A new polythreaded Mn^(Ⅱ)-MOF based on a tridentate N-containing ligand was synthesized via a hydrothermal method,namely,[Mn_(2)(Tipa)_(2)(1,4-bdc)_(2)(H_(2)O)_(2)]·3H_(2)O(MnTB),where Tipa and 1,4-bdc are short...A new polythreaded Mn^(Ⅱ)-MOF based on a tridentate N-containing ligand was synthesized via a hydrothermal method,namely,[Mn_(2)(Tipa)_(2)(1,4-bdc)_(2)(H_(2)O)_(2)]·3H_(2)O(MnTB),where Tipa and 1,4-bdc are short for tri(4-imidazolylphenyl)amine and 1,4-benzenedicarboxylate.MnTB possesses a fascinating 2D→2D polyrotaxane layer with a(4^(2)·6)(4^(2)·6^(3)·8)topology.展开更多
基金was supported by the Qing Lan Project of Jiangsu Province,the National Natural Science Foundation of China(21901120,21371098)the Natural Science Foundation of Jiangsu Province(BK20180514,SBK2019040146,BK20131314)+2 种基金the China Postdoctoral Science Foundation(2015M570430)the Jiangsu Postdoctoral Science Foundation(1401007C)Jiangsu province entrepreneurship training program for college students(86717408).
文摘A new polythreaded Mn^(Ⅱ)-MOF based on a tridentate N-containing ligand was synthesized via a hydrothermal method,namely,[Mn_(2)(Tipa)_(2)(1,4-bdc)_(2)(H_(2)O)_(2)]·3H_(2)O(MnTB),where Tipa and 1,4-bdc are short for tri(4-imidazolylphenyl)amine and 1,4-benzenedicarboxylate.MnTB possesses a fascinating 2D→2D polyrotaxane layer with a(4^(2)·6)(4^(2)·6^(3)·8)topology.
