To clarify the mechanism of differential enrichment of intrasource shale oil,taking the third of seventh member of the Triassic Yanchang Formation(Chang 7_(3)submember for short)in the Ordos Basin,NW China as an examp...To clarify the mechanism of differential enrichment of intrasource shale oil,taking the third of seventh member of the Triassic Yanchang Formation(Chang 7_(3)submember for short)in the Ordos Basin,NW China as an example,we integrated high-resolution scanning electron microscopy(SEM),optical microscopy,laser Raman spectroscopy,rock pyrolysis,and organic solvent extraction experiments to identify solid bitumen of varying origins,obtain direct evidence of intrasource micro-migration of shale oil,and establish the coupling between the shale nano/micro-fabric and the oil generation,migration and accumulation.The Chang 7_(3)shale with rich alginite in laminae has the highest hydrocarbon generation potential but a low thermal transformation ratio.Frequent alternations of micron-scale argillaceous-felsic laminae enhance the hydrocarbon expulsion efficiency,yielding consistent aromaticity between in-situ and migrated solid bitumen.Mudstone laminae rich in terrestrial organic matter(OM)and clay minerals exhibit lower hydrocarbon generation threshold but stronger hydrocarbon retention capacity,with a certain amount of light oil/bitumen preserved to differentiate the chemical structure of in-situ versus migrated bitumen.Tuffaceous and sandy laminae contain abundant felsic minerals and migrated bitumen.Tuffaceous laminae develop high-angle microfractures under shale overpressure,facilitating oil charging into rigid mineral intergranular pores of sandy laminae.Fractionation during micro-migration progressively decreases the aromatization of solid bitumen from shale,through tuffaceous and mudstone,to sandy laminae,while increasing light hydrocarbon components and enhancing OM-hosted pore development.The intrasource micro-migration and enrichment of the Chang 7_(3)shale oil result from synergistic organic-inorganic diagenesis,with crude oil component fractionation being a key mechanism for forming sweet spots in laminated shale oil reservoirs.展开更多
Taking the Lower Permian Fengcheng Formation shale in Mahu Sag of Junggar Basin,NW China,as an example,core observation,test analysis,geological analysis and numerical simulation were applied to identify the shale oil...Taking the Lower Permian Fengcheng Formation shale in Mahu Sag of Junggar Basin,NW China,as an example,core observation,test analysis,geological analysis and numerical simulation were applied to identify the shale oil micro-migration phenomenon.The hydrocarbon micro-migration in shale oil was quantitatively evaluated and verified by a self-created hydrocarbon expulsion potential method,and the petroleum geological significance of shale oil micro-migration evaluation was determined.Results show that significant micro-migration can be recognized between the organic-rich lamina and organic-poor lamina.The organic-rich lamina has strong hydrocarbon generation ability.The heavy components of hydrocarbon preferentially retained by kerogen swelling or adsorption,while the light components of hydrocarbon were migrated and accumulated to the interbedded felsic or carbonate organic-poor laminae as free oil.About 69% of the Fengcheng Formation shale samples in Well MY1 exhibit hydrocarbon charging phenomenon,while 31% of those exhibit hydrocarbon expulsion phenomenon.The reliability of the micro-migration evaluation results was verified by combining the group components based on the geochromatography effect,two-dimension nuclear magnetic resonance analysis,and the geochemical behavior of inorganic manganese elements in the process of hydrocarbon migration.Micro-migration is a bridge connecting the hydrocarbon accumulation elements in shale formations,which reflects the whole process of shale oil generation,expulsion and accumulation,and controls the content and composition of shale oil.The identification and evaluation of shale oil micro-migration will provide new perspectives for dynamically differential enrichment mechanism of shale oil and establishing a“multi-peak model in oil generation”of shale.展开更多
Shale oil resources are abundant on Earth,of which hybrid sedimentary shale(HSS)oil is an important component,including high and medium-low organic matter content(TOC).Oil content,especially the oiliness gradation,is ...Shale oil resources are abundant on Earth,of which hybrid sedimentary shale(HSS)oil is an important component,including high and medium-low organic matter content(TOC).Oil content,especially the oiliness gradation,is a key parameter for shale oil evaluation and numerous studies had been conducted.However,most studies concentrated on the HSS with high TOC,making oil content evaluation of the HSS with medium-low TOC challenging.The Paleocene Shahejie Formation(E2s)shale in Dongpu Depression is a typical HSS with low-moderate TOC,showing great shale oil resource potential.Integrated geochemical characterization of 270 core samples were conducted and results show that,the E2s shale has fairgood hydrocarbon generation potential,with TOC ranging from 0.06%to 3.6%(Avg.0.86%)andⅡ1-Ⅱ2 kerogen type in thermally mature.The hydrocarbon generation potential decreases with kerogen types changing from type I toⅢ,but S1C and the oil saturation index(OSI)(S1*100/TOC>100)increase from type I toⅡ1,and then decrease from typeⅡ2 toⅢ,indicating shale with typeⅡ2 kerogen have the greatest oil content.This is related to the diferences in hydrocarbon expulsion efciency caused by diferential hydrocarbon generation potential and pore-microfractures evolution among shales with diferent kerogen types.Signifcant oil micro-migration occurred in E2s shale,with micro-migration quantity(∆Q)ranging from-846 to 993 mg/g(Avg.-120 mg/g),and 90%and 10%shale exhibit hydrocarbon intra-micro-migration(∆Q<0)and extra-micro-migration(∆Q>0).The shale with typeⅡ2 kerogen has the greatest intra-micro-migration.Based on S1C,TOC and OSI values and their evolution pattern,shale oil resources were classifed into enriched,moderately enriched,less efcient and invalid resources,accounting for 11%,53%,16%and 21%respectively,with S1C thresholds of 3.5 and 0.5 mg/g,OSI threshold of 100 mg/g.Compared with previous grading criteria,the gradation criterion established in this study is relatively lower,which is mainly due to the lower TOC and clay mineral content in HSS.Enriched and moderately enriched resources are mainly shales with typeⅡ2 kerogen,followed by typeⅡ1 kerogen,and the E2s4 U and E2s3 L shale are the most favorable targets for further shale oil exploration.The established oiliness gradation criteria are applicable for the HSS with TOC in other parts of the world.展开更多
This paper discusses the exploration and development history and lessons of the large ultra-deep biogenic reef gas field in Yuanba area,where the previous“Kaijiang-Liangping shelf”model provides an insight for the d...This paper discusses the exploration and development history and lessons of the large ultra-deep biogenic reef gas field in Yuanba area,where the previous“Kaijiang-Liangping shelf”model provides an insight for the discovery of the biological reef and bank on the platform margin.Systematic analysis of key geological conditions for hydrocarbon accumulation shows that the reef and bank reservoirs in Yuanba area are characterized by row and zonal distribution along“Kaijiang-Liangping shelf”,the bank in early and the reef in late,the reef in the front and the bank in the back,and dominated by lateral accretion and progradation.The major exploration target of high-quality reef-bank reservoirs are developed in Changxing Formation instead of in Feixianguan Formation,Three stages of fractures and dissolution,and dolomitization control the development of the high-quality reservoirs.Two sets of effective source rocks(Permian Dalong Formation and Wujiaping Formation)provide sufficient gas source for the large gas field.Three dimensional migration pathway system composed of micro-faults,micro-fractures and interlayer fissures facilitates the hydrocarbon migration and accumulation.The accumulation model of Yuanba gas field is characterized by the near-source accumulation,three-micro migration pathway system,lithological-stratigraphic reservoirs and tectonics controlling enrichment.According to the complex geological conditions such as ultra-deep reservoirs and multiple pressure systems in Yuanba gas field,several key technologies are developed during hydrocarbon exploration and development,including fine prediction of ultra-deep reef-bank reservoirs and identification of gas and water,fine-scale reservoir description and characterization of complex thin and small reef gas reservoirs,optimal&fast drilling of ultra-deep horizontal well,geo-steering of ultra-deep horizontal well for complex reef and bank.All these technologies resulted in the efficient exploration and development of Yuanba gas field and accelerated the innovation of theoretical technology and methods for ultra-deep reservoirs.展开更多
基金Supported by the National Science and Technology Major Project(2024ZD1404901,2017ZX05035)Strategic Priority Research Program(Category B)of the Chinese Academy of Sciences(XDB10050100).
文摘To clarify the mechanism of differential enrichment of intrasource shale oil,taking the third of seventh member of the Triassic Yanchang Formation(Chang 7_(3)submember for short)in the Ordos Basin,NW China as an example,we integrated high-resolution scanning electron microscopy(SEM),optical microscopy,laser Raman spectroscopy,rock pyrolysis,and organic solvent extraction experiments to identify solid bitumen of varying origins,obtain direct evidence of intrasource micro-migration of shale oil,and establish the coupling between the shale nano/micro-fabric and the oil generation,migration and accumulation.The Chang 7_(3)shale with rich alginite in laminae has the highest hydrocarbon generation potential but a low thermal transformation ratio.Frequent alternations of micron-scale argillaceous-felsic laminae enhance the hydrocarbon expulsion efficiency,yielding consistent aromaticity between in-situ and migrated solid bitumen.Mudstone laminae rich in terrestrial organic matter(OM)and clay minerals exhibit lower hydrocarbon generation threshold but stronger hydrocarbon retention capacity,with a certain amount of light oil/bitumen preserved to differentiate the chemical structure of in-situ versus migrated bitumen.Tuffaceous and sandy laminae contain abundant felsic minerals and migrated bitumen.Tuffaceous laminae develop high-angle microfractures under shale overpressure,facilitating oil charging into rigid mineral intergranular pores of sandy laminae.Fractionation during micro-migration progressively decreases the aromatization of solid bitumen from shale,through tuffaceous and mudstone,to sandy laminae,while increasing light hydrocarbon components and enhancing OM-hosted pore development.The intrasource micro-migration and enrichment of the Chang 7_(3)shale oil result from synergistic organic-inorganic diagenesis,with crude oil component fractionation being a key mechanism for forming sweet spots in laminated shale oil reservoirs.
基金Supported by the National Natural Science Foundation(42202133,42072174,42130803,41872148)PetroChina Science and Technology Innovation Fund(2023DQ02-0106)PetroChina Basic Technology Project(2021DJ0101).
文摘Taking the Lower Permian Fengcheng Formation shale in Mahu Sag of Junggar Basin,NW China,as an example,core observation,test analysis,geological analysis and numerical simulation were applied to identify the shale oil micro-migration phenomenon.The hydrocarbon micro-migration in shale oil was quantitatively evaluated and verified by a self-created hydrocarbon expulsion potential method,and the petroleum geological significance of shale oil micro-migration evaluation was determined.Results show that significant micro-migration can be recognized between the organic-rich lamina and organic-poor lamina.The organic-rich lamina has strong hydrocarbon generation ability.The heavy components of hydrocarbon preferentially retained by kerogen swelling or adsorption,while the light components of hydrocarbon were migrated and accumulated to the interbedded felsic or carbonate organic-poor laminae as free oil.About 69% of the Fengcheng Formation shale samples in Well MY1 exhibit hydrocarbon charging phenomenon,while 31% of those exhibit hydrocarbon expulsion phenomenon.The reliability of the micro-migration evaluation results was verified by combining the group components based on the geochromatography effect,two-dimension nuclear magnetic resonance analysis,and the geochemical behavior of inorganic manganese elements in the process of hydrocarbon migration.Micro-migration is a bridge connecting the hydrocarbon accumulation elements in shale formations,which reflects the whole process of shale oil generation,expulsion and accumulation,and controls the content and composition of shale oil.The identification and evaluation of shale oil micro-migration will provide new perspectives for dynamically differential enrichment mechanism of shale oil and establishing a“multi-peak model in oil generation”of shale.
基金supported by the National Natural Science Foundation of China(U24B6002,42202133,U22B6004)CNPC Innovation Fund(2022DQ02-0106)+5 种基金Key Laboratory of Tectonics and Petroleum Resources of the Ministry of Education(TPR-2023-05)major science and technology projects of CNPC during the"14th five-year plan"(2021DJ0101)National Natural Science Foundation of China(41872148,42072174,42130803)Strategic Cooperation Technology Projects of the CNPC and CUPB(ZLZX2020-01-05)Sinopec Zhongyuan Oilfeld and CUPB Cooperation Project(31300027-23-ZC0613-0013)AAPG Foundation Grantsin-Aid Program(22272306).
文摘Shale oil resources are abundant on Earth,of which hybrid sedimentary shale(HSS)oil is an important component,including high and medium-low organic matter content(TOC).Oil content,especially the oiliness gradation,is a key parameter for shale oil evaluation and numerous studies had been conducted.However,most studies concentrated on the HSS with high TOC,making oil content evaluation of the HSS with medium-low TOC challenging.The Paleocene Shahejie Formation(E2s)shale in Dongpu Depression is a typical HSS with low-moderate TOC,showing great shale oil resource potential.Integrated geochemical characterization of 270 core samples were conducted and results show that,the E2s shale has fairgood hydrocarbon generation potential,with TOC ranging from 0.06%to 3.6%(Avg.0.86%)andⅡ1-Ⅱ2 kerogen type in thermally mature.The hydrocarbon generation potential decreases with kerogen types changing from type I toⅢ,but S1C and the oil saturation index(OSI)(S1*100/TOC>100)increase from type I toⅡ1,and then decrease from typeⅡ2 toⅢ,indicating shale with typeⅡ2 kerogen have the greatest oil content.This is related to the diferences in hydrocarbon expulsion efciency caused by diferential hydrocarbon generation potential and pore-microfractures evolution among shales with diferent kerogen types.Signifcant oil micro-migration occurred in E2s shale,with micro-migration quantity(∆Q)ranging from-846 to 993 mg/g(Avg.-120 mg/g),and 90%and 10%shale exhibit hydrocarbon intra-micro-migration(∆Q<0)and extra-micro-migration(∆Q>0).The shale with typeⅡ2 kerogen has the greatest intra-micro-migration.Based on S1C,TOC and OSI values and their evolution pattern,shale oil resources were classifed into enriched,moderately enriched,less efcient and invalid resources,accounting for 11%,53%,16%and 21%respectively,with S1C thresholds of 3.5 and 0.5 mg/g,OSI threshold of 100 mg/g.Compared with previous grading criteria,the gradation criterion established in this study is relatively lower,which is mainly due to the lower TOC and clay mineral content in HSS.Enriched and moderately enriched resources are mainly shales with typeⅡ2 kerogen,followed by typeⅡ1 kerogen,and the E2s4 U and E2s3 L shale are the most favorable targets for further shale oil exploration.The established oiliness gradation criteria are applicable for the HSS with TOC in other parts of the world.
基金The work was supported by the National Science and Technology Major Project of China(No.2011ZX05005-003).
文摘This paper discusses the exploration and development history and lessons of the large ultra-deep biogenic reef gas field in Yuanba area,where the previous“Kaijiang-Liangping shelf”model provides an insight for the discovery of the biological reef and bank on the platform margin.Systematic analysis of key geological conditions for hydrocarbon accumulation shows that the reef and bank reservoirs in Yuanba area are characterized by row and zonal distribution along“Kaijiang-Liangping shelf”,the bank in early and the reef in late,the reef in the front and the bank in the back,and dominated by lateral accretion and progradation.The major exploration target of high-quality reef-bank reservoirs are developed in Changxing Formation instead of in Feixianguan Formation,Three stages of fractures and dissolution,and dolomitization control the development of the high-quality reservoirs.Two sets of effective source rocks(Permian Dalong Formation and Wujiaping Formation)provide sufficient gas source for the large gas field.Three dimensional migration pathway system composed of micro-faults,micro-fractures and interlayer fissures facilitates the hydrocarbon migration and accumulation.The accumulation model of Yuanba gas field is characterized by the near-source accumulation,three-micro migration pathway system,lithological-stratigraphic reservoirs and tectonics controlling enrichment.According to the complex geological conditions such as ultra-deep reservoirs and multiple pressure systems in Yuanba gas field,several key technologies are developed during hydrocarbon exploration and development,including fine prediction of ultra-deep reef-bank reservoirs and identification of gas and water,fine-scale reservoir description and characterization of complex thin and small reef gas reservoirs,optimal&fast drilling of ultra-deep horizontal well,geo-steering of ultra-deep horizontal well for complex reef and bank.All these technologies resulted in the efficient exploration and development of Yuanba gas field and accelerated the innovation of theoretical technology and methods for ultra-deep reservoirs.
