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Fabrication, property characterization and thermal performance of composite phase change material plates based on tetradecanol-myristic acid binary eutectic mixture/expanded perlite and expanded vermiculite for building application 被引量:7
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作者 YANG Hua CHEN Wan-he +1 位作者 KONG Xiang-fei RONG Xian 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第9期2578-2595,共18页
A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum ... A binary eutectic mixture composed of tetradecanol(TD)and myristic acid(MA)was maximally absorbed into the microstructures of expanded perlite(EP)and expanded vermiculite(EVMT),respectively,through a self-made vacuum adsorption roller to prepare phase change material(PCM)particle(PCP).Then EP and EVMT-based composite PCM plates were respectively fabricated through a mold pressing method.The thermal property,chemical stability,microstructure and durability were characterized by differential scanning calorimeter(DSC),Fourier transform infrared spectroscope(FT-IR),scanning electron microscope(SEM)and thermal cycling tests,respectively.The results show that both PCPs have high latent heats with 110 J/g for EP-based PCP and more than 130 J/g for EVMT-based PCP,compact microstructure without PCM leakage,stable chemical property and good durability.The research results have proved the feasibility for the vacuum adsorption roller used in the composite PCM fabrication.Results of thermal storage performance experiment indicate that the fabricated PCM plates have better thermal inertia than common building materials,and the thermal storage performance of PCM plates has nonlinearly changed with outside air velocity and temperature increase.Therefore,PCM plates show a significant potential for the practical application of building thermal storage. 展开更多
关键词 thermal storage phase change material expanded perlite expanded vermiculite binary eutectic mixture
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Thermal Energy Storage Characteristics of Myristic and Stearic Acids Eutectic Mixture for Low Temperature Heating Applications 被引量:6
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作者 Ahmet Sari Kamil Kaygusuz 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第2期270-275,共6页
Stearic acid (67.83℃) and myristic acid (52.32℃) have high melting temperatures that can limit their use as phase change material (PCM) in low temperature solar heating applications such as solar space and greenhous... Stearic acid (67.83℃) and myristic acid (52.32℃) have high melting temperatures that can limit their use as phase change material (PCM) in low temperature solar heating applications such as solar space and greenhouse heating in regard to climatic requirements. However, their melting temperatures can be adjusted to a suitable value by preparing a eutectic mixture of the myristic acid (MA) and the stearic acid (SA). In the present study, the thermal analysis based on differential scanning calorimetry (DSC) technique shows that the mixture of myristic acid (MA) and stearic acid (SA) in the respective composition (by mass) of 64% and 36% forms a eutectic mixture having melting temperature of 44.13℃ and the latent heat of fusion of 182.4J·g-1. The thermal energy storage characteristics of the MA-SA eutectic mixture filled in the annulus of two concentric pipes were also experimentally established. The heat recovery rate and heat charging/discharging fractions were determined with respect to the change in the mass flow rate and the inlet temperature of heat transfer fluid. Based on the results obtained by DSC analysis and by the heat charg- ing/discharging processes of the PCM, it can be concluded that the MA-SA eutectic mixture is a potential material for low temperature thermal energy storage applications in terms of its thermo-physical and thermal characteristics. 展开更多
关键词 eutectic mixture myristic and stearic acids phase change material thermal energy storage differential scanning calorimetry
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Eutectic mixture promoted CO_2 sorption on MgO-TiO_2 composite at elevated temperature
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作者 Vishwanath Hiremath Monica Louise T.Trivino Jeong Gil Seo 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2019年第2期80-88,共9页
The development of carbon dioxide(CO_2) sorbents that can operate at elevated temperatures is significant for the advancement of pre-combustion capture technologies.Recently, promoter-based systems composed of alkali/... The development of carbon dioxide(CO_2) sorbents that can operate at elevated temperatures is significant for the advancement of pre-combustion capture technologies.Recently, promoter-based systems composed of alkali/alkaline earth metal nitrates and/or carbonates have been considered as next-generation solid sorbents due to their improved CO_2 uptake and kinetics. However, obtaining stable MgO sorbents against temperature swing regeneration still remained challenging. Herein, we report MgO-TiO_2 solid sorbents promoted by eutectic mixture(KNO_3 and LiNO_3) for elevated temperature CO_2 sorption. The developed sorbents show improved CO_2 sorption capacity, which may be attributed to the alternative CO_2 sorption pathway provided by the ionization of highly dispersed MgO in the eutectic mixture. The MgO-TiO_2 framework was also shown to assist in retaining the MgO configuration by constraining its interaction with CO_2. Furthermore, it is demonstrated that constructing composite structures is essential to improve the CO_2 sorption characteristics,mainly recyclability, at elevated temperatures. The developed promoter integrated sorbents showed exceptionally high CO_2 sorption capacity of > 30 wt.% at an elevated temperature(300°C) with pronounced stability under temperature swing operation. 展开更多
关键词 MgO-TiO2 COMPOSITE ELEVATED temperature CO2 capture eutectic mixture PROMOTER MGO stability
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Thermal Characterization of Lauric Acid and Stearic Acid Binary Eutectic Mixture in Latent Heat Thermal Storage Systems with Tube and Fins
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作者 丁磊 WANG Lixiong +2 位作者 Georgios Kokogiannakis Lü Yajun 周卫兵 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2017年第4期753-759,共7页
In order to obtain the suitable phase change material(PCM) with low phase change temperature and improve its heat transfer rate, experimental investigation was conducted. Firstly, different mass ratios of lauric aci... In order to obtain the suitable phase change material(PCM) with low phase change temperature and improve its heat transfer rate, experimental investigation was conducted. Firstly, different mass ratios of lauric acid(LA) and stearic acid(SA) eutectic mixtures were prepared and characterized by differential scanning calorimetry(DSC). Then, the performance of eutectic mixture during charging process under different fin widths in vertical condition, and performance during charging and discharging processes under different inlet temperature heat transfer fluid(HTF) in horizontal condition were investigated, respectively. The results revealed that the LA-SA eutectic mixture had the suitable phase change temperature and desired latent heat for low-temperature water floor heating system. Wide fins and high inlet temperature HTF significantly enhanced the transfer rate and decreased the melting time. 展开更多
关键词 LA-SA binary eutectic mixture thermal properties heat exchanger heat transfer mechanism
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Multiscale Study on Low Temperature Crack Resistance Mechanism of Steel Slag Asphalt Mixture
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作者 白雪峰 王岚 CHEN Xiunan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期705-715,共11页
The objective of this paper was to study low temperature crack resistance mechanism of steel slag asphalt mixture(SAM).Thermal stress restrained specimen test(TSRST)and three-point bending test were carried out to eva... The objective of this paper was to study low temperature crack resistance mechanism of steel slag asphalt mixture(SAM).Thermal stress restrained specimen test(TSRST)and three-point bending test were carried out to evaluate the low-temperature crack resistance of SAM and basalt asphalt mixture(BAM).Based on the digital image correlation technique(DIC),the strain field distribution and crack propagation of SAM were analyzed from the microscopic point of view,and a new index,crack length factor(C),was proposed to evaluate the crack resistance of the asphalt mixture.The crystal phase composition and microstructure of steel slag aggregate(SA)and basalt aggregate(BA)were studied by X-ray diffraction(XRD)and scanning electron microscopy(SEM)to explore the low-temperature crack resistance mechanism of SAM.Results show that the low-temperature crack resistance of SAM is better than that of BAM;SAM has good integrity and persistent elastic deformation,and its bending failure mode is a hysteretic quasi-brittle failure;The SA surface is evenly distributed with pores and has surface roughness.SA has the composition phase of alkaline aggregate-calcite(CaCO3),so it has good adhesion to asphalt,which reveals the mechanism of excellent low-temperature crack resistance of SAM. 展开更多
关键词 steel slag asphalt mixture ·low-temperature crack resistance ·strain energy density ·XRD SEM
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Fatigue Property of Basalt Fiber-Modified Asphalt Mixture under Complicated Environment 被引量:10
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作者 郑元勋 CAI Yingchun +1 位作者 ZHANG Guanghai FANG Hongyuan 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2014年第5期996-1004,共9页
The fatigue property of asphalt mixtures under complicated environment (low-temperature bending performance, chloride penetration, freezing-thawing cycle and their coupling effect) and the improvement effect for rel... The fatigue property of asphalt mixtures under complicated environment (low-temperature bending performance, chloride penetration, freezing-thawing cycle and their coupling effect) and the improvement effect for relevant property of basalt fiber-reinforcing asphalt mixture under complicated environment are studied. Two grading types of asphalt mixtures, AC-16I and AC-13I, are chosen, whose optimum asphalt-aggregate ratio and optimum dosage of basalt fiber are determined by the Marshall test. The standard specimens are made firstly, and then the low temperature bending tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under the coupling effect of the chloride erosion and freezing-thawing cycle have been carried out. Finally, the fatigue property tests of asphalt mixture and basalt fiber-reinforced asphalt mixture under complex environment are performed on MTS material testing system. The results indicate that the tensile strength, the maximum curving tensile stress, the curving stiffness modulus, and fatigue properties of asphalt mixture are influenced by the coupling effect of the chloride erosion and freezing-thawing cycle. The low-temperature bending performance and fatigue property of asphalt mixtures under complicated environment can be greatly improved by adding moderate basalt fiber. The dense gradation asphalt mixture possesses stronger ability to resist adverse environmental effects under the same condition. 展开更多
关键词 asphalt mixture basalt fiber the chloride erosion freezing-thawing cycle the coupling effect low-temperature performance fatigue property
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Low-temperature phase transitions of sodium aluminate solutions 被引量:5
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作者 Wei LIU Zhou-lan YIN Zhi-ying DING 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第1期194-199,共6页
A series of low-temperature phase transitions of sodium aluminate solutions were studied by differential scanning calorimetry (DSC) and Raman spectroscopy. The results indicate that NaOH concentration is a primary imp... A series of low-temperature phase transitions of sodium aluminate solutions were studied by differential scanning calorimetry (DSC) and Raman spectroscopy. The results indicate that NaOH concentration is a primary impact factor for the binary eutectic point and ice melting temperature of sodium aluminate solutions with low NaOH concentration. In addition, the phase transition process of sodium aluminate solutions with low NaOH concentration from 123.15 to 283.15 K is divided into four steps: non-crystal to crystal, ternary eutectic reaction, binary eutectic reaction and ice melt. The projection phase diagram of NaOH-Al(OH)3-H2O system at low temperature was plotted, in which the ternary eutectic temperature for sodium aluminate solutions is 183.15 K. 展开更多
关键词 sodium aluminate solution low-temperature phase transition differential scanning calorimetry Raman spectroscopy eutectic reaction
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Deep Eutectic Solvents: Green Solvents for Separation Applications 被引量:23
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作者 HOU Yucui YAO Congfei WU Weize 《物理化学学报》 SCIE CAS CSCD 北大核心 2018年第8期873-885,共13页
关键词 深共晶溶剂 化学物 氢键 化学分析
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Low-melting mixture solvents:extension of deep eutectic solvents and ionic liquids for broadening green solvents and green chemistry 被引量:1
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作者 Yu Chen Zhiwu Yu 《Green Chemical Engineering》 EI CSCD 2024年第4期409-417,共9页
Green solvents such as water and ionic liquids(ILs)are pillars of the great mansion of green chemistry and green processing.Initially proposed as a new family of ILs,deep eutectic solvents(DESs)have received fast deve... Green solvents such as water and ionic liquids(ILs)are pillars of the great mansion of green chemistry and green processing.Initially proposed as a new family of ILs,deep eutectic solvents(DESs)have received fast development in the past two decades.In this contribution,DESs are reviewed critically and the concept is extended to lowmelting mixture solvents(Lo MMSs),which cover all kinds of materials including ionic compounds,molecular compounds,and metals.Six classes of Lo MMSs are proposed as the new classification system and examples are given.Finally,several thermodynamic issues concerning Lo MMSs are discussed.Two new concepts,robustness of Lo MMSs and high-entropy Lo MMSs,are proposed. 展开更多
关键词 Green solvents Deep eutectic solvents Low transition temperature mixture solvents Phase diagram EGaIn
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冰片-薄荷脑低共熔物载川芎嗪纳米乳凝胶制备
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作者 文静 牛俊淞 +2 位作者 吴玉珍 邓婕 李楠 《中成药》 北大核心 2025年第8期2522-2529,共8页
目的制备冰片-薄荷脑低共熔物载川芎嗪纳米乳凝胶。方法测定川芎嗪在不同油相、乳化剂、助乳化剂中的平衡溶解度,进行配伍实验,绘制伪三元相图。以Km值、油相占比、水相用量为影响因素,粒径、PDI、饱和载药量为评价指标,星点设计-响应... 目的制备冰片-薄荷脑低共熔物载川芎嗪纳米乳凝胶。方法测定川芎嗪在不同油相、乳化剂、助乳化剂中的平衡溶解度,进行配伍实验,绘制伪三元相图。以Km值、油相占比、水相用量为影响因素,粒径、PDI、饱和载药量为评价指标,星点设计-响应面法优化处方。将载药纳米乳分散于卡波姆940凝胶基质中制备纳米乳凝胶,考察其理化性质、体外释药和透皮吸收性能。结果最佳处方为低共熔物、EL-40、1,2-丙二醇、水比例3.31∶6.16∶1.56∶88.97,粒径、PDI、饱和载药量分别为37.85 nm、23.04、5.82 mg/g。所得纳米乳凝胶呈白色半固体,平均pH值为6.68±0.07,黏度为(289.69±1.06)mPa·s,体外释药符合Higuchi方程,24 h内单位面积累积渗透量为(2048.23±55.6)μg/cm^(2),分别是水凝胶、水溶液的3.72、1.21倍。结论冰片-薄荷脑低共熔物载川芎嗪纳米乳凝胶满足制剂要求,可实现原料药有效经皮递送。 展开更多
关键词 川芎嗪 纳米乳凝胶 低共熔物 冰片 薄荷脑 制备
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石蜡-脂肪酸二元低共熔混合物的制备及其相变特性研究
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作者 李琳 王宇 汪霞 《化工新型材料》 北大核心 2025年第12期151-156,共6页
以石蜡(PC)、癸酸(CA)、月桂酸(LA)、肉豆蔻酸(MA)、棕榈酸(PA)、硬脂酸(SA)为相变材料,采用熔融共混法制备了5组石蜡-脂肪酸二元低共熔混合物,利用步冷曲线法验证了PC-CA和PC-LA相变温度符合建筑节能领域的温度范围要求。采用差示扫描... 以石蜡(PC)、癸酸(CA)、月桂酸(LA)、肉豆蔻酸(MA)、棕榈酸(PA)、硬脂酸(SA)为相变材料,采用熔融共混法制备了5组石蜡-脂肪酸二元低共熔混合物,利用步冷曲线法验证了PC-CA和PC-LA相变温度符合建筑节能领域的温度范围要求。采用差示扫描量热仪、傅里叶变换红外光谱仪、热重分析仪等研究了石蜡-脂肪酸二元低共熔混合物的热物性、结构稳定性和热稳定性等相变性能。结果表明:理论估算的PC-CA、PC-LA、PC-MA、PC-PA、PC-SA的相变温度分别为27.79℃、34.16℃、39.26℃、42.42℃、45.51℃;差示扫描量热法测试的相变温度分别为27.97℃、36.68℃、43.53℃、45.50℃、47.45℃,两者误差值较小说明理论估算法对于预测相变温度具有较高的可靠性。石蜡与脂肪酸之间仅为物理结合,无新物质产生;石蜡-脂肪酸二元低共熔混合物在150℃以下未发生分解,能够保持稳定的工作性能。 展开更多
关键词 石蜡 脂肪酸 热物性 低共熔混合物
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风冷墙对进口炉排炉结焦的抑制机理及效果分析
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作者 张莹莹 刘晓吉 +4 位作者 喻武 封全武 张泉 叶江 李烨 《环境卫生工程》 2025年第1期93-97,共5页
我国某生活垃圾焚烧项目进口炉排炉为绝热炉墙设计,在运行过程中会出现结焦严重的问题。通过对焦块进行表征分析发现,其主要成分为钙黄长石,容易形成低温共融物。当炉膛温度过高时,焚烧产生的灰粒易软化、熔融,黏附在高温炉墙表面结成... 我国某生活垃圾焚烧项目进口炉排炉为绝热炉墙设计,在运行过程中会出现结焦严重的问题。通过对焦块进行表征分析发现,其主要成分为钙黄长石,容易形成低温共融物。当炉膛温度过高时,焚烧产生的灰粒易软化、熔融,黏附在高温炉墙表面结成焦块。针对此问题,该项目对原焚烧炉侧墙进行模块化设计,使得各段炉墙之间封闭独立,并在局部高温区域将原绝热炉墙改造为风冷墙,以降低炉墙温度。改造后,炉墙结焦问题得到明显改善,增强了焚烧炉运行的安全稳定性,提高了锅炉热效率,节省运行成本,项目改造达到预期效果。 展开更多
关键词 进口炉排炉 结焦 低温共融物 风冷墙
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Temperature-Dependent Rheological Behaviors of Binary Eutectic Mixtures of Sugar Alcohols for Latent Heat Storage:A Comparative Study with Pure Sugar Alcohols 被引量:1
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作者 SHAO Xuefeng YANG Sheng +2 位作者 CHEN Chenlin FAN Liwu YU Zitao 《Journal of Thermal Science》 SCIE EI CAS CSCD 2021年第6期2002-2014,共13页
The temperature-dependent rheological behaviors of five selected binary eutectic mixture sugar alcohols,with great potential for latent heat storage in the range of 353.15 K to 523.15 K,were investigated.It was found ... The temperature-dependent rheological behaviors of five selected binary eutectic mixture sugar alcohols,with great potential for latent heat storage in the range of 353.15 K to 523.15 K,were investigated.It was found that the rheological behaviors of the mixture sugar alcohols depend on those of the pure compounds as well as their molar ratios.The two mixtures of xylitol(75 mol%)+erythritol and erythritol(84 mol%)+d-mannitol behave like pseudoplastic fluids with typical non-Newtonian shear-thinning behaviors,as indicated by the power law index of 0.99(<1).The mixture of d-mannitol(70 mol%)+d-dulcitol is a nonlinear Bingham fluid,exhibiting a slight yield stress(0.001 Pa to 0.01 Pa)at low shear rates.The rest two mixtures containing the cyclic-structured inositol behave like Herschel-Bulkley fluids.The infinite shear viscosities of the eutectic mixtures over the entire temperature range appear to be higher than those of their respective pure compounds,except for inositol.The mixture of xylitol(75 mol%)+erythritol at its melting point shows higher dynamic viscosity of about 0.546 Pa·s than the values of about 0.396 Pa·s and 0.035 Pa·s for xylitol and erythritol,respectively.In addition,the activation energies of viscous flow of the mixtures,as determined by fitting the dynamic viscosity-temperature curves using the Arrhenius model,also exhibit higher values than those of their pure compounds.The activation energy of viscous flow of the mixture xylitol(75 mol%)+erythritol was determined to be about 92400 J/mol in the supercooled liquid state,while the supercooled liquid xylitol and erythritol have much lower values of 83500 J/mol and 51900 J/mol,respectively.Both the increased dynamic viscosities and activation energies of viscous flow can result in deteriorated crystallization performance during latent heat retrieval. 展开更多
关键词 binary eutectic mixture dynamic viscosity phase change material rheological behavior sugar alcohol latent heat storage
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Low-temperature processing of LiZn-based ferrite ceramics by co-doping of V_(2)O_(5)and Sb_(2)O_(3):Composition,microstructure and magnetic properties
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作者 Renquan Wang Tingchuan Zhou Zhiyong Zhong 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第4期1-8,共8页
Low-temperature fired ferrites or ceramics are usually processed by using low-melting materials(e.g.,glasses,oxides,and eutectics)as sintering aids to obtain compact and uniform microstructures.Herein,a dual-strategy ... Low-temperature fired ferrites or ceramics are usually processed by using low-melting materials(e.g.,glasses,oxides,and eutectics)as sintering aids to obtain compact and uniform microstructures.Herein,a dual-strategy of co-doping with V_(2)O_(5)and Sb_(2)O_(3)oxides and forming a eutectic liquid phase has been employed to reduce the melting point of LiZn ferrite ceramics in an effective way.The results indicate that miniscule amounts of V_(2)O_(5)and Sb_(2)O_(3)co-doping contribute in producing dense and uniform microstructures with enhanced magnetic performance by low-temperature firing.The phase structural and microstructural evolutions have been studied in detail.Thereafter their correlations with magnetic properties have been revealed.Enhanced magnetic performance(B_(s)=475.4 mT,M_(s)=82.51 emu/g,B_(r)/B_(s)=0.85,H_(c)=2.2 Oe,ΔH=153.8 Oe)of the LiZn-based ferrite ceramics is achieved by optimized composition and microstructure,which shows great potential for microwave applications including phase shifters and radars.More importantly,such a co-doping strategy can be also extended to other material systems,like dielectric ceramics,hexagonal ferrites or piezoelectric ceramics. 展开更多
关键词 low-temperature firing eutectic liquid phase Magnetic properties Uniform microstructure FMR line width
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月桂酸-棕榈酸-硬脂酸/膨胀石墨复合相变材料的制备及性能 被引量:41
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作者 袁亚光 袁艳平 +2 位作者 张楠 李天宇 曹晓玲 《化工学报》 EI CAS CSCD 北大核心 2014年第S2期286-292,共7页
以理论计算为基础,制备了月桂酸-棕榈酸-硬脂酸三元低共熔混合物(LA-PA-SA)。利用膨胀石墨(EG)的网状多孔结构,制备了最佳质量配比为15:1(LA-PA-SA:EG)的LA-PA-SA/EG复合相变材料。综合利用FT-IR、SEM、DSC、冷热加速循环和蓄放热实验... 以理论计算为基础,制备了月桂酸-棕榈酸-硬脂酸三元低共熔混合物(LA-PA-SA)。利用膨胀石墨(EG)的网状多孔结构,制备了最佳质量配比为15:1(LA-PA-SA:EG)的LA-PA-SA/EG复合相变材料。综合利用FT-IR、SEM、DSC、冷热加速循环和蓄放热实验等对复合相变材料的结构和性能进行了研究。结果表明:LAPA-SA通过物理吸附作用均匀分布于EG的多孔结构中;复合相变材料的熔化和凝固温度分别为32.1℃和30.3℃,熔化和凝固潜热分别为143.2J·g-1和143.1J·g-1;经过1000次冷热循环后具有良好的热稳定性和化学稳定性;EG的高导热性加快了复合相变材料的蓄放热速率。 展开更多
关键词 低共熔混合物 膨胀石墨 复合相变材料 结构 热性能
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高能量密度材料3,4-二硝基呋咱基氧化呋咱性能及应用研究 被引量:103
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作者 胡焕性 张志忠 +3 位作者 赵凤起 肖川 王亲会 袁宝慧 《兵工学报》 EI CAS CSCD 北大核心 2004年第2期155-158,共4页
3 ,4 二硝基呋咱基氧化呋咱 (DNTF)是一种新型高能量密度材料 ,通过对其理化、爆轰性能研究 ,证明其各项性能优于奥克托今 (HMX)而接近六硝基六氮杂异全兹烷 (CL - 2 0 ) .DNTF能量高、熔点低、热安定性良好、感度适中 ,适于在推进剂... 3 ,4 二硝基呋咱基氧化呋咱 (DNTF)是一种新型高能量密度材料 ,通过对其理化、爆轰性能研究 ,证明其各项性能优于奥克托今 (HMX)而接近六硝基六氮杂异全兹烷 (CL - 2 0 ) .DNTF能量高、熔点低、热安定性良好、感度适中 ,适于在推进剂、战斗部装药及爆炸网络中应用。另外 ,DNTF能与梯恩梯 (TNT)形成低共熔物 ,可以调配成不同熔点、不同能量要求的液相载体 。 展开更多
关键词 高能量密度材料 3 4-二硝基呋咱基氧化呋咱 有机高分子材料 低共熔物 混合炸药 推进剂 爆炸网络 战斗部
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在非水介质中进行酶促反应的几个重要问题 被引量:19
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作者 田桂玲 邢国文 叶蕴华 《有机化学》 SCIE CAS CSCD 北大核心 1998年第1期11-19,共9页
介绍了在非水介质中酶促反应的最新进展。较深入地讨论了介质性质对酶的催化活性及立体选择性的影响,有机溶剂中必需水含量对酶催化反应的重要性,描述了非缓冲体系中的盐及其它极性添加剂对酶活性的影响,介绍了在非均相的低共熔体系中... 介绍了在非水介质中酶促反应的最新进展。较深入地讨论了介质性质对酶的催化活性及立体选择性的影响,有机溶剂中必需水含量对酶催化反应的重要性,描述了非缓冲体系中的盐及其它极性添加剂对酶活性的影响,介绍了在非均相的低共熔体系中进行酶促合成肽的研究。 展开更多
关键词 酶促反应 非水介质 低共熔混合物 肽合成
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脂肪酸三元低共熔混合物相变温度和潜热的理论预测 被引量:26
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作者 刘程 袁艳平 +2 位作者 张楠 曹晓玲 杨晓娇 《材料导报》 EI CAS CSCD 北大核心 2014年第2期165-168,共4页
对脂肪酸低共熔混合物相变温度和潜热的理论预测公式进行了选择和实验验证,通过DSC实验测试月桂酸-肉豆蔻酸二元低共熔混合物、月桂酸-肉豆蔻酸-棕榈酸三元低共熔混合物的热物性参数,发现理论预测公式对低共熔质量配比和相变温度的预测... 对脂肪酸低共熔混合物相变温度和潜热的理论预测公式进行了选择和实验验证,通过DSC实验测试月桂酸-肉豆蔻酸二元低共熔混合物、月桂酸-肉豆蔻酸-棕榈酸三元低共熔混合物的热物性参数,发现理论预测公式对低共熔质量配比和相变温度的预测与实验结果吻合较好,可以用于计算脂肪酸类低共熔混合物的热特性参数。在此基础上对10种脂肪酸三元低共熔混合物的质量配比、相变温度和潜热进行了预测计算,这10种脂肪酸三元相变温度范围为16.12~38.86℃,相变潜热范围为154.99~177.39J/g。脂肪酸三元低共熔混合物的研究丰富了脂肪酸的相变温度和相变潜热范围,为脂肪酸类相变材料的工程应用提供了更广阔的空间。 展开更多
关键词 脂肪酸低共熔混合物 相变温度 相变潜热 理论计算
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具有特殊形貌的多级孔SAPO-5分子筛的常压合成 被引量:7
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作者 赵新红 李晓斌 +3 位作者 陈静 祁永东 问娟娟 季东 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2014年第8期821-826,共6页
以丁二酸-氯化胆碱-四乙基溴化铵三元低共熔混合物作为溶剂和模板剂,借助微波辐射在常压下合成了具有多级孔结构的SAPO-5分子筛。系统地考察了P2O5/Al2O3与HF/Al2O3摩尔比,硅源与晶化时间等条件对多级孔SAPO-5分子筛合成的影响。采用X... 以丁二酸-氯化胆碱-四乙基溴化铵三元低共熔混合物作为溶剂和模板剂,借助微波辐射在常压下合成了具有多级孔结构的SAPO-5分子筛。系统地考察了P2O5/Al2O3与HF/Al2O3摩尔比,硅源与晶化时间等条件对多级孔SAPO-5分子筛合成的影响。采用X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、N2物理吸脱附以及29Si魔角旋转核磁共振(29Si MAS-NMR)等手段对合成产物的结构和性质进行了表征。分析结果表明:在SAPO-5分子筛晶体中同时存在晶体内介孔和晶体间介孔,29Si MAS-NMR分析表明Si的取代方式以SM3取代机理为主。此外,通过SEM可知在特定合成条件下可得到具有六角纳米盘状特殊形貌的多级孔SAPO-5分子筛。 展开更多
关键词 SAPO-5 低共熔混合物 微波辐射 多级孔
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脂肪酸二元低共熔混合物相变温度和潜热的理论预测 被引量:26
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作者 袁艳平 白力 牛犇 《材料导报》 EI CAS CSCD 北大核心 2010年第2期111-113,共3页
对低共熔混合物相变温度和潜热的理论预测公式进行了选择和验证,对脂肪酸类二元低共熔混合物的配比、熔点和熔化潜热进行了理论计算。从实际的计算过程来看,计算值与实验值吻合得很好,可以用来计算脂肪酸类低共熔混合物的热特性参数。... 对低共熔混合物相变温度和潜热的理论预测公式进行了选择和验证,对脂肪酸类二元低共熔混合物的配比、熔点和熔化潜热进行了理论计算。从实际的计算过程来看,计算值与实验值吻合得很好,可以用来计算脂肪酸类低共熔混合物的热特性参数。在15种脂肪酸类低共熔混合物中,熔点最低为10.2℃,最高为51.5℃;熔化潜热最低为138.6J/g,最高为187.5J/g。从工程实际应用来看,脂肪酸类低共熔混合物适用于低温采暖、生活热水、相变墙体、温控混凝土、相变服装等领域。 展开更多
关键词 低共熔混合物 熔点 熔化潜热 理论计算
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