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Occurrence of beryllium and its microscale interactions with coexisting phases in beryllium-containing sludge
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作者 Xiaobo Min Lin Yu +6 位作者 Yong Ke Yunyan Wang Wenming Zeng Hui Xu Yun Li Cong Peng Zhumei Sun 《Journal of Environmental Sciences》 2026年第1期383-390,共8页
Beryllium-containing sludge(BCS)is a typical hazardous waste from Be smelting,which can cause serious harm to ecology and human health by releasing harmful Be if it is stored long-term in environment.Nonetheless,the o... Beryllium-containing sludge(BCS)is a typical hazardous waste from Be smelting,which can cause serious harm to ecology and human health by releasing harmful Be if it is stored long-term in environment.Nonetheless,the occurrence of Be in BCS is unclear,which seriously hinders the development of pollution control technologies.In order to enhance the understanding of BCS,the occurrence of Be and the microscale interactions with coexisting phases were investigated for the first time.It was found that CaSO_(4)·2H_(2)O and amorphous SiO_(2) are the primary phases of BCS.The simulated experiments of purified materials showed that Be interacted with CaSO_(4)·2H_(2)O and amorphous SiO_(2).Be can enter into the lattice of CaSO_(4)·2H_(2)O mainly as free Be2+.Amorphous SiO_(2) can adsorb Be2+particularly at a pH range of 3–5.The dissolution behavior experiment of BCS shows that about 52%of the Be is readily extracted under acidic conditions,which refers to the Be of independent occurrence.In contrast,the remaining 48%of Be can be extracted only after the CaSO_(4)·2H_(2)O has completely dissolved.Hence,CaSO_(4)·2H_(2)O is identified as the key occurrence phase which determines the highly efficient dissolution of Be.As a result,this study enhances the understanding of BCS and lays the foundation for the development of Be separation technologies. 展开更多
关键词 Beryllium-containing sludge(BCS) Occurrence phase CaSO_(4)·2H_(2)O Amorphous SiO_(2) microscale interactions
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VIBRATION ANALYSIS OF MICROSCALE PLATES BASED ON MODIFIED COUPLE STRESS THEORY 被引量:9
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作者 Li Yin 《Acta Mechanica Solida Sinica》 SCIE EI 2010年第5期386-393,共8页
A non-classical Kirchhoff plate model is developed for the dynamic analysis of microscale plates based on the modified couple stress theory in which an internal material length scale parameter is included. Unlike the ... A non-classical Kirchhoff plate model is developed for the dynamic analysis of microscale plates based on the modified couple stress theory in which an internal material length scale parameter is included. Unlike the classical Kirchhoff plate model, the newly developed model can capture the size effect of microscale plates. Two boundary value problems of rectangular micro- plates are solved and the size effect on the lowest two natural frequencies is investigated. It is shown that the natural frequencies of the microscale plates predicted by the current model are size-dependent when the plate thickness is comparable to the material length scale parameter. 展开更多
关键词 microscale plate VIBRATION natural frequency modified couple stress theory size effect
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Non-contact tensile viscoelastic characterization of microscale biological materials 被引量:4
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作者 Yuhui Li Yuan Hong +7 位作者 Guang-Kui Xu Shaobao Liu Qiang Shi Deding Tang Hui Yang Guy M.Genin Tian Jian Lu Feng Xu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2018年第3期589-599,共11页
Many structures and materials in nature and physiology have important "meso-scale" structures at the micron lengthscale whose tensile responses have proven difficult to characterize mechanically. Although techniques... Many structures and materials in nature and physiology have important "meso-scale" structures at the micron lengthscale whose tensile responses have proven difficult to characterize mechanically. Although techniques such as atomic force microscopy and micro- and nano-identation are mature for compression and indentation testing at the nano-scale, and standard uniaxial and shear rheometry techniques exist for the macroscale, few techniques are applicable for tensile-testing at the micrometre-scale, leaving a gap in our understanding of hierarchical biomaterials. Here, we present a novel magnetic mechanical testing (MMT) system that enables viscoelastic tensile testing at this critical length scale. The MMT system applies non-contact loading, avoiding gripping and surface interaction effects. We demonstrate application of the MMT system to the first analyses of the pure tensile responses of several native and engineered tissue systems at the mesoscale, showing the broad potential of the system for exploring micro- and meso-scale analysis of structured and hierarchical biological systems. 展开更多
关键词 Mechanical testing Hierarchical biomaterials Non-contact actuation microscale analysis
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Microscale Chemical Features of Sediment-Water Interface in Hongfeng Lake 被引量:2
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作者 Jingfu Wang Jing'an Chen +3 位作者 Zhihui Dai Jian Li Yang Xu Jing Luo 《Journal of Earth Science》 SCIE CAS CSCD 2016年第6期1038-1044,共7页
In situ microscale distributions of 02, H2S, pH and redox potential in sediments of Hongfeng Lake, SW China, were investigated using the powerful microsensor technique. Our results show that O2 was depleted within the... In situ microscale distributions of 02, H2S, pH and redox potential in sediments of Hongfeng Lake, SW China, were investigated using the powerful microsensor technique. Our results show that O2 was depleted within the top 3.9 mm in surface sediments, and H2S was subsequently detected at -6.0 mm depth, and reached its maximum concentrations at -25 mm. The degradation of organic matter and reduction of sulfate might be the major pathways of producing H2S in sediments, pH rapidly reduced in surface layers mainly due to H+ release in the oxidation of organic matter. Eh also decreased sharply in surface sediments, probabl indicating the coexistence of Fe and Mn oxides with O2 in aerobic region. Furthermore, the programme of PROFILE was applied to model the 02 gradient, and good fit was obtained between the simulative values and the factual values both in sediments and in the diffusive boundary layer (DBL). The results indicate that the depth-integrated O2 consumption rates within sediments were 0.083 and 0.134 nmol·m-3·s-1 in site S1 and site S2, respectively. In addition, there were distinct DBL in two sediment profiles, with 1.2 mm thickness in S1 and 0.9 mm thickness in S2. The diffusive fluxes of O2 within the DBL were 67.13 nmol·m-2·s-1 in S1 and 88.54 nmol·m-2·s-1 in S2. 展开更多
关键词 microscale chemical feature DBL SEDIMENT Hongfeng Lake.
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Functionalized alginate-based bioinks for microscale electrohydrodynamic bioprinting of living tissue constructs with improved cellular spreading and alignment 被引量:6
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作者 Zhennan Qiu Hui Zhu +3 位作者 Yutao Wang Ayiguli Kasimu Dichen Li Jiankang He 《Bio-Design and Manufacturing》 SCIE EI CAS CSCD 2023年第2期136-149,共14页
Bioprinting has been widely investigated for tissue engineering and regenerative medicine applications.However,it is still difficult to reconstruct the complex native cell arrangement due to the limited printing resol... Bioprinting has been widely investigated for tissue engineering and regenerative medicine applications.However,it is still difficult to reconstruct the complex native cell arrangement due to the limited printing resolution of conventional bioprinting techniques such as extrusion-and inkjet-based printing.Recently,an electrohydrodynamic(EHD)bioprinting strategy was reported for the precise deposition of well-organized cell-laden constructs with microscale filament size,whereas few studies have been devoted to developing bioinks that can be applied for EHD bioprinting and simultaneously support cell spreading.This study describes functionalized alginate-based bioinks for microscale EHD bioprinting using peptide grafting and fibrin incorporation,which leads to high cell viability(>90%)and cell spreading.The printed filaments can be further refined to as small as 30μm by incorporating polyoxyethylene and remained stable over one week when exposed to an aqueous environment.By utilizing the presented alginate-based bioinks,layer-specific cell alignment along the printing struts could be observed inside the EHD-printed microscale filaments,which allows fabricating living constructs with cell-scale filament resolution for guided cellular orientation. 展开更多
关键词 microscale electrohydrodynamic bioprinting Alginate-based bioinks Cell spreading Cell alignment
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Photochemical effect driven fluid behavior control in microscale pores and channels 被引量:2
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作者 Shuli Wang Ruimin Zhou +2 位作者 Yaqi Hou Miao Wang Xu Hou 《Chinese Chemical Letters》 SCIE CAS CSCD 2022年第8期3650-3656,共7页
Manipulating the fluid transport in the microscale pores and channels is playing a paramount role in the realization of the versatile functions of microfluidics.In recent years,using light to control the fluid behavio... Manipulating the fluid transport in the microscale pores and channels is playing a paramount role in the realization of the versatile functions of microfluidics.In recent years,using light to control the fluid behavior in the microchannels/pores has attracted many researchers'attention due to the advantages of light such as non-contact stimulation,tunable excitation,high spatial and temporal resolution.With efforts,great achievements and progresses have been achieved for photochemical effect driven microscale flow control,including fluid pumping,flow rate control,and fluid mixing,etc.In this review,we discuss the responsive mechanisms of photochemical effect driven fluid behavior control at the microscale.We also give a comprehensive review on the latest research progresses in photochemical effect controlled microfluid behaviors.Besides,prospective opportunities for the future development of light control of microscale flow are provided to attract scientific interest for the fast development and applications of various microchannel/pore systems. 展开更多
关键词 Photochemical effect Fluid behavior microscale pore MICROCHANNEL MICROFLUIDICS
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Investigation of normal,lateral,and oblique impact of microscale projectiles into unidirectional glass/epoxy composites 被引量:1
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作者 Christopher S.Meyer Isabel G.Catugas +1 位作者 John W.Gillespie Jr. Bazle Z.Gama Haque 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2022年第11期1960-1978,共19页
Spacesuits and spacecraft must endure high velocity impacts from micrometeoroids. This work considers the impact of 100 μm diameter projectiles into composite targets at velocities from 0.5 km/s to 2 km/s.This work b... Spacesuits and spacecraft must endure high velocity impacts from micrometeoroids. This work considers the impact of 100 μm diameter projectiles into composite targets at velocities from 0.5 km/s to 2 km/s.This work begins by presenting an energy-based theoretical model relating depth of penetration(Do P)and impact force to impact velocity, characteristic time, and threshold velocity and force. Next, this work compares numerical simulations of normal impact on composites to the theoretical model. Numerical simulations are conducted with LS-DYNA and the well-known composite model, MAT-162. The numerical models consider unidirectional S2-glass fiber reinforced SC-15 epoxy composite laminates. The numerical model shows good correlation with the theoretical model. The numerical model also investigates lateral impact, parallel to the fiber direction, and oblique impact at angles from 30°to 82.5°.This work decomposes oblique impact into normal and lateral components, and compares them with normal and lateral impact results. The results show good correlation of the normal component of oblique results with the theoretical model. This numerical and theoretical study focuses on Do P, velocity, and penetration resistance force as functions of time. The theoretical model and numerical simulations are used to determine new Do P parameters: characteristic time of depth of penetration and threshold impact velocity. These models are a first step in developing the capability to predict Do P for oblique,microscale, high-speed impact on composite materials. 展开更多
关键词 microscale Hypervelocity impact Composites EROSION PENETRATION
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APPLICATIONS AND MANUFACTURE OF THE MICROSCALE LONG-OPTICAL-PATH ELECTROCHEMICAL CELL WITH A PLUG-IN THIN-LAYER ELECTRODE 被引量:2
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作者 Zhang Yu YU Mao Chun JING Shen Hua MIAO Department of Chemistry,Qufu Normal University,Qufu Shandong,273165 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第8期725-728,共4页
The construction and characteristics of a microscale long-optical-path electrochemi- cal cell with a plug-in thin-layer electrode are described.Using ferricyanide as the test species,the thermodynamic parameters of el... The construction and characteristics of a microscale long-optical-path electrochemi- cal cell with a plug-in thin-layer electrode are described.Using ferricyanide as the test species,the thermodynamic parameters of electron transfer processes are determined at car- bon,plantinum,and gold electrodes. 展开更多
关键词 APPLICATIONS AND MANUFACTURE OF THE microscale LONG-OPTICAL-PATH ELECTROCHEMICAL CELL WITH A PLUG-IN THIN-LAYER ELECTRODE SCE PLUG
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Predicting the probability distribution of Martian rocks mechanical property based on microscale rock mechanical experiments and accurate grain-based modeling 被引量:1
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作者 Shuohui Yin Yingjie Wang Jingang Liu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1327-1339,共13页
The exploration of Mars would heavily rely on Martian rocks mechanics and engineering technology.As the mechanical property of Martian rocks is uncertain,it is of utmost importance to predict the probability distribut... The exploration of Mars would heavily rely on Martian rocks mechanics and engineering technology.As the mechanical property of Martian rocks is uncertain,it is of utmost importance to predict the probability distribution of Martian rocks mechanical property for the success of Mars exploration.In this paper,a fast and accurate probability distribution method for predicting the macroscale elastic modulus of Martian rocks was proposed by integrating the microscale rock mechanical experiments(micro-RME),accurate grain-based modeling(AGBM)and upscaling methods based on reliability principles.Firstly,the microstructure of NWA12564 Martian sample and elastic modulus of each mineral were obtained by micro-RME with TESCAN integrated mineral analyzer(TIMA)and nanoindentation.The best probability distribution function of the minerals was determined by Kolmogorov-Smirnov(K-S)test.Secondly,based on best distribution function of each mineral,the Monte Carlo simulations(MCS)and upscaling methods were implemented to obtain the probability distribution of upscaled elastic modulus.Thirdly,the correlation between the upscaled elastic modulus and macroscale elastic modulus obtained by AGBM was established.The accurate probability distribution of the macroscale elastic modulus was obtained by this correlation relationship.The proposed method can predict the probability distribution of Martian rocks mechanical property with any size and shape samples. 展开更多
关键词 Probability distribution Martian rocks microscale rock mechanic experiment Nanoindentation Accurate grain-based modeling
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A basic model of unconventional gas microscale flow based on the lattice Boltzmann method 被引量:2
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作者 ZHAO Yulong LIU Xiangyu +1 位作者 ZHANG Liehui SHAN Baochao 《Petroleum Exploration and Development》 CSCD 2021年第1期179-189,共11页
A new method for selecting dimensionless relaxation time in the lattice Boltzmann model was proposed based on similarity criterion and gas true physical parameters.At the same time,the dimensionless relaxation time wa... A new method for selecting dimensionless relaxation time in the lattice Boltzmann model was proposed based on similarity criterion and gas true physical parameters.At the same time,the dimensionless relaxation time was modified by considering the influence of the boundary Knudsen layer.On this basis,the second-order slip boundary condition of the wall was considered,and the key parameters in the corresponding combined bounce-back/specular-reflection boundary condition were deduced to build a new model of unconventional gas microscale flow simulation based on the lattice Boltzmann method suitable for high temperatures and high pressures.The simulation results of methane gas flow driven by body force in infinite micro-channels and flow driven by inlet-outlet pressure differential in long straight channels were compared with the numerical and analytical solutions in the literature to verify the accuracy of the model,and the dimensionless relaxation time modification was formally optimized.The results show that the new model can effectively characterize the slippage effect,compression effect,gas density and the effect of boundary Knudsen layer in the micro-scale flow of unconventional natural gas.The new model can achieve a more comprehensive characterization of the real gas flow conditions and can be used as a basic model for the simulation of unconventional gas flow on the micro-nano scale. 展开更多
关键词 lattice Boltzmann method dimensionless relaxation time microscale flow similarity criterion slippage effect compressibility effect unconventional gas
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Microscale stray grains formation in single-crystal turbine blades of Ni-based superalloys 被引量:1
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作者 Fu Wang Yang Liu +2 位作者 Qiang Yang Dexin Ma Dichen Li 《Journal of Materials Science & Technology》 CSCD 2024年第24期134-145,共12页
Microscale stray grains(MSGs),which are composed of misoriented and fragmented high-ordered dendrite arms,small-sized equiaxed grains,and columnar grains,are a novel grain defect that occurs within the shrouds of sing... Microscale stray grains(MSGs),which are composed of misoriented and fragmented high-ordered dendrite arms,small-sized equiaxed grains,and columnar grains,are a novel grain defect that occurs within the shrouds of single-crystal(SC)blades made from Ni-based superalloy.State-of-the-art non-destructive testing methods are incapable of detecting this defect,resulting in a high-risk application of SC blades.This study aims to control this defect by systematically investigating directional solidification processing parameters,shroud dimensions,and rhenium(Re)content in the formation of MSG defects.The results reveal that the defect forms exclusively at the overhanging extremities of the upper shrouds on the back side of the blades that face the heater.Increasing the withdrawal rate reduces the occurrence of MSG defects.As the shroud dimensions increase,MSG defects appear in the transition area between the downward suspended extremity of the blade shroud and the side of the blade body,as well as near the corner of the downward suspended extremity of the shroud.The occurrence of MSG defects increases with increasing shroud dimensions.Varying Re content sharply decreases the formation of MSG defects.A concentration-attached Rayleigh-Taylor instability(RTI)superheating(CARTISH)model,considering solidification shrinkage,was proposed to comprehend the formation of MSG defects.Simulation results based on this model are consistent with the experimentally observed distribution and degree of MSG defects under different conditions.Effective control of the CARTISH is critical to managing MSG defects. 展开更多
关键词 Ni-based superalloy Single-crystal blade microscale stray grains MECHANISM Numerical simulation
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Microscale Infrared Observation of Liquid-Vapor Phase Change Process on the Surface of Porous Media for Loop Heat Pipe
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作者 Kimihide Odagiri Masahito Nishikawara Hosei Nagano 《Journal of Electronics Cooling and Thermal Control》 2016年第2期33-41,共9页
Loop Heat Pipe (LHP) performance strongly depends on the performance of a wick that is porous media inserted in an evaporator. In this paper, the visualization results of thermo-fluid behavior on the surface of the wi... Loop Heat Pipe (LHP) performance strongly depends on the performance of a wick that is porous media inserted in an evaporator. In this paper, the visualization results of thermo-fluid behavior on the surface of the wick with microscopic infrared thermography were reported. In this study, 2 different samples that simulated a part of wick in the evaporator were used. The wicks were made by different two materials: polytetrafluoroethylene (PTFE) and stainless steel (SUS). The pore radii of PTFE wick and SUS wick are 1.2 μm and 22.5 μm. The difference of thermo-fluid behavior that was caused by the difference of material was investigated. These two materials include 4 different properties: pore radius, thermal conductivity, permeability and porosity. In order to investigate the effect of the thermal conductivity on wick’s operating mode, the phase diagram on the q-k<sub>eff</sub> plane was made. Based on the temperature line profiles, two operating modes: mode of heat conduction and mode of convection were observed. The effective thermal conductivity of the porous media has strong effect on the operating modes. In addition, the difference of heat leak through the wick that was caused by the difference of the material was discussed. 展开更多
关键词 Evaporator Liquid-Vapor Phase Change Loop Heat Pipe microscale Infrared Observation Porous Media
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Developing From Tranditional Microscale Chemistry to Microscale Green Chemistry
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作者 Wing-Hong Chan Albert W. M. Lee 《内蒙古民族大学学报》 2009年第4期9-10,共2页
  Microscale chemistry is appealing to all levels of education.In contrast to conventional macroscale chemistry,only minute amount of chemicals are required to undertaking a chemical investigation.……
关键词 In Developing From Tranditional microscale Chemistry to microscale Green Chemistry
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Experiment on microscale flames stabilized on surface of annular porous media
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作者 LIN Peihua LIN Yuzhen +2 位作者 XUE Xin ZHANG Liang ZHANG Chi 《航空动力学报》 EI CAS CSCD 北大核心 2017年第12期2955-2963,共9页
The characteristics of the surface-stabilized flame on a porous medium in an annular microscale channel were studied experimentally with methane/air mixture.In the pressure drop characteristic study,three porous media... The characteristics of the surface-stabilized flame on a porous medium in an annular microscale channel were studied experimentally with methane/air mixture.In the pressure drop characteristic study,three porous media with the same pore diameter and different porosities were used and compared.The substitution of the air for the mixture was verified accurately at first.Then the relationship expression of the air pressure drop characteristic was acquired for each porous medium according to the Forcheimer correlation.The third porous medium was selected for the following research,as it had the expression closer to the Darcy's law.As for the ignition characteristic study of the surface-stabilized flame,a reasonable criterion was established for the flammability limit determination.Based on the criterion,the result showed that the limit reached the minimum value when the mixture equivalence ratio was 0.9.During the extinction characteristic study,through the well-designed operating procedure,the experiment was conducted to obtain the strict extinction limit of the surfacestabilized flame.It was indicated that the extinction limit at mixture equivalence ratio of 0.8 was the least. 展开更多
关键词 高旋转数 通道转角 梯形 回转通道 换热特性
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Microscale Chemistry in Japan
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作者 OGINO Kazuko 《内蒙古民族大学学报》 2009年第4期16-,共1页
  Microscale laboratory is environmentally benign as the amount of reagents,waste,energy and cost can be reduced dramatically,and exposure to potentially toxic chemicals is diminished.……
关键词 microscale Chemistry in Japan
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微反应器内传质和反应过程强化的研究进展
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作者 齐亚兵 赵亚娟 +1 位作者 穆乃外尔·吐尔逊 张思敬 《高校化学工程学报》 北大核心 2026年第1期10-24,共15页
微反应器因具有体积小、传热传质性能好、安全性高、易于控制等优点,在化工、制药、环境、材料、冶金、能源、医疗诊断等领域得到了广泛应用。强化微反应器内传质和反应过程一直是全球研究者关注的焦点。文中系统地总结了微反应器的结... 微反应器因具有体积小、传热传质性能好、安全性高、易于控制等优点,在化工、制药、环境、材料、冶金、能源、医疗诊断等领域得到了广泛应用。强化微反应器内传质和反应过程一直是全球研究者关注的焦点。文中系统地总结了微反应器的结构、超声场强化、离心场强化、磁场强化、光强化、搅拌强化等措施,深入地分析了微反应器内传质和反应过程强化产生的原因,展望了微反应器内传质和反应过程强化发展的方向。为了强化微反应器内的传质和反应过程,需从以下方面做起:(1)深入地研究微反应器内液滴、液柱、液流、气泡、气柱、气流的形成机制以及微反应器内流体流型的影响因素和转变机理;(2)将不同强化措施耦合使用,以达到满意的强化效果,例如:螺旋微通道与超声场的耦合、螺旋微通道与光催化的耦合、气体搅拌与旋转微通道的耦合等;(3)通过数值模拟、实验研究以及中试放大不断优化提高微反应器的性能,将微反应器逐渐应用于工业生产。 展开更多
关键词 微反应器 微通道 微尺度 传质 过程强化
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合成双射流结合不同金属-水的微米流体的强化换热研究
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作者 于新莹 康赢 +3 位作者 罗振兵 邓雄 程盼 王杨肖 《国防科技大学学报》 北大核心 2026年第1期69-77,共9页
为提高临近空间飞行器电子设备系统散热能力,解决集成化、微型化电子设备芯片高热流密度的问题,针对合成双射流激励器、微米颗粒两相流及二者的结合开展换热性能的研究。对合成双射流激励器增强换热能力机理进行分析,并对合成双射流激... 为提高临近空间飞行器电子设备系统散热能力,解决集成化、微型化电子设备芯片高热流密度的问题,针对合成双射流激励器、微米颗粒两相流及二者的结合开展换热性能的研究。对合成双射流激励器增强换热能力机理进行分析,并对合成双射流激励器与铜-水微米流体管内流动过程进行建模,运用单欧拉模型模拟分析五种颗粒体积分数对流体强化换热能力的影响,还对铜-水、氧化铜-水、氧化铝-水微米流体进行了数值模拟。结果显示:合成双射流激励器能增强流体换热能力,换热能力随微米颗粒体积分数的增加而提高;不同金属颗粒种类的两相流换热能力不同,随金属颗粒导热性能变化。当微米颗粒流体为颗粒体积分数为8%的铜颗粒时,开启合成双射流激励器后芯片温度由328.225 K降低至303.816 K。 展开更多
关键词 合成双射流 微米流体 两相流 强化换热 数值模拟
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WRF-CFD模式耦合的山地风电场非定常仿真方法与验证
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作者 马国林 宋翌蕾 +1 位作者 田琳琳 赵宁 《中国电机工程学报》 北大核心 2026年第2期679-690,I0019,共13页
复杂地形风电场流动具有强烈的非定常现象和多尺度特征,其准确模拟是风资源精细化评估的难点。为兼顾宏观中尺度大气环流和微观非定常流动细节,该文结合中尺度气象研究与预报(weather research and forecasting,WRF)模式和微尺度计算流... 复杂地形风电场流动具有强烈的非定常现象和多尺度特征,其准确模拟是风资源精细化评估的难点。为兼顾宏观中尺度大气环流和微观非定常流动细节,该文结合中尺度气象研究与预报(weather research and forecasting,WRF)模式和微尺度计算流体动力学(computational fluid dynamics,CFD)技术,构建一套WRF-CFD模式耦合的复杂地形风电场非定常仿真方法。以国际经典案例Askervein山和Bolund岛为验证对象,研究复杂地形流场中平均风速和湍流强度的分布特征,并简要分析复杂地形中风力机布置策略。结果表明,基于WRF-CFD模式的数值模拟结果与实验观测值有较好的一致性,且优于中尺度数值模拟结果,在选取的特征点位置,风速绝对误差均在2 m/s以内。结果可为风力机的设计、布局、载荷评估及风电场运行控制提供一定参考。 展开更多
关键词 风资源评估 风电场 复杂地形 中微尺度耦合 气象研究与预报模式 计算流体动力学
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含甲基膦酸二甲酯的细水雾对氢-空气爆炸的影响机制
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作者 夏远辰 张彬 +4 位作者 王博乔 叶刻 朱文斌 张斯琦 张金男 《爆炸与冲击》 北大核心 2026年第2期44-55,共12页
为有效控制受限空间氢-空气爆炸强度,并揭示含甲基膦酸二甲酯(dimethyl methylphosphonate, O=P(CH_(3))(OCH_(3))_(2))的微米级水雾的抑爆机理,通过定容燃烧弹试验平台及Chemkin-Pro程序,开展了试验研究和化学动力学分析。结果表明:含O... 为有效控制受限空间氢-空气爆炸强度,并揭示含甲基膦酸二甲酯(dimethyl methylphosphonate, O=P(CH_(3))(OCH_(3))_(2))的微米级水雾的抑爆机理,通过定容燃烧弹试验平台及Chemkin-Pro程序,开展了试验研究和化学动力学分析。结果表明:含O=P(CH_(3))(OCH_(3))_(2)的细水雾可导致火焰锋面细胞状结构增多,促使火焰失稳传播;当氢-空气混合的当量比Φ=0.8, 1.0和1.5时,含O=P(CH_(3))(OCH_(3))_(2)的细水雾有效衰减了平均火焰传播速度(衰减率为24.2%~47.2%)并阻止了郁金香火焰形成,取而代之的是波纹状火焰。含O=P(CH_(3))(OCH_(3))_(2)的细水雾通过降低层流燃烧速度降低升压速率,另一方面增强火焰的失稳特性提高升压速率,最终抑制效果(衰减率为41.0%~65.8%)取决于上述2种作用的耦合效应。含O=P(CH_(3))(OCH_(3))_(2)的细水雾通过降低H·、O·和OH·的浓度实现爆炸的有效抑制,其中H·、O·和OH·的浓度衰减80%以上。细水雾基于火焰前沿冷却效应和物理稀释效应实现爆炸抑制,O=P(CH_(3))(OCH_(3))_(2)基于分解后产生的HOPO·、HOPO_(2)·、HPO_(2)·、PO(OH)_(2)·和PO(H)(OH)·,捕捉H·和OH·,生成H_(2)和H_(2)O等稳定化合物,从而中断氢-空气爆炸过程中的链式反应。 展开更多
关键词 甲基膦酸二甲酯 微米级细水雾 氢-空气爆炸 气液两相耦合抑制 抑爆机理
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Cu-MOF/微米铝粉复合材料的制备与性能表征
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作者 张雨奇 付小龙 +1 位作者 陈锟 李雅津 《火炸药学报》 北大核心 2026年第2期162-171,I0002,共11页
为了解决传统铝热剂中微米铝粉反应速率低、能量释放率低、点火温度高等缺陷,采用液态金属晶界渗透破坏铝表面钝化层的方法,同时在其基础上原位合成具有高比表面积的Cu-MOF作为新型氧化剂,制备了传热传质效率提高的Cu-MOF/微米铝粉复合... 为了解决传统铝热剂中微米铝粉反应速率低、能量释放率低、点火温度高等缺陷,采用液态金属晶界渗透破坏铝表面钝化层的方法,同时在其基础上原位合成具有高比表面积的Cu-MOF作为新型氧化剂,制备了传热传质效率提高的Cu-MOF/微米铝粉复合材料;利用SEM、XRD、FTIR、XPS对Cu-MOF/微米铝粉复合材料的形貌、结构进行表征;利用热分析技术对复合材料的热反应性能进行研究。结果表明,液态金属改性铝(LM-Al)表面出现了裂纹,随着液态金属含量升高,裂纹数量变多,深度加大,当液态金属质量分数为3%时,热反应性能最好,其放热起始温度、放热峰值温度、放热终止温度分别降至883.9、936.1、985.2℃,氧化质量增加可达27.0%;Cu-MOF呈现规则的八面体形状,延长合成时间可有效提升其在Al表面的负载量和复合材料的热性能,与Al@Cu-MOF_(1)(11.15%和10.83%)和LM-Al_(3)@Cu-MOF_(1)(2.71%和15.28%)的Cu-MOF负载量和氧化质量增加相比,Al@Cu-MOF_(2)(16.01%和14.82%)和LM-Al_(3)@Cu-MOF_(2)(11.86%和56.31%)均有明显提高;液态金属改性和原位合成Cu-MOF都可以提升Al的热反应性能,且这两种处理具有协同性,其中LM-Al_(3)@Cu-MOF_(2)的性能提升最为显著,放热起始温度比Al降低了50.05℃,高温阶段氧化质量增加升高了49.21%。 展开更多
关键词 物理化学 微米铝粉 液态金属 金属有机框架 MOF 复合材料
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