent advances in DEFC anode catalyst design have focused on optimizing material composition and elucidating catalytic mechanisms.This review systematically examines developments in ethanol electrooxidation catalysts over the past five years,highlighting strategies to improve C1 pathway selectivity and C-C bond activation.Key approaches,such as alloying,nanostructure engineering,and interfacial synergy effects,are discussed alongside their mechanistic implications.Finally,we outline current challenges and future prospects for DEFC commercialization.展开更多
The differential event rate for direct detection of dark matter,both the time averaged and the modulated one due to the motion of the Earth,are discussed.The calculations focus on relatively light cold dark matter can...The differential event rate for direct detection of dark matter,both the time averaged and the modulated one due to the motion of the Earth,are discussed.The calculations focus on relatively light cold dark matter candidates (WIMP) and low energy transfers.It is shown that for sufficiently light WIMPs the extraction of relatively large nucleon cross sections is possible.Furthermore for some WIMP masses the modulation amplitude may change sign,meaning that,in such a case,the maximum rate may occur six months later than naively expected.This effect can be exploited to yield information about the mass of the dark matter candidate,if and when the observation of the modulation of the event rate is established.展开更多
Currently,the global 5G network,cloud computing,and data center industries are experiencing rapid development.The continuous growth of data center traffic has driven the vigorous progress in high-speed optical transce...Currently,the global 5G network,cloud computing,and data center industries are experiencing rapid development.The continuous growth of data center traffic has driven the vigorous progress in high-speed optical transceivers for optical interconnection within data centers.The electro-absorption modulated laser(EML),which is widely used in optical fiber communications,data centers,and high-speed data transmission systems,represents a high-performance photoelectric conversion device.Compared to traditional directly modulated lasers(DMLs),EMLs demonstrate lower frequency chirp and higher modulation bandwidth,enabling support for higher data rates and longer transmission distances.This article introduces the composition,working principles,manufacturing processes,and applications of EMLs.It reviews the progress on advanced indium phosphide(InP)-based EML devices from research institutions worldwide,while summarizing and comparing data transmission rates and key technical approaches across various studies.展开更多
Wavelength tunable and directly modulated distributed Bragg reflector （DBR） lasers with butt-joint technology are designed, fabricated and characterized. The DBR laser consists of a gain section and a DBR section. T...Wavelength tunable and directly modulated distributed Bragg reflector （DBR） lasers with butt-joint technology are designed, fabricated and characterized. The DBR laser consists of a gain section and a DBR section. To increase the electrical isolation between the gain section and the DBR section, parts of a p-doped material in the isolation region are etched off selectively. Over 2kΩ isolation resistance is realized ultimately without the need of ion implantation, which simplifies the fabrication process. The laser exhibits high speed modulation with a large tunable range. The 3dB direct modulation bandwidth of the device is over 8GHz in a 12nm tunable range. This widely tunable DBR laser with the simple structure is promising as a colorless light source for the next-generation time and wavelength division multiplexed passive optical network （TWDM-PON） systems.展开更多
Microrobots play an essential role in early diagnosis and precision medicine with the increasing demands for controllability in bio-medicine and micromanipulation,which can complete the pre-designed behavior under ext...Microrobots play an essential role in early diagnosis and precision medicine with the increasing demands for controllability in bio-medicine and micromanipulation,which can complete the pre-designed behavior under external stimulation.However,most microrobots are currently made of a single material system and focus on fabricating a driving module as the main structure of microrobots.This hinders the integration of diverse functions in one microrobot to fulfill the complex application.Here,a multi-material and multi-module hand-microrobot based on femtosecond laser direct writing technology is proposed,which has a pH-responsive capturing module and a magnetic-responsive transportation module(MRTM).This microrobot can not only respond to pH for capturing and releasing objects,but also respond to magnetic fields for cargo delivery even with obstacles.The two responding modules of the hand-microrobot are fabricated independently,and can collaborate with each other to achieve the delivery of target objects like polystyrene(PS)microsphere(10µm)or 786-O cell by capturing,transporting,and spatial rolling.Besides,the MRTM can be locally fabricated on any prefabricated static structure,so that the whole microrobot can achieve controllable motion.This strategy is expected to be used to manipulate cells,deliver drugs for precise treatment,and environmental treatment.展开更多
A 10 Gbit/s 16-km-long reconfigurable wavelength-division-multiplexing passive optical network(WDM-PON) is presented empowered by a low-cost multi-channel directly modulated laser(DML) module. Compared with the case u...A 10 Gbit/s 16-km-long reconfigurable wavelength-division-multiplexing passive optical network(WDM-PON) is presented empowered by a low-cost multi-channel directly modulated laser(DML) module. Compared with the case using discrete devices in conventional scheme, the proposed DML module provides a cost-effective solution with reduced complexity. The clear eye diagram and the bit error rate(BER) of less than 2×10^(-7) with a sensitivity of-7 dB m are obtained. Due to the special packaging design, the crosstalk between channels under condition of simultaneous operation can be negligible.展开更多
Two-dimensional(2D)superconductors have attracted significant research interest due to their promising potential applications in optoelectronic and microelectronic devices.Herein,we employ first-principles calculation...Two-dimensional(2D)superconductors have attracted significant research interest due to their promising potential applications in optoelectronic and microelectronic devices.Herein,we employ first-principles calculations to predicted a new 2D conventional superconductor,Tc_(2)B_(2),demonstrating its stable structural configuration.Remarkably,under biaxial strain,the superconducting transition temperature(T_(c))of Tc_(2)B_(2)demonstrates a significant enhancement,achieving 19.5 K under 3%compressive strain and 9.2 K under 11%tensile strain.Our study reveals that strain-induced modifications in Fermi surface topology significantly enhance the Fermi surface nesting effect,which amplifies electron–phonon coupling interactions and consequently elevates Tc.Additionally,the presence of the Lifshitz transition results in a more pronounced rise in Tc under compressive strain compared to tensile strain.These insights offer important theoretical guidance for designing 2D superconductors with high-Tc through strain modulation.展开更多
基金supported by the Erciyes University Scientific Research Projects Coordination Unit (No.FDK-2019-8750)。
文摘In this paper, we have evaluated a bidirectional wavelength division multiplexing passive optical network(WDM-PON) employing intensity modulated/direct detection optical orthogonal frequency division multiplexing(IM/DD-OFDM). The proposed system employs 100 Gbit/s 16 quadrature amplitude modulation(16-QAM) downstream and 5 Gbit/s on-off keying(OOK) upstream wavelengths, respectively. The proposed system is considered low-cost as non-coherent IM/DD OFDM technology and a simple reflective semiconductor optical amplifier(RSOA) colorless transmitter are employed and no dispersion compensating fiber(DCF) is needed. Based on the bit error rate(BER) results of WDM signals, the proposed WDM-PON system can achieve up to 1.6 Tbit/s(100 Gbit/s/λ × 16 wavelengths) downstream transmission over a 30 km single mode fiber(SMF).
基金ZTE Industry-University-Institute Cooperation Funds under Grant No.HC-CN-20230105001National Natural Science Foundation of China under Grant No.62001045。
文摘The 200 Gbit/s passive optical network(PON)is most likely to be the next-generation scheme following 50G PON.The costeffective direct detection(DD)system is the economical choice.However,larger-capacity DD systems will face much more serious power fading caused by chromatic dispersion(CD)combined with square-law DD and thereby significantly increases the complexity of equalization algorithms.In this paper,a 200 Gbit/s Nyquist 4-level pulse amplitude modulation(PAM4)single side-band(SSB)modulation-DD downlink scheme is designed,and a low complexity quadratic-nonlinear equalizer is proposed for this system.The computational complexity of the quadratic nonlinear equalizer is about 28%of that of the conventional Volterra nonlinear equalizer,while still exhibiting excellent nonlinear equalization ability.Simulation results for the 200 Gbit/s system with 20 km fiber transmission show that it can achieve a power budget of 29 dB,while a 30.4 dB power budget is obtained in the 50 Gbit/s experimental transmission.
基金supported by the National Natural Science Foundation of China(NSFC)(Nos.12074399,12204500,and 12004403)the Key Projects of Intergovernmental International Scientific and Technological Innovation Cooperation(No.2021YFE0116700)+1 种基金the Shanghai Natural Science Foundation(No.20ZR1464400)the Shanghai Sailing Program(No.22YF1455300).
文摘The suppression of ablative Rayleigh–Taylor instability(ARTI)by a spatially modulated laser in inertial confinement fusion(ICF)is studied through numerical simulations.The results show that in the acceleration phase of ICF implosion,the growth of ARTI can be suppressed by using a short-wavelength spatially modulated laser.The ARTI growth rate decreases as the wavelength of the spatially modulated laser decreases,and ARTI is completely suppressed after a certain wavelength has been reached.A spatially uniform laser is introduced to keep the state of motion of the implosion fluid consistent,and it is found that the proportion of the spatially modulated laser required for complete suppression of ARTI decreases as the wavelength continues to decrease.We also optimize the spatial intensity distribution of the spatially modulated laser.In addition,as the duration of the spatially modulated laser decreases,the proportion required for completely suppressing ARTI increases,but the required energy decreases.When the perturbation wavenumber decreases,the wavelength of the spatially modulated laser required for complete suppression of ARTI becomes longer.In the case of multimode perturbation,ARTI can also be significantly suppressed by a spatially modulated laser,and the perturbation amplitude can be reduced to less than 10% of that without a spatially modulated laser.We believe that the conclusions drawn from our simulations can provide the basis for new approaches to control ARTI in ICF.
基金supported by the National Natural Science Foundation of China(Nos.W2412093 and 52170068)the Fundamental Research Funds for the Central Universities(No.DUT24RC(3)079).
文摘Peroxymonosulfate(PMS)-based advanced oxidation technology has been proven to be a viable option for the decontamination of organic pollutants from water bodies.Advanced catalyst design is essential to this technology.Herein,a vanadium-doped LaFeO_(3) perovskite(LFO-V)featuring asymmetric Fe-O-V sites was rationally designed.Thanks to orbital electron interaction between Fe and V atoms,the modified electronic structure elevated electron density near the Fermi energy level while reducing the energy barrier toward effective PMS activation.This facilitated concurrent PMS reduction at the Fe sites to generate SO_(4)^(·-)and·OH(57.7%),and PMS oxidation at V sites to produce ^(1)O_(2)(42.3%).The LFO-V/PMS system demonstrated excellent tetracycline(TC)degradation performance with a 2-fold enhancement in rate constant compared to that of pristine LFO.Further,the LFO-V maintained long-term stability,and the toxicity of degradation intermediates was evaluated through microbial metabolomics.This work establishes an effective route to regulate the PMS activation pathways through precise electronic structure modulation,advancing the rational design of advanced Fenton-like catalysts.
基金Funded by the Guangdong Major Project of Basic and Applied Basic Research(No.2021B0301030001)the Foundation of National Key Laboratory of Shock Wave and Detonation Physics(No.JCKYS2022212004)。
文摘We used hydrodynamic simulations and shock wave propagation theories to analyze the behavior of shock waves within Ti/Pt periodically modulated graded structures and their integration layers.The effects of the total number of periodic layers,the total thickness of graded materials and loading velocity on the integration layer thickness and behavior of pressure-strain rate were systematically investigated.The results reveal that,by adjusting the total number of periodically modulated layers,the total thickness of graded materials and loading velocity the pressure amplitudes of the reflected compressive and rarefaction waves at different interfaces of Ti/Pt periodically modulated graded materials can be precisely controlled.Furthermore,empirical structural design criteria for Ti/Pt periodically modulated graded materials are established.The thickness ratio variation between adjacent Ti/Pt layers in the periodic structure must exceed 0.32.After the collaborative design of the integration layer,Ti/Pt periodically modulated graded materials can achieve a controllable loading function with pressures ranging from 1.4 to 144 GPa and strain rates from 3.8×10^(4) to 1.7×10^(7) s^(–1).The outcomes of this research provide a theoretical and simulation basis for the optimized design of periodically modulated graded materials to be utilized in ramp compression experiments.
基金supported by the National Natural Science Foundation of China (Grant Nos.T2325004 and 52161160330)the National Natural Science Foundation of China (Grants No.12504233)+2 种基金Advanced MaterialsNational Science and Technology Major Project (Grant No.2024ZD0606900)the Talent Hub for “AI+New Materials” Basic Researchthe Key Research and Development Program of Ningbo (Grant No.2025Z088)。
文摘The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ simulations with varied protocols to evaluate the effectiveness of different descriptors in predicting mechanical properties across both low-and high-pressure regimes.Our findings demonstrate that conventional structural and configurational descriptors fail to correlate with the mechanical response following pressure release,whereas the activation energy descriptor exhibits robust linearity with shear modulus after correcting for pressure effects.Notably,the soft mode parameter emerges as an ideal and computationally efficient alternative for capturing this mechanical behavior.These findings provide critical insights into the influence of pressure on glassy properties,integrating the distinct features of compressed glasses into a unified theoretical framework.
基金supported by the National Key R&D Program of China(2024YFB3408700 and 2024YFB3408702)the National Natural Science Foundation of China(Grant Numbers 12225203,12402100,11991030,11991033,11622215,and 11872111)the 111 project(Grant Number B16003).
文摘The classical-quantum analogue offers a new platform for exploring extreme dynamic control of mechanical systems.In this work,the concept of the stimulated adiabatic passage of quantum states is extended to mechanical systems for achieving unidirectional energy transportation.The mechanical analog of stimulated adiabatic passage is realized in three mechanical resonators coupled with the time-varying stiffness,which are delicately modulated to mimic the selective population of quantum states.Based on the tight-binding approximation,an analytical model for the classical-quantum analogue of the adiabatic passage effect is established to realize the one-way energy transfer control.Numerical results demonstrate that the vibration energy acquired from an initially excited resonator can be transferred to the target one via an intermediate resonator,while flow in the reverse direction is prohibited due to energy localization in the intermediate resonator.The model holds application potentials in energy suppression and harvesting,and offers promising prospects for unidirectional wave and vibration control.
基金supported by National Natural Science Foundation of China(Nos.52077026,51977023,52177126 and 12475253)the Fundamental Research Funds for the Central Universities(No.DUT23YG227)the Dalian Life&Health Guiding Project(No.2023ZXYG34)。
文摘In this study,we explored a one-step direct synthesis of NH3 under mild experimental conditions utilizing pulse-modulated microwave plasma technology at atmospheric pressure.At a substantial gas flow rate,a microwave plasma jet was formed and the microwave-assisted ammonia synthesis can be realized.Impacts of various parameters including the gas flow rate,gas component,microwave absorbed power,pulse modulation frequency,and pulse duty cycle on ammonia synthesis were systematically investigated.To indicate the reaction path of ammonia synthesis,the distributions of both the gas temperature and active species were also studied using optical emission spectra technology.It is found that a considerable amount of ammonia was directly synthesized without involvement of any catalysts,the highest ammonia production rate and energy efficiency(EE),up to 2.93μmol·min^(-1) and 6.64×10^(-2)g·(k W·h)^(-1),respectively,were achieved under low microwave power of 84.42 W.The duty cycle has obvious influences on the synthesis efficiency,compared to a duty cycle of 80%,the ammonia synthesis rate,EE and nitrogen conversion decreased by about 22%at a duty cycle of 100%.This finding underscores the significance of incorporating pulse modulation in the microwave discharge process for ammonia synthesis.Furthermore,it was found that vibrational excitation of microwave plasma has a significant driving effect on ammonia synthesis.
基金supported by National Key Research and Development Program of China (No. 2018YFB2201101)the National Natural Science Foundation of China (Nos. 61635001 and 61575186)
文摘The 4-level pulse amplitude modulation(PAM4)based on an 23 GHz ultrabroadband directly modulated laser(DML)was proposed.We have experimentally demonstrated that based on intensity modulation and direct detection(IMDD)56 Gbps per wavelength PAM4 signals transferred over 35 km standard single mode fiber(SSMF)without any optical amplification and we have achieved the bit error rate(BER)of the PAM4 transmission was under 2.9×10–4 by using feed forward equalization(FFE).
基金The International Cooperation Project of Sichuan Province,Sichuan Science and Technology Program(2020YFH0108)NWO Zwaartekracht program on Integrated Nanophotonics+2 种基金ZJUTU/e IDEAS projectand Key Research and Development Program of China(2018YFE0201000)Anhui Provincial Natural Science Foundation of China(1808085MF186).
文摘It is very attractive to apply a directly modulated laser(DML)-based intensity-modulation and direct-detection(IM/DD)system in future data centers and 5G fronthaul networks due to the advantages of low cost,low system complexity,and high energy efficiency,which perfectly match the application scenarios of the data centers and 5G fronthaul networks,in which a large number of high-speed optical interconnections are needed.However,as the data traffic in the data centers and 5G fronthaul networks continues to grow exponentially,the future requirements for data rates beyond 100 Gbaud are challenging the existing DML-based IM/DD system,and the main bottleneck is the modulation bandwidth of the DML.In this paper,the data rate demands and technical standards of the data centers and 5G fronthaul networks are reviewed in detail.With the modulation bandwidth requirements,the technical routes and achievements of recent DMLs are reviewed and discussed.In this way,the prospects,challenges,and future development of DMLs in the applications of future data centers and 5G fronthaul networks are comprehensively explored.
基金the Alexander von Humboldt Foundation for their support
文摘We investigate a wavelength-division-multiplexing passive optical network(WDM-PON) with centralized lightwave and direct detection. The system is demonstrated for symmetric 10 Gbit/s differential phase-shift keying(DPSK) downstream signals and on-off keying(OOK) upstream signals,respectively. A wavelength reused scheme is employed to carry the upstream data by using a reflective semiconductor optical amplifier(RSOA) as an intensity modulator at the optical network unit(ONU). The constant-intensity property of the DPSK modulation format can keep high extinction ratio(ER) of downstream signal and reduce the crosstalk to the upstream signal. The bit error rate(BER) performance of our scheme shows that the proposed 10 Gbit/s symmetric WDM-PON can achieve error free transmission over 25-km-long fiber transmission with low power penalty.
基金supported in part by the National Key Research and Development Program of China(No.2023YFF0612900).
文摘In this paper,a novel directional modulation(DM)network utilizing the distributed active intelligent reflecting surface(IRS)to enhance the secrecy sum-rate(SSR)performance is established,with each unmanned aerial vehicle(UAV)hanging an IRS.The degree of freedom(DoF)is only two in the single-IRS-aided DM network,which will seriously limit its rate performance.Multiple active IRSs will create more DoFs for DM network and dramatically enhance its rate.Three IRS-user matching methods,path loss coefficient(PLC)matching,distance matching,and signal-to-interference-plus-noise ratio(SINR)matching,are proposed to enhance the SSR performance,where all IRSs are equipartitioned into two parts,one part is matched to Bob and the other part to Eve.The double layer leakage(DLL)and minimum-mean square error(MMSE)rules,called DLL-MMSE,are adopted to construct beamforming at transmitter,IRS and receiver,respectively.The double layer null-space projection(DLNSP),Rayleigh ratio(RR)and MMSE schemes,called DLNSP-RR-MMSE,are used to acquire the transmit beamforming vector,phase shift matrix(PSM)and receive beamforming vector,respectively.Simulation results show that the proposed SINR matching scheme outperforms the remaining two ones in terms of SSR.It is also verified that a significant SSR enhancement over single IRS is achieved by using multiple distributed IRSs.
文摘In this paper,the covert age of information(CAoI),which characterizes the timeliness and covertness performance of communication,is first investigated in the short-packet covert communication with time modulated retrodirective array(TMRDA).Specifically,the TMRDA is designed to maximize the antenna gain in the target direction while the side lobe is sufficiently suppressed.On this basis,the covertness constraint and CAoI are derived in closed form.To facilitate the covert transmission design,the transmit power and block-length are jointly optimized to minimize the CAoI,which demonstrates the trade-off between covertness and timelessness.Our results illustrate that there exists an optimal block-length that yields the minimum CAoI,and the presented optimization results can achieve enhanced performance compared with the fixed block-length case.Additionally,we observe that smaller beam pointing error at Bob leads to improvements in CAoI.
基金supported by the National Natural Science Foundation of China(22472023,22202037)the Jilin Province Science and Technology Development Program(20250102077JC)the Fundamental Research Funds for the Central Universities(2412024QD014,2412023QD019).
文摘Direct ethanol fuel cells(DEFCs)are a promising alternative to conventional energy sources,offering high energy density,environmental sustainability,and operational safety.Compared to methanol fuel cells,DEFCs exhibit lower toxicity and a more mature preparation process.Unlike hydrogen fuel cells,DEFCs provide superior storage and transport feasibility,as well as cost-effectiveness,significantly enhancing their commercial viability.However,the stable C-C bond in ethanol creates a high activation energy barrier,often resulting in incomplete electrooxidation.Current commercial platinum(Pt)-and palladium(Pd)-based catalysts demonstrate low C-C bond cleavage efficiency(<7.5%),severely limiting DEFC energy output and power density.Furthermore,high catalyst costs and insufficient activity impede large-scale commercialization.Recent advances in DEFC anode catalyst design have focused on optimizing material composition and elucidating catalytic mechanisms.This review systematically examines developments in ethanol electrooxidation catalysts over the past five years,highlighting strategies to improve C1 pathway selectivity and C-C bond activation.Key approaches,such as alloying,nanostructure engineering,and interfacial synergy effects,are discussed alongside their mechanistic implications.Finally,we outline current challenges and future prospects for DEFC commercialization.
文摘The differential event rate for direct detection of dark matter,both the time averaged and the modulated one due to the motion of the Earth,are discussed.The calculations focus on relatively light cold dark matter candidates (WIMP) and low energy transfers.It is shown that for sufficiently light WIMPs the extraction of relatively large nucleon cross sections is possible.Furthermore for some WIMP masses the modulation amplitude may change sign,meaning that,in such a case,the maximum rate may occur six months later than naively expected.This effect can be exploited to yield information about the mass of the dark matter candidate,if and when the observation of the modulation of the event rate is established.
基金supported by the Strategic Priority Research Program of CAS(Grant No.XDB43020202)the Natural Science Foundation of China(Grant Nos.61934007,62274153,62090053).
文摘Currently,the global 5G network,cloud computing,and data center industries are experiencing rapid development.The continuous growth of data center traffic has driven the vigorous progress in high-speed optical transceivers for optical interconnection within data centers.The electro-absorption modulated laser(EML),which is widely used in optical fiber communications,data centers,and high-speed data transmission systems,represents a high-performance photoelectric conversion device.Compared to traditional directly modulated lasers(DMLs),EMLs demonstrate lower frequency chirp and higher modulation bandwidth,enabling support for higher data rates and longer transmission distances.This article introduces the composition,working principles,manufacturing processes,and applications of EMLs.It reviews the progress on advanced indium phosphide(InP)-based EML devices from research institutions worldwide,while summarizing and comparing data transmission rates and key technical approaches across various studies.
基金Supported by the National Key Project under Grant No 2016YFB0402301the National High Technology Research and Development Program of China under Grant No 2013AA014502the National Natural Science Foundation of China under Grant Nos 61635010,61320106013,61474112,61321063 and 61274071
文摘Wavelength tunable and directly modulated distributed Bragg reflector （DBR） lasers with butt-joint technology are designed, fabricated and characterized. The DBR laser consists of a gain section and a DBR section. To increase the electrical isolation between the gain section and the DBR section, parts of a p-doped material in the isolation region are etched off selectively. Over 2kΩ isolation resistance is realized ultimately without the need of ion implantation, which simplifies the fabrication process. The laser exhibits high speed modulation with a large tunable range. The 3dB direct modulation bandwidth of the device is over 8GHz in a 12nm tunable range. This widely tunable DBR laser with the simple structure is promising as a colorless light source for the next-generation time and wavelength division multiplexed passive optical network （TWDM-PON） systems.
基金financial support of the National Key R&D Program of China(Grant Nos.2024YFB4607402 and 2016YFA0200500)National Natural Science Foundation of China(NSFC,Grant Nos.61975213,61475164 and 61205194)International Partnership Program of Chinese Academy of Sciences(GJHZ2021130)。
文摘Microrobots play an essential role in early diagnosis and precision medicine with the increasing demands for controllability in bio-medicine and micromanipulation,which can complete the pre-designed behavior under external stimulation.However,most microrobots are currently made of a single material system and focus on fabricating a driving module as the main structure of microrobots.This hinders the integration of diverse functions in one microrobot to fulfill the complex application.Here,a multi-material and multi-module hand-microrobot based on femtosecond laser direct writing technology is proposed,which has a pH-responsive capturing module and a magnetic-responsive transportation module(MRTM).This microrobot can not only respond to pH for capturing and releasing objects,but also respond to magnetic fields for cargo delivery even with obstacles.The two responding modules of the hand-microrobot are fabricated independently,and can collaborate with each other to achieve the delivery of target objects like polystyrene(PS)microsphere(10µm)or 786-O cell by capturing,transporting,and spatial rolling.Besides,the MRTM can be locally fabricated on any prefabricated static structure,so that the whole microrobot can achieve controllable motion.This strategy is expected to be used to manipulate cells,deliver drugs for precise treatment,and environmental treatment.
基金supported by the National High-Tech Research and Development Program of China(No.2013AA014201)the National Natural Science Foundation of China(Nos.61575186 and 61635001)
文摘A 10 Gbit/s 16-km-long reconfigurable wavelength-division-multiplexing passive optical network(WDM-PON) is presented empowered by a low-cost multi-channel directly modulated laser(DML) module. Compared with the case using discrete devices in conventional scheme, the proposed DML module provides a cost-effective solution with reduced complexity. The clear eye diagram and the bit error rate(BER) of less than 2×10^(-7) with a sensitivity of-7 dB m are obtained. Due to the special packaging design, the crosstalk between channels under condition of simultaneous operation can be negligible.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12274169,12122405,and 52072188)the National Key Research and Development Program of China(Grant No.2022YFA1402304)+1 种基金the Program for Science and Technology Innovation Team in Zhejiang Province,China(Grant No.2021R01004)the Fundamental Research Funds for the Central Universities.
文摘Two-dimensional(2D)superconductors have attracted significant research interest due to their promising potential applications in optoelectronic and microelectronic devices.Herein,we employ first-principles calculations to predicted a new 2D conventional superconductor,Tc_(2)B_(2),demonstrating its stable structural configuration.Remarkably,under biaxial strain,the superconducting transition temperature(T_(c))of Tc_(2)B_(2)demonstrates a significant enhancement,achieving 19.5 K under 3%compressive strain and 9.2 K under 11%tensile strain.Our study reveals that strain-induced modifications in Fermi surface topology significantly enhance the Fermi surface nesting effect,which amplifies electron–phonon coupling interactions and consequently elevates Tc.Additionally,the presence of the Lifshitz transition results in a more pronounced rise in Tc under compressive strain compared to tensile strain.These insights offer important theoretical guidance for designing 2D superconductors with high-Tc through strain modulation.
