A method was developed to make a quantitative analysis of the microstructure of asphalt modified with styrene-butadiene-styrene block（SBS） copolymer. Moreover, both mixed and branched SBS were employed in the prepar...A method was developed to make a quantitative analysis of the microstructure of asphalt modified with styrene-butadiene-styrene block（SBS） copolymer. Moreover, both mixed and branched SBS were employed in the preparation of modified asphalt. By sampling specimens from the top, middle, and bottom, a number of microscope slides were made and 400 times micro images were gained. Binarized with the software of MATLAB, the images then went to the process of distribution test, when four typical distributions were employed to investigate the distribution of modifi er spread in asphalt. The distribution characteristic and its parameter were both found. The results show that asphalt phase clearly obeys Poisson distribution, and its parameter, λ, is bond up with the condition SBS performs in. Based on this parameter, indexes can be set up to evaluate the structure of the mixture and its performance as well. Compared with that modifi ed with mixed SBS, the asphalt modifi ed with branched SBS has better performance but worse stability, for it is easier to segregate.展开更多
Molecular dynamics simulations were carried out to study the internal energy and microstructure of potassium dihydrogen phosphates （KDP） solution at different temperatures. The water molecule was treated as a simple...Molecular dynamics simulations were carried out to study the internal energy and microstructure of potassium dihydrogen phosphates （KDP） solution at different temperatures. The water molecule was treated as a simple-point-charge model, while a seven-site model for the dihydrogen phosphate ion was adopted. The internal energy functions and the radial distribution functions of the solution were studied in detail. An unusually large local particle number density fluctuation was observed in the system at saturation temperature. It has been found that the specific heat of oversaturated solution is higher than that of unsaturated solution, which indicates the solution experiences a crystallization process below saturation temperature. The radial distribution function between the oxygen atom of water and the hydrogen atom of the dihydrogen phosphate ion shows a very strong hydrogen bond structure. There are strong interactions between potassium cation and oxygen atom of dihydrogen phosphate ion in KDP solution, and much more ion pairs were formed in saturated solution.展开更多
The distributions of local structural units of calcium silicate melts were quantified by means of classical molecular dynamics simulation and a newly constructed structural thermodynamic model. The distribution of fiv...The distributions of local structural units of calcium silicate melts were quantified by means of classical molecular dynamics simulation and a newly constructed structural thermodynamic model. The distribution of five kinds of Si-O tetrahedra Qi from these two methods was compared with each other and also with the experimental Raman spectra, an excellent agreement was achieved. These not only displayed the panorama distribution of microstructural units in the whole composition range, but also proved that the thermodynamic model is suitable for the utilization as the subsequent application model of spectral experiments for the thermodynamic calculation. Meanwhile, the five refined regions mastered by different disproportionating reactions were obtained. Finally, the distributions of two kinds of connections between Qi were obtained, denoted as Qi-Ca-Qj and Qi-[Ob]-Qj, from the thermodynamic model, and a theoretical verification was given that the dominant connections for any composition are equivalent connections.展开更多
The thread rolling process has been widely applied to manufacture high-performance thread parts.In this process,the evolutions of surface and subsurface are frequently introduced,which affect the working performance o...The thread rolling process has been widely applied to manufacture high-performance thread parts.In this process,the evolutions of surface and subsurface are frequently introduced,which affect the working performance of manufactured parts.In this study,an axial-infeed thread rolling process(ATRP)is employed,and the macro-meso surface characteristics under different lubrications and operating conditions are investigated.Moreover,the distributions of microstructure and hardness on the subsurface of formed tooth are analyzed in detail,along with the study of stress state and yield strength change.It is found that the MoS_(2)grease is more effective in reducing the surface roughness and defects than the lubrication oil and water-base graphite during the ATRP process.Increasing rolling speed improves the quality of surface morphology and can reduce the surface roughness.On the subsurface of bottom and flank,intensive shear stress occurs in a narrow region,resulting in the elongation and refinement of the grains and increasing the low angle grain boundary fraction.Based on the grain size and plastic strain,the yield strength is predicted.The maximum yield strength and hardness on the bottom of formed tooth are improved by 41.2% and 39.4%,respectively.展开更多
7085-T7452 plates with a thickness of 12 mm were welded by conventional single side and bobbin tool friction stir welding （SS-FSW and BB-FSW, respectively） at different welding parameters. The temperature distributi...7085-T7452 plates with a thickness of 12 mm were welded by conventional single side and bobbin tool friction stir welding （SS-FSW and BB-FSW, respectively） at different welding parameters. The temperature distribution, microstructure evolution and mechanical properties of joints along the thickness direction were investigated, and digital image correlation （DIC） was utilized to evaluate quantitatively the deformation of different zones during tensile tests. The results indicated that heat-affected zone （HAZ）, the local softening region, was responsible for the early plastic deformation and also the fracture location for SS-FSW samples, while a rapid fracture was observed in weld nugget zone （WNZ） before yield behavior for all BB-FSW specimens. The ultimate tensile strength （UTS） of SS-FSW joints presented the highest value of 410 MPa, 82% of the base material, at a rotational speed of 300 rpm and welding speed of 60 mm/min, much higher than that of BB-FSW joints, with a joint efficiency of only 47%. This should be attributed to the Lazy S defect produced by a larger extent of heat input during the BB-FSW process, The whole joint exhibited a much higher elongation than the slices. Scanning electron microscopic （SEM） analysis of the fracture morphologies showed that joints failed through ductile fracture for SS-FSW and brittle fracture for BB-FSW.展开更多
A program of Monte Carlo simulation of binary copolymerization for E-SBR (emulsion polymn. SB rubber) was made according to the terminal model. The simulation results obtained by this program were in good agreement wi...A program of Monte Carlo simulation of binary copolymerization for E-SBR (emulsion polymn. SB rubber) was made according to the terminal model. The simulation results obtained by this program were in good agreement with those experimental ones. A detail microstructure information of E-SBR molecular chain has been provided.展开更多
基金Funded by the National Natural Science Foundation of China(51178348)
文摘A method was developed to make a quantitative analysis of the microstructure of asphalt modified with styrene-butadiene-styrene block（SBS） copolymer. Moreover, both mixed and branched SBS were employed in the preparation of modified asphalt. By sampling specimens from the top, middle, and bottom, a number of microscope slides were made and 400 times micro images were gained. Binarized with the software of MATLAB, the images then went to the process of distribution test, when four typical distributions were employed to investigate the distribution of modifi er spread in asphalt. The distribution characteristic and its parameter were both found. The results show that asphalt phase clearly obeys Poisson distribution, and its parameter, λ, is bond up with the condition SBS performs in. Based on this parameter, indexes can be set up to evaluate the structure of the mixture and its performance as well. Compared with that modifi ed with mixed SBS, the asphalt modifi ed with branched SBS has better performance but worse stability, for it is easier to segregate.
文摘Molecular dynamics simulations were carried out to study the internal energy and microstructure of potassium dihydrogen phosphates （KDP） solution at different temperatures. The water molecule was treated as a simple-point-charge model, while a seven-site model for the dihydrogen phosphate ion was adopted. The internal energy functions and the radial distribution functions of the solution were studied in detail. An unusually large local particle number density fluctuation was observed in the system at saturation temperature. It has been found that the specific heat of oversaturated solution is higher than that of unsaturated solution, which indicates the solution experiences a crystallization process below saturation temperature. The radial distribution function between the oxygen atom of water and the hydrogen atom of the dihydrogen phosphate ion shows a very strong hydrogen bond structure. There are strong interactions between potassium cation and oxygen atom of dihydrogen phosphate ion in KDP solution, and much more ion pairs were formed in saturated solution.
基金Project(2012CB722805)supported by the National Basic Research Program of ChinaProjects(50504010,50974083,51174131,51374141)supported by the National Natural Science Foundation of China+1 种基金Project(50774112)supported by the Joint Fund of NSFC and Baosteel,ChinaProject(07QA4021)supported by the Shanghai"Phosphor"Science Foundation,China
文摘The distributions of local structural units of calcium silicate melts were quantified by means of classical molecular dynamics simulation and a newly constructed structural thermodynamic model. The distribution of five kinds of Si-O tetrahedra Qi from these two methods was compared with each other and also with the experimental Raman spectra, an excellent agreement was achieved. These not only displayed the panorama distribution of microstructural units in the whole composition range, but also proved that the thermodynamic model is suitable for the utilization as the subsequent application model of spectral experiments for the thermodynamic calculation. Meanwhile, the five refined regions mastered by different disproportionating reactions were obtained. Finally, the distributions of two kinds of connections between Qi were obtained, denoted as Qi-Ca-Qj and Qi-[Ob]-Qj, from the thermodynamic model, and a theoretical verification was given that the dominant connections for any composition are equivalent connections.
基金supported by the Shaanxi Province Key Research and Development Program(2021GXLH-Z-049,2020GY-168)the Joint Fund for Aerospace Advanced Manufacturing Technology Research Key Program(U1937203)+3 种基金the State Scholarship Fund from the China Scholarship Council(CSC)the Talent Project of Bright Pearl of the Yellow Sea of Yanchengsupport of Institute of Engineering Research at Seoul National Universitygrant from NRF(No.2022R1A2C2009315)。
文摘The thread rolling process has been widely applied to manufacture high-performance thread parts.In this process,the evolutions of surface and subsurface are frequently introduced,which affect the working performance of manufactured parts.In this study,an axial-infeed thread rolling process(ATRP)is employed,and the macro-meso surface characteristics under different lubrications and operating conditions are investigated.Moreover,the distributions of microstructure and hardness on the subsurface of formed tooth are analyzed in detail,along with the study of stress state and yield strength change.It is found that the MoS_(2)grease is more effective in reducing the surface roughness and defects than the lubrication oil and water-base graphite during the ATRP process.Increasing rolling speed improves the quality of surface morphology and can reduce the surface roughness.On the subsurface of bottom and flank,intensive shear stress occurs in a narrow region,resulting in the elongation and refinement of the grains and increasing the low angle grain boundary fraction.Based on the grain size and plastic strain,the yield strength is predicted.The maximum yield strength and hardness on the bottom of formed tooth are improved by 41.2% and 39.4%,respectively.
基金financial support of the project from the National Natural Science Foundation of China(No.51405392)Specialized Research Fund for the Doctoral Program of Higher Education(No.20136102120022)Hong Kong Scholar Program(No.XJ2016043)
文摘7085-T7452 plates with a thickness of 12 mm were welded by conventional single side and bobbin tool friction stir welding （SS-FSW and BB-FSW, respectively） at different welding parameters. The temperature distribution, microstructure evolution and mechanical properties of joints along the thickness direction were investigated, and digital image correlation （DIC） was utilized to evaluate quantitatively the deformation of different zones during tensile tests. The results indicated that heat-affected zone （HAZ）, the local softening region, was responsible for the early plastic deformation and also the fracture location for SS-FSW samples, while a rapid fracture was observed in weld nugget zone （WNZ） before yield behavior for all BB-FSW specimens. The ultimate tensile strength （UTS） of SS-FSW joints presented the highest value of 410 MPa, 82% of the base material, at a rotational speed of 300 rpm and welding speed of 60 mm/min, much higher than that of BB-FSW joints, with a joint efficiency of only 47%. This should be attributed to the Lazy S defect produced by a larger extent of heat input during the BB-FSW process, The whole joint exhibited a much higher elongation than the slices. Scanning electron microscopic （SEM） analysis of the fracture morphologies showed that joints failed through ductile fracture for SS-FSW and brittle fracture for BB-FSW.
文摘A program of Monte Carlo simulation of binary copolymerization for E-SBR (emulsion polymn. SB rubber) was made according to the terminal model. The simulation results obtained by this program were in good agreement with those experimental ones. A detail microstructure information of E-SBR molecular chain has been provided.
