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Surface Wettability and Boiling Heat Transfer Enhancement in Microchannels Using Graphene Nanoplatelet and Multi-Walled Carbon Nanotube Coatings
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作者 Ghinwa Al Mimar Natrah Kamaruzaman Kamil Talib Alkhateeb 《Frontiers in Heat and Mass Transfer》 2025年第6期1933-1956,共24页
The pivotal role microchannels play in the thermal management of electronic components has,in recent decades,prompted extensive research into methods for enhancing their heat transfer performance.Among these methods,s... The pivotal role microchannels play in the thermal management of electronic components has,in recent decades,prompted extensive research into methods for enhancing their heat transfer performance.Among these methods,surface wettability modification was found to be highly effective owing to its significant influence on boiling dynamics and heat transfer mechanisms.In this study,we modified surface wettability using a nanocomposite coating composed of graphene nano plate(GNPs)and multi-walled carbon nanotubes(MWCNT)and then examined how the modification affected the transfer of boiling heat in microchannels.The resultant heat transfer coefficients for hydrophilic and hydrophilic composite(GNPs+MWCNT)microchannels were,respectively,42.8%and 33.95%higher compared with that of the uncoated surface.These results verify that hydrophilic GNP-based coating significantly improves boiling heat transfer performance.It was observed that a minor increase in contact angle,θfrom 73.142°to 75.73°,resulted in a noticeable decrease in thermal performance.This is attributed to diminished liquid film stability,reduced nucleation site activity,and weakened capillary-driven liquid replenishment.These findings underscore the crucial role of optimized surface wettability in maintaining efficient microchannel boiling.At high mass flux,the GNPS microchannels exhibited maximum pressure drop values,with a pressure drop ratio as high as 36%compared to 29%for the GNPs+MWCNT composite samples.Nevertheless,when a composite hydrophilic–hydrophobic coating was deposited through electrodeposition,the enhancement in heat transfer was less significant.This was probably due to decreased surface uniformity,diminished liquid film stability,and the disruption of effective nucleation behavior,all associated with the slight increase in surface contact angle.The obtained results can be used as guidance for designing advanced cooling surfaces in high-performance microelectronic and energy systems,where precise control of surface characteristics is critical. 展开更多
关键词 MICROCHANNEL flow boiling NANOCOMPOSITE heat transfer
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Boiling Dynamics and Entropy Generation in Inclined Tubular Systems:Analysis and Optimization
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作者 Hao Tang Jianchang Yang +2 位作者 Yunxin Zhou Jianxin Xu Hua Wang 《Fluid Dynamics & Materials Processing》 2025年第7期1571-1600,共30页
This research explores the characteristics of boiling in inclined pipes,a domain of great importance in engineering.Employing an experimental visualization technique,the boiling dynamics of deionizedwater are examined... This research explores the characteristics of boiling in inclined pipes,a domain of great importance in engineering.Employing an experimental visualization technique,the boiling dynamics of deionizedwater are examined at varying inclination angles,paying special attention to the emerging flow patterns.The findings demonstrate that the inclination angle significantly impacts flow pattern transitions within the 0°to 90°range.As the heat flux rises,bubbles form in the liquid.The liquid’s inertia extends the bubble-wall contact time,thereby delaying the onset of bulk bubble flow.Beyond a 90°inclination,however,the patterning behavior is more influenced by the fluid velocity.At low speeds,incomplete pipe filling results in a large liquid plug hindering flow,while high speeds lead to full pipe filling.In general,gravity,inertia,buoyancy forces,and capillary forces are themain influential factors in the considered problem.However,an analysis of the heat transfer coefficient and boiling curve for different inclination angles reveals that the observed variations are essentially due to corresponding changes in the flow pattern.Finally,an optimal mass flux and inclination angle,able to minimize total entropy generation and improve heat transfer efficiency,are determined by means of an entropy generation analysis. 展开更多
关键词 Flow boiling inclination angle entropy generation flow pattern transition
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Flow Boiling Heat Transfer and Pressure Gradient of R410A in Micro-Channel Flat Tubes at 25℃ and 30℃
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作者 Bo Yu Yuye Luo +1 位作者 Luyao Guo Long Huang 《Frontiers in Heat and Mass Transfer》 2025年第2期553-575,共23页
This study investigates the flow boiling heat transfer coefficient and pressure gradient of refrigerant R410A inmicro-channel flat tubes.Experiments were conducted at saturation temperatures ranging from 25℃ to 30℃,... This study investigates the flow boiling heat transfer coefficient and pressure gradient of refrigerant R410A inmicro-channel flat tubes.Experiments were conducted at saturation temperatures ranging from 25℃ to 30℃,mass fluxes between 198 and 305 kg/m^(2)s,and heat fluxes from 9.77 to 20.18 kW/m^(2),yielding 99 sets of local heat transfer coefficient data.The results show that increasing heat flux and mass flux enhances the heat transfer coefficient,although the rate of enhancement decreases with increasing vapor quality.Conversely,higher saturation temperatures slightly reduce the heat transfer coefficient.Additionally,the experimental findings reveal discrepancies in the accuracy of existing pressure drop and heat transfer coefficient prediction models under the studied conditions.This study recommends using the Kimand Mudawar correlation to predict pressure gradients within the tested range,with aMean Error(ME)of−5.24%observed in this study.For heat transfer coefficients,the Cooper and Kandlikar correlations are recommended,achieving a Mean Absolute Error(MAE)of approximately 22%.This research provides value for performance prediction and parameter selection of micro-channel technology in broader application scenarios within heating,ventilation and air-conditioning fields. 展开更多
关键词 MICRO-CHANNEL flow boiling heat transfer coefficient pressure gradient R410A
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Experimental Study on Flow Boiling Characteristics of Low-GWP Fluid R1234yf in Microchannels Heat Sink
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作者 Ying Zhang Chao Dang Zhiqiang Zhang 《Frontiers in Heat and Mass Transfer》 2025年第4期1215-1242,共28页
In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 k... In this study,the flow boiling characteristics of R1234yf in parallel microchannels were experimentally investigated.The experiments were conducted with heat flux from 0 to 550 kW/m^(2),mass flux of 434,727,and 1015 kg/(m2 s),saturation temperatures of 293,298,and 303 K,and inlet sub-cooling of 5,10,and 15 K.The analysis of the experimental results provides the following conclusions:a reduced mass flux and lower subcooling correspond to a diminished degree of superheat at the boiling inception wall;conversely,an elevated saturation temperature results in a reduced amount of superheat at the boiling inception wall.Furthermore,an increase in sub-cooling and saturation temperature will enhance heat transfer efficiency.The wall temperature is mostly influenced by variations in saturation temperature and is minimally related to changes in mass flux and subcooling degree.An increase in mass flux results in a greater pressure drop attributed to heightened frictional pressure loss.The variation in pressure drop with respect to sub-cooling is minimal,while an increased saturation temperature correlates with a reduced pressure drop due to the formation of smaller bubbles and lowered frictional pressure loss at high saturation pressures.This study thoroughly examines and summarizes the effects of mass flow rate,saturation temperature,and subcooling on the flow-boiling heat transfer and pressure drop characteristics of R1234yf.Furthermore,the new correlation has 93.42%of the predicted values fall within a 15%mean absolute error,exhibiting a mean absolute error of 5.75%.It provides a superior method for predicting the flow-boiling heat transfer coefficients of R1234yf in the heat sink of parallel microchannels compared to existing correlations. 展开更多
关键词 Flow boiling microchannels high heat flux heat transfer pressure drop
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Enhanced Boiling Heat Transfer in Water Pools with Perforated Copper Beads and Sodium Dodecyl Sulfate Surfactant
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作者 Pengcheng Cai Teng Li +4 位作者 Jianxin Xu Xiaobo Li Zhiqiang Li Zhiwen Xu Hua Wang 《Fluid Dynamics & Materials Processing》 2025年第2期325-349,共25页
In modern engineering,enhancing boiling heat transfer efficiency is crucial for optimizing energy use and several industrial processes involving different types of materials.This study explores the enhancement of pool... In modern engineering,enhancing boiling heat transfer efficiency is crucial for optimizing energy use and several industrial processes involving different types of materials.This study explores the enhancement of pool boiling heat transfer potentially induced by combining perforated copper particles on a heated surface with a sodium dodecyl sulfate(SDS)surfactant in saturated deionized water.Experiments were conducted at standard atmospheric pressure,with heat flux ranging from 20 to 100 kW/m2.The heating surface,positioned below the layer of freely moving copper beads,allowed the particle layer to shift due to liquid convection and steam nucleation.The study reports on the influence of copper bead diameter(2,3,4,and 5 mm),particle quantity,arrangement,and SDS concentration(20,200,and 500 ppm).It is shown that the combination of 5 mm particles and a 500 ppm SDS concentration can yield a remarkable 139%improvement in heat transfer efficiency.As demonstrated by direct flow visualization,bubble formation occurs primarily in the gaps between the particles and the heated surface,with the presence of SDS reducing bubble size and accelerating bubble detachment. 展开更多
关键词 Pool boiling heat transfer enhancement perforated copper beads SURFACTANT bubble nucleation mechanism flow visualization
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Experimental Study on the Flow Boiling of R134a in Sintered Porous Microchannels
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作者 Shuo Wang Huiming Wang +2 位作者 Ying Zhang Zhiqiang Zhang Li Jia 《Frontiers in Heat and Mass Transfer》 2025年第6期1721-1740,共20页
This experimental investigation was conducted on the flow boiling performance of refrigerant R134a in two types of parallel microchannels:sintered porous microchannels(PP-MCs)and smooth parallel microchannels(SP-MCs).... This experimental investigation was conducted on the flow boiling performance of refrigerant R134a in two types of parallel microchannels:sintered porous microchannels(PP-MCs)and smooth parallel microchannels(SP-MCs).The tests were performed under controlled conditions including an inlet subcooling of 5±0.2℃,saturation temperature of 33℃,mass fluxes of 346 and 485 kg/m2·s,and a range of heat fluxes.Key findings reveal that the sintered porous microstructure significantly enhances bubble nucleation,reducing the wall superheat required for the onset of nucleate boiling(ONB)to only 0.13℃ compared to 2.2℃ in smooth channels.The porous structure also improves heat transfer coefficients at low and medium heat fluxes(<20–30 W/cm^(2))and low vapor quality(x<0.2–0.4)due to augmented thin-film evaporation and intensified nucleate boiling.However,smooth microchannels exhibit superior performance under high heat flux and high vapor quality conditions,as the porous structure is prone to early dry-out and flow blockage.Notably,the porous microchannels demonstrate lower flow resistance and enhanced stability,with pressure drop fluctuations reduced by up to 46.4%in amplitude and 44.8%in standard deviation,attributed to improved capillary-assisted liquid replenishment and suppressed flow oscillations.The results underscore the potential of PP-MCs as a high-performance cooling solution for high-heat-flux applications. 展开更多
关键词 Flow boiling porous microchannels heat transfer pressure drop flow instability R134A sintered surface
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Enhanced Flow Boiling Heat Transfer of HFE-7100 in Open Microchannels Using Micro-Nano Composite Structures
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作者 Liaofei Yin Kexin Zhang +3 位作者 Tianjun Qin Wenhao Ma YiDing Yawei Xu 《Frontiers in Heat and Mass Transfer》 2025年第3期751-764,共14页
Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.Ho... Flow boiling in open microchannels offers highly efficient heat transfer performance and has attracted increasing attention in the fields of heat transfer and thermalmanagement of electronic devices in recent years.However,the continuous rise in power density of electronic components imposesmore stringent requirements on the heat transfer capability of microchannel flow boiling.HFE-7100,a dielectric coolant with favorable thermophysical properties,has become a focal point of research for enhancing flow boiling performance in open microchannels.The flow boiling heat transfer performance ofHFE-7100 was investigated in this study by fabricating micro-nano composite structures on the bottom surface of open microchannels using laser ablation technology.Based on visualization results,a comparative analysis was conducted on the bubble dynamics and flow pattern characteristics of HFE-7100 flow boiling in micronano structured open microchannels(MNSOMC)and smooth-surface open microchannels(SSOMC),to elucidate the enhancement mechanism of micro-nano structures on flow boiling heat transfer in open microchannels.The results indicate that the surface structures and strong wettability of MNSOMC accelerated bubble nucleation and departure.Moreover,bubbles in the channel tended to coalesce along the flow direction,forming elongated slug bubbles with high aspect ratios,which enabled efficient thin film evaporation in conjunction with intense nucleate boiling,thereby significantly enhancing flow boiling heat transfer.Under the experimental conditions of this study,the maximum enhancements in the heat transfer coefficient(HTC)and critical heat flux(CHF)of HFE-7100 inMNSOMC were 33.4%and 133.1%,respectively,with the CHF reaching up to 1542.3 kW⋅m^(−2).Furthermore,due to the superior wettability and capillary wicking capability of the micro-nano composite structures,the significant enhancement in flow boiling heat transfer was achieved without incurring a noticeable pressure drop penalty. 展开更多
关键词 Open microchannel laser ablation micro-nano composite structures flow boiling heat transfer enhancement
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A new heat transfer correlation for flow boiling in helically coiled tubes 被引量:1
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作者 冀翠莲 韩吉田 +2 位作者 刘晓鹏 邵莉 陈常念 《Journal of Southeast University(English Edition)》 EI CAS 2015年第3期380-383,共4页
Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of th... Based on the superposition principle of the nucleate boiling and convective heat transfer terms,a new correlation is developed for flow boiling heat transfer characteristics in helically coiled tubes.The effects of the geometric and system parameters on heat transfer characteristics in helically coiled tubes are investigated by collecting large amounts of experimental data and analyzing the heat transfer mechanisms. The existing correlations are divided into two categories,and they are calculated with the experimental data.The Dn factor is introduced to take into account the effect of a complex geometrical structure on flow boiling heat transfer.A new correlation is developed for predicting the flow boiling heat transfer coefficients in the helically coiled tubes,which is validated by the experimental data of R134a flow boiling heat transfer in them;and the average relative error and root mean square error of the new correlation are calculated.The results show that the new correlation agrees well with the experimental data,indicating that the new correlation can be used for predicting flow boiling heat transfer characteristics in the helically coiled tubes. 展开更多
关键词 helically coiled tube flow boiling heat transfer coefficient correlation heat transfer
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Pool boiling performance of porous surface tubes under vacuum conditions 被引量:1
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作者 王学生 代晶晶 +1 位作者 从建立 陈琴珠 《Journal of Southeast University(English Edition)》 EI CAS 2010年第2期339-342,共4页
Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles... Two types of tube bundles are designed,which are,respectively,composed of six tubes arranged in the boiling chamber.The nucleate pool boiling performance of smooth tube bundles and sintered porous surface tube bundles with deionized water as a medium are experimentally studied at atmospheric and sub-atmospheric pressures,respectively.The experimental results indicate that the boiling heat transfer coefficients of the two types of tube bundles increase with the increase in pressure under vacuum conditions as they behave under ordinary pressure.As the pressure varies from 10 to 100 kPa,it also can be seen that the heat transfer coefficient of the sintered porous surface tube is increased by 0.2 to 4 times compared with the smooth one under the same operating parameters.In addition,the experimental data show that a definite bundle effect exists in both sintered porous surface tubes and smooth tubes under vacuum conditions. 展开更多
关键词 pool boiling porous surface tube heat transfer enhancement
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Preparation and characteristic analysis of rice husk high boiling solvent lignin 被引量:2
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作者 陈云平 程贤甦 《Journal of Forestry Research》 SCIE CAS CSCD 2008年第2期159-163,共5页
Rice husk high boiling solvent lignin (RHL) was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR s... Rice husk high boiling solvent lignin (RHL) was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data. 展开更多
关键词 high boiling solvent method rice husk lignin C9-formula
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Forced Convection Boiling Heat Transfer and Dryout Characteristics in Helical Coiled Tubes with Various Axial Angles 被引量:4
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作者 郭烈锦 张西民 +1 位作者 冯自平 陈学俊 《应用基础与工程科学学报》 EI CSCD 1998年第4期61-69,共9页
对水和水蒸汽汽液两相流体在螺旋轴呈各种倾角放置的螺旋管内强制对流沸腾传热与烧毁特性进行了系统地试验研究,试验中系统及结构参数范围如下:压力:P=0.4~3.0MPa质量流速:G=100~2400kg/m2·s进口... 对水和水蒸汽汽液两相流体在螺旋轴呈各种倾角放置的螺旋管内强制对流沸腾传热与烧毁特性进行了系统地试验研究,试验中系统及结构参数范围如下:压力:P=0.4~3.0MPa质量流速:G=100~2400kg/m2·s进口水温:T=30~80℃出口干度:x=-0.05~1.2管内壁面热负荷:q=0~540kE/m2试验段结构参数:总长L=6448mm,管内径d=11mm,螺旋直径D=256mm,螺旋升角β=4.27°螺旋管轴向放置倾角:水平位置(0°)、向上倾斜45°(+45°)、垂直向上(+90°)、向下倾斜45°(-45°).共进行了1050个工况的试验.试验结果表明,螺旋管内汽液两相流强制对流沸腾传热可以划分为核态沸腾区、两相流强制对流区、烧毁及烧毁后传热区等3种区域.通过数据处理和分析总结,给出了3区域间转变的边界方程,和3个区域内两相流传热系数的计算公式.根据试验观察和数据结果,对烧毁现象及烧毁点或区域发生的条件及机理进行了深入的分析研究,发现一系列有关现象的规律和特点,指出了其主要影响因素,并给出了烧毁点临界质量干度的预报公式. 展开更多
关键词 螺旋管 水/水蒸汽汽液两相流 强制对流沸腾传热 烧毁
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Changes of Petroleum Acid Distribution Characterized by FT-ICR MS in Heavy Acidic Crude Oil after True Boiling Point Distillation 被引量:8
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作者 Liu Yingrong Zhang Qundan +3 位作者 Wang Wei Liu Zelong Zhu Xinyi Tian Songbai 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第1期8-12,共5页
The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier tran... The molecular transformations of carboxylic acids in heavy acidic SL crude before and after true boiling point distillation were examined by ultra-high resolution negative-ion electrospray ionization(ESI) Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS). The acid class(heteroatom number), type(z numbers) and carbon number distributions were positively characterized. It was found out that the total acid number(TAN) of SL crude decreased after true boiling point distillation, and the abundance of O2 class in mass spectra was also found to be reduced from 67.6% to 34.5% in SL TBP mixed crude as measured by MS spectra, indicating to a potential carboxylic acid decomposition. However, it was interesting that the carboxylic acids type distribution in both oils was almost the same although their relative abundance in SL TBP mixed crude turned to be much lower, suggesting that various petroleum carboxylic acid types have the similar thermal decomposition reaction behavior. Furthermore, for each O2 type of acids in SL TBP mixed crude, the abundance of carboxylic acids with carbon number higher than 35 was reduced greatly, especially for those with carbon number higher than 60, the mass peaks of which were nearly totally removed, indicating that the large carboxylic acid molecules in heavy fractions decomposed more significantly because of longer heating time during the true boiling point distillation process. As a result, the reduction of TAN may be caused by the thermal decomposition of carboxylic acids especially those with high carbon number, suggesting that quick distillation or much lower pressure is required to avoid the thermal decomposition. 展开更多
关键词 true boiling point distillation carboxylic acid ESI FT-ICR MS acidic crude total acid number(TAN)
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Experimental investigation on boiling heat transfer characteristics of Al_2O_3-water nanofluids in swirl microchannels subjected to an acceleration force 被引量:2
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作者 Sujun DONG Hongsheng JIANG +3 位作者 Yongqi XIE Xiaoming WANG Zhongliang HU Jun WANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2019年第5期1136-1144,共9页
Experiments were carried out to investigate the boiling heat transfer characteristics of Al_2O_3-water nanofluids in swirl microchannels under terrestrial gravity and acceleration fields. A centrifuge with a two-meter... Experiments were carried out to investigate the boiling heat transfer characteristics of Al_2O_3-water nanofluids in swirl microchannels under terrestrial gravity and acceleration fields. A centrifuge with a two-meter long rotational arm was used to simulate the acceleration magnitude up to 9 g and three various acceleration directions. Three test sections with different geometric parameters were applied. The volume concentration of Al_2O_3 nanoparticles with an average diameter of 13 nm was varied from 0.07% to 0.1%. The mass flow rate and vapor quality were in ranges of 3–6 kg/h and 0.4–1.0%, respectively. The effects of the mass flow rate, microchannel aspect ratio,vapor quality, nanoparticle volume concentration, and acceleration direction and magnitude were analyzed in a systematic manner. Experimental results showed that the acceleration direction and magnitude had significant influences on the boiling heat transfer. The heat transfer under configuration C was found to be superior to that under configurations A and B. Moreover, the heat transfer coefficient increased with increases of the mass flow rate and the volume concentration and decreased with the aspect ratio. 展开更多
关键词 ACCELERATION boiling heat transfer MICROCHANNEL NANOFLUID SWIRL microchannels
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FLOW BOILING HEAT TRANSFER WITH FLUIDIZED SOLID PARTICLES 被引量:1
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作者 李修伦 闻建平 谷俊杰 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1995年第3期42-49,共8页
In order to solve the fouling problems in boiling processes,a boiling system was designedby adding solid particles to the boiling liquid In this paper.both theoretical analyses andexperimental studies on the boiling h... In order to solve the fouling problems in boiling processes,a boiling system was designedby adding solid particles to the boiling liquid In this paper.both theoretical analyses andexperimental studies on the boiling heat transfer in such a three-phase flow boiling were carried out.Based on the analysis of heat transfer characters of this three-phase flow boiling,a mathematical mod-el for the heat transfer coefficient of flow boiling was developed.The experiments show that,in thepresence of particles the boiling heat transfer is enhanced and is about 2 times that of the vaporliquid two phase one with better flow stability.The fluidized particles rub the heat transfer wall toprevent and to clean the fouling. 展开更多
关键词 FLOW boiling fluidized SOLID PARTICLES FOULING
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Position Group Contribution Method for Predicting the Normal Boiling Point of Organic Compounds 被引量:7
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作者 王强 马沛生 +1 位作者 王昶 夏淑倩 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第2期254-258,共5页
A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distr... A new position group contribution model is proposed for the estimation of normal boiling data of organic compounds involving a carbon chain from C2 to C18.The characteristic of this method is the use of position distribution function.It could distinguish most of isomers that include cis-or trans-structure from organic compounds.Contributions for hydrocarbons and hydrocarbon derivatives containing oxygen,nitrogen,chlorine,bromine and sulfur,are given.Compared with the predictions,results made use of the most common existing group contribution methods,the overall average absolute difference of boiling point predictions of 417 organic compounds is 4.2 K;and the average absolute percent derivation is 1.0%,which is compared with 12.3 K and 3.2% with the method of Joback,12.1 K and 3.1% with the method of Constantinou-Gani.This new position contribution groups method is not only much more accurate but also has the advantages of simplicity and stability. 展开更多
关键词 normal boiling point PREDICTION position group contribution
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A New Experimental Rig of Testing Flow Boiling Heat Transfer of Refrigerantand Lubricant Mixture 被引量:5
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作者 魏文建 丁国良 王凯建 《Journal of Shanghai Jiaotong university(Science)》 EI 2004年第4期62-67,共6页
This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accur... This paper proposed a new experimental rig of testing flow boiling heat transfer of refrigerant and lubricant oil mixture. The quantity of oil in the test section can be controlled and regulated conveniently and accurately by connecting separate lubricant oil circuit with test section in parallel. It was built up by retrofitting a multiple air-conditioner and installing three oil-separators in serials at the compressor outlet. And so the lubricant oil in the discharged refrigerant gas of compressor can be removed completely.The refrigerant flow rate through test section can be bypassed by the by-path circuit of indoor unit.This experimental rig has advantages such as on-line and continuous oil injection, short time of obtaining stability, flexible operation, simple control, which lead to high efficiency in the research of flow boiling heat transfer of refrigerant and lubricant oil mixture. 展开更多
关键词 REFRIGERANT flow boiling heat transfer lubricant oil
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Effects of boiling duration in processing of White Paeony Root on its overall quality evaluated by ultra-high performance liquid chromatography quadrupole/time-of-flight mass spectrometry based metabolomics analysis and high performance liquid chromatograp 被引量:6
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作者 KONG Ming XU Jun +6 位作者 LIU Huan-Huan XU Jin-Di LI Xiu-Yang LU Min WANG Chun-Ru CHEN Hu-Biao LI Song-Lin 《Chinese Journal of Natural Medicines》 SCIE CAS CSCD 2017年第1期62-70,共9页
Boiling processing is commonly used in post-harvest handling of White Paeony Root (WPR), in order to whiten the herbal materials and preserve the bright color, since such WPR is empirically considered to possess a h... Boiling processing is commonly used in post-harvest handling of White Paeony Root (WPR), in order to whiten the herbal materials and preserve the bright color, since such WPR is empirically considered to possess a higher quality. The present study was designed to investigate whether and how the boiling processing affects overall quality of WPR. First, an ultra-high performance liquid chromatography quadrupole/time-of-flight mass spectrometry-based metabolomics approach coupled with multivariate statistical analysis was developed to compare the holistic quality of boiled and un-boiled WPR samples. Second, ten major components in WPR samples boiled for different durations were quantitatively determined using high performance liquid chromatography to further explore the effects of boiling time on the holistic quality of WPR, meanwhile the appearance of the processed herbal materials was observed. The results suggested that the boiling processing conspicuously affected the holistic quality of WPR by simultaneously and inconsistently altering the chemical compositions and that short-time boiling processing between 2 and 10 rain could both make the WPR bright-colored and improve tile contents of major bioactive components, which were not achieved either without boiling or with prolonged boiling. In conclusion, short-term boiling (2-10 min) is recommended for post-harvest handling of WPR. 展开更多
关键词 White Paeony Root boiling processing Overall quality Major bioactive components Metabolomics
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Mechanism of Calcium Carbonate Scale Deposition under Subcooled Flow Boiling Conditions 被引量:4
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作者 XING Xiaokai(邢晓凯) +3 位作者 MA Chongfang(马重芳) CHEN Yongchang(陈永昌) 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第4期464-470,共7页
Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of ca... Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate (CaCO3), which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal (calcite and aragonite) are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated. 展开更多
关键词 heat transfer FOULING calcium carbonate subcooled flow boiling
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Enhancement of Flow Boiling Heat Transfer with Surfactant 被引量:3
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作者 QIU Yun-ren CHEN Wei-ping SI Qin 《Journal of Central South University》 SCIE EI CAS 2000年第4期219-222,共4页
The surfactant additive octadecylamine (ODA) was used to enhance the flow boiling heat transfer of water in vertical copper tube, and the effects of the aqueous solution properties, mass fraction of ODA, mass flux and... The surfactant additive octadecylamine (ODA) was used to enhance the flow boiling heat transfer of water in vertical copper tube, and the effects of the aqueous solution properties, mass fraction of ODA, mass flux and heat flux etc. on flow boiling heat transfer were investigated. In order to analyze the mechanism of enhancement on boiling heat transfer with ODA, the copper surface was detected by XPS, and the diagram of binding energy was obtained. The results show that ODA can be adsorbed on the surface of the copper wall, and affects the properties of the heating surfaces and enhances the flow boiling heat transfer of water. Only in low heat flux and in a suitable range of concentration, can ODA aqueous solution enhance flow boiling heat transfer, and the suitable mass fraction of ODA is in the range of 1×10 -5 5×10 -5 . In addition, compared with water, ODA aqueous solution does not increase the flow drag under the same experimental conditions. 展开更多
关键词 flow boiling heat transfer flow drag ENHANCEMENT ADDITIVE
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Heat Transfer in Nucleate Pool Boiling of Binary and Ternary Refrigerant Mixtures 被引量:2
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作者 赵耀华 刁彦华 +1 位作者 鹤田隆治 西川日出男 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第3期351-356,共6页
Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa.... Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa. Compared to pure components, both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased. Experimental data were compared with some empirical and semi-empirical correlations available in literature. For binary mixture, the accuracy of the correlations varied considerably with mixtures and the heat flux. Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome. For ternary mixture, the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points, and their concentration difference had important effects on boiling heat transfer coefficients. 展开更多
关键词 pool boiling heat transfer nucleate pool boiling HFC-134A HFC-32 HFC-125
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