Two isostructural 3D complexes[Mn(L)(N_(3))·MeOH]_(n)(1)and[Mn(L)(HCO_(2))·MeOH]n(2)(HL=pyrazine-2-carboxylic acid)were synthesized by using a solvothermal method.Magnetic studies indicate that 1 was a stron...Two isostructural 3D complexes[Mn(L)(N_(3))·MeOH]_(n)(1)and[Mn(L)(HCO_(2))·MeOH]n(2)(HL=pyrazine-2-carboxylic acid)were synthesized by using a solvothermal method.Magnetic studies indicate that 1 was a strong antiferromagnet,whereas 2 was a weak antiferromagnet with T_(N)38.5 K.展开更多
基金supported by the NSFC of China(21471112,21571139,21601134 and 11774178)the Natural Science Foundation of Tianjin(17JCQNJC05900)the Open Project Program of Key Laboratory of Preparation and Application of Environmentally Friendly Materials(Jilin Normal University),Ministry of Education,China(No.2017005).
文摘Two isostructural 3D complexes[Mn(L)(N_(3))·MeOH]_(n)(1)and[Mn(L)(HCO_(2))·MeOH]n(2)(HL=pyrazine-2-carboxylic acid)were synthesized by using a solvothermal method.Magnetic studies indicate that 1 was a strong antiferromagnet,whereas 2 was a weak antiferromagnet with T_(N)38.5 K.
