Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is g...Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is generally slow at low temperature,resulting in large overpotential and low current efficiency.Thus,the application of external physical fields has emerged as an effective strategy for improving the mass and charge transfer processes during electrochemical reactions.This review highlights the challenges associated with low-temperature electrochemical processes and briefly discusses recent achievements in optimizing electrodeposition processes through the use of external physical fields.The regulating effects on the optimization of the electrodeposition process and the strategies for select-ing various external physical fields,including magnetic,supergravity,and ultrasonic fields are summarized from the perspectives of equipment and mechanisms.Finally,advanced methods for in-situ characterization of external physical field-assisted electrodeposition processes are reviewed to gain a deeper understanding of metallic electrodeposition.An in-depth exploration of the mechanism by which external physical fields affect the electrode process is essential for enhancing the efficiency of metal extraction at low temperatures.展开更多
Cracking affected by wetting-drying cycles is a major cause of shallow failure of soft rock slopes.Knowledge of rock tensile properties and cracking behaviors helps better assess the stability of soft rock slopes.This...Cracking affected by wetting-drying cycles is a major cause of shallow failure of soft rock slopes.Knowledge of rock tensile properties and cracking behaviors helps better assess the stability of soft rock slopes.This study aims to examine the cracking behaviors and tensile strength of silty mudstone under wetting-drying cycles.The wetting-drying cycle and Brazilian splitting tests were performed on silty mudstone considering various cycle number and amplitude.The cracking behaviors of wetting-drying cycles were analyzed by digital image correlation,three-dimensional(3D)scanning technology,and scanning electron microscopy.The results reveal a spiral-like pattern of crack ratio escalation in silty mudstone,with a higher crack ratio observed during drying than wetting.Tensile strength and fracture energy correlate negatively with cycle number or amplitude,with cycle number exerting a more pronounced effect.The variance of the maximum principal strain reflects stages of initial deformation,linear deformation,strain localization,and stable deformation.The formation of strain localization zones reveals the physical process of crack propagation.Crack tip opening displacement progresses through stages of slow growth,exponential growth,and linear growth,delineating the process from crack initiation to stable extension.Failure modes of silty mudstone primarily involve tensile and tensile-shear failure,influenced by the geometric parameters of cracks induced by wetting-drying cycles.Fracture surface roughness and fractal dimension increase with cycle number due to mineral dissolution,physical erosion,and nondirectional crack propagation.Hydration-swelling and dehydration-shrinkage of clay minerals,along with absorption-drying cracking,initiate and merge cracks,leading to degradation of the rock mechanical properties.The findings could provide insights for mitigating shallow cracking of soft rock slopes under wetting-drying cycles.展开更多
To investigate the residual stress distribution and its influence on machining deformation in 6061-T651 aluminum alloy plates,this paper uses the crack compliance method to study the residual stress characteristics of...To investigate the residual stress distribution and its influence on machining deformation in 6061-T651 aluminum alloy plates,this paper uses the crack compliance method to study the residual stress characteristics of 6061-T651 aluminum alloy plates with a thickness of 75 mm produced by two domestic manufacturers in China.The results indicate that both types of plates exhibit highly consistent and symmetrical M-shaped residual stress profile along the thickness direction,manifested as surface layer compression and core tension.The strain energy density across all specimens ranges from 1.27 kJ/m^(3)to 1.43 kJ/m^(3).Machining deformation simulations of an aerospace component incorporating these measured stresses showed minimal final deformation difference between the material sources,with a maximum deviation of only 0.009 mm across specimens.These findings provide critical data for material selection and deformation control in aerospace manufacturing.展开更多
Percussive drilling is gaining interest for both shallow and deep applications due to its potential for higher drilling rates in hard rocks.Therefore,for efficient rock breaking,the development of advanced percussive ...Percussive drilling is gaining interest for both shallow and deep applications due to its potential for higher drilling rates in hard rocks.Therefore,for efficient rock breaking,the development of advanced percussive drilling simulation tools has the potential to be transformative.Such tools must accurately capture the rock’s response to enable an effective analysis of the fragmentation process.Traditional continuum numerical methods,such as the finite element method(FEM),do not simulate discrete cracks or the contact interaction between rock fragments.The finite-discrete element method(FDEM)is a three-dimensional hybrid method that combines FEM with the discrete element method(DEM)that addresses these limitations.New FDEM simulation results of impacts on Kuru Grey granite show good agreement with published experimental data.The interpretation focuses on two significant processes in percussive drilling:crack propagation and chipping generation.FDEM successfully simulates the evolution of cracks,including radial,side,and inclined cracks,as well as crushed and cracked zones.The simulation also reproduces the coalescence of adjacent craters to generate more chippings.Additionally,the stress state,velocity field and discrete fractures simulated by FDEM provide detailed insights into the different fracture patterns for Kuru Grey granite,enhancing understanding of the fundamental underlying mechanisms.展开更多
The modeling of crack growth in three-dimensional(3D)space poses significant challenges in rock mechanics due to the complex numerical computation involved in simulating crack propagation and interaction in rock mater...The modeling of crack growth in three-dimensional(3D)space poses significant challenges in rock mechanics due to the complex numerical computation involved in simulating crack propagation and interaction in rock materials.In this study,we present a novel approach that introduces a 3D numerical manifold method(3D-NMM)with a geometric kernel to enhance computational efficiency.Specifically,the maximum tensile stress criterion is adopted as a crack growth criterion to achieve strong discontinuous crack growth,and a local crack tracking algorithm and an angle correction technique are incorporated to address minor limitations of the algorithm in a 3D model.The implementation of the program is carried out in Python,using object-oriented programming in two independent modules:a calculation module and a crack module.Furthermore,we propose feasible improvements to enhance the performance of the algorithm.Finally,we demonstrate the feasibility and effectiveness of the enhanced algorithm in the 3D-NMM using four numerical examples.This study establishes the potential of the 3DNMM,combined with the local tracking algorithm,for accurately modeling 3D crack propagation in brittle rock materials.展开更多
The rutting and low-temperature resistances of warm-mix recycled asphalt binders under the secondary aging condition were measured by the dynamic shear rheometer test and bending beam rheometer test.Effects of differe...The rutting and low-temperature resistances of warm-mix recycled asphalt binders under the secondary aging condition were measured by the dynamic shear rheometer test and bending beam rheometer test.Effects of different types of warm-mix asphalt(WMA)technologies and additives were evaluated.Aging and improvement mechanisms were investigated by the Fourier transform infrared spectroscopy test.It is found that recycled binders after the secondary aging are more resistant to rutting and less resistant to low-temperature cracking.The two warm-mix asphalt technologies have opposite effects.Using the Sasobit WMA significantly improves the rutting resistance and reduces the low temperature resistance for the recycled binders due to its morphological change at different temperatures.The rutting factor values of recycled asphalt binders with the Sasobit additive increase by 4.6 to 5.6 times.However,using the Evotherm WMA causes the deterioration of the rutting resistance due to the structural lubrication effect.The rutting factor values of recycled asphalt binders with the Evotherm additive show the reduction of 52%to 62%.It is recommended to add the styrene butadiene rubber latex or crumb rubber powder into the warm-mix recycled asphalt binders to simultaneously improve the rutting and low-temperature cracking resistances.展开更多
Lithium-ion batteries(LIBs)have evolved into the mainstream power source of ene rgy sto rage equipment by reason of their advantages such as high energy density,high power,long cycle life and less pollution.With the e...Lithium-ion batteries(LIBs)have evolved into the mainstream power source of ene rgy sto rage equipment by reason of their advantages such as high energy density,high power,long cycle life and less pollution.With the expansion of their applications in deep-sea exploration,aerospace and military equipment,special working conditions have placed higher demands on the low-temperature performance of LIBs.However,at low temperatures,the severe polarization and inferior electrochemical activity of electrode materials cause the acute capacity fading upon cycling,which greatly hindered the further development of LIBs.In this review,we summarize the recent important progress of LIBs in low-temperature operations and introduce the key methods and the related action mechanisms for enhancing the capacity of the various cathode and anode materials.It aims to promote the development of high-performance electrode materials and broaden the application range of LIBs.展开更多
The high-strength low-alloy steel plates with varying Ni/Mo contents were manufactured using the thermos-mechanical control process.The investigation was conducted to explore the effect of Ni/Mo microalloying on micro...The high-strength low-alloy steel plates with varying Ni/Mo contents were manufactured using the thermos-mechanical control process.The investigation was conducted to explore the effect of Ni/Mo microalloying on microstructure evolution and mechanical properties of the steel.The results revealed that the increase in Ni content from 1 to 2 wt.%reduced the transition temperature of ferrite and the growth range of ferritic grain was narrowed,which promoted grain refinement.The optimized combination of grain size,high-angle grain boundaries(HAGBs),and martensite-austenite(M-A)islands parameter contributed to the excellent impact toughness of S1 steel at-100℃(impact absorbed energy of 218.2 J at-100℃).As the Mo increases from 0 to 2 wt.%,the matrix structure changes from multiphase structure to granular bainite,which increases the average effective grain size to~4.62 pm and reduces HAGBs proportion to~36.22%.With these changes,the low-temperature impact toughness of S3 steel is weakened.In addition,based on the analysis of the characteristics of crack propagation path,it was found that M-A islands with low content(~2.21%)and small size(~1.76 pm)significantly retarded crack propagation,and the fracture model of M-A islands with different morphologies was further proposed.Furthermore,correlation between behaviour of delamination and toughness was further analysed by observing delamination size and impact energy parameters.展开更多
Static cracking agent(SCA)is actively investigated as an alternative to explosive blasting for rock breakage due to its immense expansion property.SCA can eliminate the negative effects of shock,noise and harmful gase...Static cracking agent(SCA)is actively investigated as an alternative to explosive blasting for rock breakage due to its immense expansion property.SCA can eliminate the negative effects of shock,noise and harmful gases encountered in explosive blasting processes.Accurate measurement and deep understanding of the expansive properties of SCAs are important in their industrial application.An improved outer pipe method(OPM),termed the upper end surface method(UESM),is proposed in this paper to overcome the shortcomings of the OPM in the expansive pressure measurement of SCAs.Numerical simulation is used to proof the concept and a mathematical model established to relate the internal pressure and the radial strains at different positions in the upper end surface method test equipment.The new equipment is calibrated using oil pressure and strain measurements.The calibrated equipment is then used to measure the expansion pressure of SCA at three different water contents to proof its potential.The differences in the measurements with OPM and UESM at three different moisture contents are less than 4%.The experimental results confirm the accuracy and applicability of the more user friendly and less expensive UESM in the measurement of the expansive pressures of SCAs.展开更多
The cracking behavior of lightweight aggregate concrete(LWAC) was investigated by mechanical analysis, SEM and cracking-resistant test where a shrinkage-restrained ring with a clapboard was used. The relationship betw...The cracking behavior of lightweight aggregate concrete(LWAC) was investigated by mechanical analysis, SEM and cracking-resistant test where a shrinkage-restrained ring with a clapboard was used. The relationship between the ceramsite type and the cracking resistance of LWAC was built up and compared with that of normal-weight coarse aggregate concrete(NWAC). A new method was proposed to evaluate the cracking resistance of concrete, where the concepts of cracking coefficient ζt(t) and the evaluation index Acr(t) were proposed, and the development of micro-cracks and damage accumulation were recognized. For the concrete with an ascending cracking coefficient curve, the larger Acr(t) is, the lower cracking resistance of concrete is. For the concrete with a descending cracking coefficient curve, the larger Acr(t) is, the stronger the cracking resistance of concrete is. The evaluation results show that in the case of that all the three types of coarse aggregates in concrete are pre-soaked for 24 h, NWAC has the lowest cracking resistance, followed by the LWAC with lower water absorption capacity ceramsite and the LWAC with higher water absorption capacity ceramsite has the strongest cracking resistance. The proposed method has obvious advantages over the cracking age method, because it can evaluate the cracking behavior of concrete even if the concrete has not an observable crack.展开更多
In the finite element method,the numerical simulation of three-dimensional crack propagation is relatively rare,and it is often realized by commercial programs.In addition to the geometric complexity,the determination...In the finite element method,the numerical simulation of three-dimensional crack propagation is relatively rare,and it is often realized by commercial programs.In addition to the geometric complexity,the determination of the cracking direction constitutes a great challenge.In most cases,the local stress state provides the fundamental criterion to judge the presence of cracks and the direction of crack propagation.However,in the case of three-dimensional analysis,the coordination relationship between grid elements due to occurrence of cracks becomes a difficult problem for this method.In this paper,based on the extended finite element method,the stress-related function field is introduced into the calculation domain,and then the boundary value problem of the function is solved.Subsequently,the envelope surface of all propagation directions can be obtained at one time.At last,the possible surface can be selected as the direction of crack development.Based on the aforementioned procedure,such method greatly reduces the programming complexity of tracking the crack propagation.As a suitable method for simulating tension-induced failure,it can simulate multiple cracks simultaneously.展开更多
Self-deformation cracking is the cracking caused by thermal deformation, autogenous volume deformation or shrinkage deformation. In this paper, an extended finite element calculation method was deduced for concrete cr...Self-deformation cracking is the cracking caused by thermal deformation, autogenous volume deformation or shrinkage deformation. In this paper, an extended finite element calculation method was deduced for concrete crack propagation under a constant hydration and hardening condition during the construction period, and a corresponding programming code was developed. The experimental investigation shows that initial crack propagation caused by self-deformation loads can be analyzed by this program. This improved algorithm was a preliminary application of the XFEM to the problem of the concrete self-deformation cracking during the hydration and hardening period. However, room for improvement exists for this algorithm in terms of matching calculation programs with mass concrete temperature fields containing cooling pipes and the influence of creep or damage on crack propagation.展开更多
The Finite Element Method of Lines （FEMOL） is a semi-analytic approach and takes a position between FEM and analytic methods. First, FEMOL in Fracture Mechanics is presented in detail. Then, the method is applied to...The Finite Element Method of Lines （FEMOL） is a semi-analytic approach and takes a position between FEM and analytic methods. First, FEMOL in Fracture Mechanics is presented in detail. Then, the method is applied to a set of examples such as edge-crack plate, the central-crack plate, the plate with cracks emanating from a hole under tensile or under combination loads of tensile and bending. Their dimensionless stress distribution, the stress intensify factor （SIF） and crack opening displacement （COD） are obtained, and comparison with known solutions by other methods are reported. It is found that a good accuracy is achieved by FEMOL. The method is successfully modified to remarkably increase the accuracy and reduce convergence difficulties. So it is a very useful and new tool in studying fracture mechanics problems.展开更多
To improve the cracking behavior of hydrocarbon,Ni-Mo/SiO_(2) bimetallic catalysts were synthesized by different preparation methods(sol-gel,co-impregnation and single-impregnation) and added the additives(citric acid...To improve the cracking behavior of hydrocarbon,Ni-Mo/SiO_(2) bimetallic catalysts were synthesized by different preparation methods(sol-gel,co-impregnation and single-impregnation) and added the additives(citric acid,polyethylene glycol and cetyltrimethylammonium bromide) based on the most suitable method above.The cracking reaction of methylcyclohexane under supercritical conditions was performed as the probe reaction to estimate the catalytic performance,and the properties of Ni-Mo/SiO_(2) catalyst were characterized by N_(2) absorption-desorption,XRD,XPS,H_(2)-TPR,NH_(3)-TPD,in-situ IR of NH_(3) desorption,HRTEM and STEM-mapping so as to study the structure-activity relationship.The catalyst synthesized via sol-gel method showed the best conversion and heat sink,being 81.8% and 3.81 MJ/kg,which was closely related to strong mutual effect between active components and SiO_(2) as well as strong acid sites.Besides,the introduction of additives by sol-gel method has an affirmative influence on properties of Ni-Mo/SiO_(2) catalysts,being that the acidity(more L and B acid sites) was modulated and organic groups interact with metal to suppress the aggregation of metal species(Ni and Mo),thereby enhancing the catalytic activity.At 750℃,the conversion(89.3%) as well as heat sink(3.99 MJ/kg) of MCH cracking obtained an optimum over Ni-Mo/SiO_(2) catalyst with addition of citric acid.展开更多
Damage in a rock mass is heavily dependent on the existence and growth of joints,which are also influenced by the complex stress states induced by human activities(e.g.,tunneling and excavation).A proper representatio...Damage in a rock mass is heavily dependent on the existence and growth of joints,which are also influenced by the complex stress states induced by human activities(e.g.,tunneling and excavation).A proper representation of the loading path is essential for understanding the mechanical behaviors of rock masses.Based on the discrete element method(DEM),the influence of the loading path on the cracking process of a rock specimen containing an open flaw is examined.The effectiveness of the model is confirmed by comparing the simulation results under a uniaxial compression test to existing research findings,where wing crack initiates first and secondary cracks contribute to the failure of the specimen.Simulation results confirm that the cracking process is dependent upon both the confining pressure and the loading path.Under the axial loading test,a higher confining pressure suppresses the development of tensile wing cracks and forces the formation of secondary cracks in the form of shear bands perpendicular to the flaw.Increase of confining pressure also decreases the influence of the loading path on the cracking process.Reduction of confining pressure during an unloading test amplifies the concentration of tensile stress and ultimately promotes the appearance of a tensile splitting fracture at meso-scale.Confining pressure at the failure stage is well predicted by the Hoek-Brown failure criterion under quasi-static conditions.展开更多
The crack tip strain gauge method in the compliance technique was used to determine the opening load of notched crack of axle steel,and the nonlinear finite element ADINA program, to which the cyclic stress-strain cur...The crack tip strain gauge method in the compliance technique was used to determine the opening load of notched crack of axle steel,and the nonlinear finite element ADINA program, to which the cyclic stress-strain curve of axle steel was applied,was used to analyze the stress-strain field ahead of the crack tip and the opening load of notched crack.The results of both the compliance technique and the numerical method were in good agreement.In this pa- per,the concept of the sensitive point is proposed and the key to the determination of the crack opening load in the experiment is to place a strain gauge at sensitive point.It is certified by both experimental and numerical methods that the sensitive point has the best linear relation- ship character and the value of strain is much greater.展开更多
This paper proposes a new, simple and efficient method for nonlinear simulation of arch dam cracking from the construction period to the operation period, which takes into account the arch dam construction process and...This paper proposes a new, simple and efficient method for nonlinear simulation of arch dam cracking from the construction period to the operation period, which takes into account the arch dam construction process and temperature loads. In the calculation mesh, the contact surface of pair nodes is located at places on the arch dam where cracking is possible. A new effective iterative method, the mixed finite element method for friction-contact problems, is improved and used for nonlinear simulation of the cracking process. The forces acting on the structure are divided into two parts： external forces and contact forces. The displacement of the structure is chosen as the basic variable and the nodal contact force in the possible contact region of the local coordinate system is chosen as the iterative variable, so that the nonlinear iterative process is only limited within the possible contact surface and is much more economical. This method was used to simulate the cracking process of the Shuanghe Arch Dam in Southwest China. In order to prove the validity and accuracy of this method and to study the effect of thermal stress on arch dam cracking, three schemes were designed for calculation. Numerical results agree with actual measured data, proving that it is feasible to use this method to simulate the entire process of nonlinear arch dam cracking.展开更多
In this paper a new method for preventing welding hot cracking—the inverse strain method(ISM)is developed on the principle of welding mechan- ics.Effectiveness and feasiblity of method in preventing welding hot crack...In this paper a new method for preventing welding hot cracking—the inverse strain method(ISM)is developed on the principle of welding mechan- ics.Effectiveness and feasiblity of method in preventing welding hot cracking of high strength aluminum alloy LY12CZ by synchronous rolling during welding (SRDW)along both sides of the weld at a suitable distance behind the welding arc are examined.Experimental resulte indicate that welding hot cracking of LY12CY can be effectively prevented and the mechanical properties of welded joint can also be improved by the method.It is an important new solution for preventing hot cracking in welding of sheet metal.展开更多
Using XRD,TEM and VSM methods,the phase,morphology and magnetic property of iron hydroxide oxide(FeOOH) which has been prepared by low-temperature neutralization reaction under different magnetic fields were analyzed....Using XRD,TEM and VSM methods,the phase,morphology and magnetic property of iron hydroxide oxide(FeOOH) which has been prepared by low-temperature neutralization reaction under different magnetic fields were analyzed.It can be found that the magnetic field had a great influence on the product.Acicular goethite(α-FeOOH) was synthetized without magnetic field.When the magnetic flux density was increased to 0.1T,γ-FeOOH was obtained.If the magnetic field intensity was raised to 0.5T,the product was all composed of δ-FeOOH.Moreover,the crystallization of FeOOH was greatly influenced by magnetic field as well.Thermodynamic calculation results show that the magnetic free energy of chemical reaction reached to more than hundreds KJ/mol when the magnetic field is applied.It meaned that the application of magnetic field was conducived to producing the products with higher susceptibility.Even under the low magnetic field,due to the stability of the reaction products was broken by the magnetic field,the magnetic free energy was also effective.展开更多
Factors affecting the resistance of asphalt mixtures against low-temperature cracking are divided into three categories:pavement structure geometry,material properties,and environmental conditions.Most of the existing...Factors affecting the resistance of asphalt mixtures against low-temperature cracking are divided into three categories:pavement structure geometry,material properties,and environmental conditions.Most of the existing models for evaluating and predicting the resistance of asphalt mixtures against low-temperature cracking have focused more on environmental factors and pavement structure geometry.However,the impact of material properties has been neglected.The concepts of surface free energy(SFE)that focus on material properties have a high potential to assess different failures of asphalt mixtures.Accordingly,in this research,the effect of SFE parameters,along with mix design parameters and bitumen rheological properties,were studied on the resistance of asphalt mixture against low-temperature cracking using an artificial neural network(ANN)model.Two indicators of fracture energy and fracture toughness were considered as the criteria for the resistance of asphalt mixtures against low-temperature cracking which is measured by the semi-circular bending(SCB)test.The sensitivity analysis results of the models indicated a positive correlation between the resistance of asphalt mixtures against low-temperature cracking and independent variables,including the apparent film thickness(AFT)on the surface of the aggregate,the index of aggregate(Ia),adhesion free energy(AFE),the ratio of the base to acid component of the aggregates(base to acid),cohesion free energy(CFE),the specific surface area(SSA)of the aggregates,and the stress relaxation rate(m-value).Among the variables studied,bitumen creep stiffness had a reverse relationship with the resistance of asphalt mixtures against low-temperature cracking.In addition,the sensitivity analysis results based on normalized data illustrated that the AFT and m-value were the most significant parameters affecting the asphalt mixtures'resistance against low-temperature cracking.展开更多
基金supported by Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.SML2023SP243)the National Key Research and Development Program of China(No.2022YFC2906100)the National Natural Science Foundation of China(No.92475202)are acknowledged.
文摘Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is generally slow at low temperature,resulting in large overpotential and low current efficiency.Thus,the application of external physical fields has emerged as an effective strategy for improving the mass and charge transfer processes during electrochemical reactions.This review highlights the challenges associated with low-temperature electrochemical processes and briefly discusses recent achievements in optimizing electrodeposition processes through the use of external physical fields.The regulating effects on the optimization of the electrodeposition process and the strategies for select-ing various external physical fields,including magnetic,supergravity,and ultrasonic fields are summarized from the perspectives of equipment and mechanisms.Finally,advanced methods for in-situ characterization of external physical field-assisted electrodeposition processes are reviewed to gain a deeper understanding of metallic electrodeposition.An in-depth exploration of the mechanism by which external physical fields affect the electrode process is essential for enhancing the efficiency of metal extraction at low temperatures.
基金the financial support by the National Natural Science Foundation of China(Grant No.52108397)“Xiaohe”Science and Technology Talent Special Project(Grant No.2024 TJ-X06)Water Resources Science and Technology Project of Hunan Province(Grant No.XSKJ2023059-41).
文摘Cracking affected by wetting-drying cycles is a major cause of shallow failure of soft rock slopes.Knowledge of rock tensile properties and cracking behaviors helps better assess the stability of soft rock slopes.This study aims to examine the cracking behaviors and tensile strength of silty mudstone under wetting-drying cycles.The wetting-drying cycle and Brazilian splitting tests were performed on silty mudstone considering various cycle number and amplitude.The cracking behaviors of wetting-drying cycles were analyzed by digital image correlation,three-dimensional(3D)scanning technology,and scanning electron microscopy.The results reveal a spiral-like pattern of crack ratio escalation in silty mudstone,with a higher crack ratio observed during drying than wetting.Tensile strength and fracture energy correlate negatively with cycle number or amplitude,with cycle number exerting a more pronounced effect.The variance of the maximum principal strain reflects stages of initial deformation,linear deformation,strain localization,and stable deformation.The formation of strain localization zones reveals the physical process of crack propagation.Crack tip opening displacement progresses through stages of slow growth,exponential growth,and linear growth,delineating the process from crack initiation to stable extension.Failure modes of silty mudstone primarily involve tensile and tensile-shear failure,influenced by the geometric parameters of cracks induced by wetting-drying cycles.Fracture surface roughness and fractal dimension increase with cycle number due to mineral dissolution,physical erosion,and nondirectional crack propagation.Hydration-swelling and dehydration-shrinkage of clay minerals,along with absorption-drying cracking,initiate and merge cracks,leading to degradation of the rock mechanical properties.The findings could provide insights for mitigating shallow cracking of soft rock slopes under wetting-drying cycles.
基金supported in part by the National Natural Science Foundation of China(Nos.61201048,61107063)the National Science and Technology Major Project(No.2017-VI-001-0094).
文摘To investigate the residual stress distribution and its influence on machining deformation in 6061-T651 aluminum alloy plates,this paper uses the crack compliance method to study the residual stress characteristics of 6061-T651 aluminum alloy plates with a thickness of 75 mm produced by two domestic manufacturers in China.The results indicate that both types of plates exhibit highly consistent and symmetrical M-shaped residual stress profile along the thickness direction,manifested as surface layer compression and core tension.The strain energy density across all specimens ranges from 1.27 kJ/m^(3)to 1.43 kJ/m^(3).Machining deformation simulations of an aerospace component incorporating these measured stresses showed minimal final deformation difference between the material sources,with a maximum deviation of only 0.009 mm across specimens.These findings provide critical data for material selection and deformation control in aerospace manufacturing.
文摘Percussive drilling is gaining interest for both shallow and deep applications due to its potential for higher drilling rates in hard rocks.Therefore,for efficient rock breaking,the development of advanced percussive drilling simulation tools has the potential to be transformative.Such tools must accurately capture the rock’s response to enable an effective analysis of the fragmentation process.Traditional continuum numerical methods,such as the finite element method(FEM),do not simulate discrete cracks or the contact interaction between rock fragments.The finite-discrete element method(FDEM)is a three-dimensional hybrid method that combines FEM with the discrete element method(DEM)that addresses these limitations.New FDEM simulation results of impacts on Kuru Grey granite show good agreement with published experimental data.The interpretation focuses on two significant processes in percussive drilling:crack propagation and chipping generation.FDEM successfully simulates the evolution of cracks,including radial,side,and inclined cracks,as well as crushed and cracked zones.The simulation also reproduces the coalescence of adjacent craters to generate more chippings.Additionally,the stress state,velocity field and discrete fractures simulated by FDEM provide detailed insights into the different fracture patterns for Kuru Grey granite,enhancing understanding of the fundamental underlying mechanisms.
基金supported by the National Natural Science Foundation of China(Grant Nos.42172312 and 52211540395)support from the Institut Universitaire de France(IUF).
文摘The modeling of crack growth in three-dimensional(3D)space poses significant challenges in rock mechanics due to the complex numerical computation involved in simulating crack propagation and interaction in rock materials.In this study,we present a novel approach that introduces a 3D numerical manifold method(3D-NMM)with a geometric kernel to enhance computational efficiency.Specifically,the maximum tensile stress criterion is adopted as a crack growth criterion to achieve strong discontinuous crack growth,and a local crack tracking algorithm and an angle correction technique are incorporated to address minor limitations of the algorithm in a 3D model.The implementation of the program is carried out in Python,using object-oriented programming in two independent modules:a calculation module and a crack module.Furthermore,we propose feasible improvements to enhance the performance of the algorithm.Finally,we demonstrate the feasibility and effectiveness of the enhanced algorithm in the 3D-NMM using four numerical examples.This study establishes the potential of the 3DNMM,combined with the local tracking algorithm,for accurately modeling 3D crack propagation in brittle rock materials.
基金The Natural Science Foundation of Jiangsu Province(No.BK20181404)Qing Lan Project(2016)the Training Plan Project for Young Core Teachers of Nanjing Forestry University(2017).
文摘The rutting and low-temperature resistances of warm-mix recycled asphalt binders under the secondary aging condition were measured by the dynamic shear rheometer test and bending beam rheometer test.Effects of different types of warm-mix asphalt(WMA)technologies and additives were evaluated.Aging and improvement mechanisms were investigated by the Fourier transform infrared spectroscopy test.It is found that recycled binders after the secondary aging are more resistant to rutting and less resistant to low-temperature cracking.The two warm-mix asphalt technologies have opposite effects.Using the Sasobit WMA significantly improves the rutting resistance and reduces the low temperature resistance for the recycled binders due to its morphological change at different temperatures.The rutting factor values of recycled asphalt binders with the Sasobit additive increase by 4.6 to 5.6 times.However,using the Evotherm WMA causes the deterioration of the rutting resistance due to the structural lubrication effect.The rutting factor values of recycled asphalt binders with the Evotherm additive show the reduction of 52%to 62%.It is recommended to add the styrene butadiene rubber latex or crumb rubber powder into the warm-mix recycled asphalt binders to simultaneously improve the rutting and low-temperature cracking resistances.
基金supported by the National Natural Science Foundation of China(NSFC,Nos.51772205,51572192,51772208,51472179)the General Program of Municipal Natural Science Foundation of Tianjin(Nos.17JCYBJC17000,17JCYBJC22700)。
文摘Lithium-ion batteries(LIBs)have evolved into the mainstream power source of ene rgy sto rage equipment by reason of their advantages such as high energy density,high power,long cycle life and less pollution.With the expansion of their applications in deep-sea exploration,aerospace and military equipment,special working conditions have placed higher demands on the low-temperature performance of LIBs.However,at low temperatures,the severe polarization and inferior electrochemical activity of electrode materials cause the acute capacity fading upon cycling,which greatly hindered the further development of LIBs.In this review,we summarize the recent important progress of LIBs in low-temperature operations and introduce the key methods and the related action mechanisms for enhancing the capacity of the various cathode and anode materials.It aims to promote the development of high-performance electrode materials and broaden the application range of LIBs.
基金supported by the Project of Promoting Talents in Liaoning province (Grant No.XLYC2007036).
文摘The high-strength low-alloy steel plates with varying Ni/Mo contents were manufactured using the thermos-mechanical control process.The investigation was conducted to explore the effect of Ni/Mo microalloying on microstructure evolution and mechanical properties of the steel.The results revealed that the increase in Ni content from 1 to 2 wt.%reduced the transition temperature of ferrite and the growth range of ferritic grain was narrowed,which promoted grain refinement.The optimized combination of grain size,high-angle grain boundaries(HAGBs),and martensite-austenite(M-A)islands parameter contributed to the excellent impact toughness of S1 steel at-100℃(impact absorbed energy of 218.2 J at-100℃).As the Mo increases from 0 to 2 wt.%,the matrix structure changes from multiphase structure to granular bainite,which increases the average effective grain size to~4.62 pm and reduces HAGBs proportion to~36.22%.With these changes,the low-temperature impact toughness of S3 steel is weakened.In addition,based on the analysis of the characteristics of crack propagation path,it was found that M-A islands with low content(~2.21%)and small size(~1.76 pm)significantly retarded crack propagation,and the fracture model of M-A islands with different morphologies was further proposed.Furthermore,correlation between behaviour of delamination and toughness was further analysed by observing delamination size and impact energy parameters.
基金funded by the State Key Research Development Program of China(No.2018YFC0604400)the National Science Foundation of China(Nos.51874068,52074062)+2 种基金the Fundamental Research Funds for the Central Universities(Nos.N2001003,N160107001,N180701016,N182608003,N2001001)the 111 Project(No.B17009)The authors also acknowledge Nazarbayev University for funding the research through its Collaborative Research Program(No.OPCRP2020014).
文摘Static cracking agent(SCA)is actively investigated as an alternative to explosive blasting for rock breakage due to its immense expansion property.SCA can eliminate the negative effects of shock,noise and harmful gases encountered in explosive blasting processes.Accurate measurement and deep understanding of the expansive properties of SCAs are important in their industrial application.An improved outer pipe method(OPM),termed the upper end surface method(UESM),is proposed in this paper to overcome the shortcomings of the OPM in the expansive pressure measurement of SCAs.Numerical simulation is used to proof the concept and a mathematical model established to relate the internal pressure and the radial strains at different positions in the upper end surface method test equipment.The new equipment is calibrated using oil pressure and strain measurements.The calibrated equipment is then used to measure the expansion pressure of SCA at three different water contents to proof its potential.The differences in the measurements with OPM and UESM at three different moisture contents are less than 4%.The experimental results confirm the accuracy and applicability of the more user friendly and less expensive UESM in the measurement of the expansive pressures of SCAs.
基金Project(51078090)supported by the National Natural Science Foundation of China
文摘The cracking behavior of lightweight aggregate concrete(LWAC) was investigated by mechanical analysis, SEM and cracking-resistant test where a shrinkage-restrained ring with a clapboard was used. The relationship between the ceramsite type and the cracking resistance of LWAC was built up and compared with that of normal-weight coarse aggregate concrete(NWAC). A new method was proposed to evaluate the cracking resistance of concrete, where the concepts of cracking coefficient ζt(t) and the evaluation index Acr(t) were proposed, and the development of micro-cracks and damage accumulation were recognized. For the concrete with an ascending cracking coefficient curve, the larger Acr(t) is, the lower cracking resistance of concrete is. For the concrete with a descending cracking coefficient curve, the larger Acr(t) is, the stronger the cracking resistance of concrete is. The evaluation results show that in the case of that all the three types of coarse aggregates in concrete are pre-soaked for 24 h, NWAC has the lowest cracking resistance, followed by the LWAC with lower water absorption capacity ceramsite and the LWAC with higher water absorption capacity ceramsite has the strongest cracking resistance. The proposed method has obvious advantages over the cracking age method, because it can evaluate the cracking behavior of concrete even if the concrete has not an observable crack.
基金Project(2017YFC0404802)supported by the National Key R&D Program of ChinaProjects(U1965206,51979143)supported by the National Natural Science Foundation of China。
文摘In the finite element method,the numerical simulation of three-dimensional crack propagation is relatively rare,and it is often realized by commercial programs.In addition to the geometric complexity,the determination of the cracking direction constitutes a great challenge.In most cases,the local stress state provides the fundamental criterion to judge the presence of cracks and the direction of crack propagation.However,in the case of three-dimensional analysis,the coordination relationship between grid elements due to occurrence of cracks becomes a difficult problem for this method.In this paper,based on the extended finite element method,the stress-related function field is introduced into the calculation domain,and then the boundary value problem of the function is solved.Subsequently,the envelope surface of all propagation directions can be obtained at one time.At last,the possible surface can be selected as the direction of crack development.Based on the aforementioned procedure,such method greatly reduces the programming complexity of tracking the crack propagation.As a suitable method for simulating tension-induced failure,it can simulate multiple cracks simultaneously.
基金Funded by the National Natural Science Foundation of China(Nos.51409264,51509020,51209219)Zhejiang Provincial Natural Science Foundation(No.LQ15E090003)
文摘Self-deformation cracking is the cracking caused by thermal deformation, autogenous volume deformation or shrinkage deformation. In this paper, an extended finite element calculation method was deduced for concrete crack propagation under a constant hydration and hardening condition during the construction period, and a corresponding programming code was developed. The experimental investigation shows that initial crack propagation caused by self-deformation loads can be analyzed by this program. This improved algorithm was a preliminary application of the XFEM to the problem of the concrete self-deformation cracking during the hydration and hardening period. However, room for improvement exists for this algorithm in terms of matching calculation programs with mass concrete temperature fields containing cooling pipes and the influence of creep or damage on crack propagation.
文摘The Finite Element Method of Lines （FEMOL） is a semi-analytic approach and takes a position between FEM and analytic methods. First, FEMOL in Fracture Mechanics is presented in detail. Then, the method is applied to a set of examples such as edge-crack plate, the central-crack plate, the plate with cracks emanating from a hole under tensile or under combination loads of tensile and bending. Their dimensionless stress distribution, the stress intensify factor （SIF） and crack opening displacement （COD） are obtained, and comparison with known solutions by other methods are reported. It is found that a good accuracy is achieved by FEMOL. The method is successfully modified to remarkably increase the accuracy and reduce convergence difficulties. So it is a very useful and new tool in studying fracture mechanics problems.
基金supported by National Natural Science Foundation of China [grant number 91841301]Fundamental Research Funds for the Central Universities [grant number YJ201791]。
文摘To improve the cracking behavior of hydrocarbon,Ni-Mo/SiO_(2) bimetallic catalysts were synthesized by different preparation methods(sol-gel,co-impregnation and single-impregnation) and added the additives(citric acid,polyethylene glycol and cetyltrimethylammonium bromide) based on the most suitable method above.The cracking reaction of methylcyclohexane under supercritical conditions was performed as the probe reaction to estimate the catalytic performance,and the properties of Ni-Mo/SiO_(2) catalyst were characterized by N_(2) absorption-desorption,XRD,XPS,H_(2)-TPR,NH_(3)-TPD,in-situ IR of NH_(3) desorption,HRTEM and STEM-mapping so as to study the structure-activity relationship.The catalyst synthesized via sol-gel method showed the best conversion and heat sink,being 81.8% and 3.81 MJ/kg,which was closely related to strong mutual effect between active components and SiO_(2) as well as strong acid sites.Besides,the introduction of additives by sol-gel method has an affirmative influence on properties of Ni-Mo/SiO_(2) catalysts,being that the acidity(more L and B acid sites) was modulated and organic groups interact with metal to suppress the aggregation of metal species(Ni and Mo),thereby enhancing the catalytic activity.At 750℃,the conversion(89.3%) as well as heat sink(3.99 MJ/kg) of MCH cracking obtained an optimum over Ni-Mo/SiO_(2) catalyst with addition of citric acid.
基金supported by the Shandong Provincial Natural Science Foundation of China(No.ZR2020YQ44)the National Natural Science Foundation of China(No.51909138)。
文摘Damage in a rock mass is heavily dependent on the existence and growth of joints,which are also influenced by the complex stress states induced by human activities(e.g.,tunneling and excavation).A proper representation of the loading path is essential for understanding the mechanical behaviors of rock masses.Based on the discrete element method(DEM),the influence of the loading path on the cracking process of a rock specimen containing an open flaw is examined.The effectiveness of the model is confirmed by comparing the simulation results under a uniaxial compression test to existing research findings,where wing crack initiates first and secondary cracks contribute to the failure of the specimen.Simulation results confirm that the cracking process is dependent upon both the confining pressure and the loading path.Under the axial loading test,a higher confining pressure suppresses the development of tensile wing cracks and forces the formation of secondary cracks in the form of shear bands perpendicular to the flaw.Increase of confining pressure also decreases the influence of the loading path on the cracking process.Reduction of confining pressure during an unloading test amplifies the concentration of tensile stress and ultimately promotes the appearance of a tensile splitting fracture at meso-scale.Confining pressure at the failure stage is well predicted by the Hoek-Brown failure criterion under quasi-static conditions.
文摘The crack tip strain gauge method in the compliance technique was used to determine the opening load of notched crack of axle steel,and the nonlinear finite element ADINA program, to which the cyclic stress-strain curve of axle steel was applied,was used to analyze the stress-strain field ahead of the crack tip and the opening load of notched crack.The results of both the compliance technique and the numerical method were in good agreement.In this pa- per,the concept of the sensitive point is proposed and the key to the determination of the crack opening load in the experiment is to place a strain gauge at sensitive point.It is certified by both experimental and numerical methods that the sensitive point has the best linear relation- ship character and the value of strain is much greater.
基金supported by the National Nature Science Foundation of China (Grant No 90510017)
文摘This paper proposes a new, simple and efficient method for nonlinear simulation of arch dam cracking from the construction period to the operation period, which takes into account the arch dam construction process and temperature loads. In the calculation mesh, the contact surface of pair nodes is located at places on the arch dam where cracking is possible. A new effective iterative method, the mixed finite element method for friction-contact problems, is improved and used for nonlinear simulation of the cracking process. The forces acting on the structure are divided into two parts： external forces and contact forces. The displacement of the structure is chosen as the basic variable and the nodal contact force in the possible contact region of the local coordinate system is chosen as the iterative variable, so that the nonlinear iterative process is only limited within the possible contact surface and is much more economical. This method was used to simulate the cracking process of the Shuanghe Arch Dam in Southwest China. In order to prove the validity and accuracy of this method and to study the effect of thermal stress on arch dam cracking, three schemes were designed for calculation. Numerical results agree with actual measured data, proving that it is feasible to use this method to simulate the entire process of nonlinear arch dam cracking.
文摘In this paper a new method for preventing welding hot cracking—the inverse strain method(ISM)is developed on the principle of welding mechan- ics.Effectiveness and feasiblity of method in preventing welding hot cracking of high strength aluminum alloy LY12CZ by synchronous rolling during welding (SRDW)along both sides of the weld at a suitable distance behind the welding arc are examined.Experimental resulte indicate that welding hot cracking of LY12CY can be effectively prevented and the mechanical properties of welded joint can also be improved by the method.It is an important new solution for preventing hot cracking in welding of sheet metal.
基金Item Sponsored by the National Natural Science Foundation of China(Key Basic Project,No.51034010)International cooperation project from Shanghai Science and Technology Commission(No.075207015)Key Basic Project from Science and Technology Commission of Shanghai Municipality(No.08JC1410000)
文摘Using XRD,TEM and VSM methods,the phase,morphology and magnetic property of iron hydroxide oxide(FeOOH) which has been prepared by low-temperature neutralization reaction under different magnetic fields were analyzed.It can be found that the magnetic field had a great influence on the product.Acicular goethite(α-FeOOH) was synthetized without magnetic field.When the magnetic flux density was increased to 0.1T,γ-FeOOH was obtained.If the magnetic field intensity was raised to 0.5T,the product was all composed of δ-FeOOH.Moreover,the crystallization of FeOOH was greatly influenced by magnetic field as well.Thermodynamic calculation results show that the magnetic free energy of chemical reaction reached to more than hundreds KJ/mol when the magnetic field is applied.It meaned that the application of magnetic field was conducived to producing the products with higher susceptibility.Even under the low magnetic field,due to the stability of the reaction products was broken by the magnetic field,the magnetic free energy was also effective.
文摘Factors affecting the resistance of asphalt mixtures against low-temperature cracking are divided into three categories:pavement structure geometry,material properties,and environmental conditions.Most of the existing models for evaluating and predicting the resistance of asphalt mixtures against low-temperature cracking have focused more on environmental factors and pavement structure geometry.However,the impact of material properties has been neglected.The concepts of surface free energy(SFE)that focus on material properties have a high potential to assess different failures of asphalt mixtures.Accordingly,in this research,the effect of SFE parameters,along with mix design parameters and bitumen rheological properties,were studied on the resistance of asphalt mixture against low-temperature cracking using an artificial neural network(ANN)model.Two indicators of fracture energy and fracture toughness were considered as the criteria for the resistance of asphalt mixtures against low-temperature cracking which is measured by the semi-circular bending(SCB)test.The sensitivity analysis results of the models indicated a positive correlation between the resistance of asphalt mixtures against low-temperature cracking and independent variables,including the apparent film thickness(AFT)on the surface of the aggregate,the index of aggregate(Ia),adhesion free energy(AFE),the ratio of the base to acid component of the aggregates(base to acid),cohesion free energy(CFE),the specific surface area(SSA)of the aggregates,and the stress relaxation rate(m-value).Among the variables studied,bitumen creep stiffness had a reverse relationship with the resistance of asphalt mixtures against low-temperature cracking.In addition,the sensitivity analysis results based on normalized data illustrated that the AFT and m-value were the most significant parameters affecting the asphalt mixtures'resistance against low-temperature cracking.
