The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by t...The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by the freezing-point depression method . The results of γ± are 0. 9945-0. 7695, it is in close agreement with that by isopiestic method.展开更多
The moving-mean method is one of the conventional approaches for trend-extraction from a data set. It is usually applied in an empirical way. The smoothing degree of the trend depends on the selections of window lengt...The moving-mean method is one of the conventional approaches for trend-extraction from a data set. It is usually applied in an empirical way. The smoothing degree of the trend depends on the selections of window length and weighted coefficients, which are associated with the change pattern of the data. Are there any uniform criteria for determining them? The present article is a reaction to this fundamental problem. By investigating many kinds of data, the results show that: 1) Within a certain range, the more points which participate in moving-mean, the better the trend function. However, in case the window length is too long, the trend function may tend to the ordinary global mean. 2) For a given window length, what matters is the choice of weighted coefficients. As the five-point case concerned, the local-midpoint, local-mean and global-mean criteria hold. Among these three criteria, the local-mean one has the strongest adaptability, which is suggested for your usage.展开更多
In alloy bar rolling process, the component of alloyed steel influenced the spread coefficient greatly, therefore, the component influence coefficient m of different alloyed steel has been determined firstly to calcul...In alloy bar rolling process, the component of alloyed steel influenced the spread coefficient greatly, therefore, the component influence coefficient m of different alloyed steel has been determined firstly to calculate the maximum spread. Then the curvature radius of stress free surface and the ＂critical point on the contact boundary＂ have been solved, the surface profile of outgoing workpiece has been obtained. Furthermore, the formula of the equivalent contact section area has been proposed and the mean roll radius has been calculated. The bar rolling experiment and the rigid-plastic FEM （finite element method） simulation have been carried out to verify the novel approach. Compared with experimental data and simulation results, the novel approach can be used in setting processing parameter and design of finishing groove.展开更多
文摘The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by the freezing-point depression method . The results of γ± are 0. 9945-0. 7695, it is in close agreement with that by isopiestic method.
文摘The moving-mean method is one of the conventional approaches for trend-extraction from a data set. It is usually applied in an empirical way. The smoothing degree of the trend depends on the selections of window length and weighted coefficients, which are associated with the change pattern of the data. Are there any uniform criteria for determining them? The present article is a reaction to this fundamental problem. By investigating many kinds of data, the results show that: 1) Within a certain range, the more points which participate in moving-mean, the better the trend function. However, in case the window length is too long, the trend function may tend to the ordinary global mean. 2) For a given window length, what matters is the choice of weighted coefficients. As the five-point case concerned, the local-midpoint, local-mean and global-mean criteria hold. Among these three criteria, the local-mean one has the strongest adaptability, which is suggested for your usage.
文摘In alloy bar rolling process, the component of alloyed steel influenced the spread coefficient greatly, therefore, the component influence coefficient m of different alloyed steel has been determined firstly to calculate the maximum spread. Then the curvature radius of stress free surface and the ＂critical point on the contact boundary＂ have been solved, the surface profile of outgoing workpiece has been obtained. Furthermore, the formula of the equivalent contact section area has been proposed and the mean roll radius has been calculated. The bar rolling experiment and the rigid-plastic FEM （finite element method） simulation have been carried out to verify the novel approach. Compared with experimental data and simulation results, the novel approach can be used in setting processing parameter and design of finishing groove.
