We analyzed statistically the linear correlation of the solvatochromic shifts of the stilbazolium-like dyes in the nonselected solvents with the reaction field function, L(?T) — bL(n2), and the solvent polarity param...We analyzed statistically the linear correlation of the solvatochromic shifts of the stilbazolium-like dyes in the nonselected solvents with the reaction field function, L(?T) — bL(n2), and the solvent polarity parameter, ENT respectively, and observed that there were not perfectly linearity relationships between them, so we introduced ENT into L(?T) — bL( n2) to form a new reaction field function, L(?T) — bL(n2) + g ENT called as me modified reaction field function, which can be perfectly linearly correlated with the solvatochromic shifts of the stilbazolium-like dyes in the nonselected solvents.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 29682001 and 29832030).
文摘We analyzed statistically the linear correlation of the solvatochromic shifts of the stilbazolium-like dyes in the nonselected solvents with the reaction field function, L(?T) — bL(n2), and the solvent polarity parameter, ENT respectively, and observed that there were not perfectly linearity relationships between them, so we introduced ENT into L(?T) — bL( n2) to form a new reaction field function, L(?T) — bL(n2) + g ENT called as me modified reaction field function, which can be perfectly linearly correlated with the solvatochromic shifts of the stilbazolium-like dyes in the nonselected solvents.
