A wet-chemical method was presented for preparation of spherical, flowerlike, hexagonal, and triangular microsized silver crystals. Well-defined particles were prepared by mixing of iron（II） sulfate heptahydrate sol...A wet-chemical method was presented for preparation of spherical, flowerlike, hexagonal, and triangular microsized silver crystals. Well-defined particles were prepared by mixing of iron（II） sulfate heptahydrate solution with silver nitrate solution at the presence of different modifiers with high-speed stirring at 8-20℃. It is found that the diameters of resulting products are 0.6-6.0 um and the morphologies of the silver microcrystals are greatly affected by the introduced modifiers. It is concluded that the microsized silver crystals with different morphologies can be synthesized by introducing appropriate modifiers at appropriate experimental parameters. Scanning electron microscopy and X-ray diffraction were used to characterize the resulting products.展开更多
Recently, Hsieh and Horng [1] published the paper entitled as above. In section 3 results and discussion, the authors mentioned the first and the second order kinetic models without any quotations. In fact these two k...Recently, Hsieh and Horng [1] published the paper entitled as above. In section 3 results and discussion, the authors mentioned the first and the second order kinetic models without any quotations. In fact these two kinetic models have been published [2-5]. In order to distinguish a kinetics model based on the ad- sorption capacity of a solid from the one based on the concentration of a solution, Lagergren＇s first-order rate equation has been called pseudo-first-order [6-7]. The Lagergren＇s equation has been widely cited, but there are far more mistakes made in the quotation and in the reference section of papers, including the title, the author＇s name, journal title, year of publishing, volume, and page number [3]. In addition, the second order kinetic expression for the adsorption systems of divalent metal ions using sphagnum moss peat has been reported by Ho [8].展开更多
The preparation of microsized hematite powder from ferrous sulfate using microwave calcination was investigated based on the TG/DTG curves. The decomposition of industrial ferrous sulfate under air atmosphere was divi...The preparation of microsized hematite powder from ferrous sulfate using microwave calcination was investigated based on the TG/DTG curves. The decomposition of industrial ferrous sulfate under air atmosphere was divided into three stages, and a ferrous sulfate sample added with 15% Fe_2O_3 could strongly absorb microwave energy. Therefore, preparing hematite powder from ferrous sulfate using microwave calcination was feasible. Hematite was obtained under the following optimized conditions: calcination temperature, 850 °C; microwave power, 650 W; and sample amount, 40 g. The obtained hematite satisfied the first-grade quality requirements. The total ferrum value was more than 58%, and the total sulfur and phosphorus contents were less than 0.5% and 0.2%, respectively. X-ray powder diffraction and scanning electron microscopy were used to characterize the structure and morphology of microsized hematite powder. The particles were non-spherical in shape, and the average particle size distribution was 10.45 μm. This work provides new potential applications for waste ferrous sulfate.展开更多
Silicon with high specific capacity is deemed an ideal anode material for lithium ion batteries,which,however suffers from low cycling life due to its dramatic volume changes.Water-soluble polymer binders recently gai...Silicon with high specific capacity is deemed an ideal anode material for lithium ion batteries,which,however suffers from low cycling life due to its dramatic volume changes.Water-soluble polymer binders recently gain increasing attention by providing an eco-friendly and low-cost way in improving the cycling stability of Si-based anodes.Herein,a novel bioinspired supramolecular mineral hydrogel binder consisting of polyacrylic acid (PAA) physically crosslinked with amorphous calcium carbonate (ACC) nanoparticles is designed for high-performance anodes made from low-cost microsized Si particles.Owing to its organic-inorganic hydrophilic nature,ACC-PAA hybrid binder exhibits the reported highest modulus (~22 GPa) for polymer binders in electrolyte,even higher than lithiated Si species (Li15Si4,~12 GPa).Together with its excellent adhesion and electrochemical stability,ACC-PAA binder can effectively suppress the pulverization of Si particles and maintain the mechanical integrity of electrodes during cycling.Therefore,even with a low binder content,the anode still shows an initial discharge capacity of 2,973 mAh·g^-1 and Coulombic efficiency of 81.5%,and retains 75% at a current density of 600 mA·g^-1 after 100 cycles.The present organic-inorganic hybrid mineral binder may open a new approach for designing more effective polymer binders for Si-based lithium-ion batteries.展开更多
To compare the cytotoxicity on HeLa cells induced by nanosized and microsized tellurium powders, HeLa cells were exposed to different concentrations of tellurium powders （0, 50, 100, 150 and 200 μg/mL） for 12 h. In...To compare the cytotoxicity on HeLa cells induced by nanosized and microsized tellurium powders, HeLa cells were exposed to different concentrations of tellurium powders （0, 50, 100, 150 and 200 μg/mL） for 12 h. In this study, detection of a series of biomarkers, including reactive oxygen species （ROS）, glutathione （GSH）, 8-hydroxy-2＇- deoxyguanosine （8-OHdG）, in addition to DNA and protein crosslink （DPC） and MTT assay, were conducted to evaluate the cytotoxicity. It is indicated that compared with the control group, there was no significant difference in the induced cytotoxicity at concentrations lower than 50 μg/mL for both nanosized and microsized tellurium powders. While there appears a significant difference in the induced cytotoxicity for nanosized tellurium powders when the concentration is higher than 100 μg/mL as well as for microsized tellurium powders when the concentration is higher than 200 μg/mL. Moreover, it is found that the cytotoxicity induced on HeLa cells exhibits a certain dose-effect relationship with the concentration of tellurium powders. A conclusion has been reached that the toxicity on HeLa cells can be induced by both nanosized and microsized tellurium powders, and the toxicity of the nanosized tellurium powders is significantly greater than the microsized one.展开更多
Microsized bismuth(Bi)with in-situ constructed three-dimensional(3D)porous network has been considered as a promising anode for high-performance potassium-ion batteries(PIBs).However,the mechanism of the in-situ porou...Microsized bismuth(Bi)with in-situ constructed three-dimensional(3D)porous network has been considered as a promising anode for high-performance potassium-ion batteries(PIBs).However,the mechanism of the in-situ porous evolution of microsized Bi during the charge/discharge process is still mysterious.Herein,various electrolytes are employed to disclose the origin of porous evolution of microsized Bi in PIBs.Experimentally and theoretically,the 3D porous network originates from the uniform interfacial charge distribution on the Bi surface in the linear ether-based electrolyte.In addition,the universality of the interfacial charge distribution mechanism was verified by microsized Sn and Sb.The in-situ constructed 3D porous network of Bi enables a superior potassium storage performance in a wide temperature range from-40 to 40℃.More importantly,the K_(0.9)Mn_(0.7)Ni_(0.3)O_(2)||Bi full cell delivers excellent cycling stability(a high capacity retention of 88.44%even after 2,000 cycles)and good temperature tolerance.This work gives a distinct clarification of the origin of the porous evolution of microsized Bi during cycling,which is critical for developing high-performance PIBs.展开更多
Micro-sized anode materials demonstrate greater potential for practical applications than nanomaterials in the aspects of volumetric energy density,coulombic efficiency,fabrication process,and cost.However,the huge vo...Micro-sized anode materials demonstrate greater potential for practical applications than nanomaterials in the aspects of volumetric energy density,coulombic efficiency,fabrication process,and cost.However,the huge volume changes of alloy anodes(up to∼500%)during repeated charge/discharge has led to a series of challenging issues including pulverization of active material particles and delamination from current collectors,formation of thick and fragile solid-electrolyte interphase(SEI)and depletion of electrolytes,eventually leading to rapid cell degradation.Herein,we review recent progress of rational strategies to enable the use of microsized alloy anodes(Si,P,Sb,Sn,etc.)including electrolyte modulation,binder design and architecture engineering.We also provide perspectives on future directions and remaining challenges of microsized anodes towards practical applications.展开更多
In this study, we use the Bohai Sea area as an example to investigate the characteristics of secondary microseisms and their impact on seismic noise based on the temporal frequency spectral analysis of observation dat...In this study, we use the Bohai Sea area as an example to investigate the characteristics of secondary microseisms and their impact on seismic noise based on the temporal frequency spectral analysis of observation data from 33 broadband seismic stations during strong gust periods, and new perspectives are proposed on the generation mechanisms of secondary microseisms. The results show that short-period double- frequency (SPDF) and long-period double-frequency (LPDF) microseisms exhibit significant alternating trends of strengthening and weakening in the northwest area of the Bohai Sea. SPDF microseisms are generated by irregular wind waves during strong off shore wind periods, with a broad frequency band distributed in the range of 0.2-1 Hz;LPDF microseisms are generated by regular swells during periods of sea wind weakening, with a narrow frequency band concentrated between 0.15 and 0.3 Hz. In terms of temporal dimensions, as the sea wind weakens, the energy of SPDF microseisms weakens, and the dominant frequencies increase, whereas the energy of LPDF microseisms strengthens and the dominant frequencies decrease, which is consistent with the process of the decay of wind waves and the growth of swells. In terms of spatial dimensions, as the microseisms propagate inland areas, the advantageous frequency band and energy of SPDF microseisms are reduced and significantly attenuated, respectively, whereas LPDF microseisms show no significant changes. And during the propagation process in high-elevation areas, LPDF microseisms exhibit a certain site amplifi cation eff ect when the energy is strong. The results provide important supplements to the basic theory of secondary microseisms, preliminarily reveal the relationship between the atmosphere, ocean, and seismic noise, and provide important theoretical references for conducting geological and oceanographic research based on the characteristics of secondary microseisms.展开更多
This article introduces a cable-free real-time telemetry seismic acquisition system(hereinafter referred to as the cable-free real-time telemetry system)that utilizes 4G/5G technology.This system facilitates the real-...This article introduces a cable-free real-time telemetry seismic acquisition system(hereinafter referred to as the cable-free real-time telemetry system)that utilizes 4G/5G technology.This system facilitates the real-time acquisition and quality control of seismic data,the real-time monitoring of equipment location and health status,the synchronous transmission of collected data between the cloud and client,and the real-time issuance of operational instructions.It addresses the critical limitation of existing seismic node equipment,which is often restricted to mining and blind storage due to the absence of a wired or wireless communication link between the acquisition node device and the central control unit.This limitation necessitates local data storage and rendering real-time quality control unfeasible.Typically,quality control is conducted post-task completion,requiring the overall retrieval and downloading of data.If data issues are identifi ed,it becomes necessary to eliminate faulty tracks and determine the need for supplementary acquisition,which can lead to delays in the acquisition process.The implementation of real-time monitoring and early warning systems for equipment health status aims to mitigate the risk of poor data quality resulting from equipment anomalies.Furthermore,the real-time synchronous transmission between the cloud and server addresses the bottleneck of slow download speeds associated with the centralized retrieval of data from multiple node devices during blind acquisition and storage.A real-time microseismic data acquisition test and verifi cation were conducted at a fracturing site in an eastern oil and gas fi eld.Analysis of the test data indicates that the overall performance indicators of the system are comparable to those of existing mainstream system equipment,demonstrating stability and reliability.The performance parameters fully satisfy the technical requirements for oilfield fracturing monitoring scenarios,suggesting promising prospects for further promotion and application.展开更多
Shake table testing was performed to investigate the dynamic stability of a mid-dip bedding rock slope under frequent earthquakes. Then, numerical modelling was established to further study the slope dynamic stability...Shake table testing was performed to investigate the dynamic stability of a mid-dip bedding rock slope under frequent earthquakes. Then, numerical modelling was established to further study the slope dynamic stability under purely microseisms and the influence of five factors, including seismic amplitude, slope height, slope angle, strata inclination and strata thickness, were considered. The experimental results show that the natural frequency of the slope decreases and damping ratio increases as the earthquake loading times increase. The dynamic strength reduction method is adopted for the stability evaluation of the bedding rock slope in numerical simulation, and the slope stability decreases with the increase of seismic amplitude, increase of slope height, reduction of strata thickness and increase of slope angle. The failure mode of a mid-dip bedding rock slope in the shaking table test is integral slipping along the bedding surface with dipping tensile cracks at the slope rear edge going through the bedding surfaces. In the numerical simulation, the long-term stability of a mid-dip bedding slope is worst under frequent microseisms and the slope is at risk of integral sliding instability, whereas the slope rock mass is more broken than shown in the shaking table test. The research results are of practical significance to better understand the formation mechanism of reservoir landslides and prevent future landslide disasters.展开更多
Ever since the impoundment of Three Gorges Reservoir（TGR）, the seismicity in head region of TGR has increased significantly. Coupled with wide fluctuation of water level each year, it becomes more important to study...Ever since the impoundment of Three Gorges Reservoir（TGR）, the seismicity in head region of TGR has increased significantly. Coupled with wide fluctuation of water level each year, it becomes more important to study the deformation forecasting of landslides beside TGR. As a famous active landslide beside TGR, Huangtupo riverside landslide is selected for a case study. Based on long term water level fluctuation and seismic monitoring, three typical adverse conditions are determined. With the established 3D numerical landslide model, seepage-dynamic coupling calculation is conducted under the seismic intensity of V degree. Results are as follows： 1. the dynamic water pressure formed by water level fluctuation will intensify the deformation of landslide; 2. under seismic load, the dynamic hysteresis is significant in defective geological bodies, such as weak layer and slip zone soil, because of much higher damping ratios, the seismic accelerate would be amplified in these elements; 3. microseisms are not intense enough to cause the landslide instability suddenly, but long term deformation accumulation effect of landslide should be paid more attention; 4. in numerical simulation, the factors of unbalance force and excess pore pressure also can be used in forecasting deformation tendency of landslide.展开更多
The isothermal compression testing of Ti555211 titanium alloys was carried out at deformation temperatures from 750 to 950 ℃ in 50 ℃ intervals,with strain rate of 0.001-1.000 s-1and height reduction of 20%-60%.The e...The isothermal compression testing of Ti555211 titanium alloys was carried out at deformation temperatures from 750 to 950 ℃ in 50 ℃ intervals,with strain rate of 0.001-1.000 s-1and height reduction of 20%-60%.The effect of processing parameters（deformation temperature,strain rate and deformation degree） on the microstructure evolution and the microstructure variables was investigated.The results show that the content of primary α phase decreases with the increase in deformation temperature.The effect of strain rate on microstructure variables of isothermally compressed Ti555211 alloy is mainly dependent on the deformation temperature.The fine second α phase partly transforms to β phase due to the deformation heat effect at the high strain rate,α phase becomes globular with temperature increasing and strain rate decreasing.In contrast,α phase is refined with temperature decreasing and strain rate increasing.The deformation degree has a little influence on the grain size and the morphology of primary α phase,but the effect of deformation degree on the morphology of second α phase is significant.The larger deformation degree is in favor of the globularization of lamellar α structure.展开更多
Evaluating the seismic site effect by the ambient noise based horizontal-to-vertical spectral ratio(HVSR)method is strongly affected by the spatial and temporal variations of the ambient noise sources.Therefore,it is ...Evaluating the seismic site effect by the ambient noise based horizontal-to-vertical spectral ratio(HVSR)method is strongly affected by the spatial and temporal variations of the ambient noise sources.Therefore,it is necessary to locate the source regions of ambient noise and investigate the relationships between the source energy and HVSR values at the predominant frequency(HVSRf_(0))of the site.The generation mechanisms of the single-and double-frequency microseisms(SFMs,0.05-0.085 Hz and DFMs,0.1-0.5 Hz)in ambient noise are better understood than the noise in other frequency bands and they are dominantly composed of fundamental Rayleigh(Rg)waves.With this advantage,the recordings of SFMs and DFMs at 30 stations in the east coast region of the United States are used to demonstrate a study on locating their source regions with reasonable certainty and constructing the functional relationship between the HVSRf_(0) and the source energy of SFMs and DFMs.The recordings are processed in four sub-frequency bands(Fs)of SF and DF bands and a polarization analysis is carried out to select the ellipsoids approximating the particle motions of Rg waves.Then the probability density functions of the back azimuths of the ellipsoids’semi-major axes are computed for each F and station,and are projected on the ocean to determine their possible source regions.These regions are further constrained by(1)the correlation coefficients between the SFMs and the WAVEWATCHⅢ(WWⅢ)hindcasts of ocean wave spectra in the SF band,or between the DFMs and the modeled DF energy on ocean surface in the selected time windows in the DF band,(2)the energy contribution defined by(i)the average WWⅢocean wave energy and the ocean bottom topographical gradient in the SF band,or(ii)the average modeled DF energy on ocean surface and a frequency and water depth dependent coefficient measuring the conversion efficiency of DF energy from water to solid earth in the DF band,and(3)the percentile retained energy of Rg waves in both the SF and DF bands.Results of source regions reveal that(1)the SFMs recorded in eastern US result from the interactions of low frequency(0.05-0.085 Hz)ocean waves with the continental slope and shelf of western North Atlantic Ocean;(2)the source regions for long-(0.1-0.2 Hz)period DFMs are located in the deep ocean close to the continental slope;and(3)the short-(0.2–0.5 Hz)period DFMs are generated in the continental shelf.Finally,the correlation analyses between the simulated source energy and the HVSRf_(0) values at the stations whose f_(0) s fall in DF band are carried out revealing significant source effect on thick sediments at low frequencies.展开更多
文摘A wet-chemical method was presented for preparation of spherical, flowerlike, hexagonal, and triangular microsized silver crystals. Well-defined particles were prepared by mixing of iron（II） sulfate heptahydrate solution with silver nitrate solution at the presence of different modifiers with high-speed stirring at 8-20℃. It is found that the diameters of resulting products are 0.6-6.0 um and the morphologies of the silver microcrystals are greatly affected by the introduced modifiers. It is concluded that the microsized silver crystals with different morphologies can be synthesized by introducing appropriate modifiers at appropriate experimental parameters. Scanning electron microscopy and X-ray diffraction were used to characterize the resulting products.
文摘Recently, Hsieh and Horng [1] published the paper entitled as above. In section 3 results and discussion, the authors mentioned the first and the second order kinetic models without any quotations. In fact these two kinetic models have been published [2-5]. In order to distinguish a kinetics model based on the ad- sorption capacity of a solid from the one based on the concentration of a solution, Lagergren＇s first-order rate equation has been called pseudo-first-order [6-7]. The Lagergren＇s equation has been widely cited, but there are far more mistakes made in the quotation and in the reference section of papers, including the title, the author＇s name, journal title, year of publishing, volume, and page number [3]. In addition, the second order kinetic expression for the adsorption systems of divalent metal ions using sphagnum moss peat has been reported by Ho [8].
基金Project(2013AA064003)supported by the National Technology Research and Development Program of ChinaProject(51564033)supported by the National Natural Science Foundation of ChinaProject(2016FA023)supported by the Yunnan Applied Basic Research(CNMRCUXT1403)State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization,Kunming University of Science and Technology,China
文摘The preparation of microsized hematite powder from ferrous sulfate using microwave calcination was investigated based on the TG/DTG curves. The decomposition of industrial ferrous sulfate under air atmosphere was divided into three stages, and a ferrous sulfate sample added with 15% Fe_2O_3 could strongly absorb microwave energy. Therefore, preparing hematite powder from ferrous sulfate using microwave calcination was feasible. Hematite was obtained under the following optimized conditions: calcination temperature, 850 °C; microwave power, 650 W; and sample amount, 40 g. The obtained hematite satisfied the first-grade quality requirements. The total ferrum value was more than 58%, and the total sulfur and phosphorus contents were less than 0.5% and 0.2%, respectively. X-ray powder diffraction and scanning electron microscopy were used to characterize the structure and morphology of microsized hematite powder. The particles were non-spherical in shape, and the average particle size distribution was 10.45 μm. This work provides new potential applications for waste ferrous sulfate.
基金the National Natural Science Foundation of China (NSFC)(Nos.51733003 and 51873035).
文摘Silicon with high specific capacity is deemed an ideal anode material for lithium ion batteries,which,however suffers from low cycling life due to its dramatic volume changes.Water-soluble polymer binders recently gain increasing attention by providing an eco-friendly and low-cost way in improving the cycling stability of Si-based anodes.Herein,a novel bioinspired supramolecular mineral hydrogel binder consisting of polyacrylic acid (PAA) physically crosslinked with amorphous calcium carbonate (ACC) nanoparticles is designed for high-performance anodes made from low-cost microsized Si particles.Owing to its organic-inorganic hydrophilic nature,ACC-PAA hybrid binder exhibits the reported highest modulus (~22 GPa) for polymer binders in electrolyte,even higher than lithiated Si species (Li15Si4,~12 GPa).Together with its excellent adhesion and electrochemical stability,ACC-PAA binder can effectively suppress the pulverization of Si particles and maintain the mechanical integrity of electrodes during cycling.Therefore,even with a low binder content,the anode still shows an initial discharge capacity of 2,973 mAh·g^-1 and Coulombic efficiency of 81.5%,and retains 75% at a current density of 600 mA·g^-1 after 100 cycles.The present organic-inorganic hybrid mineral binder may open a new approach for designing more effective polymer binders for Si-based lithium-ion batteries.
文摘To compare the cytotoxicity on HeLa cells induced by nanosized and microsized tellurium powders, HeLa cells were exposed to different concentrations of tellurium powders （0, 50, 100, 150 and 200 μg/mL） for 12 h. In this study, detection of a series of biomarkers, including reactive oxygen species （ROS）, glutathione （GSH）, 8-hydroxy-2＇- deoxyguanosine （8-OHdG）, in addition to DNA and protein crosslink （DPC） and MTT assay, were conducted to evaluate the cytotoxicity. It is indicated that compared with the control group, there was no significant difference in the induced cytotoxicity at concentrations lower than 50 μg/mL for both nanosized and microsized tellurium powders. While there appears a significant difference in the induced cytotoxicity for nanosized tellurium powders when the concentration is higher than 100 μg/mL as well as for microsized tellurium powders when the concentration is higher than 200 μg/mL. Moreover, it is found that the cytotoxicity induced on HeLa cells exhibits a certain dose-effect relationship with the concentration of tellurium powders. A conclusion has been reached that the toxicity on HeLa cells can be induced by both nanosized and microsized tellurium powders, and the toxicity of the nanosized tellurium powders is significantly greater than the microsized one.
基金supported by the National Natural Science Foundation of China(No.22005082,52202286)Natural Science Foundation of Hebei Province(No.B2020202065)+2 种基金the Special Project of Local Science and Technology Development Guided by the Central Government of China(226Z4402G)Science Research Project of Hebei Education Department(No.QN2020209,CXY2024036)Basic Research Project of Wenzhou City(G20220016)。
文摘Microsized bismuth(Bi)with in-situ constructed three-dimensional(3D)porous network has been considered as a promising anode for high-performance potassium-ion batteries(PIBs).However,the mechanism of the in-situ porous evolution of microsized Bi during the charge/discharge process is still mysterious.Herein,various electrolytes are employed to disclose the origin of porous evolution of microsized Bi in PIBs.Experimentally and theoretically,the 3D porous network originates from the uniform interfacial charge distribution on the Bi surface in the linear ether-based electrolyte.In addition,the universality of the interfacial charge distribution mechanism was verified by microsized Sn and Sb.The in-situ constructed 3D porous network of Bi enables a superior potassium storage performance in a wide temperature range from-40 to 40℃.More importantly,the K_(0.9)Mn_(0.7)Ni_(0.3)O_(2)||Bi full cell delivers excellent cycling stability(a high capacity retention of 88.44%even after 2,000 cycles)and good temperature tolerance.This work gives a distinct clarification of the origin of the porous evolution of microsized Bi during cycling,which is critical for developing high-performance PIBs.
文摘Micro-sized anode materials demonstrate greater potential for practical applications than nanomaterials in the aspects of volumetric energy density,coulombic efficiency,fabrication process,and cost.However,the huge volume changes of alloy anodes(up to∼500%)during repeated charge/discharge has led to a series of challenging issues including pulverization of active material particles and delamination from current collectors,formation of thick and fragile solid-electrolyte interphase(SEI)and depletion of electrolytes,eventually leading to rapid cell degradation.Herein,we review recent progress of rational strategies to enable the use of microsized alloy anodes(Si,P,Sb,Sn,etc.)including electrolyte modulation,binder design and architecture engineering.We also provide perspectives on future directions and remaining challenges of microsized anodes towards practical applications.
基金supported by Earthquake Science and Technology Spark Program of China Earthquake Administration (No. XH20006Y)Local Standards Formulation and Revision Program of Hebei Province (No. FW202154)+1 种基金Earthquake Science and Technology Spark Program of Hebei Earthquake Agency (No. DZ2024112100002)2023 Seismological Data Sharing Project of China Earthquake Networks Center (Dataset Project)。
文摘In this study, we use the Bohai Sea area as an example to investigate the characteristics of secondary microseisms and their impact on seismic noise based on the temporal frequency spectral analysis of observation data from 33 broadband seismic stations during strong gust periods, and new perspectives are proposed on the generation mechanisms of secondary microseisms. The results show that short-period double- frequency (SPDF) and long-period double-frequency (LPDF) microseisms exhibit significant alternating trends of strengthening and weakening in the northwest area of the Bohai Sea. SPDF microseisms are generated by irregular wind waves during strong off shore wind periods, with a broad frequency band distributed in the range of 0.2-1 Hz;LPDF microseisms are generated by regular swells during periods of sea wind weakening, with a narrow frequency band concentrated between 0.15 and 0.3 Hz. In terms of temporal dimensions, as the sea wind weakens, the energy of SPDF microseisms weakens, and the dominant frequencies increase, whereas the energy of LPDF microseisms strengthens and the dominant frequencies decrease, which is consistent with the process of the decay of wind waves and the growth of swells. In terms of spatial dimensions, as the microseisms propagate inland areas, the advantageous frequency band and energy of SPDF microseisms are reduced and significantly attenuated, respectively, whereas LPDF microseisms show no significant changes. And during the propagation process in high-elevation areas, LPDF microseisms exhibit a certain site amplifi cation eff ect when the energy is strong. The results provide important supplements to the basic theory of secondary microseisms, preliminarily reveal the relationship between the atmosphere, ocean, and seismic noise, and provide important theoretical references for conducting geological and oceanographic research based on the characteristics of secondary microseisms.
基金funded by the National Natural Science Foundation of China (42074127)the Key Program of National Natural Science Foundation of China (41930425)Research on Key Technologies for the Production, Exploration, and Development of Continental Shale Oil (2023ZZ15YJ02)。
文摘This article introduces a cable-free real-time telemetry seismic acquisition system(hereinafter referred to as the cable-free real-time telemetry system)that utilizes 4G/5G technology.This system facilitates the real-time acquisition and quality control of seismic data,the real-time monitoring of equipment location and health status,the synchronous transmission of collected data between the cloud and client,and the real-time issuance of operational instructions.It addresses the critical limitation of existing seismic node equipment,which is often restricted to mining and blind storage due to the absence of a wired or wireless communication link between the acquisition node device and the central control unit.This limitation necessitates local data storage and rendering real-time quality control unfeasible.Typically,quality control is conducted post-task completion,requiring the overall retrieval and downloading of data.If data issues are identifi ed,it becomes necessary to eliminate faulty tracks and determine the need for supplementary acquisition,which can lead to delays in the acquisition process.The implementation of real-time monitoring and early warning systems for equipment health status aims to mitigate the risk of poor data quality resulting from equipment anomalies.Furthermore,the real-time synchronous transmission between the cloud and server addresses the bottleneck of slow download speeds associated with the centralized retrieval of data from multiple node devices during blind acquisition and storage.A real-time microseismic data acquisition test and verifi cation were conducted at a fracturing site in an eastern oil and gas fi eld.Analysis of the test data indicates that the overall performance indicators of the system are comparable to those of existing mainstream system equipment,demonstrating stability and reliability.The performance parameters fully satisfy the technical requirements for oilfield fracturing monitoring scenarios,suggesting promising prospects for further promotion and application.
基金National Natural Science Foundation of China under Grant No. 41372356the College Cultivation Project of the National Natural Science Foundation of China under Grant No. 2018PY30+1 种基金the Basic Research and Frontier Exploration Project of Chongqing,China under Grant No. cstc2018jcyj A1597the Graduate Scientific Research and Innovation Foundation of Chongqing,China under Grant No. CYS18026。
文摘Shake table testing was performed to investigate the dynamic stability of a mid-dip bedding rock slope under frequent earthquakes. Then, numerical modelling was established to further study the slope dynamic stability under purely microseisms and the influence of five factors, including seismic amplitude, slope height, slope angle, strata inclination and strata thickness, were considered. The experimental results show that the natural frequency of the slope decreases and damping ratio increases as the earthquake loading times increase. The dynamic strength reduction method is adopted for the stability evaluation of the bedding rock slope in numerical simulation, and the slope stability decreases with the increase of seismic amplitude, increase of slope height, reduction of strata thickness and increase of slope angle. The failure mode of a mid-dip bedding rock slope in the shaking table test is integral slipping along the bedding surface with dipping tensile cracks at the slope rear edge going through the bedding surfaces. In the numerical simulation, the long-term stability of a mid-dip bedding slope is worst under frequent microseisms and the slope is at risk of integral sliding instability, whereas the slope rock mass is more broken than shown in the shaking table test. The research results are of practical significance to better understand the formation mechanism of reservoir landslides and prevent future landslide disasters.
基金financially supported by the National Natural Science Foundation of China (Nos. 51409011 and 51309029)the Basic Scientific Research Operating Expenses of Central-Level Public Academies and Institutes (Nos. CKSF2014057/YT and CKSF2015051/YT)
文摘Ever since the impoundment of Three Gorges Reservoir（TGR）, the seismicity in head region of TGR has increased significantly. Coupled with wide fluctuation of water level each year, it becomes more important to study the deformation forecasting of landslides beside TGR. As a famous active landslide beside TGR, Huangtupo riverside landslide is selected for a case study. Based on long term water level fluctuation and seismic monitoring, three typical adverse conditions are determined. With the established 3D numerical landslide model, seepage-dynamic coupling calculation is conducted under the seismic intensity of V degree. Results are as follows： 1. the dynamic water pressure formed by water level fluctuation will intensify the deformation of landslide; 2. under seismic load, the dynamic hysteresis is significant in defective geological bodies, such as weak layer and slip zone soil, because of much higher damping ratios, the seismic accelerate would be amplified in these elements; 3. microseisms are not intense enough to cause the landslide instability suddenly, but long term deformation accumulation effect of landslide should be paid more attention; 4. in numerical simulation, the factors of unbalance force and excess pore pressure also can be used in forecasting deformation tendency of landslide.
基金financially supported by the Project of Introducing Talents of Discipline to Universities (‘‘111’’ Project) (No. B08040)
文摘The isothermal compression testing of Ti555211 titanium alloys was carried out at deformation temperatures from 750 to 950 ℃ in 50 ℃ intervals,with strain rate of 0.001-1.000 s-1and height reduction of 20%-60%.The effect of processing parameters（deformation temperature,strain rate and deformation degree） on the microstructure evolution and the microstructure variables was investigated.The results show that the content of primary α phase decreases with the increase in deformation temperature.The effect of strain rate on microstructure variables of isothermally compressed Ti555211 alloy is mainly dependent on the deformation temperature.The fine second α phase partly transforms to β phase due to the deformation heat effect at the high strain rate,α phase becomes globular with temperature increasing and strain rate decreasing.In contrast,α phase is refined with temperature decreasing and strain rate increasing.The deformation degree has a little influence on the grain size and the morphology of primary α phase,but the effect of deformation degree on the morphology of second α phase is significant.The larger deformation degree is in favor of the globularization of lamellar α structure.
文摘Evaluating the seismic site effect by the ambient noise based horizontal-to-vertical spectral ratio(HVSR)method is strongly affected by the spatial and temporal variations of the ambient noise sources.Therefore,it is necessary to locate the source regions of ambient noise and investigate the relationships between the source energy and HVSR values at the predominant frequency(HVSRf_(0))of the site.The generation mechanisms of the single-and double-frequency microseisms(SFMs,0.05-0.085 Hz and DFMs,0.1-0.5 Hz)in ambient noise are better understood than the noise in other frequency bands and they are dominantly composed of fundamental Rayleigh(Rg)waves.With this advantage,the recordings of SFMs and DFMs at 30 stations in the east coast region of the United States are used to demonstrate a study on locating their source regions with reasonable certainty and constructing the functional relationship between the HVSRf_(0) and the source energy of SFMs and DFMs.The recordings are processed in four sub-frequency bands(Fs)of SF and DF bands and a polarization analysis is carried out to select the ellipsoids approximating the particle motions of Rg waves.Then the probability density functions of the back azimuths of the ellipsoids’semi-major axes are computed for each F and station,and are projected on the ocean to determine their possible source regions.These regions are further constrained by(1)the correlation coefficients between the SFMs and the WAVEWATCHⅢ(WWⅢ)hindcasts of ocean wave spectra in the SF band,or between the DFMs and the modeled DF energy on ocean surface in the selected time windows in the DF band,(2)the energy contribution defined by(i)the average WWⅢocean wave energy and the ocean bottom topographical gradient in the SF band,or(ii)the average modeled DF energy on ocean surface and a frequency and water depth dependent coefficient measuring the conversion efficiency of DF energy from water to solid earth in the DF band,and(3)the percentile retained energy of Rg waves in both the SF and DF bands.Results of source regions reveal that(1)the SFMs recorded in eastern US result from the interactions of low frequency(0.05-0.085 Hz)ocean waves with the continental slope and shelf of western North Atlantic Ocean;(2)the source regions for long-(0.1-0.2 Hz)period DFMs are located in the deep ocean close to the continental slope;and(3)the short-(0.2–0.5 Hz)period DFMs are generated in the continental shelf.Finally,the correlation analyses between the simulated source energy and the HVSRf_(0) values at the stations whose f_(0) s fall in DF band are carried out revealing significant source effect on thick sediments at low frequencies.
