The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial....The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial.Mixing intensification encompasses innovative methods and tools that address the limitations of inadequate mixing within reactors,enabling efficient reaction scaling and boosting the productivity of industrial processes.This review provides a concise introduction to the fundamentals of multiphase mixing,followed by case studies highlighting the application of mixing intensification in the production of energy-storage materials,advanced optical materials,and nanopesticides.These examples illustrate the significance of theoretical analysis in informing and advancing engineering practices within the chemical industry.We also explore the challenges and opportunities in this field,offering insights based on our current understanding.展开更多
While steady improvements have been achieved for the track forecasts of typhoons,there has been a lack of improvement for intensity forecasts.One challenge for intensity forecasts is to capture the rapid intensificati...While steady improvements have been achieved for the track forecasts of typhoons,there has been a lack of improvement for intensity forecasts.One challenge for intensity forecasts is to capture the rapid intensification(RI),whose nonlinear characteristics impose great difficulties for numerical models.The ensemble sensitivity analysis(ESA)method is used here to analyze the initial conditions that contribute to typhoon intensity forecasts,especially with RI.Six RI processes from five typhoons(Chaba,Haima,Meranti,Sarika,and Songda)in 2016,are applied with ESA,which also gives a composite initial condition that favors subsequent RI.Results from individual cases have generally similar patterns of ESA,but with different magnitudes,when various cumulus parameterization schemes are applied.To draw the initial conditions with statistical significance,sample-mean azimuthal components of ESA are obtained.Results of the composite sensitivity show that typhoons that experience RI in 24 h favor enhanced primary circulation from low to high levels,intensified secondary circulation with increased radial inflow at lower levels and increased radial outflow at upper levels,a prominent warm core at around 300 hPa,and increased humidity at low levels.As the forecast lead time increases,the patterns of ESA are retained,while the sensitivity magnitudes decay.Given the general and quantitative composite sensitivity along with associated uncertainties for different cumulus parameterization schemes,appropriate sampling of the composite sensitivity in numerical models could be beneficial to capturing the RI and improving the forecasting of typhoon intensity.展开更多
The rapid intensification(RI)magnitude of tropical cyclones(TCs)over the western North Pacific(WNP)exhibits significant interannual variability and is influenced by multiple factors across various scales.These factors...The rapid intensification(RI)magnitude of tropical cyclones(TCs)over the western North Pacific(WNP)exhibits significant interannual variability and is influenced by multiple factors across various scales.These factors primarily include:interannual factors—sea surface temperature(SST)in key regions of the WNP,eastern Indian Ocean SST,El Niño-Southern Oscillation(ENSO),South Pacific Subtropical Dipole(SPSD),and western Pacific teleconnection;decadal factors—Atlantic Multidecadal Oscillation(AMO)and Pacific Decadal Oscillation(PDO);and longer-term factor—global warming.This study systematically analyzes these factors and their potential impacts,quantitatively assessing their relative importance.A statistical prediction model for the WNP TC-RI magnitude is developed based on ridge regression methods.The results indicate that the influence of these factors on the RI magnitude is closely related to the large-scale thermodynamic and dynamic conditions.Among them,the SPSD plays the most critical role in the interannual variability of the RI magnitude,followed by global warming and the AMO.Further analysis reveals that the statistical prediction model based on multiple factors demonstrates good predictive skill for the interannual variability of the TC RI magnitude.展开更多
The synoptic process of a super Arctic cyclone in August 2016(AC16)is investigated based on the Weather Research and Forecasting(WRF)model,and the key factors affecting the rapid intensification(RI)of AC16 and their r...The synoptic process of a super Arctic cyclone in August 2016(AC16)is investigated based on the Weather Research and Forecasting(WRF)model,and the key factors affecting the rapid intensification(RI)of AC16 and their relative contributions are analyzed by diagnosing a new surface pressure tendency equation(SPTE).The major physical mechanisms behind the two RI stages of AC16 are revealed.The trajectory,intensity changes,and structural characteristics of AC16 are well simulated by the WRF model.A diagnosis based on the SPTE promisingly reproduces the two RI stages of AC16.The leading factor that influenced the intensity of AC16 was identified to be the air-column potential temperature tendency,while the pressure change at the upper boundary had less of an impact.Further analysis reveals that the horizontal potential temperature advection was the decisive factor in a warming of the air column.Specifically,the upper-level warm advection generated by the strong wind field of the upper-level jet played a dominant role in warming the air column,which caused the initial RI of AC16.The AC16 movement into a strong potential temperature gradient generated by tropopause polar vortices increased the upper-level warm advection,which warmed the air column and thereby induced the second RI of AC16.However,the net effect of vertical potential temperature advection and latent heating,as well as radiation processes,caused a cooling of the air column and thereby negatively contributed to the RI of AC16.展开更多
Existing studies have mostly focused on sustainable intensification(SI)in agricultural systems,while neglecting the integrated analysis of SI for the land space utilization system(LSUS).This has resulted in a lack of ...Existing studies have mostly focused on sustainable intensification(SI)in agricultural systems,while neglecting the integrated analysis of SI for the land space utilization system(LSUS).This has resulted in a lack of systematic solutions in balancing sustainable resource utilization and environmental protection.This study reviewed SI's conceptual framework and evaluation,identified the gaps,and proposed an analytical framework of SI with clear logic and modeling processes for LSUS.Key findings include:(1)Resource competition and ecosystem pressures have highlighted the need to extend traditional agriculture-focused SI to LSUS and establish a clear quantitative evaluation framework for SI;(2)SI for LSUS refers to a system state in which a specific sub-system produces its dominant functions with resource savings,reduced environmental impact,efficient function output,and stable/enhanced function provision,while sub-systems evolve in a coordinated and orderly manner;(3)The assessment framework of SI for LSUS clarifies modeling processes,suggested indicators,methods and scale hierarchy system to help policymakers identify SI priorities across scales,informing strategies to balance agricultural,socioeconomic,and ecosystem goals.This study overcomes the limitations of traditional SI,providing crucial insights for tracking SI performance and identifying barriers in LSUS to enlighten the sustainable land use and management practices.展开更多
The aim of this study is to establish several important factors representing land use intensification in cultivated land （denoted by ClI）, using a multi-dimensional approach to achieve realistic and practical cultiv...The aim of this study is to establish several important factors representing land use intensification in cultivated land （denoted by ClI）, using a multi-dimensional approach to achieve realistic and practical cultivated land use policies in China. For this reason, the theoretical framework was first built to explain the changes of land use intensification in the cultivated land, and then the variables and index were further developed for the purpose of characterizing the dynamic trends and driving forces of the land use intensification in the cultivated land at the provincial level. The study results indicate that the extent of Cll significantly increased during the period of 1996 to 2008, due to the extensive use of fertilizers, machinery and pesticide, increased labor and capital input, and intensified land use. Moreover, the principal component regression results show that the productivity of cultivated land, economic benefits of cultivated land, labor productivity, and land use conversion are the main factors affecting the village development. The first three factors play a positive role, while the last one has a negative effect on the land use intensification in the cultivated land. According to these results, the main policies for sustainable intensification in cultivated land are proposed. First, the sustainable pathways for intensification should be adopted to reduce the unsustainable uses of chemical fertilizer, agricultural chemicals, etc. Second, the conditions for agricultural production should be further improved to increase the cultivated land productivity. Third, it is very necessary and helpful for improving labor productivity and land use efficiency from the viewpoint of accelerated the cultivated land circulation. The last step is to positively affect the production activities of peasants by means of reforming the subsidy standards.展开更多
Sustainable feeding of the growing population in China without ecological destabilization is a grand challenge. In this populous country where agriculture is dominated by smallholder farming, developing innovative tec...Sustainable feeding of the growing population in China without ecological destabilization is a grand challenge. In this populous country where agriculture is dominated by smallholder farming, developing innovative technology and translating scientific knowledge into action for smallholder farmers is a crucial step in addressing this challenge. Here, we present a novel approach for technology innovation and dissemination to achieve sustainable intensification in the fields of smallholder farmers. The Science and Technology Backyard(STB) is a hub in a rural area that links knowledge with practices to promote technology innovation and exchange. In this study, the framework and functions of STB are introduced, and the key implications for sustainable intensification across millions of smallholder farmers are explicitly stated:(i) develop innovative technology based on stated demands of farmers;(ii) disseminate technology by innovative social service models though combined top-down approaches with bottom-up measures to enable smallholders in rural areas. This paper provides a perspective on transformation of small-scale agriculture toward sustainable intensification in China and useful knowledge applicable to other developing countries.展开更多
To investigate the impacts of the diurnal cycle on tropical cyclones （TCs）,a set of idealized simulations were conducted by specifying different radiation （i.e.,nighttime-only,daytime-only,full diurnal cycle）.It w...To investigate the impacts of the diurnal cycle on tropical cyclones （TCs）,a set of idealized simulations were conducted by specifying different radiation （i.e.,nighttime-only,daytime-only,full diurnal cycle）.It was found that,for an initially weak storm,it developed faster during nighttime than daytime.The impacts of radiation were not only on TC intensification,but also on TC structure and size.The nighttime storm tended to have a larger size than its daytime counterparts.During nighttime,the radiative cooling steepened the lapse rate and thus reduced the static stability in cloudy regions,enhancing convection.Diabatic heating associated with outer convection induced boundary layer inflows,which led to outward expansion of tangential winds and thus increased the storm size.展开更多
Reactive distillation(RD) process is an innovative hybrid process combining reaction with distillation, which has recently come into sharp focus as a successful case of process intensification. Considered as the most ...Reactive distillation(RD) process is an innovative hybrid process combining reaction with distillation, which has recently come into sharp focus as a successful case of process intensification. Considered as the most representative case of process intensification, it has been applied for many productions, especially for production of ester compounds. However, such problems existing in the RD system for ester productions are still hard to solve,as the removal of the water which comes from the esterification, and the separation of the azeotropes of ester–alcohol(–water). Many methods have been studying on the process to solve the problems resulting in further intensification and energy saving. In this paper, azeotropic–reactive distillation or entrainer enhanced reactive distillation(ERD) process, reactive extractive distillation(RED) process, the method of co-production in RD process, pressure-swing reactive distillation(PSRD) process, reactive distillation–pervaporation coupled process(RD–PV), are introduced to solve the problems above, so the product(s) can be separated efficiently and the chemical equilibrium can be shifted. Dividing-wall column(DWC) structure and novel methods of loading catalyst are also introduced as the measures to intensify the process and save energy.展开更多
Die casting process is widely applied in making Al parts. However, due to high speed of liquid metal flow in the die cavity, gases are prone to be entrapped in the filling, resulting in porosity defects. The X-ray com...Die casting process is widely applied in making Al parts. However, due to high speed of liquid metal flow in the die cavity, gases are prone to be entrapped in the filling, resulting in porosity defects. The X-ray computed tomography scanning technique was used to detect the pores in die-cast ADC12 alloys with different intensification pressures. The three-dimensional features of pores including pore size, number, sphericity have been obtained. The effect of different intensification pressures on two different kinds of pores, namely gas-pores and shrinkage pores, was analyzed. The results show that with increasing the pressure, the pore fractions and quantity gradually decrease. When the pressure increased to 85 MPa, the pores from gas entrapment during the mold filling were compressed, leading to a lower porosity fraction. The pressure cannot affect the pores in the samples with a thin wall (2 mm) due to a great solidification rate.展开更多
In this study, the dependence of tropical cyclone （TC） development on the inner-core structure of the parent vortex is examined using a pair of idealized numerical simulations. It is found that the radial profile of...In this study, the dependence of tropical cyclone （TC） development on the inner-core structure of the parent vortex is examined using a pair of idealized numerical simulations. It is found that the radial profile of inner-core relative vorticity may have a great impact on its subsequent development. For a system with a larger inner-core relative vorticity/inertial stability, the conversion ratio of the diabatic heating to kinetic energy is greater. Furthermore, the behavior of the convective vorticity eddies is likely modulated by the system-scale circulation. For a parent vortex with a relatively higher inner-core vorticity and larger negative radial vorticity gradient, convective eddy formation and radially inward propagation is promoted through vorticity segregation. This provides a greater potential for these small-scale convective cells to self-organize into a mesoscale inner-core structure in the TC. In turn, convectively induced diabatic heating that is close to the center, along with higher inertial stability, efficiently enhances system-scale secondary circulation. This study provides a solid basis for further research into how the initial structure of a TC influences storm dynamics and thermodynamics.展开更多
Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications ...Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C—OH, C O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) was identified as pseudo-second-order kinetics. The rate constants of adsorption were evaluated.展开更多
Intensification in rice crop production is generally understood as requiring increased use of material inputs: water, inorganic fertilizers, and agrochemicals. However, this is not the only kind of intensification ava...Intensification in rice crop production is generally understood as requiring increased use of material inputs: water, inorganic fertilizers, and agrochemicals. However, this is not the only kind of intensification available. More productive crop phenotypes, with traits such as more resistance to biotic and abiotic stresses and shorter crop cycles, are possible through modifications in the management of rice plants, soil, water, and nutrients, reducing rather than increasing material inputs. Greater factor productivity can be achieved through the application of new knowledge and more skill, and(initially) more labor, as seen from the System of Rice Intensification(SRI), whose practices are used in various combinations by as many as 10 million farmers on about 4 million hectares in over 50 countries. The highest yields achieved with these management methods have come from hybrids and improved rice varieties, confirming the importance of making genetic improvements. However,unimproved varieties are also responsive to these changes, which induce better growth and functioning of rice root systems and more abundance, diversity, and activity of beneficial soil organisms. Some of these organisms as symbiotic endophytes can affect and enhance the expression of rice plants' genetic potential as well as their phenotypic resilience to multiple stresses, including those of climate change. SRI experience and data suggest that decades of plant breeding have been selecting for the best crop genetic endowments under suboptimal growing conditions, with crowding of plants that impedes their photosynthesis and growth, flooding of rice paddies that causes roots to degenerate and forgoes benefits derived from aerobic soil organisms, and overuse of agrochemicals that adversely affect these organisms as well as soil and human health. This review paper reports evidence from research in India and Indonesia that changes in crop and water management can improve the expression of rice plants' genetic potential, thereby creating more productive and robustphenotypes from given rice genotypes. Data indicate that increased plant density does not necessarily enhance crop yield potential, as classical breeding methods suggest. Developing cultivars that can achieve their higher productivity under a wide range of plant densities—breeding for density-neutral cultivars using alternative selection strategies—will enable more effective exploitation of available crop growth resources. Density-neutral cultivars that achieve high productivity under ample environmental growth resources can also achieve optimal productivity under limited resources, where lower densities can avert crop failure due to overcrowding. This will become more important to the extent that climatic and other factors become more adverse to crop production. Focusing more on which management practices can evoke the most productive and robust phenotypes from given genotypes is important for rice breeding and improvement programs since it is phenotypes that feed our human populations.展开更多
Using the biogeochemical model den itrification/decomposition （DN DC）, the dynamic changes of soil organic carbon （SOC） of farmland from the 1980s to 2030s were investigated in Huantai County, a typical intensive ...Using the biogeochemical model den itrification/decomposition （DN DC）, the dynamic changes of soil organic carbon （SOC） of farmland from the 1980s to 2030s were investigated in Huantai County, a typical intensive agricultural region in the Huang- Huai-Hai Plain of China. Prior to modelling, validation of the DNDC model against field data sets of SOC from Quzhou Experimental Station in the Huang-Huai-Hai Plain was conducted at the site scale. We compared the simulated results with the observed SOC in Huantai County during 1982-2011 under two different classification methods of simulation unit （the first method integrated soil type and land use of Huantai County to form the overlapped modeling units; the second selected the 11 administrative towns as the modeling units）, and achieved a high accuracy in the model simulation with the improvement of the model parameters. Regional SOC （0-20 cm） density and stocks for Huantai County in the years 2012-2031 were predicted under different scenarios of farming management. Compared with current management practices, optimized fertilization （20% decrease of mineral N）, crop straw incorporation （90%） and appropriate animal manure input （40 kg N ha-1 yr-1） could achieve the highest level of SOC density （56.8% higher than 2011） in the period of 2012-2031. The research highlighted the importance of crop straw incorporation, optimized N fertilization and integration of crop production with ani- mal husbandry on the farmland carbon sequestration for maintaining a high land productivity in the Huang-Huai-Hai Plain.展开更多
Diagnostics are presented from an ensemble of high-resolution forecasts that differed markedly in their predictions of the rapid intensification(RI)of Typhoon Rammasun.We show that the basic difference stems from subt...Diagnostics are presented from an ensemble of high-resolution forecasts that differed markedly in their predictions of the rapid intensification(RI)of Typhoon Rammasun.We show that the basic difference stems from subtle differences in initializations of(a)500-850-h Pa environmental winds,and(b)midlevel moisture and ventilation.We then describe how these differences impact on the evolving convective organization,storm structure,and the timing of RI.As expected,ascent,diabatic heating and the secondary circulation near the inner-core are much stronger in the member that best forecasts the RI.The evolution of vortex cloudiness from this member is similar to the actual imagery,with the development of an inner cloud band wrapping inwards to form the eyewall.We present evidence that this structure,and hence the enhanced diabatic heating,is related to the tilt and associated dynamics of the developing inner-core in shear.For the most accurate ensemble member:(a)inhibition of ascent and a reduction in convection over the up-shear sector allow moistening of the boundary-layer air,which is transported to the down-shear sector to feed a developing convective asymmetry;(b)with minimal ventilation,undiluted clouds and moisture from the down-shear left quadrant are then wrapped inwards to the up-shear left quadrant to form the eyewall cloud;and(c)this process seems related to a critical down-shear tilt of the vortex from midlevels,and the vertical phase-locking of the circulation over up-shear quadrants.For the member that forecasts a much-delayed RI,these processes are inhibited by stronger vertical wind shear,initially resulting in poor vertical coherence of the circulation,lesser moisture and larger ventilation.Our analysis suggests that ensemble prediction is needed to account for the sensitivity of forecasts to a relatively narrow range of environmental wind shear,moisture and vortex inner-structure.展开更多
Fluidized beds enable good solids mixing,high rates of heat and mass transfer,and large throughputs,but there remain issues related to fluidization quality and scale-up.In this work I review modification techniques fo...Fluidized beds enable good solids mixing,high rates of heat and mass transfer,and large throughputs,but there remain issues related to fluidization quality and scale-up.In this work I review modification techniques for fluidized beds from the perspective of the principles of process intensification(PI),that is,effective bubbling suppression and elutriation control.These techniques are further refined into(1)design factors,e.g.modifying the bed configuration,or the application of internal and external forces,and(2)operational factors,including altering the particle properties(e.g.size,density,surface area)and fluidizing gas properties(e.g.density,viscosity,or velocity).As far as two proposed PI principles are concerned,our review suggests that it ought to be possible to gain improvements of between 2 and 4 times over conventional fluidized bed designs by the application of these techniques.展开更多
We present how the luminescence of europium RR-2-P-oxides complexes can be increased by interaction of electronic levels of the complex with the radiation field of silver nanoparticles （NPs）. The procedure by which ...We present how the luminescence of europium RR-2-P-oxides complexes can be increased by interaction of electronic levels of the complex with the radiation field of silver nanoparticles （NPs）. The procedure by which silver NPs are formed in a sol-gel polyurethane matrix precursor was elaborated. The formed Ag NPs were combined with Eu complex incorporated in ormocer matrix. The emission spectra of the complexes without silver NPs were compared with spectra of the same complexes with addition of silver NPs. As the result of the interaction of the electronic levels of lanthaaide ligands with silver plasmons, dramatic increase of luminescence was observed.展开更多
The crop intensification program（CIP）was introduced in Rwanda in 2007 by the Ministry of Agriculture and Animal Resources（MINAGRI）,Rwanda,as a solution to the land fragmentation,low use of agricultural inputs and ...The crop intensification program（CIP）was introduced in Rwanda in 2007 by the Ministry of Agriculture and Animal Resources（MINAGRI）,Rwanda,as a solution to the land fragmentation,low use of agricultural inputs and low access to extension services.However,due to the voluntary nature of farmers’participation and their reluctance to participate,this study aimed at assessing the factors that influence their participation.Data were collected from 340 respondents through a household survey in Mayange and Rusarabuye sectors.Descriptive statistics and binary logistic regression model were used to analyze the data.Results show that the factors that significantly influenced the farmers’participation in the CIP include gender,non-farm income,farmland size,farming experience,land acquisition means,market access,trust and agro-ecological conditions.In fact,the non-farm income significantly increased the farmers’decisions to participate in the CIP（P〈0.001）as it eases the financial capital needed to invest in the CIP activities.On the land acquisition means,the farmers who inherited or bought the land positively and significantly participated in the CIP（P〈0.05）because they had the land tenure security.However,the participation in the CIP was hindered by inadequate irrigation and mechanization facilities,lack of farmers’participation in the CIP planning process,inadequate extension services,inadequate agricultural inputs and inadequate post-harvest technologies.Closer collaboration between farmers,local leaders,extension agents and agricultural service providers as well as the farmers’practical skills in irrigation and mechanization could enhance the participation to the program.Therefore,there is a need on the part of policymakers to empower farmers with adequate knowledge on better cropping practices and agricultural technologies through appropriate extension services and bottom-up based program.展开更多
There is a lack of quantitative assessments available on the effect of agricultural intensification on soil aggregate distribution and microbial properties. Here, we investigated how short-term nitrogen(N) intensifica...There is a lack of quantitative assessments available on the effect of agricultural intensification on soil aggregate distribution and microbial properties. Here, we investigated how short-term nitrogen(N) intensification induced changes in aggregate size distribution and microbial properties in a soil of a hot moist semi-arid region(Bangalore, India). We hypothesised that N intensification would increase the accumulation of macroaggregates > 2 mm and soil microbial biomass and activity, and that the specific crop plant sowed would influence the level of this increase. In November 2016, surface(0–10 cm) and subsurface(10–20 cm) soil samples were taken from three N fertilisation treatments, low N(50 kg N ha-1), medium N(75 and 100 kg N ha-1 for finger millet and maize, respectively),and high N(100 and 150 kg N ha-1 for finger millet and maize, respectively). Distribution of water-stable aggregate concentrations,carbon(C) and N dynamics within aggregate size class, and soil microbial biomass and activity were evaluated. The high-N treatment significantly increased the concentration of large macroaggregates in the subsurface soil of the maize crop treatment, presumably due to an increased C input from root growth. Different N fertilisation levels did not significantly affect C and N concentrations in different aggregate size classes or the bulk soil. High-N applications significantly increased dehydrogenase activity in both the surface soil and the subsurface soil and urease activity in the surface soil, likely because of increased accumulation of enzymes stabilised by soil colloids in dry soils. Dehydrogenase activity was significantly affected by the type of crop, but urease activity not. Overall, our results showed that high N application rates alter large macroaggregates and enzyme activities in surface and subsurface soils through an increased aboveground and corresponding belowground biomass input in the maize crop.展开更多
基金supported by the National Natural Science Foundation of China(22288102,22035007,and 22122815)。
文摘The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial.Mixing intensification encompasses innovative methods and tools that address the limitations of inadequate mixing within reactors,enabling efficient reaction scaling and boosting the productivity of industrial processes.This review provides a concise introduction to the fundamentals of multiphase mixing,followed by case studies highlighting the application of mixing intensification in the production of energy-storage materials,advanced optical materials,and nanopesticides.These examples illustrate the significance of theoretical analysis in informing and advancing engineering practices within the chemical industry.We also explore the challenges and opportunities in this field,offering insights based on our current understanding.
基金supported by the National Natural Science Foundation of China[grant numbers 42192553 and 41922036]the Fundamental Research Funds for the Central Universities–Cemac“GeoX”Interdisciplinary Program[grant number 020714380207]。
文摘While steady improvements have been achieved for the track forecasts of typhoons,there has been a lack of improvement for intensity forecasts.One challenge for intensity forecasts is to capture the rapid intensification(RI),whose nonlinear characteristics impose great difficulties for numerical models.The ensemble sensitivity analysis(ESA)method is used here to analyze the initial conditions that contribute to typhoon intensity forecasts,especially with RI.Six RI processes from five typhoons(Chaba,Haima,Meranti,Sarika,and Songda)in 2016,are applied with ESA,which also gives a composite initial condition that favors subsequent RI.Results from individual cases have generally similar patterns of ESA,but with different magnitudes,when various cumulus parameterization schemes are applied.To draw the initial conditions with statistical significance,sample-mean azimuthal components of ESA are obtained.Results of the composite sensitivity show that typhoons that experience RI in 24 h favor enhanced primary circulation from low to high levels,intensified secondary circulation with increased radial inflow at lower levels and increased radial outflow at upper levels,a prominent warm core at around 300 hPa,and increased humidity at low levels.As the forecast lead time increases,the patterns of ESA are retained,while the sensitivity magnitudes decay.Given the general and quantitative composite sensitivity along with associated uncertainties for different cumulus parameterization schemes,appropriate sampling of the composite sensitivity in numerical models could be beneficial to capturing the RI and improving the forecasting of typhoon intensity.
基金Guangdong Major Project of Basic and Applied Basic Research(2020B0301030004)National Natural Science Foundation of China(41875114)Science and Technology Commission of Shanghai Municipality,China(23DZ1204703)。
文摘The rapid intensification(RI)magnitude of tropical cyclones(TCs)over the western North Pacific(WNP)exhibits significant interannual variability and is influenced by multiple factors across various scales.These factors primarily include:interannual factors—sea surface temperature(SST)in key regions of the WNP,eastern Indian Ocean SST,El Niño-Southern Oscillation(ENSO),South Pacific Subtropical Dipole(SPSD),and western Pacific teleconnection;decadal factors—Atlantic Multidecadal Oscillation(AMO)and Pacific Decadal Oscillation(PDO);and longer-term factor—global warming.This study systematically analyzes these factors and their potential impacts,quantitatively assessing their relative importance.A statistical prediction model for the WNP TC-RI magnitude is developed based on ridge regression methods.The results indicate that the influence of these factors on the RI magnitude is closely related to the large-scale thermodynamic and dynamic conditions.Among them,the SPSD plays the most critical role in the interannual variability of the RI magnitude,followed by global warming and the AMO.Further analysis reveals that the statistical prediction model based on multiple factors demonstrates good predictive skill for the interannual variability of the TC RI magnitude.
基金sponsored by the funding of the National Natural Science Foundation of China(Grant Nos.42075011,42192552,42005025,and 42075035).
文摘The synoptic process of a super Arctic cyclone in August 2016(AC16)is investigated based on the Weather Research and Forecasting(WRF)model,and the key factors affecting the rapid intensification(RI)of AC16 and their relative contributions are analyzed by diagnosing a new surface pressure tendency equation(SPTE).The major physical mechanisms behind the two RI stages of AC16 are revealed.The trajectory,intensity changes,and structural characteristics of AC16 are well simulated by the WRF model.A diagnosis based on the SPTE promisingly reproduces the two RI stages of AC16.The leading factor that influenced the intensity of AC16 was identified to be the air-column potential temperature tendency,while the pressure change at the upper boundary had less of an impact.Further analysis reveals that the horizontal potential temperature advection was the decisive factor in a warming of the air column.Specifically,the upper-level warm advection generated by the strong wind field of the upper-level jet played a dominant role in warming the air column,which caused the initial RI of AC16.The AC16 movement into a strong potential temperature gradient generated by tropopause polar vortices increased the upper-level warm advection,which warmed the air column and thereby induced the second RI of AC16.However,the net effect of vertical potential temperature advection and latent heating,as well as radiation processes,caused a cooling of the air column and thereby negatively contributed to the RI of AC16.
基金National Natural Science Foundation of China,No.42201269,No.42401316Natural Science Foundation of Jiangsu Province,No.BK20241666+3 种基金Humanity and Social Science Youth Foundation of Ministry of Education of China,No.22YJC630087Social Science Foundation of Jiangsu Province,No.24EYB004Open Fund of Key Laboratory of Coastal Zone Exploitation and Protection,Ministry of Natural Resources,No.2023CZEPK07Fundamental Research Funds for the Central Universities,No.2024QN11056。
文摘Existing studies have mostly focused on sustainable intensification(SI)in agricultural systems,while neglecting the integrated analysis of SI for the land space utilization system(LSUS).This has resulted in a lack of systematic solutions in balancing sustainable resource utilization and environmental protection.This study reviewed SI's conceptual framework and evaluation,identified the gaps,and proposed an analytical framework of SI with clear logic and modeling processes for LSUS.Key findings include:(1)Resource competition and ecosystem pressures have highlighted the need to extend traditional agriculture-focused SI to LSUS and establish a clear quantitative evaluation framework for SI;(2)SI for LSUS refers to a system state in which a specific sub-system produces its dominant functions with resource savings,reduced environmental impact,efficient function output,and stable/enhanced function provision,while sub-systems evolve in a coordinated and orderly manner;(3)The assessment framework of SI for LSUS clarifies modeling processes,suggested indicators,methods and scale hierarchy system to help policymakers identify SI priorities across scales,informing strategies to balance agricultural,socioeconomic,and ecosystem goals.This study overcomes the limitations of traditional SI,providing crucial insights for tracking SI performance and identifying barriers in LSUS to enlighten the sustainable land use and management practices.
基金National Natural Science Foundation of China, No.41401203, No.41130748 Central Research Institutes of Basic Research and Public Service Special Operations, No.005201400127
文摘The aim of this study is to establish several important factors representing land use intensification in cultivated land （denoted by ClI）, using a multi-dimensional approach to achieve realistic and practical cultivated land use policies in China. For this reason, the theoretical framework was first built to explain the changes of land use intensification in the cultivated land, and then the variables and index were further developed for the purpose of characterizing the dynamic trends and driving forces of the land use intensification in the cultivated land at the provincial level. The study results indicate that the extent of Cll significantly increased during the period of 1996 to 2008, due to the extensive use of fertilizers, machinery and pesticide, increased labor and capital input, and intensified land use. Moreover, the principal component regression results show that the productivity of cultivated land, economic benefits of cultivated land, labor productivity, and land use conversion are the main factors affecting the village development. The first three factors play a positive role, while the last one has a negative effect on the land use intensification in the cultivated land. According to these results, the main policies for sustainable intensification in cultivated land are proposed. First, the sustainable pathways for intensification should be adopted to reduce the unsustainable uses of chemical fertilizer, agricultural chemicals, etc. Second, the conditions for agricultural production should be further improved to increase the cultivated land productivity. Third, it is very necessary and helpful for improving labor productivity and land use efficiency from the viewpoint of accelerated the cultivated land circulation. The last step is to positively affect the production activities of peasants by means of reforming the subsidy standards.
基金supported by the National Basic Research Program of China (2015CB150405)
文摘Sustainable feeding of the growing population in China without ecological destabilization is a grand challenge. In this populous country where agriculture is dominated by smallholder farming, developing innovative technology and translating scientific knowledge into action for smallholder farmers is a crucial step in addressing this challenge. Here, we present a novel approach for technology innovation and dissemination to achieve sustainable intensification in the fields of smallholder farmers. The Science and Technology Backyard(STB) is a hub in a rural area that links knowledge with practices to promote technology innovation and exchange. In this study, the framework and functions of STB are introduced, and the key implications for sustainable intensification across millions of smallholder farmers are explicitly stated:(i) develop innovative technology based on stated demands of farmers;(ii) disseminate technology by innovative social service models though combined top-down approaches with bottom-up measures to enable smallholders in rural areas. This paper provides a perspective on transformation of small-scale agriculture toward sustainable intensification in China and useful knowledge applicable to other developing countries.
基金sponsored by the National Natural Science Foundation of China (Grant Nos. 41275095, 41075037)the National Key Basic Research Program of China (Grant No.2012CB955204)the Key University Science Research Project of Jiangsu Province (Grant No.14KJA170005)
文摘To investigate the impacts of the diurnal cycle on tropical cyclones （TCs）,a set of idealized simulations were conducted by specifying different radiation （i.e.,nighttime-only,daytime-only,full diurnal cycle）.It was found that,for an initially weak storm,it developed faster during nighttime than daytime.The impacts of radiation were not only on TC intensification,but also on TC structure and size.The nighttime storm tended to have a larger size than its daytime counterparts.During nighttime,the radiative cooling steepened the lapse rate and thus reduced the static stability in cloudy regions,enhancing convection.Diabatic heating associated with outer convection induced boundary layer inflows,which led to outward expansion of tangential winds and thus increased the storm size.
基金Supported by the National Key Research and Development Program of China(2017YFB0602500)the Basic Research Program of Hebei Province(16964502D)
文摘Reactive distillation(RD) process is an innovative hybrid process combining reaction with distillation, which has recently come into sharp focus as a successful case of process intensification. Considered as the most representative case of process intensification, it has been applied for many productions, especially for production of ester compounds. However, such problems existing in the RD system for ester productions are still hard to solve,as the removal of the water which comes from the esterification, and the separation of the azeotropes of ester–alcohol(–water). Many methods have been studying on the process to solve the problems resulting in further intensification and energy saving. In this paper, azeotropic–reactive distillation or entrainer enhanced reactive distillation(ERD) process, reactive extractive distillation(RED) process, the method of co-production in RD process, pressure-swing reactive distillation(PSRD) process, reactive distillation–pervaporation coupled process(RD–PV), are introduced to solve the problems above, so the product(s) can be separated efficiently and the chemical equilibrium can be shifted. Dividing-wall column(DWC) structure and novel methods of loading catalyst are also introduced as the measures to intensify the process and save energy.
基金financially supported by the Industry Base Enhanced Project(TC160A310-10-01),China
文摘Die casting process is widely applied in making Al parts. However, due to high speed of liquid metal flow in the die cavity, gases are prone to be entrapped in the filling, resulting in porosity defects. The X-ray computed tomography scanning technique was used to detect the pores in die-cast ADC12 alloys with different intensification pressures. The three-dimensional features of pores including pore size, number, sphericity have been obtained. The effect of different intensification pressures on two different kinds of pores, namely gas-pores and shrinkage pores, was analyzed. The results show that with increasing the pressure, the pore fractions and quantity gradually decrease. When the pressure increased to 85 MPa, the pores from gas entrapment during the mold filling were compressed, leading to a lower porosity fraction. The pressure cannot affect the pores in the samples with a thin wall (2 mm) due to a great solidification rate.
基金sponsored by the National Key Basic Research Program of China (Grant No.2015CB452803)the State Key Laboratory of Severe Weather,Chinese Academy of Meteorological Sciences (Grant No.2014LASW-B08)+1 种基金the "six peaks of high-level talents" funding projectthe Key University Science Research Project of Jiangsu Province (Grant No.14KJA170005)
文摘In this study, the dependence of tropical cyclone （TC） development on the inner-core structure of the parent vortex is examined using a pair of idealized numerical simulations. It is found that the radial profile of inner-core relative vorticity may have a great impact on its subsequent development. For a system with a larger inner-core relative vorticity/inertial stability, the conversion ratio of the diabatic heating to kinetic energy is greater. Furthermore, the behavior of the convective vorticity eddies is likely modulated by the system-scale circulation. For a parent vortex with a relatively higher inner-core vorticity and larger negative radial vorticity gradient, convective eddy formation and radially inward propagation is promoted through vorticity segregation. This provides a greater potential for these small-scale convective cells to self-organize into a mesoscale inner-core structure in the TC. In turn, convectively induced diabatic heating that is close to the center, along with higher inertial stability, efficiently enhances system-scale secondary circulation. This study provides a solid basis for further research into how the initial structure of a TC influences storm dynamics and thermodynamics.
文摘Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C—OH, C O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) was identified as pseudo-second-order kinetics. The rate constants of adsorption were evaluated.
文摘Intensification in rice crop production is generally understood as requiring increased use of material inputs: water, inorganic fertilizers, and agrochemicals. However, this is not the only kind of intensification available. More productive crop phenotypes, with traits such as more resistance to biotic and abiotic stresses and shorter crop cycles, are possible through modifications in the management of rice plants, soil, water, and nutrients, reducing rather than increasing material inputs. Greater factor productivity can be achieved through the application of new knowledge and more skill, and(initially) more labor, as seen from the System of Rice Intensification(SRI), whose practices are used in various combinations by as many as 10 million farmers on about 4 million hectares in over 50 countries. The highest yields achieved with these management methods have come from hybrids and improved rice varieties, confirming the importance of making genetic improvements. However,unimproved varieties are also responsive to these changes, which induce better growth and functioning of rice root systems and more abundance, diversity, and activity of beneficial soil organisms. Some of these organisms as symbiotic endophytes can affect and enhance the expression of rice plants' genetic potential as well as their phenotypic resilience to multiple stresses, including those of climate change. SRI experience and data suggest that decades of plant breeding have been selecting for the best crop genetic endowments under suboptimal growing conditions, with crowding of plants that impedes their photosynthesis and growth, flooding of rice paddies that causes roots to degenerate and forgoes benefits derived from aerobic soil organisms, and overuse of agrochemicals that adversely affect these organisms as well as soil and human health. This review paper reports evidence from research in India and Indonesia that changes in crop and water management can improve the expression of rice plants' genetic potential, thereby creating more productive and robustphenotypes from given rice genotypes. Data indicate that increased plant density does not necessarily enhance crop yield potential, as classical breeding methods suggest. Developing cultivars that can achieve their higher productivity under a wide range of plant densities—breeding for density-neutral cultivars using alternative selection strategies—will enable more effective exploitation of available crop growth resources. Density-neutral cultivars that achieve high productivity under ample environmental growth resources can also achieve optimal productivity under limited resources, where lower densities can avert crop failure due to overcrowding. This will become more important to the extent that climatic and other factors become more adverse to crop production. Focusing more on which management practices can evoke the most productive and robust phenotypes from given genotypes is important for rice breeding and improvement programs since it is phenotypes that feed our human populations.
基金financially supported by the Non-profit Research Foundation for Agriculture, China (201103039)the National Natural Science Foundation of China (31261140367 and 31370527)
文摘Using the biogeochemical model den itrification/decomposition （DN DC）, the dynamic changes of soil organic carbon （SOC） of farmland from the 1980s to 2030s were investigated in Huantai County, a typical intensive agricultural region in the Huang- Huai-Hai Plain of China. Prior to modelling, validation of the DNDC model against field data sets of SOC from Quzhou Experimental Station in the Huang-Huai-Hai Plain was conducted at the site scale. We compared the simulated results with the observed SOC in Huantai County during 1982-2011 under two different classification methods of simulation unit （the first method integrated soil type and land use of Huantai County to form the overlapped modeling units; the second selected the 11 administrative towns as the modeling units）, and achieved a high accuracy in the model simulation with the improvement of the model parameters. Regional SOC （0-20 cm） density and stocks for Huantai County in the years 2012-2031 were predicted under different scenarios of farming management. Compared with current management practices, optimized fertilization （20% decrease of mineral N）, crop straw incorporation （90%） and appropriate animal manure input （40 kg N ha-1 yr-1） could achieve the highest level of SOC density （56.8% higher than 2011） in the period of 2012-2031. The research highlighted the importance of crop straw incorporation, optimized N fertilization and integration of crop production with ani- mal husbandry on the farmland carbon sequestration for maintaining a high land productivity in the Huang-Huai-Hai Plain.
基金partially supported by the National Natural Science Foundation of China (Grant Nos. 41365005, 41765007 and 41705038)the Hainan Key Cooperation Program (Grant No. ZDYF2019213)the Natural Science Foundation of Hainan Province of China (Grant No. 417298)
文摘Diagnostics are presented from an ensemble of high-resolution forecasts that differed markedly in their predictions of the rapid intensification(RI)of Typhoon Rammasun.We show that the basic difference stems from subtle differences in initializations of(a)500-850-h Pa environmental winds,and(b)midlevel moisture and ventilation.We then describe how these differences impact on the evolving convective organization,storm structure,and the timing of RI.As expected,ascent,diabatic heating and the secondary circulation near the inner-core are much stronger in the member that best forecasts the RI.The evolution of vortex cloudiness from this member is similar to the actual imagery,with the development of an inner cloud band wrapping inwards to form the eyewall.We present evidence that this structure,and hence the enhanced diabatic heating,is related to the tilt and associated dynamics of the developing inner-core in shear.For the most accurate ensemble member:(a)inhibition of ascent and a reduction in convection over the up-shear sector allow moistening of the boundary-layer air,which is transported to the down-shear sector to feed a developing convective asymmetry;(b)with minimal ventilation,undiluted clouds and moisture from the down-shear left quadrant are then wrapped inwards to the up-shear left quadrant to form the eyewall cloud;and(c)this process seems related to a critical down-shear tilt of the vortex from midlevels,and the vertical phase-locking of the circulation over up-shear quadrants.For the member that forecasts a much-delayed RI,these processes are inhibited by stronger vertical wind shear,initially resulting in poor vertical coherence of the circulation,lesser moisture and larger ventilation.Our analysis suggests that ensemble prediction is needed to account for the sensitivity of forecasts to a relatively narrow range of environmental wind shear,moisture and vortex inner-structure.
文摘Fluidized beds enable good solids mixing,high rates of heat and mass transfer,and large throughputs,but there remain issues related to fluidization quality and scale-up.In this work I review modification techniques for fluidized beds from the perspective of the principles of process intensification(PI),that is,effective bubbling suppression and elutriation control.These techniques are further refined into(1)design factors,e.g.modifying the bed configuration,or the application of internal and external forces,and(2)operational factors,including altering the particle properties(e.g.size,density,surface area)and fluidizing gas properties(e.g.density,viscosity,or velocity).As far as two proposed PI principles are concerned,our review suggests that it ought to be possible to gain improvements of between 2 and 4 times over conventional fluidized bed designs by the application of these techniques.
基金supported by the Institute of Physical Chemistry of the Polish Academy of Sciences
文摘We present how the luminescence of europium RR-2-P-oxides complexes can be increased by interaction of electronic levels of the complex with the radiation field of silver nanoparticles （NPs）. The procedure by which silver NPs are formed in a sol-gel polyurethane matrix precursor was elaborated. The formed Ag NPs were combined with Eu complex incorporated in ormocer matrix. The emission spectra of the complexes without silver NPs were compared with spectra of the same complexes with addition of silver NPs. As the result of the interaction of the electronic levels of lanthaaide ligands with silver plasmons, dramatic increase of luminescence was observed.
基金The Institute of Resources, Ecosystem and Environment of Agriculture (IREEA) at Nanjing Agricultural University,Chinathe Chinese Scholarship Council (CSC) are thanked for the financial support
文摘The crop intensification program（CIP）was introduced in Rwanda in 2007 by the Ministry of Agriculture and Animal Resources（MINAGRI）,Rwanda,as a solution to the land fragmentation,low use of agricultural inputs and low access to extension services.However,due to the voluntary nature of farmers’participation and their reluctance to participate,this study aimed at assessing the factors that influence their participation.Data were collected from 340 respondents through a household survey in Mayange and Rusarabuye sectors.Descriptive statistics and binary logistic regression model were used to analyze the data.Results show that the factors that significantly influenced the farmers’participation in the CIP include gender,non-farm income,farmland size,farming experience,land acquisition means,market access,trust and agro-ecological conditions.In fact,the non-farm income significantly increased the farmers’decisions to participate in the CIP（P〈0.001）as it eases the financial capital needed to invest in the CIP activities.On the land acquisition means,the farmers who inherited or bought the land positively and significantly participated in the CIP（P〈0.05）because they had the land tenure security.However,the participation in the CIP was hindered by inadequate irrigation and mechanization facilities,lack of farmers’participation in the CIP planning process,inadequate extension services,inadequate agricultural inputs and inadequate post-harvest technologies.Closer collaboration between farmers,local leaders,extension agents and agricultural service providers as well as the farmers’practical skills in irrigation and mechanization could enhance the participation to the program.Therefore,there is a need on the part of policymakers to empower farmers with adequate knowledge on better cropping practices and agricultural technologies through appropriate extension services and bottom-up based program.
基金financially supported by German Research Foundation(DFG)the Indian Department of Biotechnology(DBT)
文摘There is a lack of quantitative assessments available on the effect of agricultural intensification on soil aggregate distribution and microbial properties. Here, we investigated how short-term nitrogen(N) intensification induced changes in aggregate size distribution and microbial properties in a soil of a hot moist semi-arid region(Bangalore, India). We hypothesised that N intensification would increase the accumulation of macroaggregates > 2 mm and soil microbial biomass and activity, and that the specific crop plant sowed would influence the level of this increase. In November 2016, surface(0–10 cm) and subsurface(10–20 cm) soil samples were taken from three N fertilisation treatments, low N(50 kg N ha-1), medium N(75 and 100 kg N ha-1 for finger millet and maize, respectively),and high N(100 and 150 kg N ha-1 for finger millet and maize, respectively). Distribution of water-stable aggregate concentrations,carbon(C) and N dynamics within aggregate size class, and soil microbial biomass and activity were evaluated. The high-N treatment significantly increased the concentration of large macroaggregates in the subsurface soil of the maize crop treatment, presumably due to an increased C input from root growth. Different N fertilisation levels did not significantly affect C and N concentrations in different aggregate size classes or the bulk soil. High-N applications significantly increased dehydrogenase activity in both the surface soil and the subsurface soil and urease activity in the surface soil, likely because of increased accumulation of enzymes stabilised by soil colloids in dry soils. Dehydrogenase activity was significantly affected by the type of crop, but urease activity not. Overall, our results showed that high N application rates alter large macroaggregates and enzyme activities in surface and subsurface soils through an increased aboveground and corresponding belowground biomass input in the maize crop.
