The electrical performance of radomes on high-speed aircraft can be influenced by the thermal and mechanical loads produced during high-speed flight,which can affect the detection dis-tance and accuracy of the guidanc...The electrical performance of radomes on high-speed aircraft can be influenced by the thermal and mechanical loads produced during high-speed flight,which can affect the detection dis-tance and accuracy of the guidance system.This paper presents a new method that uses the Finite Difference Time Domain(FDTD)method to calculate the electrical performance of radomes under Thermo-Mechanical-Electrical(TME)coupling.This method can accurately characterize the effects of material dielectric temperature drift and structural deformation on the electrical performance of the radome under flight conditions,enabling high-precision full-wave calculations of the broadband electrical performance of the radome.The method initiates by utilizing a Finite Element Grid Model(FE-GM)of the radome to sequentially acquire the radome's response temperature field and structural deformation field through thermal and mechanical simulations.Subsequently,spatial mapping techniques are developed to accurately incorporate the dielectric temperature drift and structural deformation of the radome into its Yee grid Electromagnetic(EM)simulation model.A verification case was designed to test the proposed method,and the results confirmed its high computational accuracy.Additionally,the effectiveness and necessity of the method were further demonstrated by analyzing the electrical performance of a fused silica ceramic radome used on a high-speed aircraft.展开更多
During high-speed flight,both thermal and mechani-cal loads can degrade the electrical performance of the antenna-radome system,which can subsequently affect the performance of the guidance system.This paper presents ...During high-speed flight,both thermal and mechani-cal loads can degrade the electrical performance of the antenna-radome system,which can subsequently affect the performance of the guidance system.This paper presents a method for evalu-ating the electrical performance of the radome when subjected to thermo-mechanical-electrical(TME)coupling.The method involves establishing a TME coupling model(TME-CM)based on the TME sharing mesh model(TME-SMM)generated by the tetrahedral mesh partitioning of the radome structure.The effects of dielectric temperature drift and structural deformation on the radome’s electrical performance are also considered.Firstly,the temperature field of the radome is obtained by tran-sient thermal analysis while the deformation field of the radome is obtained by static analysis.Subsequently,the dielectric varia-tion and structural deformation of the radome are accurately incorporated into the electrical simulation model based on the TME-SMM.The three-dimensional(3D)ray tracing method with the aperture integration technique is used to calculate the radome’s electrical performance.A representative example is provided to illustrate the superiority and necessity of the pro-posed method.This is achieved by calculating and analyzing the changes in the radome’s electrical performance over time dur-ing high-speed flight.展开更多
Using a recently established liquid crystal model for vesicles, we present a theoretical method to analyze the morphological stability of liquid crystal vesicles in an electric field. The coupled mechanical-electrical...Using a recently established liquid crystal model for vesicles, we present a theoretical method to analyze the morphological stability of liquid crystal vesicles in an electric field. The coupled mechanical-electrical effects associated with elastic bending, osmotic pressure, surface tension, Max- well pressure, as well as flexoelectric and dielectric proper- ties of the membrane are taken into account. The first and second variations of the free energy are derived in a com- pact form by virtue of the surface variational principle. The former leads to the shape equation of a vesicle embedded in an electric field, and the latter allows us to examine the stabil- ity of a given vesicle morphology. As an illustrative exam- ple, we analyze the stability of a spherical vesicle under a uniform electric field. This study is helpful for understanding and revealing the morphological evolution mechanisms of vesicles in electric fields and some associated phenomena of cells.展开更多
The largely bending bilayer electrode model battery has been widely used to measure the mechanical properties of composite electrode materials.The assumption used in the method that lithium is uniformly distributed in...The largely bending bilayer electrode model battery has been widely used to measure the mechanical properties of composite electrode materials.The assumption used in the method that lithium is uniformly distributed in the active layer lacks quantitative evaluation,and the uniformity of concentration distribution is crucial for accurate in-situ measurements of concentration-related material properties and stress in bilayer electrodes.Therefore,this paper proposes a mechanical-electrochemical coupled model to study the lithium concentration distribution in the active layer during lithiation.This model includes lithium concentration diffusion and active layer deformation.By comparing experimental and simulated curvature evolution of the active layer during lithiation and delithiation,the reliability of this simulation model is verified.We then derive the precise concentration distribution inside the active layer and suggest using relative error to quantitatively evaluate the uniformity of lithium concentration in the active layer.Results show that a low relative error in lithium concentration can be achieved in the middle region of the active layer.Additionally,the effects of different rates and geometric parameters on the lithium concentration distribution in the active layer are discussed.Results indicate that reduced rates,thinner active layers,shorter active layer lengths,and increased spacing between the working and counter electrodes can lead to a more uniform distribution of lithium concentration in the active layer.These insights help improve experimental methods and equipment,promoting uniform distribution of lithium in the active layer and enhancing measurement accuracy.展开更多
Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,how...Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.展开更多
The occurrence of top-down(TD)cracking has gradually become a prevalent issue in semi-rigid base asphalt pavements after prolonged service.A coupled simulation model integrating the finite difference method(FDM)and di...The occurrence of top-down(TD)cracking has gradually become a prevalent issue in semi-rigid base asphalt pavements after prolonged service.A coupled simulation model integrating the finite difference method(FDM)and discrete element method(DEM)was employed to investigate the mechanical behavior of asphalt pavement containing a pre-existing TD crack.The mesoscopic parameters of the model were calibrated based on the mixture modulus and the static mechanical response on the MLS66 test road.Finally,an analysis was performed to assess how variations in TD crack depth and longitudinal length affect the distribution patterns of transverse tensile stress,vertical shear stress,and vertical compressive stress.The results indicate that the vertical propagation of TD crack significantly increases both the tensile stress value and range on the middle surface,while the longitudinal development of TD crack has minimal impact.This phenomenon may result in more severe fatigue failure on the middle surface.With the vertical and longitudinal development of TD crack,the vertical shear stress and compressive stress show obvious"two-stage"characteristics.When the crack's vertical length reaches 40 mm,there is a sharp increase in stress on the upper surface.As the crack continues to propagate vertically,the growth of stress on the upper surface becomes negligible,while the stress in the middle and lower layers increased significantly.Conversely,for longitudinal development of TD crack,any changes in stress are insignificant when their length is less than 180 mm;however,as they continue to develop longitudinally beyond this threshold,there is a sharp increase in stress levels.These findings hold great significance for understanding pavement structure deterioration and maintenance behavior associated with TD crack.展开更多
Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,sy...Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,synthesized via cation exchange and calcination oxidation.These catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and selectivities.These catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as precursors.The porous architecture and polymetallic composition of the NiCo_(2)O_(4)spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for phenol.Key innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT simulations.This work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.展开更多
Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression an...Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.展开更多
This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expan...This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expansion with environmental protection,a comprehensive evaluation index system is constructed,encompassing two key dimensions:regional economy and ecological environment.Using panel data from 2013 to 2022,the coupling coordination degree model is employed to quantify the interactions and synergy between these dimensions.Additionally,spatial econometric methods are applied to calculate both global and local Moran’s Index,revealing spatial clustering patterns,regional disparities,and heterogeneity.The relative development model further identifies critical factors influencing regional coordination,with a focus on the lagging development of basic infrastructure and public services.The findings demonstrate a positive temporal trend toward improved regional coordination and reduced development gaps,with a spatial pattern characterized by higher coupling degrees in eastern and central regions compared to western areas.Based on these results,this study proposes actionable strategies to enhance coordinated development,emphasizing ecological conservation,the establishment of green production and consumption systems,ecological restoration,and strengthened municipal collaboration.This revised abstract emphasizes the study’s purpose,methods,and key findings more clearly while maintaining a professional and concise tone.Finally,based on the above analysis results,the corresponding coordinated development suggestions of regional economy and ecological environment are given from the aspects of ecological environment protection measures,green production and consumption system construction,ecological environment restoration and municipal coordination.展开更多
Dislocations and disclinations are fundamental topological defects within crystals,which determine the mechanical properties of metals and alloys.Despite their important roles in multiple physical mechanisms,e.g.,dyna...Dislocations and disclinations are fundamental topological defects within crystals,which determine the mechanical properties of metals and alloys.Despite their important roles in multiple physical mechanisms,e.g.,dynamic recovery and grain boundary mediated plasticity,the intrinsic coupling and correlation between disclinations and dislocations,and their impacts on the deformation behavior of metallic materials still remain obscure,partially due to the lack of a theoretical tool to capture the rotational nature of disclinations.By using a Lie-algebra-based theoretical framework,we obtain a general equation to quantify the intrinsic coupling of disclinations and dislocations.Through quasi in-situ electron backscatter diffraction characterizations and disclination/dislocation density analyses in Mg alloys,the generation,coevolution and reactions of disclinations and dislocations during dynamic recovery and superplastic deformation have been quantitatively analyzed.It has been demonstrated that the obtained governing equation can capture multiple physical processes associated with mechanical deformation of metals,e.g.,grain rotation and grain boundary migration,at both room temperature and high temperature.By establishing the disclination-dislocation coupling equation within a Lie algebra description,our work provides new insights for exploring the coevolution and reaction of disclinations/dislocations,with profound implications for elucidating the microstructure-property relationship and underlying deformation mechanisms in metallic materials.展开更多
Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic str...Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic structure. In this work, Sb^(3+)/Te^(4+)ions doped Zn-based halide single crystals(SCs) with two STEs emissions have been synthesized and the possibility of its anti-counterfeiting application was explored.Further, the relationship between the strength of electron-phonon coupling and photoluminescence quantum yields(PLQYs) for STEs in a series of metal halides has been studied. And the semi-empirical range of the Huang-Rhys factors(S) for metal halides with excellent photoluminescence(PL) property has been summarized. This work provides ideas for further research into the relationship between luminescence performance and electron-phonon coupling of metal halides, and also provides a reference for designing the metal halides with high PLQYs.展开更多
Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to re...Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to reinforce GRS. The effects of cement content and SiO_(2)/Na2O ratio of the alkaline solution on the static and dynamic strengths of GRS were discussed. Microscopically, the reinforcement mechanism and coupling effect were examined using X-ray diffraction (XRD), micro-computed tomography (micro-CT), and scanning electron microscopy (SEM). The results indicated that the addition of 2% cement and an alkaline solution with an SiO_(2)/Na2O ratio of 0.5 led to the densest matrix, lowest porosity, and highest static compressive strength, which was 4994 kPa with a dynamic impact resistance of 75.4 kN after adding glass fiber. The compressive strength and dynamic impact resistance were a result of the coupling effect of cement hydration, a pozzolanic reaction of clay minerals in the GRS, and the alkali activation of clay minerals. Excessive cement addition or an excessively high SiO_(2)/Na2O ratio in the alkaline solution can have negative effects, such as the destruction of C-(A)-S-H gels by the alkaline solution and hindering the production of N-A-S-H gels. This can result in damage to the matrix of reinforced GRS, leading to a decrease in both static and dynamic strengths. This study suggests that further research is required to gain a more precise understanding of the effects of this mixture in terms of reducing our carbon footprint and optimizing its properties. The findings indicate that cement and alkaline solution are appropriate for GRS and that the reinforced GRS can be used for high-strength foundation and embankment construction. The study provides an analysis of strategies for mitigating and managing GRS slope failures, as well as enhancing roadbed performance.展开更多
The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the ...The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the compact integration of the OMP presents challenges inefficiently dissipating internal heat,leading to a performance degradation of the EHA due to ele-vated temperatures.Therefore,accurately modeling and predicting the internal thermal dynamicsof the OMP hold considerable significance for monitoring the operational condition of the EHA.In view of this,a modeling method considering cumulative thermal coupling was hereby proposed.Based on the proposed method,the thermal models of the motor and the pump were established,taking into account heat accumulation and transfer.Taking the leakage oil as the heat couplingpoint between the motor and the pump,the dynamic thermal coupling model of the OMP wasdeveloped,with the thermal characteristics of the oil considered.Additionally,the comparativeexperiments were conducted to illustrate the efficiency of the proposed model.The experimentalresults demonstrate that the proposed dynamic thermal coupling model accurately captured thethermal behavior of OMP,outperforming the static thermal parameter model.Overall,thisadvancement is crucial for effectively monitoring the health of EHA and ensuring flight safety.展开更多
Ground source heat pump systems demonstrate significant potential for northern rural heating applications;however,the effectiveness of these systems is often limited by challenging geological conditions.For instance,i...Ground source heat pump systems demonstrate significant potential for northern rural heating applications;however,the effectiveness of these systems is often limited by challenging geological conditions.For instance,in certain regions,the installation of buried pipes for heat exchangers may be complicated,and these pipes may not always serve as efficient low-temperature heat sources for the heat pumps of the system.To address this issue,the current study explored the use of solar-energy-collecting equipment to supplement buried pipes.In this design,both solar energy and geothermal energy provide low-temperature heat to the heat pump.First,a simulation model of a solar‒ground source heat pump coupling system was established using TRNSYS.The accuracy of this model was validated through experiments and simulations on various system configurations,including varying numbers of buried pipes,different areas of solar collectors,and varying volumes of water tanks.The simulations examined the coupling characteristics of these components and their influence on system performance.The results revealed that the operating parameters of the system remained consistent across the following configurations:three buried pipes,burial depth of 20 m,collector area of 6 m^(2),and water tank volume of 0.5 m^(3);four buried pipes,burial depth of 20 m,collector area of 3 m^(2),and water tank volume of 0.5 m^(3);and five buried pipes with a burial depth of 20 m.Furthermore,the heat collection capacity of the solar collectors spanning an area of 3 m^(2)was found to be equivalent to that of one buried pipe.Moreover,the findings revealed that the solar‒ground source heat pump coupling system demonstrated a lower annual cumulative energy consumption compared to the ground source heat pump system,presenting a reduction of 5.31%compared to the energy consumption of the latter.展开更多
Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoti...Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.展开更多
For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of t...For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of the measurement system.We present a method for analyzing TTL coupling noise under the joint influence of multiple factors.An equivalent simulated optical bench for the test mass interferometer was designed,and Gaussian beam tracing was adopted to simulate beam propagation.By simulating the interference signal,it can analyze the impact of various factors on the TTL coupling noise,including positional,beam parameters,detector parameters,and signal definition factors.On this basis,a random parameter space composed of multiple influential factors was constructed within a range satisfying the analysis requirement,and the corresponding simulation results from random sampling were evaluated via variance-based global sensitivity analysis.The calculated results of the main and total effect indexes show that the test mass rotation angle and the piston effect(lateral)significantly influence the TTL coupling noise in the test mass interferometer.The analysis provides a qualitative reference for designing and optimizing space-borne laser interferometry systems.展开更多
By using a newly developed 4-hydroxy picolinohydrazide as the ligand,Cu-catalyzed coupling of(hetero)aryl chlorides with sodium aryl sulfonates proceeded smoothly at 130℃to give a series of biarylsulfones in 53%~96%y...By using a newly developed 4-hydroxy picolinohydrazide as the ligand,Cu-catalyzed coupling of(hetero)aryl chlorides with sodium aryl sulfonates proceeded smoothly at 130℃to give a series of biarylsulfones in 53%~96%yields.This represents the first metal-catalyzed coupling reaction of(hetero)aryl chlorides with sodium aryl sulfonates.Aryl and heteroaryl chlorides bearing either electron-donating or electron-withdrawing groups were applicable for this coupling reaction.展开更多
Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these mat...Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these materials isfrequently constrained by heat generation during light absorption,resulting in significant thermal losses.Most offerroelectric films produce photocurrent and thermocurrent with opposite polarity,thus weakening the coupledphoto-thermoelectric output of the devices.Here we report on a LaNiO_(3)/BiMn_(2)O_(5)(BMO)/ITO ferroelectric film toproduce photocurrent and thermocurrent with the same polarity.The polarity of the photocurrent generated bythe BMO film is shown to be determined solely by the direction of spontaneous polarization,overcoming thedetrimental effect of Schottky barrier for energy harvesting in device.We propose a new strategy to enhance thecoupling factor,thereby offering valuable new insights for optimizing the utilization of ferroelectric materials inboth light and heat energy applications.展开更多
We report a theoretical analysis of magnon–magnon coupling in a noncollinear magnetic sandwiched structure with interlayer exchange interaction,which consists of two ferromagnetic layers with perpendicular and in-pla...We report a theoretical analysis of magnon–magnon coupling in a noncollinear magnetic sandwiched structure with interlayer exchange interaction,which consists of two ferromagnetic layers with perpendicular and in-plane magnetic anisotropy,respectively.Based on the Landau–Lifshitz equation,the spin wave dispersion is derived,and then the frequency gap is observed due to the magnon–magnon coupling effect induced by symmetry breaking.The influence of saturation magnetization,exchange coupling interaction,perpendicular magnetic anisotropy,and wave vector on the coupling strength is studied in detail.We find that the coupling strength is strongly dependent on the saturation magnetization and a small saturation magnetization can lead to strong coupling strength.By selecting the appropriate magnetic materials,the ultra-strong coupling regime can be achieved.The precession information in time domain is solved and the alternating change of the precession components in two ferromagnetic layers implies the exchange of energy and information.展开更多
The uneven distribution of medical resources has led to increasingly frequent patient mobility;however, the interaction between this phenomenon and the healthcare supply-demand relationship remains underexplored. The ...The uneven distribution of medical resources has led to increasingly frequent patient mobility;however, the interaction between this phenomenon and the healthcare supply-demand relationship remains underexplored. The present study constructed the 2023Cross-City Patient Mobility Network in China using one million patient mobility data records obtained from online healthcare platforms. We applied urban network analysis to uncover mobility patterns and used the coupling coordination degree model to assess healthcare supply-demand relationships before and after patient mobility. Explainable machine learning further revealed the impact of supply-demand coupling on patient mobility. The results indicated the following: Patient mobility followed administrative boundaries, although megacities serve areas beyond provincial borders;The scale of healthcare supply and demand displayed a multi-centric spatial pattern with a general decline from east to west, and these characteristics of demand distribution were further solidified by patient mobility;Cities with low supply-demand coupling and undersupply experienced patient outflows, while cities with high coupling and oversupply attracted them. In turn, patient mobility helped balance healthcare supply and demand, optimising the coupling relationship across cities. Thus, this research not only provides a methodological reference for understanding the interaction between patient mobility and healthcare systems but also offers empirical insights for public health policy.展开更多
文摘The electrical performance of radomes on high-speed aircraft can be influenced by the thermal and mechanical loads produced during high-speed flight,which can affect the detection dis-tance and accuracy of the guidance system.This paper presents a new method that uses the Finite Difference Time Domain(FDTD)method to calculate the electrical performance of radomes under Thermo-Mechanical-Electrical(TME)coupling.This method can accurately characterize the effects of material dielectric temperature drift and structural deformation on the electrical performance of the radome under flight conditions,enabling high-precision full-wave calculations of the broadband electrical performance of the radome.The method initiates by utilizing a Finite Element Grid Model(FE-GM)of the radome to sequentially acquire the radome's response temperature field and structural deformation field through thermal and mechanical simulations.Subsequently,spatial mapping techniques are developed to accurately incorporate the dielectric temperature drift and structural deformation of the radome into its Yee grid Electromagnetic(EM)simulation model.A verification case was designed to test the proposed method,and the results confirmed its high computational accuracy.Additionally,the effectiveness and necessity of the method were further demonstrated by analyzing the electrical performance of a fused silica ceramic radome used on a high-speed aircraft.
文摘During high-speed flight,both thermal and mechani-cal loads can degrade the electrical performance of the antenna-radome system,which can subsequently affect the performance of the guidance system.This paper presents a method for evalu-ating the electrical performance of the radome when subjected to thermo-mechanical-electrical(TME)coupling.The method involves establishing a TME coupling model(TME-CM)based on the TME sharing mesh model(TME-SMM)generated by the tetrahedral mesh partitioning of the radome structure.The effects of dielectric temperature drift and structural deformation on the radome’s electrical performance are also considered.Firstly,the temperature field of the radome is obtained by tran-sient thermal analysis while the deformation field of the radome is obtained by static analysis.Subsequently,the dielectric varia-tion and structural deformation of the radome are accurately incorporated into the electrical simulation model based on the TME-SMM.The three-dimensional(3D)ray tracing method with the aperture integration technique is used to calculate the radome’s electrical performance.A representative example is provided to illustrate the superiority and necessity of the pro-posed method.This is achieved by calculating and analyzing the changes in the radome’s electrical performance over time dur-ing high-speed flight.
基金supported by the National Natural Science Foundation of China(10972121,10732050 and 10525210)973 Program(2010CB631005)
文摘Using a recently established liquid crystal model for vesicles, we present a theoretical method to analyze the morphological stability of liquid crystal vesicles in an electric field. The coupled mechanical-electrical effects associated with elastic bending, osmotic pressure, surface tension, Max- well pressure, as well as flexoelectric and dielectric proper- ties of the membrane are taken into account. The first and second variations of the free energy are derived in a com- pact form by virtue of the surface variational principle. The former leads to the shape equation of a vesicle embedded in an electric field, and the latter allows us to examine the stabil- ity of a given vesicle morphology. As an illustrative exam- ple, we analyze the stability of a spherical vesicle under a uniform electric field. This study is helpful for understanding and revealing the morphological evolution mechanisms of vesicles in electric fields and some associated phenomena of cells.
基金supported by the National Natural Science Foundation of China(Grant No.11872236).
文摘The largely bending bilayer electrode model battery has been widely used to measure the mechanical properties of composite electrode materials.The assumption used in the method that lithium is uniformly distributed in the active layer lacks quantitative evaluation,and the uniformity of concentration distribution is crucial for accurate in-situ measurements of concentration-related material properties and stress in bilayer electrodes.Therefore,this paper proposes a mechanical-electrochemical coupled model to study the lithium concentration distribution in the active layer during lithiation.This model includes lithium concentration diffusion and active layer deformation.By comparing experimental and simulated curvature evolution of the active layer during lithiation and delithiation,the reliability of this simulation model is verified.We then derive the precise concentration distribution inside the active layer and suggest using relative error to quantitatively evaluate the uniformity of lithium concentration in the active layer.Results show that a low relative error in lithium concentration can be achieved in the middle region of the active layer.Additionally,the effects of different rates and geometric parameters on the lithium concentration distribution in the active layer are discussed.Results indicate that reduced rates,thinner active layers,shorter active layer lengths,and increased spacing between the working and counter electrodes can lead to a more uniform distribution of lithium concentration in the active layer.These insights help improve experimental methods and equipment,promoting uniform distribution of lithium in the active layer and enhancing measurement accuracy.
基金financially supported by the National Natural Science Foundation of China(Grants nos.62201411,62371378,22205168,52302150 and 62304171)the China Postdoctoral Science Foundation(2022M722500)+1 种基金the Fundamental Research Funds for the Central Universities(Grants nos.ZYTS2308 and 20103237929)Startup Foundation of Xidian University(10251220001).
文摘Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.
基金supported by National Key R&D Program of China(Grant No.2021YFB2601200)Open Fund of National Engineering Research Center of Highway Maintenance Technology(Changsha University of Science&Technology)(No.kfj230207).
文摘The occurrence of top-down(TD)cracking has gradually become a prevalent issue in semi-rigid base asphalt pavements after prolonged service.A coupled simulation model integrating the finite difference method(FDM)and discrete element method(DEM)was employed to investigate the mechanical behavior of asphalt pavement containing a pre-existing TD crack.The mesoscopic parameters of the model were calibrated based on the mixture modulus and the static mechanical response on the MLS66 test road.Finally,an analysis was performed to assess how variations in TD crack depth and longitudinal length affect the distribution patterns of transverse tensile stress,vertical shear stress,and vertical compressive stress.The results indicate that the vertical propagation of TD crack significantly increases both the tensile stress value and range on the middle surface,while the longitudinal development of TD crack has minimal impact.This phenomenon may result in more severe fatigue failure on the middle surface.With the vertical and longitudinal development of TD crack,the vertical shear stress and compressive stress show obvious"two-stage"characteristics.When the crack's vertical length reaches 40 mm,there is a sharp increase in stress on the upper surface.As the crack continues to propagate vertically,the growth of stress on the upper surface becomes negligible,while the stress in the middle and lower layers increased significantly.Conversely,for longitudinal development of TD crack,any changes in stress are insignificant when their length is less than 180 mm;however,as they continue to develop longitudinally beyond this threshold,there is a sharp increase in stress levels.These findings hold great significance for understanding pavement structure deterioration and maintenance behavior associated with TD crack.
基金National Natural Science Foundation of China (U23A6005 and 22078069)Project funded by China Postdoctoral Science Foundation (GZB20230172 and 2023M740748)。
文摘Electrochemical conversion of lignin for the production of high-value heterocyclic aromatic compounds has great potential.We demonstrate the targeted synthesis and cation modulation of NiCo_(2)O_(4)spinel nanoboxes,synthesized via cation exchange and calcination oxidation.These catalysts exhibit excellent efficacy in the electrocatalytic conversion of lignin model compounds,specifically 2-phenoxy-1-phenylethanol,into nitrogen-containing aromatics,achieving high conversion rates and selectivities.These catalysts were synthesized via a cation exchange and calcination oxidation process,using Prussian blue nanocubes as precursors.The porous architecture and polymetallic composition of the NiCo_(2)O_(4)spinel demonstrated superior performance in electrocatalytic oxidative coupling,achieving a 99.2 wt%conversion rate of the 2-phenoxy-1-phenylethanol with selectivities of 37.5 wt%for quinoline derivatives and 31.5 wt%for phenol.Key innovations include the development of a sustainable one-pot synthesis method for quinoline derivatives,the elucidation of a multistage reaction pathway involving CAO bond cleavage,hydroxyaldol condensation,and CAN bond formation,and a deeper mechanistic understanding derived from DFT simulations.This work establishes a new strategy for lignin valorization,offering a sustainable route to produce high-value nitrogen-containing aromatics from renewable biomass under mild conditions,without the need for additional reagents.
基金financially supported by the National Natural Science Foundation of China(Nos.42272153 and 42472195)the Research Fund of PetroChina Tarim Oilfield Company(No.671023060003)the Research Fund of China National Petroleum Corporation Limited(No.2023ZZ16YJ04).
文摘Deep tight reservoirs exhibit complex stress and seepage fields due to varying pore structures,thus the seepage characteristics are significant for enhancing oil production.This study conducted triaxial compression and permeability tests to investigate the mechanical and seepage properties of tight sandstone.A digital core of tight sandstone was built using Computed Tomography(CT)scanning,which was divided into matrix and pore phases by a pore equivalent diameter threshold.A fluid-solid coupling model was established to investigate the seepage characteristics at micro-scale.The results showed that increasing the confining pressure decreased porosity,permeability,and flow velocity,with the pore phase becoming the dominant seepage channel.Cracks and large pores closed first under increasing pressure,resulted in a steep drop in permeability.However,permeability slightly decreased under high confining pressure,which followed a first-order exponential function.Flow velocity increased with seepage pressure.And the damage mainly occurred in stress-concentration regions under low seepage pressure.Seepage behavior followed linear Darcy flow,the damage emerged at seepage entrances under high pressure,which decreased rock elastic modulus and significantly increased permeability.
基金support from Guangdong Science and Technology(20230505)Guangdong Provincial Philosophy and Social Science Planning Project(GD20SQ25)Guangdong Provincial Special Fund for Science and Technology Innovation Strategy in 2024(Cultivation of College Students’Science and Technology Innovation)(pdjh2024a391)during preparation of this manuscript.
文摘This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expansion with environmental protection,a comprehensive evaluation index system is constructed,encompassing two key dimensions:regional economy and ecological environment.Using panel data from 2013 to 2022,the coupling coordination degree model is employed to quantify the interactions and synergy between these dimensions.Additionally,spatial econometric methods are applied to calculate both global and local Moran’s Index,revealing spatial clustering patterns,regional disparities,and heterogeneity.The relative development model further identifies critical factors influencing regional coordination,with a focus on the lagging development of basic infrastructure and public services.The findings demonstrate a positive temporal trend toward improved regional coordination and reduced development gaps,with a spatial pattern characterized by higher coupling degrees in eastern and central regions compared to western areas.Based on these results,this study proposes actionable strategies to enhance coordinated development,emphasizing ecological conservation,the establishment of green production and consumption systems,ecological restoration,and strengthened municipal collaboration.This revised abstract emphasizes the study’s purpose,methods,and key findings more clearly while maintaining a professional and concise tone.Finally,based on the above analysis results,the corresponding coordinated development suggestions of regional economy and ecological environment are given from the aspects of ecological environment protection measures,green production and consumption system construction,ecological environment restoration and municipal coordination.
基金Financial supports from the National Natural Science Foundation of China(Nos.52171116,U22A20109,52334010 and T2325013)are greatly acknowledgedPartial financial support came from The Program for the Central University Youth Innovation Team,and the Fundamental Research Funds for the Central Universities,JLU.
文摘Dislocations and disclinations are fundamental topological defects within crystals,which determine the mechanical properties of metals and alloys.Despite their important roles in multiple physical mechanisms,e.g.,dynamic recovery and grain boundary mediated plasticity,the intrinsic coupling and correlation between disclinations and dislocations,and their impacts on the deformation behavior of metallic materials still remain obscure,partially due to the lack of a theoretical tool to capture the rotational nature of disclinations.By using a Lie-algebra-based theoretical framework,we obtain a general equation to quantify the intrinsic coupling of disclinations and dislocations.Through quasi in-situ electron backscatter diffraction characterizations and disclination/dislocation density analyses in Mg alloys,the generation,coevolution and reactions of disclinations and dislocations during dynamic recovery and superplastic deformation have been quantitatively analyzed.It has been demonstrated that the obtained governing equation can capture multiple physical processes associated with mechanical deformation of metals,e.g.,grain rotation and grain boundary migration,at both room temperature and high temperature.By establishing the disclination-dislocation coupling equation within a Lie algebra description,our work provides new insights for exploring the coevolution and reaction of disclinations/dislocations,with profound implications for elucidating the microstructure-property relationship and underlying deformation mechanisms in metallic materials.
基金supported by the financial aid from the National Natural Science Foundation of China (No. 22271273)International Partnership Program of Chinese Academy of Sciences (No. 121522KYSB20190022)。
文摘Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic structure. In this work, Sb^(3+)/Te^(4+)ions doped Zn-based halide single crystals(SCs) with two STEs emissions have been synthesized and the possibility of its anti-counterfeiting application was explored.Further, the relationship between the strength of electron-phonon coupling and photoluminescence quantum yields(PLQYs) for STEs in a series of metal halides has been studied. And the semi-empirical range of the Huang-Rhys factors(S) for metal halides with excellent photoluminescence(PL) property has been summarized. This work provides ideas for further research into the relationship between luminescence performance and electron-phonon coupling of metal halides, and also provides a reference for designing the metal halides with high PLQYs.
基金the support provided by the National Natural Science Foundation of China(Grant Nos.52278336 and 42302032)Guangdong Basic and Applied Research Foundation(Grant Nos.2023B1515020061).
文摘Granite residual soil (GRS) is a type of weathering soil that can decompose upon contact with water, potentially causing geological hazards. In this study, cement, an alkaline solution, and glass fiber were used to reinforce GRS. The effects of cement content and SiO_(2)/Na2O ratio of the alkaline solution on the static and dynamic strengths of GRS were discussed. Microscopically, the reinforcement mechanism and coupling effect were examined using X-ray diffraction (XRD), micro-computed tomography (micro-CT), and scanning electron microscopy (SEM). The results indicated that the addition of 2% cement and an alkaline solution with an SiO_(2)/Na2O ratio of 0.5 led to the densest matrix, lowest porosity, and highest static compressive strength, which was 4994 kPa with a dynamic impact resistance of 75.4 kN after adding glass fiber. The compressive strength and dynamic impact resistance were a result of the coupling effect of cement hydration, a pozzolanic reaction of clay minerals in the GRS, and the alkali activation of clay minerals. Excessive cement addition or an excessively high SiO_(2)/Na2O ratio in the alkaline solution can have negative effects, such as the destruction of C-(A)-S-H gels by the alkaline solution and hindering the production of N-A-S-H gels. This can result in damage to the matrix of reinforced GRS, leading to a decrease in both static and dynamic strengths. This study suggests that further research is required to gain a more precise understanding of the effects of this mixture in terms of reducing our carbon footprint and optimizing its properties. The findings indicate that cement and alkaline solution are appropriate for GRS and that the reinforced GRS can be used for high-strength foundation and embankment construction. The study provides an analysis of strategies for mitigating and managing GRS slope failures, as well as enhancing roadbed performance.
基金supported by the National Key R&D Program of China(No.2021YFB2011300)the National Natural Science Foundation of China(Nos.52275044,U2233212)。
文摘The Electro–Hydrostatic Actuator(EHA)is applied to drive the control surface in flightcontrol system of more electric aircraft.In EHA,the Oil-Immersed Motor Pump(OMP)serves asthe core as a power assembly.However,the compact integration of the OMP presents challenges inefficiently dissipating internal heat,leading to a performance degradation of the EHA due to ele-vated temperatures.Therefore,accurately modeling and predicting the internal thermal dynamicsof the OMP hold considerable significance for monitoring the operational condition of the EHA.In view of this,a modeling method considering cumulative thermal coupling was hereby proposed.Based on the proposed method,the thermal models of the motor and the pump were established,taking into account heat accumulation and transfer.Taking the leakage oil as the heat couplingpoint between the motor and the pump,the dynamic thermal coupling model of the OMP wasdeveloped,with the thermal characteristics of the oil considered.Additionally,the comparativeexperiments were conducted to illustrate the efficiency of the proposed model.The experimentalresults demonstrate that the proposed dynamic thermal coupling model accurately captured thethermal behavior of OMP,outperforming the static thermal parameter model.Overall,thisadvancement is crucial for effectively monitoring the health of EHA and ensuring flight safety.
基金supported by 2024 Central Guidance Local Science and Technology Development Fund Project"Study on the mechanism and evaluation method of thermal pollution in water bodies,as well as research on thermal carrying capacity".(Grant 246Z4506G)Key Research and Development Project in Hebei Province:"Key Technologies and Equipment Research and Demonstration of Multiple Energy Complementary(Electricity,Heat,Cold System)for Solar Energy,Geothermal Energy,Phase Change Energy"(Grant 236Z4310G)the Hebei Academy of Sciences Key Research and Development Program"Research on Heat Transfer Mechanisms and Efficient Applications of Intermediate and Deep Geothermal Energy"(22702)。
文摘Ground source heat pump systems demonstrate significant potential for northern rural heating applications;however,the effectiveness of these systems is often limited by challenging geological conditions.For instance,in certain regions,the installation of buried pipes for heat exchangers may be complicated,and these pipes may not always serve as efficient low-temperature heat sources for the heat pumps of the system.To address this issue,the current study explored the use of solar-energy-collecting equipment to supplement buried pipes.In this design,both solar energy and geothermal energy provide low-temperature heat to the heat pump.First,a simulation model of a solar‒ground source heat pump coupling system was established using TRNSYS.The accuracy of this model was validated through experiments and simulations on various system configurations,including varying numbers of buried pipes,different areas of solar collectors,and varying volumes of water tanks.The simulations examined the coupling characteristics of these components and their influence on system performance.The results revealed that the operating parameters of the system remained consistent across the following configurations:three buried pipes,burial depth of 20 m,collector area of 6 m^(2),and water tank volume of 0.5 m^(3);four buried pipes,burial depth of 20 m,collector area of 3 m^(2),and water tank volume of 0.5 m^(3);and five buried pipes with a burial depth of 20 m.Furthermore,the heat collection capacity of the solar collectors spanning an area of 3 m^(2)was found to be equivalent to that of one buried pipe.Moreover,the findings revealed that the solar‒ground source heat pump coupling system demonstrated a lower annual cumulative energy consumption compared to the ground source heat pump system,presenting a reduction of 5.31%compared to the energy consumption of the latter.
基金Supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX24_0102)the China Scholarship Council Program(202406190114)。
文摘Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.
文摘For space-borne gravitational wave detection missions based on the heterodyne interferometry principle,tilt-to-length(TTL)coupling noise is an important optical noise source,significantly influencing the accuracy of the measurement system.We present a method for analyzing TTL coupling noise under the joint influence of multiple factors.An equivalent simulated optical bench for the test mass interferometer was designed,and Gaussian beam tracing was adopted to simulate beam propagation.By simulating the interference signal,it can analyze the impact of various factors on the TTL coupling noise,including positional,beam parameters,detector parameters,and signal definition factors.On this basis,a random parameter space composed of multiple influential factors was constructed within a range satisfying the analysis requirement,and the corresponding simulation results from random sampling were evaluated via variance-based global sensitivity analysis.The calculated results of the main and total effect indexes show that the test mass rotation angle and the piston effect(lateral)significantly influence the TTL coupling noise in the test mass interferometer.The analysis provides a qualitative reference for designing and optimizing space-borne laser interferometry systems.
文摘By using a newly developed 4-hydroxy picolinohydrazide as the ligand,Cu-catalyzed coupling of(hetero)aryl chlorides with sodium aryl sulfonates proceeded smoothly at 130℃to give a series of biarylsulfones in 53%~96%yields.This represents the first metal-catalyzed coupling reaction of(hetero)aryl chlorides with sodium aryl sulfonates.Aryl and heteroaryl chlorides bearing either electron-donating or electron-withdrawing groups were applicable for this coupling reaction.
基金supported by the National Natural Science Foundation of China(grant no.52072041)the Beijing Natural Science Foundation(grant no.JQ21007).
文摘Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these materials isfrequently constrained by heat generation during light absorption,resulting in significant thermal losses.Most offerroelectric films produce photocurrent and thermocurrent with opposite polarity,thus weakening the coupledphoto-thermoelectric output of the devices.Here we report on a LaNiO_(3)/BiMn_(2)O_(5)(BMO)/ITO ferroelectric film toproduce photocurrent and thermocurrent with the same polarity.The polarity of the photocurrent generated bythe BMO film is shown to be determined solely by the direction of spontaneous polarization,overcoming thedetrimental effect of Schottky barrier for energy harvesting in device.We propose a new strategy to enhance thecoupling factor,thereby offering valuable new insights for optimizing the utilization of ferroelectric materials inboth light and heat energy applications.
基金supported by the National Natural Science Foundation of China(Grant No.52201290)the Natural Science Foundation of Gansu Province(Grant No.24JRRA402)the 9th Research Institute of China Electronics Technology Group Corporation’s open projects(Grant No.2024SK-001-4).
文摘We report a theoretical analysis of magnon–magnon coupling in a noncollinear magnetic sandwiched structure with interlayer exchange interaction,which consists of two ferromagnetic layers with perpendicular and in-plane magnetic anisotropy,respectively.Based on the Landau–Lifshitz equation,the spin wave dispersion is derived,and then the frequency gap is observed due to the magnon–magnon coupling effect induced by symmetry breaking.The influence of saturation magnetization,exchange coupling interaction,perpendicular magnetic anisotropy,and wave vector on the coupling strength is studied in detail.We find that the coupling strength is strongly dependent on the saturation magnetization and a small saturation magnetization can lead to strong coupling strength.By selecting the appropriate magnetic materials,the ultra-strong coupling regime can be achieved.The precession information in time domain is solved and the alternating change of the precession components in two ferromagnetic layers implies the exchange of energy and information.
基金Humanities and Social Sciences Fund of Ministry of Education of China,No.24YJA630097National Natural Science Foundation of China,No.42471304。
文摘The uneven distribution of medical resources has led to increasingly frequent patient mobility;however, the interaction between this phenomenon and the healthcare supply-demand relationship remains underexplored. The present study constructed the 2023Cross-City Patient Mobility Network in China using one million patient mobility data records obtained from online healthcare platforms. We applied urban network analysis to uncover mobility patterns and used the coupling coordination degree model to assess healthcare supply-demand relationships before and after patient mobility. Explainable machine learning further revealed the impact of supply-demand coupling on patient mobility. The results indicated the following: Patient mobility followed administrative boundaries, although megacities serve areas beyond provincial borders;The scale of healthcare supply and demand displayed a multi-centric spatial pattern with a general decline from east to west, and these characteristics of demand distribution were further solidified by patient mobility;Cities with low supply-demand coupling and undersupply experienced patient outflows, while cities with high coupling and oversupply attracted them. In turn, patient mobility helped balance healthcare supply and demand, optimising the coupling relationship across cities. Thus, this research not only provides a methodological reference for understanding the interaction between patient mobility and healthcare systems but also offers empirical insights for public health policy.