The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial....The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial.Mixing intensification encompasses innovative methods and tools that address the limitations of inadequate mixing within reactors,enabling efficient reaction scaling and boosting the productivity of industrial processes.This review provides a concise introduction to the fundamentals of multiphase mixing,followed by case studies highlighting the application of mixing intensification in the production of energy-storage materials,advanced optical materials,and nanopesticides.These examples illustrate the significance of theoretical analysis in informing and advancing engineering practices within the chemical industry.We also explore the challenges and opportunities in this field,offering insights based on our current understanding.展开更多
While steady improvements have been achieved for the track forecasts of typhoons,there has been a lack of improvement for intensity forecasts.One challenge for intensity forecasts is to capture the rapid intensificati...While steady improvements have been achieved for the track forecasts of typhoons,there has been a lack of improvement for intensity forecasts.One challenge for intensity forecasts is to capture the rapid intensification(RI),whose nonlinear characteristics impose great difficulties for numerical models.The ensemble sensitivity analysis(ESA)method is used here to analyze the initial conditions that contribute to typhoon intensity forecasts,especially with RI.Six RI processes from five typhoons(Chaba,Haima,Meranti,Sarika,and Songda)in 2016,are applied with ESA,which also gives a composite initial condition that favors subsequent RI.Results from individual cases have generally similar patterns of ESA,but with different magnitudes,when various cumulus parameterization schemes are applied.To draw the initial conditions with statistical significance,sample-mean azimuthal components of ESA are obtained.Results of the composite sensitivity show that typhoons that experience RI in 24 h favor enhanced primary circulation from low to high levels,intensified secondary circulation with increased radial inflow at lower levels and increased radial outflow at upper levels,a prominent warm core at around 300 hPa,and increased humidity at low levels.As the forecast lead time increases,the patterns of ESA are retained,while the sensitivity magnitudes decay.Given the general and quantitative composite sensitivity along with associated uncertainties for different cumulus parameterization schemes,appropriate sampling of the composite sensitivity in numerical models could be beneficial to capturing the RI and improving the forecasting of typhoon intensity.展开更多
The rapid intensification(RI)magnitude of tropical cyclones(TCs)over the western North Pacific(WNP)exhibits significant interannual variability and is influenced by multiple factors across various scales.These factors...The rapid intensification(RI)magnitude of tropical cyclones(TCs)over the western North Pacific(WNP)exhibits significant interannual variability and is influenced by multiple factors across various scales.These factors primarily include:interannual factors—sea surface temperature(SST)in key regions of the WNP,eastern Indian Ocean SST,El Niño-Southern Oscillation(ENSO),South Pacific Subtropical Dipole(SPSD),and western Pacific teleconnection;decadal factors—Atlantic Multidecadal Oscillation(AMO)and Pacific Decadal Oscillation(PDO);and longer-term factor—global warming.This study systematically analyzes these factors and their potential impacts,quantitatively assessing their relative importance.A statistical prediction model for the WNP TC-RI magnitude is developed based on ridge regression methods.The results indicate that the influence of these factors on the RI magnitude is closely related to the large-scale thermodynamic and dynamic conditions.Among them,the SPSD plays the most critical role in the interannual variability of the RI magnitude,followed by global warming and the AMO.Further analysis reveals that the statistical prediction model based on multiple factors demonstrates good predictive skill for the interannual variability of the TC RI magnitude.展开更多
The synoptic process of a super Arctic cyclone in August 2016(AC16)is investigated based on the Weather Research and Forecasting(WRF)model,and the key factors affecting the rapid intensification(RI)of AC16 and their r...The synoptic process of a super Arctic cyclone in August 2016(AC16)is investigated based on the Weather Research and Forecasting(WRF)model,and the key factors affecting the rapid intensification(RI)of AC16 and their relative contributions are analyzed by diagnosing a new surface pressure tendency equation(SPTE).The major physical mechanisms behind the two RI stages of AC16 are revealed.The trajectory,intensity changes,and structural characteristics of AC16 are well simulated by the WRF model.A diagnosis based on the SPTE promisingly reproduces the two RI stages of AC16.The leading factor that influenced the intensity of AC16 was identified to be the air-column potential temperature tendency,while the pressure change at the upper boundary had less of an impact.Further analysis reveals that the horizontal potential temperature advection was the decisive factor in a warming of the air column.Specifically,the upper-level warm advection generated by the strong wind field of the upper-level jet played a dominant role in warming the air column,which caused the initial RI of AC16.The AC16 movement into a strong potential temperature gradient generated by tropopause polar vortices increased the upper-level warm advection,which warmed the air column and thereby induced the second RI of AC16.However,the net effect of vertical potential temperature advection and latent heating,as well as radiation processes,caused a cooling of the air column and thereby negatively contributed to the RI of AC16.展开更多
Sustainable intensification of cultivated land use(SICLU) and large-scale operations(LSO) are widely acknowledged strategies for enhancing agricultural performance.However,the existing literature has faced challenges ...Sustainable intensification of cultivated land use(SICLU) and large-scale operations(LSO) are widely acknowledged strategies for enhancing agricultural performance.However,the existing literature has faced challenges in precisely defining SICLU and constructing comprehensive indicators,which has hindered the exploration of factors influencing LSO within the SICLU framework.To address this gap,we integrated self-efficacy theory into the design of an index framework for evaluating SICLU.We subsequently employed econometric models to analyze the significant factors that impact LSO.Our findings reveal that SICLU can be divided into four key dimensions:intensive management,efficient output,resource conservation,and ecological environment optimization.Furthermore,it is crucial to incorporate belief-based cognitive factors into the index system,as farmers’ understanding of fertilizer and pesticide application significantly influences their willingness to engage in LSO.Moreover,we identify grain market turnover as the most influential factor in promoting LSO,with single-factor contribution rates reaching 70.9% for cultivated land transfer willingness and 62.5% for the total planting areas.Interestingly,unlike irrigation and agricultural machinery inputs,increased labor inputs correspond to larger planting areas for farmers.This trend may be attributed to reduced labor availability because of rural labor migration,whereas the reduction in irrigation and agricultural input is contingent on innovations in production practices and the transfer of cultivated land management rights.Importantly,SICLU dynamically influences LSO,with each index related to SICLU having an optimal range that fosters LSO.These insights offer valuable guidance for policymakers,emphasizing farmers as their central focus,with the adjustment of input and output factors as a means to achieve LSO as the ultimate goal.In conclusion,we propose research avenues for further enriching the SICLU framework to ensure that it aligns with the specific characteristics of regional agricultural development.展开更多
Recent observational and numerical studies have revealed the dependence of the intensification rate on the inner-core size of tropical cyclones(TCs). In this study, with the initial inner-core size(i.e., the radius of...Recent observational and numerical studies have revealed the dependence of the intensification rate on the inner-core size of tropical cyclones(TCs). In this study, with the initial inner-core size(i.e., the radius of maximum wind—RMW)varied from 20–180 km in idealized simulations using two different numerical models, we found a nonmonotonic dependence of the lifetime maximum intensification rate(LMIR) on the inner-core size. Namely, there is an optimal innercore size for the LMIR of a TC. Tangential wind budget analysis shows that, compared to large TCs, small TCs have large inward flux of absolute vorticity due to large absolute vorticity inside the RMW. However, small TCs also suffer from strong lateral diffusion across the eyewall, which partly offsets the positive contribution from large inward flux of absolute vorticity. These two competing processes ultimately lead to the TC with an intermediate initial inner-core size having the largest LMIR. Results from sensitivity experiments show that the optimal size varies in the range of 40–120 km and increases with higher sea surface temperature, lower latitude, larger horizontal mixing length, and weaker initial TC intensity. The 40–120 km RMW corresponds to the inner-core size most commonly found for intensifying TCs in observations, suggesting the natural selection of initial TC size for intensification. This study highlights the importance of accurate representation of TC inner-core size to TC intensity forecasts by numerical weather prediction models.展开更多
Recent studies on tropical cyclone(TC)intensity change indicate that the development of a vertically aligned TC circulation is a key feature of its rapid intensification(RI),however,understanding how vortex alignment ...Recent studies on tropical cyclone(TC)intensity change indicate that the development of a vertically aligned TC circulation is a key feature of its rapid intensification(RI),however,understanding how vortex alignment occurs remains a challenging topic in TC intensity change research.Based on the simulation outputs of North Atlantic Hurricane Wilma(2005)and western North Pacific Typhoon Rammasun(2014),vortex track oscillations at different vertical levels and their associated role in vortex alignment are examined to improve our understanding of the vortex alignment during RI of TCs with initial hurricane intensity.It is found that vortex tracks at different vertical levels oscillate consistently in speed and direction during the RI of the two simulated TCs.While the consistent track oscillation reduces the oscillation tilt during RI,the reduction of vortex tilt results mainly from the mean track before RI.It is also found that the vortex tilt is primarily due to the mean vortex track before and after RI.The track oscillations are closely associated with wavenumber-1 vortex Rossby waves that are dominant wavenumber-1 circulations in the TC inner-core region.This study suggests that the dynamics of the wavenumber-1 vortex Rossby waves play an important role in the regulation of the physical processes associated with the track oscillation and vertical alignment of TCs.展开更多
One of the greatest challenges in the agroecosystem is to improve cropland intensification while preserving agroecosystem services.While many studies have investigated the effect of cropland intensification on agroeco...One of the greatest challenges in the agroecosystem is to improve cropland intensification while preserving agroecosystem services.While many studies have investigated the effect of cropland intensification on agroecosystem service,the interactive coupling and coordination among these factors remain largely unexplored.In view of this,this study performed a case study of the Loess Plateau in Shaanxi Province,China and constructed comprehensive evaluation models to quantify the cropland intensification and agroecosystem service in this area.Balance analysis and the coupling coordination degree model were used to evaluate the interactive relationship between cropland intensification and agroecosystem service,and statistical analysis and spatial autocorrelation were used to analyze the spatial characteristics and potential mechanism of the coupling coordination.Results show that both the cropland intensification and agroecosystem service in the study area were relatively low yet gradually increased from 2000 to 2020.Agroecosystem service lag was identified as the dominant unbalanced development type.Improving the supply capacity of agroecosystem services plays a key role in the balanced development of cropland in the Loess Plateau.The coupling coordination degree between cropland intensification and agroecosystem service ranges from basic coordination to serious incoordination.Therefore,cropland intensification practices in the area should be optimized to enhance this coordination degree.An upward trend was also observed in the coupling coordination degree from2000 to 2020.The withdrawal of marginal cropland in the Grain for Green program is one of the most important reasons for this trend,especially for the northern region.Around 83.6%of the high-high clusters are concentrated in the southern region of the Loess Plateau,whereas 70.5%of the low-low clusters are distributed in the northern region.These clustering characteristics are mainly attributed to the environmental suitability of these areas for agriculture and their degree of economic development.展开更多
Upland crop-rice cropping systems(UCR)facilitate sustainable agricultural intensification.Accurate UCR cultivation mapping is needed to ensure food security,sustainable water management,and rural revitalization.Howeve...Upland crop-rice cropping systems(UCR)facilitate sustainable agricultural intensification.Accurate UCR cultivation mapping is needed to ensure food security,sustainable water management,and rural revitalization.However,datasets describing cropping systems are limited in spatial coverage and crop types.Mapping UCR is more challenging than crop identification and most existing approaches rely heavily on accurate phenology calendars and representative training samples,which limits its applications over large regions.We describe a novel algorithm(RRSS)for automatic mapping of upland crop-rice cropping systems using Sentinel-1 Synthetic Aperture Radar(SAR)and Sentinel-2 Multispectral Instrument(MSI)data.One indicator,the VV backscatter range,was proposed to discriminate UCR and another two indicators were designed by coupling greenness and pigment indices to further discriminate tobacco or oilseed UCR.The RRSS algorithm was applied to South China characterized by complex smallholder rice cropping systems and diverse topographic conditions.This study developed 10-m UCR maps of a major rice bowl in South China,the Xiang-Gan-Min(XGM)region.The performance of the RRSS algorithm was validated based on 5197 ground-truth reference sites,with an overall accuracy of 91.92%.There were7348 km^(2) areas of UCR,roughly one-half of them located in plains.The UCR was represented mainly by oilseed-UCR and tobacco-UCR,which contributed respectively 69%and 15%of UCR area.UCR patterns accounted for only one-tenth of rice production,which can be tripled by intensification from single rice cropping.Application to complex and fragmented subtropical regions suggested the spatiotemporal robustness of the RRSS algorithm,which could be further applied to generate 10-m UCR datasets for application at national or global scales.展开更多
The aim of this study is to establish several important factors representing land use intensification in cultivated land （denoted by ClI）, using a multi-dimensional approach to achieve realistic and practical cultiv...The aim of this study is to establish several important factors representing land use intensification in cultivated land （denoted by ClI）, using a multi-dimensional approach to achieve realistic and practical cultivated land use policies in China. For this reason, the theoretical framework was first built to explain the changes of land use intensification in the cultivated land, and then the variables and index were further developed for the purpose of characterizing the dynamic trends and driving forces of the land use intensification in the cultivated land at the provincial level. The study results indicate that the extent of Cll significantly increased during the period of 1996 to 2008, due to the extensive use of fertilizers, machinery and pesticide, increased labor and capital input, and intensified land use. Moreover, the principal component regression results show that the productivity of cultivated land, economic benefits of cultivated land, labor productivity, and land use conversion are the main factors affecting the village development. The first three factors play a positive role, while the last one has a negative effect on the land use intensification in the cultivated land. According to these results, the main policies for sustainable intensification in cultivated land are proposed. First, the sustainable pathways for intensification should be adopted to reduce the unsustainable uses of chemical fertilizer, agricultural chemicals, etc. Second, the conditions for agricultural production should be further improved to increase the cultivated land productivity. Third, it is very necessary and helpful for improving labor productivity and land use efficiency from the viewpoint of accelerated the cultivated land circulation. The last step is to positively affect the production activities of peasants by means of reforming the subsidy standards.展开更多
Sustainable feeding of the growing population in China without ecological destabilization is a grand challenge. In this populous country where agriculture is dominated by smallholder farming, developing innovative tec...Sustainable feeding of the growing population in China without ecological destabilization is a grand challenge. In this populous country where agriculture is dominated by smallholder farming, developing innovative technology and translating scientific knowledge into action for smallholder farmers is a crucial step in addressing this challenge. Here, we present a novel approach for technology innovation and dissemination to achieve sustainable intensification in the fields of smallholder farmers. The Science and Technology Backyard(STB) is a hub in a rural area that links knowledge with practices to promote technology innovation and exchange. In this study, the framework and functions of STB are introduced, and the key implications for sustainable intensification across millions of smallholder farmers are explicitly stated:(i) develop innovative technology based on stated demands of farmers;(ii) disseminate technology by innovative social service models though combined top-down approaches with bottom-up measures to enable smallholders in rural areas. This paper provides a perspective on transformation of small-scale agriculture toward sustainable intensification in China and useful knowledge applicable to other developing countries.展开更多
To investigate the impacts of the diurnal cycle on tropical cyclones （TCs）,a set of idealized simulations were conducted by specifying different radiation （i.e.,nighttime-only,daytime-only,full diurnal cycle）.It w...To investigate the impacts of the diurnal cycle on tropical cyclones （TCs）,a set of idealized simulations were conducted by specifying different radiation （i.e.,nighttime-only,daytime-only,full diurnal cycle）.It was found that,for an initially weak storm,it developed faster during nighttime than daytime.The impacts of radiation were not only on TC intensification,but also on TC structure and size.The nighttime storm tended to have a larger size than its daytime counterparts.During nighttime,the radiative cooling steepened the lapse rate and thus reduced the static stability in cloudy regions,enhancing convection.Diabatic heating associated with outer convection induced boundary layer inflows,which led to outward expansion of tangential winds and thus increased the storm size.展开更多
Reactive distillation(RD) process is an innovative hybrid process combining reaction with distillation, which has recently come into sharp focus as a successful case of process intensification. Considered as the most ...Reactive distillation(RD) process is an innovative hybrid process combining reaction with distillation, which has recently come into sharp focus as a successful case of process intensification. Considered as the most representative case of process intensification, it has been applied for many productions, especially for production of ester compounds. However, such problems existing in the RD system for ester productions are still hard to solve,as the removal of the water which comes from the esterification, and the separation of the azeotropes of ester–alcohol(–water). Many methods have been studying on the process to solve the problems resulting in further intensification and energy saving. In this paper, azeotropic–reactive distillation or entrainer enhanced reactive distillation(ERD) process, reactive extractive distillation(RED) process, the method of co-production in RD process, pressure-swing reactive distillation(PSRD) process, reactive distillation–pervaporation coupled process(RD–PV), are introduced to solve the problems above, so the product(s) can be separated efficiently and the chemical equilibrium can be shifted. Dividing-wall column(DWC) structure and novel methods of loading catalyst are also introduced as the measures to intensify the process and save energy.展开更多
Die casting process is widely applied in making Al parts. However, due to high speed of liquid metal flow in the die cavity, gases are prone to be entrapped in the filling, resulting in porosity defects. The X-ray com...Die casting process is widely applied in making Al parts. However, due to high speed of liquid metal flow in the die cavity, gases are prone to be entrapped in the filling, resulting in porosity defects. The X-ray computed tomography scanning technique was used to detect the pores in die-cast ADC12 alloys with different intensification pressures. The three-dimensional features of pores including pore size, number, sphericity have been obtained. The effect of different intensification pressures on two different kinds of pores, namely gas-pores and shrinkage pores, was analyzed. The results show that with increasing the pressure, the pore fractions and quantity gradually decrease. When the pressure increased to 85 MPa, the pores from gas entrapment during the mold filling were compressed, leading to a lower porosity fraction. The pressure cannot affect the pores in the samples with a thin wall (2 mm) due to a great solidification rate.展开更多
In this study, the dependence of tropical cyclone （TC） development on the inner-core structure of the parent vortex is examined using a pair of idealized numerical simulations. It is found that the radial profile of...In this study, the dependence of tropical cyclone （TC） development on the inner-core structure of the parent vortex is examined using a pair of idealized numerical simulations. It is found that the radial profile of inner-core relative vorticity may have a great impact on its subsequent development. For a system with a larger inner-core relative vorticity/inertial stability, the conversion ratio of the diabatic heating to kinetic energy is greater. Furthermore, the behavior of the convective vorticity eddies is likely modulated by the system-scale circulation. For a parent vortex with a relatively higher inner-core vorticity and larger negative radial vorticity gradient, convective eddy formation and radially inward propagation is promoted through vorticity segregation. This provides a greater potential for these small-scale convective cells to self-organize into a mesoscale inner-core structure in the TC. In turn, convectively induced diabatic heating that is close to the center, along with higher inertial stability, efficiently enhances system-scale secondary circulation. This study provides a solid basis for further research into how the initial structure of a TC influences storm dynamics and thermodynamics.展开更多
Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications ...Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C—OH, C O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) was identified as pseudo-second-order kinetics. The rate constants of adsorption were evaluated.展开更多
Intensification in rice crop production is generally understood as requiring increased use of material inputs: water, inorganic fertilizers, and agrochemicals. However, this is not the only kind of intensification ava...Intensification in rice crop production is generally understood as requiring increased use of material inputs: water, inorganic fertilizers, and agrochemicals. However, this is not the only kind of intensification available. More productive crop phenotypes, with traits such as more resistance to biotic and abiotic stresses and shorter crop cycles, are possible through modifications in the management of rice plants, soil, water, and nutrients, reducing rather than increasing material inputs. Greater factor productivity can be achieved through the application of new knowledge and more skill, and(initially) more labor, as seen from the System of Rice Intensification(SRI), whose practices are used in various combinations by as many as 10 million farmers on about 4 million hectares in over 50 countries. The highest yields achieved with these management methods have come from hybrids and improved rice varieties, confirming the importance of making genetic improvements. However,unimproved varieties are also responsive to these changes, which induce better growth and functioning of rice root systems and more abundance, diversity, and activity of beneficial soil organisms. Some of these organisms as symbiotic endophytes can affect and enhance the expression of rice plants' genetic potential as well as their phenotypic resilience to multiple stresses, including those of climate change. SRI experience and data suggest that decades of plant breeding have been selecting for the best crop genetic endowments under suboptimal growing conditions, with crowding of plants that impedes their photosynthesis and growth, flooding of rice paddies that causes roots to degenerate and forgoes benefits derived from aerobic soil organisms, and overuse of agrochemicals that adversely affect these organisms as well as soil and human health. This review paper reports evidence from research in India and Indonesia that changes in crop and water management can improve the expression of rice plants' genetic potential, thereby creating more productive and robustphenotypes from given rice genotypes. Data indicate that increased plant density does not necessarily enhance crop yield potential, as classical breeding methods suggest. Developing cultivars that can achieve their higher productivity under a wide range of plant densities—breeding for density-neutral cultivars using alternative selection strategies—will enable more effective exploitation of available crop growth resources. Density-neutral cultivars that achieve high productivity under ample environmental growth resources can also achieve optimal productivity under limited resources, where lower densities can avert crop failure due to overcrowding. This will become more important to the extent that climatic and other factors become more adverse to crop production. Focusing more on which management practices can evoke the most productive and robust phenotypes from given genotypes is important for rice breeding and improvement programs since it is phenotypes that feed our human populations.展开更多
Using the biogeochemical model den itrification/decomposition （DN DC）, the dynamic changes of soil organic carbon （SOC） of farmland from the 1980s to 2030s were investigated in Huantai County, a typical intensive ...Using the biogeochemical model den itrification/decomposition （DN DC）, the dynamic changes of soil organic carbon （SOC） of farmland from the 1980s to 2030s were investigated in Huantai County, a typical intensive agricultural region in the Huang- Huai-Hai Plain of China. Prior to modelling, validation of the DNDC model against field data sets of SOC from Quzhou Experimental Station in the Huang-Huai-Hai Plain was conducted at the site scale. We compared the simulated results with the observed SOC in Huantai County during 1982-2011 under two different classification methods of simulation unit （the first method integrated soil type and land use of Huantai County to form the overlapped modeling units; the second selected the 11 administrative towns as the modeling units）, and achieved a high accuracy in the model simulation with the improvement of the model parameters. Regional SOC （0-20 cm） density and stocks for Huantai County in the years 2012-2031 were predicted under different scenarios of farming management. Compared with current management practices, optimized fertilization （20% decrease of mineral N）, crop straw incorporation （90%） and appropriate animal manure input （40 kg N ha-1 yr-1） could achieve the highest level of SOC density （56.8% higher than 2011） in the period of 2012-2031. The research highlighted the importance of crop straw incorporation, optimized N fertilization and integration of crop production with ani- mal husbandry on the farmland carbon sequestration for maintaining a high land productivity in the Huang-Huai-Hai Plain.展开更多
Diagnostics are presented from an ensemble of high-resolution forecasts that differed markedly in their predictions of the rapid intensification(RI)of Typhoon Rammasun.We show that the basic difference stems from subt...Diagnostics are presented from an ensemble of high-resolution forecasts that differed markedly in their predictions of the rapid intensification(RI)of Typhoon Rammasun.We show that the basic difference stems from subtle differences in initializations of(a)500-850-h Pa environmental winds,and(b)midlevel moisture and ventilation.We then describe how these differences impact on the evolving convective organization,storm structure,and the timing of RI.As expected,ascent,diabatic heating and the secondary circulation near the inner-core are much stronger in the member that best forecasts the RI.The evolution of vortex cloudiness from this member is similar to the actual imagery,with the development of an inner cloud band wrapping inwards to form the eyewall.We present evidence that this structure,and hence the enhanced diabatic heating,is related to the tilt and associated dynamics of the developing inner-core in shear.For the most accurate ensemble member:(a)inhibition of ascent and a reduction in convection over the up-shear sector allow moistening of the boundary-layer air,which is transported to the down-shear sector to feed a developing convective asymmetry;(b)with minimal ventilation,undiluted clouds and moisture from the down-shear left quadrant are then wrapped inwards to the up-shear left quadrant to form the eyewall cloud;and(c)this process seems related to a critical down-shear tilt of the vortex from midlevels,and the vertical phase-locking of the circulation over up-shear quadrants.For the member that forecasts a much-delayed RI,these processes are inhibited by stronger vertical wind shear,initially resulting in poor vertical coherence of the circulation,lesser moisture and larger ventilation.Our analysis suggests that ensemble prediction is needed to account for the sensitivity of forecasts to a relatively narrow range of environmental wind shear,moisture and vortex inner-structure.展开更多
Fluidized beds enable good solids mixing,high rates of heat and mass transfer,and large throughputs,but there remain issues related to fluidization quality and scale-up.In this work I review modification techniques fo...Fluidized beds enable good solids mixing,high rates of heat and mass transfer,and large throughputs,but there remain issues related to fluidization quality and scale-up.In this work I review modification techniques for fluidized beds from the perspective of the principles of process intensification(PI),that is,effective bubbling suppression and elutriation control.These techniques are further refined into(1)design factors,e.g.modifying the bed configuration,or the application of internal and external forces,and(2)operational factors,including altering the particle properties(e.g.size,density,surface area)and fluidizing gas properties(e.g.density,viscosity,or velocity).As far as two proposed PI principles are concerned,our review suggests that it ought to be possible to gain improvements of between 2 and 4 times over conventional fluidized bed designs by the application of these techniques.展开更多
基金supported by the National Natural Science Foundation of China(22288102,22035007,and 22122815)。
文摘The mixing process plays a pivotal role in the design,optimization,and scale-up of chemical reactors.For most chemical reactions,achieving uniform and rapid contact between reactants at the molecular level is crucial.Mixing intensification encompasses innovative methods and tools that address the limitations of inadequate mixing within reactors,enabling efficient reaction scaling and boosting the productivity of industrial processes.This review provides a concise introduction to the fundamentals of multiphase mixing,followed by case studies highlighting the application of mixing intensification in the production of energy-storage materials,advanced optical materials,and nanopesticides.These examples illustrate the significance of theoretical analysis in informing and advancing engineering practices within the chemical industry.We also explore the challenges and opportunities in this field,offering insights based on our current understanding.
基金supported by the National Natural Science Foundation of China[grant numbers 42192553 and 41922036]the Fundamental Research Funds for the Central Universities–Cemac“GeoX”Interdisciplinary Program[grant number 020714380207]。
文摘While steady improvements have been achieved for the track forecasts of typhoons,there has been a lack of improvement for intensity forecasts.One challenge for intensity forecasts is to capture the rapid intensification(RI),whose nonlinear characteristics impose great difficulties for numerical models.The ensemble sensitivity analysis(ESA)method is used here to analyze the initial conditions that contribute to typhoon intensity forecasts,especially with RI.Six RI processes from five typhoons(Chaba,Haima,Meranti,Sarika,and Songda)in 2016,are applied with ESA,which also gives a composite initial condition that favors subsequent RI.Results from individual cases have generally similar patterns of ESA,but with different magnitudes,when various cumulus parameterization schemes are applied.To draw the initial conditions with statistical significance,sample-mean azimuthal components of ESA are obtained.Results of the composite sensitivity show that typhoons that experience RI in 24 h favor enhanced primary circulation from low to high levels,intensified secondary circulation with increased radial inflow at lower levels and increased radial outflow at upper levels,a prominent warm core at around 300 hPa,and increased humidity at low levels.As the forecast lead time increases,the patterns of ESA are retained,while the sensitivity magnitudes decay.Given the general and quantitative composite sensitivity along with associated uncertainties for different cumulus parameterization schemes,appropriate sampling of the composite sensitivity in numerical models could be beneficial to capturing the RI and improving the forecasting of typhoon intensity.
基金Guangdong Major Project of Basic and Applied Basic Research(2020B0301030004)National Natural Science Foundation of China(41875114)Science and Technology Commission of Shanghai Municipality,China(23DZ1204703)。
文摘The rapid intensification(RI)magnitude of tropical cyclones(TCs)over the western North Pacific(WNP)exhibits significant interannual variability and is influenced by multiple factors across various scales.These factors primarily include:interannual factors—sea surface temperature(SST)in key regions of the WNP,eastern Indian Ocean SST,El Niño-Southern Oscillation(ENSO),South Pacific Subtropical Dipole(SPSD),and western Pacific teleconnection;decadal factors—Atlantic Multidecadal Oscillation(AMO)and Pacific Decadal Oscillation(PDO);and longer-term factor—global warming.This study systematically analyzes these factors and their potential impacts,quantitatively assessing their relative importance.A statistical prediction model for the WNP TC-RI magnitude is developed based on ridge regression methods.The results indicate that the influence of these factors on the RI magnitude is closely related to the large-scale thermodynamic and dynamic conditions.Among them,the SPSD plays the most critical role in the interannual variability of the RI magnitude,followed by global warming and the AMO.Further analysis reveals that the statistical prediction model based on multiple factors demonstrates good predictive skill for the interannual variability of the TC RI magnitude.
基金sponsored by the funding of the National Natural Science Foundation of China(Grant Nos.42075011,42192552,42005025,and 42075035).
文摘The synoptic process of a super Arctic cyclone in August 2016(AC16)is investigated based on the Weather Research and Forecasting(WRF)model,and the key factors affecting the rapid intensification(RI)of AC16 and their relative contributions are analyzed by diagnosing a new surface pressure tendency equation(SPTE).The major physical mechanisms behind the two RI stages of AC16 are revealed.The trajectory,intensity changes,and structural characteristics of AC16 are well simulated by the WRF model.A diagnosis based on the SPTE promisingly reproduces the two RI stages of AC16.The leading factor that influenced the intensity of AC16 was identified to be the air-column potential temperature tendency,while the pressure change at the upper boundary had less of an impact.Further analysis reveals that the horizontal potential temperature advection was the decisive factor in a warming of the air column.Specifically,the upper-level warm advection generated by the strong wind field of the upper-level jet played a dominant role in warming the air column,which caused the initial RI of AC16.The AC16 movement into a strong potential temperature gradient generated by tropopause polar vortices increased the upper-level warm advection,which warmed the air column and thereby induced the second RI of AC16.However,the net effect of vertical potential temperature advection and latent heating,as well as radiation processes,caused a cooling of the air column and thereby negatively contributed to the RI of AC16.
基金Under the auspices of National Natural Science Foundation of China(No.42071226,41671176)Taishan Scholars Youth Expert Support Plan of Shandong Province(No.TSQN202306183)。
文摘Sustainable intensification of cultivated land use(SICLU) and large-scale operations(LSO) are widely acknowledged strategies for enhancing agricultural performance.However,the existing literature has faced challenges in precisely defining SICLU and constructing comprehensive indicators,which has hindered the exploration of factors influencing LSO within the SICLU framework.To address this gap,we integrated self-efficacy theory into the design of an index framework for evaluating SICLU.We subsequently employed econometric models to analyze the significant factors that impact LSO.Our findings reveal that SICLU can be divided into four key dimensions:intensive management,efficient output,resource conservation,and ecological environment optimization.Furthermore,it is crucial to incorporate belief-based cognitive factors into the index system,as farmers’ understanding of fertilizer and pesticide application significantly influences their willingness to engage in LSO.Moreover,we identify grain market turnover as the most influential factor in promoting LSO,with single-factor contribution rates reaching 70.9% for cultivated land transfer willingness and 62.5% for the total planting areas.Interestingly,unlike irrigation and agricultural machinery inputs,increased labor inputs correspond to larger planting areas for farmers.This trend may be attributed to reduced labor availability because of rural labor migration,whereas the reduction in irrigation and agricultural input is contingent on innovations in production practices and the transfer of cultivated land management rights.Importantly,SICLU dynamically influences LSO,with each index related to SICLU having an optimal range that fosters LSO.These insights offer valuable guidance for policymakers,emphasizing farmers as their central focus,with the adjustment of input and output factors as a means to achieve LSO as the ultimate goal.In conclusion,we propose research avenues for further enriching the SICLU framework to ensure that it aligns with the specific characteristics of regional agricultural development.
基金supported by the National Natural Science Foundation of China (Grant No.41730960)Wuxi University Research Start-up Fund for Introduced Talents (2024r037)Yuqing WANG was supported by the NSF (Grant No. AGS-1834300)。
文摘Recent observational and numerical studies have revealed the dependence of the intensification rate on the inner-core size of tropical cyclones(TCs). In this study, with the initial inner-core size(i.e., the radius of maximum wind—RMW)varied from 20–180 km in idealized simulations using two different numerical models, we found a nonmonotonic dependence of the lifetime maximum intensification rate(LMIR) on the inner-core size. Namely, there is an optimal innercore size for the LMIR of a TC. Tangential wind budget analysis shows that, compared to large TCs, small TCs have large inward flux of absolute vorticity due to large absolute vorticity inside the RMW. However, small TCs also suffer from strong lateral diffusion across the eyewall, which partly offsets the positive contribution from large inward flux of absolute vorticity. These two competing processes ultimately lead to the TC with an intermediate initial inner-core size having the largest LMIR. Results from sensitivity experiments show that the optimal size varies in the range of 40–120 km and increases with higher sea surface temperature, lower latitude, larger horizontal mixing length, and weaker initial TC intensity. The 40–120 km RMW corresponds to the inner-core size most commonly found for intensifying TCs in observations, suggesting the natural selection of initial TC size for intensification. This study highlights the importance of accurate representation of TC inner-core size to TC intensity forecasts by numerical weather prediction models.
基金National Natural Science Foundation of China(Grant Nos:42150710531,42192551,61827901)supported this study.
文摘Recent studies on tropical cyclone(TC)intensity change indicate that the development of a vertically aligned TC circulation is a key feature of its rapid intensification(RI),however,understanding how vortex alignment occurs remains a challenging topic in TC intensity change research.Based on the simulation outputs of North Atlantic Hurricane Wilma(2005)and western North Pacific Typhoon Rammasun(2014),vortex track oscillations at different vertical levels and their associated role in vortex alignment are examined to improve our understanding of the vortex alignment during RI of TCs with initial hurricane intensity.It is found that vortex tracks at different vertical levels oscillate consistently in speed and direction during the RI of the two simulated TCs.While the consistent track oscillation reduces the oscillation tilt during RI,the reduction of vortex tilt results mainly from the mean track before RI.It is also found that the vortex tilt is primarily due to the mean vortex track before and after RI.The track oscillations are closely associated with wavenumber-1 vortex Rossby waves that are dominant wavenumber-1 circulations in the TC inner-core region.This study suggests that the dynamics of the wavenumber-1 vortex Rossby waves play an important role in the regulation of the physical processes associated with the track oscillation and vertical alignment of TCs.
基金Under the auspices of the National Natural Science Foundation of China(No.41901262)Natural Science Basic Research Program of Shaanxi(No.2024JC-YBQN-0300)Fundamental Research Funds for the Central Universities(No.GK202103125,GK202207005)。
文摘One of the greatest challenges in the agroecosystem is to improve cropland intensification while preserving agroecosystem services.While many studies have investigated the effect of cropland intensification on agroecosystem service,the interactive coupling and coordination among these factors remain largely unexplored.In view of this,this study performed a case study of the Loess Plateau in Shaanxi Province,China and constructed comprehensive evaluation models to quantify the cropland intensification and agroecosystem service in this area.Balance analysis and the coupling coordination degree model were used to evaluate the interactive relationship between cropland intensification and agroecosystem service,and statistical analysis and spatial autocorrelation were used to analyze the spatial characteristics and potential mechanism of the coupling coordination.Results show that both the cropland intensification and agroecosystem service in the study area were relatively low yet gradually increased from 2000 to 2020.Agroecosystem service lag was identified as the dominant unbalanced development type.Improving the supply capacity of agroecosystem services plays a key role in the balanced development of cropland in the Loess Plateau.The coupling coordination degree between cropland intensification and agroecosystem service ranges from basic coordination to serious incoordination.Therefore,cropland intensification practices in the area should be optimized to enhance this coordination degree.An upward trend was also observed in the coupling coordination degree from2000 to 2020.The withdrawal of marginal cropland in the Grain for Green program is one of the most important reasons for this trend,especially for the northern region.Around 83.6%of the high-high clusters are concentrated in the southern region of the Loess Plateau,whereas 70.5%of the low-low clusters are distributed in the northern region.These clustering characteristics are mainly attributed to the environmental suitability of these areas for agriculture and their degree of economic development.
基金supported by the National Natural Science Foundation of China(42171325,41771468)the National Key Research and Development Program of China(2022YFD2001101)+1 种基金the Science Bureau of Fujian Province(2023Y0042)the Finance Department and the Digital Economy Alliance of Fujian Province。
文摘Upland crop-rice cropping systems(UCR)facilitate sustainable agricultural intensification.Accurate UCR cultivation mapping is needed to ensure food security,sustainable water management,and rural revitalization.However,datasets describing cropping systems are limited in spatial coverage and crop types.Mapping UCR is more challenging than crop identification and most existing approaches rely heavily on accurate phenology calendars and representative training samples,which limits its applications over large regions.We describe a novel algorithm(RRSS)for automatic mapping of upland crop-rice cropping systems using Sentinel-1 Synthetic Aperture Radar(SAR)and Sentinel-2 Multispectral Instrument(MSI)data.One indicator,the VV backscatter range,was proposed to discriminate UCR and another two indicators were designed by coupling greenness and pigment indices to further discriminate tobacco or oilseed UCR.The RRSS algorithm was applied to South China characterized by complex smallholder rice cropping systems and diverse topographic conditions.This study developed 10-m UCR maps of a major rice bowl in South China,the Xiang-Gan-Min(XGM)region.The performance of the RRSS algorithm was validated based on 5197 ground-truth reference sites,with an overall accuracy of 91.92%.There were7348 km^(2) areas of UCR,roughly one-half of them located in plains.The UCR was represented mainly by oilseed-UCR and tobacco-UCR,which contributed respectively 69%and 15%of UCR area.UCR patterns accounted for only one-tenth of rice production,which can be tripled by intensification from single rice cropping.Application to complex and fragmented subtropical regions suggested the spatiotemporal robustness of the RRSS algorithm,which could be further applied to generate 10-m UCR datasets for application at national or global scales.
基金National Natural Science Foundation of China, No.41401203, No.41130748 Central Research Institutes of Basic Research and Public Service Special Operations, No.005201400127
文摘The aim of this study is to establish several important factors representing land use intensification in cultivated land （denoted by ClI）, using a multi-dimensional approach to achieve realistic and practical cultivated land use policies in China. For this reason, the theoretical framework was first built to explain the changes of land use intensification in the cultivated land, and then the variables and index were further developed for the purpose of characterizing the dynamic trends and driving forces of the land use intensification in the cultivated land at the provincial level. The study results indicate that the extent of Cll significantly increased during the period of 1996 to 2008, due to the extensive use of fertilizers, machinery and pesticide, increased labor and capital input, and intensified land use. Moreover, the principal component regression results show that the productivity of cultivated land, economic benefits of cultivated land, labor productivity, and land use conversion are the main factors affecting the village development. The first three factors play a positive role, while the last one has a negative effect on the land use intensification in the cultivated land. According to these results, the main policies for sustainable intensification in cultivated land are proposed. First, the sustainable pathways for intensification should be adopted to reduce the unsustainable uses of chemical fertilizer, agricultural chemicals, etc. Second, the conditions for agricultural production should be further improved to increase the cultivated land productivity. Third, it is very necessary and helpful for improving labor productivity and land use efficiency from the viewpoint of accelerated the cultivated land circulation. The last step is to positively affect the production activities of peasants by means of reforming the subsidy standards.
基金supported by the National Basic Research Program of China (2015CB150405)
文摘Sustainable feeding of the growing population in China without ecological destabilization is a grand challenge. In this populous country where agriculture is dominated by smallholder farming, developing innovative technology and translating scientific knowledge into action for smallholder farmers is a crucial step in addressing this challenge. Here, we present a novel approach for technology innovation and dissemination to achieve sustainable intensification in the fields of smallholder farmers. The Science and Technology Backyard(STB) is a hub in a rural area that links knowledge with practices to promote technology innovation and exchange. In this study, the framework and functions of STB are introduced, and the key implications for sustainable intensification across millions of smallholder farmers are explicitly stated:(i) develop innovative technology based on stated demands of farmers;(ii) disseminate technology by innovative social service models though combined top-down approaches with bottom-up measures to enable smallholders in rural areas. This paper provides a perspective on transformation of small-scale agriculture toward sustainable intensification in China and useful knowledge applicable to other developing countries.
基金sponsored by the National Natural Science Foundation of China (Grant Nos. 41275095, 41075037)the National Key Basic Research Program of China (Grant No.2012CB955204)the Key University Science Research Project of Jiangsu Province (Grant No.14KJA170005)
文摘To investigate the impacts of the diurnal cycle on tropical cyclones （TCs）,a set of idealized simulations were conducted by specifying different radiation （i.e.,nighttime-only,daytime-only,full diurnal cycle）.It was found that,for an initially weak storm,it developed faster during nighttime than daytime.The impacts of radiation were not only on TC intensification,but also on TC structure and size.The nighttime storm tended to have a larger size than its daytime counterparts.During nighttime,the radiative cooling steepened the lapse rate and thus reduced the static stability in cloudy regions,enhancing convection.Diabatic heating associated with outer convection induced boundary layer inflows,which led to outward expansion of tangential winds and thus increased the storm size.
基金Supported by the National Key Research and Development Program of China(2017YFB0602500)the Basic Research Program of Hebei Province(16964502D)
文摘Reactive distillation(RD) process is an innovative hybrid process combining reaction with distillation, which has recently come into sharp focus as a successful case of process intensification. Considered as the most representative case of process intensification, it has been applied for many productions, especially for production of ester compounds. However, such problems existing in the RD system for ester productions are still hard to solve,as the removal of the water which comes from the esterification, and the separation of the azeotropes of ester–alcohol(–water). Many methods have been studying on the process to solve the problems resulting in further intensification and energy saving. In this paper, azeotropic–reactive distillation or entrainer enhanced reactive distillation(ERD) process, reactive extractive distillation(RED) process, the method of co-production in RD process, pressure-swing reactive distillation(PSRD) process, reactive distillation–pervaporation coupled process(RD–PV), are introduced to solve the problems above, so the product(s) can be separated efficiently and the chemical equilibrium can be shifted. Dividing-wall column(DWC) structure and novel methods of loading catalyst are also introduced as the measures to intensify the process and save energy.
基金financially supported by the Industry Base Enhanced Project(TC160A310-10-01),China
文摘Die casting process is widely applied in making Al parts. However, due to high speed of liquid metal flow in the die cavity, gases are prone to be entrapped in the filling, resulting in porosity defects. The X-ray computed tomography scanning technique was used to detect the pores in die-cast ADC12 alloys with different intensification pressures. The three-dimensional features of pores including pore size, number, sphericity have been obtained. The effect of different intensification pressures on two different kinds of pores, namely gas-pores and shrinkage pores, was analyzed. The results show that with increasing the pressure, the pore fractions and quantity gradually decrease. When the pressure increased to 85 MPa, the pores from gas entrapment during the mold filling were compressed, leading to a lower porosity fraction. The pressure cannot affect the pores in the samples with a thin wall (2 mm) due to a great solidification rate.
基金sponsored by the National Key Basic Research Program of China (Grant No.2015CB452803)the State Key Laboratory of Severe Weather,Chinese Academy of Meteorological Sciences (Grant No.2014LASW-B08)+1 种基金the "six peaks of high-level talents" funding projectthe Key University Science Research Project of Jiangsu Province (Grant No.14KJA170005)
文摘In this study, the dependence of tropical cyclone （TC） development on the inner-core structure of the parent vortex is examined using a pair of idealized numerical simulations. It is found that the radial profile of inner-core relative vorticity may have a great impact on its subsequent development. For a system with a larger inner-core relative vorticity/inertial stability, the conversion ratio of the diabatic heating to kinetic energy is greater. Furthermore, the behavior of the convective vorticity eddies is likely modulated by the system-scale circulation. For a parent vortex with a relatively higher inner-core vorticity and larger negative radial vorticity gradient, convective eddy formation and radially inward propagation is promoted through vorticity segregation. This provides a greater potential for these small-scale convective cells to self-organize into a mesoscale inner-core structure in the TC. In turn, convectively induced diabatic heating that is close to the center, along with higher inertial stability, efficiently enhances system-scale secondary circulation. This study provides a solid basis for further research into how the initial structure of a TC influences storm dynamics and thermodynamics.
文摘Pyrolysis has the potential of transforming waste into valuable recyclable products. Pyrolytic char(PC) is one of the most important products from the pyrolysis of used tires. One of the most significant applications for pyrolytic char recovered is used for the removal of Cr(Ⅵ) in the wastewater effluent to control waste by waste. The surface chemistry properties of surface element distribution / concentration and chemical structure were examined for the pyrolytic char and the commercial activated carbon(CAC) respectively. The results showed that surfaces of PC possesses a large amount of ester and hydrocarbon graft, whereas there are mainly carbon functional components of C—OH, C O and COOH on the surface of CAC. Therefore the surface electronegativity of PC is lower than that of CAC in the water. The repulsive interactions between the surfaces of PC and the negatively charged Cr(Ⅵ) ion are weaker than that of CAC, which results in an intensification of the adsorption process by the utilization of PC. The adsorption isotherms of Cr(Ⅵ) ion on the two kinds of carbons were determined experimentally. The larger adsorption amount on the PC in the case of Cr(Ⅵ) may be attributed mainly to its special surface micro-chemical environment. The mechanism of the removal Cr(Ⅵ) from aqueous solution was assumed to be the integration of adsorption and redox reaction. The adsorption was the rate-controlled step for Cr(Ⅵ) removal. The adsorption of Cr(Ⅵ) was identified as pseudo-second-order kinetics. The rate constants of adsorption were evaluated.
文摘Intensification in rice crop production is generally understood as requiring increased use of material inputs: water, inorganic fertilizers, and agrochemicals. However, this is not the only kind of intensification available. More productive crop phenotypes, with traits such as more resistance to biotic and abiotic stresses and shorter crop cycles, are possible through modifications in the management of rice plants, soil, water, and nutrients, reducing rather than increasing material inputs. Greater factor productivity can be achieved through the application of new knowledge and more skill, and(initially) more labor, as seen from the System of Rice Intensification(SRI), whose practices are used in various combinations by as many as 10 million farmers on about 4 million hectares in over 50 countries. The highest yields achieved with these management methods have come from hybrids and improved rice varieties, confirming the importance of making genetic improvements. However,unimproved varieties are also responsive to these changes, which induce better growth and functioning of rice root systems and more abundance, diversity, and activity of beneficial soil organisms. Some of these organisms as symbiotic endophytes can affect and enhance the expression of rice plants' genetic potential as well as their phenotypic resilience to multiple stresses, including those of climate change. SRI experience and data suggest that decades of plant breeding have been selecting for the best crop genetic endowments under suboptimal growing conditions, with crowding of plants that impedes their photosynthesis and growth, flooding of rice paddies that causes roots to degenerate and forgoes benefits derived from aerobic soil organisms, and overuse of agrochemicals that adversely affect these organisms as well as soil and human health. This review paper reports evidence from research in India and Indonesia that changes in crop and water management can improve the expression of rice plants' genetic potential, thereby creating more productive and robustphenotypes from given rice genotypes. Data indicate that increased plant density does not necessarily enhance crop yield potential, as classical breeding methods suggest. Developing cultivars that can achieve their higher productivity under a wide range of plant densities—breeding for density-neutral cultivars using alternative selection strategies—will enable more effective exploitation of available crop growth resources. Density-neutral cultivars that achieve high productivity under ample environmental growth resources can also achieve optimal productivity under limited resources, where lower densities can avert crop failure due to overcrowding. This will become more important to the extent that climatic and other factors become more adverse to crop production. Focusing more on which management practices can evoke the most productive and robust phenotypes from given genotypes is important for rice breeding and improvement programs since it is phenotypes that feed our human populations.
基金financially supported by the Non-profit Research Foundation for Agriculture, China (201103039)the National Natural Science Foundation of China (31261140367 and 31370527)
文摘Using the biogeochemical model den itrification/decomposition （DN DC）, the dynamic changes of soil organic carbon （SOC） of farmland from the 1980s to 2030s were investigated in Huantai County, a typical intensive agricultural region in the Huang- Huai-Hai Plain of China. Prior to modelling, validation of the DNDC model against field data sets of SOC from Quzhou Experimental Station in the Huang-Huai-Hai Plain was conducted at the site scale. We compared the simulated results with the observed SOC in Huantai County during 1982-2011 under two different classification methods of simulation unit （the first method integrated soil type and land use of Huantai County to form the overlapped modeling units; the second selected the 11 administrative towns as the modeling units）, and achieved a high accuracy in the model simulation with the improvement of the model parameters. Regional SOC （0-20 cm） density and stocks for Huantai County in the years 2012-2031 were predicted under different scenarios of farming management. Compared with current management practices, optimized fertilization （20% decrease of mineral N）, crop straw incorporation （90%） and appropriate animal manure input （40 kg N ha-1 yr-1） could achieve the highest level of SOC density （56.8% higher than 2011） in the period of 2012-2031. The research highlighted the importance of crop straw incorporation, optimized N fertilization and integration of crop production with ani- mal husbandry on the farmland carbon sequestration for maintaining a high land productivity in the Huang-Huai-Hai Plain.
基金partially supported by the National Natural Science Foundation of China (Grant Nos. 41365005, 41765007 and 41705038)the Hainan Key Cooperation Program (Grant No. ZDYF2019213)the Natural Science Foundation of Hainan Province of China (Grant No. 417298)
文摘Diagnostics are presented from an ensemble of high-resolution forecasts that differed markedly in their predictions of the rapid intensification(RI)of Typhoon Rammasun.We show that the basic difference stems from subtle differences in initializations of(a)500-850-h Pa environmental winds,and(b)midlevel moisture and ventilation.We then describe how these differences impact on the evolving convective organization,storm structure,and the timing of RI.As expected,ascent,diabatic heating and the secondary circulation near the inner-core are much stronger in the member that best forecasts the RI.The evolution of vortex cloudiness from this member is similar to the actual imagery,with the development of an inner cloud band wrapping inwards to form the eyewall.We present evidence that this structure,and hence the enhanced diabatic heating,is related to the tilt and associated dynamics of the developing inner-core in shear.For the most accurate ensemble member:(a)inhibition of ascent and a reduction in convection over the up-shear sector allow moistening of the boundary-layer air,which is transported to the down-shear sector to feed a developing convective asymmetry;(b)with minimal ventilation,undiluted clouds and moisture from the down-shear left quadrant are then wrapped inwards to the up-shear left quadrant to form the eyewall cloud;and(c)this process seems related to a critical down-shear tilt of the vortex from midlevels,and the vertical phase-locking of the circulation over up-shear quadrants.For the member that forecasts a much-delayed RI,these processes are inhibited by stronger vertical wind shear,initially resulting in poor vertical coherence of the circulation,lesser moisture and larger ventilation.Our analysis suggests that ensemble prediction is needed to account for the sensitivity of forecasts to a relatively narrow range of environmental wind shear,moisture and vortex inner-structure.
文摘Fluidized beds enable good solids mixing,high rates of heat and mass transfer,and large throughputs,but there remain issues related to fluidization quality and scale-up.In this work I review modification techniques for fluidized beds from the perspective of the principles of process intensification(PI),that is,effective bubbling suppression and elutriation control.These techniques are further refined into(1)design factors,e.g.modifying the bed configuration,or the application of internal and external forces,and(2)operational factors,including altering the particle properties(e.g.size,density,surface area)and fluidizing gas properties(e.g.density,viscosity,or velocity).As far as two proposed PI principles are concerned,our review suggests that it ought to be possible to gain improvements of between 2 and 4 times over conventional fluidized bed designs by the application of these techniques.
