From an engineering feasibility standpoint, what level of performance metrics can be ultimately achieved when designing a reactor using well-established nuclear fuels and structural materials that have already undergo...From an engineering feasibility standpoint, what level of performance metrics can be ultimately achieved when designing a reactor using well-established nuclear fuels and structural materials that have already undergone irradiation testing? The irradiation capability, which hinges on parameters like neutron flux level, irradiation channels' volume, and fuel cycle duration, is a core indicator for high-flux reactors. We propose a conceptual design of an ultra-high flux fast reactor(UFFR) with strong irradiation capability, which utilizes U-20Pu-10Zr alloy fuel and employs lead-bismuth as the coolant. The maximum neutron flux in the core reaches 1.32×10^(16) cm^(-2)s^(-1), while the average neutron flux in the irradiation channels attains 1.19×10^(16) cm^(-2)s^(-1). The volume of the central irradiation channel exceeds 10000 cm^(3), and the fuel cycle duration is 165 d, placing all its performance indicators among the top in the world. Based on the analyses of reactor physics and thermalhydraulics, it has been demonstrated that all reactivity coefficients are negative and all physical parameters meet the design criteria, ensuring the inherent safety of UFFR. An assessment of the irradiation capability has been carried out based on californium-252(^(252)Cf) production, indicating that the irradiation capability of UFFR surpasses that of the high flux isotope reactor(HFIR). The yield of ^(252)Cf from UFFR is 14.39 times that of HFIR, and its nuclei conversion rate is 3.21 times that of HFIR.展开更多
Molten salt reactors,being the only reactor type among Generation Ⅳ advanced nuclear reactors that utilize liquid fuels,offer inherent safety,high-temperature,and low-pressure operation,as well as the capability for ...Molten salt reactors,being the only reactor type among Generation Ⅳ advanced nuclear reactors that utilize liquid fuels,offer inherent safety,high-temperature,and low-pressure operation,as well as the capability for online fuel reprocessing.However,the fuel-salt flow results in the decay of delayed neutron precursors(DNPs)outside the core,causing fluctuations in the effective delayed neutron fraction and consequently impacting the reactor reactivity.Particularly in accident scenarios—such as a combined pump shutdown and the inability to rapidly scram the reactor—the sole reliance on negative temperature feedback may cause a significant increase in core temperature,posing a threat to reactor safety.To address these problems,this paper introduces an innovative design for a passive fluid-driven suspended control rod(SCR)to dynamically compensate for reactivity fluctuations caused by DNPs flowing with the fuel.The control rod operates passively by leveraging the combined effects of gravity,buoyancy,and fluid dynamic forces,thereby eliminating the need for an external drive mechanism and enabling direct integration within the active region of the core.Using a 150 MWt thorium-based molten salt reactor as the reference design,we develop a mathematical model to systematically analyze the effects of key parameters—including the geometric dimensions and density of the SCR—on its performance.We examine its motion characteristics under different core flow conditions and assess its feasibility for the dynamic compensation of reactivity changes caused by fuel flow.The results of this study demonstrate that the SCR can effectively counteract reactivity fluctuations induced by fuel flow within molten salt reactors.A sensitivity analysis reveals that the SCR’s average density exerts a profound impact on its start-up flow threshold,channel flow rate,resistance to fuel density fluctuations,and response characteristics.This underscores the critical need to optimize this parameter.Moreover,by judiciously selecting the SCR’s length,number of deployed units,and the placement we can achieve the necessary reactivity control while maintaining a favorable balance between neutron economy and heat transfer performance.Ultimately,this paper provides an innovative solution for the passive reactivity control in molten salt reactors,offering significant potential for practical engineering applications.展开更多
The synthesis of propylene carbonate(PC)from CO_(2) and propylene oxide(PO)is a typical gas-liquid biphasic system,where gas-liquid mass transfer efficiency significantly influences CO_(2) cycloaddition reactions.Here...The synthesis of propylene carbonate(PC)from CO_(2) and propylene oxide(PO)is a typical gas-liquid biphasic system,where gas-liquid mass transfer efficiency significantly influences CO_(2) cycloaddition reactions.Here,we proposed a microchannel reaction system for the CO_(2) cycloaddition reaction catalyzed by ionic liquid within an aqueous environment.The effect of liquid flow rate,temperature and residence time on gas-liquid flow pattern,catalytic performance and mass transfer were systematically investigated.The results revealed that the PC generation rate reached 560.11 mmol·ml^(−1)·h^(−1)at a 50 cm of flow distance under reaction conditions of 105℃,2.5 MPa,QG=176 ml·min^(−1) and QL=0.3 ml·min^(−1).Variations in mass transfer rate and reaction rate at different flow distances were experimentally studied.The reaction efficiency gradually decreased with increasing flow distance,which were attributed to the reduction of mass transfer caused by decreasing bubble velocity.Optimizing bubble velocity at an appropriate position enhanced reaction efficiency by improving mass transfer,achieving a 97.7%PC yield within 2.85 min.Furthermore,a kinetic model coupling intrinsic kinetics with gas-liquid mass transfer was developed for CO_(2) cycloaddition reaction.The kinetic model was applied to predict PC reaction rates in microchannel reactors at various temperatures and liquid flow rates,achieving an average relative error of 9.6%.展开更多
Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generat...Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generated aerosol particles using a water spray system integrated with an innovative system for pre-injecting electrically charged mist in our facility.To simulate aerosol generation in reactor decommissioning,a high-power laser was used to irradiate various materials(including stainless steel,carbon steel,and concrete),generating aerosol particles that were agglomerated with injected water mist and subsequently scavenged by water spray.Experimental results demonstrate enhanced aerosol removal via aerosol-mist agglomeration,with charged mist significantly improving particle capture by increasing wettability and size.The average improvements for the stainless steel,carbon steel,and concrete were 40%,44%,and 21%,respectively.The results of experiments using charged mist with different polarities(both positive and negative)and different surface coatings reveal that the dominant polarity of aerosols varies with the irradiated materials,influenced by their crystal structure and electron emission properties.Notably,surface coatings such as ZrO_(2)and CeO_(2)were found to possibly alter aerosol charging characteristics,thereby affecting aerosol removal efficiency with charged mist configurations.The innovative aerosol-mist agglomeration approach shows promise in mitigating radiation exposure,ensuring environmental safety,and reducing contaminated water during reactor dismantling.This study contributes critical knowledge for the development of advanced aerosol management strategies for nuclear reactor decommissioning.The understanding obtained in this work is also expected to be useful for various environmental and chemical engineering applications such as gas decontamination,air purification,and pollution control.展开更多
One of the main issues in designing optimum tapered cascades for uranium enrichment for annual fuel production in a power reactor is whether to employ large(fat)or small(thin)cascades.What will be the permissible and ...One of the main issues in designing optimum tapered cascades for uranium enrichment for annual fuel production in a power reactor is whether to employ large(fat)or small(thin)cascades.What will be the permissible and optimal ranges of the number of machines that can be used in a cascade?For the first time,the permissible and optimal ranges of the number of gas centrifuges that can be utilized in a cascade were investigated using two types of centrifuges,and the performance of small and large tapered cascades was discussed.The particle swarm optimization algorithm(PSO)has been used to optimize tapered cascades.The results show:(1)For the first centrifuge,41 cascades(91≤n≤4897)and for the second centrifuge,49 cascades(18≤n≤3839)with small and large sizes can be used in enrichment facilities,and the best cascade for them has 530(with 23 stages)and 39(with 7 stages)centrifuges,respectively.(2)For both centrifuges,when 600≤n(number of centrifuges=n),the large cascade performance changes are relatively insignificant.(3)For both types of gas centrifuges,the annual los s of separation power in enrichment facilities is approximately 1.25%-4.82%of the total separation work required.展开更多
Medical isotopes are the foundation material for nuclear medicine and are primarily produced through in-reactor irradia-tion.Neutron spectrum regulation is the main technical approach for enhancing the production of m...Medical isotopes are the foundation material for nuclear medicine and are primarily produced through in-reactor irradia-tion.Neutron spectrum regulation is the main technical approach for enhancing the production of medical isotopes,and it requires determining the optimal neutron spectrum and quantifying the values of neutrons in different energy regions.We calculated the neutron energy region values for 20 medical isotopes(^(14)C,^(32)P,^(47)Sc,^(60)Co,^(64)Cu,^(67)Cu,^(89)Sr,^(90)Y,^(99)Mo,^(125)I,^(131)I,^(153)Sm,^(161)Tb,^(166)Ho,^(177)Lu,^(186)Re,^(188)Re,^(92)Ir,^(225)Ac,and ^(252)Cf).The entire energy range was divided into 238 energy regions to improve the energy spectrum resolution,and both fast and thermal reactors were simulated to enhance universal applicability.A dataset of neutron energy region values across the entire energy range was built,which identifies the positive and negative-energy regions and guides the neutron spectrum regulation process during in-reactor medical isotope produc-tion.We conducted neutron spectrum regulation based on this dataset,which effectively improved the production efficiency of medical isotopes and demonstrated the correctness and feasibility of the dataset.展开更多
Small modular reactor(SMR)belongs to the research forefront of nuclear reactor technology.Nowadays,advancement of intelligent control technologies paves a new way to the design and build of unmanned SMR.The autonomous...Small modular reactor(SMR)belongs to the research forefront of nuclear reactor technology.Nowadays,advancement of intelligent control technologies paves a new way to the design and build of unmanned SMR.The autonomous control process of SMR can be divided into three stages,say,state diagnosis,autonomous decision-making and coordinated control.In this paper,the autonomous state recognition and task planning of unmanned SMR are investigated.An operating condition recognition method based on the knowledge base of SMR operation is proposed by using the artificial neural network(ANN)technology,which constructs a basis for the state judgment of intelligent reactor control path planning.An improved reinforcement learning path planning algorithm is utilized to implement the path transfer decision-makingThis algorithm performs condition transitions with minimal cost under specified modes.In summary,the full range control path intelligent decision-planning technology of SMR is realized,thus provides some theoretical basis for the design and build of unmanned SMR in the future.展开更多
Core power is a key parameter of nuclear reactor.Traditionally,the proportional-integralderivative(PID)controllers are used to control the core power.Fractional-order PID(FOPID)controller represents the cutting edge i...Core power is a key parameter of nuclear reactor.Traditionally,the proportional-integralderivative(PID)controllers are used to control the core power.Fractional-order PID(FOPID)controller represents the cutting edge in core power control research.In comparing with the integer-order models,fractional-order models describe the variation of core power more accurately,thus provide a comprehensive and realistic depiction for the power and state changes of reactor core.However,current fractional-order controllers cannot adjust their parameters dynamically to response the environmental changes or demands.In this paper,we aim at the stable control and dynamic responsiveness of core power.Based on the strong selflearning ability of artificial neural network(ANN),we propose a composite controller combining the ANN and FOPID controller.The FOPID controller is firstly designed and a back propagation neural network(BPNN)is then utilized to optimize the parameters of FOPID.It is shown by simulation that the composite controller enables the real-time parameter tuning via ANN and retains the advantage of FOPID controller.展开更多
A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the ph...A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.展开更多
Based on the service characteristics of fuel elements for molten salt reactors,they need to have a high power density,resistance to coolant infiltration,and excellent thermodynamic properties.To solve the problem of t...Based on the service characteristics of fuel elements for molten salt reactors,they need to have a high power density,resistance to coolant infiltration,and excellent thermodynamic properties.To solve the problem of the graphite used in the fuel element for these reactors being susceptible to molten salt infiltration,carbon black(CB)was added to increase the density of the graphite,and a fuel element(TRISO(tri-structural isotropic)fuel particles were randomly distributed in the modified graphite matrix)was prepared by cold isostatic pressing process.An out-of-pile performance study shows that the densification and pore structure of the modified graphite matrix were improved,as was the resistance to molten salt infiltration.The median pore size of the modified graphite was reduced from 673 to 433 nm and the threshold pressure for molten salt(FLiBe,66%(molar fraction)LiF and 34%BeF_(2))infiltration was increased from 0.88 to 1.37 MPa.The isotropic CB made the graphite matrix less anisotropic,while its thermal conductivity and compressive strength were reduced due to the difficult graphitization of CB.Fuel elements containing 20%(volume fraction)TRISO particles were prepared.Numerical simulations show that the power and temperature distribution of the fuel were in line with the design requirements.The modified graphite matrix had a higher density,smaller pores,a lower anisotropy and a greater resistance to FLiBe infiltration.展开更多
Electrocatalytic carbon dioxide reduction is a promising technology for addressing global energy and environmental crises. However, its practical application faces two critical challenges: the complex and energy-inten...Electrocatalytic carbon dioxide reduction is a promising technology for addressing global energy and environmental crises. However, its practical application faces two critical challenges: the complex and energy-intensive process of separat-ing mixed reduction products and the economic viability of the carbon sources (reactants) used. To tackle these challenges simultaneously, solid-state electrolyte (SSE) reactors are emerging as a promising solution. In this review, we focus on the feasibility of applying SSE for tandem electrochemical CO_(2) capture and conversion. The configurations and fundamental principles of SSE reactors are first discussed, followed by an introduction to its applications in these two specific areas, along with case studies on the implementation of tandem electrolysis. In comparison to conventional H-type cell, flow cell and membrane electrode assembly cell reactors, SSE reactors incorporate gas diffusion electrodes and utilize a solid electro-lyte layer positioned between an anion exchange membrane (AEM) and a cation exchange membrane (CEM). A key inno-vation of this design is the sandwiched SSE layer, which enhances efficient ion transport and facilitates continuous product extraction through a stream of deionized water or humidified nitrogen, effectively separating ion conduction from product collection. During electrolysis, driven by an electric field and concentration gradient, electrochemically generated ions (e.g., HCOO- and CH3COO-) migrate through the AEM into the SSE layer, while protons produced from water oxidation at the anode traverse the CEM into the central chamber to maintain charge balance. Targeted products like HCOOH can form in the middle layer through ionic recombination and are efficiently carried away by the flowing medium through the porous SSE layer, in the absence of electrolyte salt impurities. As CO_(2)RR can generate a series of liquid products, advancements in catalyst discovery over the past several years have facilitated the industrial application of SSE for more efficient chemicals production. Also noteworthy, the cathode reduction reaction can readily consume protons from water, creating a highly al-kaline local environment. SSE reactors are thereby employed to capture acidic CO_(2), forming CO_(3)^(2-) from various gas sources including flue gases. Driven by the electric field, the formed CO_(3)^(2-) can traverse through the AEM and react with protons originating from the anode, thereby regenerating CO_(2). This CO_(2) can then be collected and utilized as a low-cost feedstock for downstream CO_(2) electrolysis. Based on this principle, several cell configurations have been proposed to enhance CO_(2) capture from diverse gas sources. Through the collaboration of two SSE units, tandem electrochemical CO_(2) capture and con-version has been successfully implemented. Finally, we offer insights into the future development of SSE reactors for prac-tical applications aimed at achieving carbon neutrality. We recommend that greater attention be focused on specific aspects, including the fundamental physicochemical properties of the SSE layer, the electrochemical engineering perspective related to ion and species fluxes and selectivity, and the systematic pairing of consecutive CO_(2) capture and conversion units. These efforts aim to further enhance the practical application of SSE reactors within the broader electrochemistry community.展开更多
Liquid-fueled molten-salt reactors have dynamic features that distinguish them from solid-fueled reactors,such that conventional system-analysis codes are not directly applicable.In this study,a coupled dynamic model ...Liquid-fueled molten-salt reactors have dynamic features that distinguish them from solid-fueled reactors,such that conventional system-analysis codes are not directly applicable.In this study,a coupled dynamic model of the Molten-Salt Reactor Experiment(MSRE)is developed.The coupled model includes the neutronics and single-phase thermal-hydraulics modeling of the reactor and validated xenon-transport modeling from previous studies.The coupled dynamic model is validated against the frequency-response and transient-response data from the MSRE.The validated model is then applied to study the effects of xenon and void transport on the dynamic behaviors of the reactor.Plant responses during the unique initiating events such as off-gas system blockages and loss of circulating voids are investigated.展开更多
This study develops a CFD-ML integrated framework to achieve multi-objective optimization for the partial oxidation of n-butane to maleic anhydride(MA).A reactor-pellet coupled model was established to investigate the...This study develops a CFD-ML integrated framework to achieve multi-objective optimization for the partial oxidation of n-butane to maleic anhydride(MA).A reactor-pellet coupled model was established to investigate the effects of four key operating parameters,revealing that inlet temperature dominates reactor performance by increasing MA yield from 35.0%to 37.6%while sharply raising hotspot temperatures by 42 K.The coupled model was then employed to generate 621 cases for training machine learning models,among which the Gaussian Process Regression(GPR)model exhibits superior accuracy.The GPR model was further integrated with the genetic algorithm to generate Pareto-optimal sets.The results indicate that a critical inflection point is identified on the Pareto front,and once this point is exceeded,even a slight increase in MA yield could lead to a sharp rise in the reactor hotspot temperature,thereby increasing the risk of thermal runaway.展开更多
Molten salt reactors(MSRs)are a promising candidate for Generation IV reactor technologies,and the small modular molten salt reactor(SM-MSR),which utilizes low-enriched uranium and thorium fuels,is regarded as a wise ...Molten salt reactors(MSRs)are a promising candidate for Generation IV reactor technologies,and the small modular molten salt reactor(SM-MSR),which utilizes low-enriched uranium and thorium fuels,is regarded as a wise development path to accelerate deployment time.Uncertainty and sensitivity analyses of accidents guide nuclear reactor design and safety analyses.Uncertainty analysis can ascertain the safety margin,and sensitivity analysis can reveal the correlation between accident consequences and input parameters.Loss of forced cooling(LOFC)represents an accident scenario of the SM-MSR,and the study of LOFC could offer useful information to improve physical thermohydraulic and structural designs.Therefore,this study investigates the uncertainty of LOFC consequences and the sensitivity of related parameters.The uncertainty of the LOFC consequences was analyzed using the Monte Carlo method,and multiple linear regression was employed to analyze the sensitivity of the input parameters.The uncertainty and sensitivity analyses showed that the maximum reactor outlet fuel salt temperature was 725.5℃,which is lower than the acceptable criterion,and five important parameters influencing LOFC consequences were identified.展开更多
Paired electrosynthesis has received considerable attention as a consequence of simultaneously synthesizing target products at both cathode and anode,whereas the related synthetic efficiency in batch reactors is still...Paired electrosynthesis has received considerable attention as a consequence of simultaneously synthesizing target products at both cathode and anode,whereas the related synthetic efficiency in batch reactors is still undesirable under certain circumstances.Encouragingly,laminar microfluidic reactor offers prospective options that possess controllable flow characteristics such as enhanced mass transport,precise laminar flow control and the ability to expand production scale progressively.In this comprehensive review,the underlying fundamentals of the paired electrosynthesis are initially summarized,followed by categorizing the paired electrosynthesis including parallel paired electrosynthesis,divergent paired electrosynthesis,convergent paired electrosynthesis,sequential paired electrosynthesis and linear paired electrosynthesis.Thereafter,a holistic overview of microfluidic reactor equipment,integral fundamentals and research methodology as well as channel extension and scale-up strategies is proposed.The established fundamentals and evaluated metrics further inspired the applications of microfluidic reactors in paired electrosynthesis.This work stimulated the overwhelming investigation of mechanism discovery,material screening strategies,and device assemblies.展开更多
This study discusses the scope of application of the Doppler backscattering(DBS)diagnostic for the tokamak with reactor technologies(TRT)project.This involved numerical modeling of the three-dimensional(3D)beam trajec...This study discusses the scope of application of the Doppler backscattering(DBS)diagnostic for the tokamak with reactor technologies(TRT)project.This involved numerical modeling of the three-dimensional(3D)beam trajectories.Calculations were performed to investigate the propagation of microwaves in the V(40–75 GHz)and W(75–110 GHz)frequency ranges with O-mode polarization for the density profile of the base TRT scenario.Our analysis showed that the DBS system antenna on the TRT would need to be tilted in both the poloidal and toroidal directions in order to meet the condition Kperp/Kpar<10%..For the DBS system located in the equatorial plane it was shown that a wide range of poloidal and toroidal angles is available for the successful implementation of the diagnostic to study the core,pedestal and scrape-off layer(SOL)regions.The DBS system located at 35 cm above the equatorial plane would be more limited in measurements only covering the SOL and pedestal regions.A shift of the cut-offs in the toroidal direction highlighted the need for 3D analysis of the DBS data.展开更多
This study presents a systematic investigation of pressure drop and gas holdup in an upward-flow fixedbed reactor,examining the effects of bubble size,bed height,particle shape,superficial gas velocity(SGV),and superf...This study presents a systematic investigation of pressure drop and gas holdup in an upward-flow fixedbed reactor,examining the effects of bubble size,bed height,particle shape,superficial gas velocity(SGV),and superficial liquid velocity(SLV)based on experimental measurements and empirical correlations.Two bubble generators,namely ring tube generator(RTG)and porous sintered film generator(PSG),are used.Key findings reveal that for the PSG,increasing SGV decreases small-bubble population while promoting large-bubble formation,with the bubbles stabilizing at a Sauter mean diameter(d_(32))of~3 mm.The RTG produces stable large bubbles(d_(32)=6—7 mm)with minimal size variations across the range of tested SGVs.The pressure drop decreases with an increase in SGV but increases with higher SLV and bed height,primarily due to the reduced liquid holdup and the dominance of static pressure.Smaller bubbles reduce the pressure drop by slowing rise velocity and minimizing frictional resistance.Clover-shaped particles exhibit the highest pressure drop owing to large porosity,while 3-mm toothed spheres show higher pressure drop than 5-mm spheres at high SGV because of intensified capillary forces.The gas holdup increases with increasing SGV and bed height but decreases slightly with increasing SLV.Smaller bubbles enhance gas holdup by improving bed distribution and residence time.The 3-mm toothed spheres show the highest gas holdup due to stronger capillary trapping,whereas the clover-shaped particles exhibit the lowest.Empirical correlations for pressure drop and gas holdup are developed,yielding calculation errors within±1%and±20%of the experimental values,respectively.展开更多
Owing to high thermal stability and large reaction enthalpy,Mg H_(2) has high reaction temperatures and sluggish reaction kinetics in the dehydrogenation process,which consumes lots of energy.To achieve hydrogen relea...Owing to high thermal stability and large reaction enthalpy,Mg H_(2) has high reaction temperatures and sluggish reaction kinetics in the dehydrogenation process,which consumes lots of energy.To achieve hydrogen release with low energy consumption,accelerated reaction rate,and high heating uniformity,this paper proposes a novel method of graphite responsive microwave-assisted thermal management with NaTiO_(x)H catalyst.A multi-physics model of the 5 wt%NaTiO_(x)H catalyzed Mg H_(2) reactor integrated with a microwave generator is developed to investigate the reaction,heat and mass transfer process of hydrogen release.It is found that the graphite responsive microwave heating method could improve the temperature uniformity of reaction bed,reduce the energy consumption by at least 10.71%and save the hydrogen release time by 53.49% compared with the traditional electric heating method.Moreover,the hydrogen desorption thermodynamics could be improved with the increase of microwave power.The hydrogen release time is shortened by 19.55%with the increase of 20 W microwave power.Meanwhile,it is also concluded that the microwave excitation frequency of 2.1 GHz and the graphite content of 2 wt%have better heating performance.Therefore,it can be verified that the graphite responsive microwave heating helps to low-energy and accelerated hydrogen release from MgH_(2) hydrogen storage reactor.展开更多
High flux reactors(HFRs)are a special type of research reactor aimed at providing a high neutron flux.Compared with power reactors and other research reactors,HFRs have unique technical features in terms of reactor co...High flux reactors(HFRs)are a special type of research reactor aimed at providing a high neutron flux.Compared with power reactors and other research reactors,HFRs have unique technical features in terms of reactor core design,irradiation capability,and operating characteristics.They can be applied to the irradiation tests of nuclear fuels and materials,radioisotope production,neutron science,and experiments.This paper reviews HFRs,including their development history,technical features,and application areas,as well as trends in the development of new and advanced HFRs.展开更多
Hydrogenation reactions,vital in chemical engineering,are hampered by limitations including catalyst recovery,mass transfer issues,and scalability.Catalytic membrane reactors offer a promising alternative by integrati...Hydrogenation reactions,vital in chemical engineering,are hampered by limitations including catalyst recovery,mass transfer issues,and scalability.Catalytic membrane reactors offer a promising alternative by integrating reaction and separation,boosting efficiency and simplifying catalyst handling.However,scaling these membranes to industrial levels while ensuring long-term stability and high efficiency remains a significant challenge.This study tackles this by developing and demonstrating a pilot-scale multi-channel ceramic catalytic membrane reactor system.This system,featuring three 19-channel ceramic catalytic membranes,achieved nearly 100%p-nitrophenol hydrogenation conversion consistently over 600 h of continuous liquid-phase operation.This underscores the superior catalytic efficiency,remarkable long-term stability,and strong scalability of multi-channel ceramic catalytic membrane.This work establishes a robust platform for continuous-flow hydrogenation,providing a solid foundation for practical catalytic membrane reactor technology application in the chemical industry.展开更多
基金supported by the National Natural Science Foundation of China (Grant No.12575180)the Lingchuang Research Project of China National Nuclear Corporation (CNNC)。
文摘From an engineering feasibility standpoint, what level of performance metrics can be ultimately achieved when designing a reactor using well-established nuclear fuels and structural materials that have already undergone irradiation testing? The irradiation capability, which hinges on parameters like neutron flux level, irradiation channels' volume, and fuel cycle duration, is a core indicator for high-flux reactors. We propose a conceptual design of an ultra-high flux fast reactor(UFFR) with strong irradiation capability, which utilizes U-20Pu-10Zr alloy fuel and employs lead-bismuth as the coolant. The maximum neutron flux in the core reaches 1.32×10^(16) cm^(-2)s^(-1), while the average neutron flux in the irradiation channels attains 1.19×10^(16) cm^(-2)s^(-1). The volume of the central irradiation channel exceeds 10000 cm^(3), and the fuel cycle duration is 165 d, placing all its performance indicators among the top in the world. Based on the analyses of reactor physics and thermalhydraulics, it has been demonstrated that all reactivity coefficients are negative and all physical parameters meet the design criteria, ensuring the inherent safety of UFFR. An assessment of the irradiation capability has been carried out based on californium-252(^(252)Cf) production, indicating that the irradiation capability of UFFR surpasses that of the high flux isotope reactor(HFIR). The yield of ^(252)Cf from UFFR is 14.39 times that of HFIR, and its nuclei conversion rate is 3.21 times that of HFIR.
基金supported by Youth Innovation Promotion Association of Chinese Academy of Sciences(No.2020261)Strategic Priority Research Program of Chinese Academy of Sciences(No.XDA02010000)the Young Potential Program of Shanghai Institute of Applied Physics,Chinese Academy of Sciences(No.SINAP-YXJH-202412).
文摘Molten salt reactors,being the only reactor type among Generation Ⅳ advanced nuclear reactors that utilize liquid fuels,offer inherent safety,high-temperature,and low-pressure operation,as well as the capability for online fuel reprocessing.However,the fuel-salt flow results in the decay of delayed neutron precursors(DNPs)outside the core,causing fluctuations in the effective delayed neutron fraction and consequently impacting the reactor reactivity.Particularly in accident scenarios—such as a combined pump shutdown and the inability to rapidly scram the reactor—the sole reliance on negative temperature feedback may cause a significant increase in core temperature,posing a threat to reactor safety.To address these problems,this paper introduces an innovative design for a passive fluid-driven suspended control rod(SCR)to dynamically compensate for reactivity fluctuations caused by DNPs flowing with the fuel.The control rod operates passively by leveraging the combined effects of gravity,buoyancy,and fluid dynamic forces,thereby eliminating the need for an external drive mechanism and enabling direct integration within the active region of the core.Using a 150 MWt thorium-based molten salt reactor as the reference design,we develop a mathematical model to systematically analyze the effects of key parameters—including the geometric dimensions and density of the SCR—on its performance.We examine its motion characteristics under different core flow conditions and assess its feasibility for the dynamic compensation of reactivity changes caused by fuel flow.The results of this study demonstrate that the SCR can effectively counteract reactivity fluctuations induced by fuel flow within molten salt reactors.A sensitivity analysis reveals that the SCR’s average density exerts a profound impact on its start-up flow threshold,channel flow rate,resistance to fuel density fluctuations,and response characteristics.This underscores the critical need to optimize this parameter.Moreover,by judiciously selecting the SCR’s length,number of deployed units,and the placement we can achieve the necessary reactivity control while maintaining a favorable balance between neutron economy and heat transfer performance.Ultimately,this paper provides an innovative solution for the passive reactivity control in molten salt reactors,offering significant potential for practical engineering applications.
基金supported by the National Key Projects for Fundamental Research and development of China(2020YFA0710202)the China Postdoctoral Science Foundation(2024M761567)Shandong Postdoctoral Science Foundation(SDCX-ZG-202400271).
文摘The synthesis of propylene carbonate(PC)from CO_(2) and propylene oxide(PO)is a typical gas-liquid biphasic system,where gas-liquid mass transfer efficiency significantly influences CO_(2) cycloaddition reactions.Here,we proposed a microchannel reaction system for the CO_(2) cycloaddition reaction catalyzed by ionic liquid within an aqueous environment.The effect of liquid flow rate,temperature and residence time on gas-liquid flow pattern,catalytic performance and mass transfer were systematically investigated.The results revealed that the PC generation rate reached 560.11 mmol·ml^(−1)·h^(−1)at a 50 cm of flow distance under reaction conditions of 105℃,2.5 MPa,QG=176 ml·min^(−1) and QL=0.3 ml·min^(−1).Variations in mass transfer rate and reaction rate at different flow distances were experimentally studied.The reaction efficiency gradually decreased with increasing flow distance,which were attributed to the reduction of mass transfer caused by decreasing bubble velocity.Optimizing bubble velocity at an appropriate position enhanced reaction efficiency by improving mass transfer,achieving a 97.7%PC yield within 2.85 min.Furthermore,a kinetic model coupling intrinsic kinetics with gas-liquid mass transfer was developed for CO_(2) cycloaddition reaction.The kinetic model was applied to predict PC reaction rates in microchannel reactors at various temperatures and liquid flow rates,achieving an average relative error of 9.6%.
基金financial support from the Nuclear Energy Science&Technology and Human Resource Development Project of the Japan Atomic Energy Agency/Collaborative Laboratories for Advanced Decommissioning Science(No.R04I034)The author Ruicong Xu appreciates the scholarship(financial support)from the China Scholarship Council(CSC,No.202106380073).
文摘Laser-induced aerosols,predominantly submicron in size,pose significant environmental and health risks during the decommissioning of nuclear reactors.This study experimentally investigated the removal of laser-generated aerosol particles using a water spray system integrated with an innovative system for pre-injecting electrically charged mist in our facility.To simulate aerosol generation in reactor decommissioning,a high-power laser was used to irradiate various materials(including stainless steel,carbon steel,and concrete),generating aerosol particles that were agglomerated with injected water mist and subsequently scavenged by water spray.Experimental results demonstrate enhanced aerosol removal via aerosol-mist agglomeration,with charged mist significantly improving particle capture by increasing wettability and size.The average improvements for the stainless steel,carbon steel,and concrete were 40%,44%,and 21%,respectively.The results of experiments using charged mist with different polarities(both positive and negative)and different surface coatings reveal that the dominant polarity of aerosols varies with the irradiated materials,influenced by their crystal structure and electron emission properties.Notably,surface coatings such as ZrO_(2)and CeO_(2)were found to possibly alter aerosol charging characteristics,thereby affecting aerosol removal efficiency with charged mist configurations.The innovative aerosol-mist agglomeration approach shows promise in mitigating radiation exposure,ensuring environmental safety,and reducing contaminated water during reactor dismantling.This study contributes critical knowledge for the development of advanced aerosol management strategies for nuclear reactor decommissioning.The understanding obtained in this work is also expected to be useful for various environmental and chemical engineering applications such as gas decontamination,air purification,and pollution control.
文摘One of the main issues in designing optimum tapered cascades for uranium enrichment for annual fuel production in a power reactor is whether to employ large(fat)or small(thin)cascades.What will be the permissible and optimal ranges of the number of machines that can be used in a cascade?For the first time,the permissible and optimal ranges of the number of gas centrifuges that can be utilized in a cascade were investigated using two types of centrifuges,and the performance of small and large tapered cascades was discussed.The particle swarm optimization algorithm(PSO)has been used to optimize tapered cascades.The results show:(1)For the first centrifuge,41 cascades(91≤n≤4897)and for the second centrifuge,49 cascades(18≤n≤3839)with small and large sizes can be used in enrichment facilities,and the best cascade for them has 530(with 23 stages)and 39(with 7 stages)centrifuges,respectively.(2)For both centrifuges,when 600≤n(number of centrifuges=n),the large cascade performance changes are relatively insignificant.(3)For both types of gas centrifuges,the annual los s of separation power in enrichment facilities is approximately 1.25%-4.82%of the total separation work required.
基金sponsored by the National Natural Science Foundation of China(No.12305190)Lingchuang Research Project of China National Nuclear Corporation(CNNC).
文摘Medical isotopes are the foundation material for nuclear medicine and are primarily produced through in-reactor irradia-tion.Neutron spectrum regulation is the main technical approach for enhancing the production of medical isotopes,and it requires determining the optimal neutron spectrum and quantifying the values of neutrons in different energy regions.We calculated the neutron energy region values for 20 medical isotopes(^(14)C,^(32)P,^(47)Sc,^(60)Co,^(64)Cu,^(67)Cu,^(89)Sr,^(90)Y,^(99)Mo,^(125)I,^(131)I,^(153)Sm,^(161)Tb,^(166)Ho,^(177)Lu,^(186)Re,^(188)Re,^(92)Ir,^(225)Ac,and ^(252)Cf).The entire energy range was divided into 238 energy regions to improve the energy spectrum resolution,and both fast and thermal reactors were simulated to enhance universal applicability.A dataset of neutron energy region values across the entire energy range was built,which identifies the positive and negative-energy regions and guides the neutron spectrum regulation process during in-reactor medical isotope produc-tion.We conducted neutron spectrum regulation based on this dataset,which effectively improved the production efficiency of medical isotopes and demonstrated the correctness and feasibility of the dataset.
文摘Small modular reactor(SMR)belongs to the research forefront of nuclear reactor technology.Nowadays,advancement of intelligent control technologies paves a new way to the design and build of unmanned SMR.The autonomous control process of SMR can be divided into three stages,say,state diagnosis,autonomous decision-making and coordinated control.In this paper,the autonomous state recognition and task planning of unmanned SMR are investigated.An operating condition recognition method based on the knowledge base of SMR operation is proposed by using the artificial neural network(ANN)technology,which constructs a basis for the state judgment of intelligent reactor control path planning.An improved reinforcement learning path planning algorithm is utilized to implement the path transfer decision-makingThis algorithm performs condition transitions with minimal cost under specified modes.In summary,the full range control path intelligent decision-planning technology of SMR is realized,thus provides some theoretical basis for the design and build of unmanned SMR in the future.
文摘Core power is a key parameter of nuclear reactor.Traditionally,the proportional-integralderivative(PID)controllers are used to control the core power.Fractional-order PID(FOPID)controller represents the cutting edge in core power control research.In comparing with the integer-order models,fractional-order models describe the variation of core power more accurately,thus provide a comprehensive and realistic depiction for the power and state changes of reactor core.However,current fractional-order controllers cannot adjust their parameters dynamically to response the environmental changes or demands.In this paper,we aim at the stable control and dynamic responsiveness of core power.Based on the strong selflearning ability of artificial neural network(ANN),we propose a composite controller combining the ANN and FOPID controller.The FOPID controller is firstly designed and a back propagation neural network(BPNN)is then utilized to optimize the parameters of FOPID.It is shown by simulation that the composite controller enables the real-time parameter tuning via ANN and retains the advantage of FOPID controller.
基金supported by the National Key R&D Program of China(2021YFF0500703)Natural Science Foundation of Shanghai(22JC1404200)+3 种基金Program of Shanghai Academic/Technology Research Leader(20XD1404000)Natural Science Foundation of China(U22B20136,22293023)Science and Technology Major Project of Inner Mongolia(2021ZD0042)the Youth Innovation Promotion Association of CAS。
文摘A radical C−C-coupling reaction of acetonitrile into succinonitrile over hydrophobic TiO_(2) photocatalyst with enhanced catalytic activity was developed.In addition,the usage of a flow reactor further improved the photon utilization efficiency for succinonitrile synthesis at room temperature.The space time yield of succinonitrile reached 55.59μmol/(g·h)over hydrophobic TiO_(2) catalyst,which was much higher than that of pristine TiO_(2)(4.23μmol/(g·h)).Mechanistic studies revealed that the hydrophobic modification of TiO_(2) promoted the separation and transfer of photogenerated carriers,as well as suppressed their recombination.Hydrophobic TiO_(2) also enhanced the adsorption of−CH3 of acetonitrile,thus facilitating the activation of C−H bond and the utilization efficiency of photocarriers.
文摘Based on the service characteristics of fuel elements for molten salt reactors,they need to have a high power density,resistance to coolant infiltration,and excellent thermodynamic properties.To solve the problem of the graphite used in the fuel element for these reactors being susceptible to molten salt infiltration,carbon black(CB)was added to increase the density of the graphite,and a fuel element(TRISO(tri-structural isotropic)fuel particles were randomly distributed in the modified graphite matrix)was prepared by cold isostatic pressing process.An out-of-pile performance study shows that the densification and pore structure of the modified graphite matrix were improved,as was the resistance to molten salt infiltration.The median pore size of the modified graphite was reduced from 673 to 433 nm and the threshold pressure for molten salt(FLiBe,66%(molar fraction)LiF and 34%BeF_(2))infiltration was increased from 0.88 to 1.37 MPa.The isotropic CB made the graphite matrix less anisotropic,while its thermal conductivity and compressive strength were reduced due to the difficult graphitization of CB.Fuel elements containing 20%(volume fraction)TRISO particles were prepared.Numerical simulations show that the power and temperature distribution of the fuel were in line with the design requirements.The modified graphite matrix had a higher density,smaller pores,a lower anisotropy and a greater resistance to FLiBe infiltration.
基金This work was supported by the National Key R&D Program of China(2022YFB4102000 and 2022YFA1505100)the NSFC(22472038)the Shanghai Science and Technology Innovation Action Plan(22dz1205500).
文摘Electrocatalytic carbon dioxide reduction is a promising technology for addressing global energy and environmental crises. However, its practical application faces two critical challenges: the complex and energy-intensive process of separat-ing mixed reduction products and the economic viability of the carbon sources (reactants) used. To tackle these challenges simultaneously, solid-state electrolyte (SSE) reactors are emerging as a promising solution. In this review, we focus on the feasibility of applying SSE for tandem electrochemical CO_(2) capture and conversion. The configurations and fundamental principles of SSE reactors are first discussed, followed by an introduction to its applications in these two specific areas, along with case studies on the implementation of tandem electrolysis. In comparison to conventional H-type cell, flow cell and membrane electrode assembly cell reactors, SSE reactors incorporate gas diffusion electrodes and utilize a solid electro-lyte layer positioned between an anion exchange membrane (AEM) and a cation exchange membrane (CEM). A key inno-vation of this design is the sandwiched SSE layer, which enhances efficient ion transport and facilitates continuous product extraction through a stream of deionized water or humidified nitrogen, effectively separating ion conduction from product collection. During electrolysis, driven by an electric field and concentration gradient, electrochemically generated ions (e.g., HCOO- and CH3COO-) migrate through the AEM into the SSE layer, while protons produced from water oxidation at the anode traverse the CEM into the central chamber to maintain charge balance. Targeted products like HCOOH can form in the middle layer through ionic recombination and are efficiently carried away by the flowing medium through the porous SSE layer, in the absence of electrolyte salt impurities. As CO_(2)RR can generate a series of liquid products, advancements in catalyst discovery over the past several years have facilitated the industrial application of SSE for more efficient chemicals production. Also noteworthy, the cathode reduction reaction can readily consume protons from water, creating a highly al-kaline local environment. SSE reactors are thereby employed to capture acidic CO_(2), forming CO_(3)^(2-) from various gas sources including flue gases. Driven by the electric field, the formed CO_(3)^(2-) can traverse through the AEM and react with protons originating from the anode, thereby regenerating CO_(2). This CO_(2) can then be collected and utilized as a low-cost feedstock for downstream CO_(2) electrolysis. Based on this principle, several cell configurations have been proposed to enhance CO_(2) capture from diverse gas sources. Through the collaboration of two SSE units, tandem electrochemical CO_(2) capture and con-version has been successfully implemented. Finally, we offer insights into the future development of SSE reactors for prac-tical applications aimed at achieving carbon neutrality. We recommend that greater attention be focused on specific aspects, including the fundamental physicochemical properties of the SSE layer, the electrochemical engineering perspective related to ion and species fluxes and selectivity, and the systematic pairing of consecutive CO_(2) capture and conversion units. These efforts aim to further enhance the practical application of SSE reactors within the broader electrochemistry community.
基金partly supported by the University of Shanghai for Science and Technology(No.10-24-301-101)。
文摘Liquid-fueled molten-salt reactors have dynamic features that distinguish them from solid-fueled reactors,such that conventional system-analysis codes are not directly applicable.In this study,a coupled dynamic model of the Molten-Salt Reactor Experiment(MSRE)is developed.The coupled model includes the neutronics and single-phase thermal-hydraulics modeling of the reactor and validated xenon-transport modeling from previous studies.The coupled dynamic model is validated against the frequency-response and transient-response data from the MSRE.The validated model is then applied to study the effects of xenon and void transport on the dynamic behaviors of the reactor.Plant responses during the unique initiating events such as off-gas system blockages and loss of circulating voids are investigated.
基金financially supported by the National Natural Science Foundation of China(22408098 and 22393952)the China Postdoctoral Science Foundation(2024M750908)the National Key Research and Development Program of China(2024YFA1509903)。
文摘This study develops a CFD-ML integrated framework to achieve multi-objective optimization for the partial oxidation of n-butane to maleic anhydride(MA).A reactor-pellet coupled model was established to investigate the effects of four key operating parameters,revealing that inlet temperature dominates reactor performance by increasing MA yield from 35.0%to 37.6%while sharply raising hotspot temperatures by 42 K.The coupled model was then employed to generate 621 cases for training machine learning models,among which the Gaussian Process Regression(GPR)model exhibits superior accuracy.The GPR model was further integrated with the genetic algorithm to generate Pareto-optimal sets.The results indicate that a critical inflection point is identified on the Pareto front,and once this point is exceeded,even a slight increase in MA yield could lead to a sharp rise in the reactor hotspot temperature,thereby increasing the risk of thermal runaway.
基金supported by the Youth Innovation Promotion Association(YIPA)(No.E329290101)of the Chinese Academy of Sciences。
文摘Molten salt reactors(MSRs)are a promising candidate for Generation IV reactor technologies,and the small modular molten salt reactor(SM-MSR),which utilizes low-enriched uranium and thorium fuels,is regarded as a wise development path to accelerate deployment time.Uncertainty and sensitivity analyses of accidents guide nuclear reactor design and safety analyses.Uncertainty analysis can ascertain the safety margin,and sensitivity analysis can reveal the correlation between accident consequences and input parameters.Loss of forced cooling(LOFC)represents an accident scenario of the SM-MSR,and the study of LOFC could offer useful information to improve physical thermohydraulic and structural designs.Therefore,this study investigates the uncertainty of LOFC consequences and the sensitivity of related parameters.The uncertainty of the LOFC consequences was analyzed using the Monte Carlo method,and multiple linear regression was employed to analyze the sensitivity of the input parameters.The uncertainty and sensitivity analyses showed that the maximum reactor outlet fuel salt temperature was 725.5℃,which is lower than the acceptable criterion,and five important parameters influencing LOFC consequences were identified.
基金supported by the National Natural Science Foundation of China(22178361,22378402,52302310)the International Partnership Project of CAS(039GJHZ2022029GC)+5 种基金the National Key R&D Program of China(2020YFA0710200)the foundation of the Innovation Academy for Green Manufacture Institute,Chinese Academy of Sciences(IAGM2022D07)the China Postdoctoral Science Foundation(2022M722597)QinChuangYuan Cites High-level Innovation and Entrepreneurship Talent Programs(QCYRCXM-2022-335)the Fundamental Research Funds for the Central Universities(G2022KY05111)the Open Project Program of Anhui Province International Research Center on Advanced Building Materials(JZCL2303KF)。
文摘Paired electrosynthesis has received considerable attention as a consequence of simultaneously synthesizing target products at both cathode and anode,whereas the related synthetic efficiency in batch reactors is still undesirable under certain circumstances.Encouragingly,laminar microfluidic reactor offers prospective options that possess controllable flow characteristics such as enhanced mass transport,precise laminar flow control and the ability to expand production scale progressively.In this comprehensive review,the underlying fundamentals of the paired electrosynthesis are initially summarized,followed by categorizing the paired electrosynthesis including parallel paired electrosynthesis,divergent paired electrosynthesis,convergent paired electrosynthesis,sequential paired electrosynthesis and linear paired electrosynthesis.Thereafter,a holistic overview of microfluidic reactor equipment,integral fundamentals and research methodology as well as channel extension and scale-up strategies is proposed.The established fundamentals and evaluated metrics further inspired the applications of microfluidic reactors in paired electrosynthesis.This work stimulated the overwhelming investigation of mechanism discovery,material screening strategies,and device assemblies.
基金financial support of the Ministry of Science and Higher Education of the Russian Federation in the framework of the state contract in the field of science(No.FSEG-2024-0005)。
文摘This study discusses the scope of application of the Doppler backscattering(DBS)diagnostic for the tokamak with reactor technologies(TRT)project.This involved numerical modeling of the three-dimensional(3D)beam trajectories.Calculations were performed to investigate the propagation of microwaves in the V(40–75 GHz)and W(75–110 GHz)frequency ranges with O-mode polarization for the density profile of the base TRT scenario.Our analysis showed that the DBS system antenna on the TRT would need to be tilted in both the poloidal and toroidal directions in order to meet the condition Kperp/Kpar<10%..For the DBS system located in the equatorial plane it was shown that a wide range of poloidal and toroidal angles is available for the successful implementation of the diagnostic to study the core,pedestal and scrape-off layer(SOL)regions.The DBS system located at 35 cm above the equatorial plane would be more limited in measurements only covering the SOL and pedestal regions.A shift of the cut-offs in the toroidal direction highlighted the need for 3D analysis of the DBS data.
基金financially supported by the National Natural Science Foundation of China(52025103)。
文摘This study presents a systematic investigation of pressure drop and gas holdup in an upward-flow fixedbed reactor,examining the effects of bubble size,bed height,particle shape,superficial gas velocity(SGV),and superficial liquid velocity(SLV)based on experimental measurements and empirical correlations.Two bubble generators,namely ring tube generator(RTG)and porous sintered film generator(PSG),are used.Key findings reveal that for the PSG,increasing SGV decreases small-bubble population while promoting large-bubble formation,with the bubbles stabilizing at a Sauter mean diameter(d_(32))of~3 mm.The RTG produces stable large bubbles(d_(32)=6—7 mm)with minimal size variations across the range of tested SGVs.The pressure drop decreases with an increase in SGV but increases with higher SLV and bed height,primarily due to the reduced liquid holdup and the dominance of static pressure.Smaller bubbles reduce the pressure drop by slowing rise velocity and minimizing frictional resistance.Clover-shaped particles exhibit the highest pressure drop owing to large porosity,while 3-mm toothed spheres show higher pressure drop than 5-mm spheres at high SGV because of intensified capillary forces.The gas holdup increases with increasing SGV and bed height but decreases slightly with increasing SLV.Smaller bubbles enhance gas holdup by improving bed distribution and residence time.The 3-mm toothed spheres show the highest gas holdup due to stronger capillary trapping,whereas the clover-shaped particles exhibit the lowest.Empirical correlations for pressure drop and gas holdup are developed,yielding calculation errors within±1%and±20%of the experimental values,respectively.
基金supported by the National Key R&D Program of China(2023YFB3809103)the National Natural Science Foundation of China(No.52176203)+2 种基金the Key R&D Project of Shaanxi Province,China(No.2023KXJ-283)the Key R&D Project of Shaanxi Province,China(No.2024CY2-GJHX-19)the“Young Talent Support Plan”of Xi’an Jiaotong University(No.QB-A-JZB2015004)。
文摘Owing to high thermal stability and large reaction enthalpy,Mg H_(2) has high reaction temperatures and sluggish reaction kinetics in the dehydrogenation process,which consumes lots of energy.To achieve hydrogen release with low energy consumption,accelerated reaction rate,and high heating uniformity,this paper proposes a novel method of graphite responsive microwave-assisted thermal management with NaTiO_(x)H catalyst.A multi-physics model of the 5 wt%NaTiO_(x)H catalyzed Mg H_(2) reactor integrated with a microwave generator is developed to investigate the reaction,heat and mass transfer process of hydrogen release.It is found that the graphite responsive microwave heating method could improve the temperature uniformity of reaction bed,reduce the energy consumption by at least 10.71%and save the hydrogen release time by 53.49% compared with the traditional electric heating method.Moreover,the hydrogen desorption thermodynamics could be improved with the increase of microwave power.The hydrogen release time is shortened by 19.55%with the increase of 20 W microwave power.Meanwhile,it is also concluded that the microwave excitation frequency of 2.1 GHz and the graphite content of 2 wt%have better heating performance.Therefore,it can be verified that the graphite responsive microwave heating helps to low-energy and accelerated hydrogen release from MgH_(2) hydrogen storage reactor.
文摘High flux reactors(HFRs)are a special type of research reactor aimed at providing a high neutron flux.Compared with power reactors and other research reactors,HFRs have unique technical features in terms of reactor core design,irradiation capability,and operating characteristics.They can be applied to the irradiation tests of nuclear fuels and materials,radioisotope production,neutron science,and experiments.This paper reviews HFRs,including their development history,technical features,and application areas,as well as trends in the development of new and advanced HFRs.
基金financial support from the National Key R&D Program(2022YFB3805504)the National Natural Science Foundation(U24A20536,U23A20117,22208149,22278209,22178165,21921006)the Natural Science Foundation of Jiangsu Province(BK20220354,BK20211262)of China.
文摘Hydrogenation reactions,vital in chemical engineering,are hampered by limitations including catalyst recovery,mass transfer issues,and scalability.Catalytic membrane reactors offer a promising alternative by integrating reaction and separation,boosting efficiency and simplifying catalyst handling.However,scaling these membranes to industrial levels while ensuring long-term stability and high efficiency remains a significant challenge.This study tackles this by developing and demonstrating a pilot-scale multi-channel ceramic catalytic membrane reactor system.This system,featuring three 19-channel ceramic catalytic membranes,achieved nearly 100%p-nitrophenol hydrogenation conversion consistently over 600 h of continuous liquid-phase operation.This underscores the superior catalytic efficiency,remarkable long-term stability,and strong scalability of multi-channel ceramic catalytic membrane.This work establishes a robust platform for continuous-flow hydrogenation,providing a solid foundation for practical catalytic membrane reactor technology application in the chemical industry.
