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Structural design in re duce d graphene oxide(RGO)metacomposites for enhanced microwave absorption in wide temperature spectrum 被引量:4
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作者 Haoxu Si Yi Zhang +5 位作者 Yuhao Liu Zhiyang Jiang Cuiping Li Jingwei Zhang Xiaoxiao Huang Chunhong Gong 《Journal of Materials Science & Technology》 2025年第3期211-220,共10页
High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increa... High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increased conduction loss often leads to a significant decline in electromagnetic wave absorp-tion(EMWA)performance at elevated temperatures,which severely restricts their practical application.In this study,we propose a novel approach for efficient electromagnetic wave absorption across a wide temperature range using reduced graphene oxide(RGO)/epoxy resin(EP)metacomposites that integrate both electromagnetic parameters and metamaterial design concepts.Due to the discrete distribution of the units,electromagnetic waves can more easily penetrate the interior of materials,thereby exhibiting stable microwave absorption(MA)performance and impedance-matching characteristics suitable across a wide temperature range.Consequently,exceptional MA properties can be achieved within the tem-perature range from 298 to 473 K.Furthermore,by carefully controlling the structural parameters in RGO metacomposites,both the resonant frequency and effective absorption bandwidth(EAB)can be optimized based on precise manipulation of equivalent electromagnetic parameters.This study not only provides an effective approach for the rational design of MA performance but also offers novel insights into achieving super metamaterials with outstanding performance across a wide temperature spectrum. 展开更多
关键词 microwave absorbing materials Metacomposites Equivalent electromagnetic parameters Structural parameters Wide temperature spectrum
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Fabrication of flake-like NiCo_(2)O_(4)/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber 被引量:1
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作者 Konghu Tian Hang Yang +4 位作者 Chao Zhang Ruiwen Shu Qun Shao Xiaowei Liu Kaipeng Gao 《International Journal of Minerals,Metallurgy and Materials》 2025年第3期556-565,共10页
Carbon-based foams with a three-dimensional structure can serve as a lightweight template for the rational design and control-lable preparation of metal oxide/carbon-based composite microwave absorption materials.In t... Carbon-based foams with a three-dimensional structure can serve as a lightweight template for the rational design and control-lable preparation of metal oxide/carbon-based composite microwave absorption materials.In this study,a flake-like nickel cobaltate/re-duced graphene oxide/melamine-derived carbon foam(FNC/RGO/MDCF)was successfully fabricated through a combination of solvo-thermal treatment and high-temperature pyrolysis.Results indicated that RGO was evenly distributed in the MDCF skeleton,providing ef-fective support for the load growth of FNC on its surface.Sample S3,the FNC/RGO/MDCF composite prepared by solvothermal method for 16 h,exhibited a minimum reflection loss(RL_(min))of-66.44 dB at a thickness of 2.29 mm.When the thickness was reduced to 1.50 mm,the optimal effective absorption bandwidth was 3.84 GHz.Analysis of the absorption mechanism of FNC/RGO/MDCF revealed that its excellent absorption performance was primarily attributed to the combined effects of conduction loss,multiple reflection,scattering,in-terface polarization,and dipole polarization. 展开更多
关键词 carbon foam reduced graphene oxide flake-like nickel cobaltate microwave absorbing materials
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Preparation of hierarchical MoS_(2)microsphere/BN composites for microwave absorption and thermal management 被引量:1
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作者 Haoliang Wen Weidong Zhang 《International Journal of Minerals,Metallurgy and Materials》 2025年第3期718-727,共10页
The increase in the utilization of infrared heat detection technology in military applications necessitates research on composites with improved thermal transmission performance and microwave absorption capabilities.T... The increase in the utilization of infrared heat detection technology in military applications necessitates research on composites with improved thermal transmission performance and microwave absorption capabilities.This study satisfactorily fabricated a series of MoS_(2)/BN-xyz composites(which were characterized by the weight ratio of MoS_(2)to BN,denoted by xy:z)through chemical vapor depos-ition,which resulted in their improved thermal stability and thermal transmission performance.The results show that the remaining mass of MoS_(2)/BN-101 was as high as 69.25wt%at 800℃under air atmosphere,and a temperature difference of 31.7℃was maintained between the surface temperature and the heating source at a heating temperature of 200℃.Furthermore,MoS_(2)/BN-301 exhibited an im-pressive minimum reflection loss value of-32.21 dB at 4.0 mm and a wide effective attenuation bandwidth ranging from 9.32 to 18.00 GHz(8.68 GHz).Therefore,these simplified synthesized MoS_(2)/BN-xyz composites demonstrate great potential as highly efficient con-tenders for the enhancement of microwave absorption performance and thermal conductance. 展开更多
关键词 microwave absorbers thermal transmission hierarchical molybdenum disulfide microsphere boron nitride nanosheets
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Structural modification of mesoporous lanthanum oxide into 3D coral-like and nano needle-like structure for effective broadband microwave absorbing materials
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作者 Muzakkiy P.M.Akhir Ade Mulyawan +10 位作者 Okta Tiara Novitasari Rizky Ramadhani Didin S.Winatapura Anjar Anggraini Harumningtyas Suyanti Sari Hasnah Dewi Fatmawati Nurcahyani Firda Amalia Ramlan Murni Handayani Wisnu Ari Adi 《Journal of Rare Earths》 2025年第11期2500-2510,I0007,共12页
Structural modification of three dimensional(3D)materials for the application of dielectric loss-based microwave absorbing materials(MAMs)usually relies on intricate synthesis process and can pose challenges in terms ... Structural modification of three dimensional(3D)materials for the application of dielectric loss-based microwave absorbing materials(MAMs)usually relies on intricate synthesis process and can pose challenges in terms of scalability and mass production for practical application.In this work,we reported a successful attempt in modifying the 3D structure of mesoporous lanthanum oxide(La_(2)O_(3))for effective broadband MAMs candidate via simple co-precipitation process.The inclusion of cetyltrimethylammonium bromide(CTAB)and hydrothermal aging treatment result in a significant transformation of La_(2)O_(3)particles from their original polygonal form to a 3D coral-like and nano needle-like structure.The utilization of CTAB and hydrothermal aging results in the increase of surface area and a two-fold increase in pore volume of the resulting La_(2)O_(3).Due to its unique 3D structure,the 3D coral-like and nano needle-like La_(2)O_(3)materials possess a broadband electromagnetic(EM)wave absorption characteristic with the effective absorption bandwidth(EAB)covering the C-band frequency range.Specifically,in the La_(2)O_(3)C-H sample(with CTAB-with hydrothermal),it exhibits strong EM wave absorption with a reflection loss(RL)value of-33.07 dB which equals to 99.95%EM wave absorption at a thickness of only 1.50 mm.The detailed analysis of EM wave absorption properties reveals that the improvement of La_(2)O_(3)materials to attenuate EM wave energy arises from the dielectric loss phenomenon,the enhanced interfacial polarization,multiple reflections mechanism,and conduction loss mechanism induced by the 3D structural formation of the La_(2)O_(3)structure.This work proposes a novel and efficient approach in synthesizing and modifying 3D materials for effective broadband EM wave absorption. 展开更多
关键词 Mesoporous La_(2)O_(3) Rare earths Hydrothermal aging treatment 3D structural modification electromagnetic wave absorbing properties microwave absorbing materials
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Pseudo-binary composite of Sr_(2)TiMoO_(6)-Al_(2)O_(3)as a novel microwave absorbing material
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作者 Peng Wu Jun Wang +3 位作者 Jian-Yu Li Jing Feng Wen-Ting He Hong-Bo Guo 《Rare Metals》 2025年第1期503-514,共12页
In this work,a novel microwave absorbing material(MAM)made of a pseudo-binary of Sr_(2)TiMoO_(6)-Al_(2)O_(3)(STM)is proposed first.The MAMs labeled as STM X(X=60,70,80 and 100,respectively),in which X is the initial w... In this work,a novel microwave absorbing material(MAM)made of a pseudo-binary of Sr_(2)TiMoO_(6)-Al_(2)O_(3)(STM)is proposed first.The MAMs labeled as STM X(X=60,70,80 and 100,respectively),in which X is the initial weight percent of Sr_(2)TiMoO_(6),were synthesized using the solid-state reaction method.Compared with STM100,some equilibrium phases,including SrTiO_(3),Mo,Sr_(8)(Al1_(2)O_(24))(MoO_(4))_(2)and a few undefined ones,are presented in the composites as evidenced by X-ray diffraction results and scanning electron microscopy due to the chemical reaction between Sr_(2)TiMoO_(6)and Al_(2)O_(3)component.Besides conductance loss,heterogeneous interfaces between various equilibrium phases introduce interfacial polarization,which causes an enhancement of dissipation for the incident electromagnetic wave.Among the synthesized samples,STM80 presents the best microwave absorbing properties.It has a minimum reflection loss(RLmin)of-26 dB and an effective absorbing bandwidth up to 2.7 GHz when the thickness is only 1 mm.This indicates that STM80 is a new type of microwave absorbing material with strong absorption and ultrathin thickness. 展开更多
关键词 microwave absorbing material Dielectric property Reflection loss Double perovskite ceramics Sr_(2)TiMoO_(6)
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Anticorrosive magnetic microwave absorbers by turbulent sol-gel method
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作者 Feng Wang Wei Li +1 位作者 Zhihong Chen Jianguo Guan 《Journal of Materials Science & Technology》 2025年第27期205-218,共14页
Coating uniform,compact and thin nanoshells on micro-sized particles is critical to various applications including anticorrosive broadband microwave absorbing materials(MAMs),yet effective processing methods remain la... Coating uniform,compact and thin nanoshells on micro-sized particles is critical to various applications including anticorrosive broadband microwave absorbing materials(MAMs),yet effective processing methods remain lacking.In this work,a turbulent sol-gel method is developed to coat the desired SiO2 nanoshells on flaky carbonyl iron(FCI)particles.The adding millimeter-sized zirconia balls,driven by the orbital shaking,squeeze the solution and create significant relative motion between the liquid and balls,which generates turbulent flows.This significantly promotes the heterogeneous nucleation rate and high nucleation density,ultimately forming highly compact and uniform SiO2 nanoshells covering FCI particles to enhance the electromagnetic absorption and anticorrosion properties.The as-obtained core-shell particles minimize the interface polarization and retain high magnetic loss,resulting in an improved impedance matching and a reflection loss<−10 dB with a bandwidth of 6.5 GHz at a thin thickness of 1 mm.Moreover,they also show a substantial order-of-magnitude improvement in anticorrosion performance.This work provides a promising method to fabricate anticorrosive,broadband and thin-thickness MAMs.The turbulent sol-gel method developed herein offers a facile and effective approach for fabricating uniform compact nanoshells on micro-sized particles. 展开更多
关键词 Magnetic absorbers Core-shell structures Compact nanoshells Corrosion resistance microwave absorbers
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Effects of thermal oxidation on microwave-absorbing and mechanical properties of SiC_f/SiC composites with PyC interphase 被引量:3
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作者 史毅敏 罗发 +3 位作者 丁冬海 穆阳 周万城 朱冬梅 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第5期1484-1489,共6页
The SiCf/SiC composites containing PyC interphase were prepared by chemical vapor infiltration process. The influences of thermal oxidation on the complex permittivity and microwave absorption properties of Si Cf/Si C... The SiCf/SiC composites containing PyC interphase were prepared by chemical vapor infiltration process. The influences of thermal oxidation on the complex permittivity and microwave absorption properties of Si Cf/Si C composites were investigated in the frequency range of 8.2-12.4 GHz. Both the real and imaginary parts of the complex permittivity decreased after thermal oxidation. The composites after 100 h thermal oxidation showed that reflection loss exceeded-10 d B in the frequency of 9.7-11.9 GHz and the minimum value was-11.4 d B at 11.0 GHz. The flexural strength of composites decreased but fracture behavior was improved obviously after thermal oxidation. These results indicate that the SiCf/SiC composites containing PyC interphase after thermal oxidation possess good microwave absorbing property and fracture behavior. 展开更多
关键词 SiCf/SiC composites thermal oxidation dielectric properties microwave absorbing mechanical properties
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Magnetic and microwave absorbing properties of M-type barium ferrite/graphene oxide composite microwave absorber 被引量:2
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作者 荆洪阳 唐梦茹 +2 位作者 韩永典 徐连勇 李敏 《Journal of Southeast University(English Edition)》 EI CAS 2015年第4期511-515,共5页
In order to improve the absorbing properties of M- type barium ferrite absorbing materials, M-type barium ferrite/graphene oxide composites with different graphene oxide contents were synthesized by the sol-gel autoco... In order to improve the absorbing properties of M- type barium ferrite absorbing materials, M-type barium ferrite/graphene oxide composites with different graphene oxide contents were synthesized by the sol-gel autocombustion method. X-ray diffraction (XRD), a scanning electronic microscopy ( SEM ), a physical properties measurement system (PPMS-9), and a vector network analyzer were used to analyze their structure, surface morphology, magnetic and absorbing properties, respectively. The results show that the absorbing band of the composite absorbing material is widened and the absorbing strength is increased compared with the pure M-type barium ferrite. The sample with the content of doped graphene oxide of 3% has the minimum reflectivity at 10 to 18 GHz frequencies. Hence, the doped graphene oxide effectively improves the absorbing properties of M-type barium ferrite. 展开更多
关键词 M-type barium ferrite graphene oxide composite microwave absorber magnetic property microwave absorbing property
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Synthesis and Microwave Absorption Properties of BaTiO3-polypyrrole Composite
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作者 李巧玲 张存瑞 李建强 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第5期603-607,622,共6页
BaTiO3 powders are prepared by sol-gel method by cotton template. Polypyrrole is prepared by chemical oxidation route in the emulsion polymerization system. Then BaTiO3- polypyrrole composites with different mixture r... BaTiO3 powders are prepared by sol-gel method by cotton template. Polypyrrole is prepared by chemical oxidation route in the emulsion polymerization system. Then BaTiO3- polypyrrole composites with different mixture ratios are prepared by as-prepared material. The structure, morphology, and properties of the composites are characterized with Infrared spectrum, X-ray diffraction, scanning electron microscope, and net-wok analyzer. The com- plex permittivity and reflection loss of the composites are measured at different microwave frequencies in S-band and C-band (0.03-6 GHz) employing vector network analyzer model PNA 3629D vector. The effect of the mass ratio of BaTiO3 to polypyrrole on the microwave loss properties of the composites is investigated. A possible microwave absorbing mechanism of BaTiOa-polypyrrole composite is proposed. The BaTiO3-polypyrrole composite can find applications in suppression of electromagnetic interference and reduction of radar signature. 展开更多
关键词 BATIO3 POLYPYRROLE microwave absorbing
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Conversion of Biomass to Hydrocarbon-rich Bio-oil via Microwave-assisted Catalytic Pyrolysis: A Review
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作者 Wang Yunpu Zhang Shumeil +4 位作者 Yu Zhenting Jiang Lin Liu Yuhuan Ruan Roger Fu Guiming 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2018年第3期7-16,共10页
The method for pyrolysis of biomass to manufacture hydrocarbon-rich fuel remains challenging in terms of conversion of multifunctional biomass with high oxygen content and low thermal stability into a high-quality com... The method for pyrolysis of biomass to manufacture hydrocarbon-rich fuel remains challenging in terms of conversion of multifunctional biomass with high oxygen content and low thermal stability into a high-quality compound, featuring high content of hydrocarbons, low oxygen content, few functional groups, and high thermal stability. This study offers a promising prospect to derive hydrocarbon-rich oil through microwave-assisted fast catalytic pyrolysis by improving the effective hydrogen to carbon ratio(H/Ceff) of the raw materials. The proposed technique can promote the production of high-quality bio-oil through the molecular sieve catalyzed reduction of oxygenated compounds and mutagenic polyaromatic hydrocarbons. This work aims to review and summarize the research progress on microwave copyrolysis and microwave catalytic copyrolysis to demonstrate their benefits on enhancement of bio-oils derived from the biomass. This review focuses on the potential of optimizing the H/Ceff ratio, the microwave absorbent, and the HZSM-5 catalyst during the microwave copyrolysis to produce the valuable liquid fuel. This paper also proposes future directions for the use of this technique to obtain high yields of bio-oils. 展开更多
关键词 BIOMASS microwave pyrolysis H/Ceff microwave absorbent HZSM-5 catalyst hydrocarbon-rich bio-oil
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Synthesis and microwave absorbing properties of La-doped Sr-hexaferrite nanopowders via sol-gel auto-combustion method 被引量:12
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作者 Jun-Liang Liu Peng Zhang +4 位作者 Xing-Kai Zhang Qing-Qing Xie Dong-Jun Pan Jian Zhang Ming Zhang 《Rare Metals》 SCIE EI CAS CSCD 2017年第9期704-710,共7页
La-doped Sr-hexaferrite(Sr(1-x)LaxFe(12)O(19))(x=0.05,0.10,0.15,0.20) nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation te... La-doped Sr-hexaferrite(Sr(1-x)LaxFe(12)O(19))(x=0.05,0.10,0.15,0.20) nanopowders with particle size ranging from 80 to 110 nm were successfully synthesized by sol-gel auto-combustion. The phase formation temperature increases, while the particle size decreases as the Ladoping content goes up. The partial substitution of Sr^(2+) by La^(3+) results in the suppression effects on the growth-up of the crystallites and the enhancement of the electron hopping between Fe^(3+) with different valences, which leads to the improvement in the dielectric loss and magnetic loss.Therefore, both the microwave absorbing abilities and absorbing frequency ranges are tuned by La-doping. The synthesized Sr-hexaferrite nanopowders with doping element content of 0.10 demonstrate the fine broad microwave absorbing properties. 展开更多
关键词 FERRITE La-doping NANOPOWDERS Sol-gelauto-combustion microwave absorbing properties
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Microwave electromagnetic and absorbing properties of Dy^(3+) doped MnZn ferrites 被引量:11
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作者 宋杰 王丽熙 +1 位作者 许乃岑 张其土 《Journal of Rare Earths》 SCIE EI CAS CSCD 2010年第3期451-455,共5页
Dy3+ doped Mn-Zn ferrites Mn0.3Zn0.7Fe2-xDyxO4(x=0,0.01,0.02,0.03,0.04)were prepared by the conventional solid-state reaction.The crystal structure,surface morphology and electromagnetic properties of the calcined sam... Dy3+ doped Mn-Zn ferrites Mn0.3Zn0.7Fe2-xDyxO4(x=0,0.01,0.02,0.03,0.04)were prepared by the conventional solid-state reaction.The crystal structure,surface morphology and electromagnetic properties of the calcined samples were characterized by X-ray diffraction analysis(XRD),scanning electron microscopy(SEM) and network analyzer(Agilent 8722ET).All the XRD patterns showed the single phase of the spinel-type ferrite without other intermediate when x≤0.03.The average crystallite size was about 44?56 nm.The mi... 展开更多
关键词 Mn-Zn ferrite Dy-doped PERMITTIVITY PERMEABILITY microwave absorbing properties rare earths
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Electromagnetic and microwave absorbing properties of FeCoB powder composites 被引量:7
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作者 Shen-Gen Zhang Hang-Xin Zhu +3 位作者 Jian-Jun Tian De-An Pan Bo Liu Yan-Tao Kang 《Rare Metals》 SCIE EI CAS CSCD 2013年第4期402-407,共6页
The electromagnetic and microwave absorbing properties of FeCoB powder composites prepared by sin- gle-roller melt-spinning and mechanical milling processes were investigated in this paper. The result indicates that t... The electromagnetic and microwave absorbing properties of FeCoB powder composites prepared by sin- gle-roller melt-spinning and mechanical milling processes were investigated in this paper. The result indicates that the flake-like powders are obtained. As milling time increases, the flake-like powder particles tend to agglomerate, causing the flake-like powders decrease gradually. The milling time plays an important role in the electromagnetic parameters which relates to the shape and size of the powder particles. The calculation shows that the sample milled for 6 h could achieve an optimal reflection loss of -11.5 dB at 5.8 GHz, with mass fraction of 83 % and a matching thickness of 1.8 mm. The result also indicates that the microwave absorbing properties of the FeCoB powder composites are adjustable by changing their thickness, and can be applied as a thinner microwave absorbing material in the range of 2-8 GHz. 展开更多
关键词 Fe48Co48B4 powder composites Mechanical milling Electromagnetic parameters microwave absorbing properties
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Toward high performance microwave absorber by implanting La_(0.8)CoO_(3)nanoparticles on rGO 被引量:5
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作者 Li Chang Yu-Ze Wang +3 位作者 Xin-Ci Zhang Lin Li Hua-Zhang Zhai Mao-Sheng Cao 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第7期176-187,共12页
The advent of“intelligent era”brings our life more convenience,but the electromagnetic radiation sur-rounding us not only greatly threatens human health,also makes information leakage and hidden trouble to national ... The advent of“intelligent era”brings our life more convenience,but the electromagnetic radiation sur-rounding us not only greatly threatens human health,also makes information leakage and hidden trouble to national defense security.Hence,it is very urgent to develop novel electromagnetic wave absorption materials with lightweight,strong absorption,tunable absorption frequency and broad band absorption.Herein,a novel electromagnetic wave absorber is obtained by constructing La_(0.8)CoO_(3)-rGO nanocompos-ite,where La_(0.8)CoO_(3)nanoparticles are anchored on graphene nanosheets by the electrostatic interaction between GO and La_(0.8)CoO_(3).The effect of hybridization ratio of La_(0.8)CoO_(3)and rGO on microwave ab-sorption properties is carefully studied.The optimal reflection loss of La_(0.8)CoO_(3)-rGO nanocomposite can reach-62.34 dB with the maximum effective bandwidth of 6.08 GHz,presenting 48.78%and 245.45%increment compared to bare La_(0.8)CoO_(3)nanoparticles,respectively.The effective absorption bandwidth covers a broad electromagnetic wave absorption band from Ku band to the C band by tailoring thickness of the absorbers from 2.4 mm to 4.4 mm.The fascinating electromagnetic wave absorption performance is attributed to the synergy effect of La_(0.8)CoO_(3)and rGO,which integrates magnetic and dielectric loss caused by resonance,conductance,relaxation,and scattering loss.This result confirms that La_(0.8)CoO_(3)-rGO nanocomposite is potential candidates toward high-efficiency microwave absorbers and provides a valuable pathway for designing high-performance microwave attenuation materials in the future. 展开更多
关键词 Perovskite La_(0.8)CoO_(3)nanoparticles Graphene NANOCOMPOSITE microwave absorbing Broad band absorption
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Effect of La^(3+)substitution on structural,microstructure,magnetic properties,and microwave absorbing ability of yttrium iron garnet 被引量:4
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作者 Sari Hasnah Dewi Ade Mulyawan +2 位作者 Yosef Sarwanto Didin S.Winatapura Wisnu Ari Adi 《Journal of Rare Earths》 SCIE EI CAS CSCD 2023年第4期578-587,共10页
Synthesis and characterization of lanthanum-doped yttrium iro n garnet(YIG)in the compositional se ries of Y_(3-x)La_(x)Fe_(5)O_(12)(x=0.0,0.1,0.3,and 0.5)were carried out.All compositions were made by using solid sta... Synthesis and characterization of lanthanum-doped yttrium iro n garnet(YIG)in the compositional se ries of Y_(3-x)La_(x)Fe_(5)O_(12)(x=0.0,0.1,0.3,and 0.5)were carried out.All compositions were made by using solid state reaction method with ball-milling technique.The phase formation,surface morphology,magnetic properties,and microwave absorbing ability of all compositions were characterized by using an X-ray diffractometer,a scanning electron microscope,a vibrating sample magnetometer,and a Vector network analyzer.The results reveal that all compositions are crystallized into Y_(3)Fe_(5)O_(12)phase(space group la-3d(230).It was observed that the lattice constant is increased from 1.2373 to 1.2421 nm with the increase of lanthanum substitution level from x=0.0-0.5.The crystallite size of Y_(3-x)La_(x)Fe_(5)O_(12)series calculated by Scherrer method is found to decrease from 78 nm in x=0.0-63 nm in x=0.5.The particle size distribution from the surface morphology image analysis is shifted to lower-range number with the increase of lanthanum substitution level from x=0.0 to 0.5.The substitution process also affects the lattice distortion in La-doped samples and changes the bond angles and bond lengths of the YIG structure.As the results,a linear correlation between the Fe'-O-Fe bond angle with magnetic properties parameters of saturation magnetization(M_(s))and remanence magnetization(M_(r))was studied.Due to the lanthanum substitution process,all La^(3+)-doped samples possess higher M_(s)and M_(r)values compared to the original composition.The results of Vector network analyzer show that the improvement of the M_(s)and M_(r)plays an important role in enhancing the microwave absorbing ability of the materials.The minimum RL changes from-8.22 dB(~85.22%microwave absorption)in x=0.0 to-14.21 dB(~96.25%microwave absorption)in x=0.5.The enhancement is mainly ascribed to the natural magnetic resonance loss and dipoIe-polarization loss due to the substitution process.The decreasing particle size also enhances the microwave absorbing ability of the La-doped samples via multiple-reflections mechanism. 展开更多
关键词 Yttrium iron garnet Rare-earth doping Solid-state reaction Magnetic properties Structural properties microwave absorbing ability
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Dielectric,magnetic and microwave absorbing properties of polyaniline-Co0.7Cr0.1Zn0.2Fe2O4 composites 被引量:4
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作者 Rui-Ting Ma Huai-Yu Shang +1 位作者 Xiao Wang Dan Jiang 《Rare Metals》 SCIE EI CAS CSCD 2017年第2期118-122,共5页
The spinel cobalt chromium zinc ferrites(Co0.7Cr0.1Zn0.2Fe2O4) and the polyaniline(PANI)-Co0.7Cr0.1Zn0.2Fe2O4 composites were prepared by polyacrylamide gel and an in situ polymerization method,respectively.The st... The spinel cobalt chromium zinc ferrites(Co0.7Cr0.1Zn0.2Fe2O4) and the polyaniline(PANI)-Co0.7Cr0.1Zn0.2Fe2O4 composites were prepared by polyacrylamide gel and an in situ polymerization method,respectively.The structure of the synthesized material was characterized by X-ray diffraction(XRD) and Fourier transform infrared spectrometer(FTIR),which shows that the spinel Co0.7Cr0.1Zn0.2Fe2O4 ferrites and the PANI Co0.7Cr0.1Zn0.2Fe2O4 composites are obtained.As a small amount of Co^2+ in the octahedron ferrite is replaced by Cr^3+,the lattice constant of Co0.8Cr0.2Zn0.2Fe2O4 ferrites reduces from0.8409 to 0.8377 nm.The magnetic properties of the two materials were investigated by vibrating sample magnetometer(VSM).The VSM results confirm that the saturation magnetization(Ms),remanent magnetization(Mr) and coercive force(Hc) of the PANI-Co0.7Cr0.1Zn0.2Fe2O4composites are 8.80 mA·m^2·g^-1,3.14 mA·m^2·g^-1 and37.22 kA·m^-1,respectively,which are smaller than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites.The microwave absorbing capability of the two materials was studied by waveguide method.In the frequency range of 5-20 GHz,two reflection loss maximum values of the PANI-Co0.7Cr0.1Zn0.2Fe2O4 composites appear at 14.1 and 17.9 GHz with-13.17 and-15.36 dB,respectively,which are obviously higher than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites. 展开更多
关键词 COMPOSITES microwave absorbing properties Dielectric properties Magnetic properties
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Electromagnetic and microwave absorption properties of Er-Ho-Fe alloys 被引量:4
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作者 Jialiang Luo Shunkang Pan +3 位作者 Lichun Cheng Peihao Lin Yu He Junqing Chang 《Journal of Rare Earths》 SCIE EI CAS CSCD 2018年第7期715-720,共6页
The ErxHo(2-x)Fe(17)(x = 0.0, 0.1,0.2, 0.3, 0.4) powders were prepared by arc melting and high energy ball milling method. The influence of the Er substitution on phase structure, morphology, saturation magnetiz... The ErxHo(2-x)Fe(17)(x = 0.0, 0.1,0.2, 0.3, 0.4) powders were prepared by arc melting and high energy ball milling method. The influence of the Er substitution on phase structure, morphology, saturation magnetization,electromagnetic parameters was investigated by X-ray diffraction(XRD),scanning electron microscopy(SEM), vibrating sample magnetometer(VSM) and vector network analyzer(VNA),respectively. The results show that the saturation magnetization increases and the average particle size increases with the increase of Er content. The minimum absorption peak frequency shifts towards a lower frequency region with the increase of Er content. The ErxHo2-xFe17 powder can achieve the minimum RL of-24.07 dB at 6.96 GHz with a thickness of 2.0 mm and the minimum RL is less than-20 dB at the thickness range from 2.0 to 3.0 mm. The minimum RL of ErxHo2-xFe17 is-37.26 dB at5.68 GHz and the frequency bandwidth of R〈-10 dB reaches about 1.2 GHz with a thickness of 2.4 mm.And the microwave absorbing properties of the composite with different weight ratios of Er0.3Ho1.7Fe17/graphene were researched. The microwave absorbing peaks of the composite shift to lower frequency with the increase of graphene content. The values of the minimum RL of ErxHo2-xFe17/graphene are close to-10 dB with absorbing coating thicknesses increased. 展开更多
关键词 ErxHo2-xFe17 alloys Reflection loss Electromagnetic parameters Magnetic properties microwave absorbing properties Rare earths
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Effect of Adding Microwave Absorber on Structures and Properties of Hypercoal-Based Activated Carbons 被引量:4
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作者 XU Lijun FAN Lihua +2 位作者 HOU Caixia LIU Junke SUN Zhang 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2020年第3期488-494,共7页
Using lignite-based hypercoal as raw material, KOH as activator and CuO as microwave absorber, we prepared hypercoal-based activated carbons by microwave-assisted activation. The pore structure and the electrochemical... Using lignite-based hypercoal as raw material, KOH as activator and CuO as microwave absorber, we prepared hypercoal-based activated carbons by microwave-assisted activation. The pore structure and the electrochemical performance of the activated carbons were tested, and the effects of adding CuO in the activation reaction process were also investigated. The activated carbons prepared were characterized by nitrogen adsorption-desorption, X-ray diffraction (XRD) and scanning electron microscopy (SEM). The specific surface area and mesoporous ratio of the hypercoal-based activated carbon are 1257 m2/g and 55.4%, respectively. When the activated carbons are used as the electrode materials, the specific capacitance reaches 309 F/g in 3 M KOH electrolyte. In comparison with those prepared without CuO absorber, the specific capacitance increases by 11.6%. It was proved that the addition of microwave absorber in microwave-assisted activation was a low-cost method for rapidly preparing activated carbon, and it could effectively promote the development of the pore structure and improve its electrochemical performance. 展开更多
关键词 hypercoal activated carbon microwave absorber pore structure electrochemical performance
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Analyzing Bandwidth on the Microwave Absorber by the Interface Reflection Model 被引量:3
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作者 乔亮 王涛 +4 位作者 梅忠磊 李喜玲 隋文波 唐丽云 李发伸 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第2期118-121,共4页
Metallic flaky sendust particles are prepared for use as fillers in electromagnetic attenuation composites. We report the interface reflection model to divide the broad bandwidth into electromagnetic loss and quarter-... Metallic flaky sendust particles are prepared for use as fillers in electromagnetic attenuation composites. We report the interface reflection model to divide the broad bandwidth into electromagnetic loss and quarter-wavelength (λ/4) cancelation. Combining with the face reflection calculation, we identify the electromagnetic loss originated from skin effect, which is used to explain over half of the absorbed energy in high frequency band. Most impor- tantly, the unique electromagnetic loss cannot generate the reflection loss (RL) peak. Using the phase relation of face reflection, we show evidence that the λ/4 cancelation is vital to generate the RL peak. The calculated energy loss agrees well with the experimental data and lays the foundation for further research. 展开更多
关键词 of ab in by Analyzing Bandwidth on the microwave Absorber by the Interface Reflection Model IS on
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Characterization of a Y-type hexagonal ferrite-based frequency tunable microwave absorber 被引量:3
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作者 Fang Xu Yang Bai +1 位作者 Kai Jiang Li-jie Qiao 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2012年第5期453-456,共4页
A Y-type hexaferrite rod with the composition of Ba2COl.8Cuo.2Fe12022 was presented as an absorbing material with high absorb- anee. Its high absorbance and wide absorption band result from ferromagnetic resonance (... A Y-type hexaferrite rod with the composition of Ba2COl.8Cuo.2Fe12022 was presented as an absorbing material with high absorb- anee. Its high absorbance and wide absorption band result from ferromagnetic resonance (FMR) that is self-biased by strong shape and mag- netocrystaUine anisotropy fields. Around the FMR frequency the specimen of the ferrite rods exhibits very high absorbance and the FMR frequency can be tuned by the rod dimension. In addition to the high absorbance and the wide tunable absorption band, the microwave ab- sorber has another advantage of light weight due to the use of the ferrite rods instead of ferrite slabs. 展开更多
关键词 hexagonal ferfite microwave materials microwave absorbers cobalt compounds ferromagnetic resonance
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