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Grain refinement effects of Al based alloys with low titanium content produced by electrolysis 被引量:12
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作者 刘志勇 王明星 +3 位作者 翁永刚 宋天福 谢敬佩 霍裕平 《中国有色金属学会会刊:英文版》 CSCD 2002年第6期1121-1126,共6页
A series of Al based alloys with low titanium contents (mass fraction) from 0.178% to 0.526% were directly produced in ordinary industrial electrolyzer. The electrolyzing results show that producing Al based alloys wi... A series of Al based alloys with low titanium contents (mass fraction) from 0.178% to 0.526% were directly produced in ordinary industrial electrolyzer. The electrolyzing results show that producing Al based alloys with titanium contents of less than 0.30% without great loss of electrolysis efficiency is possible. The quantitative analysis shows that this method has a great refining effect on transiting the coarse columnar grains in pure Al to equiaxed grains. The grain sizes decrease with the increase of titanium content and tend to a low limit at about 130 μm. During the solidification, the non equilibrium distribution of titanium leads to a great growth restricting effect and a constitutional under cooling zone in front of the growing liquid /solid interface. 展开更多
关键词 铝合金 低钛含量 电解 晶粒细化
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Control of Ultra Low Titanium in Ultra Low Carbon Al-Si Killed Steel 被引量:4
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作者 ZHANG Feng LI Guang-qiang 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2013年第4期20-25,共6页
Titanium is the impurity in some special steel grades.The existence of titanium decreases the grain size,depresses the yield strength,and results in the low quality of these steels in various properties.Thus,titanium ... Titanium is the impurity in some special steel grades.The existence of titanium decreases the grain size,depresses the yield strength,and results in the low quality of these steels in various properties.Thus,titanium should be removed to the minimum.Based on the industrial production of ultra low carbon Al-Si killed steel,the physical-chemical behavior of titanium was investigated in vacuum degassing refining(RH)process with and without desulfurization.The influences of titanium content in hot metal,ladle slag composition,and ladle slag quantity,etc,on titanium content of refined liquid steel were discussed.The results showed that the partition ratio of titanium between ladle slag and liquid steel is in inverse proportion to the 4/3square of aluminum content.The maximum partition ratio of titanium between top slag and liquid steel can be obtained by adjusting an optimum slag composition including contents of FeOxand Al2O3and the slag basicity,and the suitable range of them should be controlled higher than 6%,less than 20%,and within 1.5to 3.0,respectively.Moreover,desulfurization refining by RH decreases the partition ratio of titanium between ladle slag and liquid steel significantly.To ensure the titanium content stably less than 15×10-6 in a 300tladle,the titanium content in hot metal must be less than 500×10-6 and the thickness of basic oxygen furnace(BOF)slag carrying over must be less than 50mm. 展开更多
关键词 titanium desulfurization RH refining ultra low carbon steel Al-Si killed steel
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Low-cyclic fatigue properties of electrolytic low-titanium A356 alloys
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作者 刘忠侠 宋谋胜 +3 位作者 翁永刚 王明星 宋天福 刘志勇 《中国有色金属学会会刊:英文版》 CSCD 2006年第A03期1351-1355,共5页
The low-cycle fatigue (LCF) behavior of two kinds of A356 alloys produced by different titanium alloying methods was investigated and compared. The effect of titanium content and titanium alloying methods on LCF behav... The low-cycle fatigue (LCF) behavior of two kinds of A356 alloys produced by different titanium alloying methods was investigated and compared. The effect of titanium content and titanium alloying methods on LCF behavior is analyzed with plastic strain energy density. The results show that all alloys exhibit the cyclic hardening behavior. Raising Ti content can obviously increase the cyclic hardening ability. But the effect of Ti alloying method isn't distinct. Whether for the EA356 alloys or for MA356 alloys, the alloys with low titanium content have longer low-cycle fatigue life than that of the alloys with high titanium content. This is because that the alloys with low titanium content can consume higher cyclic plastic strain energy during cyclic deformation compared with alloys with high titanium content. 展开更多
关键词 金属疲劳 钛合金 微观结构 循环硬化
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An Efficient Preparation of 2, 3-Disubstituted Indole Derivatives Induced by Low-valent Titanium
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作者 XueSenFAN XinYingZHANG +1 位作者 YongMinZHANG GuiRongQU 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第5期518-520,共3页
An efficient synthesis of 2, 3-disubstituted indole derivatives through low-valent titanium induced reductive cyclization of acylamido carbonyl compounds is described.
关键词 Indole derivatives low-valent titanium reductive cyclization process.
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Low cycle fatigue improvement of powder metallurgy titanium alloy through thermomechanical treatment 被引量:1
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作者 刘彬 刘咏 +2 位作者 何小禹 汤慧萍 陈丽芳 《中国有色金属学会会刊:英文版》 EI CSCD 2008年第2期227-232,共6页
A low-cost β type Ti-1.5Fe-6.8Mo-4.8Al-1.2Nd (mass fraction, %)(T12LCC) alloy was produced by blended elemental powder metallurgy(P/M) method and subsequent thermomechanical treatment. Low cycle fatigue(LCF) behavior... A low-cost β type Ti-1.5Fe-6.8Mo-4.8Al-1.2Nd (mass fraction, %)(T12LCC) alloy was produced by blended elemental powder metallurgy(P/M) method and subsequent thermomechanical treatment. Low cycle fatigue(LCF) behavior of P/M T12LCC alloy before and after thermomechanical treatment was studied. The results show that the LCF resistance of P/M titanium alloy is significantly enhanced through the thermomechanical treatment. The mechanisms for the improvement of LCF behavior are attributed to the elimination of residual pores, the microstructure refining and homogenization. 展开更多
关键词 冶金术 变形热处理 合金材料
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Low cyclic fatigue behavior of electron-beam-welded Ti–6Al–4V titanium joint
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作者 Hong-Yu Qi Li-Qiang Ma +1 位作者 Shao-Lin Li Xiao-Guang Yang 《Rare Metals》 SCIE EI CAS CSCD 2016年第3期230-234,共5页
The low cycle fatigue(LCF) tests were carried out using symmetrical cyclic loading under total strain amplitude control conditions.The present paper is devoted to investigating the cyclic deformation response of Ti... The low cycle fatigue(LCF) tests were carried out using symmetrical cyclic loading under total strain amplitude control conditions.The present paper is devoted to investigating the cyclic deformation response of Ti–6Al–4V titanium and the electron-beam-welded(EBW) joint in the following aspects,i.e.,cyclic deformation behavior,fatigue life and fatigue fracture behavior.The results show that the softening of the joint is significant at larger strain ranges,while not obvious at smaller strain ranges.The joint shows shorter fatigue life at larger strain ranges and equivalent fatigue life at smaller strain ranges compared with Ti–6Al–4V base metal.A fatigue crack of the joint not only originates at the surface or subsurface,but also at defects in the fusion zone(FZ).The crack propagation zone of Ti–6Al–4V base metal shows ductile fracture mechanism,while the joint shows brittle fracture mechanism.In all the fatigue fracture zones many dimples appear,showing the typical ductile fracture. 展开更多
关键词 Ti–6Al–4V titanium alloy Electron beam welding low cyclic fatigue Fracture analysis
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INFLUENCE OF DWELL TIME ON HIGH TEM-PERATURE LOW CYCLE FATIGUE (HTLCF) BEHAVIOR IN AN Nd-BEARING NEAR-α TITANIUM ALLOY
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作者 Zhu Zhishou, Cao Chunxiao, Ma Jimin, Gao Yang, Yan Minggao (Beijing Institute of Aeronautical Materials, Beijing, 100095, China) 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 1997年第3期42-47,共6页
The influences of strain amplitude ranges and dwell time at peak strains on the low cycle fatigue (LCF) properties at 600℃ of a new near α high temperature titanium alloy containing rare earth Nd are investigated. ... The influences of strain amplitude ranges and dwell time at peak strains on the low cycle fatigue (LCF) properties at 600℃ of a new near α high temperature titanium alloy containing rare earth Nd are investigated. The creep fatigue interaction behavior is discussed in this paper in terms of a creep fatigue interaction cumulative law and fatigue crack propagation model. The results show that the creep fatigue interaction is largely dependent on the strain amplitude range, and the tensile dwell periods, as well as compressive dwell periods, have a great influence on the LCF life of this alloy. 展开更多
关键词 creep analysis fatigue (materials) titanium alloys dwell time low cycle fatigue (LCF)
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Biomedical titanium alloys and their additive manufacturing 被引量:27
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作者 Yu-Lin Hao Shu-Jun Li Rui Yang 《Rare Metals》 SCIE EI CAS CSCD 2016年第9期661-671,共11页
Titanium and its alloys have been widely used for biomedical applications due to their better biomechanical and biochemical compatibility than other metallic materials such as stainless steels and Co-based alloys.A br... Titanium and its alloys have been widely used for biomedical applications due to their better biomechanical and biochemical compatibility than other metallic materials such as stainless steels and Co-based alloys.A brief review on the development of the b-type titanium alloys with high strength and low elastic modulus is given and the use of additive manufacturing technologies to produce porous titanium alloy parts,using Ti-6Al-4V as a reference,and its potential in fabricating biomedica replacements are discussed in this paper. 展开更多
关键词 Beta titanium alloys High strength low elastic modulus Additive manufacturing Biomedical application
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Effect of interface morphology on the mechanical properties of titanium clad steel plates 被引量:5
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作者 Ji-xiong Liu Ai-min Zhao +3 位作者 Hai-tao Jiang Di Tang Xiao-ge Duan Heng-yong Shui 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2012年第5期404-408,共5页
Interface morphology has important influence on the bond quality of titanium clad steel plates. The mechanical properties of titanium clad steel plates with wavy and straight interfaces were investigated by tensile-sh... Interface morphology has important influence on the bond quality of titanium clad steel plates. The mechanical properties of titanium clad steel plates with wavy and straight interfaces were investigated by tensile-shear tests and bending tests. The interface morphology of the plates was examined by optical microscopy (OM) and scanning electron microscopy (SEM). The experimental results show that the shear strength of a wavy interface is higher than that of a straight interface. A wavy interface is the guarantee for obtaining high shear strength to provide a greater shear resistance. During the maerobending process, cracks appear in the swirl of the wave tip and ferrotitanium intermetallies. For in-situ observing the bending process by SEM, the wave tip of a wavy interface and the massive ferrotitartium intermetallies of a straight interface are places where cracks initiate and propagate. The results are the same as those observed in the macrobending process. Became of high hardness, the wave tip and the massive ferrotitanium intermetallies are hard in terms of compatible deformation. 展开更多
关键词 clad metals CLADDING titanium low carbon steel interfaces MORPHOLOGY mechanical properties
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Population Evolution of Oxide Inclusions in Ti-stabilized Ultra-low Carbon Steels after Deoxidation 被引量:6
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作者 Wen YANG Ying ZHANG +2 位作者 Li-feng ZHANG Hao-jian DUAN Li WANG 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2015年第12期1069-1077,共9页
Population density function (PDF), which can eliminate the arbitrariness caused by the choice of the num- ber and the size of bins compared to the well-used histograms, was introduced to analyze the amount of inclus... Population density function (PDF), which can eliminate the arbitrariness caused by the choice of the num- ber and the size of bins compared to the well-used histograms, was introduced to analyze the amount of inclusions. The population evolution of oxide inclusions in forms of PDF in Ti-stabilized ultra-low carbon steels after deoxidation during industrial RH refining and continuous casting processes was analyzed using an automated SEM-EDS system. It was found that after deoxidation till the early stage of casting, the alumina inclusions exhibited a lognormal PDF distribution, and three factors including the existence of a large amount of alumina clusters, the generation of alumi- na from the reduction of Al-Ti-O inclusions and the reoxidation of molten steel were estimated as the reasons. The shape parameter σ was high after deoxidation and then decreased after Ti treatment, indicating that in a short period after deoxidation, the size of alumina inclusions was widely distributed. After Ti treatment, the distribution of inclu- sion size was more concentrated. The scale parameter m decreased with time during the whole refining process, indi- cating that the proportion of large inclusions decreased during refining. Contrarily, the Al-Ti-O inclusions presented a fractal PDF distribution except at the end of casting with fractal dimension D of 4.3, and the constant of propor- tionality C decreased with time during RH refining and increased during casting process. The reoxidation of steel by slag entrapped from ladle was considered as the reason for the lognormal PDF behavior of Al-Ti-O inclusions at the end of casting. 展开更多
关键词 non-metallic inclusion population density function titanium treatment ultra-low carbon steel REOXIDATION
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Synthesis of Anatase TiO_2 Nanoparticles by Improved Sol-Gel Process at Low Temperature
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作者 王玉玲 杜海燕 +1 位作者 韩晶 崔兰 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第S1期306-308,共3页
The nanocrystalline TiO_2 powder were prepared by improved sol-gel method at low temperature under ambient pressure. The prepared TiO_2 powder was characterized by X-ray diffraction (XRD), transmission electron micros... The nanocrystalline TiO_2 powder were prepared by improved sol-gel method at low temperature under ambient pressure. The prepared TiO_2 powder was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM). It is found that the yield of anatase TiO_2 significantly increases with the reduction of pH by increasing the nucleation rate of anatase. There is an optimum amount of water in sol for the formation of anatase by combining two effects on the concentration of Ti(OH)_4 in gels. Increasing in reaction temperature also benefit to the nucleation of anatase of TiO_2. 展开更多
关键词 improved sol-gel process titanium dioxide NANOCRYSTALLINE low temperature
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钛/钢电阻单元焊接头的组织与性能研究
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作者 王楠楠 张家宁 +2 位作者 赵培峰 石红信 邱然锋 《热加工工艺》 北大核心 2025年第5期62-65,72,共5页
为强化钛/钢电阻点焊接头性能,采用钢质铆钉的单元件对纯钛与Q235低碳钢进行了电阻单元焊,测试了接头的抗剪载荷,观察分析了接头的微观组织特性。结果表明:在接头中铆钉腿与Q235下板间形成了熔核,其直径达到铆钉腿径左右时,在铆钉腿与... 为强化钛/钢电阻点焊接头性能,采用钢质铆钉的单元件对纯钛与Q235低碳钢进行了电阻单元焊,测试了接头的抗剪载荷,观察分析了接头的微观组织特性。结果表明:在接头中铆钉腿与Q235下板间形成了熔核,其直径达到铆钉腿径左右时,在铆钉腿与纯钛上板的界面形成金属间化合物层。钛/低碳钢电阻单元焊接头抗剪载荷随焊接电流、焊接时间的增大而先增加后下降,接头最大抗剪载荷约为11.9 kN。实践表明,采用电阻单元焊方法焊接钛与低碳钢是比较有效的。 展开更多
关键词 低碳钢 电阻单元焊
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低品位钛渣提取钛的过程研究
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作者 蒋伟 薛济来 +3 位作者 汪胜东 蒋训雄 谢思源 张登高 《中国有色金属学报》 北大核心 2025年第4期1291-1303,共13页
针对低品位钛渣提取钛工艺技术难以实现工业化的现状,综合采用化学分析、XRD、扫描电镜等方法研究钛渣中有价成分及矿物结构。据此提出以氯化铵作为活化剂进行焙烧活化-浸出除杂制备钛富集渣的工艺路线,并借助正交实验设计与优化,探明... 针对低品位钛渣提取钛工艺技术难以实现工业化的现状,综合采用化学分析、XRD、扫描电镜等方法研究钛渣中有价成分及矿物结构。据此提出以氯化铵作为活化剂进行焙烧活化-浸出除杂制备钛富集渣的工艺路线,并借助正交实验设计与优化,探明活化过程主要影响因素作用;通过实验确定了钛富集渣酸解过程最优工艺参数,并研究了钛富集渣酸解过程反应动力学。结果表明:低品位钛渣的主要矿物为绿辉石、辉石和尖晶石,钛、钙元素主要分布在钙钛矿中。活化过程主要影响因素作用的降序为活化温度>活化剂用量>活化时间。最优酸解提钛工艺参数为酸矿比1.2∶1、初始硫酸浓度90%、温度200℃、时间50 min。在最优条件下,钛富集渣的钛酸解率可达90.41%,实现了钛富集渣中TiO2的有效分离提取。钛富集渣酸解过程反应化学动力学主要受内扩散控制,计算获得表观活化能为18.05 kJ/mol。 展开更多
关键词 低品位 钛渣 活化 正交试验 酸解 动力学
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Numerical Analysis and Experimental Verification of Ti/APC-2/Kevlar Hybrid Composite Laminates Due to Low-Velocity Impact
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作者 Ming Hwa R. Jen Che Kai Chang Ying Hui Wu 《Materials Sciences and Applications》 2018年第13期1083-1095,共13页
The mechanical properties of Ti/APC-2/Kevlar/epoxy hybrid composite laminates after low velocity impact were investigated at room temperature. There were three types of samples, including three layered [Ti/(0/90)s/Ti]... The mechanical properties of Ti/APC-2/Kevlar/epoxy hybrid composite laminates after low velocity impact were investigated at room temperature. There were three types of samples, including three layered [Ti/(0/90)s/Ti], five layered [Ti/(0/90)2/]s and nine layered [Ti/Kevlar/Ti/(0/90)2/]s. The lay-ups of APC-2 were crossply, while Ti layers were treated by chromic acid anodic method. Ti and APC-2 were stacked to fabricate the composite laminates via hot press curing process. Kevlar layers were added to fabricate nine-layered composite laminates via vacuum assisted resin transfer molding. The drop-weight tests were conducted with a hemispherical nosed projectile in 10 mm diameter. The impact loads were 5 kg and 10 kg and impact heights were adjusted to penetrate samples or the maximum height 1.50 m. The static tensile tests were conducted to measure the residual mechanical properties after impact. The free body drop tests were also simulated by using finite element method and software ANSYS LS-DYNA3D. The results showed that the bottom Ti layer absorbed more internal energy than the top Ti layer, then the cracks were found in the bottom Ti layer more often. The ultimate tensile strength reduced significantly after impact. The initial longitudinal compliance increased with the impact height increasing and decreased after the samples penetrated. Comparing the experimental data with the numerical results, it was found that the damage of the latter was more serious than that of the former. On the conservative side, the results of numerical simulation are acceptable and adopted for applications when no testing data available. 展开更多
关键词 titanium APC-2 KEVLAR low-Velocity Impact TENSILE Test
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Analysis of thermodynamics and kinetics of titanium between top slag and liquid steel
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作者 ZHANG Feng 《Baosteel Technical Research》 CAS 2013年第1期28-33,共6页
: Titanium is an impurity element in some special steel grades. The existence of titanium decreases the grain size and lowers the yield strength ,resulting in low quality of these steels with regard to various proper... : Titanium is an impurity element in some special steel grades. The existence of titanium decreases the grain size and lowers the yield strength ,resulting in low quality of these steels with regard to various properties. Thus, the titanium content should be reduced to the minimum. Based on the industrial production of ultra-low carbon A1-Si killed steel, this paper investigated the physical-chemical behaviors of titanium with and without desulfurization during RH refining. The influences of Ti content in hot metal, ladle slag composition, and ladle slag quantity, etc., on the Ti content in refined liquid steel were discussed. The results show that the partition ratio of titanium between ladle slag and liquid steel is inversely proportional to the AI content to the power of 4/3 ,and the empirical formula regressed from practical experience can be expressed as w(TiO2)/WTi=48/w[AI]4/3 Maximum partition ratio of titanium between top slag and liquid steel can be ensured W[Til WIAIIby an optimum slag composition including components of FeOx and A12 03 and an appropriate slag basicity. The contents of FetO and A1203 should be controlled above 6% and below 20% respectively and the slag basicity should be kept within 1.5 to 3.0. Moreover, desulfurization refining in the RH vacuum will decrease the partition ratio of titanium between ladle slag and liquid steel significantly. To keep the Ti content stably below 15 ×10 ^-4% in a 300 ton ladle ,the Ti content in hot metal must be lower than 500 × 10^-4% and the thickness of ladle slag carried over from BOF slag must be less than 50 ram. 展开更多
关键词 titanium DESULFURIZATION RH refining ultra-low carbon steel Al-Si killed steel
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Effect of an upward magnetic field on nanosized sulfide precipitation in ultra-low carbon steel
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作者 Kang-jia Duan Ling Zhang +3 位作者 Xi-zhi Yuan Shan-shan Han Yu Liu Qing-song Huang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第7期714-720,共7页
An induction levitation melting (ILM) refining process is performed to remove most microsized inclusions in ultra-low carbon steel (UCS). Nanosized, spheroid shaped sulfide precipitates remain dispersed in the UCS... An induction levitation melting (ILM) refining process is performed to remove most microsized inclusions in ultra-low carbon steel (UCS). Nanosized, spheroid shaped sulfide precipitates remain dispersed in the UCS. During the ILM process, the UCS is molten and is rotated under an upward magnetic field. With the addition of Ti additives, the spinning molten steel under the upward magnetic field ejects particles because of resultant centrifugal, floating, and magnetic forces. Magnetic force plays a key role in removing sub-micrometer-sized particles, composed of porous aluminum titanate enwrapping alumina nuclei. Consequently, sulfide precipitates with sizes less than 50 nan remain dispersed in the steel matrix. These findings open a path to the fabrication of clean steel or steel bearing only a nanosized strengthen- ing phase. 展开更多
关键词 ultra-low carbon steel magnetic field sulfide precipitation induction levitation titanium
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低成本钛合金厚板热弯曲工艺与组织性能 被引量:1
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作者 张涛 陈利华 +5 位作者 程远 曲海涛 曹宏东 李德崇 韩玉杰 曹凤超 《锻压技术》 北大核心 2025年第1期92-101,共10页
以一种新型低成本钛合金TC4LCA为研究对象,通过V型件弯曲实验,研究成形温度、保压时间以及弯曲半径对TC4LCA钛合金V型件成形精度、微观组织及力学性能的影响。结果表明:弯曲半径为t时随着成形温度从700℃升高至800℃、保压时间从5 min... 以一种新型低成本钛合金TC4LCA为研究对象,通过V型件弯曲实验,研究成形温度、保压时间以及弯曲半径对TC4LCA钛合金V型件成形精度、微观组织及力学性能的影响。结果表明:弯曲半径为t时随着成形温度从700℃升高至800℃、保压时间从5 min增加至25 min,弯曲构件的回弹角从16′减小至0′,壁厚减薄率从2.6%增大至5.8%,维氏硬度与强度均有小幅降低,性能均达到了母材的90%;在成形温度为750℃、保压时间为15 min的条件下,随着成形弯曲半径从2.0t减小至0.5t时,构件壁厚减薄率从2.3%增加至6.7%,回弹角从2′增大至9′。该研究成果可为低成本TC4LCA钛合金V型件热弯曲工艺参数的合理设计提供依据,在保证钛合金构件服役性能的同时,降低成本以拓展其应用范围。 展开更多
关键词 低成本钛合金 热弯曲 微观组织 回弹 力学性能
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“双碳”目标下钒钛产业绿色低碳发展的路径与政策协同研究
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作者 张友鹏 陈永怀 《现代工业经济和信息化》 2025年第9期215-217,共3页
在“双碳”目标背景下,钒钛产业作为我国战略性资源产业,其绿色低碳转型面临技术瓶颈、成本压力与政策碎片化等多重挑战。基于政策与市场机制协同视角,通过文献分析、案例研究与专家访谈,系统探讨钒钛产业低碳发展的技术路径、政策工具... 在“双碳”目标背景下,钒钛产业作为我国战略性资源产业,其绿色低碳转型面临技术瓶颈、成本压力与政策碎片化等多重挑战。基于政策与市场机制协同视角,通过文献分析、案例研究与专家访谈,系统探讨钒钛产业低碳发展的技术路径、政策工具及市场激励措施。研究发现,氢冶金技术、碳捕集与封存(CCS)及智能化生产是技术突破的关键方向;绿色金融支持、碳交易机制与财政补贴可有效降低企业转型成本;跨部门协同与政策整合则是制度优化的核心。研究提出“技术-政策-市场”三位一体的协同框架,为钒钛产业实现经济与环境双赢提供理论支撑与实践参考。 展开更多
关键词 “双碳”目标 钒钛产业 绿色低碳 政策协同
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锻造变形对Ti-5Al-6.5Mo-1.5Fe低成本钛合金组织性能演化的影响研究
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作者 张元东 赵张龙 +5 位作者 曹胜 冯凯凯 李璞 查小晖 李倩 辛社伟 《稀有金属材料与工程》 北大核心 2025年第9期2325-2335,共11页
进行了Ti-5Al-6.5Mo-1.5Fe低成本钛合金不同锻造参数下微观组织与拉伸性能演化的分析研究,发现合金在不同锻造参数下的组织性能之间存在明显关联。结果表明:合金在两相区锻造时,组织中等轴初生α相(α_(p))含量随温度升高逐渐降低、尺... 进行了Ti-5Al-6.5Mo-1.5Fe低成本钛合金不同锻造参数下微观组织与拉伸性能演化的分析研究,发现合金在不同锻造参数下的组织性能之间存在明显关联。结果表明:合金在两相区锻造时,组织中等轴初生α相(α_(p))含量随温度升高逐渐降低、尺寸减小,抗拉强度和塑性略有波动;随锻造变形量增大,组织中α_(p)相形态发生明显改变,合金抗拉强度和塑性稳定性较好,α_(p)相内部呈现出连续的取向差累积,促进了球化和再结晶,β相在变形力作用下取向逐渐转变为Cube织构{001}<100>。在单相区锻造时,原始α_(p)相完全消失,β晶粒粗大,长条状晶界α相(α_(GB))析出,晶内次生α相(α_(s))增多,合金拉伸塑性急剧下降。组织内可协调变形的等轴α_(p)相和显著提高强度的纳米级α_(s)相的共存可同时实现高强度和高韧性,使得合金在两相区锻造能够获得更好的力学性能,而β粗晶是造成合金单相区锻造后塑性下降的主要原因,试样拉伸断裂机制从两相区锻造变形后的单一韧窝断裂转变为β单相区锻造后的解理-韧窝混合断裂。 展开更多
关键词 低成本钛合金 锻造工艺 微观组织 力学性能 断裂机制
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氢辅助镁热还原二氧化钛制备低氧氢化钛
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作者 王卓 徐浩元 +3 位作者 魏永刚 李博 郑永兴 王华 《中国有色冶金》 北大核心 2025年第2期56-64,共9页
目前,工业上应用最广泛的制备金属钛的方法是Kroll法,但是Kroll法的生产过程不连续、生产周期长、成本高,导致钛金属的价格高昂,限制了钛的应用。因此,开发连续生产、短流程、低成本的钛冶炼新技术具有重要意义。氢辅助镁热还原法通过... 目前,工业上应用最广泛的制备金属钛的方法是Kroll法,但是Kroll法的生产过程不连续、生产周期长、成本高,导致钛金属的价格高昂,限制了钛的应用。因此,开发连续生产、短流程、低成本的钛冶炼新技术具有重要意义。氢辅助镁热还原法通过在系统中引入氢气使Ti-O固溶体转变为Ti-O-H固溶体,打破了镁热还原二氧化钛的热力学极限。本文通过氢辅助镁热还原法使用粒度为0.05 mm的TiO_(2)在650℃还原2 h制备了高纯度的低氧氢化钛,并通过热力学计算研究了氢气对Ti-O固溶体的失稳作用,氢的存在使镁热还原二氧化钛过程所需的温度更低、时间更短、还原更加彻底;通过单因素试验考察粒度对产物的氧含量的影响,结果表明,粒度越大产物的表面氧含量越低,但过大的粒度会导致其晶格氧的还原效果变差;还原产物的脱氧是对其晶格氧的脱除。本研究结果可为氢辅助镁热还原法的进一步发展提供参考。 展开更多
关键词 金属钛 低氧氢化钛 氢辅助镁热还原法 Ti-O固溶体 Ti-O-H固溶体 表面氧 晶格氧 粒度
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