To investigate the effect of Au thickness on evolution of AuSnx IMCs, pads with 0. 1, 0. 5 and 4. 0 μm thickness of Au surface finish were utilized. Laser reflowed solder joints were aged in 125℃ isothermal ovens. R...To investigate the effect of Au thickness on evolution of AuSnx IMCs, pads with 0. 1, 0. 5 and 4. 0 μm thickness of Au surface finish were utilized. Laser reflowed solder joints were aged in 125℃ isothermal ovens. Results indicated that little IMC formed at the interface of solder and pad with 0. 1 μm thickness of Au. Even in condition of 744 hours aging, thickness of lMCs did not increase obviously. As for the joints with 0. 5 μm thickness of Au, most of AuSn4 IMCs stayed at the inteornce and were in needle-like or dendritic morphology. With the increase of aging time, AuSn4 IMCs beeame flat and changed to a continuous layer. In the joints with 4. 0 μm thickness of Au on pads, AuSn, AuSn2, AuSn4 IMCs and Au2Sn phase formed at the interface. As aging time was increased, more Sn rich IMCs formed at the interface, and evolved to AuSn4 IMCs in condition of long time aging. Thickness of AuSn4 IMCs reached about 30μm.展开更多
采用光学显微镜、电子显微镜和动态力学分析等方法研究Bi含量对直径为400μm、高度为200μm的无铅Cu/Sn-0.3Ag-0.7Cu(SAC0307)/Cu微尺度焊点的显微组织及蠕变性能的影响。结果表明:当焊点中Bi含量较低(1%(质量分数))时,其基体组织细小,C...采用光学显微镜、电子显微镜和动态力学分析等方法研究Bi含量对直径为400μm、高度为200μm的无铅Cu/Sn-0.3Ag-0.7Cu(SAC0307)/Cu微尺度焊点的显微组织及蠕变性能的影响。结果表明:当焊点中Bi含量较低(1%(质量分数))时,其基体组织细小,Cu_6Sn_5为粗大块状,Ag_3Sn分布不均匀;当焊点中Bi含量较多(3%(质量分数))时,基体组织与Cu_6Sn_5进一步细化,Ag_3Sn在细化的同时分布更均匀,界面扇贝状IMC层更平直。另外,温度为80~125℃、应力为8~15 MPa条件下,拉伸蠕变试验得到SAC0307微焊点的蠕变激活能(Q)和蠕变应力指数(n)分别为82.9 k J/mol和4.35;当钎料中Bi含量由1.0%增加到3.0%时,焊点的Q值从89.2 k J/mol增加到94.6 k J/mol,n值由4.48增加到4.73,钎焊接头的抗蠕变能力明显提高,所有焊点的蠕变变形机制主要受位错攀移控制。展开更多
基金Acknowledgement This work is finaneially supported by the National Natural Science Foundation of China （Grant No. 51005058）, National Hight- eeh R＆D Program （863 Program ） of China （Grant No. 2007AA04Z314） and Natural Scientific Research Innovation Foundation in Harbin Institute of Technology （ HIT. NSRIF. 2009037 ）.
文摘To investigate the effect of Au thickness on evolution of AuSnx IMCs, pads with 0. 1, 0. 5 and 4. 0 μm thickness of Au surface finish were utilized. Laser reflowed solder joints were aged in 125℃ isothermal ovens. Results indicated that little IMC formed at the interface of solder and pad with 0. 1 μm thickness of Au. Even in condition of 744 hours aging, thickness of lMCs did not increase obviously. As for the joints with 0. 5 μm thickness of Au, most of AuSn4 IMCs stayed at the inteornce and were in needle-like or dendritic morphology. With the increase of aging time, AuSn4 IMCs beeame flat and changed to a continuous layer. In the joints with 4. 0 μm thickness of Au on pads, AuSn, AuSn2, AuSn4 IMCs and Au2Sn phase formed at the interface. As aging time was increased, more Sn rich IMCs formed at the interface, and evolved to AuSn4 IMCs in condition of long time aging. Thickness of AuSn4 IMCs reached about 30μm.
文摘采用光学显微镜、电子显微镜和动态力学分析等方法研究Bi含量对直径为400μm、高度为200μm的无铅Cu/Sn-0.3Ag-0.7Cu(SAC0307)/Cu微尺度焊点的显微组织及蠕变性能的影响。结果表明:当焊点中Bi含量较低(1%(质量分数))时,其基体组织细小,Cu_6Sn_5为粗大块状,Ag_3Sn分布不均匀;当焊点中Bi含量较多(3%(质量分数))时,基体组织与Cu_6Sn_5进一步细化,Ag_3Sn在细化的同时分布更均匀,界面扇贝状IMC层更平直。另外,温度为80~125℃、应力为8~15 MPa条件下,拉伸蠕变试验得到SAC0307微焊点的蠕变激活能(Q)和蠕变应力指数(n)分别为82.9 k J/mol和4.35;当钎料中Bi含量由1.0%增加到3.0%时,焊点的Q值从89.2 k J/mol增加到94.6 k J/mol,n值由4.48增加到4.73,钎焊接头的抗蠕变能力明显提高,所有焊点的蠕变变形机制主要受位错攀移控制。
