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Recent Advancements and Perspectives of Low-Dimensional Halide Perovskites for Visual Perception and Optoelectronic Applications
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作者 Humaira Rafique Ghulam Abbas +5 位作者 Manuel J.Mendes Pedro Barquinha Rodrigo Martins Elvira Fortunato Hugo Aguas Santanu Jana 《Nano-Micro Letters》 2026年第2期199-259,共61页
Low-dimensional(LD)halide perovskites have attracted considerable attention due to their distinctive structures and exceptional optoelectronic properties,including high absorption coefficients,extended charge carrier ... Low-dimensional(LD)halide perovskites have attracted considerable attention due to their distinctive structures and exceptional optoelectronic properties,including high absorption coefficients,extended charge carrier diffusion lengths,suppressed non-radiative recombination rates,and intense photoluminescence.A key advantage of LD perovskites is the tunability of their optical and electronic properties through the precise optimization of their structural arrangements and dimensionality.This review systematically examines recent progress in the synthesis and optoelectronic characterizations of LD perovskites,focusing on their structural,optical,and photophysical properties that underpin their versatility in diverse applications.The review further summarizes advancements in LD perovskite-based devices,including resistive memory,artificial synapses,photodetectors,light-emitting diodes,and solar cells.Finally,the challenges associated with stability,scalability,and integration,as well as future prospects,are discussed,emphasizing the potential of LD perovskites to drive breakthroughs in device efficiency and industrial applicability. 展开更多
关键词 low-dimensional perovskites Light-emitting diodes PHOTODETECTORS PHOTOTRANSISTORS Photovoltaics
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Exploring the potential of low-dimensional materials from cigarette butts for energy applications: A comprehensive review
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作者 Ye Chen Shilong Li +9 位作者 Congxin Xia Miao Tian Yaxin Guo Xupo Liu Mingjin Cui Shixue Dou Hanleem Lee Vadivel Subramaniam Krishnamoorthy Ramachandran Xinghui Liu 《Advanced Powder Materials》 2025年第3期90-109,共20页
Carbon-based low-dimensional materials(CLDM)with elemental carbon as the main component have unique physical and chemical properties,and become the focus of research in many fields including energy,environmental prote... Carbon-based low-dimensional materials(CLDM)with elemental carbon as the main component have unique physical and chemical properties,and become the focus of research in many fields including energy,environmental protection,and information technology.Notably,cellulose acetate,the main component of cigarette butts(CBs),is a one-dimensional precursor with a large specific surface area and aspect ratio.Still,their usefulness as building fillers has often been underestimated before.This review summarizes recent advances in CBs recycling and provides suggested guidelines for its use as a CLDM material in renewable energy.Specifically,we first describe the harmful effects of CBs as pollutants in our lives to emphasize the importance of proper recycling.We then summarize previous methods of recycling CBs waste,including clay bricks,asphalt concrete pavement,gypsum,acoustic materials,chemisorption,vector control,and corrosion control.The potential applications of CBs include triboelectric nanogenerator applications,flexible batteries,enhanced metal-organic framework material energy storage devices,and carbon-based hydrogen storage.Finally,the advantages of utilizing CBs-derived CLDM materials over conventional solutions in the energy field are discussed.This review will provide new avenues for solving the intractable problem of CBs and reducing the manufacturing costs of renewable materials. 展开更多
关键词 low-dimensional materials Cigarette butts Cellulose acetate Energy storage GRAPHENE
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Linearly polarized photodetectors based on low-dimensional perovskites:theory,material,and device
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作者 Yuan-Yuan Zheng He-Bin Wang +3 位作者 Shu Wang Peng-Yi Yue Guan-Kui Long Cong Wang 《Rare Metals》 2025年第10期6839-6864,共26页
Linearly polarized photodetectors(PDs),leveraging the inherent structural and material information encoded in light's polarization state,hold transformative potential for applications ranging from remote sensing t... Linearly polarized photodetectors(PDs),leveraging the inherent structural and material information encoded in light's polarization state,hold transformative potential for applications ranging from remote sensing to biomedical imaging.Traditional systems that rely on external polarizing elements face challenges in miniaturization and efficiency,driving interest in materials with intrinsic anisotropy.Low-dimensional metal halide perovskites,distinguished by their tunable bandgaps,high carrier mobility,and quantum confinement effects,have emerged as a groundbreaking platform for next-generation polarized PDs.This review comprehensively summarizes the theory,materials,and device engineering of linearly polarized PDs based on low-dimensional perovskites.It aims to elucidate polarization mechanisms across dimensions by establishing a rigorous theoretical foundation for linearly polarized PDs of low-dimensional perovskites.Beyond theoretical insights,the review also highlights cutting-edge fabrication techniques for one-dimensional nano wires and two-dimensional heterostructures,along with performance benchmarks of state-of-the-art devices.By integrating experimental advancements with theoretical insights,this work not only advances the fundamental understanding of polarization mechanisms but also outlines actionable pathways for optimizing device performance,stability,and scalability,which may serve as a critical resource for researchers aiming to harness the full potential of low-dimensional perovskites in polarized optoelectronics. 展开更多
关键词 Perovskite materials low-dimensional structure ANISOTROPY Linearly polarized photodetector
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Low-dimensional antimicrobial nanomaterials in anti-infection treatment and wound healing
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作者 Yunfen Gao Liying Wang +3 位作者 Chufan Zhou Yi Zhao Hai Huang Jun Wu 《Chinese Chemical Letters》 2025年第3期95-103,共9页
Bacterial infections have always been a major threat to human health.Skin wounds are frequently exposed to the external environment,and they may become contaminated by bacteria derived from the surrounding skin,the lo... Bacterial infections have always been a major threat to human health.Skin wounds are frequently exposed to the external environment,and they may become contaminated by bacteria derived from the surrounding skin,the local environment,and the patient’s own endogenous sources.Contaminated wounds may enter a state of chronic inflammation that impedes healing.Urgent development of antibacterial wound dressings capable of effectively combating bacteria and overcoming resistance is necessary.Nanotechnology and nanomaterials present promising potential as innovative strategies for antimicrobial wound dressings,owing to their robust antibacterial characteristics and the inherent advantage of avoiding antibiotic resistance.Therefore,this review provides a concise overview of the antimicrobial mechanisms exhibited by low-dimensional nanomaterials.It further categorizes common low-dimensional antimicrobial nanomaterials into zero-dimensional(0D),one-dimensional(1D)and two-dimensional(2D)nanomaterials based on their structural characteristics,and gives a detailed compendium of the latest research advances and applications of different low-dimensional antimicrobial nanomaterials in wound healing,which could be helpful for the development of more effective wound dressings. 展开更多
关键词 Nano-antimicrobial materials Antimicrobial mechanisms low-dimensional Anti-infection treatment Wound healing
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Support Vector-Guided Class-Incremental Learning:Discriminative Replay with Dual-Alignment Distillation
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作者 Moyi Zhang Yixin Wang Yu Cheng 《Computers, Materials & Continua》 2026年第3期2040-2061,共22页
Modern intelligent systems,such as autonomous vehicles and face recognition,must continuously adapt to new scenarios while preserving their ability to handle previously encountered situations.However,when neural netwo... Modern intelligent systems,such as autonomous vehicles and face recognition,must continuously adapt to new scenarios while preserving their ability to handle previously encountered situations.However,when neural networks learn new classes sequentially,they suffer from catastrophic forgetting—the tendency to lose knowledge of earlier classes.This challenge,which lies at the core of class-incremental learning,severely limits the deployment of continual learning systems in real-world applications with streaming data.Existing approaches,including rehearsalbased methods and knowledge distillation techniques,have attempted to address this issue but often struggle to effectively preserve decision boundaries and discriminative features under limited memory constraints.To overcome these limitations,we propose a support vector-guided framework for class-incremental learning.The framework integrates an enhanced feature extractor with a Support Vector Machine classifier,which generates boundary-critical support vectors to guide both replay and distillation.Building on this architecture,we design a joint feature retention strategy that combines boundary proximity with feature diversity,and a Support Vector Distillation Loss that enforces dual alignment in decision and semantic spaces.In addition,triple attention modules are incorporated into the feature extractor to enhance representation power.Extensive experiments on CIFAR-100 and Tiny-ImageNet demonstrate effective improvements.On CIFAR-100 and Tiny-ImageNet with 5 tasks,our method achieves 71.68%and 58.61%average accuracy,outperforming strong baselines by 3.34%and 2.05%.These advantages are consistently observed across different task splits,highlighting the robustness and generalization of the proposed approach.Beyond benchmark evaluations,the framework also shows potential in few-shot and resource-constrained applications such as edge computing and mobile robotics. 展开更多
关键词 Class-incremental learning catastrophic forgetting support vector machine knowledge distillation
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Adeno-associated viral vectors for modeling Parkinson's disease in non-human primates
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作者 Julia Chocarro José L.Lanciego 《Neural Regeneration Research》 2026年第1期224-232,共9页
The development of clinical candidates that modify the natural progression of sporadic Parkinson's disease and related synucleinopathies is a praiseworthy endeavor,but extremely challenging.Therapeutic candidates ... The development of clinical candidates that modify the natural progression of sporadic Parkinson's disease and related synucleinopathies is a praiseworthy endeavor,but extremely challenging.Therapeutic candidates that were successful in preclinical Parkinson's disease animal models have repeatedly failed when tested in clinical trials.While these failures have many possible explanations,it is perhaps time to recognize that the problem lies with the animal models rather than the putative candidate.In other words,the lack of adequate animal models of Parkinson's disease currently represents the main barrier to preclinical identification of potential disease-modifying therapies likely to succeed in clinical trials.However,this barrier may be overcome by the recent introduction of novel generations of viral vectors coding for different forms of alpha-synuclein species and related genes.Although still facing several limitations,these models have managed to mimic the known neuropathological hallmarks of Parkinson's disease with unprecedented accuracy,delineating a more optimistic scenario for the near future. 展开更多
关键词 adeno-associated viral vectors ALPHA-SYNUCLEIN DOPAMINE Lewy bodies NEURODEGENERATION NEUROMELANIN NEUROPATHOLOGY substantia nigra
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Yaw stabilization and maneuvering control of tailless flying wing by co-directional fluidic thrust vectoring
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作者 Liu ZHANG Meng HE 《Chinese Journal of Aeronautics》 2026年第1期66-77,共12页
Fluidic Thrust Vectoring(FTV)is used for the yaw attitude control of tailless flying wing,which can significantly improve stealth performance,maneuverability and lateral/heading maneuverability.The FTV control scheme ... Fluidic Thrust Vectoring(FTV)is used for the yaw attitude control of tailless flying wing,which can significantly improve stealth performance,maneuverability and lateral/heading maneuverability.The FTV control scheme of co-directional secondary flow was designed based on a 30 kgf thrust turbojet engine,an equivalent rudder deflection control variable of Mass Flow Combination(MFC)was proposed,and a control model was established to form a FTV control system scheme,which was integrated with the flight control system of a 100 kg tailless flying wing with medium aspect ratio to achieve closed-loop control of the yaw attitude based on FTV.The heading stability augmentation and maneuvering control characteristics and time response characteristics of tailless flying wing by FTV were quantitatively studied through virtual flight test in a wind tunnel at a wind speed of 35 m/s.The results show that the control strategy based on MFC achieves bidirectional continuous and stable control of thrust vector angle in a range of±11°,and the thrust vector angle varies monotonically with MFC;the co-directional FTV realizes bidirectional continuous and stable control of the yaw attitude of tailless flying wing,without longitudinal/lateral coupling moment.The increment of the maximum yawing moment coefficient is 0.0029,the maximum yaw rate is 7.55(°)/s,and the response time of the yaw rate of the vectoring nozzle actuated by the secondary flow is about 0.06 s,which satisfies the heading stability augmentation and maneuvering control response requirements of the aircraft with statically unstable heading,and provides new control means for the heading rudderless attitude control of tailless flying wing. 展开更多
关键词 Thrust vectoring Flow control Coanda effect Flying-wing aircraft Flight tests Yaw control
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Using mixed kernel support vector machine to improve the predictive accuracy of genome selection
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作者 Jinbu Wang Wencheng Zong +6 位作者 Liangyu Shi Mianyan Li Jia Li Deming Ren Fuping Zhao Lixian Wang Ligang Wang 《Journal of Integrative Agriculture》 2026年第2期775-787,共13页
The advantages of genome selection(GS) in animal and plant breeding are self-evident.Traditional parametric models have disadvantage in better fit the increasingly large sequencing data and capture complex effects acc... The advantages of genome selection(GS) in animal and plant breeding are self-evident.Traditional parametric models have disadvantage in better fit the increasingly large sequencing data and capture complex effects accurately.Machine learning models have demonstrated remarkable potential in addressing these challenges.In this study,we introduced the concept of mixed kernel functions to explore the performance of support vector machine regression(SVR) in GS.Six single kernel functions(SVR_L,SVR_C,SVR_G,SVR_P,SVR_S,SVR_L) and four mixed kernel functions(SVR_GS,SVR_GP,SVR_LS,SVR_LP) were used to predict genome breeding values.The prediction accuracy,mean squared error(MSE) and mean absolute error(MAE) were used as evaluation indicators to compare with two traditional parametric models(GBLUP,BayesB) and two popular machine learning models(RF,KcRR).The results indicate that in most cases,the performance of the mixed kernel function model significantly outperforms that of GBLUP,BayesB and single kernel function.For instance,for T1 in the pig dataset,the predictive accuracy of SVR_GS is improved by 10% compared to GBLUP,and by approximately 4.4 and 18.6% compared to SVR_G and SVR_S respectively.For E1 in the wheat dataset,SVR_GS achieves 13.3% higher prediction accuracy than GBLUP.Among single kernel functions,the Laplacian and Gaussian kernel functions yield similar results,with the Gaussian kernel function performing better.The mixed kernel function notably reduces the MSE and MAE when compared to all single kernel functions.Furthermore,regarding runtime,SVR_GS and SVR_GP mixed kernel functions run approximately three times faster than GBLUP in the pig dataset,with only a slight increase in runtime compared to the single kernel function model.In summary,the mixed kernel function model of SVR demonstrates speed and accuracy competitiveness,and the model such as SVR_GS has important application potential for GS. 展开更多
关键词 genome selection machine learning support vector machine kernel function mixed kernel function
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A viral masterstroke:Geminivirus C4 protein reprograms auxin transport to attract its insect vector
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作者 Mingjun Li Lyuxin Wang +1 位作者 Gentu Wu Ling Qing 《Molecular Plant》 2026年第2期239-241,共3页
Disruption of host physiological processes,leading to symptom expression,is a common hallmark during plant virus infections.The concept of“symptoms as strategy”is rapidly reshaping our understanding of plant virolog... Disruption of host physiological processes,leading to symptom expression,is a common hallmark during plant virus infections.The concept of“symptoms as strategy”is rapidly reshaping our understanding of plant virology.An emerging theme is that symptom expressions—such as stunting,curling,and yellowing,which devastate yield—may themselves be evolved viral adaptation strategies rather than collateral damage. 展开更多
关键词 symptom expressions such viral masterstroke insect vector disruption host physiological processesleading geminivirus C protein host physiological processes auxin transport symptom expressionis
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A Convolutional Neural Network-Based Deep Support Vector Machine for Parkinson’s Disease Detection with Small-Scale and Imbalanced Datasets
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作者 Kwok Tai Chui Varsha Arya +2 位作者 Brij B.Gupta Miguel Torres-Ruiz Razaz Waheeb Attar 《Computers, Materials & Continua》 2026年第1期1410-1432,共23页
Parkinson’s disease(PD)is a debilitating neurological disorder affecting over 10 million people worldwide.PD classification models using voice signals as input are common in the literature.It is believed that using d... Parkinson’s disease(PD)is a debilitating neurological disorder affecting over 10 million people worldwide.PD classification models using voice signals as input are common in the literature.It is believed that using deep learning algorithms further enhances performance;nevertheless,it is challenging due to the nature of small-scale and imbalanced PD datasets.This paper proposed a convolutional neural network-based deep support vector machine(CNN-DSVM)to automate the feature extraction process using CNN and extend the conventional SVM to a DSVM for better classification performance in small-scale PD datasets.A customized kernel function reduces the impact of biased classification towards the majority class(healthy candidates in our consideration).An improved generative adversarial network(IGAN)was designed to generate additional training data to enhance the model’s performance.For performance evaluation,the proposed algorithm achieves a sensitivity of 97.6%and a specificity of 97.3%.The performance comparison is evaluated from five perspectives,including comparisons with different data generation algorithms,feature extraction techniques,kernel functions,and existing works.Results reveal the effectiveness of the IGAN algorithm,which improves the sensitivity and specificity by 4.05%–4.72%and 4.96%–5.86%,respectively;and the effectiveness of the CNN-DSVM algorithm,which improves the sensitivity by 1.24%–57.4%and specificity by 1.04%–163%and reduces biased detection towards the majority class.The ablation experiments confirm the effectiveness of individual components.Two future research directions have also been suggested. 展开更多
关键词 Convolutional neural network data generation deep support vector machine feature extraction generative artificial intelligence imbalanced dataset medical diagnosis Parkinson’s disease small-scale dataset
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Low-dimensional multi-spectral space for color reproduction based on nonnegative constrained principal component analysis 被引量:1
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作者 王莹 曾平 +1 位作者 罗雪梅 谢琨 《Journal of Southeast University(English Edition)》 EI CAS 2009年第4期486-490,共5页
In order to overcome the shortcomings that the reconstructed spectral reflectance may be negative when using the classic principal component analysis (PCA)to reduce the dimensions of the multi-spectral data, a nonne... In order to overcome the shortcomings that the reconstructed spectral reflectance may be negative when using the classic principal component analysis (PCA)to reduce the dimensions of the multi-spectral data, a nonnegative constrained principal component analysis method is proposed to construct a low-dimensional multi-spectral space and accomplish the conversion between the new constructed space and the multispectral space. First, the reason behind the negative data is analyzed and a nonnegative constraint is imposed on the classic PCA. Then a set of nonnegative linear independence weight vectors of principal components is obtained, by which a lowdimensional space is constructed. Finally, a nonlinear optimization technique is used to determine the projection vectors of the high-dimensional multi-spectral data in the constructed space. Experimental results show that the proposed method can keep the reconstructed spectral data in [ 0, 1 ]. The precision of the space created by the proposed method is equivalent to or even higher than that by the PCA. 展开更多
关键词 spectral color science nonnegative constrained principal component analysis low-dimensional spectral space nonlinear optimization multi-spectral images spectral reflectance
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Low-dimensional structures formed by irradiation of laser 被引量:5
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作者 黄伟其 刘世荣 +3 位作者 许丽 吴克跃 秦朝建 蔡绍洪 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第3期725-729,共5页
Some kinds of low-dimensional nanostructures can be formed by irradiation of laser on the pure silicon sample and the SiGe alloy sample. This paper has studied the photoluminescence (PL) of the hole-net structure of... Some kinds of low-dimensional nanostructures can be formed by irradiation of laser on the pure silicon sample and the SiGe alloy sample. This paper has studied the photoluminescence (PL) of the hole-net structure of silicon and the porous structure of SiGe where the PL intensity at 706nm and 725nm wavelength increases obviously. The effect of intensity-enhancing in the PL peaks cannot be explained within the quantum confinement alone. A mechanism for increasing PL emission in the above structures is proposed, in which the trap states of the interface between SiO2 and nanocrystal play an important role. 展开更多
关键词 low-dimensional nanostructures PHOTOLUMINESCENCE PL intensity interface state
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Low-Dimensional Halide Perovskites and Their Advanced Optoelectronic Applications 被引量:11
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作者 Jian Zhang Xiaokun Yang +7 位作者 Hui Deng Keke Qiao Umar Farooq Muhammad Ishaq Fei Yi Huan Liu Jiang Tang Haisheng Song 《Nano-Micro Letters》 SCIE EI CAS 2017年第3期118-143,共26页
Metal halide perovskites are crystalline materials originally developed out of scientific curiosity. They have shown great potential as active materials in optoelectronic applications. In the last 6 years, their certi... Metal halide perovskites are crystalline materials originally developed out of scientific curiosity. They have shown great potential as active materials in optoelectronic applications. In the last 6 years, their certified photovoltaic efficiencies have reached 22.1%. Compared to bulk halide perovskites, low-dimensional ones exhibited novel physical properties. The photoluminescence quantum yields of perovskite quantum dots are close to 100%. The external quantum efficiencies and current efficiencies of perovskite quantum dot light-emitting diodes have reached 8% and 43 cd A^(-1),respectively, and their nanowire lasers show ultralow-threshold room-temperature lasing with emission tunability and ease of synthesis. Perovskite nanowire photodetectors reached a responsivity of 10 A W^(-1)and a specific normalized detectivity of the order of 10^(12 )Jones. Different from most reported reviews focusing on photovoltaic applications, we summarize the rapid progress in the study of low-dimensional perovskite materials, as well as their promising applications in optoelectronic devices. In particular, we review the wide tunability of fabrication methods and the state-of-the-art research outputs of low-dimensional perovskite optoelectronic devices. Finally, the anticipated challenges and potential for this exciting research are proposed. 展开更多
关键词 Metal halide perovskites low-dimensional effect SYNTHESIS Optoelectronic devices VERSATILITY
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Negative photoconductivity in low-dimensional materials 被引量:4
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作者 Boyao Cui Yanhui Xing +7 位作者 Jun Han Weiming Lv Wenxing Lv Ting Lei Yao Zhang Haixin Ma Zhongming Zeng Baoshun Zhang 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第2期121-130,共10页
In recent years,low-dimensional materials have received extensive attention in the field of electronics and optoelectronics.Among them,photoelectric devices based on photoconductive effect in low-dimensional materials... In recent years,low-dimensional materials have received extensive attention in the field of electronics and optoelectronics.Among them,photoelectric devices based on photoconductive effect in low-dimensional materials have a broad development space.In contrast to positive photoconductivity,negative photoconductivity(NPC)refers to a phenomenon that the conductivity decreases under illumination.It has novel application prospects in the field of optoelectronics,memory,and gas detection,etc.In this paper,we review reports about the NPC effect in low-dimensional materials and systematically summarize the mechanisms to form the NPC effect in existing low-dimensional materials. 展开更多
关键词 negative photoconductivity low-dimensional materials optoelectronic devices
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Low-dimensional materials for photovoltaic application 被引量:2
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作者 Rokas Kondrotas Chao Chen +2 位作者 XinXing Liu Bo Yang Jiang Tang 《Journal of Semiconductors》 EI CAS CSCD 2021年第3期37-44,共8页
The photovoltaic(PV)market is currently dominated by silicon based solar cells.However technological diversification is essential to promote competition,which is the driving force for technological growth.Historically... The photovoltaic(PV)market is currently dominated by silicon based solar cells.However technological diversification is essential to promote competition,which is the driving force for technological growth.Historically,the choice of PV materials has been limited to the three-dimensional(3D)compounds with a high crystal symmetry and direct band gap.However,to meet the strict demands for sustainable PV applications,material space has been expanded beyond 3D compounds.In this perspective we discuss the potential of low-dimensional materials(2D,1D)for application in PVs.We present unique features of low-dimensional materials in context of their suitability in the solar cells.The band gap,absorption,carrier dynamics,mobility,defects,surface states and growth kinetics are discussed and compared to 3D counterparts,providing a comprehensive view of prospects of low-dimensional materials.Structural dimensionality leads to a highly anisotropic carrier transport,complex defect chemistry and peculiar growth dynamics.By providing fundamental insights into these challenges we aim to deepen the understanding of low-dimensional materials and expand the scope of their application.Finally,we discuss the current research status and development trend of solar cell devices made of low-dimensional materials. 展开更多
关键词 low-dimensional materials PHOTOVOLTAIC ABSORPTION DEFECT ANISOTROPY
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Co-or Ni-modified Sn-MnO_(x) low-dimensional multi-oxides for high-efficient NH_(3)-SCR De-NO_(x):Performance optimization and reaction mechanism 被引量:7
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作者 Fengyu Gao Chen Yang +2 位作者 Xiaolong Tang Honghong Yi Chengzhi Wang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2022年第3期204-218,共15页
NH_(3)-SCR performances were explored to the relationship between structure morphology and physio-chemical properties over low-dimensional ternary Mn-based catalysts prepared by one-step synthesis method.Due to its st... NH_(3)-SCR performances were explored to the relationship between structure morphology and physio-chemical properties over low-dimensional ternary Mn-based catalysts prepared by one-step synthesis method.Due to its strong oxidation performance,Sn-MnO_(x) was prone to side reactions between NO,NH_(3)and O_(2),resulting in the generation of more NO_(2)and N_(2)O,here most of N_(2)O was driven from the non-selective oxidation of NH_(3),while a small part generated from the side reaction between NH_(3)and NO_(2).Co or Ni doping into Sn-MnO_(x) as solid solution components obviously stronged the electronic interaction for actively mobilization and weakened the oxidation performance for signally reducing the selective tendency of side reactions to N_(2)O.The optimal modification resulted in improving the surface area and enhancing the strong interaction between polyvalent cations in Co/Ni-Mn-SnO_(2)to provide more surface adsorbed oxygen,active sites of Mn^(3+) and Mn^(4+),high-content Sn^(4+) and plentiful Lewis-acidity for more active intermediates,which significantly broadened the activity window of Sn-MnOx,improved the N^(2) selectivity by inhibiting N_(2)O formation,and also contributed to an acceptable resistances to water and sulfur.At low reaction temperatures,the SCR reactions over three catalysts mainly obeyed the typical Elye-rideal(E-R)routs via the reactions of adsorbed L-NH_(x)(x=3,2,1)and B-NH_(4)^(+) with the gaseous NO to generate N_(2) but also N_(2)O by-products.Except for the above basic E-R reactions,as increasing the reaction temperature,the main adsorbed NO_(x)-species were bidentate nitrates that were also active in the Langmuir-Hinshelwood reactions with adsorbed L-NH_(x) species over Co/Ni modified Mn-SnO_(2) catalyst. 展开更多
关键词 low-dimensional catalysts One-step synthesis Mn-SnO_(2)nanosheet Ni or Co modification SCR performances Promotional mechanism
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Machine Learning-Assisted Low-Dimensional Electrocatalysts Design for Hydrogen Evolution Reaction 被引量:2
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作者 Jin Li Naiteng Wu +7 位作者 Jian Zhang Hong‑Hui Wu Kunming Pan Yingxue Wang Guilong Liu Xianming Liu Zhenpeng Yao Qiaobao Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第12期161-187,共27页
Efficient electrocatalysts are crucial for hydrogen generation from electrolyzing water.Nevertheless,the conventional"trial and error"method for producing advanced electrocatalysts is not only cost-ineffecti... Efficient electrocatalysts are crucial for hydrogen generation from electrolyzing water.Nevertheless,the conventional"trial and error"method for producing advanced electrocatalysts is not only cost-ineffective but also time-consuming and labor-intensive.Fortunately,the advancement of machine learning brings new opportunities for electrocatalysts discovery and design.By analyzing experimental and theoretical data,machine learning can effectively predict their hydrogen evolution reaction(HER)performance.This review summarizes recent developments in machine learning for low-dimensional electrocatalysts,including zero-dimension nanoparticles and nanoclusters,one-dimensional nanotubes and nanowires,two-dimensional nanosheets,as well as other electrocatalysts.In particular,the effects of descriptors and algorithms on screening low-dimensional electrocatalysts and investigating their HER performance are highlighted.Finally,the future directions and perspectives for machine learning in electrocatalysis are discussed,emphasizing the potential for machine learning to accelerate electrocatalyst discovery,optimize their performance,and provide new insights into electrocatalytic mechanisms.Overall,this work offers an in-depth understanding of the current state of machine learning in electrocatalysis and its potential for future research. 展开更多
关键词 Machine learning Hydrogen evolution reaction low-dimensional electrocatalyst DESCRIPTOR Algorithm
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Origin of Luminescent Centers and Edge States in Low-Dimensional Lead Halide Perovskites:Controversies,Challenges and Instructive Approaches 被引量:3
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作者 Jiming Bao Viktor G.Hadjiev 《Nano-Micro Letters》 SCIE EI CAS CSCD 2019年第2期109-126,共18页
With only a few deep-level defect states having a high formation energy and dominance of shallow carrier non-trapping defects,the defect-tolerant electronic and optical properties of lead halide perovskites have made ... With only a few deep-level defect states having a high formation energy and dominance of shallow carrier non-trapping defects,the defect-tolerant electronic and optical properties of lead halide perovskites have made them appealing materials for high-efficiency,low-cost,solar cells and light-emitting devices.As such,recent observations of apparently deep-level and highly luminescent states in low-dimensional perovskites have attracted enormous attention as well as intensive debates.The observed green emission in 2D CsPb2Br5 and 0 D Cs4PbBr6 poses an enigma over whether it is originated from intrinsic point defects or simply from highly luminescent CsPbBr3 nanocrystals embedded in the otherwise transparent wide band gap semiconductors.The nature of deep-level edge emission in 2D Ruddlesden–Popper perovskites is also not well understood.In this mini review,the experimental evidences that support the opposing interpretations are analyzed,and challenges and root causes forthe controversy are discussed.Shortcomings in the current density functional theory approaches to modeling of properties and intrinsic point defects in lead halide perovskites are also noted.Selected experimental approaches are suggested to better correlate property with structure of a material and help resolve the controversies.Understanding and identification of the origin of luminescent centers will help design and engineer perovskites for wide device applications. 展开更多
关键词 low-dimensional perovskites LUMINESCENT CENTERS Edge STATES Cesium LEAD halides Deep-level STATES Ruddlesden–Popper perovskites
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Low-dimensional MXenes as noble metal-free co-catalyst for solar-to-fuel production:Progress and prospects 被引量:4
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作者 Wanying Lei Tong Zhou +2 位作者 Xin Pang Shixiang Xue Quanlong Xu 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第19期143-164,共22页
Direct conversion of solar energy into chemical fuels via semiconducting materials through photocatalytic technology is a sustainable way to tackle the global warming, environmental issue and energy crisis. Transition... Direct conversion of solar energy into chemical fuels via semiconducting materials through photocatalytic technology is a sustainable way to tackle the global warming, environmental issue and energy crisis. Transition metal carbides and nitrides(MXenes), a newly emerging class of 2D layered materials, has gained tremendous attention as a noble metal-free co-catalyst for boosting photoreactivity due to its extraordinary characteristics like elemental abundance, excellent electrical conductivity, abundant surface functional groups, unique hydrophilic behavior and flexible modulation of chemical composition. The rational integration of low-dimensional MXenes in the form of 2D layered structures or 0D quantum dots with diverse semiconducting materials offer more versatile and robust heterostructured-photocatalysts that are applicable in solar fuel generation. Herein, we summarize the recent advances and achievements in the synthesis of low-dimensional MXenes and their application in hydrogen production from water splitting and CO_(2) photoreduction. A comprehensive discussion of the fundamentals for solar fuel production, synthesis strategies and theoretical calculations for MXenes-based photocatalysts are also given. Finally, the existing challenges and further perspectives of MXenes-based nanostructures for efficient solar fuel production are addressed. 展开更多
关键词 MXenes low-dimensional materials CO-CATALYST Photocatalytic H_(2)evolution CO_(2)photoreduction
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A refined design method for precoolers with consideration of multi-parameter variations based on low-dimensional analysis 被引量:4
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作者 Hui LI Zhengping ZOU Yumin LIU 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2022年第3期329-344,共16页
The precooler is a distinctive component of precooled air-breathing engines but constitutes a challenge to conventional thermal design methods.The latter are based upon assumptions that often reveal to be limited for ... The precooler is a distinctive component of precooled air-breathing engines but constitutes a challenge to conventional thermal design methods.The latter are based upon assumptions that often reveal to be limited for precooler design.In this paper,a refined design method considering the variations of fluid thermophysical properties,flow area and thermal parameters distortion,was proposed to remediate their limitations.Firstly,the precooler was discretized into a fixed number of sub-microtubes based on a new discretization criterion.Next,in-house one-dimensional(1D)and two-dimensional(2D)segmented models were established for rapid thermal design and precooler rating with non-uniform airflow,respectively.The heat transfer experimental studies of supercritical hydrocarbon fuel were performed to verify the Jackson correlation for precooler design and the in-house models were validated against the reported data from open literature.On this basis,the proposed method was employed for the design analysis of hydrocarbon fuel precoolers for precooled-Turbine Based Combined Cycle(TBCC)engines.The results show that the local performance of precoolers is intrinsically impacted by the aforementioned three variations.In the case study,the local heat transfer performance is drastically affected by coolant flow transition.While the circumferential temperature distortion of airflow is weakened by heat transfer.With consideration of additional parameter variations,this novel method improves design accuracy and shortens the design time. 展开更多
关键词 Compact heat exchangers Heat exchanger design low-dimensional segmented model Non-uniform inflow Precooled engine Thermophysical properties variation
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