This paper reports new geochronological(U-Pb) and isotope(C,O,and S) data to investigate the timing of mineralization and mode of ore genesis for the recently discovered Changtuxili Mn-Ag-Pb-Zn deposit,located on the ...This paper reports new geochronological(U-Pb) and isotope(C,O,and S) data to investigate the timing of mineralization and mode of ore genesis for the recently discovered Changtuxili Mn-Ag-Pb-Zn deposit,located on the western slopes of the southern Great Hinggan Range in NE China.The mineralization is hosted by intermediate-acidic lavas and pyroclastic rocks of the Baiyingaolao Formation.Three stages of mineralization are identified:quartz-pyrite(Stage I),galena-sphalerite-tetrahedrite-rhodochrosite(Stage II),and quartz-pyrite(Stage Ⅲ).δ13C and δ18O values for carbonate from the ore vary from-8.51‰ to-4.96‰ and 3.97‰ to 15.90‰,respectively,which are indicative of a low-temperature alteration environment.δ34SV-CDT values of sulfides range from-1.77‰ to 4.16‰ and show a trend of equilibrium fractionation(δ34SPy>δ34SSp>δ34SGn).These features indicate that pyrite,sphalerite,and galena precipitated during the period of mineralization.The alteration mineral assemblage and isotope data indicate that the weakly acidic to weakly alkaline ore-forming fluid was derived largely from meteoric water and the ore-forming elements C and S originated from magma.During the mineralization,a geochemical barrier was formed by changes in the pH of the ore-forming fluid,leading to the precipitation of rhodochrosite.On the basis of the mineralization characteristics,new isotope data,and comparison with adjacent deposits,we propose that the Changtuxili Mn-Ag-Pb-Zn deposit is an intermediate-to lowsulfidation epithermal deposit whose formation was controlled by fractures and variability in the pH of the oreforming fluid.The surrounding volcanic rocks yield zircon U-Pb ages of 160-146 Ma(Late Jurassic),indicating that the mineralization is younger than 146 Ma.展开更多
The Xiong’ershan area,as a part of a metallogenic province in cetral China,contains substantial Leimengou porphyry molybdenite deposit,Qiyugou breccia gold deposits and vein gold deposit occurred in fault zone,as wel...The Xiong’ershan area,as a part of a metallogenic province in cetral China,contains substantial Leimengou porphyry molybdenite deposit,Qiyugou breccia gold deposits and vein gold deposit occurred in fault zone,as well as previously refer to as orogenic gold deposit.Around or nearby the Mesozoic porphyry granite,the typical porphyry deposit,much more breccia pipes and breccia gold deposit are developed in the area.In this paper we focus on reporting preliminary results obtained from field,petrographic work on the Leimengou porphyry molybdenite and the Qiyugou breccia gold deposit,as well as laser Raman microspectroscopy and microprobe analyses carried out on samples from the Au-bearing Qiyugou breccia pipes.An adularia-calcite assemblage is reported in these breccia gold deposits.Two stages of hydrothermal alteration,pervasive and vein,are identified.The first stage consists of the alteration of the breccia clasts and rock flour by actinolite,green biotite,epidote,chlorite and minor sericite.This hydrothermal activity is likely to relate to the molybdenite mineralisation episode.The second stage is characterised by quartz veining and adularia and calcite filling open-spaces.Vein ores associated with quartz,sericite,and minor calcite alteration occur in NE-trending fault that cut the first stage of alteration.The adularia-calcite alteration is genetically associated with gold mineralization.The adularia-calcite assemblage in the area suggest that the Qiyugou pipes are of low-sulphidation epithermal in nature.The Qiyugou breccia pipes are coeval and spatially associated with the nearby Leimengou porphyry Mo deposit,which together conform to an alkalic mineralising system.We propose a model for the development and evolution of the breccia pipes in conjunction with a model that describes the genesis of the porphyry Mo and auriferous breccia pipes as a unified magmatic-hydrothermal system,which is linked with transition from collisional compressional to extensional geodynamic regime.展开更多
基金This study was funded in part by the China Geological Survey(Grant Nos.DD20190075 and DD20160041).
文摘This paper reports new geochronological(U-Pb) and isotope(C,O,and S) data to investigate the timing of mineralization and mode of ore genesis for the recently discovered Changtuxili Mn-Ag-Pb-Zn deposit,located on the western slopes of the southern Great Hinggan Range in NE China.The mineralization is hosted by intermediate-acidic lavas and pyroclastic rocks of the Baiyingaolao Formation.Three stages of mineralization are identified:quartz-pyrite(Stage I),galena-sphalerite-tetrahedrite-rhodochrosite(Stage II),and quartz-pyrite(Stage Ⅲ).δ13C and δ18O values for carbonate from the ore vary from-8.51‰ to-4.96‰ and 3.97‰ to 15.90‰,respectively,which are indicative of a low-temperature alteration environment.δ34SV-CDT values of sulfides range from-1.77‰ to 4.16‰ and show a trend of equilibrium fractionation(δ34SPy>δ34SSp>δ34SGn).These features indicate that pyrite,sphalerite,and galena precipitated during the period of mineralization.The alteration mineral assemblage and isotope data indicate that the weakly acidic to weakly alkaline ore-forming fluid was derived largely from meteoric water and the ore-forming elements C and S originated from magma.During the mineralization,a geochemical barrier was formed by changes in the pH of the ore-forming fluid,leading to the precipitation of rhodochrosite.On the basis of the mineralization characteristics,new isotope data,and comparison with adjacent deposits,we propose that the Changtuxili Mn-Ag-Pb-Zn deposit is an intermediate-to lowsulfidation epithermal deposit whose formation was controlled by fractures and variability in the pH of the oreforming fluid.The surrounding volcanic rocks yield zircon U-Pb ages of 160-146 Ma(Late Jurassic),indicating that the mineralization is younger than 146 Ma.
基金projects of China Geological Survey(No.12120113072600)National Natural Science Foundation of China(No.41830215).
文摘The Xiong’ershan area,as a part of a metallogenic province in cetral China,contains substantial Leimengou porphyry molybdenite deposit,Qiyugou breccia gold deposits and vein gold deposit occurred in fault zone,as well as previously refer to as orogenic gold deposit.Around or nearby the Mesozoic porphyry granite,the typical porphyry deposit,much more breccia pipes and breccia gold deposit are developed in the area.In this paper we focus on reporting preliminary results obtained from field,petrographic work on the Leimengou porphyry molybdenite and the Qiyugou breccia gold deposit,as well as laser Raman microspectroscopy and microprobe analyses carried out on samples from the Au-bearing Qiyugou breccia pipes.An adularia-calcite assemblage is reported in these breccia gold deposits.Two stages of hydrothermal alteration,pervasive and vein,are identified.The first stage consists of the alteration of the breccia clasts and rock flour by actinolite,green biotite,epidote,chlorite and minor sericite.This hydrothermal activity is likely to relate to the molybdenite mineralisation episode.The second stage is characterised by quartz veining and adularia and calcite filling open-spaces.Vein ores associated with quartz,sericite,and minor calcite alteration occur in NE-trending fault that cut the first stage of alteration.The adularia-calcite alteration is genetically associated with gold mineralization.The adularia-calcite assemblage in the area suggest that the Qiyugou pipes are of low-sulphidation epithermal in nature.The Qiyugou breccia pipes are coeval and spatially associated with the nearby Leimengou porphyry Mo deposit,which together conform to an alkalic mineralising system.We propose a model for the development and evolution of the breccia pipes in conjunction with a model that describes the genesis of the porphyry Mo and auriferous breccia pipes as a unified magmatic-hydrothermal system,which is linked with transition from collisional compressional to extensional geodynamic regime.
