The emergence of mechanically one-way materials presents an exciting opportunity for materials science and engineering. These substances exhibit unique nonreciprocal mechanical responses, enabling them to selectively ...The emergence of mechanically one-way materials presents an exciting opportunity for materials science and engineering. These substances exhibit unique nonreciprocal mechanical responses, enabling them to selectively channel mechanical energy and facilitate directed sound propagation, controlled mass transport, and concentration of mechanical energy amidst random motion. This article explores the fundamentals of mechanically one-way materials, their potential applications across various industries, and the economic and environmental considerations related to their production and use.展开更多
The hot or cold processing would induce the change and the inhomogeneous of the material mechanical properties in the local processing region of the structure,and it is difficult to obtain the specific mechanical prop...The hot or cold processing would induce the change and the inhomogeneous of the material mechanical properties in the local processing region of the structure,and it is difficult to obtain the specific mechanical properties in these regions by using the traditional material tensile test.To accurately get actual material mechanical properties in the local region of structure,a micro-indentation test system incorporated by an electronic universal material test device has been established.An indenter displacement sensor and a group of special micro-indenter assemblies are estab-lished.A numerical indentation inversion analysis method by using ABAQUS software is also proposed in this study.Based on the above test system and analysis platform,an approach to obtaining material mechanical properties in the local region of structures is proposed and established.The ball indentation test is performed and combined with the energy method by using various changed mechanical properties of 316L austenitic stainless steel under differ-ent elongations.The investigated results indicate that the material mechanical properties and the micro-indentation morphological changes have evidently relevance.Compared with the tensile test results,the deviations of material mechanical parameters,such as hardness H,the hardening exponent n,the yield strength σy and others are within 5%obtained through the indentation test and the finite element analysis.It provides an effective and convenient method for obtaining the actual material mechanical properties in the local processing region of the structure.展开更多
Strength and deformability characteristics of rock with pre-existing fissures are governed by cracking behavior. To further research the effects of pre-existing fissures on the mechanical properties and crack coalesce...Strength and deformability characteristics of rock with pre-existing fissures are governed by cracking behavior. To further research the effects of pre-existing fissures on the mechanical properties and crack coalescence process, a series of uniaxial compression tests were carried out for rock-like material with two unparallel fissures.In the present study, cement, quartz sand, and water were used to fabricate a kind of brittle rock-like material cylindrical model specimen. The mechanical properties of rock-like material specimen used in this research were all in good agreement with the brittle rock materials. Two unparallel fissures（a horizontal fissure and an inclined fissure） were created by inserting steel during molding the model specimen.Then all the pre-fissured rock-like specimens were tested under uniaxial compression by a rock mechanics servocontrolled testing system. The peak strength and Young＇s modulus of pre-fissured specimen all first decreased and then increased when the fissure angle increased from 0？to 75？.In order to investigate the crack initiation, propagation and coalescence process, photographic monitoring was adopted to capture images during the entire deformation process.Moreover, acoustic emission（AE） monitoring technique was also used to obtain the AE evolution characteristic of prefissured specimen. The relationship between axial stress, AE events, and the crack coalescence process was set up： when a new crack was initiated or a crack coalescence occurred, thecorresponding axial stress dropped in the axial stress–time curve and a big AE event could be observed simultaneously.Finally, the mechanism of crack propagation under microscopic observation was discussed. These experimental results are expected to increase the understanding of the strength failure behavior and the cracking mechanism of rock containing unparallel fissures.展开更多
The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hyperso...The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hypersonic vehicles. It is our great pleasure to present the seven papers in this special subject of Theoretical ＆ Applied Mechanics Letters （TAML） and introduce the recent progresses on the mechanical behavior of thermal protection materials and structures by the authors.展开更多
The fabrication. microstructure and mechanical properties of ZrO2-Ni functionally gradient materials (FGM ) have been studied. FGM as well as non-FG M of ZrO2-Ni system was developed by powder metallurgical process. X...The fabrication. microstructure and mechanical properties of ZrO2-Ni functionally gradient materials (FGM ) have been studied. FGM as well as non-FG M of ZrO2-Ni system was developed by powder metallurgical process. X-ray diffractometer (XRD ). electron probe microanalyzer (EPMA), scanning electron microscope (SEM ) and optical microscope were employed to investigate the crystalline phases. chemical composition and microstructure Experimental results demonstrate that the composition and microstructure of ZrO2-Ni FGM have the expected gradient distribution. There are no distinct interfaces in the FGM due to the gradient change of components. that is, the constituents are continuous in microstructure everywhere. Moreover, Vickers hardness and flexural strength were measured for the common composites as a function of composition. It is made clear that the mechanical properties of the FGM vary corresponding to the constitutional changes as well展开更多
In this paper,stress distribution is obtained by employing the interface element to simulate the interphase feature between fiber-matrix in single-ply laminar which consists of fiber arranged periodically in the x-axi...In this paper,stress distribution is obtained by employing the interface element to simulate the interphase feature between fiber-matrix in single-ply laminar which consists of fiber arranged periodically in the x-axis direction and matrix,and which is subjected to far-field transverse load the contour of stress σsz and radial stress σr in the vicinity of interphase are plotted for three different interphase cases.It is made known that the effect of interphase properties in stress distribution is obvious.展开更多
Accumulative roll bonding(ARB)is a severe plastic deformation method to prepare the metallic composite material by physical method at room to elevate temperature,without the generation of additional waste solid or gas...Accumulative roll bonding(ARB)is a severe plastic deformation method to prepare the metallic composite material by physical method at room to elevate temperature,without the generation of additional waste solid or gas.With the physical characteristicsmulti-material and hybrid structure,the mechanical and function properties of the ARB composite material,like Al/steel,Al/Mg,Al/Cu,etc.,shall have the"1+1>2"effect on the mechanical and functional properties,including the remarkable properties that include lightweight,high strength,thermal/electrical conductivity,electromagnetic shielding,and other functions.To deeply investigate the preparation method and microstructural evolution of various metal laminates by ARB,as well as the mechanical and functional properties of the laminate,an overview of the history of ARB technique,the breakthrough of ARB sheet properties,as well as the relative products in industries is provided.Addi-tionally,the future development of ARB technology and the utilization of composite materials in different areas will be discussed.展开更多
The Fenton-like reaction between Cu^(2+)and H_(2)O_(2)was employed in chemical mechanical polishing to achieve efficient and high-quality processing of tungsten.The microstructure evolution and material removal rate o...The Fenton-like reaction between Cu^(2+)and H_(2)O_(2)was employed in chemical mechanical polishing to achieve efficient and high-quality processing of tungsten.The microstructure evolution and material removal rate of tungsten during polishing process were investigated via scanning electron microscopy,X-ray photoelectron spectroscopy,ultraviolet−visible spectrophotometry,and electrochemical experiments.The passivation behavior and material removal mechanism were discussed.Results show that the use of mixed H_(2)O_(2)+Cu(NO_(3))_(2)oxidant can achieve higher polishing efficiency and surface quality compared with the single oxidant Cu(NO_(3))_(2)or H_(2)O_(2).The increase in material removal rate is attributed to the rapid oxidation of W into WO_(3)via the chemical reaction between the substrate and hydroxyl radicals produced by the Fenton-like reaction.In addition,material removal rate and static etch rate exhibit significantly different dependencies on the concentration of Cu(NO_(3))_(2),while the superior oxidant for achieving the balance between polishing efficiency and surface quality is 0.5 wt.%H_(2)O_(2)+1.0 wt.%Cu(NO_(3))_(2).展开更多
The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals（·OH）from reactions between recyclable solid catalysts and H2O2 at acidic or even circumneutral pH.Hence,it can effectively oxidiz...The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals（·OH）from reactions between recyclable solid catalysts and H2O2 at acidic or even circumneutral pH.Hence,it can effectively oxidize refractory organics in water or soils and has become a promising environmentally friendly treatment technology.Due to the complex reaction system,the mechanism behind heterogeneous Fenton reactions remains unresolved but fascinating,and is crucial for understanding Fenton chemistry and the development and application of efficient heterogeneous Fenton technologies.Iron-based materials usually possess high catalytic activity,low cost,negligible toxicity and easy recovery,and are a superior type of heterogeneous Fenton catalysts.Therefore,this article reviews the fundamental but important interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials..OH,hydroperoxyl radicals/superoxide anions（HO2./O2^-.）and high-valent iron are the three main types of reactive oxygen species（ROS）,with different oxidation reactivity and selectivity.Based on the mechanisms of ROS generation,the interfacial mechanisms of heterogeneous Fenton systems can be classified as the homogeneous Fenton mechanism induced by surface-leached iron,the heterogeneous catalysis mechanism,and the heterogeneous reaction-induced homogeneous mechanism.Different heterogeneous Fenton systems catalyzed by characteristic iron-based materials are comprehensively reviewed.Finally,related future research directions are also suggested.展开更多
Difficult-to-machine materials (DMMs) are extensively applied in critical fields such as aviation,semiconductor,biomedicine,and other key fields due to their excellent material properties.However,traditional machining...Difficult-to-machine materials (DMMs) are extensively applied in critical fields such as aviation,semiconductor,biomedicine,and other key fields due to their excellent material properties.However,traditional machining technologies often struggle to achieve ultra-precision with DMMs resulting from poor surface quality and low processing efficiency.In recent years,field-assisted machining (FAM) technology has emerged as a new generation of machining technology based on innovative principles such as laser heating,tool vibration,magnetic magnetization,and plasma modification,providing a new solution for improving the machinability of DMMs.This technology not only addresses these limitations of traditional machining methods,but also has become a hot topic of research in the domain of ultra-precision machining of DMMs.Many new methods and principles have been introduced and investigated one after another,yet few studies have presented a comprehensive analysis and summarization.To fill this gap and understand the development trend of FAM,this study provides an important overview of FAM,covering different assisted machining methods,application effects,mechanism analysis,and equipment design.The current deficiencies and future challenges of FAM are summarized to lay the foundation for the further development of multi-field hybrid assisted and intelligent FAM technologies.展开更多
Brittle materials are widely used for producing important components in the industry of optics,optoelectronics,and semiconductors.Ultraprecision machining of brittle materials with high surface quality and surface int...Brittle materials are widely used for producing important components in the industry of optics,optoelectronics,and semiconductors.Ultraprecision machining of brittle materials with high surface quality and surface integrity helps improve the functional performance and lifespan of the components.According to their hardness,brittle materials can be roughly divided into hard-brittle and soft-brittle.Although there have been some literature reviews for ultraprecision machining of hard-brittle materials,up to date,very few review papers are available that focus on the processing of soft-brittle materials.Due to the‘soft’and‘brittle’properties,this group of materials has unique machining characteristics.This paper presents a comprehensive overview of recent advances in ultraprecision machining of soft-brittle materials.Critical aspects of machining mechanisms,such as chip formation,surface topography,and subsurface damage for different machining methods,including diamond turning,micro end milling,ultraprecision grinding,and micro/nano burnishing,are compared in terms of tool-workpiece interaction.The effects of tool geometries on the machining characteristics of soft-brittle materials are systematically analyzed,and dominating factors are sorted out.Problems and challenges in the engineering applications are identified,and solutions/guidelines for future R&D are provided.展开更多
An approach for designing the compliant adaptive wing leading edge with composite material is proposed based on the topology optimization. Firstly, an equivalent constitutive relationship of laminated glass fiber rein...An approach for designing the compliant adaptive wing leading edge with composite material is proposed based on the topology optimization. Firstly, an equivalent constitutive relationship of laminated glass fiber reinforced epoxy composite plates has been built based on the symmetric laminated plate theory. Then, an optimization objective function of compliant adaptive wing leading edge was used to minimize the least square error（LSE） between deformed curve and desired aerodynamics shape. After that, the topology structures of wing leading edge of different glass fiber ply-orientations were obtained by using the solid isotropic material with penalization（SIMP） model and sensitivity filtering technique. The desired aerodynamics shape of compliant adaptive wing leading edge was obtained based on the proposed approach. The topology structures of wing leading edge depend on the glass fiber ply-orientation. Finally, the corresponding morphing experiment of compliant wing leading edge with composite materials was implemented, which verified the morphing capability of topology structure and illustrated the feasibility for designing compliant wing leading edge. The present paper lays the basis of ply-orientation optimization for compliant adaptive wing leading edge in unmanned aerial vehicle（UAV） field.展开更多
Na-ion batteries are considered a promising alternative to Li-ion batteries for large-scale energy storage systems due to their low cost and the natural abundance of Na resource. Great effort is making worldwide to de...Na-ion batteries are considered a promising alternative to Li-ion batteries for large-scale energy storage systems due to their low cost and the natural abundance of Na resource. Great effort is making worldwide to develop high-performance electrode materials for Na-ion batteries,which is critical for Na-ion batteries. This review provides a comprehensive overview of anode materials for Na-ion batteries based on Na-storage mechanism： insertion-based materials, alloy-based materials, conversion-based materials and organic composites. And we summarize the Nastorage mechanism of those anode materials and discuss their failure mechanism. Furthermore, the problems and challenges associated with those anodes are pointed out,and feasible strategies are proposed for designing highperformance anode materials. According to the current state of research, the search for suitable anode materials for Na-ion batteries is still challenging although substantial progress has been achieved. Nevertheless, we believe that high-performance Na-ion batteries would be promising for practical applications in large-scale energy storage systems in the near future.展开更多
Single crystal silicon carbide(SiC)is widely used for optoelectronics applications.Due to the anisotropic characteristics of single crystal materials,the C face and Si face of single crystal SiC have different physica...Single crystal silicon carbide(SiC)is widely used for optoelectronics applications.Due to the anisotropic characteristics of single crystal materials,the C face and Si face of single crystal SiC have different physical properties,which may fit for particular application purposes.This paper presents an investigation of the material removal and associated subsurface defects in a set of scratching tests on the C face and Si face of 4H-SiC and 6H-SiC materials using molecular dynamics simulations.The investigation reveals that the sample material deformation consists of plastic,amorphous transformations and dislocation slips that may be prone to brittle split.The results showed that the material removal at the C face is more effective with less amorphous deformation than that at the Si face.Such a phenomenon in scratching relates to the dislocations on the basal plane(0001)of the SiC crystal.Subsurface defects were reduced by applying scratching cut depths equal to integer multiples of a half molecular lattice thickness,which formed a foundation for selecting machining control parameters for the best surface quality.展开更多
Glass-ceramics have many excellent properties and are widely used in various fields. During the grinding process,the workpiece surface is typically subject to material removal by grit of incremental heights, which has...Glass-ceramics have many excellent properties and are widely used in various fields. During the grinding process,the workpiece surface is typically subject to material removal by grit of incremental heights, which has rarely been the focus of research. As such, it is necessary to study the material removal mechanism of glass-ceramics under consecutive incremental loading, which more closely reflects the actual grinding process. In this paper,to analyze the plastic deformation and residual stress of lithium aluminosilicate(LAS) glass-ceramics, a finite element model is established based on the Drucker–Prager yield criterion for ductile regimes. A nano-scratch test was also conducted and the test results show that both the residual depth and residual stress increase with an increase in the number of increments, and that consecutive incremental loading promotes the plastic deformation of glass-ceramics and increases the residual stress of the material in the ductile-regime process. These findings provide guidance for achieving higher dimensional accuracy in the actual grinding of glass-ceramics parts.展开更多
Vibration-assisted grinding is one of the most promising technologies for manufacturing optical components due to its efficiency and quality advantages.However,the damage and crack propagation mechanisms of materials ...Vibration-assisted grinding is one of the most promising technologies for manufacturing optical components due to its efficiency and quality advantages.However,the damage and crack propagation mechanisms of materials in vibration-assisted grinding are not well understood.In order to elucidate the mechanism of abrasive scratching during vibration-assisted grinding,a kinematic model of vibration scratching was developed.The influence of process parameters on the evolution of vibration scratches to indentation or straight scratches is revealed by displacement metrics and velocity metrics.Indentation,scratch and vibration scratch experiments were performed on quartz glass,and the results showed that the vibration scratch cracks are a combination of indentation cracks and scratch cracks.Vibration scratch cracks change from indentation cracks to scratch cracks as the indenter moves from the entrance to the exit of the workpiece or as the vibration frequency changes from high to low.A vertical vibration scratch stress field model is established for the first time,which reveals that the maximum principal stress and tensile stress distribution is the fundamental cause for inducing the transformation of the vibration scratch cracking system.This model provides a theoretical basis for understanding of the mechanism of material damage and crack propagation during vibration-assisted grinding.展开更多
Electrochemical jet machining(EJM)encounters significant challenges in the microstructuring of chemically inert and passivating materials because an oxide layer is easily formed on the material surface,preventing the ...Electrochemical jet machining(EJM)encounters significant challenges in the microstructuring of chemically inert and passivating materials because an oxide layer is easily formed on the material surface,preventing the progress of electrochemical dissolution.This research demonstrates for the first time a jet-electrolytic plasma micromachining(Jet-EPM)method to overcome this problem.Specifically,an electrolytic plasma is intentionally induced at the jet-material contact area by applying a potential high enough to surmount the surface boundary layer(such as a passive film or gas bubble)and enable material removal.Compared to traditional EJM,introducing plasma in the electrochemical jet system leads to considerable differences in machining performance due to the inclusion of plasma reactions.In this work,the implementation of Jet-EPM for fabricating microstructures in the semiconductor material 4H-SiC is demonstrated,and the machining principle and characteristics of Jet-EPM,including critical parameters and process windows,are comprehensively investigated.Theoretical modeling and experiments have elucidated the mechanisms of plasma ignition/evolution and the corresponding material removal,showing the strong potential of Jet-EPM for micromachining chemically resistant materials.The present study considerably augments the range of materials available for processing by the electrochemical jet technique.展开更多
Realizing the accurate characterization for the dynamic damage process is a great challenge. Here we carry out testing simultaneously for dynamic monitoring and acoustic emission （AE） statistical analysis towards fi...Realizing the accurate characterization for the dynamic damage process is a great challenge. Here we carry out testing simultaneously for dynamic monitoring and acoustic emission （AE） statistical analysis towards fiber composites under mode-Ⅱ delamination damage. The load curve, AE relative energy, amplitude distribution, and amplitude spectrum are obtained and the delamination damage mechanism of the composites is investigated by the microscopic observation of a fractured specimen. The results show that the micro-damage accumulation around the crack tip region has a great effect on the evolutionary process of delamination. AE characteristics and amplitude spectrum represent the damage and the physical mechanism originating from the hierarchical microstructure. Our finding provides a novel aud feasible strategy to simultaneously evaluate the dynamic response and micro-damage mechanism for fiber composites.展开更多
In this paper, with K＋, Ca2＋ and Fe3＋ as the objects of study, retardation of soil-bentonite （SB） barrier materials for metal ions with different valences is investigated, and the adsorption mechanism, migration ...In this paper, with K＋, Ca2＋ and Fe3＋ as the objects of study, retardation of soil-bentonite （SB） barrier materials for metal ions with different valences is investigated, and the adsorption mechanism, migration patterns and permeation behavior are explored so as to provide a theoretical basis for their application. The results show that the adsorption process for metal ions with different valences by SB barrier materials is fast, and the higher the valence, the greater the adsorption capacity. The fitting of the adsorption process conforms to pseudo-second-order adsorption kinetics and Langmuir-Freundlich adsorption equation, which explains that chemical adsorption is the dominating state and that the SB surface has certain heterogeneity. The permeability coefficient of K＋, Ca2＋ and Fe3＋ in SB each has a maximum and the higher the valence, the sooner the maximum appears. Also the higher the valence, the more obvious the effect on SB retardation performance; and the sooner the ion breaks through the barrier wall completely, that is, the wall＇s retardation performance for higher valent ions may decline.展开更多
Diamond particles reinforced aluminum–silicon matrix composites,abbreviated as Al（Si）/diamond composites,were fabricated by squeeze casting.The effect of Si content on the microstructure and mechanical properties o...Diamond particles reinforced aluminum–silicon matrix composites,abbreviated as Al（Si）/diamond composites,were fabricated by squeeze casting.The effect of Si content on the microstructure and mechanical properties of the composites were investigated.The mechanical properties are found to increase monotonically with Si content increasing up to 7.0 wt%.The Al-7.0 wt% Si/diamond composite exhibits tensile strength of 78 MPa,bending strength of 230 MPa,and compressive strength of426 MPa.Al–Si eutectic phases are shown to connect with Al matrix and diamond particles tightly,which is responsible for the enhancement of mechanical properties in the Al（Si）/diamond composites.展开更多
文摘The emergence of mechanically one-way materials presents an exciting opportunity for materials science and engineering. These substances exhibit unique nonreciprocal mechanical responses, enabling them to selectively channel mechanical energy and facilitate directed sound propagation, controlled mass transport, and concentration of mechanical energy amidst random motion. This article explores the fundamentals of mechanically one-way materials, their potential applications across various industries, and the economic and environmental considerations related to their production and use.
基金Supported by National Natural Science Foundation of China(Grant No.52075434)Key R&D Projects in Shaanxi Province(Grant No.2021KW-36).
文摘The hot or cold processing would induce the change and the inhomogeneous of the material mechanical properties in the local processing region of the structure,and it is difficult to obtain the specific mechanical properties in these regions by using the traditional material tensile test.To accurately get actual material mechanical properties in the local region of structure,a micro-indentation test system incorporated by an electronic universal material test device has been established.An indenter displacement sensor and a group of special micro-indenter assemblies are estab-lished.A numerical indentation inversion analysis method by using ABAQUS software is also proposed in this study.Based on the above test system and analysis platform,an approach to obtaining material mechanical properties in the local region of structures is proposed and established.The ball indentation test is performed and combined with the energy method by using various changed mechanical properties of 316L austenitic stainless steel under differ-ent elongations.The investigated results indicate that the material mechanical properties and the micro-indentation morphological changes have evidently relevance.Compared with the tensile test results,the deviations of material mechanical parameters,such as hardness H,the hardening exponent n,the yield strength σy and others are within 5%obtained through the indentation test and the finite element analysis.It provides an effective and convenient method for obtaining the actual material mechanical properties in the local processing region of the structure.
基金supported by the National Natural Science Foundation of China (Grant 51179189)the National Basic Research 973 Program of China (Grant 2013CB036003)+2 种基金the Program for New Century Excellent Talents in University (Grant NCET-120961)Outstanding Innovation Team Project in China University of Mining and Technology (Grant 2014QN002)the Fundamental Research Funds for the Central Universities (Grants 2014YC10 and 2014XT03)
文摘Strength and deformability characteristics of rock with pre-existing fissures are governed by cracking behavior. To further research the effects of pre-existing fissures on the mechanical properties and crack coalescence process, a series of uniaxial compression tests were carried out for rock-like material with two unparallel fissures.In the present study, cement, quartz sand, and water were used to fabricate a kind of brittle rock-like material cylindrical model specimen. The mechanical properties of rock-like material specimen used in this research were all in good agreement with the brittle rock materials. Two unparallel fissures（a horizontal fissure and an inclined fissure） were created by inserting steel during molding the model specimen.Then all the pre-fissured rock-like specimens were tested under uniaxial compression by a rock mechanics servocontrolled testing system. The peak strength and Young＇s modulus of pre-fissured specimen all first decreased and then increased when the fissure angle increased from 0？to 75？.In order to investigate the crack initiation, propagation and coalescence process, photographic monitoring was adopted to capture images during the entire deformation process.Moreover, acoustic emission（AE） monitoring technique was also used to obtain the AE evolution characteristic of prefissured specimen. The relationship between axial stress, AE events, and the crack coalescence process was set up： when a new crack was initiated or a crack coalescence occurred, thecorresponding axial stress dropped in the axial stress–time curve and a big AE event could be observed simultaneously.Finally, the mechanism of crack propagation under microscopic observation was discussed. These experimental results are expected to increase the understanding of the strength failure behavior and the cracking mechanism of rock containing unparallel fissures.
基金support from the Natural Science Foundation of China(91016029,91216302,and 91216301)
文摘The thermal protection materials and structures are widely used in hypersonic vehicles for the purpose of thermal insulation, and their mechanical behavior is one of the key issues in design and manufacture of hypersonic vehicles. It is our great pleasure to present the seven papers in this special subject of Theoretical ＆ Applied Mechanics Letters （TAML） and introduce the recent progresses on the mechanical behavior of thermal protection materials and structures by the authors.
文摘The fabrication. microstructure and mechanical properties of ZrO2-Ni functionally gradient materials (FGM ) have been studied. FGM as well as non-FG M of ZrO2-Ni system was developed by powder metallurgical process. X-ray diffractometer (XRD ). electron probe microanalyzer (EPMA), scanning electron microscope (SEM ) and optical microscope were employed to investigate the crystalline phases. chemical composition and microstructure Experimental results demonstrate that the composition and microstructure of ZrO2-Ni FGM have the expected gradient distribution. There are no distinct interfaces in the FGM due to the gradient change of components. that is, the constituents are continuous in microstructure everywhere. Moreover, Vickers hardness and flexural strength were measured for the common composites as a function of composition. It is made clear that the mechanical properties of the FGM vary corresponding to the constitutional changes as well
文摘In this paper,stress distribution is obtained by employing the interface element to simulate the interphase feature between fiber-matrix in single-ply laminar which consists of fiber arranged periodically in the x-axis direction and matrix,and which is subjected to far-field transverse load the contour of stress σsz and radial stress σr in the vicinity of interphase are plotted for three different interphase cases.It is made known that the effect of interphase properties in stress distribution is obvious.
基金supported by Special Topic of the Industrialization of Scientific and Technological Achievements from Hong Kong and Macao to Guangdong Province(Grant No.2023A0505030002)Shenzhen-Hong Kong-Macao Sciencaend Technology Program(Category C)(Grant No.SGDX20220530111402013)+2 种基金Department of Science and Technology of Guangdong Province(Grant No.2022A0505050081)the Guangdong Major Project of Basic and Applied Basic Research(Grant No.2020B0301030006)the Guangdong Academy of Science Fund(Grant No.2020GDASYL-20200101001).
文摘Accumulative roll bonding(ARB)is a severe plastic deformation method to prepare the metallic composite material by physical method at room to elevate temperature,without the generation of additional waste solid or gas.With the physical characteristicsmulti-material and hybrid structure,the mechanical and function properties of the ARB composite material,like Al/steel,Al/Mg,Al/Cu,etc.,shall have the"1+1>2"effect on the mechanical and functional properties,including the remarkable properties that include lightweight,high strength,thermal/electrical conductivity,electromagnetic shielding,and other functions.To deeply investigate the preparation method and microstructural evolution of various metal laminates by ARB,as well as the mechanical and functional properties of the laminate,an overview of the history of ARB technique,the breakthrough of ARB sheet properties,as well as the relative products in industries is provided.Addi-tionally,the future development of ARB technology and the utilization of composite materials in different areas will be discussed.
文摘The Fenton-like reaction between Cu^(2+)and H_(2)O_(2)was employed in chemical mechanical polishing to achieve efficient and high-quality processing of tungsten.The microstructure evolution and material removal rate of tungsten during polishing process were investigated via scanning electron microscopy,X-ray photoelectron spectroscopy,ultraviolet−visible spectrophotometry,and electrochemical experiments.The passivation behavior and material removal mechanism were discussed.Results show that the use of mixed H_(2)O_(2)+Cu(NO_(3))_(2)oxidant can achieve higher polishing efficiency and surface quality compared with the single oxidant Cu(NO_(3))_(2)or H_(2)O_(2).The increase in material removal rate is attributed to the rapid oxidation of W into WO_(3)via the chemical reaction between the substrate and hydroxyl radicals produced by the Fenton-like reaction.In addition,material removal rate and static etch rate exhibit significantly different dependencies on the concentration of Cu(NO_(3))_(2),while the superior oxidant for achieving the balance between polishing efficiency and surface quality is 0.5 wt.%H_(2)O_(2)+1.0 wt.%Cu(NO_(3))_(2).
基金supported by the National Natural Science Foundation of China (Nos. 21107125, 21577160, 51221892, 51290282 and 41201498)
文摘The heterogeneous Fenton reaction can generate highly reactive hydroxyl radicals（·OH）from reactions between recyclable solid catalysts and H2O2 at acidic or even circumneutral pH.Hence,it can effectively oxidize refractory organics in water or soils and has become a promising environmentally friendly treatment technology.Due to the complex reaction system,the mechanism behind heterogeneous Fenton reactions remains unresolved but fascinating,and is crucial for understanding Fenton chemistry and the development and application of efficient heterogeneous Fenton technologies.Iron-based materials usually possess high catalytic activity,low cost,negligible toxicity and easy recovery,and are a superior type of heterogeneous Fenton catalysts.Therefore,this article reviews the fundamental but important interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials..OH,hydroperoxyl radicals/superoxide anions（HO2./O2^-.）and high-valent iron are the three main types of reactive oxygen species（ROS）,with different oxidation reactivity and selectivity.Based on the mechanisms of ROS generation,the interfacial mechanisms of heterogeneous Fenton systems can be classified as the homogeneous Fenton mechanism induced by surface-leached iron,the heterogeneous catalysis mechanism,and the heterogeneous reaction-induced homogeneous mechanism.Different heterogeneous Fenton systems catalyzed by characteristic iron-based materials are comprehensively reviewed.Finally,related future research directions are also suggested.
基金supported by the National Key Research and Development Project of China (Grant No.2023YFB3407200)the National Natural Science Foundation of China (Grant Nos.52225506,52375430,and 52188102)the Program for HUST Academic Frontier Youth Team (Grant No.2019QYTD12)。
文摘Difficult-to-machine materials (DMMs) are extensively applied in critical fields such as aviation,semiconductor,biomedicine,and other key fields due to their excellent material properties.However,traditional machining technologies often struggle to achieve ultra-precision with DMMs resulting from poor surface quality and low processing efficiency.In recent years,field-assisted machining (FAM) technology has emerged as a new generation of machining technology based on innovative principles such as laser heating,tool vibration,magnetic magnetization,and plasma modification,providing a new solution for improving the machinability of DMMs.This technology not only addresses these limitations of traditional machining methods,but also has become a hot topic of research in the domain of ultra-precision machining of DMMs.Many new methods and principles have been introduced and investigated one after another,yet few studies have presented a comprehensive analysis and summarization.To fill this gap and understand the development trend of FAM,this study provides an important overview of FAM,covering different assisted machining methods,application effects,mechanism analysis,and equipment design.The current deficiencies and future challenges of FAM are summarized to lay the foundation for the further development of multi-field hybrid assisted and intelligent FAM technologies.
文摘Brittle materials are widely used for producing important components in the industry of optics,optoelectronics,and semiconductors.Ultraprecision machining of brittle materials with high surface quality and surface integrity helps improve the functional performance and lifespan of the components.According to their hardness,brittle materials can be roughly divided into hard-brittle and soft-brittle.Although there have been some literature reviews for ultraprecision machining of hard-brittle materials,up to date,very few review papers are available that focus on the processing of soft-brittle materials.Due to the‘soft’and‘brittle’properties,this group of materials has unique machining characteristics.This paper presents a comprehensive overview of recent advances in ultraprecision machining of soft-brittle materials.Critical aspects of machining mechanisms,such as chip formation,surface topography,and subsurface damage for different machining methods,including diamond turning,micro end milling,ultraprecision grinding,and micro/nano burnishing,are compared in terms of tool-workpiece interaction.The effects of tool geometries on the machining characteristics of soft-brittle materials are systematically analyzed,and dominating factors are sorted out.Problems and challenges in the engineering applications are identified,and solutions/guidelines for future R&D are provided.
基金co-supported by the National Natural Science Foundation of China (No. 51375383)Graduate Starting Seed Fund of Northwestern Polytechnical University of China (No. Z2014110)
文摘An approach for designing the compliant adaptive wing leading edge with composite material is proposed based on the topology optimization. Firstly, an equivalent constitutive relationship of laminated glass fiber reinforced epoxy composite plates has been built based on the symmetric laminated plate theory. Then, an optimization objective function of compliant adaptive wing leading edge was used to minimize the least square error（LSE） between deformed curve and desired aerodynamics shape. After that, the topology structures of wing leading edge of different glass fiber ply-orientations were obtained by using the solid isotropic material with penalization（SIMP） model and sensitivity filtering technique. The desired aerodynamics shape of compliant adaptive wing leading edge was obtained based on the proposed approach. The topology structures of wing leading edge depend on the glass fiber ply-orientation. Finally, the corresponding morphing experiment of compliant wing leading edge with composite materials was implemented, which verified the morphing capability of topology structure and illustrated the feasibility for designing compliant wing leading edge. The present paper lays the basis of ply-orientation optimization for compliant adaptive wing leading edge in unmanned aerial vehicle（UAV） field.
基金financially supported by the Fund for Innovative Research Groups of the National Natural Science Foundation of China (No.NSFC51621001)the National Natural Science Foundation of China (No.51671089)+1 种基金Guangdong Natural Science Funds for Distinguished Young Scholar (No.2017B030306004)the Fundamental Research Funds for the Central Universities (No.2017ZD011)
文摘Na-ion batteries are considered a promising alternative to Li-ion batteries for large-scale energy storage systems due to their low cost and the natural abundance of Na resource. Great effort is making worldwide to develop high-performance electrode materials for Na-ion batteries,which is critical for Na-ion batteries. This review provides a comprehensive overview of anode materials for Na-ion batteries based on Na-storage mechanism： insertion-based materials, alloy-based materials, conversion-based materials and organic composites. And we summarize the Nastorage mechanism of those anode materials and discuss their failure mechanism. Furthermore, the problems and challenges associated with those anodes are pointed out,and feasible strategies are proposed for designing highperformance anode materials. According to the current state of research, the search for suitable anode materials for Na-ion batteries is still challenging although substantial progress has been achieved. Nevertheless, we believe that high-performance Na-ion batteries would be promising for practical applications in large-scale energy storage systems in the near future.
基金financial support from National Natural Science Foundation of China(Grant No.51835004 and 51575197)Huaqiao University International Cultivation Program for Outstanding Postgraduates and Subsidized Projec for Postgraduates’Innovative Fund in Scientific Research of Huaqiao University(No.18011080010)。
文摘Single crystal silicon carbide(SiC)is widely used for optoelectronics applications.Due to the anisotropic characteristics of single crystal materials,the C face and Si face of single crystal SiC have different physical properties,which may fit for particular application purposes.This paper presents an investigation of the material removal and associated subsurface defects in a set of scratching tests on the C face and Si face of 4H-SiC and 6H-SiC materials using molecular dynamics simulations.The investigation reveals that the sample material deformation consists of plastic,amorphous transformations and dislocation slips that may be prone to brittle split.The results showed that the material removal at the C face is more effective with less amorphous deformation than that at the Si face.Such a phenomenon in scratching relates to the dislocations on the basal plane(0001)of the SiC crystal.Subsurface defects were reduced by applying scratching cut depths equal to integer multiples of a half molecular lattice thickness,which formed a foundation for selecting machining control parameters for the best surface quality.
基金supported by the National Key Research and Development Program of China (No. 2018YFB1107602)the National Natural Science Foundation of China (Nos. 51875405 & 51375336)。
文摘Glass-ceramics have many excellent properties and are widely used in various fields. During the grinding process,the workpiece surface is typically subject to material removal by grit of incremental heights, which has rarely been the focus of research. As such, it is necessary to study the material removal mechanism of glass-ceramics under consecutive incremental loading, which more closely reflects the actual grinding process. In this paper,to analyze the plastic deformation and residual stress of lithium aluminosilicate(LAS) glass-ceramics, a finite element model is established based on the Drucker–Prager yield criterion for ductile regimes. A nano-scratch test was also conducted and the test results show that both the residual depth and residual stress increase with an increase in the number of increments, and that consecutive incremental loading promotes the plastic deformation of glass-ceramics and increases the residual stress of the material in the ductile-regime process. These findings provide guidance for achieving higher dimensional accuracy in the actual grinding of glass-ceramics parts.
基金co-supported by the National Natural Science Foundation of China(Nos.52275458,and 52275207)the Natural Science Foundation of Tianjin(No.22JCZDJC00050).
文摘Vibration-assisted grinding is one of the most promising technologies for manufacturing optical components due to its efficiency and quality advantages.However,the damage and crack propagation mechanisms of materials in vibration-assisted grinding are not well understood.In order to elucidate the mechanism of abrasive scratching during vibration-assisted grinding,a kinematic model of vibration scratching was developed.The influence of process parameters on the evolution of vibration scratches to indentation or straight scratches is revealed by displacement metrics and velocity metrics.Indentation,scratch and vibration scratch experiments were performed on quartz glass,and the results showed that the vibration scratch cracks are a combination of indentation cracks and scratch cracks.Vibration scratch cracks change from indentation cracks to scratch cracks as the indenter moves from the entrance to the exit of the workpiece or as the vibration frequency changes from high to low.A vertical vibration scratch stress field model is established for the first time,which reveals that the maximum principal stress and tensile stress distribution is the fundamental cause for inducing the transformation of the vibration scratch cracking system.This model provides a theoretical basis for understanding of the mechanism of material damage and crack propagation during vibration-assisted grinding.
基金supported by the National Key R&D Pro-gram of China(No.2021YFF0501700)the National Nat-ural Science Foundation of China(No.51905255)+1 种基金the Project of Guangdong Provincial Department of Education(No.2019KTSCX152)the Shenzhen Science and Technology Pro-gram(No.GJHZ20200731095204014).
文摘Electrochemical jet machining(EJM)encounters significant challenges in the microstructuring of chemically inert and passivating materials because an oxide layer is easily formed on the material surface,preventing the progress of electrochemical dissolution.This research demonstrates for the first time a jet-electrolytic plasma micromachining(Jet-EPM)method to overcome this problem.Specifically,an electrolytic plasma is intentionally induced at the jet-material contact area by applying a potential high enough to surmount the surface boundary layer(such as a passive film or gas bubble)and enable material removal.Compared to traditional EJM,introducing plasma in the electrochemical jet system leads to considerable differences in machining performance due to the inclusion of plasma reactions.In this work,the implementation of Jet-EPM for fabricating microstructures in the semiconductor material 4H-SiC is demonstrated,and the machining principle and characteristics of Jet-EPM,including critical parameters and process windows,are comprehensively investigated.Theoretical modeling and experiments have elucidated the mechanisms of plasma ignition/evolution and the corresponding material removal,showing the strong potential of Jet-EPM for micromachining chemically resistant materials.The present study considerably augments the range of materials available for processing by the electrochemical jet technique.
基金Supported by the Natural Science Foundation of Hebei Province under Grant No E2012201084the National University Students’ Innovative Training Program under Grant No 201410075004
文摘Realizing the accurate characterization for the dynamic damage process is a great challenge. Here we carry out testing simultaneously for dynamic monitoring and acoustic emission （AE） statistical analysis towards fiber composites under mode-Ⅱ delamination damage. The load curve, AE relative energy, amplitude distribution, and amplitude spectrum are obtained and the delamination damage mechanism of the composites is investigated by the microscopic observation of a fractured specimen. The results show that the micro-damage accumulation around the crack tip region has a great effect on the evolutionary process of delamination. AE characteristics and amplitude spectrum represent the damage and the physical mechanism originating from the hierarchical microstructure. Our finding provides a novel aud feasible strategy to simultaneously evaluate the dynamic response and micro-damage mechanism for fiber composites.
基金supported by Public Welfare Special Research of National Environmental Protection of China (No. 201309004)
文摘In this paper, with K＋, Ca2＋ and Fe3＋ as the objects of study, retardation of soil-bentonite （SB） barrier materials for metal ions with different valences is investigated, and the adsorption mechanism, migration patterns and permeation behavior are explored so as to provide a theoretical basis for their application. The results show that the adsorption process for metal ions with different valences by SB barrier materials is fast, and the higher the valence, the greater the adsorption capacity. The fitting of the adsorption process conforms to pseudo-second-order adsorption kinetics and Langmuir-Freundlich adsorption equation, which explains that chemical adsorption is the dominating state and that the SB surface has certain heterogeneity. The permeability coefficient of K＋, Ca2＋ and Fe3＋ in SB each has a maximum and the higher the valence, the sooner the maximum appears. Also the higher the valence, the more obvious the effect on SB retardation performance; and the sooner the ion breaks through the barrier wall completely, that is, the wall＇s retardation performance for higher valent ions may decline.
基金financially supported by the National Natural Science Foundation of China (No.51271017)the Fundamental Research Funds for the Central Universities (No.FRFTP-13-033A)the Program for New Century Excellent Talents in University (No.NCET-10-0227)
文摘Diamond particles reinforced aluminum–silicon matrix composites,abbreviated as Al（Si）/diamond composites,were fabricated by squeeze casting.The effect of Si content on the microstructure and mechanical properties of the composites were investigated.The mechanical properties are found to increase monotonically with Si content increasing up to 7.0 wt%.The Al-7.0 wt% Si/diamond composite exhibits tensile strength of 78 MPa,bending strength of 230 MPa,and compressive strength of426 MPa.Al–Si eutectic phases are shown to connect with Al matrix and diamond particles tightly,which is responsible for the enhancement of mechanical properties in the Al（Si）/diamond composites.
