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Model-based design method of two-axis four-actuator fast steering mirror system 被引量:3
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作者 黑沫 张连超 +2 位作者 周擎坤 鲁亚飞 范大鹏 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第1期150-158,共9页
This work was focused on the model-based design method of two-axis four-actuator(TAFA) fast steering mirror system(FSM), in order to improve the design efficiency. The structure and operation principle commonality of ... This work was focused on the model-based design method of two-axis four-actuator(TAFA) fast steering mirror system(FSM), in order to improve the design efficiency. The structure and operation principle commonality of normal TAFA FSM were investigated. Based on the structure and the commonality, the conditions of single-axis idea, high-frequency resonance and coupling were modeled gradually. Combining these models, a holonomic system model was established to reflect and predict the performance of TAFA FSM. A model-based design method was proposed based on the holonomic system model. The design flow and design concept of the method were described. In accordance with the method, a TAFA FSM was designed. Simulations and experiments of the FSM were done, and the results of them were compared. The compared results indicate that the holonomic system model can well reflect and predict the performance of TAFA FSM. The bandwidth of TAFA FSM is more than 250 Hz; adjust time is less than 15 ms;overshoot is less than 8%; position accuracy is better than 10 μrad; the FSM prototype can satisfy the requirements. 展开更多
关键词 fast steering mirror system model-based design dynamic modeling
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A Custom Manipulator for Dental Implantation Through Model-Based Design 被引量:2
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作者 Anitha Govindhan Karnam Anantha Sunitha Sivanathan Kandhasamy 《Intelligent Automation & Soft Computing》 SCIE 2023年第1期351-365,共15页
This paper presents a Model-Based Design(MBD)approach for the design and control of a customized manipulator intended for drilling and position-ing of dental implants accurately with minimal human intervention.While p... This paper presents a Model-Based Design(MBD)approach for the design and control of a customized manipulator intended for drilling and position-ing of dental implants accurately with minimal human intervention.While performing an intra-oral surgery for a prolonged duration within a limited oral cavity,the tremor of dentist's hand is inevitable.As a result,wielding the drilling tool and inserting the dental implants safely in accurate position and orientation is highly challenging even for experienced dentists.Therefore,we introduce a customized manipulator that is designed ergonomically by taking in to account the dental chair specifications and anthropomorphic data such that it can be readily mounted onto the existing dental chair.The manipulator can be used to drill holes for dental inserts and position them with improved accuracy and safety.Further-more,a thorough multi-body motion analysis of the manipulator was carried out by creating a virtual prototype of the manipulator and simulating its controlled movements in various scenarios.The overall design was prepared and validated in simulation using Solid works,MATLAB and Simulink through Model Based Design(MBD)approach.The motion simulation results indicate that the manipulator could be built as a prototype readily. 展开更多
关键词 Model based design multi-body motion simulation custom manipulator orthodontic implants mathematical approach
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Modeling of a Lithium-Ion Capacitor and Its Charging and Discharging Circuit in a Model-Based Design
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作者 Kyoji Nakajo Shinji Aoki +4 位作者 Takashi Yatsuda Shuji Takahashi Kazuhiro Motegi Yasuhiro Kobayashi Yoichi Shiraishi 《Circuits and Systems》 2016年第1期11-22,共12页
For several years now, electric vehicles (EVs) have been expected to become widely available in the micro-mobility field. However, the insufficiency of such vehicles’ battery-charging and discharging performance has ... For several years now, electric vehicles (EVs) have been expected to become widely available in the micro-mobility field. However, the insufficiency of such vehicles’ battery-charging and discharging performance has limited their practical use. A hybrid energy storage system, which comprises a capacitor and battery, is a promising solution to this problem;however, to apply model-based designs, which are indispensable to embedded systems, such as the electronic control units used in EVs, a simple and accurate capacitor model is required. Within this framework, a lithium-ion capacitor (LIC) model is proposed, and its charging and discharging performances are evaluated against an actual LIC. The model corresponds accurately to the actual LIC, and the results indicate that the proposed LIC model will work well when used with Model-Based Design (MBD). 展开更多
关键词 Model CAPACITOR LITHIUM-ION Model Based design Electric Vehicle Battery HESS
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Model-Based System Multidisciplinary Design Optimization for Preliminary Design of a Blended Wing-Body Underwater Glider
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作者 WANG Zhi-long LI Jing-lu +3 位作者 WANG Peng DONG Hua-chao WANG Xin-jing WEN Zhi-wen 《China Ocean Engineering》 2025年第4期755-767,共13页
Unlike traditional propeller-driven underwater vehicles,blended-wing-body underwater gliders(BWBUGs)achieve zigzag gliding through periodic adjustments of their net buoyancy,enhancing their cruising capabilities while... Unlike traditional propeller-driven underwater vehicles,blended-wing-body underwater gliders(BWBUGs)achieve zigzag gliding through periodic adjustments of their net buoyancy,enhancing their cruising capabilities while mini-mizing energy consumption.However,enhancing gliding performance is challenging due to the complex system design and limited design experience.To address this challenge,this paper introduces a model-based,multidisciplinary system design optimization method for BWBUGs at the conceptual design stage.First,a model-based,multidisciplinary co-simulation design framework is established to evaluate both system-level and disciplinary indices of BWBUG performance.A data-driven,many-objective multidisciplinary optimization is subsequently employed to explore the design space,yielding 32 Pareto optimal solutions.Finally,a model-based physical system simulation,which represents the design with the largest hyper-volume contribution among the 32 final designs,is established.Its gliding perfor-mance,validated by component behavior,lays the groundwork for constructing the entire system’s digital prototype.In conclusion,this model-based,multidisciplinary design optimization method effectively generates design schemes for innovative underwater vehicles,facilitating the development of digital prototypes. 展开更多
关键词 model-based design multidisciplinary design optimization data-driven optimization blended-wingbody underwater glider(BWBUG) physical system simulation
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Accelerating multi-objective catalytic material design:A model-based method
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作者 Baolei Li Da Wang +7 位作者 Miao Yu Chaozheng He Xue Li Jing Zhai Mdmahadi Hasan Chenxu Zhao Min Wang Dingcai Shen 《Chinese Chemical Letters》 2025年第12期363-367,共5页
Cobalt phosphide has been successfully used as a catalyst in the production of ammonia from nitric acid.Substituting appropriate atoms is expected to further improve its catalytic performance.Owing to the diversity of... Cobalt phosphide has been successfully used as a catalyst in the production of ammonia from nitric acid.Substituting appropriate atoms is expected to further improve its catalytic performance.Owing to the diversity of substituting elements,substitution sites,adsorption sites,and adsorption configurations,extensive time-consuming simulation calculations are required for the high-throughput screening method.Additionally,multi-objective attributes should be considered simultaneously in catalytic design.To tackle this challenge,this paper suggests a multi-objective cobalt phosphide catalytic material design method based on surrogate models.And the effectiveness of the proposed method was validated through comparative experiments.The proposed method led to the discovery of fifteen promising cobalt phosphide catalyst configurations.This study provides a new avenue for expediting the design of catalyst,with the potential for application in other systems. 展开更多
关键词 Surrogate model MULTI-OBJECTIVE Catalytic design Cobalt phosphide Simulation calculations
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Metamodel-based Global Optimization Using Fuzzy Clustering for Design Space Reduction 被引量:14
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作者 LI Yulin LIU Li +1 位作者 LONG Teng DONG Weili 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2013年第5期928-939,共12页
High fidelity analysis are utilized in modern engineering design optimization problems which involve expensive black-box models.For computation-intensive engineering design problems,efficient global optimization metho... High fidelity analysis are utilized in modern engineering design optimization problems which involve expensive black-box models.For computation-intensive engineering design problems,efficient global optimization methods must be developed to relieve the computational burden.A new metamodel-based global optimization method using fuzzy clustering for design space reduction(MGO-FCR) is presented.The uniformly distributed initial sample points are generated by Latin hypercube design to construct the radial basis function metamodel,whose accuracy is improved with increasing number of sample points gradually.Fuzzy c-mean method and Gath-Geva clustering method are applied to divide the design space into several small interesting cluster spaces for low and high dimensional problems respectively.Modeling efficiency and accuracy are directly related to the design space,so unconcerned spaces are eliminated by the proposed reduction principle and two pseudo reduction algorithms.The reduction principle is developed to determine whether the current design space should be reduced and which space is eliminated.The first pseudo reduction algorithm improves the speed of clustering,while the second pseudo reduction algorithm ensures the design space to be reduced.Through several numerical benchmark functions,comparative studies with adaptive response surface method,approximated unimodal region elimination method and mode-pursuing sampling are carried out.The optimization results reveal that this method captures the real global optimum for all the numerical benchmark functions.And the number of function evaluations show that the efficiency of this method is favorable especially for high dimensional problems.Based on this global design optimization method,a design optimization of a lifting surface in high speed flow is carried out and this method saves about 10 h compared with genetic algorithms.This method possesses favorable performance on efficiency,robustness and capability of global convergence and gives a new optimization strategy for engineering design optimization problems involving expensive black box models. 展开更多
关键词 global optimization metamodel-based optimization reduction of design space fuzzy clustering
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基于MATLAB App Designer的数字岩心建模软件设计与开发
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作者 左艳彤 邢兰昌 +1 位作者 贾宁洪 刘宝 《计算机测量与控制》 2026年第1期235-243,共9页
为解决现有商用数字岩心建模软件功能可扩展性弱、成本高等问题,文章基于MATLAB App Designer工具开发了一款集成化的数字岩心建模软件,该软件包括图像处理、图像分析和孔隙网络提取等三大功能模块;图像处理模块集成了中值滤波、高斯滤... 为解决现有商用数字岩心建模软件功能可扩展性弱、成本高等问题,文章基于MATLAB App Designer工具开发了一款集成化的数字岩心建模软件,该软件包括图像处理、图像分析和孔隙网络提取等三大功能模块;图像处理模块集成了中值滤波、高斯滤波、SUSAN平滑、图像锐化及阈值分割等多种图像处理算法;图像分析模块采用多平面切片与序列叠加方法、借助三维交互技术实现了岩心结构的三维可视化、切面展示与旋转浏览;孔隙网络提取模块采用最大球法提取孔隙网络,从而获取配位数、孔隙半径、孔隙体积等关键结构参数,利用直方图对结构参数分布进行统计分析;利用典型岩心样本对所开发的软件进行功能测试,结果表明:该软件功能集成度高、界面友好、操作简便,能够有效提升图像质量、对岩心图像进行三维可视化展示以及准确提取三维岩心的孔隙网络结构特征;软件具备良好的可扩展性和二次开发潜力,为后续开发数字岩心电学、声学、核磁共振等响应的数值仿真模块提供了前提。 展开更多
关键词 数字岩心 MATLAB App designer 图像处理 图像分析 孔隙网络提取
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Model-based optimal design of phase change ionic liquids for efficient thermal energy storage 被引量:3
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作者 Huaiwei Shi Xiang Zhang +1 位作者 Kai Sundmacher Teng Zhou 《Green Energy & Environment》 SCIE CSCD 2021年第3期392-404,共13页
The selection of phase change material(PCM)plays an important role in developing high-efficient thermal energy storage(TES)processes.Ionic liquids(ILs)or organic salts are thermally stable,non-volatile,and non-flammab... The selection of phase change material(PCM)plays an important role in developing high-efficient thermal energy storage(TES)processes.Ionic liquids(ILs)or organic salts are thermally stable,non-volatile,and non-flammable.Importantly,researchers have proved that some ILs possess higher latent heat of fusion than conventional PCMs.Despite these attractive characteristics,yet surprisingly,little research has been performed to the systematic selection or structural design of ILs for TES.Besides,most of the existing work is only focused on the latent heat when selecting PCMs.However,one should note that other properties such as heat capacity and thermal conductivity could affect the TES performance as well.In this work,we propose a computer-aided molecular design(CAMD)based method to systematically design IL PCMs for a practical TES process.The effects of different IL properties are simultaneously captured in the IL property models and TES process models.Optimal ILs holding a best compromise of all the properties are identified through the solution of a formulated CAMD problem where the TES performance of the process is maximized.[MPyEtOH][TfO]is found to be the best material and excitingly,the identified top nine ILs all show a higher TES performance than the traditional PCM paraffin wax at 10 h thermal charging time. 展开更多
关键词 Ionic liquid Phase change material Thermal energy storage Computer-aided molecular design Process modelling and evaluation
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Classification of forest vegetation with the application of iterative reallocation and model-based clustering
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作者 Naghmeh Pakgohar Javad Eshaghi Rad +4 位作者 Hossein Gholami Ahmad Alijanpour David W.Roberts Attila Lengyel Enrico Feoli 《Journal of Forestry Research》 2025年第5期103-112,共10页
Numerous clustering algorithms are valuable in pattern recognition in forest vegetation,with new ones continually being proposed.While some are well-known,others are underutilized in vegetation science.This study comp... Numerous clustering algorithms are valuable in pattern recognition in forest vegetation,with new ones continually being proposed.While some are well-known,others are underutilized in vegetation science.This study compares the performance of practical iterative reallocation algorithms with model-based clustering algorithms.The data is from forest vegetation in Virginia(United States),the Hyrcanian Forest(Asia),and European beech forests.Practical iterative reallocation algorithms were applied as non-hierarchical methods and Finite Gaussian mixture modeling was used as a model-based clustering method.Due to limitations on dimensionality in model-based clustering,principal coordinates analysis was employed to reduce the dataset’s dimensions.A log transformation was applied to achieve a normal distribution for the pseudo-species data before calculating the Bray-Curtis dissimilarity.The findings indicate that the reallocation of misclassified objects based on silhouette width(OPTSIL)with Flexible-β(-0.25)had the highest mean among the tested clustering algorithms with Silhouette width 1(REMOS1)with Flexible-β(-0.25)second.However,model-based clustering performed poorly.Based on these results,it is recommended using OPTSIL with Flexible-β(-0.25)and REMOS1 with Flexible-β(-0.25)for forest vegetation classification instead of model-based clustering particularly for heterogeneous datasets common in forest vegetation community data. 展开更多
关键词 CLASSIFICATION Heuristic clustering Finite mixture Forest ecosystems model-based clustering
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Model-Based Decentralized Dynamic Periodic Event-Triggered Control for Nonlinear Systems Subject to Packet Losses
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作者 Chengchao Li Xudong Zhao +2 位作者 Wei Xing Ning Xu Ning Zhao 《IEEE/CAA Journal of Automatica Sinica》 2025年第9期1908-1919,共12页
This paper studies the problem of designing a modelbased decentralized dynamic periodic event-triggering mechanism(DDPETM)for networked control systems(NCSs)subject to packet losses and external disturbances.Firstly,t... This paper studies the problem of designing a modelbased decentralized dynamic periodic event-triggering mechanism(DDPETM)for networked control systems(NCSs)subject to packet losses and external disturbances.Firstly,the entire NCSs,comprising the triggering mechanism,packet losses and output-based controller,are unified into a hybrid dynamical framework.Secondly,by introducing dynamic triggering variables,the DDPETM is designed to conserve network resources while guaranteeing desired performance properties and tolerating the maximum allowable number of successive packet losses.Thirdly,some stability conditions are derived using the Lyapunov approach.Differing from the zero-order-hold(ZOH)case,the model-based control sufficiently exploits the model information at the controller side.Between two updates,the controller predicts the plant state based on the models and received feedback information.With the model-based control,less transmission may be expected than with ZOH.Finally,numerical examples and comparative experiments demonstrate the effectiveness of the proposed method. 展开更多
关键词 Decentralized dynamic periodic event-triggering mechanism(DDPETM) hybrid system approach model-based control networked control system successive packet losses
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Inverse design framework of hybrid honeycomb structure with high impact resistance based on active learning 被引量:1
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作者 Xingyu Shen Ke Yan +5 位作者 Difeng Zhu Hao Wu Shijun Luo Shaobo Qi Mengqi Yuan Xinming Qian 《Defence Technology(防务技术)》 2026年第1期407-421,共15页
In this study,an inverse design framework was established to find lightweight honeycomb structures(HCSs)with high impact resistance.The hybrid HCS,composed of re-entrant(RE)and elliptical annular re-entrant(EARE)honey... In this study,an inverse design framework was established to find lightweight honeycomb structures(HCSs)with high impact resistance.The hybrid HCS,composed of re-entrant(RE)and elliptical annular re-entrant(EARE)honeycomb cells,was created by constructing arrangement matrices to achieve structural lightweight.The machine learning(ML)framework consisted of a neural network(NN)forward regression model for predicting impact resistance and a multi-objective optimization algorithm for generating high-performance designs.The surrogate of the local design space was initially realized by establishing the NN in the small sample dataset,and the active learning strategy was used to continuously extended the local optimal design until the model converged in the global space.The results indicated that the active learning strategy significantly improved the inference capability of the NN model in unknown design domains.By guiding the iteration direction of the optimization algorithm,lightweight designs with high impact resistance were identified.The energy absorption capacity of the optimal design reached 94.98%of the EARE honeycomb,while the initial peak stress and mass decreased by 28.85%and 19.91%,respectively.Furthermore,Shapley Additive Explanations(SHAP)for global explanation of the NN indicated a strong correlation between the arrangement mode of HCS and its impact resistance.By reducing the stiffness of the cells at the top boundary of the structure,the initial impact damage sustained by the structure can be significantly improved.Overall,this study proposed a general lightweight design method for array structures under impact loads,which is beneficial for the widespread application of honeycomb-based protective structures. 展开更多
关键词 Re-entrant honeycomb Hybrid structures Inverse design Impact resistance LIGHTWEIGHT
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Model-based predictive controller design for a class of nonlinear networked systems with communication delays and data loss
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作者 安宝冉 刘国平 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第8期211-216,共6页
This paper discusses the model-based predictive controller design of networked nonlinear systems with communica- tion delay and data loss. Based on the analysis of the closed-loop networked predictive control systems,... This paper discusses the model-based predictive controller design of networked nonlinear systems with communica- tion delay and data loss. Based on the analysis of the closed-loop networked predictive control systems, the model-based networked predictive control strategy can compensate for communication delay and data loss in an active way. The designed model-based predictive controller can also guarantee the stability of the closed-loop networked system. The simulation re- suits demonstrate the feasibility and efficacy of the proposed model-based predictive controller design scheme. 展开更多
关键词 communication delays data loss model-based networked predictive control
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A Wireframe Model-Based Method for Automated Internal Design
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作者 XU Xiaosheng JIN Ping ZHANG Lanxin 《Wuhan University Journal of Natural Sciences》 CAS CSCD 2016年第4期319-323,共5页
This paper proposes a wireframe model-based method for automated internal design. The method is used to extract geometric structure of an internal wireframe model and find out all loop structures of furniture models. ... This paper proposes a wireframe model-based method for automated internal design. The method is used to extract geometric structure of an internal wireframe model and find out all loop structures of furniture models. The wireframe models are classified as the multiple independent sub-models according to the geometric structure by statistical analysis. The corresponding models are selected from a 3D model database to build an internal scene based on characteristic points of furniture wireframe models. In the experiments 3D database via manually selected 268 3D furniture models from Google 3D warehouse is built up. The experiments show that the method can construct 3D scenes in 1.1×103 ms. This method costs less time compared with traditional hierarchical method and depth-sensing camera method in the same experimental conditions. The method can be also used for 3D visualization either with complex backgrounds. 展开更多
关键词 wireframe model statistical analysis automated internal design
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基于OpenRoads Designer的桥梁下部结构设计应用研究
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作者 李昊 胡霜 《四川建材》 2026年第1期115-119,共5页
为积极推动BIM技术在我国桥梁工程领域的发展和落地应用,研究将桥梁下部结构的参数化设计与快速建模作为切入点。以Bentley平台为基础,以中国公路桥梁设计规范为依据,对OpenRoads Designer软件进行二次开发。通过分析当前桥梁建模软件... 为积极推动BIM技术在我国桥梁工程领域的发展和落地应用,研究将桥梁下部结构的参数化设计与快速建模作为切入点。以Bentley平台为基础,以中国公路桥梁设计规范为依据,对OpenRoads Designer软件进行二次开发。通过分析当前桥梁建模软件的现状及不足,系统阐述二次开发技术路线、参数化设计理念以及下部结构批量化布置方法。结合实际工程案例验证表明,该二次开发成果显著提升桥梁下部结构建模效率与准确性,为桥梁工程BIM技术的持续深化应用提供实践参考。 展开更多
关键词 BIM OpenRoads designer 二次开发 桥梁下部结构 参数化设计
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Interface management on high speed two:managing multiple complex interfaces in the design and construction of high speed railway infrastructure in the United Kingdom
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作者 Hudson Taivo Hitesh Shantilal Mistry 《Railway Sciences》 2026年第1期1-28,共28页
Purpose-Interface management is the process of managing communications,responsibilities and coordination of project parties,phases or physical entities which are dependent on one another.Interface management is a cruc... Purpose-Interface management is the process of managing communications,responsibilities and coordination of project parties,phases or physical entities which are dependent on one another.Interface management is a crucial part of managing any construction project-but particularly important for high-speed railway projects that often have several contractual parties and stakeholders,very long project timelines and huge upfront cost overlays.This paper discusses how various project interfaces were managed during the design and construction of the civil engineering infrastructure for the High Speed Two(HS2)project in the United Kingdom.Design/methodology/approach-The paper uses the case study methodology.Key interfaces on the HS2 project are grouped into various categories and the paper discusses how they were managed within the Area North Integrated Project Team(IPT)of the HS2 project made up of contractor Balfour Beatty VINCI(BBV),the Mott MacDonald SYSTRA Design Joint Venture(DJV)and client HS2 Ltd.3 different case studies drawn from across the IPT are used,each of them highlighting different interfaces and how these interfaces were managed.Findings-The paper shows how innovative technical designs and modern methods of construction were used to address some of the unique and peculiar challenges of designing a brand-new railway in the United Kingdom.Addressing the contrasting and often competing requirements of different stakeholders,coupled with challenging physical constraints of the very limited land available for the project and the use of a rarely used Act of Parliament in the delivery of the project required different approach to interface management.Collaboration and proactive stakeholder engagement are necessary for successful interface management on megaprojects.The authors posit that adopting an integrated approach to engineering and construction management is an essential ingredient for the successful delivery of high-speed railway projects.Originality/value-With many high-speed railway projects around the world coming up in the next few years,understanding the context and challenges for each country will help engineering and design managers adopt appropriate approaches for their projects.The lessons learned on the HS2 project are also transferable to other mega infrastructure projects with complex project interfaces. 展开更多
关键词 Interface management design management design constraints Project management
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少数民族文化在现代设计中的转译——以国际A’Design获奖作品为例
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作者 张卫伟 张阳阳 《绿色包装》 2026年第2期102-105,117,共5页
本文探讨少数民族文化在现代设计中的有效转译,聚焦国际A’Design奖获奖作品的创新实践。通过案例分析,研究揭示设计师如何运用文化多样性理论,将传统文化元素融合现代设计语言,实现文化内涵与当代表达的统一。结果显示,此类设计不仅强... 本文探讨少数民族文化在现代设计中的有效转译,聚焦国际A’Design奖获奖作品的创新实践。通过案例分析,研究揭示设计师如何运用文化多样性理论,将传统文化元素融合现代设计语言,实现文化内涵与当代表达的统一。结果显示,此类设计不仅强化文化认同与用户体验,也可提升产品市场竞争力。研究强调文化转译对推动设计创新、增强文化自信及维护文化多样性的理论与实践价值,并提出未来跨学科融合与文化深层挖掘的研究方向。 展开更多
关键词 少数民族文化 现代设计 A’design 文化转译
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Progress in MOF-based catalyst design and reaction mechanisms for CO_(2)hydrogenation to methanol
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作者 YU Zhifu JIANG Lei WU Mingbo 《燃料化学学报(中英文)》 北大核心 2026年第1期146-162,共17页
Against the backdrop of escalating global climate change and energy crises,the resource utilization of carbon dioxide(CO_(2)),a major greenhouse gas,has become a crucial pathway for achieving carbon peaking and carbon... Against the backdrop of escalating global climate change and energy crises,the resource utilization of carbon dioxide(CO_(2)),a major greenhouse gas,has become a crucial pathway for achieving carbon peaking and carbon neutrality goals.The hydrogenation of CO_(2)to methanol not only enables carbon sequestration and recycling,but also provides a route to produce high value-added fuels and basic chemical feedstocks,holding significant environmental and economic potential.However,this conversion process is thermodynamically and kinetically limited,and traditional catalyst systems(e.g.,Cu/ZnO/Al_(2)O_(3))exhibit inadequate activity,selectivity,and stability under mild conditions.Therefore,the development of novel high-performance catalysts with precisely tunable structures and functionalities is imperative.Metal-organic frameworks(MOFs),as crystalline porous materials with high surface area,tunable pore structures,and diverse metal-ligand compositions,have the great potential in CO_(2)hydrogenation catalysis.Their structural design flexibility allows for the construction of well-dispersed active sites,tailored electronic environments,and enhanced metal-support interactions.This review systematically summarizes the recent advances in MOF-based and MOF-derived catalysts for CO_(2)hydrogenation to methanol,focusing on four design strategies:(1)spatial confinement and in situ construction,(2)defect engineering and ion-exchange,(3)bimetallic synergy and hybrid structure design,and(4)MOF-derived nanomaterial synthesis.These approaches significantly improve CO_(2)conversion and methanol selectivity by optimizing metal dispersion,interfacial structures,and reaction pathways.The reaction mechanism is further explored by focusing on the three main reaction pathways:the formate pathway(HCOO*),the RWGS(Reverse Water Gas Shift reaction)+CO*hydrogenation pathway,and the trans-COOH pathway.In situ spectroscopic studies and density functional theory(DFT)calculations elucidate the formation and transformation of key intermediates,as well as the roles of active sites,metal-support interfaces,oxygen vacancies,and promoters.Additionally,representative catalytic performance data for MOFbased systems are compiled and compared,demonstrating their advantages over traditional catalysts in terms of CO_(2)conversion,methanol selectivity,and space-time yield.Future perspectives for MOF-based CO_(2)hydrogenation catalysts will prioritize two main directions:structural design and mechanistic understanding.The precise construction of active sites through multi-metallic synergy,defect engineering,and interfacial electronic modulation should be made to enhance catalyst selectivity and stability.In addition,advanced in situ characterization techniques combined with theoretical modeling are essential to unravel the detailed reaction mechanisms and intermediate behaviors,thereby guiding rational catalyst design.Moreover,to enable industrial application,challenges related to thermal/hydrothermal stability,catalyst recyclability,and cost-effective large-scale synthesis must be addressed.The development of green,scalable preparation methods and the integration of MOF catalysts into practical reaction systems(e.g.,flow reactors)will be crucial for bridging the gap between laboratory research and commercial deployment.Ultimately,multi-scale structure-performance optimization and catalytic system integration will be vital for accelerating the industrialization of MOF-based CO_(2)-to-methanol technologies. 展开更多
关键词 CO_(2)hydrogenation metal-organic frameworks(MOFs) catalyst design reaction mechanism METHANOL
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pH-dependent electrochemical oxidation of 5-hydroxymethylfurfural:Reaction mechanism,catalyst design,and reactor design across alkaline to acidic media
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作者 Peiyun Zhou Xikang Zhao +2 位作者 Yang Song Ruixiang Ge Haohong Duan 《Smart Molecules》 2026年第1期45-67,共23页
The electrochemical oxidation of biomass-derived platform molecule 5-hydroxymethylfurfural(HMF)represents a crucial pathway for green transformation into high-value chemicals,yet its reaction pathway selectivity,effic... The electrochemical oxidation of biomass-derived platform molecule 5-hydroxymethylfurfural(HMF)represents a crucial pathway for green transformation into high-value chemicals,yet its reaction pathway selectivity,efficiency,and catalyst stability are strongly dependent on the electrolyte pH environment.Under alkaline conditions,high OH−concentration facilitates preferential aldehyde group oxidation and efficient deprotonation,enabling highly efficient synthesis of 2,5-furandicarboxylic acid,but simultaneously induces HMF self-degradation and complicates product separation.As pH decreases,the reaction mechanism shifts toward enhanced hydroxymethyl oxidation,leading to intermediate accumulation(such as 5-hydroxymethyl-2-furancarboxylic acid,2,5-diformylfuran,and 5-formyl-2-furancarboxylic acid)with challenging selectivity control and significantly slowed reaction kinetics.This review comprehensively examines the systematic differences in HMF oxidation pathways and surface catalytic mechanisms across the full pH range from alkaline to acidic conditions.Addressing the distinct reaction characteristics and core challenges in alkaline,near-neutral,and acidic media,we systematically evaluate design strategies for high-efficiency electrocatalysts and explore reactor design aspects.Future research should focus on process integration(with tailored reactor design)for energy consumption reduction in alkaline systems,targeted synthesis of diverse oxidation products in near-neutral systems,and innovative catalyst development for acidic systems,thereby advancing the efficiency,selectivity,and practical application of HMF electrooxidation technologies across the entire pH spectrum through synergistic optimization of catalyst,reactor,and process. 展开更多
关键词 biomass valorization electrocatalyst design full pH HMF electrooxidation reaction mechanism reactor design
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Optimal orthogonal block designs for threecomponent symmetric general blending models in mixture experiment
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作者 Jiawei Bao Yu Tang 《Statistical Theory and Related Fields》 2026年第1期117-134,共18页
In mixture experiments,the observed response is determined by the relative proportions of the components,consequently rendering the experimental region a simplex.This paper focuses primarily on the optimal designs of ... In mixture experiments,the observed response is determined by the relative proportions of the components,consequently rendering the experimental region a simplex.This paper focuses primarily on the optimal designs of mixture experiments that involve process variables.Prior research has extensively delved into optimal orthogonal block designs for some classic mixture models with process variables.Based on the framework of general blending models,this paper proposes a class of symmetric linear mixture models,which can be regarded as a generalization of many existing ones.Under the orthogonal blocking conditions,orthogonal block designs are devised through Latin squares in the presence of process variables.TheD-,A-,and E-optimality criteria are utilized to obtain optimal designs at the boundary of the simplex in the case of 3 components.As the values of the exponents change,numerically derived optimal design points are presented to illustrate the pattern of their variations,and to verify the consistency of the results with previous research on some specific symmetric general blending models. 展开更多
关键词 Mixture experiments general blending models optimal designs orthogonal Latin squares block designs
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Modern Graphics APIs:Design Principles,A Use Case,and New Perspectives
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作者 Lu Ping Sun Qi +3 位作者 Wang Chen Guo Jie Guo Yanwen Shi Wenzhe 《ZTE Communications》 2026年第1期97-106,共10页
In this paper,we provide a comprehensive examination of the evolution of graphics Application Programming Interfaces(APIs).We begin by exploring traditional graphics APIs,elucidating their distinct features and inhere... In this paper,we provide a comprehensive examination of the evolution of graphics Application Programming Interfaces(APIs).We begin by exploring traditional graphics APIs,elucidating their distinct features and inherent challenges.This sets the stage for a detailed exploration of modern graphics APIs,with a focus on four critical design principles.These principles are further analyzed through specific case studies and categorical examinations.The paper then introduces MoerEngine,a bespoke rendering engine,as a practical case to demonstrate the real-world application of these modern principles in software engineering.In conclusion,the study offers insights into the potential future trajectory of graphics APIs,spotlighting emerging design patterns and technological innovations.It also ventures to predict the development trends and capabilities of next-generation graphics APIs. 展开更多
关键词 graphics API RENDERING design principle MoerEngine
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