Inducing ferromagnetism into graphene is vital today because it has a wide range of applications such as spintronics devices and magnetic memory devices. In this paper, we will report a new method to synthesize ferrom...Inducing ferromagnetism into graphene is vital today because it has a wide range of applications such as spintronics devices and magnetic memory devices. In this paper, we will report a new method to synthesize ferromagnetic graphene by nitrogen doping. X-ray photoelectron spectroscopy(XPS) and Raman spectroscopy were utilized to testify the N-doped material and further discuss the N-doped process.The superconducting quantum interference device(SQUID) was put in and used to analyze the magnetic properties of the N-doped graphene sheets. It shows that the material exhibits ferromagnetism at both 3 K and 300 K and the ferromagnetic saturation moment is 0.412 emu/g and 0.051 emu/g, respectively.The mechanism of the origin of the ferromagnetism in N-doped graphene sheets will also be discussed in this paper. It shows that, when the amount graphitic N reached the threshold, the origin of the ferromagnetism will change from defects induced by nitrogen atoms to the transition in energy band caused by graphitic N.展开更多
Experimental and theoretical researches on nanostructured exchange coupled magnets have been carried out since about 1988. Here, we review the structure and magnetic properties of the anisotropic nanocomposite soft/ha...Experimental and theoretical researches on nanostructured exchange coupled magnets have been carried out since about 1988. Here, we review the structure and magnetic properties of the anisotropic nanocomposite soft/hard multilayer magnets including some new results and phenomena from an experimental point of view. According to the different component of the oriented hard phase in the nanocomposite soft/hard multilayer magnets, three types of magnets will be discussed：1） anisotropic Nd2Fe（14）B based nanocomposite multilayer magnets, 2） anisotropic SmCo5 based nanocomposite multilayer magnets, and 3） anisotropic rare-earth free based nanocomposite multilayer magnets. For each of them, the formation of the oriented hard phase, exchange coupling, coercivity mechanism, and magnetic properties of the corresponding anisotropic nanocomposite multilayer magnets are briefly reviewed, and then the prospect of realization of bulk magnets on new results of anisotropic nanocomposite multilayer magnets will be carried out.展开更多
基金supported by National Natural Science Foundation of China (Nos. 21271082 and 21371068)。
文摘Inducing ferromagnetism into graphene is vital today because it has a wide range of applications such as spintronics devices and magnetic memory devices. In this paper, we will report a new method to synthesize ferromagnetic graphene by nitrogen doping. X-ray photoelectron spectroscopy(XPS) and Raman spectroscopy were utilized to testify the N-doped material and further discuss the N-doped process.The superconducting quantum interference device(SQUID) was put in and used to analyze the magnetic properties of the N-doped graphene sheets. It shows that the material exhibits ferromagnetism at both 3 K and 300 K and the ferromagnetic saturation moment is 0.412 emu/g and 0.051 emu/g, respectively.The mechanism of the origin of the ferromagnetism in N-doped graphene sheets will also be discussed in this paper. It shows that, when the amount graphitic N reached the threshold, the origin of the ferromagnetism will change from defects induced by nitrogen atoms to the transition in energy band caused by graphitic N.
基金Project supported by the State Key Project of Research and Development of China(Grant No.2017YFA0206302)the National Nature Science Foundation of China(Grant Nos.51590883,51331006,and 51471167)the Chinese Academy of Sciences(Grant No.KJZD-EW-M05-3)
文摘Experimental and theoretical researches on nanostructured exchange coupled magnets have been carried out since about 1988. Here, we review the structure and magnetic properties of the anisotropic nanocomposite soft/hard multilayer magnets including some new results and phenomena from an experimental point of view. According to the different component of the oriented hard phase in the nanocomposite soft/hard multilayer magnets, three types of magnets will be discussed：1） anisotropic Nd2Fe（14）B based nanocomposite multilayer magnets, 2） anisotropic SmCo5 based nanocomposite multilayer magnets, and 3） anisotropic rare-earth free based nanocomposite multilayer magnets. For each of them, the formation of the oriented hard phase, exchange coupling, coercivity mechanism, and magnetic properties of the corresponding anisotropic nanocomposite multilayer magnets are briefly reviewed, and then the prospect of realization of bulk magnets on new results of anisotropic nanocomposite multilayer magnets will be carried out.
