Titanium in different amounts has been successfully doped into the zirconium-based metal–organic framework UiO-66 via an in situ synthesis method,resulting in a series of hybrid UiO-66-nTi MOFs.These materials mainta...Titanium in different amounts has been successfully doped into the zirconium-based metal–organic framework UiO-66 via an in situ synthesis method,resulting in a series of hybrid UiO-66-nTi MOFs.These materials maintain a relatively high crystallinity and excellent structural stability.The addition of titanium has a significant effect on the crystal size and morphology of UiO-66.The UiO-66-nTi MOFs exhibit a sphere-like crystal morphology with a smaller crystal size and a rougher surface compared to the octahedral UiO-66 crystals.展开更多
基金supported by the State Key Program of National Natural Science Foundation of China(grant no.21236008)the Fundamental Research Funds for the Central Universities(2342013DUT13RC(3)704).
文摘Titanium in different amounts has been successfully doped into the zirconium-based metal–organic framework UiO-66 via an in situ synthesis method,resulting in a series of hybrid UiO-66-nTi MOFs.These materials maintain a relatively high crystallinity and excellent structural stability.The addition of titanium has a significant effect on the crystal size and morphology of UiO-66.The UiO-66-nTi MOFs exhibit a sphere-like crystal morphology with a smaller crystal size and a rougher surface compared to the octahedral UiO-66 crystals.