In this article the affiliation of Jin-Ke Shen,Nai-Teng Wu,Li-Yuan Wang,Gang Jiang,Jin Li,Gui-Long Liu,Xian-Ming Liu were incorrectly given as:State Key Laboratory of Chemistry and Utilization of Carbon Based Energy R...In this article the affiliation of Jin-Ke Shen,Nai-Teng Wu,Li-Yuan Wang,Gang Jiang,Jin Li,Gui-Long Liu,Xian-Ming Liu were incorrectly given as:State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources,School of Chemical Engineering and Technology,Xinjiang University,Urumqi 830046,China.展开更多
Tailoring a rational structure to control the huge volume variation is practical in regulating alkali-ion battery performance on the basis of the anisotropic properties of crystallized anode materials.Here,a double-se...Tailoring a rational structure to control the huge volume variation is practical in regulating alkali-ion battery performance on the basis of the anisotropic properties of crystallized anode materials.Here,a double-serrated orthorhombic antimony oxide(Sb_(2)O_(3))microbelt was prepared by a thermally induced recrystallization/sublimation process.In situ transmission electron microscopy(TEM),in situ X-ray powder diffraction(XRD),and ex situ scanning electron microscopy(SEM)measurements demonstrate that Sb_(2)O_(3)microbelts exhibit a quasi-one-dimensional expansion perpendicular to the belt(along the[100]direction)during sodiation.The unconstrained microbelt surface space can appropriately accommodate the oriented volume variation.Thus,Sb_(2)O_(3)microbelts exhibit enhanced cycling and rate performance in half-cell sodium-ion batteries samples.Via support of reduced graphene oxide(RGO),Sb_(2)O_(3)@RGOcomposites deliver good rate capability(312.3 mAh g−1 at 3 A g−1)for sodium-ion full-cell batteries and good cycling performance(473.9 mAh g−1 at 100 mA g−1 after 100 cycles)for half-cell potassium-ion batteries.In situ Raman measurements reveal that the conversion/alloying-type Sb_(2)O_(3)anode undergoes a fully reversible alloying reaction and partially reversible conversion mechanism,which explains its irreversible capacity during the first cycle.The delicate structural design and clarification of the alkali-ion storage mechanisms facilitate the development of Sb_(2)O_(3)anodes for energy storage applications.展开更多
Recently,self-powered ultraviolet photodetectors(UV PDs)based on SnO_(2)have gained increasing interest due to its feature of working continuously without the need for external power sources.Nevertheless,the productio...Recently,self-powered ultraviolet photodetectors(UV PDs)based on SnO_(2)have gained increasing interest due to its feature of working continuously without the need for external power sources.Nevertheless,the production of the majority of these existing UV PDs necessitates additional manufacturing stages or intricate processes.In this work,we present a facile,cost-effective approach for the fabrication of a self-powered UV PD based on p-Si/n-SnO_(2)junction.The self-powered device was achieved simply by integrating a p-Si substrate with a n-type SnO_(2)microbelt,which was synthesized via the chemical vapor deposition(CVD)method.The high-quality feature,coupled with the belt-like shape of the SnO_(2)microbelt enables the favorable contact between the n-type SnO_(2)and p-type silicon.The built-in electric field created at the interface endows the self-powered performance of the device.The p-Si/n-SnO_(2)junction photodetector demonstrated a high responsivity(0.12 mA/W),high light/dark current ratio(>103),and rapid response speed at zero bias.This method offers a practical way to develop cost-effective and high-performance self-powered UV PDs.展开更多
Polypyrrole （PPY） microbelts are synthesized via the absorbent cotton template for the first time. PPY microbelts are characterized by Fourier transform infrared spectroscopy.The stability, the morphology and electr...Polypyrrole （PPY） microbelts are synthesized via the absorbent cotton template for the first time. PPY microbelts are characterized by Fourier transform infrared spectroscopy.The stability, the morphology and electrical conductivity of such microbelts are evaluated by means of scanning electron microscope, thermo-gravimetric analysis and four-probe con-ductivity. A possible mechanism for the formation of PPY microbelts are proposed. The conductivity is measured, and the conductivity variation mechanism of the PPY microbelts with the pyrrole monomer concentrations is analyzed.展开更多
文摘In this article the affiliation of Jin-Ke Shen,Nai-Teng Wu,Li-Yuan Wang,Gang Jiang,Jin Li,Gui-Long Liu,Xian-Ming Liu were incorrectly given as:State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources,School of Chemical Engineering and Technology,Xinjiang University,Urumqi 830046,China.
基金This study is supported by the National Natural Science Foundation of China(nos.21701163,21671181,and 21831006)the Anhui Provincial Natural Science Foundation(no.1808085QB25).
文摘Tailoring a rational structure to control the huge volume variation is practical in regulating alkali-ion battery performance on the basis of the anisotropic properties of crystallized anode materials.Here,a double-serrated orthorhombic antimony oxide(Sb_(2)O_(3))microbelt was prepared by a thermally induced recrystallization/sublimation process.In situ transmission electron microscopy(TEM),in situ X-ray powder diffraction(XRD),and ex situ scanning electron microscopy(SEM)measurements demonstrate that Sb_(2)O_(3)microbelts exhibit a quasi-one-dimensional expansion perpendicular to the belt(along the[100]direction)during sodiation.The unconstrained microbelt surface space can appropriately accommodate the oriented volume variation.Thus,Sb_(2)O_(3)microbelts exhibit enhanced cycling and rate performance in half-cell sodium-ion batteries samples.Via support of reduced graphene oxide(RGO),Sb_(2)O_(3)@RGOcomposites deliver good rate capability(312.3 mAh g−1 at 3 A g−1)for sodium-ion full-cell batteries and good cycling performance(473.9 mAh g−1 at 100 mA g−1 after 100 cycles)for half-cell potassium-ion batteries.In situ Raman measurements reveal that the conversion/alloying-type Sb_(2)O_(3)anode undergoes a fully reversible alloying reaction and partially reversible conversion mechanism,which explains its irreversible capacity during the first cycle.The delicate structural design and clarification of the alkali-ion storage mechanisms facilitate the development of Sb_(2)O_(3)anodes for energy storage applications.
基金support for this research was provided by the High-Level Scientific Research Cultivation Project at Hubei Minzu University,with the grant identifier PY22001the Guiding Projects from the Department of Education in Hubei Province,identified by the grant number B2018088.
文摘Recently,self-powered ultraviolet photodetectors(UV PDs)based on SnO_(2)have gained increasing interest due to its feature of working continuously without the need for external power sources.Nevertheless,the production of the majority of these existing UV PDs necessitates additional manufacturing stages or intricate processes.In this work,we present a facile,cost-effective approach for the fabrication of a self-powered UV PD based on p-Si/n-SnO_(2)junction.The self-powered device was achieved simply by integrating a p-Si substrate with a n-type SnO_(2)microbelt,which was synthesized via the chemical vapor deposition(CVD)method.The high-quality feature,coupled with the belt-like shape of the SnO_(2)microbelt enables the favorable contact between the n-type SnO_(2)and p-type silicon.The built-in electric field created at the interface endows the self-powered performance of the device.The p-Si/n-SnO_(2)junction photodetector demonstrated a high responsivity(0.12 mA/W),high light/dark current ratio(>103),and rapid response speed at zero bias.This method offers a practical way to develop cost-effective and high-performance self-powered UV PDs.
基金This work was supported by the National Natural Science Foundation of China （No.20571066 and No.20871108）, the Program for the Top Scietutions of Shanxi, and the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi.nce and Technology Inovation Team of Higher Learning Insti
文摘Polypyrrole （PPY） microbelts are synthesized via the absorbent cotton template for the first time. PPY microbelts are characterized by Fourier transform infrared spectroscopy.The stability, the morphology and electrical conductivity of such microbelts are evaluated by means of scanning electron microscope, thermo-gravimetric analysis and four-probe con-ductivity. A possible mechanism for the formation of PPY microbelts are proposed. The conductivity is measured, and the conductivity variation mechanism of the PPY microbelts with the pyrrole monomer concentrations is analyzed.
