The hybrid CO_(2) thermal technique has achieved considerable success globally in extracting residual heavy oil from reserves following a long-term steam stimulation process.Using microscopic visualization experiments...The hybrid CO_(2) thermal technique has achieved considerable success globally in extracting residual heavy oil from reserves following a long-term steam stimulation process.Using microscopic visualization experiments and molecular dynamics(MD)simulations,this study investigates the microscopic enhanced oil recovery(EOR)mechanisms underlying residual oil removal using hybrid CO_(2) thermal systems.Based on the experimental models for the occurrence of heavy oil,this study evaluates the performance of hybrid CO_(2) thermal systems under various conditions using MD simulations.The results demonstrate that introducing CO_(2) molecules into heavy oil can effectively penetrate and decompose dense aggregates that are originally formed on hydrophobic surfaces.A stable miscible hybrid CO_(2) thermal system,with a high effective distribution ratio of CO_(2),proficiently reduces the interaction energies between heavy oil and rock surfaces,as well as within heavy oil.A visualization analysis of the interactions reveals that strong van der Waals(vdW)attractions occur between CO_(2) and heavy oil molecules,effectively promoting the decomposition and swelling of heavy oil.This unlocks the residual oil on the hydrophobic surfaces.Considering the impacts of temperature and CO_(2) concentration,an optimal gas-to-steam injection ratio(here,the CO_(2):steam ratio)ranging between 1:6 and 1:9 is recommended.This study examines the microscopic mechanisms underlying the hybrid CO_(2) thermal technique at a molecular scale,providing a significant theoretical guide for its expanded application in EOR.展开更多
During the displacement of water plugging with binary flooding in internally heterogeneous reservoirs,it is essential to understand the distributions of remaining oil as well as the oil displacement mechanisms at diff...During the displacement of water plugging with binary flooding in internally heterogeneous reservoirs,it is essential to understand the distributions of remaining oil as well as the oil displacement mechanisms at different stages.In this study,two types of internally heterogeneous systems,i.e.,vertical and horizontal wells are investigated experimentally through a microscopic approach.The results show that plugging agent types have a greater impact on oil recovery than well types,and foam injection can enhance oil recovery more effectively than gel injection.Additionally,the injection sequence of plugging agents significantly affects oil displacement efficiency.Injecting gel after foam is more beneficial.According to the present results,the main formation mechanisms of remaining oil in each displacement stage are influenced by:capillary force,viscous force,inertial force,shear force,microscopic fingering&channeling.展开更多
基金financially supported by the National Natural Science Foundation of China(No.U20B6003)the China Scholarship Council(No.202306440015)a project of the China Petroleum&Chemical Corporation(No.P22174)。
文摘The hybrid CO_(2) thermal technique has achieved considerable success globally in extracting residual heavy oil from reserves following a long-term steam stimulation process.Using microscopic visualization experiments and molecular dynamics(MD)simulations,this study investigates the microscopic enhanced oil recovery(EOR)mechanisms underlying residual oil removal using hybrid CO_(2) thermal systems.Based on the experimental models for the occurrence of heavy oil,this study evaluates the performance of hybrid CO_(2) thermal systems under various conditions using MD simulations.The results demonstrate that introducing CO_(2) molecules into heavy oil can effectively penetrate and decompose dense aggregates that are originally formed on hydrophobic surfaces.A stable miscible hybrid CO_(2) thermal system,with a high effective distribution ratio of CO_(2),proficiently reduces the interaction energies between heavy oil and rock surfaces,as well as within heavy oil.A visualization analysis of the interactions reveals that strong van der Waals(vdW)attractions occur between CO_(2) and heavy oil molecules,effectively promoting the decomposition and swelling of heavy oil.This unlocks the residual oil on the hydrophobic surfaces.Considering the impacts of temperature and CO_(2) concentration,an optimal gas-to-steam injection ratio(here,the CO_(2):steam ratio)ranging between 1:6 and 1:9 is recommended.This study examines the microscopic mechanisms underlying the hybrid CO_(2) thermal technique at a molecular scale,providing a significant theoretical guide for its expanded application in EOR.
文摘During the displacement of water plugging with binary flooding in internally heterogeneous reservoirs,it is essential to understand the distributions of remaining oil as well as the oil displacement mechanisms at different stages.In this study,two types of internally heterogeneous systems,i.e.,vertical and horizontal wells are investigated experimentally through a microscopic approach.The results show that plugging agent types have a greater impact on oil recovery than well types,and foam injection can enhance oil recovery more effectively than gel injection.Additionally,the injection sequence of plugging agents significantly affects oil displacement efficiency.Injecting gel after foam is more beneficial.According to the present results,the main formation mechanisms of remaining oil in each displacement stage are influenced by:capillary force,viscous force,inertial force,shear force,microscopic fingering&channeling.
