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Numerical Simulation on Thermomechanical Coupling Process in Friction Stir-Assisted Wire Arc Additive Manufacturing
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作者 Li Long Xiao Yichen +2 位作者 Shi Lei Chen Ji Wu Chuansong 《稀有金属材料与工程》 北大核心 2026年第1期1-8,共8页
Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit... Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties. 展开更多
关键词 friction stir processing wire arc additive manufacturing numerical simulation thermomechanical coupling temperature field DEFORMATION
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郭为与他的AI for Process
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作者 姜奇平 端利涛 《互联网周刊》 2026年第2期8-12,共5页
一、作为哲学的AI for Process(一)郭为的哲学思想1.郭为是谁郭为是谁?他是一位哲学家。顺便说,他同时还领导着神州数码。为什么说郭为是哲学家呢?因为他在著作中谈到高深的哲学,如“数据如水,奔流不息,无界融合”。他引述古希腊哲学家... 一、作为哲学的AI for Process(一)郭为的哲学思想1.郭为是谁郭为是谁?他是一位哲学家。顺便说,他同时还领导着神州数码。为什么说郭为是哲学家呢?因为他在著作中谈到高深的哲学,如“数据如水,奔流不息,无界融合”。他引述古希腊哲学家赫拉克利特所说的“万物流转”,又说“你不能两次踏进同一条河流,因为新的水不断地流过你的身旁”,他所表达的意思是“世界上唯一不变的就是变化”。 展开更多
关键词 AI for process 郭为
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Towards a blank design method for manufacturing big-tapered profiled ring disk by spinning-rolling process 被引量:1
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作者 Xuechao LI Lianggang GUO +1 位作者 Xiaoqing CHEN Heng LI 《Chinese Journal of Aeronautics》 2025年第1期70-86,共17页
The big-tapered profiled ring disk is a key component of engines for rockets and missiles.A new forming technology,as called spinning-rolling process,has been proposed previously for the high performance,high efficien... The big-tapered profiled ring disk is a key component of engines for rockets and missiles.A new forming technology,as called spinning-rolling process,has been proposed previously for the high performance,high efficiency and low-cost manufacturing of the component.Blank design is the key part of plastic forming process design.For spinning-rolling process,the shape and size of the blank play a crucial role in process stability,deformation behavior and dimensional accuracy.So this work proposes a blank design method to determine the geometry structure and sizes of the blank.The mathematical model for calculating the blank size has been deduced based on volume conservation and neutral layer length invariance principle.The FE simulation and corresponding trial production of an actual big-tapered profiled ring disk show that the proposed blank design method is applicative.In order to obtain a preferred blank,the influence rules of blank size determined by different deformation degrees(rolling ratio k)on the spinning-rolling process are revealed by comprehensive FE simulations.Overall considering the process stability,circularity of the deformed ring disk and forming forces,a reasonable range of deformation degree(rolling ratio k)is recommended for the blank design of the new spinning-rolling process. 展开更多
关键词 Blank design method Spinning-rolling process Big-tapered profiled ring disk Rolling ratio Intelligent FE simulation
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Influence of Process Parameters on Forming Quality of Single-Channel Multilayer by Joule Heat Fuse Additive Manufacturing
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作者 Li Suli Fan Longfei +3 位作者 Chen Jichao Gao Zhuang Xiong Jie Yang Laixia 《稀有金属材料与工程》 北大核心 2025年第5期1165-1176,共12页
To overcome the shortage of complex equipment,large volume,and high energy consumption in space capsule manufacturing,a novel sliding pressure Joule heat fuse additive manufacturing technique with reduced volume and l... To overcome the shortage of complex equipment,large volume,and high energy consumption in space capsule manufacturing,a novel sliding pressure Joule heat fuse additive manufacturing technique with reduced volume and low energy consumption was proposed.But the unreasonable process parameters may lead to the inferior consistency of the forming quality of single-channel multilayer in Joule heat additive manufacturing process,and it is difficult to reach the condition for forming thinwalled parts.Orthogonal experiments were designed to fabricate single-channel multilayer samples with varying numbers of layers,and their forming quality was evaluated.The influence of printing current,forming speed,and contact pressure on the forming quality of the single-channel multilayer was analyzed.The optimal process parameters were obtained and the quality characterization of the experiment results was conducted.Results show that the printing current has the most significant influence on the forming quality of the single-channel multilayer.Under the optimal process parameters,the forming section is well fused and the surface is continuously smooth.The surface roughness of a single-channel 3-layer sample is 0.16μm,and the average Vickers hardness of cross section fusion zone is 317 HV,which lays a foundation for the subsequent use of Joule heat additive manufacturing technique to form thinwall parts. 展开更多
关键词 Joule heat additive manufacturing single-channel multilayer process parameter forming quality
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Assembly processes of rare and abundant microbial taxa are closely related to bacterial and fungal functionality during desert vegetation reestablishment
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作者 Zhouchang YU Wei ZHANG +11 位作者 Pian DUO Ying ZHANG Xingfang TIAN Lin SUN Yuzheng GU Junhong ZHANG Jiaxing SONG Ahejiang SAILIKE Yujie LIANG Rong FU Zhiguo XIE Peizhi YANG 《Pedosphere》 2025年第3期475-489,共15页
Effective vegetation reconstruction plays a vital role in the restoration of desert ecosystems.However,in reconstruction of different vegetation types,the community characteristics,assembly processes,and functions of ... Effective vegetation reconstruction plays a vital role in the restoration of desert ecosystems.However,in reconstruction of different vegetation types,the community characteristics,assembly processes,and functions of different soil microbial taxa under environmental changes are still disputed,which limits the understanding of the sustainability of desert restoration.Hence,we investigated the soil microbial community characteristics and functional attributes of grassland desert(GD),desert steppe(DS),typical steppe(TS),and artificial forest(AF)in the Mu Us Desert,China.Our findings confirmed the geographical conservation of soil microbial composition but highlighted decreased microbial diversity in TS.Meanwhile,the abundance of rare taxa and microbial community stability in TS improved.Heterogeneous and homogeneous selection determined the assembly of rare and abundant bacterial taxa,respectively,with both being significantly influenced by soil moisture.In contrast,fungal communities displayed stochastic processes and exhibited sensitivity to soil nutrient conditions.Furthermore,our investigation revealed a noteworthy augmentation in bacterial metabolic functionality in TS,aligning with improved vegetation restoration and the assemblage of abundant bacterial taxa.However,within nutrient-limited soils(GD,DS,and AF),the assembly dynamics of rare fungal taxa assumed a prominent role in augmenting their metabolic capacity and adaptability to desert ecosystems.These results highlighted the variations in the assembly processes and metabolic functions of soil microorganisms during vegetation reestablishment and provided corresponding theoretical support for anthropogenic revegetation of desert ecosystems. 展开更多
关键词 deterministic processes metabolic function microbial community assembly rare microbial taxa REVEGETATION stochastic processes
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A New Perspective on Fault Detection and Diagnosis for Plantwide Systems in the Era of Smart Process Manufacturing
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作者 Wangyan Li Jie Bao 《Engineering》 2025年第9期19-24,共6页
1.Background In the chemical industry,process plants-commonly referred to as plantwide systems-typically consist of many process units(unit operations).Driven by the considerable economic efficiency offered by complex... 1.Background In the chemical industry,process plants-commonly referred to as plantwide systems-typically consist of many process units(unit operations).Driven by the considerable economic efficiency offered by complex and interactive process designs,modern plantwide systems are becoming increasingly sophisticated.The operation of these processes is typically characterized by the complexity of individual units(subsystems)and the intricate interactions between geographically distributed units through networks of material and energy flows,as well as control loops[1]. 展开更多
关键词 plantwide systems smart process manufacturing process units complex interactions fault detection diagnosis chemical industry networks o
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Acoustic Noise-Based Scroll Compressor Diagnosis during the Manufacturing Process
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作者 Geunil Lee Daeil Kwon 《Computer Modeling in Engineering & Sciences》 2025年第9期3329-3342,共14页
Nondestructive testing(NDT)methods such as visual inspection and ultrasonic testing are widely applied in manufacturing quality control,but they remain limited in their ability to detect defect characteristics.Visual ... Nondestructive testing(NDT)methods such as visual inspection and ultrasonic testing are widely applied in manufacturing quality control,but they remain limited in their ability to detect defect characteristics.Visual inspection depends strongly on operator experience,while ultrasonic testing requires physical contact and stable coupling conditions that are difficult to maintain in production lines.These constraints become more pronounced when defect-related information is scarce or when background noise interferes with signal acquisition in manufacturing processes.This study presents a non-contact acoustic method for diagnosing defects in scroll compressors during the manufacturing process.The diagnostic approach leverages Mel-frequency cepstral coefficients(MFCC),and shorttime Fourier transform(STFT)parameters to capture the rotational frequency and harmonic characteristics of the scroll compressor.These parameters enable the extraction of defect-related features even in the presence of background noise.A convolutional neural network(CNN)model was constructed using MFCCs and spectrograms as image inputs.The proposed method was validated using acoustic data collected from compressors operated at a fixed rotational speed under real manufacturing process.The method identified normal operation and three defect types.These results demonstrate the applicability of this method in noise-prone manufacturing environments and suggest its potential for improving product quality,manufacturing reliability and productivity. 展开更多
关键词 DIAGNOSIS manufacturing process rotational frequency scroll compressor
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A Perspective on Artificial Intelligence for Process Manufacturing
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作者 Vipul Mann Jingyi Lu +1 位作者 Venkat Venkatasubramanian Rafiqul Gani 《Engineering》 2025年第9期60-67,共8页
To achieve sustainable development goals and the requirements of a circular economy,a new class of intelligent computer-aided methods and tools is needed.Artificial intelligence(AI)techniques have been gaining much at... To achieve sustainable development goals and the requirements of a circular economy,a new class of intelligent computer-aided methods and tools is needed.Artificial intelligence(AI)techniques have been gaining much attention due to their ability to provide options to tackle the challenges we are currently facing.However,the successful application of AI to solve problems of current interest requires AI to be integrated with associated process systems engineering methods and tools that are already available or being developed.In this perspective paper,we highlight the use of a collection of process systems engineering methods and tools augmented by AI techniques to solve problems related to process manufacturing,with a focus on chemical product design,process synthesis and design,process control,and process safety and hazards. 展开更多
关键词 Artificial intelligence Machine learning process systems engineering manufacturing
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A novel wire arc additive and subtractive hybrid manufacturing process optimization method
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作者 GUO Yiming ZHANG Wanyuan +2 位作者 XIAO Mingkun SONG Shida ZHANG Xiaoyong 《Journal of Southeast University(English Edition)》 2025年第1期109-117,共9页
A reasonable process plan is an important basis for implementing wire arc additive and subtractive hybrid manufacturing(ASHM),and a new optimization method is proposed.Firstly,the target parts and machining tools are ... A reasonable process plan is an important basis for implementing wire arc additive and subtractive hybrid manufacturing(ASHM),and a new optimization method is proposed.Firstly,the target parts and machining tools are modeled by level set functions.Secondly,the mathematical model of the additive direction optimization problem is established,and an improved particle swarm optimization algorithm is designed to decide the best additive direction.Then,the two-step strategy is used to plan the hybrid manufacturing alternating sequence.The target parts are directly divided into various processing regions;each processing region is optimized based on manufacturability and manufacturing efficiency,and the optimal hybrid manufacturing alternating sequence is obtained by merging some processing regions.Finally,the method is used to outline the process plan of the designed example model and applied to the actual hybrid manufacturing process of the model.The manufacturing result shows that the method can meet the main considerations in hybrid manufacturing.In addition,the degree of automation of process planning is high,and the dependence on manual intervention is low. 展开更多
关键词 wire arc additive manufacturing hybrid manufacturing process optimization MANUFACTURABILITY
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Textile Manufacturing Carbon Emission Analysis Method Based on Holographic Process Model
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作者 GAO Jun LI Jie +1 位作者 BAO Jinsong ZHANG Dan 《Journal of Donghua University(English Edition)》 2025年第6期580-593,共14页
The textile industry,while creating material wealth,also exerts a significant impact on the environment.Particularly in the textile manufacturing phase,which is the most energy-intensive phase throughout the product l... The textile industry,while creating material wealth,also exerts a significant impact on the environment.Particularly in the textile manufacturing phase,which is the most energy-intensive phase throughout the product lifecycle,the problem of high energy usage is increasingly notable.Nevertheless,current analyses of carbon emissions in textile manufacturing emphasize the dynamic temporal characteristics while failing to adequately consider critical information such as material flows and energy consumption.A carbon emission analysis method based on a holographic process model(HPM)is proposed to address these issues.First,the system boundary in the textile manufacturing is defined,and the characteristics of carbon emissions are analyzed.Next,an HPM based on the object-centric Petri net(OCPN)is constructed,and simulation experiments are conducted on three different scenarios in the textile manufacturing.Subsequently,the constructed HPM is utilized to achieve a multi-perspective analysis of carbon emissions.Finally,the feasibility of the method is verified by using the production data of pure cotton products from a certain textile manufacturing enterprise.The results indicate that this method can analyze the impact of various factors on the carbon emissions of pure cotton product production,and by applying targeted optimization strategies,carbon emissions have been reduced by nearly 20%.This contributes to propelling the textile manufacturing industry toward sustainable development. 展开更多
关键词 textile manufacturing carbon emission analysis holographic process model sustainable development
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Progress in additive manufacturing of nickel-based superalloys:materials,processing,microstructures,properties and alloy design
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作者 Li Gong Yu-Bo Li +3 位作者 Xiao-Pei Wang Sai Li Zhi-Gang Yang Hao Chen 《Rare Metals》 2025年第10期7041-7087,共47页
Notable advancements have been made in the additive manufacturing(AM)of aerospace materials,driven by the needs for integrated components with intricate geometries and small-lot production of high-value components.Nic... Notable advancements have been made in the additive manufacturing(AM)of aerospace materials,driven by the needs for integrated components with intricate geometries and small-lot production of high-value components.Nickel-based superalloys,pivotal materials for high-temperature bearing components in aeroengines,present significant challenges in the fabrication of complex parts due to their great hardness.Huge attention and rapid progress have been garnered in AM processing of nicklebased superalloys,largely owing to its distinct benefits in the freedom of fabrication and reduced manufacturing lifecycle.Despite extensive research into AM in nickel-based superalloys,the corresponding results and conclusions are scattered attributed to the variety of nickel-based superalloys and complex AM processing parameters.Therefore,there is still a pressing need for a comprehensive and deep understanding of the relationship between the AM processing and microstructures and mechanical performance of nickel-based superalloys.This review introduces the processing characteristics of four primary AM technologies utilized for superalloys and summarizes the microstructures and mechanical properties prior to and post-heat treatments.Additionally,this review presents innovative superalloys specifically accommodated to AM processing and offers insights into the material development and performance improvement,aiming to provide a valuable assessment on AM processing of nickel-based superalloys and an effective guidance for the future research. 展开更多
关键词 Additive manufacturing Nickel-based superalloys processing optimization Microstructures and mechanical properties Alloy design
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Conformal and rapid micro-molding manufacturing of ultraviolet-curable silver paste on curved surfaces using digital light processing
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作者 Mei-Ling Yang Guo-Xiang Zhou +8 位作者 Ning Xie Kun-Peng Lin Yan-Zhao Zhang Zhe Zhao Yun-Peng He Yu-Hang Zhang Zhi-Hua Yang De-Chang Jia Yu Zhou 《Journal of Materials Science & Technology》 2025年第10期153-161,共9页
Electronic 3D printing possesses a remarkable molding ability and convenience in integrated circuits,flexible wearables,and individual automobile requirements.However,traditional 3D printing technology still struggles... Electronic 3D printing possesses a remarkable molding ability and convenience in integrated circuits,flexible wearables,and individual automobile requirements.However,traditional 3D printing technology still struggles to meet the demands of high precision and high efficiency in the process of fabricating a curved surface circuit,particularly achieving precise silver circuit molding on irregular substrates.Here,a high-precision and muti-scaled conformal manufacturing method for silver circuits is presented through the digital light processing(DLP)of ultraviolet-curable silver paste(UV-SP)with adjustable photocuring properties,enabling the successful preparation of micro-scaled conductive structure on the sharply skewed hook face.The minimum modeling depth and width of the cured silver paste can be well controlled to 10 and 88µm,respectively.Compared with traditional printing technology,the printing efficiency of complex patterns has increased by over 70%.The printed silver circuit demonstrates an exceptionally high electrical conductivity,reaching as high as 1.16×10^(7) S/m.Additionally,the UV-SP exhibits significant manufacturing efficiency and superior molding resolution compared to conventional direct ink writing and inkjet printing techniques,thereby contributing to the attainment of high precision and efficiency of conformal and micro-molding manufacturing in sensors,communication antennas,and other electronic devices based on curved substrates. 展开更多
关键词 Digital light processing Ultraviolet-curable silver paste Conformal manufacturing Silver circuits High precision
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Toward Intelligent and Green Ethylene Manufacturing:An AI-Based Multi-Objective Dynamic Optimization Framework for the Steam Thermal Cracking Process
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作者 Yao Zhang Peng Sha +4 位作者 Meihong Wang Cheng Zheng Shengyuan Huang Xiao Wu Joan Cordiner 《Engineering》 2025年第9期160-171,共12页
With growing concerns over environmental issues,ethylene manufacturing is shifting from a sole focus on economic benefits to an additional consideration of environmental impacts.The operation of the thermal cracking f... With growing concerns over environmental issues,ethylene manufacturing is shifting from a sole focus on economic benefits to an additional consideration of environmental impacts.The operation of the thermal cracking furnace in ethylene manufacturing determines not only the profitability of an ethylene plant but also the carbon emissions it releases.While multi-objective optimization of the thermal cracking furnace to balance profit with environmental impact is an effective solution to achieve green ethylene man-ufacturing,it carries a high computational demand due to the complex dynamic processes involved.In this work,artificial intelligence(AI)is applied to develop a novel hybrid model based on physically consistent machine learning(PCML).This hybrid model not only reduces the computational demand but also retains the interpretability and scalability of the model.With this hybrid model,the computational demand of the multi-objective dynamic optimization is reduced to 77 s.The optimization results show that dynamically adjusting the operating variables with coke formation can effectively improve profit and reduce CO_(2)emissions.In addition,the results from this study indicate that sacrificing 28.97%of the annual profit can significantly reduce the annual CO_(2)emissions by 42.89%.The key findings of this study highlight the great potential for green ethylene manufacturing based on AI through modeling and optimization approaches.This study will be important for industrial practitioners and policy-makers. 展开更多
关键词 Green manufacturing Thermal cracking furnace Artificial intelligence Hybrid modeling Multi-objective optimization process modeling
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AI for Process Manufacturing:Innovations,Trends,and Challenges
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作者 Feng Qian 《Engineering》 2025年第9期1-2,共2页
Process manufacturing is going through a critical transformation in response to escalating demands for efficiency,sustainability,and intelligent innovation.With process manufacturing being characterized by complex wor... Process manufacturing is going through a critical transformation in response to escalating demands for efficiency,sustainability,and intelligent innovation.With process manufacturing being characterized by complex workflows and high resource consumption,the process manufacturing industry is under mounting pressure to optimize resource utilization,enhance intelligent design,reduce carbon emissions,and address emerging challenges in quality assurance,safety,and information integration. 展开更多
关键词 SUSTAINABILITY innovations critical transformation efficiency TRENDS CHALLENGES process manufacturing optimize resource utilizationenhance intelligent designreduce carbon emissionsand
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Cost-Benefit Analysis of Continuous Manufacturing vs. Batch Processing in Biopharmaceutical Engineering Design: A Project Management Perspective
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作者 Yang Ge 《Science International Innovative Medicine》 2025年第3期1-4,共4页
This paper investigates the economic and operational trade-offs between continuous manufacturing and batch processing in the context of biopharmaceutical engineering design,through the lens of project management.The s... This paper investigates the economic and operational trade-offs between continuous manufacturing and batch processing in the context of biopharmaceutical engineering design,through the lens of project management.The study explores the fundamental principles of both manufacturing modes,assesses their implications on capital and operational expenditures,and evaluates their performance against key project management metrics such as cost,time,quality,and risk.Drawing on current regulatory guidance,industrial practices,and technological advances,the paper concludes that while continuous manufacturing offers significant benefits in process efficiency and quality control,its implementation requires substantial upfront investment,risk management,and stakeholder alignment.The study aims to support informed decision-making in early-stage biopharmaceutical facility and process design. 展开更多
关键词 Continuous manufacturing Batch processing Biopharmaceutical Engineering Cost-Benefit Analysis Project Management Facility Design Operational Efficiency Regulatory Compliance
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Call for Papers from Agricultural Products Processing and Storage
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《肉类研究》 北大核心 2026年第1期I0017-I0017,共1页
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ... Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics. 展开更多
关键词 NUTRITION SCIENCE open access journal agricultural products processing STORAGE technology ENGINEERING agricultural product
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A Knowledge Push Method of Complex Product Assembly Process Design Based on Distillation Model-Based Dynamically Enhanced Graph and Bayesian Network
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作者 Fengque Pei Yaojie Lin +2 位作者 Jianhua Liu Cunbo Zhuang Sikuan Zhai 《Chinese Journal of Mechanical Engineering》 2025年第6期117-134,共18页
Under the paradigm of Industry 5.0,intelligent manufacturing transcends mere efficiency enhancement by emphasizing human-machine collaboration,where human expertise plays a central role in assembly processes.Despite a... Under the paradigm of Industry 5.0,intelligent manufacturing transcends mere efficiency enhancement by emphasizing human-machine collaboration,where human expertise plays a central role in assembly processes.Despite advancements in intelligent and digital technologies,assembly process design still heavily relies on manual knowledge reuse,and inefficiencies and inconsistent quality in process documentation are caused.To address the aforementioned issues,this paper proposes a knowledge push method of complex product assembly process design based on distillation model-based dynamically enhanced graph and Bayesian network.First,an initial knowledge graph is constructed using a BERT-BiLSTM-CRF model trained with integrated human expertise and a fine-tuned large language model.Then,a confidence-based dynamic weighted fusion strategy is employed to achieve dynamic incremental construction of the knowledge graph with low resource consumption.Subsequently,a Bayesian network model is constructed based on the relationships between assembly components,assembly features,and operations.Bayesian network reasoning is used to push assembly process knowledge under different design requirements.Finally,the feasibility of the Bayesian network construction method and the effectiveness of Bayesian network reasoning are verified through a specific example,significantly improving the utilization of assembly process knowledge and the efficiency of assembly process design. 展开更多
关键词 Complex product assembly process Large language model Dynamic incremental construction of knowledge graph Bayesian network Knowledge push
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Synthesis, separation and structure of zinc coordination clusters: Proposal of an assembly-disassembly-reassembly process observed from ESI-MS
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作者 Huang-Ling Lin Meng-Zhen Xu +4 位作者 Tian-Ying Gu Xing-Xing Shi Mao Le Zheng Yin Ming-Hua Zeng 《Chinese Journal of Structural Chemistry》 2025年第7期11-18,共8页
In mass spectrometry, fragments with a mass higher than the original molecular ion provide valuable insights into the molecular structure and can guide the assembly and disassembly processes for chemical synthesis. He... In mass spectrometry, fragments with a mass higher than the original molecular ion provide valuable insights into the molecular structure and can guide the assembly and disassembly processes for chemical synthesis. Here, we report such an example and following up by modifying the solvothermal reaction conditions (temperature and time) it is possible to isolate the high mass species in crystalline form. [Zn_(4)L_(4)Cl_(4)] (Zn_(4)L_(4), L = N-methylbenzimidazole-2-methanolate) has a boat-like Zn_(4)O_(4) core but electrospray ionization mass spectrometry (ESI-MS) of the solution of its crystals shows higher mass peaks of Zn_(5)L_(5), Zn_(5)L_(6) and Zn_(6)L_(6) species. Thus, both disassembly and reassembly are highly probable processes. Consequently, [Zn(HL)_(2)Cl_(2)] (Zn1, L = N-methylbenzimidazole-2-methanolate), [Zn_(4)L_(6)Cl_(2)] (Zn_(4)L_(6), L = N-methylbenzimidazole-2-methanolate) and [Zn_(6)L_(6)Cl_(4)(CH_(3)O)_(2)] (Zn_(6)L_(6), L = N-methylbenzimidazole-2-methanolate) were prepared. The results of multistage ESI-MS of their dissolved crystals led to a proposed mechanism of their formation in the gas phase as follows: [Zn_(3)L_(4)] through [ZnL] → [ZnL(HL)] → [Zn(HL)_(2)] → [Zn_(2)L] → [Zn_(2)L_(2)] → [Zn_(2)L_(3)]. The mechanism was derived in conjunction with Gibbs free energies calculated using DFT of the fragments observed in the ESI-MS of Zn_(4)L_(4), Zn_(4)L_(6) and Zn_(6)L_(6). This work reveals the complex of chemical reactions, involving fragmentation and unexpected combination, under mass spectrometry condition which allows one to synthesize the observed transients, leading to mechanism of formation by correlation of solid-state/solution structural information. 展开更多
关键词 Open cubane cluster ESI-MS Correlation of crystal/solution/gas structural information Synthesis and isolation assembly-disassembly-reassembly process
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DriftXMiner: A Resilient Process Intelligence Approach for Safe and Transparent Detection of Incremental Concept Drift in Process Mining
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作者 Puneetha B.H Manoj Kumar M.V +1 位作者 Prashanth B.S. Piyush Kumar Pareek 《Computers, Materials & Continua》 2026年第1期1086-1118,共33页
Processes supported by process-aware information systems are subject to continuous and often subtle changes due to evolving operational,organizational,or regulatory factors.These changes,referred to as incremental con... Processes supported by process-aware information systems are subject to continuous and often subtle changes due to evolving operational,organizational,or regulatory factors.These changes,referred to as incremental concept drift,gradually alter the behavior or structure of processes,making their detection and localization a challenging task.Traditional process mining techniques frequently assume process stationarity and are limited in their ability to detect such drift,particularly from a control-flow perspective.The objective of this research is to develop an interpretable and robust framework capable of detecting and localizing incremental concept drift in event logs,with a specific emphasis on the structural evolution of control-flow semantics in processes.We propose DriftXMiner,a control-flow-aware hybrid framework that combines statistical,machine learning,and process model analysis techniques.The approach comprises three key components:(1)Cumulative Drift Scanner that tracks directional statistical deviations to detect early drift signals;(2)a Temporal Clustering and Drift-Aware Forest Ensemble(DAFE)to capture distributional and classification-level changes in process behavior;and(3)Petri net-based process model reconstruction,which enables the precise localization of structural drift using transition deviation metrics and replay fitness scores.Experimental validation on the BPI Challenge 2017 event log demonstrates that DriftXMiner effectively identifies and localizes gradual and incremental process drift over time.The framework achieves a detection accuracy of 92.5%,a localization precision of 90.3%,and an F1-score of 0.91,outperforming competitive baselines such as CUSUM+Histograms and ADWIN+Alpha Miner.Visual analyses further confirm that identified drift points align with transitions in control-flow models and behavioral cluster structures.DriftXMiner offers a novel and interpretable solution for incremental concept drift detection and localization in dynamic,process-aware systems.By integrating statistical signal accumulation,temporal behavior profiling,and structural process mining,the framework enables finegrained drift explanation and supports adaptive process intelligence in evolving environments.Its modular architecture supports extension to streaming data and real-time monitoring contexts. 展开更多
关键词 process mining concept drift gradual drift incremental drift clustering ensemble techniques process model event log
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Neurodegenerative processes of aging: A perspective of restoration through insulin-like growth factor-1
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作者 Rosana Crespo Claudia Herenu 《Neural Regeneration Research》 2026年第4期1562-1563,共2页
The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurode... The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurodegenerative diseases are characterized by the progressive loss of neuronal structure and function. 展开更多
关键词 neurodegenerative diseases neurodegenerative processes cognitive impairments progressive loss neuronal structure function develo ping neurological dysfunctions insulin growth factor RESTORATION aging process
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