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Ferromagnetic coupling between 4f-and delocalizedπ-radical spins in mixed(phthalocyaninato)(porphyrinato)rare earth double-decker SMMs
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作者 Liguo Yang Xin Wang +5 位作者 Mengliang Zhu Tongtong Xiao Zhongwen Ouyang Yongzhong Bian Zhenxing Wang Jianzhuang Jian 《Inorganic Chemistry Frontiers》 2019年第8期2142-2147,共6页
Mixed(phthalocyaninato)(porphyrinato)rare earth double-decker complexes M^(III)(Pc)(TNP)(M=Tb(1),Dy(2),and Y(3);Pc=phthalocyaninate;TNP=tetranaphthylporphyrinate)were synthesized and characterized by elemental analysi... Mixed(phthalocyaninato)(porphyrinato)rare earth double-decker complexes M^(III)(Pc)(TNP)(M=Tb(1),Dy(2),and Y(3);Pc=phthalocyaninate;TNP=tetranaphthylporphyrinate)were synthesized and characterized by elemental analysis and a range of spectroscopic methods.They represent the first examples of double-decker rare earth complexes containing a tetranaphthylporphyrin ligand. 展开更多
关键词 phthalocyaninato porphyrinato ferromagnetic coupling spectroscopic methodsthey tetranaphthylporphyrin ligand rare earth rare earth double decker complexes elemental analysis
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