Ⅰ. INTRODUCTION The γω-calculus foundation, on which the generalized metacomposition rule of generalized recursive schemas is based, is discussed in this report. Generalized recursive schema is the generalization o...Ⅰ. INTRODUCTION The γω-calculus foundation, on which the generalized metacomposition rule of generalized recursive schemas is based, is discussed in this report. Generalized recursive schema is the generalization of recursive schema from defining a set展开更多
High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increa...High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increased conduction loss often leads to a significant decline in electromagnetic wave absorp-tion(EMWA)performance at elevated temperatures,which severely restricts their practical application.In this study,we propose a novel approach for efficient electromagnetic wave absorption across a wide temperature range using reduced graphene oxide(RGO)/epoxy resin(EP)metacomposites that integrate both electromagnetic parameters and metamaterial design concepts.Due to the discrete distribution of the units,electromagnetic waves can more easily penetrate the interior of materials,thereby exhibiting stable microwave absorption(MA)performance and impedance-matching characteristics suitable across a wide temperature range.Consequently,exceptional MA properties can be achieved within the tem-perature range from 298 to 473 K.Furthermore,by carefully controlling the structural parameters in RGO metacomposites,both the resonant frequency and effective absorption bandwidth(EAB)can be optimized based on precise manipulation of equivalent electromagnetic parameters.This study not only provides an effective approach for the rational design of MA performance but also offers novel insights into achieving super metamaterials with outstanding performance across a wide temperature spectrum.展开更多
The exploration of remarkable electromagnetic wave(EMW)absorbing materials with temperature-stable absorbing properties at a wide temperature range holds significant implications for both military operations and civil...The exploration of remarkable electromagnetic wave(EMW)absorbing materials with temperature-stable absorbing properties at a wide temperature range holds significant implications for both military operations and civilian life.Herein,the titanium nitride/zirconium oxide/carbon(TiN/ZrO_(2)/C)ternary nanofiber membranes have been synthesized by electrospinning followed by preoxidation-nitridation process.Thanks to the flexibility of the prepared ceramic membranes,the corresponding metacomposites,characterized by a unique hierarchical structure,were fabricated through the systematic incorporation of subwavelength scale functional units(square fiber membranes)within a polydimethylsiloxane(PDMS)matrix.This approach effectively expanded the transmission path of EMW,contributing to additional multiple reflections and scattering within the system.As a result,when the content of the functional units was as low as 10.0 wt%,the engineered metacomposites exhibited exceptional EMW absorption properties across a broad temperature range(298–573 K).This performance can be attributed to the synergistic effects of optimized impedance matching and enhanced attenuation capacity.Furthermore,the metacomposites achieved a minimum reflection loss(RL)value of−51.7 dB at 453 K,with an effective absorption bandwidth(EAB)spanning 2.3 GHz.This study may serve as a valuable reference for the design of high attenuation capacity EMW absorbing materials under complex variable high-temperature conditions.展开更多
Finely tuning spectral characteristics of the epsilon-negative(ε'<0,EN) response is full of challenges when its regulatory mechanism in metacomposites is not yet clear.Herein,we have meticulously designed Cu/C...Finely tuning spectral characteristics of the epsilon-negative(ε'<0,EN) response is full of challenges when its regulatory mechanism in metacomposites is not yet clear.Herein,we have meticulously designed Cu/CaCu_(3)Ti_(4)O_(12)(Cu/CCTO) percolative metacomposites,successfully achieved both epsilon-negative and ε'-near-zero(ENZ)responses in the radio-frequency band.Before percolation,a large number of electric dipoles in the metacomposites achieved resonance characteristics near the ENZ point under the excitation of radio frequency electromagnetic fields,and as the Cu content increased,the ENZ frequency varied from 942,858,862 to 632 MHz.展开更多
CaCu_(3)Ti_(4)O_(12)(CCTO)ceramic nanocomposites incorporating graphene–carbon black(GRCB)fillers were fabricated by spark plasma sintering process.The percolative effects of conductive GRCB fillers on dielectric res...CaCu_(3)Ti_(4)O_(12)(CCTO)ceramic nanocomposites incorporating graphene–carbon black(GRCB)fillers were fabricated by spark plasma sintering process.The percolative effects of conductive GRCB fillers on dielectric response of GRCB/CCTO ternary metacomposites were systematically investigated.The weakly real permittivity(ε′)-negative response(ε′~−1×10^(2))was achieved which originated from weakly low-frequency plasmonic state of free carriers within constructed GRCB networks.With enhancing three-dimensional GRCB network,the plasma frequency of metacomposites increased while the damping factor decreased.Herein,theε′-negative values of metacomposites were tuned from−10^(2) to−10^(4) orders of magnitude andε′-near-zero(ENZ)frequencies from~142 to~340 MHz which substantially benefited from the moderate carrier concentration of GRCB dual fillers.The Drude model and equivalent circuit models were adopted to demonstrate dielectric and electrical characteristics.The obtained metacomposites show strong EM shielding effect along with enhanced plasmonic oscillation and even better achieving perfect EM shielding effect in ENZ media.This work achieves the tunableε′-negative andε′-near-zero response and more importantly clarifies its regulation mechanism in ceramic-based ternary metacomposites,which opens up the possibility of designing high-performance EM shielding materials based on metacomposites.展开更多
An electromagnetic shielding metacomposite based on the absorbing mechanism was prepared by weaving ferromagnetic microwires into the three-dimensional(3D)fabric.The influence of the ferromagnetic microwire spacing on...An electromagnetic shielding metacomposite based on the absorbing mechanism was prepared by weaving ferromagnetic microwires into the three-dimensional(3D)fabric.The influence of the ferromagnetic microwire spacing on electromagnetic shielding performance and the electromagnetic shielding mechanism of 3D metacomposites were studied.The total electromagnetic shielding performance increases with the increase of electromagnetic wave frequency.3D metacomposites based on the absorbing mechanism can avoid the secondary pollution of electromagnetic waves,and have great potential in military,civil,aerospace and other fields.展开更多
Recently,increasing attention has been concentrated on negative permittivity with the development of the emerging metamaterials composed of periodic array structures.However,taking facile preparation into consideratio...Recently,increasing attention has been concentrated on negative permittivity with the development of the emerging metamaterials composed of periodic array structures.However,taking facile preparation into consideration,it is important to achieve negative permittivity behavior based on materials'intrinsic properties rather than their artificially periodic structures.In this paper,we proposed to fabricate the percolating composites with copper dispersed in epoxy(EP)resin by a polymerization method to realize the negative permittivity behavior.When Cu content in the composites reached to 80 wt%,the conductivity abruptly went up by three orders of magnitudes,suggesting a percolation behavior.Below the percolation threshold,the conductivity spectra conform to Jonscher's power law;when the Cu/EP composites reached to percolating state,the conductivity gradually reduced in high frequency region due to the skin effect.It is indicated that the conductive mechanism changed from hopping conduction to electron conduction.In addition,the permittivity did not increase monotonously with the increase of Cu content in the vicinity of percolation threshold,due to the presence of leakage current.Meanwhile,the negative permittivity conforming to Drude model was observed above the percolation threshold.Further investigation revealed that there was a constitutive relationship between the permittivity and the reactance.When conductive fillers are slightly above the percolation threshold,the inductive characteristic derived from conductive percolating network leads to the negative permittivity.Such epsilon-negative materials can potentially be applied in novel electrical devices,such as high-power microwave filters,stacked capacitors,negative capacitance field effect transistors and coil-free resonators.In addition,the design strategy based on percolating composites provides an approach to epsilon-negative materials.展开更多
Metacomposites with negative permittivity usually possess huge dielectric loss,showing potential for micro-wave attenuation devices where huge heat would generate.Herein,carbon nanotube-carbon black/CaCu_(3-)Ti_(4)O_(...Metacomposites with negative permittivity usually possess huge dielectric loss,showing potential for micro-wave attenuation devices where huge heat would generate.Herein,carbon nanotube-carbon black/CaCu_(3-)Ti_(4)O_(12)(CNT-CB/CCTO)ternary metacomposites were fabricated by spark plasma sintering.The CNT-CB dualphase filler was pre-pared through electrostatic selfassembly process in order to construct an effective 3-dimensional(3D)carbon network in CCTO matrix.The percolation threshold of CNT-CB/CCTO composites was identified at filler content of 12.52 wt%which accompanied with an essential change of conduction mechanism.The negative permittivity was derived from low-frequency plasmonic state of the 3D carbon network,described by Drude model.The problem of heat transport,generally occurring in negative permittivity materials,has been solved and optimized in obtained ternary metacomposites beneftting from the substantially high thermal conductivity(9.49-2.00 W·m^(-1)·K^(-1))and diffusivity(2.74-1.22mm^(2)·s^(-1)).This work could spark significant development of practical application of metacomposites on novel electronic devices and electromagnetic apparatus.展开更多
Metals have traditionally served as the primary functional phase in the development of metamaterials exhibiting epsilon-near-zero(ENZ)and epsilon-negative(EN)responses,albeit with persisting ambiguities regarding thei...Metals have traditionally served as the primary functional phase in the development of metamaterials exhibiting epsilon-near-zero(ENZ)and epsilon-negative(EN)responses,albeit with persisting ambiguities regarding their response mechanisms.This paper presents the tunable ENZ(ε′~0)and EN(ε′<0)parameters at the 20-MHz to 1-GHz region based on Cu/CaCu_(3)Ti_(4)O_(12)(Cu/CCTO)metacomposites.By means of first-principles calculations and multi-physics simulations,the underlying mechanisms governing ENZ and EN responses are unveiled.The intricate pathways through which metacomposites achieve 2 dielectric response mechanisms are delineated:At low Cu content,a weak EN response(|ε′|<200)was excited by electric dipole resonance,accompanied by ENZ effect;conversely,at high Cu content,due to the increase in effective electron concentration,plasmonic oscillation behavior occurs in the constructed 3-dimensional Cu network,resulting in strong EN response(|ε′|~1,000)in the radio frequency band.These phenomena are explicated through 2 distinct Cu/CCTO models:Cu in an isolated state and a connected network state.This study not only comprehensively elucidates the 2 EN response mechanisms achieved by typical metacomposites with metals as functional phases but also delves into their associated electromagnetic shielding and thermal properties,providing a theoretical basis for their practical applications.展开更多
Ⅰ. INTRODUCTION It seems hopeful that γω-calculus would become the most general theoretical foundation of semantics for functional programming languages (at least for the ones without types). In this note, for the ...Ⅰ. INTRODUCTION It seems hopeful that γω-calculus would become the most general theoretical foundation of semantics for functional programming languages (at least for the ones without types). In this note, for the formal functional programming language FFP, the γω-展开更多
With the increasing advance of fifth generation(5G)network and the gradual expansion of digital devices,harsh working environment for electronic devices has spawned higher requirements for microwave absorbing material...With the increasing advance of fifth generation(5G)network and the gradual expansion of digital devices,harsh working environment for electronic devices has spawned higher requirements for microwave absorbing materials(MAMs).Since both the electromagnetic response and energy conversion character vary with temperature,to achieve temperature insensitive microwave absorption behaviour in wide temperature range has become extremely challenging.In this work,structured metacomposites containing sub-wavelength reduced graphene oxide(RGO)@carbon spheres were fabricated,and the microwave absorption was further improved through structural and composition design of the RGO@carbon units.Due to the unique anti-reflection effect on microwave of the metacomposites,the temperature-insensitive electromagnetic performance at elevated temperature could be exhibited.Moreover,both the dielectric relaxation behaviour and microwave absorption proformance of the system could be further increased.As a result,the effective absorption bandwidth(reflection loss(RL)<−10 dB)of the metacomposites with only 3.0 wt.%filler content could cover the entire X-band(8.2–12.4 GHz)frequency ranging from 298 to 473K.The metacomposite proposed in this work provides a“de-correlating”strategy to break the linkage between microwave absorption behaviour and temperature,which offers an interesting plateau for fabricating efficient high-temperature microwave absorption structures with tunable and designable advantages.展开更多
文摘Ⅰ. INTRODUCTION The γω-calculus foundation, on which the generalized metacomposition rule of generalized recursive schemas is based, is discussed in this report. Generalized recursive schema is the generalization of recursive schema from defining a set
基金supported by the National Nature Science Foundation of China(Nos.22305066 and 52372041).
文摘High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increased conduction loss often leads to a significant decline in electromagnetic wave absorp-tion(EMWA)performance at elevated temperatures,which severely restricts their practical application.In this study,we propose a novel approach for efficient electromagnetic wave absorption across a wide temperature range using reduced graphene oxide(RGO)/epoxy resin(EP)metacomposites that integrate both electromagnetic parameters and metamaterial design concepts.Due to the discrete distribution of the units,electromagnetic waves can more easily penetrate the interior of materials,thereby exhibiting stable microwave absorption(MA)performance and impedance-matching characteristics suitable across a wide temperature range.Consequently,exceptional MA properties can be achieved within the tem-perature range from 298 to 473 K.Furthermore,by carefully controlling the structural parameters in RGO metacomposites,both the resonant frequency and effective absorption bandwidth(EAB)can be optimized based on precise manipulation of equivalent electromagnetic parameters.This study not only provides an effective approach for the rational design of MA performance but also offers novel insights into achieving super metamaterials with outstanding performance across a wide temperature spectrum.
基金supported by the National Nature Science Foundation of China(Nos.22475065 and 22305066)the Natural Science Foundation of Henan Province Youth Fund(No.242300421466).
文摘The exploration of remarkable electromagnetic wave(EMW)absorbing materials with temperature-stable absorbing properties at a wide temperature range holds significant implications for both military operations and civilian life.Herein,the titanium nitride/zirconium oxide/carbon(TiN/ZrO_(2)/C)ternary nanofiber membranes have been synthesized by electrospinning followed by preoxidation-nitridation process.Thanks to the flexibility of the prepared ceramic membranes,the corresponding metacomposites,characterized by a unique hierarchical structure,were fabricated through the systematic incorporation of subwavelength scale functional units(square fiber membranes)within a polydimethylsiloxane(PDMS)matrix.This approach effectively expanded the transmission path of EMW,contributing to additional multiple reflections and scattering within the system.As a result,when the content of the functional units was as low as 10.0 wt%,the engineered metacomposites exhibited exceptional EMW absorption properties across a broad temperature range(298–573 K).This performance can be attributed to the synergistic effects of optimized impedance matching and enhanced attenuation capacity.Furthermore,the metacomposites achieved a minimum reflection loss(RL)value of−51.7 dB at 453 K,with an effective absorption bandwidth(EAB)spanning 2.3 GHz.This study may serve as a valuable reference for the design of high attenuation capacity EMW absorbing materials under complex variable high-temperature conditions.
基金supported by the National Natural Science Foundation of China(No.52461002)
文摘Finely tuning spectral characteristics of the epsilon-negative(ε'<0,EN) response is full of challenges when its regulatory mechanism in metacomposites is not yet clear.Herein,we have meticulously designed Cu/CaCu_(3)Ti_(4)O_(12)(Cu/CCTO) percolative metacomposites,successfully achieved both epsilon-negative and ε'-near-zero(ENZ)responses in the radio-frequency band.Before percolation,a large number of electric dipoles in the metacomposites achieved resonance characteristics near the ENZ point under the excitation of radio frequency electromagnetic fields,and as the Cu content increased,the ENZ frequency varied from 942,858,862 to 632 MHz.
基金This work was financially supported by the National Natural Science Foundation of China(No.52205593)the Fund of Natural Science Special(Special Post)Research Foundation of Guizhou University(No.2023-032)the Platform of Science and Technology and Talent Team Plan of Guizhou Province(No.GCC[2023]007).
文摘CaCu_(3)Ti_(4)O_(12)(CCTO)ceramic nanocomposites incorporating graphene–carbon black(GRCB)fillers were fabricated by spark plasma sintering process.The percolative effects of conductive GRCB fillers on dielectric response of GRCB/CCTO ternary metacomposites were systematically investigated.The weakly real permittivity(ε′)-negative response(ε′~−1×10^(2))was achieved which originated from weakly low-frequency plasmonic state of free carriers within constructed GRCB networks.With enhancing three-dimensional GRCB network,the plasma frequency of metacomposites increased while the damping factor decreased.Herein,theε′-negative values of metacomposites were tuned from−10^(2) to−10^(4) orders of magnitude andε′-near-zero(ENZ)frequencies from~142 to~340 MHz which substantially benefited from the moderate carrier concentration of GRCB dual fillers.The Drude model and equivalent circuit models were adopted to demonstrate dielectric and electrical characteristics.The obtained metacomposites show strong EM shielding effect along with enhanced plasmonic oscillation and even better achieving perfect EM shielding effect in ENZ media.This work achieves the tunableε′-negative andε′-near-zero response and more importantly clarifies its regulation mechanism in ceramic-based ternary metacomposites,which opens up the possibility of designing high-performance EM shielding materials based on metacomposites.
基金Open Project Program of Key Laboratory of Yarn Materials Forming and Composite Processing Technology of Zhejiang Province,China(No.MTC2021-02)。
文摘An electromagnetic shielding metacomposite based on the absorbing mechanism was prepared by weaving ferromagnetic microwires into the three-dimensional(3D)fabric.The influence of the ferromagnetic microwire spacing on electromagnetic shielding performance and the electromagnetic shielding mechanism of 3D metacomposites were studied.The total electromagnetic shielding performance increases with the increase of electromagnetic wave frequency.3D metacomposites based on the absorbing mechanism can avoid the secondary pollution of electromagnetic waves,and have great potential in military,civil,aerospace and other fields.
基金sponsored by the National Natural Science Foundation of China (Grant No.51803119,51871146 and 51771108)the Innovation Program of Shanghai Municipal Education Commission (Grant No.2019-01-07-00-10-E00053)+1 种基金"Chenguang Program" supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission (Grant No.18CG56)the Science and Technology Commission of Shanghai Municipality (Grant No.18DZ1112902,No.18DZ1100802)
文摘Recently,increasing attention has been concentrated on negative permittivity with the development of the emerging metamaterials composed of periodic array structures.However,taking facile preparation into consideration,it is important to achieve negative permittivity behavior based on materials'intrinsic properties rather than their artificially periodic structures.In this paper,we proposed to fabricate the percolating composites with copper dispersed in epoxy(EP)resin by a polymerization method to realize the negative permittivity behavior.When Cu content in the composites reached to 80 wt%,the conductivity abruptly went up by three orders of magnitudes,suggesting a percolation behavior.Below the percolation threshold,the conductivity spectra conform to Jonscher's power law;when the Cu/EP composites reached to percolating state,the conductivity gradually reduced in high frequency region due to the skin effect.It is indicated that the conductive mechanism changed from hopping conduction to electron conduction.In addition,the permittivity did not increase monotonously with the increase of Cu content in the vicinity of percolation threshold,due to the presence of leakage current.Meanwhile,the negative permittivity conforming to Drude model was observed above the percolation threshold.Further investigation revealed that there was a constitutive relationship between the permittivity and the reactance.When conductive fillers are slightly above the percolation threshold,the inductive characteristic derived from conductive percolating network leads to the negative permittivity.Such epsilon-negative materials can potentially be applied in novel electrical devices,such as high-power microwave filters,stacked capacitors,negative capacitance field effect transistors and coil-free resonators.In addition,the design strategy based on percolating composites provides an approach to epsilon-negative materials.
基金financially supported by the National Natural Science Foundation of China (Nos.52101176,11604060,22005071 and 52101010)the China Postdoctoral Science Foundation (No.2020M671992)+3 种基金Guangdong Basic and Applied Basic Research Foundation (No.2021A1515110883)Guizhou Provincial Science and Technology Projects (No.ZK[2022]General044)the Cultivation Programs Research Foundation of Guizhou University (No.2019-64)support of the Fund of Natural Science Special (Special Post)Research Foundation of Guizhou University[Grant No.2023-032]。
文摘Metacomposites with negative permittivity usually possess huge dielectric loss,showing potential for micro-wave attenuation devices where huge heat would generate.Herein,carbon nanotube-carbon black/CaCu_(3-)Ti_(4)O_(12)(CNT-CB/CCTO)ternary metacomposites were fabricated by spark plasma sintering.The CNT-CB dualphase filler was pre-pared through electrostatic selfassembly process in order to construct an effective 3-dimensional(3D)carbon network in CCTO matrix.The percolation threshold of CNT-CB/CCTO composites was identified at filler content of 12.52 wt%which accompanied with an essential change of conduction mechanism.The negative permittivity was derived from low-frequency plasmonic state of the 3D carbon network,described by Drude model.The problem of heat transport,generally occurring in negative permittivity materials,has been solved and optimized in obtained ternary metacomposites beneftting from the substantially high thermal conductivity(9.49-2.00 W·m^(-1)·K^(-1))and diffusivity(2.74-1.22mm^(2)·s^(-1)).This work could spark significant development of practical application of metacomposites on novel electronic devices and electromagnetic apparatus.
基金financially supported by the National Natural Science Foundation of China(nos.52205593,22078305,62174115,and U21A20147)the Xidian University Specially Funded Project for Interdisciplinary Exploration(no.TZJH2024061).
文摘Metals have traditionally served as the primary functional phase in the development of metamaterials exhibiting epsilon-near-zero(ENZ)and epsilon-negative(EN)responses,albeit with persisting ambiguities regarding their response mechanisms.This paper presents the tunable ENZ(ε′~0)and EN(ε′<0)parameters at the 20-MHz to 1-GHz region based on Cu/CaCu_(3)Ti_(4)O_(12)(Cu/CCTO)metacomposites.By means of first-principles calculations and multi-physics simulations,the underlying mechanisms governing ENZ and EN responses are unveiled.The intricate pathways through which metacomposites achieve 2 dielectric response mechanisms are delineated:At low Cu content,a weak EN response(|ε′|<200)was excited by electric dipole resonance,accompanied by ENZ effect;conversely,at high Cu content,due to the increase in effective electron concentration,plasmonic oscillation behavior occurs in the constructed 3-dimensional Cu network,resulting in strong EN response(|ε′|~1,000)in the radio frequency band.These phenomena are explicated through 2 distinct Cu/CCTO models:Cu in an isolated state and a connected network state.This study not only comprehensively elucidates the 2 EN response mechanisms achieved by typical metacomposites with metals as functional phases but also delves into their associated electromagnetic shielding and thermal properties,providing a theoretical basis for their practical applications.
文摘Ⅰ. INTRODUCTION It seems hopeful that γω-calculus would become the most general theoretical foundation of semantics for functional programming languages (at least for the ones without types). In this note, for the formal functional programming language FFP, the γω-
基金the National Natural Science Foundation of China(Nos.U1704253 and 21671057).
文摘With the increasing advance of fifth generation(5G)network and the gradual expansion of digital devices,harsh working environment for electronic devices has spawned higher requirements for microwave absorbing materials(MAMs).Since both the electromagnetic response and energy conversion character vary with temperature,to achieve temperature insensitive microwave absorption behaviour in wide temperature range has become extremely challenging.In this work,structured metacomposites containing sub-wavelength reduced graphene oxide(RGO)@carbon spheres were fabricated,and the microwave absorption was further improved through structural and composition design of the RGO@carbon units.Due to the unique anti-reflection effect on microwave of the metacomposites,the temperature-insensitive electromagnetic performance at elevated temperature could be exhibited.Moreover,both the dielectric relaxation behaviour and microwave absorption proformance of the system could be further increased.As a result,the effective absorption bandwidth(reflection loss(RL)<−10 dB)of the metacomposites with only 3.0 wt.%filler content could cover the entire X-band(8.2–12.4 GHz)frequency ranging from 298 to 473K.The metacomposite proposed in this work provides a“de-correlating”strategy to break the linkage between microwave absorption behaviour and temperature,which offers an interesting plateau for fabricating efficient high-temperature microwave absorption structures with tunable and designable advantages.
