Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermom...Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.展开更多
The Proterozoic Aravalli-Delhi orogenic complex hosts a large number of economically important stratabound base metal sulphide deposits. In the present work, rock samples taken from Outcrop and Underground Mine of Sin...The Proterozoic Aravalli-Delhi orogenic complex hosts a large number of economically important stratabound base metal sulphide deposits. In the present work, rock samples taken from Outcrop and Underground Mine of Sindeskar Kalan, Vedanta Group, Rajpura Dariba-Bethumni Belt which is located at a distance of 76 kms from Udaipur city, Rajasthan have been studied. The chief litho units of the group which contain sulfide-bearing calc-silicate and graphite mica schist, dolomite marble, calc-biotite schist and quartzite are identified. An attempt has also been made to study/or hydrothermal in origin in the different types of fluid inclusions, hosted predominately in Geothermometry viz. heating and freezing study of entrapped palaeo-fluids (such as sedimentary and quartz host grain and a few in sphalerites). The quartz hosts are identified with four types of fluid inclusions, such as 1) monophase (gas/vapour), 2) gas-rich biphase, 3) liquid-rich biphase and 4) polyphase types. The primary types of fluid inclusions show that melting temperature of ice or depression freezing point (DFP) (ranging from -2.5°C to -7.2°C)/(salinity ranging from 4.5 - 13.25 wt% NaCl eq.) and temperature of homogenization into liquid phase (ranging from +188°C to +218°C) have been measured. Data from the fluid inclusions and salinity calculation (low salinity) reveal that rate of cooling is the important mechanism of ore deposition in the study area.展开更多
本文探讨流体包裹体组合(FIA)的原理及其对包裹体测温数据有效性的制约以及数据的表达方法。流体包裹体组合指的是一组同时被捕获的流体包裹体,其同时性的依据是岩相学关系而不是测温数据的相似性。如果根据岩相学关系建立了一个 FIA,...本文探讨流体包裹体组合(FIA)的原理及其对包裹体测温数据有效性的制约以及数据的表达方法。流体包裹体组合指的是一组同时被捕获的流体包裹体,其同时性的依据是岩相学关系而不是测温数据的相似性。如果根据岩相学关系建立了一个 FIA,且这个 FIA 内的包裹体测温数据很一致,那么这些包裹体可能属于均一捕获且在捕获后未受破坏,这些包裹体的测温数据是有效的。在进行数据汇总或统计时,应取整个 FIA 内所有包裹体的平均值为代表,而不应将每个包裹体的数据都列入。如果同一 FIA 内包裹体的测温数据变化很大,那么这些包裹体可能属于非均一捕获或在捕获后遭受了显著改变(如卡脖子、拉伸)。这种情况下包裹体的测温数据是无效的,不应纳入数据汇总或统计。在很多情况下,一组包裹体是否属于同时捕获是很难确定的,因此不能严格地用 FTA 的方法来判定数据的有效性。但是,FIA 的原理还是可以提供一些制约的。例如,如果相邻包裹体显示相似的测温数据,那么这些包裹体可能属于均一捕获且无显著捕获后变化。各个包裹体的数据都应纳入数据汇总及统计,但要注意不要将数据点过分集中在某个小区域。反之,如果相邻包裹体的测温数据相差很大,就要怀疑是不是非均一捕获、捕获后破坏,或不同期次包裹体叠加。详细的包裹体测温"填图",结合与已知 FIA 数据的比较,可能可以解决这种多解性问题。展开更多
A preliminary study was conducted to outline the laser Raman spectroscopy technique for determination of salinity in the aqueous phase in fluid inclusions. The skewing parameters of the Raman profiles of the calibrat...A preliminary study was conducted to outline the laser Raman spectroscopy technique for determination of salinity in the aqueous phase in fluid inclusions. The skewing parameters of the Raman profiles of the calibration solutions determined were used to derive a calibration curve for the estimation of the equivalent mass fraction NaCl in aqueous solutions. This technique was also verified in the analysis of the natural fluid inclusions from Tongshankou porphyry Cu (Mo) deposit, Hubei Province, China. Although the analyses on the natural fluid inclusions are limited, an acceptable agreement has been reached on the salinities, for most fluid inclusions, determined by the Raman spectroscopy and microthermometry techniques, indicating the reliability of the Raman technique for determination of salinity in fluid inclusion studies.展开更多
基金supported by the National Key R&D Program of China(2018YFA0702701)the Fundamental Research Funds for the Central Universities(WK3410000015).
文摘Infrared microthermometry allows direct measurement of fluid inclusions hosted in opaque ore minerals and can provide direct constraints on the evolution of ore-forming fluids.This study presents infrared microthermometry of spherite-hosted fluid inclusions from the Xinqiao deposit in the Middle-Lower Yangtze Metallogenic Belt and sheds new light on the ore genesis of the deposit.Considering that infrared light may lead to non-negligible temperature deviations during microthermometry,some tests were first conducted to ensure the accuracy of the microthermometric measurements.The measurement results indicated that using the lowest light intensity of the microscope and inserting an optical filter were effective in minimizing the possible temperature deviations of infrared microthermometry.All sphalerite-hosted fluid inclusions from the Xinqiao deposit were aqueous.They show homogenization temperature ranging from~200 to 350℃,but have two separate salinity groups(1.0 wt%-10 wt%and 15.1 wt%-19.2 wt%NaCl equivalent).The low-salinity group represents sedimentary exhalative(SEDEX)-associated fluids,whereas the high-salinity group results from modification by later magmatic hydrothermal fluids.Combined with published fluid inclusion data,the four-stage fluid evolution of the Xinqiao deposit was depicted.Furthermore,our data suggest that the Xinqiao deposit was formed by twostage metallogenic events including SEDEX and magmatic-hydrothermal mineralization.
文摘The Proterozoic Aravalli-Delhi orogenic complex hosts a large number of economically important stratabound base metal sulphide deposits. In the present work, rock samples taken from Outcrop and Underground Mine of Sindeskar Kalan, Vedanta Group, Rajpura Dariba-Bethumni Belt which is located at a distance of 76 kms from Udaipur city, Rajasthan have been studied. The chief litho units of the group which contain sulfide-bearing calc-silicate and graphite mica schist, dolomite marble, calc-biotite schist and quartzite are identified. An attempt has also been made to study/or hydrothermal in origin in the different types of fluid inclusions, hosted predominately in Geothermometry viz. heating and freezing study of entrapped palaeo-fluids (such as sedimentary and quartz host grain and a few in sphalerites). The quartz hosts are identified with four types of fluid inclusions, such as 1) monophase (gas/vapour), 2) gas-rich biphase, 3) liquid-rich biphase and 4) polyphase types. The primary types of fluid inclusions show that melting temperature of ice or depression freezing point (DFP) (ranging from -2.5°C to -7.2°C)/(salinity ranging from 4.5 - 13.25 wt% NaCl eq.) and temperature of homogenization into liquid phase (ranging from +188°C to +218°C) have been measured. Data from the fluid inclusions and salinity calculation (low salinity) reveal that rate of cooling is the important mechanism of ore deposition in the study area.
基金NSERCSaskatchewan Energy and Resources+2 种基金Geological Survey of Canada 国家自然科学基金(40772061)中国地质大学(北京)地质过程与矿产资源国家重点实验室(GPMR0740)资助
文摘本文探讨流体包裹体组合(FIA)的原理及其对包裹体测温数据有效性的制约以及数据的表达方法。流体包裹体组合指的是一组同时被捕获的流体包裹体,其同时性的依据是岩相学关系而不是测温数据的相似性。如果根据岩相学关系建立了一个 FIA,且这个 FIA 内的包裹体测温数据很一致,那么这些包裹体可能属于均一捕获且在捕获后未受破坏,这些包裹体的测温数据是有效的。在进行数据汇总或统计时,应取整个 FIA 内所有包裹体的平均值为代表,而不应将每个包裹体的数据都列入。如果同一 FIA 内包裹体的测温数据变化很大,那么这些包裹体可能属于非均一捕获或在捕获后遭受了显著改变(如卡脖子、拉伸)。这种情况下包裹体的测温数据是无效的,不应纳入数据汇总或统计。在很多情况下,一组包裹体是否属于同时捕获是很难确定的,因此不能严格地用 FTA 的方法来判定数据的有效性。但是,FIA 的原理还是可以提供一些制约的。例如,如果相邻包裹体显示相似的测温数据,那么这些包裹体可能属于均一捕获且无显著捕获后变化。各个包裹体的数据都应纳入数据汇总及统计,但要注意不要将数据点过分集中在某个小区域。反之,如果相邻包裹体的测温数据相差很大,就要怀疑是不是非均一捕获、捕获后破坏,或不同期次包裹体叠加。详细的包裹体测温"填图",结合与已知 FIA 数据的比较,可能可以解决这种多解性问题。
文摘A preliminary study was conducted to outline the laser Raman spectroscopy technique for determination of salinity in the aqueous phase in fluid inclusions. The skewing parameters of the Raman profiles of the calibration solutions determined were used to derive a calibration curve for the estimation of the equivalent mass fraction NaCl in aqueous solutions. This technique was also verified in the analysis of the natural fluid inclusions from Tongshankou porphyry Cu (Mo) deposit, Hubei Province, China. Although the analyses on the natural fluid inclusions are limited, an acceptable agreement has been reached on the salinities, for most fluid inclusions, determined by the Raman spectroscopy and microthermometry techniques, indicating the reliability of the Raman technique for determination of salinity in fluid inclusion studies.
