The concept of local shock strength and a quantitative measure index str of local shock strength are proposed,derived from the oblique shock relation and the monotonic relationship between total pressure loss ratio an...The concept of local shock strength and a quantitative measure index str of local shock strength are proposed,derived from the oblique shock relation and the monotonic relationship between total pressure loss ratio and normal Mach number.Utilizing the high density gradient characteristic of shock waves and the oblique shock relation,a post-processing algorithm for two-dimensional flow field data is developed.The objective of the post-processing algorithm is to obtain specific shock wave location coordinates and calculate the corresponding str from flow filed data under the calibration of the oblique shock relation.Valida-tion of this post-processing algorithm is conducted using a standard model example that can be solved analytically.Combining the concept of local shock strength with the post-processing algorithm,a local shock strength quantitative mapping approach is established for the first time.This approach enables a quantitative measure and visualization of local shock strength at distinct locations,represented by color mapping on the shock structures.The approach can be applied to post-processing numerical sim-ulation data of two-dimensional flows.Applications to the intersection of two left-running oblique shock waves(straight shock waves),the bow shock in front of a cylinder(curved shock wave),and Mach reflection(mixed straight and curved shock waves)demonstrate the accuracy,and effectiveness of the mapping approach in investigating diverse shock wave phenomena.The quan-titative mapping approach of str may be a valuable tool in the design of supersonic/hypersonic vehicles and the exploration of shock wave evolution.展开更多
A modified surface layer was formed on Ti-6Al-4V alloy by wet peening treatment. The variations of the residual stress,nano-hardness and microstructure of the modified layer with depth from surface were studied using ...A modified surface layer was formed on Ti-6Al-4V alloy by wet peening treatment. The variations of the residual stress,nano-hardness and microstructure of the modified layer with depth from surface were studied using X-ray diffraction analysis,nano-indentation analysis, scanning electron microscopy and transmission electron microscopy observations. The results show thatboth the compressive residual stress and hardness decrease with increasing depth, and the termination depths are 160 and 80 μm,respectively. The microstructure observation indicates that within 80 μm, the compressive residual stress and the hardness areenhanced by the co-action of the grain refinement strengthening and dislocation strengthening. Within 80–160 μm, the compressiveresidual stress mainly derives from the dislocation strengthening. The strengthened layer in Ti-6Al-4V alloy after wet peeningtreatment was quantitatively analyzed by a revised equation with respect to a relation between hardness and yield strength.展开更多
Employing an ideal elasto-plastic model,the typically used strength reduction method reduced the strength of all soil elements of a slope.Therefore,this method was called the global strength reduction method(GSRM).How...Employing an ideal elasto-plastic model,the typically used strength reduction method reduced the strength of all soil elements of a slope.Therefore,this method was called the global strength reduction method(GSRM).However,the deformation field obtained by GSRM could not reflect the real deformation of a slope when the slope became unstable.For most slopes,failure occurs once the strength of some regional soil is sufficiently weakened; thus,the local strength reduction method(LSRM)was proposed to analyze slope stability.In contrast with GSRM,LSRM only reduces the strength of local soil,while the strength of other soil remains unchanged.Therefore,deformation by LSRM is more reasonable than that by GSRM.In addition,the accuracy of the slope's deformation depends on the constitutive model to a large degree,and the variable-modulus elasto-plastic model was thus adopted.This constitutive model was an improvement of the Duncan–Chang model,which modified soil's deformation modulus according to stress level,and it thus better reflected the plastic feature of soil.Most importantly,the parameters of the variable-modulus elasto-plastic model could be determined through in-situ tests,and parameters determination by plate loading test and pressuremeter test were introduced.Therefore,it is easy to put this model into practice.Finally,LSRM and the variable-modulus elasto-plastic model were used to analyze Egongdai ancient landslide.Safety factor,deformation field,and optimal reinforcement measures for Egongdai ancient landslide were obtained based on the proposed method.展开更多
View synthesis is an important building block in three dimension（3D） video processing and communications.Based on one or several views,view synthesis creates other views for the purpose of view prediction（for compr...View synthesis is an important building block in three dimension（3D） video processing and communications.Based on one or several views,view synthesis creates other views for the purpose of view prediction（for compression） or view rendering（for multiview-display）.The quality of view synthesis depends on how one fills the occlusion area as well as how the pixels are created.Consequently,luminance adjustment and hole filling are two key issues in view synthesis.In this paper,two views are used to produce an arbitrary virtual synthesized view.One view is merged into another view using a local luminance adjustment method,based on local neighborhood region for the calculation of adjustment coefficient.Moreover,a maximum neighborhood spreading strength hole filling method is presented to deal with the micro texture structure when the hole is being filled.For each pixel at the hole boundary,its neighborhood pixels with the maximum spreading strength direction are selected as candidates;and among them,the pixel with the maximum spreading strength is used to fill the hole from boundary to center.If there still exist disocclusion pixels after once scan,the filling process is repeated until all hole pixels are filled.Simulation results show that the proposed method is efficient,robust and achieves high performance in subjection and objection.展开更多
Stress relaxation of glass is a dualism effect, it often lead to strength degradation in strengthened glass, but on the other hand, it improves the reliability and stress-uniformity of glasses. In this work, stress re...Stress relaxation of glass is a dualism effect, it often lead to strength degradation in strengthened glass, but on the other hand, it improves the reliability and stress-uniformity of glasses. In this work, stress relaxation of soda-lime glass was investigated using three-point bending tests at 400-560℃ which is near the brittle to ductile transition temperature, for enhancing the safety of glass productions and exploring the most economic anneal process. The experimental results show that the speed of stress relaxation increases but the ultimate stress decreases with increasing temperature. The stress uniformity of the glass samples before and after anneal was examined using spherical indentation at arranged testing points. It indicates that the scatter of the local strength measured by the Hertzian indentation is smaller in the anneal glass than in initial specimen, so that the estimated Weibull modulus for the anneal specimen is higher. Furthermore, the strength evaluation by Hertzian indentation and statistical analysis was presented.展开更多
Solid-aqueous interfaces and phenomena occurring at those interfaces are ubiquitously found in a plethora of chemical systems.When it comes to heterogeneous catalysis,however,our understanding of chemical transformati...Solid-aqueous interfaces and phenomena occurring at those interfaces are ubiquitously found in a plethora of chemical systems.When it comes to heterogeneous catalysis,however,our understanding of chemical transformations at solid-aqueous interfaces is relatively limited and primitive.This review phenomenologically describes a selection of water-engendered effects on the catalytic behavior for several prototypical acid-base-catalyzed reactions over solid catalysts,and critically assesses the general and special roles of water molecules,structural moieties derived from water,and ionic species that are dissolved in it,with an aim to extract novel concepts and principles that underpin heterogeneous acid-base catalysis in the aqueous phase.For alcohol dehydration catalyzed by solid Bronsted acids,rate inhibition by water is most typically related to the decrease in the acid strength and/or the preferential solvation of adsorbed species over the transition state as water molecules progressively solvate the acid site and form extended networks wherein protons are mobilized.Water also inhibits dehydration kinetics over most Lewis acid-base catalysts by competitive adsorption,but a few scattered reports reveal substantial rate enhancements due to the conversion of Lewis acid sites to Brønsted acid sites with higher catalytic activities upon the introduction of water.For aldol condensation on catalysts exposing Lewis acid-base pairs,the addition of water is generally observed to enhance the rate when C–C coupling is rate-limiting,but may result in rate inhibition by site-blocking when the initial unimolecular deprotonation is rate-limiting.Water can also promote aldol condensation on Brønsted acidic catalysts by facilitating inter-site communication between acid sites through hydrogen-bonding interactions.For metallozeolite-catalyzed sugar isomerization in aqueous media,the nucleation and networking of intrapore waters regulated by hydrophilic entities causes characteristic enthalpy-entropy tradeoffs as these water moieties interact with kinetically relevant hydride transfer transition states.The discussed examples collectively highlight the utmost importance of hydrogen-bonding interactions and ionization of covalently bonded surface moieties as the main factors underlying the uniqueness of water-mediated interfacial acid-base chemistries and the associated solvation effects in the aqueous phase or in the presence of water.A perspective is also provided for future research in this vibrant field.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.12372233)the Fund of NPU-Duke China Seed Program(Grant No.119003067)the“111 Project”of China(Grant No.B17037-106).
文摘The concept of local shock strength and a quantitative measure index str of local shock strength are proposed,derived from the oblique shock relation and the monotonic relationship between total pressure loss ratio and normal Mach number.Utilizing the high density gradient characteristic of shock waves and the oblique shock relation,a post-processing algorithm for two-dimensional flow field data is developed.The objective of the post-processing algorithm is to obtain specific shock wave location coordinates and calculate the corresponding str from flow filed data under the calibration of the oblique shock relation.Valida-tion of this post-processing algorithm is conducted using a standard model example that can be solved analytically.Combining the concept of local shock strength with the post-processing algorithm,a local shock strength quantitative mapping approach is established for the first time.This approach enables a quantitative measure and visualization of local shock strength at distinct locations,represented by color mapping on the shock structures.The approach can be applied to post-processing numerical sim-ulation data of two-dimensional flows.Applications to the intersection of two left-running oblique shock waves(straight shock waves),the bow shock in front of a cylinder(curved shock wave),and Mach reflection(mixed straight and curved shock waves)demonstrate the accuracy,and effectiveness of the mapping approach in investigating diverse shock wave phenomena.The quan-titative mapping approach of str may be a valuable tool in the design of supersonic/hypersonic vehicles and the exploration of shock wave evolution.
基金Project(51405059)supported by the National Natural Science Foundation of ChinaProject(2014M551074)supported by the China Postdoctoral Science FoundationProject(NCET-10-0278)supported by the Program for New Century Excellent Talents in University
文摘A modified surface layer was formed on Ti-6Al-4V alloy by wet peening treatment. The variations of the residual stress,nano-hardness and microstructure of the modified layer with depth from surface were studied using X-ray diffraction analysis,nano-indentation analysis, scanning electron microscopy and transmission electron microscopy observations. The results show thatboth the compressive residual stress and hardness decrease with increasing depth, and the termination depths are 160 and 80 μm,respectively. The microstructure observation indicates that within 80 μm, the compressive residual stress and the hardness areenhanced by the co-action of the grain refinement strengthening and dislocation strengthening. Within 80–160 μm, the compressiveresidual stress mainly derives from the dislocation strengthening. The strengthened layer in Ti-6Al-4V alloy after wet peeningtreatment was quantitatively analyzed by a revised equation with respect to a relation between hardness and yield strength.
基金Project([2005]205)supported by the Science and Technology Planning Project of Water Resources Department of Guangdong Province,ChinaProject(2012-7)supported by Guangdong Bureau of Highway Administration,ChinaProject(2012210020203)supported by the Fundamental Research Funds for the Central Universities,China
文摘Employing an ideal elasto-plastic model,the typically used strength reduction method reduced the strength of all soil elements of a slope.Therefore,this method was called the global strength reduction method(GSRM).However,the deformation field obtained by GSRM could not reflect the real deformation of a slope when the slope became unstable.For most slopes,failure occurs once the strength of some regional soil is sufficiently weakened; thus,the local strength reduction method(LSRM)was proposed to analyze slope stability.In contrast with GSRM,LSRM only reduces the strength of local soil,while the strength of other soil remains unchanged.Therefore,deformation by LSRM is more reasonable than that by GSRM.In addition,the accuracy of the slope's deformation depends on the constitutive model to a large degree,and the variable-modulus elasto-plastic model was thus adopted.This constitutive model was an improvement of the Duncan–Chang model,which modified soil's deformation modulus according to stress level,and it thus better reflected the plastic feature of soil.Most importantly,the parameters of the variable-modulus elasto-plastic model could be determined through in-situ tests,and parameters determination by plate loading test and pressuremeter test were introduced.Therefore,it is easy to put this model into practice.Finally,LSRM and the variable-modulus elasto-plastic model were used to analyze Egongdai ancient landslide.Safety factor,deformation field,and optimal reinforcement measures for Egongdai ancient landslide were obtained based on the proposed method.
基金supported by the National Natural Science Foundation of China(61075013)
文摘View synthesis is an important building block in three dimension（3D） video processing and communications.Based on one or several views,view synthesis creates other views for the purpose of view prediction（for compression） or view rendering（for multiview-display）.The quality of view synthesis depends on how one fills the occlusion area as well as how the pixels are created.Consequently,luminance adjustment and hole filling are two key issues in view synthesis.In this paper,two views are used to produce an arbitrary virtual synthesized view.One view is merged into another view using a local luminance adjustment method,based on local neighborhood region for the calculation of adjustment coefficient.Moreover,a maximum neighborhood spreading strength hole filling method is presented to deal with the micro texture structure when the hole is being filled.For each pixel at the hole boundary,its neighborhood pixels with the maximum spreading strength direction are selected as candidates;and among them,the pixel with the maximum spreading strength is used to fill the hole from boundary to center.If there still exist disocclusion pixels after once scan,the filling process is repeated until all hole pixels are filled.Simulation results show that the proposed method is efficient,robust and achieves high performance in subjection and objection.
基金supported by the National Outstanding Young Scientist Foundation(No.50125204)National High Technical Research and Development Programme of China(No.A339010).
文摘Stress relaxation of glass is a dualism effect, it often lead to strength degradation in strengthened glass, but on the other hand, it improves the reliability and stress-uniformity of glasses. In this work, stress relaxation of soda-lime glass was investigated using three-point bending tests at 400-560℃ which is near the brittle to ductile transition temperature, for enhancing the safety of glass productions and exploring the most economic anneal process. The experimental results show that the speed of stress relaxation increases but the ultimate stress decreases with increasing temperature. The stress uniformity of the glass samples before and after anneal was examined using spherical indentation at arranged testing points. It indicates that the scatter of the local strength measured by the Hertzian indentation is smaller in the anneal glass than in initial specimen, so that the estimated Weibull modulus for the anneal specimen is higher. Furthermore, the strength evaluation by Hertzian indentation and statistical analysis was presented.
文摘Solid-aqueous interfaces and phenomena occurring at those interfaces are ubiquitously found in a plethora of chemical systems.When it comes to heterogeneous catalysis,however,our understanding of chemical transformations at solid-aqueous interfaces is relatively limited and primitive.This review phenomenologically describes a selection of water-engendered effects on the catalytic behavior for several prototypical acid-base-catalyzed reactions over solid catalysts,and critically assesses the general and special roles of water molecules,structural moieties derived from water,and ionic species that are dissolved in it,with an aim to extract novel concepts and principles that underpin heterogeneous acid-base catalysis in the aqueous phase.For alcohol dehydration catalyzed by solid Bronsted acids,rate inhibition by water is most typically related to the decrease in the acid strength and/or the preferential solvation of adsorbed species over the transition state as water molecules progressively solvate the acid site and form extended networks wherein protons are mobilized.Water also inhibits dehydration kinetics over most Lewis acid-base catalysts by competitive adsorption,but a few scattered reports reveal substantial rate enhancements due to the conversion of Lewis acid sites to Brønsted acid sites with higher catalytic activities upon the introduction of water.For aldol condensation on catalysts exposing Lewis acid-base pairs,the addition of water is generally observed to enhance the rate when C–C coupling is rate-limiting,but may result in rate inhibition by site-blocking when the initial unimolecular deprotonation is rate-limiting.Water can also promote aldol condensation on Brønsted acidic catalysts by facilitating inter-site communication between acid sites through hydrogen-bonding interactions.For metallozeolite-catalyzed sugar isomerization in aqueous media,the nucleation and networking of intrapore waters regulated by hydrophilic entities causes characteristic enthalpy-entropy tradeoffs as these water moieties interact with kinetically relevant hydride transfer transition states.The discussed examples collectively highlight the utmost importance of hydrogen-bonding interactions and ionization of covalently bonded surface moieties as the main factors underlying the uniqueness of water-mediated interfacial acid-base chemistries and the associated solvation effects in the aqueous phase or in the presence of water.A perspective is also provided for future research in this vibrant field.
