Crystalline porous materials are increasingly significant in synthetic and materials chemistry.Nonetheless,their broad industrial deployment is hampered by challenges in stability,production cost,scalability,and regen...Crystalline porous materials are increasingly significant in synthetic and materials chemistry.Nonetheless,their broad industrial deployment is hampered by challenges in stability,production cost,scalability,and regenerability.Herein,we introduce a one-pot synthetic methodology for fabricating macrocyclebased hydrogen-bonded organic frameworks utilizing commercially available materials.Notably,mHOFSYSU101,as a distinguished exemplar,can be synthesized on a multigram scale with near-quantitative yield from raw materials of merely 70%purity,underscoring its substantial cost-efficiency.mHOFSYSU101 demonstrates extraordinary thermal stability up to 400°C,and exhibits remarkable chemical resilience under complex and harsh conditions over a week.This sustained stability is attributed to the strategic integration of hydrophobic methyl groups that insulate hydrogen bonds from polar molecules,coupled with multiple noncovalent interactions within its architecture.Leveraging its intrinsic onedimensional hydrophobic channels and hydrophilic surfaces,mHOF-SYSU101 achieves a remarkable 99%adsorption of iodine from seawater in just 2 min and maintains this fully reversible adsorption capacity over five cycles,showing great practical utility for the nuclear power industry.Moreover,mHOFSYSU101 can be regenerated by introducing its trifluoroacetic acid solution into dimethyl sulfoxide or methanol,endowing mHOF-SYSU101 with unprecedented processibility and recyclability.This study paves new pathways for achieving the industrial application of crystalline porous materials.展开更多
基金support from the National Natural Science Foundation of China(grant nos.21272285,22090061,and 3100041031094)Natural Science Foundation of Guangdong Province(grant nos.2021A1515010132 and 2022A1515010051)Singlecrystal structure characterization was supported by the Shanghai Synchrotron Radiation Facility.Computational resources were provided by the National Supercomputer Center in Guangzhou.
文摘Crystalline porous materials are increasingly significant in synthetic and materials chemistry.Nonetheless,their broad industrial deployment is hampered by challenges in stability,production cost,scalability,and regenerability.Herein,we introduce a one-pot synthetic methodology for fabricating macrocyclebased hydrogen-bonded organic frameworks utilizing commercially available materials.Notably,mHOFSYSU101,as a distinguished exemplar,can be synthesized on a multigram scale with near-quantitative yield from raw materials of merely 70%purity,underscoring its substantial cost-efficiency.mHOFSYSU101 demonstrates extraordinary thermal stability up to 400°C,and exhibits remarkable chemical resilience under complex and harsh conditions over a week.This sustained stability is attributed to the strategic integration of hydrophobic methyl groups that insulate hydrogen bonds from polar molecules,coupled with multiple noncovalent interactions within its architecture.Leveraging its intrinsic onedimensional hydrophobic channels and hydrophilic surfaces,mHOF-SYSU101 achieves a remarkable 99%adsorption of iodine from seawater in just 2 min and maintains this fully reversible adsorption capacity over five cycles,showing great practical utility for the nuclear power industry.Moreover,mHOFSYSU101 can be regenerated by introducing its trifluoroacetic acid solution into dimethyl sulfoxide or methanol,endowing mHOF-SYSU101 with unprecedented processibility and recyclability.This study paves new pathways for achieving the industrial application of crystalline porous materials.
