The study of scale up for the oxidative coupling of methane （OCM） has been carried out in a 200 ml stainless steel fixed-bed reactor over a 5wt% Na2WO4-1.9wt% Mn/SiO2 （W-Mn/SiO2） catalyst. The effects of reaction ...The study of scale up for the oxidative coupling of methane （OCM） has been carried out in a 200 ml stainless steel fixed-bed reactor over a 5wt% Na2WO4-1.9wt% Mn/SiO2 （W-Mn/SiO2） catalyst. The effects of reaction conditions were investigated in detail. The results showed that, with increasing reaction temperature, the gas-phase reaction was enhanced and a significant amount of methane was converted into COx; with the CH4/O2 molar ratio of 5, the highest C2 （ethylene and ethane） yield of 25% was achieved; the presence of steam （as diluent） had a positive effect on the C2 selectivity and yield. Under lower methane gaseous hourly space velocity （GHSV）, higher selectivity and yield of C2 were obtained as the result of the decrease of released heat energy. In 100 h reaction time, the C2 selectivity of 66%-61% and C2 yield of 24.2%-25.4% were achieved by a single pass without any significant loss in catalytic performance.展开更多
A model of vibrating device coupling two pendulums (VDP) which is highly nonlinear was put forward to conduct vibration analysis. Based on energy analysis, dynamic equations with cubic nonlinearities were established ...A model of vibrating device coupling two pendulums (VDP) which is highly nonlinear was put forward to conduct vibration analysis. Based on energy analysis, dynamic equations with cubic nonlinearities were established using Lagrange's equation. In order to obtain approximate solution, multiple time scales method, one of perturbation technique, was applied. Cases of non-resonant and 1:1:2:2 internal resonant were discussed. In the non-resonant case, the validity of multiple time scales method is confirmed, comparing numerical results derived from fourth order Runge-Kutta method with analytical results derived from first order approximate expression. In the 1:1:2:2 internal resonant case, modal amplitudes of Aa1 and Ab2 increase, respectively, from 0.38 to 0.63 and from 0.19 to 0.32, while the corresponding frequencies have an increase of almost 1.6 times with changes of initial conditions, indicating the existence of typical nonlinear phenomenon. In addition, the chaotic motion is found under this condition.展开更多
It is shown that the fine structure constant at Planck times tends to one as well as those of the weak and strong interactions. This results by constraining them at the Planck force. That seems to provide interesting ...It is shown that the fine structure constant at Planck times tends to one as well as those of the weak and strong interactions. This results by constraining them at the Planck force. That seems to provide interesting new results which confirm that at the beginning of space time (Planck scale) all fundamental forces converge to the same unit value.展开更多
Through field sampling survey of 18 villages over coal resources in 3 townships and towns in Zezhou County,Jincheng City,Shanxi Province,this paper analyzed the favorable conditions and obstacles for villages over coa...Through field sampling survey of 18 villages over coal resources in 3 townships and towns in Zezhou County,Jincheng City,Shanxi Province,this paper analyzed the favorable conditions and obstacles for villages over coal resources to carry out farmland scale management.On this basis,combined with the integrated land consolidation measures in villages over coal resources and their effectiveness,and using the principles of system dynamics,it studied the coupling relationship between integrated land consolidation in villages over coal resources and farmland scale management and built a coupling model.It found that the integrated land consolidation system of villages over coal resources has a coupling relationship with the external and internal conditions of the farmland scale management system at the regional and project scales.The two systems interact with and influence each other through the"bridge"of"agricultural modernization condition".The study indicates that at the same time of integrated land consolidation of villages over coal resources caring about the improvement of internal conditions,it is also necessary to improve the external conditions of farmland scale management through regional scale measures such as laws and policies,to support the implementation of land consolidation projects,and realize farmland scale management.展开更多
By the two-scale homogenization approach we justify a two-scale model of ion transport through a layered membrane, with flows being driven by a pressure gradient and an external electrical field. By up-scaling, the el...By the two-scale homogenization approach we justify a two-scale model of ion transport through a layered membrane, with flows being driven by a pressure gradient and an external electrical field. By up-scaling, the electroosmotic flow equations in horizontal thin slits separated by thin solid layers are approximated by a homogenized system of macroscale equations in the form of the Poisson equation for induced vertical electrical field and Onsager's reciprocity relations between global fluxes (hydrodynamic and electric) and forces (horizontal pressure gradient and external electrical field). In addition, the two-scale approach provides macroscopic mobility coefficients in the Onsager relations. On this way, the cross-coupling kinetic coefficient is obtained in a form which does involves the ζ -potential among the data provided the surface current is negligible.展开更多
Debris flow forecast is an important means of disaster mitigation. However, the accuracy of the statistics-based debris flow forecast is unsatisfied while the mechanism-based forecast is unavailable at the watershed s...Debris flow forecast is an important means of disaster mitigation. However, the accuracy of the statistics-based debris flow forecast is unsatisfied while the mechanism-based forecast is unavailable at the watershed scale because most of existing researches on the initiation mechanism of debris flow took a single slope as the main object. In order to solve this problem, this paper developed a model of debris flow forecast based on the water-soil coupling mechanism at the watershed scale. In this model, the runoff and the instable soil caused by the rainfall in a watershed is estimated by the distrib- uted hydrological model （GBHM） and an instable identification model of the unsaturated soil. Because the debris flow is a special fluid composed of soil and water and has a bigger density, the density esti- mated by the runoff and instable soil mass in a watershed under the action of a rainfall is employed as a key factor to identify the formation probability of debris flow in the forecast model. The Jiangjia Gulley, a typical debris flow valley with a several debris flow events each year, is selected as a case study watershed to test this forecast model of debris flow. According the observation data of Dongchuan Debris Flow Observation and Research Station, CAS located in Jiangjia Gulley, there were 4 debris flow events in 2006. The test results show that the accuracy of the model is satisfied.展开更多
A new higher-order continuum model is proposed by considering the coupling and lane changing effects of the vehicles on two adjacent lanes. A stability analysis of the proposed model provides the conditions that ensur...A new higher-order continuum model is proposed by considering the coupling and lane changing effects of the vehicles on two adjacent lanes. A stability analysis of the proposed model provides the conditions that ensure its linear stability. Issues related to lane changing, shock waves and rarefaction waves, local clustering and phase transition are also investigated with numerical experiments. The simulation results show that the proposed model is capable of providing explanations to some particular traffic phenomena commonly observable in real traffic flows.展开更多
In this paper, the iterative coupling approach is proposed for applications to solving multiphase flow equation systems in reservoir simulation, as it provides a more flexible time-stepping strategy than existing appr...In this paper, the iterative coupling approach is proposed for applications to solving multiphase flow equation systems in reservoir simulation, as it provides a more flexible time-stepping strategy than existing approaches. The iterative method decouples the whole equation systems into pressure and saturation/concentration equations, and then solves them in sequence, implicitly and semi-implicitly. At each time step, a series of iterations are computed, which involve solving linearized equations using specific tolerances that are iteration dependent. Following convergence of subproblems, material balance is checked. Convergence of time steps is based on material balance errors. Key components of the iterative method include phase scaling for deriving a pressure equation and use of several advanced numerical techniques. The iterative model is implemented for parallel computing platforms and shows high parallel efficiency and scalability.展开更多
The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic sheari...The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic shearing and opening of intersecting fractures at discrete fracture scales as a result of coupled processes,and contact alteration along rough fracture surfaces that triggers structural and physical changes of fractures at micro-asperity scale.In this paper,these challenges are tackled by developing a comprehensive modeling approach for coupled processes in fractured geological media based on numerical manifold method(NMM)at multiple scales.Based on their distinct geometric features,fractures are categorized into three different scales:dominant fracture,discrete fracture,and discontinuum asperity scales.Here the scale is relative,that of the fracture relative to that of the research interest or domain.Different geometric representations of fractures at different scales are used,and different governing equations and constitutive relationships are applied.For dominant fractures,a finite thickness zone model is developed to treat a fracture as a porous nonlinear domain.Nonlinear fracture mechanical behavior is accurately modeled with an implicit approach based on strain energy.For discrete fractures,a zero-dimensional model was developed for analyzing fluid flow and mechanics in fractures that are geometrically treated as boundaries of the rock matrix.With the zero-dimensional model,these fractures can be modeled with arbitrary orientations and intersections.They can be fluid conduits or seals,and can be open,bonded or sliding.For the discontinuum asperity scale,the geometry of rough fracture surfaces is explicitly represented and contacts involving dynamic alteration of contacts among asperities are rigorously calculated.Using this approach,fracture alteration caused by deformation,re-arrangement and sliding of rough surfaces can be captured.Our comprehensive model is able to handle the computational challenges with accurate representation of intersections and shearing of fractures at the discrete fracture scale and rigorously treats contacts along rough fracture surfaces at the discontinuum asperity scale.With future development of three-dimensional(3D)geometric representation of discrete fracture networks in porous rock and contacts among multi-body systems,this model is promising as a basis of 3D fully coupled analysis of fractures at multiple scales,for advancing understanding and optimizing energy recovery and storage in fractured geological media.展开更多
On the basis of giving an overview of efficiency research on transformation of land from fragmentation to scale economy, by using the concept of coupling in physics, this paper expounds the behavior basis of transfer ...On the basis of giving an overview of efficiency research on transformation of land from fragmentation to scale economy, by using the concept of coupling in physics, this paper expounds the behavior basis of transfer of surplus rural labor forces in China and transformation of land from fragmentation to scaling up, and analyzes behaviors of all parties and equilibrium outcomes in the three stages concerning the transformation of agricultural land from fragmentation to scaling up as follows. At the first stage of coupling, after multitudinous rural surplus labor forces emerge, the farmers begin to go to city seeking jobs. In this period, the amalgamation of land management has not occurred and the single farmer's land has not yet concentrated. The total land area of single farmer has not yet increased and the total amount of farmers has not yet decreased. At the second stage of coupling, driven by living standards and income, multitudinous rural surplus labor forces begin to live in the city permanently in fact, and the scale management of rural land begins to arise. Foreign funded enterprises begin to enter agriculture, and the industrialization management of agriculture is equipped with the most fundamental conditions due to the occurrence of scaling up of land. At the third stage of coupling, the transfer of rural surplus labor forces basically ends. The property rights of agricultural land or the management forms also, in a large measure, concentrate. The obstacles to agricultural scaling-up management are solved fundamentally, and the income gap between urban areas and rural areas is narrowed. Urban-rural population migration is no longer the main form of China's population migration. This stage has not yet been realized in China and it is the future state of villages. Finally, through the two cases researched by the predecessors, we verify the research results of the preceding two stages, which provides reliable reference for transformation of China's agricultural land management, and policy formulation of transfer of surplus labor forces.展开更多
Owing to their inexpensive and environmentally friendly properties,iron-based catalysts have been actively investigated for new organic reactions.In this account,we summarized our recent results on iron-catalyzed cros...Owing to their inexpensive and environmentally friendly properties,iron-based catalysts have been actively investigated for new organic reactions.In this account,we summarized our recent results on iron-catalyzed cross-coupling reactions and homo-coupling reactions.With iron-based catalysts,we constructed diverse carbon-carbon bonds,i.e.,C(sp^2)-C(sp^3),C(sp^3)-C(sp^3),C(sp^3)-C(sp^2)and C(sp^2)-C(sp^2)bonds.In order to demonstrate the usefulness of our iron protocol,we also carried out these reactions on gram-scale reactions,leading to good yields.展开更多
This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and ...This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation.展开更多
Owing to the absence of proper analytical solution of cantilever beams for couple stress/strain gradient elasto-plastic theory, experimental studies of the cantilever beam in the micro-scale are not suitable for the d...Owing to the absence of proper analytical solution of cantilever beams for couple stress/strain gradient elasto-plastic theory, experimental studies of the cantilever beam in the micro-scale are not suitable for the determination of material length-scale. Based on the couple stress elasto-plasticity, an analytical solution of thin cantilever beams is firstly presented, and the solution can be regarded as an extension of the elastic and rigid-plastic solutions of pure bending beam. A comparison with numerical results shows that the current analytical solution is reliable for the case of σ0 〈〈 H 〈〈 E, where σ0 is the initial yield strength, H is the hardening modulus and E is the elastic modulus. Fortunately, the above mentioned condition can be satisfied for many metal materials, and thus the solution can be used to determine the material length-scale of micro-structures in conjunction with the experiment of cantilever beams in the micro-scale.展开更多
A double-shell model of hydroelectric-generator stator system was established. Applying the theory of mechano-electric analytical dynamics theory, the nonlinear vibration equation of magnetism and solid coupling of hy...A double-shell model of hydroelectric-generator stator system was established. Applying the theory of mechano-electric analytical dynamics theory, the nonlinear vibration equation of magnetism and solid coupling of hydroelectric-generator stator system, under steadily balanced three-phases operating condition, was obtained. According to the method of multiple scales for nonlinear oscillations, the double resonances of magnetism and solid coupling of hydroelectric-generator stater system, were investigated. It is pointed out that the system has abundant dynamics phenomenon including the attendant jumps and coexistence of multiple stable motions.展开更多
That a model has sensitivity responses to parameter uncertainties is a key concept in implementing model parameter es- timation using filtering theory and methodology. Depending on the nature of associated physics and...That a model has sensitivity responses to parameter uncertainties is a key concept in implementing model parameter es- timation using filtering theory and methodology. Depending on the nature of associated physics and characteristic variability of the fluid in a coupled system, the response time scales of a model to parameters can be different, from hourly to decadal. Unlike state estimation, where the update frequency is usually linked with observational frequency, the update frequency for parameter estimation must be associated with the time scale of the model sensitivity response to the parameter being esti- mated. Here, with a simple coupled model, the impact of model sensitivity response time scales on coupled model parameter estimation is studied. The model includes characteristic synoptic to decadal scales by coupling a long-term varying deep ocean with a slow-varying upper ocean forced by a chaotic atmosphere. Results show that, using the update frequency deter- mined by the model sensitivity response time scale, both the reliability and quality of parameter estimation can be improved significantly, and thus the estimated parameters make the model more consistent with the observation. These simple model results provide a guideline for when real observations are used to optimize the parameters in a coupled general circulation model for improving climate analysis and prediction initialization.展开更多
The AFM images were obtained by an atomic force microscope (AFM) and transformed from the deformation of AFM micro cantilever probe. However, due to the surface topography and surface forces applied on the AFM tip of ...The AFM images were obtained by an atomic force microscope (AFM) and transformed from the deformation of AFM micro cantilever probe. However, due to the surface topography and surface forces applied on the AFM tip of sample, the deformation of AFM probe results in obvious edge effects and coupling effects in the AFM images.The deformation of AFM probe was analyzed,the mechanism of the edge effects and the coupling effects was investigated, and their results in the AFM images were studied. It is demonstrated by the theoretical analysis and AFM experiments that the edge effects make lateral force images more clear than the topography images,also make extraction of frictional force from lateral force images more complex and difficult. While the coupling effects make the comparison between topography images and lateral force images more advantage to acquire precise topography information by AFM.展开更多
This paper focuses on the dynamic thermo-mechanical coupled response of random particulate composite materials. Both the inertia term and coupling term are considered in the dynamic coupled problem. The formulation of...This paper focuses on the dynamic thermo-mechanical coupled response of random particulate composite materials. Both the inertia term and coupling term are considered in the dynamic coupled problem. The formulation of the problem by a statistical second-order two-scale （SSOTS） analysis method and the algorithm procedure based on the finite-element difference method are presented. Numerical results of coupled cases are compared with those of uncoupled cases. It shows that the coupling effects on temperature, thermal flux, displacement, and stresses are very distinct, and the micro- characteristics of particles affect the coupling effect of the random composites. Furthermore, the coupling effect causes a lag in the variations of temperature, thermal flux, displacement, and stresses.展开更多
The regional hydrological system is extremely complex because it is affected not only by physical factors but also by human dimensions.And the hydrological models play a very important role in simulating the complex s...The regional hydrological system is extremely complex because it is affected not only by physical factors but also by human dimensions.And the hydrological models play a very important role in simulating the complex system.However,there have not been effective methods for the model reliability and uncertainty analysis due to its complexity and difficulty.The uncertainties in hydrological modeling come from four important aspects：uncertainties in input data and parameters,uncertainties in model structure,uncertainties in analysis method and the initial and boundary conditions.This paper systematically reviewed the recent advances in the study of the uncertainty analysis approaches in the large-scale complex hydrological model on the basis of uncertainty sources.Also,the shortcomings and insufficiencies in the uncertainty analysis for complex hydrological models are pointed out.And then a new uncertainty quantification platform PSUADE and its uncertainty quantification methods were introduced,which will be a powerful tool and platform for uncertainty analysis of large-scale complex hydrological models.Finally,some future perspectives on uncertainty quantification are put forward.展开更多
The emergence of rapid transit,primarily represented by high-speed railway(HSR),while reshaping the regional traffic patterns,leads to the reconstruction and redistribution of population and industry.This leads to eit...The emergence of rapid transit,primarily represented by high-speed railway(HSR),while reshaping the regional traffic patterns,leads to the reconstruction and redistribution of population and industry.This leads to either shrinkage or expansion of urban scale.However,research on the influence mechanisms of the urban scale has mostly concentrated on historical,economic and social factors.The influence of traffic factors is rarely mentioned in current research.Therefore,this study examines Northeast China,where the change in urban scale is most significant,to discuss the spatial impact of high-speed railway on the urban scale.This is of great significance in terms of enriching current understanding of the factors affecting the urban scale.The results included the following:1)The high-speed railway produced considerable space-time convergence effects,however,simultaneously aggravated the imbalance in traffic development in Northeast China.The increase in accessibility presents attenuation characteristics from the high-speed railway.Additionally,the high-speed railway has changed the mode of cooperation between cities in the provinces,inter-regional and inter-provincial cooperation models gradually become popular.2)The change rate of accessibility and the urban scale present significant spatial coupling phenomena,with the change rate of the Harbin-Dalian trunk lines and its surroundings being more significant.3)There are predominantly four modes of the influence of high-speed railway on the urban scale,which make difference city present expansion or shrinkage.展开更多
文摘The study of scale up for the oxidative coupling of methane （OCM） has been carried out in a 200 ml stainless steel fixed-bed reactor over a 5wt% Na2WO4-1.9wt% Mn/SiO2 （W-Mn/SiO2） catalyst. The effects of reaction conditions were investigated in detail. The results showed that, with increasing reaction temperature, the gas-phase reaction was enhanced and a significant amount of methane was converted into COx; with the CH4/O2 molar ratio of 5, the highest C2 （ethylene and ethane） yield of 25% was achieved; the presence of steam （as diluent） had a positive effect on the C2 selectivity and yield. Under lower methane gaseous hourly space velocity （GHSV）, higher selectivity and yield of C2 were obtained as the result of the decrease of released heat energy. In 100 h reaction time, the C2 selectivity of 66%-61% and C2 yield of 24.2%-25.4% were achieved by a single pass without any significant loss in catalytic performance.
基金Projects(50574091, 50774084) supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions+1 种基金Project(CXLX12_0949) supported by Research and Innovation Project for College Graduates of Jiangsu Province, ChinaProject(2013DXS03) supported by the Fundamental Research Funds for the Central Universities, China
文摘A model of vibrating device coupling two pendulums (VDP) which is highly nonlinear was put forward to conduct vibration analysis. Based on energy analysis, dynamic equations with cubic nonlinearities were established using Lagrange's equation. In order to obtain approximate solution, multiple time scales method, one of perturbation technique, was applied. Cases of non-resonant and 1:1:2:2 internal resonant were discussed. In the non-resonant case, the validity of multiple time scales method is confirmed, comparing numerical results derived from fourth order Runge-Kutta method with analytical results derived from first order approximate expression. In the 1:1:2:2 internal resonant case, modal amplitudes of Aa1 and Ab2 increase, respectively, from 0.38 to 0.63 and from 0.19 to 0.32, while the corresponding frequencies have an increase of almost 1.6 times with changes of initial conditions, indicating the existence of typical nonlinear phenomenon. In addition, the chaotic motion is found under this condition.
文摘It is shown that the fine structure constant at Planck times tends to one as well as those of the weak and strong interactions. This results by constraining them at the Planck force. That seems to provide interesting new results which confirm that at the beginning of space time (Planck scale) all fundamental forces converge to the same unit value.
基金the National Key R&D Program of China(2018YDF1100301)。
文摘Through field sampling survey of 18 villages over coal resources in 3 townships and towns in Zezhou County,Jincheng City,Shanxi Province,this paper analyzed the favorable conditions and obstacles for villages over coal resources to carry out farmland scale management.On this basis,combined with the integrated land consolidation measures in villages over coal resources and their effectiveness,and using the principles of system dynamics,it studied the coupling relationship between integrated land consolidation in villages over coal resources and farmland scale management and built a coupling model.It found that the integrated land consolidation system of villages over coal resources has a coupling relationship with the external and internal conditions of the farmland scale management system at the regional and project scales.The two systems interact with and influence each other through the"bridge"of"agricultural modernization condition".The study indicates that at the same time of integrated land consolidation of villages over coal resources caring about the improvement of internal conditions,it is also necessary to improve the external conditions of farmland scale management through regional scale measures such as laws and policies,to support the implementation of land consolidation projects,and realize farmland scale management.
文摘By the two-scale homogenization approach we justify a two-scale model of ion transport through a layered membrane, with flows being driven by a pressure gradient and an external electrical field. By up-scaling, the electroosmotic flow equations in horizontal thin slits separated by thin solid layers are approximated by a homogenized system of macroscale equations in the form of the Poisson equation for induced vertical electrical field and Onsager's reciprocity relations between global fluxes (hydrodynamic and electric) and forces (horizontal pressure gradient and external electrical field). In addition, the two-scale approach provides macroscopic mobility coefficients in the Onsager relations. On this way, the cross-coupling kinetic coefficient is obtained in a form which does involves the ζ -potential among the data provided the surface current is negligible.
基金supported by the foundation of the Research Fund for Commonweal Trades (Meteorology) (No. GYHY201006039)
文摘Debris flow forecast is an important means of disaster mitigation. However, the accuracy of the statistics-based debris flow forecast is unsatisfied while the mechanism-based forecast is unavailable at the watershed scale because most of existing researches on the initiation mechanism of debris flow took a single slope as the main object. In order to solve this problem, this paper developed a model of debris flow forecast based on the water-soil coupling mechanism at the watershed scale. In this model, the runoff and the instable soil caused by the rainfall in a watershed is estimated by the distrib- uted hydrological model （GBHM） and an instable identification model of the unsaturated soil. Because the debris flow is a special fluid composed of soil and water and has a bigger density, the density esti- mated by the runoff and instable soil mass in a watershed under the action of a rainfall is employed as a key factor to identify the formation probability of debris flow in the forecast model. The Jiangjia Gulley, a typical debris flow valley with a several debris flow events each year, is selected as a case study watershed to test this forecast model of debris flow. According the observation data of Dongchuan Debris Flow Observation and Research Station, CAS located in Jiangjia Gulley, there were 4 debris flow events in 2006. The test results show that the accuracy of the model is satisfied.
基金supported by the National High Technology Research and Development Program of China(863)(511-0910-1031)the National"10th Five-Year"Science and Technique Important Program of China(2002BA404A07)
文摘A new higher-order continuum model is proposed by considering the coupling and lane changing effects of the vehicles on two adjacent lanes. A stability analysis of the proposed model provides the conditions that ensure its linear stability. Issues related to lane changing, shock waves and rarefaction waves, local clustering and phase transition are also investigated with numerical experiments. The simulation results show that the proposed model is capable of providing explanations to some particular traffic phenomena commonly observable in real traffic flows.
文摘In this paper, the iterative coupling approach is proposed for applications to solving multiphase flow equation systems in reservoir simulation, as it provides a more flexible time-stepping strategy than existing approaches. The iterative method decouples the whole equation systems into pressure and saturation/concentration equations, and then solves them in sequence, implicitly and semi-implicitly. At each time step, a series of iterations are computed, which involve solving linearized equations using specific tolerances that are iteration dependent. Following convergence of subproblems, material balance is checked. Convergence of time steps is based on material balance errors. Key components of the iterative method include phase scaling for deriving a pressure equation and use of several advanced numerical techniques. The iterative model is implemented for parallel computing platforms and shows high parallel efficiency and scalability.
基金supported by Laboratory Directed Research and Development(LDRD)funding from Berkeley Labsupported by Open Fund of the State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(Grant No.Z017004)。
文摘The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic shearing and opening of intersecting fractures at discrete fracture scales as a result of coupled processes,and contact alteration along rough fracture surfaces that triggers structural and physical changes of fractures at micro-asperity scale.In this paper,these challenges are tackled by developing a comprehensive modeling approach for coupled processes in fractured geological media based on numerical manifold method(NMM)at multiple scales.Based on their distinct geometric features,fractures are categorized into three different scales:dominant fracture,discrete fracture,and discontinuum asperity scales.Here the scale is relative,that of the fracture relative to that of the research interest or domain.Different geometric representations of fractures at different scales are used,and different governing equations and constitutive relationships are applied.For dominant fractures,a finite thickness zone model is developed to treat a fracture as a porous nonlinear domain.Nonlinear fracture mechanical behavior is accurately modeled with an implicit approach based on strain energy.For discrete fractures,a zero-dimensional model was developed for analyzing fluid flow and mechanics in fractures that are geometrically treated as boundaries of the rock matrix.With the zero-dimensional model,these fractures can be modeled with arbitrary orientations and intersections.They can be fluid conduits or seals,and can be open,bonded or sliding.For the discontinuum asperity scale,the geometry of rough fracture surfaces is explicitly represented and contacts involving dynamic alteration of contacts among asperities are rigorously calculated.Using this approach,fracture alteration caused by deformation,re-arrangement and sliding of rough surfaces can be captured.Our comprehensive model is able to handle the computational challenges with accurate representation of intersections and shearing of fractures at the discrete fracture scale and rigorously treats contacts along rough fracture surfaces at the discontinuum asperity scale.With future development of three-dimensional(3D)geometric representation of discrete fracture networks in porous rock and contacts among multi-body systems,this model is promising as a basis of 3D fully coupled analysis of fractures at multiple scales,for advancing understanding and optimizing energy recovery and storage in fractured geological media.
基金Supported by National Natural Science Foundation (10961008)Guizhou Scientific Technology Foundation (2010J2130)
文摘On the basis of giving an overview of efficiency research on transformation of land from fragmentation to scale economy, by using the concept of coupling in physics, this paper expounds the behavior basis of transfer of surplus rural labor forces in China and transformation of land from fragmentation to scaling up, and analyzes behaviors of all parties and equilibrium outcomes in the three stages concerning the transformation of agricultural land from fragmentation to scaling up as follows. At the first stage of coupling, after multitudinous rural surplus labor forces emerge, the farmers begin to go to city seeking jobs. In this period, the amalgamation of land management has not occurred and the single farmer's land has not yet concentrated. The total land area of single farmer has not yet increased and the total amount of farmers has not yet decreased. At the second stage of coupling, driven by living standards and income, multitudinous rural surplus labor forces begin to live in the city permanently in fact, and the scale management of rural land begins to arise. Foreign funded enterprises begin to enter agriculture, and the industrialization management of agriculture is equipped with the most fundamental conditions due to the occurrence of scaling up of land. At the third stage of coupling, the transfer of rural surplus labor forces basically ends. The property rights of agricultural land or the management forms also, in a large measure, concentrate. The obstacles to agricultural scaling-up management are solved fundamentally, and the income gap between urban areas and rural areas is narrowed. Urban-rural population migration is no longer the main form of China's population migration. This stage has not yet been realized in China and it is the future state of villages. Finally, through the two cases researched by the predecessors, we verify the research results of the preceding two stages, which provides reliable reference for transformation of China's agricultural land management, and policy formulation of transfer of surplus labor forces.
基金financed by National Natural Science Foundation of China (Nos. 21672181, 21272199)GRF/RGC (Nos. 403012, CUHK14309216, CUHK14303815)+1 种基金grant to the State Key Laboratory of Synthetic Chemistry from the Innovation and Technology Commission, The Chinese Academy of Sciences-Croucher Foundation Funding Scheme for Joint LaboratoriesDirect Grant (No. 4053325) from The Chinese University of Hong Kong
文摘Owing to their inexpensive and environmentally friendly properties,iron-based catalysts have been actively investigated for new organic reactions.In this account,we summarized our recent results on iron-catalyzed cross-coupling reactions and homo-coupling reactions.With iron-based catalysts,we constructed diverse carbon-carbon bonds,i.e.,C(sp^2)-C(sp^3),C(sp^3)-C(sp^3),C(sp^3)-C(sp^2)and C(sp^2)-C(sp^2)bonds.In order to demonstrate the usefulness of our iron protocol,we also carried out these reactions on gram-scale reactions,leading to good yields.
文摘This article describes a process for the synthesis of diethyl oxalate by a coupling reaction of carbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism of the coupling and regeneration reaction are also discussed. This paper presents the results of a scale-up test of the catalyst and the process based on an a priori computer simulation.
基金the National Natural Science Foundation of China (50479058, 10672032)
文摘Owing to the absence of proper analytical solution of cantilever beams for couple stress/strain gradient elasto-plastic theory, experimental studies of the cantilever beam in the micro-scale are not suitable for the determination of material length-scale. Based on the couple stress elasto-plasticity, an analytical solution of thin cantilever beams is firstly presented, and the solution can be regarded as an extension of the elastic and rigid-plastic solutions of pure bending beam. A comparison with numerical results shows that the current analytical solution is reliable for the case of σ0 〈〈 H 〈〈 E, where σ0 is the initial yield strength, H is the hardening modulus and E is the elastic modulus. Fortunately, the above mentioned condition can be satisfied for many metal materials, and thus the solution can be used to determine the material length-scale of micro-structures in conjunction with the experiment of cantilever beams in the micro-scale.
文摘A double-shell model of hydroelectric-generator stator system was established. Applying the theory of mechano-electric analytical dynamics theory, the nonlinear vibration equation of magnetism and solid coupling of hydroelectric-generator stator system, under steadily balanced three-phases operating condition, was obtained. According to the method of multiple scales for nonlinear oscillations, the double resonances of magnetism and solid coupling of hydroelectric-generator stater system, were investigated. It is pointed out that the system has abundant dynamics phenomenon including the attendant jumps and coexistence of multiple stable motions.
基金funded by the National Natural Science Foundation of China (Grant No.41676088)the National Key Research and Development Project of China (2016YFC1401800,2017YFC1404100,2017YFC1404102)+1 种基金the Fundamental Research Funds for the Central Universities (HEUCF 041705)the Foundation of the Key Laboratory of Marine Environmental Information Technology
文摘That a model has sensitivity responses to parameter uncertainties is a key concept in implementing model parameter es- timation using filtering theory and methodology. Depending on the nature of associated physics and characteristic variability of the fluid in a coupled system, the response time scales of a model to parameters can be different, from hourly to decadal. Unlike state estimation, where the update frequency is usually linked with observational frequency, the update frequency for parameter estimation must be associated with the time scale of the model sensitivity response to the parameter being esti- mated. Here, with a simple coupled model, the impact of model sensitivity response time scales on coupled model parameter estimation is studied. The model includes characteristic synoptic to decadal scales by coupling a long-term varying deep ocean with a slow-varying upper ocean forced by a chaotic atmosphere. Results show that, using the update frequency deter- mined by the model sensitivity response time scale, both the reliability and quality of parameter estimation can be improved significantly, and thus the estimated parameters make the model more consistent with the observation. These simple model results provide a guideline for when real observations are used to optimize the parameters in a coupled general circulation model for improving climate analysis and prediction initialization.
文摘The AFM images were obtained by an atomic force microscope (AFM) and transformed from the deformation of AFM micro cantilever probe. However, due to the surface topography and surface forces applied on the AFM tip of sample, the deformation of AFM probe results in obvious edge effects and coupling effects in the AFM images.The deformation of AFM probe was analyzed,the mechanism of the edge effects and the coupling effects was investigated, and their results in the AFM images were studied. It is demonstrated by the theoretical analysis and AFM experiments that the edge effects make lateral force images more clear than the topography images,also make extraction of frictional force from lateral force images more complex and difficult. While the coupling effects make the comparison between topography images and lateral force images more advantage to acquire precise topography information by AFM.
基金supported by the Special Funds for the National Basic Research Program of China(Grant No.2012CB025904)the National Natural ScienceFoundation of China(Grant Nos.90916027 and 11302052)
文摘This paper focuses on the dynamic thermo-mechanical coupled response of random particulate composite materials. Both the inertia term and coupling term are considered in the dynamic coupled problem. The formulation of the problem by a statistical second-order two-scale （SSOTS） analysis method and the algorithm procedure based on the finite-element difference method are presented. Numerical results of coupled cases are compared with those of uncoupled cases. It shows that the coupling effects on temperature, thermal flux, displacement, and stresses are very distinct, and the micro- characteristics of particles affect the coupling effect of the random composites. Furthermore, the coupling effect causes a lag in the variations of temperature, thermal flux, displacement, and stresses.
基金National Key Basic Research Program of China,No.2010CB428403National Grand Science and Technology Special Project of Water Pollution Control and Improvement,No.2009ZX07210-006
文摘The regional hydrological system is extremely complex because it is affected not only by physical factors but also by human dimensions.And the hydrological models play a very important role in simulating the complex system.However,there have not been effective methods for the model reliability and uncertainty analysis due to its complexity and difficulty.The uncertainties in hydrological modeling come from four important aspects：uncertainties in input data and parameters,uncertainties in model structure,uncertainties in analysis method and the initial and boundary conditions.This paper systematically reviewed the recent advances in the study of the uncertainty analysis approaches in the large-scale complex hydrological model on the basis of uncertainty sources.Also,the shortcomings and insufficiencies in the uncertainty analysis for complex hydrological models are pointed out.And then a new uncertainty quantification platform PSUADE and its uncertainty quantification methods were introduced,which will be a powerful tool and platform for uncertainty analysis of large-scale complex hydrological models.Finally,some future perspectives on uncertainty quantification are put forward.
基金Under the auspices of National Natural Science Foundation of China(No.41471133,41871112).
文摘The emergence of rapid transit,primarily represented by high-speed railway(HSR),while reshaping the regional traffic patterns,leads to the reconstruction and redistribution of population and industry.This leads to either shrinkage or expansion of urban scale.However,research on the influence mechanisms of the urban scale has mostly concentrated on historical,economic and social factors.The influence of traffic factors is rarely mentioned in current research.Therefore,this study examines Northeast China,where the change in urban scale is most significant,to discuss the spatial impact of high-speed railway on the urban scale.This is of great significance in terms of enriching current understanding of the factors affecting the urban scale.The results included the following:1)The high-speed railway produced considerable space-time convergence effects,however,simultaneously aggravated the imbalance in traffic development in Northeast China.The increase in accessibility presents attenuation characteristics from the high-speed railway.Additionally,the high-speed railway has changed the mode of cooperation between cities in the provinces,inter-regional and inter-provincial cooperation models gradually become popular.2)The change rate of accessibility and the urban scale present significant spatial coupling phenomena,with the change rate of the Harbin-Dalian trunk lines and its surroundings being more significant.3)There are predominantly four modes of the influence of high-speed railway on the urban scale,which make difference city present expansion or shrinkage.
