Mixed(phthalocyaninato)(porphyrinato)rare earth double-decker complexes M^(III)(Pc)(TNP)(M=Tb(1),Dy(2),and Y(3);Pc=phthalocyaninate;TNP=tetranaphthylporphyrinate)were synthesized and characterized by elemental analysi...Mixed(phthalocyaninato)(porphyrinato)rare earth double-decker complexes M^(III)(Pc)(TNP)(M=Tb(1),Dy(2),and Y(3);Pc=phthalocyaninate;TNP=tetranaphthylporphyrinate)were synthesized and characterized by elemental analysis and a range of spectroscopic methods.They represent the first examples of double-decker rare earth complexes containing a tetranaphthylporphyrin ligand.展开更多
基金the Anyang Key Laboratory for Chemical Biosensing(21302003)the Natural Science Foundation of China(21471015,21631003,and 21701046)the Fundamental Research Funds for the Central Universities(FRF-BD-17-016A)is gratefully acknowledged.
文摘Mixed(phthalocyaninato)(porphyrinato)rare earth double-decker complexes M^(III)(Pc)(TNP)(M=Tb(1),Dy(2),and Y(3);Pc=phthalocyaninate;TNP=tetranaphthylporphyrinate)were synthesized and characterized by elemental analysis and a range of spectroscopic methods.They represent the first examples of double-decker rare earth complexes containing a tetranaphthylporphyrin ligand.