Visible and infrared(RGB-IR)fusion object detection plays an important role in security,disaster relief,etc.In recent years,deep-learning-based RGB-IR fusion detection methods have been developing rapidly,but still st...Visible and infrared(RGB-IR)fusion object detection plays an important role in security,disaster relief,etc.In recent years,deep-learning-based RGB-IR fusion detection methods have been developing rapidly,but still struggle to deal with the complex and changing scenarios captured by drones,mainly due to two reasons:(A)RGB-IR fusion detectors are susceptible to inferior inputs that degrade performance and stability.(B)RGB-IR fusion detectors are susceptible to redundant features that reduce accuracy and efficiency.In this paper,an innovative RGB-IR fusion detection framework based on global-local feature optimization,named GLFDet,is proposed to improve the detection performance and efficiency of drone-captured objects.The key components of GLFDet include a Global Feature Optimization(GFO)module,a Local Feature Optimization(LFO)module and a Channel Separation Fusion(CSF)module.Specifically,GFO calculates the information content of the input image from the frequency domain and optimizes the features holistically.Then,LFO dynamically selects high-value features and filters out low-value features before fusion,which significantly improves the efficiency of fusion.Finally,CSF fuses the RGB and IR features across the corresponding channels,which avoids the rearrangement of the channel relationships and enhances the model stability.Extensive experimental results show that the proposed method achieves the best performance on three popular RGB-IR datasets Drone Vehicle,VEDAI,and LLVIP.In addition,GLFDet is more lightweight than other comparable models,making it more appealing to edge devices such as drones.The code is available at https://github.com/lao chen330/GLFDet.展开更多
Background and Objectives:The perception of sound in the vertical plane supports spatial hearing by enabling listeners to detect sources located above and below.Sounds originating from both the front and back elevatio...Background and Objectives:The perception of sound in the vertical plane supports spatial hearing by enabling listeners to detect sources located above and below.Sounds originating from both the front and back elevations along the mid-sagittal plane further contribute to a three-dimensional auditory experience.This study aimed to characterize the variability in vertical sound localization abilities among normal-hearing(NH)individuals using spatialized audio.Materials and Methods:Fifty-one NH participants(aged 18 to 35 years)completed three vertical localization tasks under headphones as part of a single-group,within-subject experimental study.These tasks included two-plane identification:(1)top-down localization,(2)front-back localization,and one discrimination task in the front plane.Hierarchical Cluster Analysis(HCA)was employed to identify distinct patterns in spatial localization profiles specific to the vertical-median plane.Fisher's Discriminant Function Analysis(FDA)was used to validate the accuracy of HCA and estimate classification error.Results:HCA revealed three distinct listener clusters:(1)cluster 1 with good performance across all three tasks,(2)cluster 2 with selective impairment in top-bottom identification,and(3)cluster 3 with selective deficits in front-back identification.FDA validated group membership of the clusters identified by the HCA,with a prediction accuracy of 98%.Conclusions:Individuals with clinically NH exhibited three distinct vertical localization profiles:uniform performers,those impaired in top-bottom identification,and those impaired in front-back identification.These profiles may be linked to the interplay between acoustic and non-acoustic perceptual factors.展开更多
The application potential of tuning two-dimensional materials(2DMs)characteristics through strain engineering for wearable and flexible devices has been widely recognized.However,the challenges lie in achieving accura...The application potential of tuning two-dimensional materials(2DMs)characteristics through strain engineering for wearable and flexible devices has been widely recognized.However,the challenges lie in achieving accurate deterministic positioning,spatial modulation,controllable magnitude,and permanent nanostrains.Herein,motivated by the skin swelling caused by mosquito bites,a technique utilizing the heated nanotip in atomic force microscopy for thermomechanical nanoindentation is demonstrated.This method enables precise positioning of localized nanostrain and regulation of bandgap in tungsten diselenide(WSe_(2))/molybdenum disulfide(MoS_(2))heterobilayer transferred onto a flexible polymethyl methacrylate film.The magnitude of strain in the WSe_(2)/MoS_(2) heterobilayer can be controlled by adjusting the parameters of nanoindentation,leading to a spatially modulated average strain of up to 2.5%on the ring-shaped expansion structure(RES).The local bandgap of the WSe_(2)/MoS_(2) heterobilayer is spatially regulated through three distinct regions.In particular,the RES exhibits the largest extent of bandgap modulation,accompanied by a significant change of~12 meV.The nanostrain significantly enhances the photoresponse speed of the photodetector device.For instance,under illumination from a 405 nm wavelength-laser,the rise time and fall time are reduced by 75%and 87.52%,respectively,compared to the device without strain.Similarly,under illumination from a 532 nm wavelength-laser,the rise time and fall time are reduced by 66.67%and 80.60%,respectively.These findings demonstrate that the proposed method serves as a versatile way for improving the photoresponse of optoelectronic devices based on 2DMs.展开更多
This paper proposes a tamper detection technique for semi-fragile watermarking using Quantizationbased Discrete Cosine Transform(DCT)for tamper localization.In this study,the proposed embedding strategy is investigate...This paper proposes a tamper detection technique for semi-fragile watermarking using Quantizationbased Discrete Cosine Transform(DCT)for tamper localization.In this study,the proposed embedding strategy is investigated by experimental tests over the diagonal order of the DCT coefficients.The cover image is divided into non-overlapping blocks of size 8×8 pixels.The DCT is applied to each block,and the coefficients are arranged using a zig-zag pattern within the block.In this study,the low-frequency coefficients are selected to examine the impact of the imperceptibility score and tamper detection accuracy.High accuracy of tamper detection can be achieved by checking the surrounding blocks to determine whether the corresponding block has been tampered with.The proposed tamper detection is tested under various malicious,incidental,and hybrid attacks(both incidental and malicious attacks).The experimental results demonstrate that the proposed technique achieves a Peak-Signal-to-Noise Ratio(PSNR)value of 41.2318 dB,an average Structural Similarity Index Measure(SSIM)value of 0.9768.The proposed scheme is also evaluated against malicious attacks such as copy-move,object deletion,object manipulation,and collage attacks.The proposed scheme can detect the malicious attack localization under various tampering rates.In addition,the proposed scheme can still detect tampered pixels under a hybrid attack,such as a combination ofmalicious and incidental attacks,with an average accuracy of 96.44%.展开更多
In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally r...In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally resonant effect,which contains two parts:the first part is induced by translation coupling,and the second part is induced by rotation coupling.The second part cannot be reflected by most existing theoretical models.The analytical solutions of the dynamic response are compared with the direct numerical simulation(DNS)results for two locally resonant plates with different resonator types,thereby validating the general applicability of the present model.The rotation coupling effect leads to the frequency-dependent effective rotational inertia density and anisotropic dispersion relation of the locally resonant plate,as well as the enhancement of the structural vibration suppression ability.展开更多
The acquisition of position information of legitimate users and jammers plays an important role in the emerging non-geostationary synchronous orbit(NGSO)satellite communications.In this paper,we study the multi-signal...The acquisition of position information of legitimate users and jammers plays an important role in the emerging non-geostationary synchronous orbit(NGSO)satellite communications.In this paper,we study the multi-signal localization problem in an uplink NGSO satellite communication system.We propose an onboard localization scheme based on multiple observations from the satellite,together with the geometric constraints of the satellite postions,the signal positions,the attitude of the satellite,and the angle-of-arrival(AoAs)of the signals.We develop a massage-passing algorithm,termed the Bayesian blind multi-signal localization(BMSL),to jointly estimate the AoAs and the signal positions.The Cramér-Rao lower bound(CRLB)is derived to characterize the fundamental performance limit of the considered localization problem.Simulation results show that the proposed BMSL algorithm can perform close to the derived CRLB and significantly outperforms its counterpart algorithms.展开更多
Localized high-concentration electrolytes(LHCEs)are considered as promising electrolyte candidates to resolve technical issues of metal batteries owing to their unique interfacial properties and solvation structures.H...Localized high-concentration electrolytes(LHCEs)are considered as promising electrolyte candidates to resolve technical issues of metal batteries owing to their unique interfacial properties and solvation structures.Herein,we propose a self-assembly chemical strategy into the LCHEs induced by ordered nanostructure of zwitterionic co-solutes for highly efficient and ultrastable zinc(Zn)metal batteries.Through the systematic screening of six zwitterionic compounds,3-(decyldimethylammonio)propanesulfonate salt(C_(10))with the decyl chain and zwitterions was determined as an optimum to construct quasi-spherical aggregates with a periodic length of 3.77 nm,as confirmed by comprehensive synchronous small-angle X-ray scattering,Guinier,pair distance distribution function,Porod,and other spectroscopic characterizations and molecular dynamic simulation.In particularly,this self-assembled structure in electrolyte environments was attributed to increasing the proportion of both contact and aggregated ion pairs for the formation of LHCEs as well as to providing fast and selective Zn^(2+)conducting channels and uniform solid electrolyte interfaces for facilitated charge transfer kinetics.Moreover,the preferential adsorption of the self-assembled C_(10)on the Zn(002)surface modulated the electrical double layer to suppress hydrogen evolution and corrosion reactions.Consequently,the Zn‖Zn symmetric cells in Zn(OTf)_(2)/C_(10)electrolytes showed long-term plating/stripping behaviors over 2800 h at 1 mA cm^(-2)and 1 mAh cm^(-2)as well as over 1200 h even at 5 mA cm^(-2)and 5 mAh cm^(-2)with a very high depth of discharge of 42.7%.Furthermore,the ZnllVO_(2)/CNT full cells in Zn(OTf)_(2)/C_(10)electrolytes delivered a record-high capacity of 8.10 mAh cm^(-2)at an ultrahigh cathode mass loading of 50 mg cm^(-2)after 150 cycles.展开更多
The stator of the maglev track plays a crucial role in the operation of the maglev system.Currently,the efficiency of maglev track inspection is limited by several factors,including the large span of elevated structur...The stator of the maglev track plays a crucial role in the operation of the maglev system.Currently,the efficiency of maglev track inspection is limited by several factors,including the large span of elevated structures,manual visual inspection,short inspection window times,and limited GPS positioning accuracy.To address these issues,this paper proposes a deep learning-based method for detecting and locating stator surface damage.This study establishes a maglev track stator surface image dataset,trains different object detection models,and compares their performance.Ultimately,YOLO and ByteTrack object tracking algorithms were chosen as the basic framework and enhanced to achieve automatic identification of high-speed maglev track stator surface damage images and track and count stator surface localization feature images.By matching the identified damaged images with their corresponding stator segment and beam segment sequence numbers,the location of the damage is pinpointed to the corresponding stator segment,enabling rapid and accurate identification and localization of complex damage to the maglev track stator surface.展开更多
In this article,we introduce a new theoretical approach to improve the accuracy of twodimensional(2D)atomic localization within a tripod-type,four-level atomic system by analyzing its transmission spectrum.In this met...In this article,we introduce a new theoretical approach to improve the accuracy of twodimensional(2D)atomic localization within a tripod-type,four-level atomic system by analyzing its transmission spectrum.In this method,the atom interacts with two orthogonal standing-wave fields and a weak probe field.By examining how the weak probe field passes through the system,we can determine the atom position.Our analysis reveals the presence of both double and sharply defined single localized peaks in the transmission spectrum,which correspond to specific positions of the atom.Importantly,we achieve ultra-high-resolution atomic localization with accuracy confined to a region smaller thanλ/32×λ/32.This level of precision is a significant improvement compared to earlier methods,which had lower localization accuracy.The increased precision is due to the complex interaction between the atom and the carefully controlled standing-wave and probe fields,which allows for precise control over the atom's position.The implications of this work are significant,especially for applications like nano-lithography,where precise atomic placement is essential,and for laser cooling technologies,where better atomic localization could lead to more effective cooling processes and improved manipulation of atomic states.展开更多
Binary segmentation tasks in computer vision exhibit diverse appearance distributions and complex boundary characteristics.To address the limited generalization and adaptability of existing models across heterogeneous...Binary segmentation tasks in computer vision exhibit diverse appearance distributions and complex boundary characteristics.To address the limited generalization and adaptability of existing models across heterogeneous tasks,we propose Abel-Net,an Aggregated Bilateral Edge Localization Network designed as a universal framework formulti-task binary segmentation.Abel-Net integrates global and local contextual cues to enhance feature learning and edge precision.Specifically,amulti-scale feature pyramid fusion strategy is implemented via anAggregated Skip Connection(ASC)module to strengthen feature adaptability,while the Edge Dual Localization(EDL)mechanism performs coarse-to-fine refinement through edge-aware supervision.Additionally,Edge Attention(EA)and Edge Fusion Attention(EFA)modules prioritize edge-critical regions and facilitate accurate boundary alignment.Extensive experiments on nine diverse binary segmentation tasks demonstrate thatAbel-Net performs comparably to or surpasses state-of-the-art task-specific networks,exhibiting strong adaptability to a wide range of visual perception challenges.展开更多
Granular materials exhibit complex macroscopic mechanical behaviors closely related to their microscalemicrostructural features.Traditional macroscopic phenomenological elasto-plastic models,however,usually have compl...Granular materials exhibit complex macroscopic mechanical behaviors closely related to their microscalemicrostructural features.Traditional macroscopic phenomenological elasto-plastic models,however,usually have complex formulations and lack explicit relations to these microstructural features.To avoid these limitations,this study proposes a micromechanics-based softening hyperelastic model for granular materials,integrating softening hyperelasticity withmicrostructural insights to capture strain softening,critical state,and strain localization behaviors.The model has two key advantages:(1)a clear conceptualization,straightforward formulation,and ease of numerical implementation(via Abaqus UMAT subroutine in this study);(2)explicit incorporation of micro-scale features(e.g.,contact stiffness,particle size,porosity)to reveal their influences on macroscopic responses.An isotropic directional distribution density of contacts and three specific microstructures are considered,and their softening hyperelastic constitutive modulus tensors are explicitly derived.By introducing a softening factor and critical failure energy density,the model can describe geomaterial behaviors,simulating residual strength,X-shaped shear bands,and strain localization evolution.Numerical validations in comparison with themacro-scale hyperelastic model,Abaqus Drucker-Prager model,and the experiment confirm its accuracy.Parametric studies reveal critical dependencies:a normal to tangential contact stiffness ratio of 2-8(depending on stiffness magnitude),an internal length of 2-4 mm to ensure shear band formation,and a critical failure energy density(≤10 kJ/m^(3))to trigger strain softening and localization.Influences of the specific microstructures on strain localization and softening are investigated.The model also shows mesh independence due to the introduction of an internal length.The model’s applicability is further demonstrated by slope stability analysis,capturing slip surface evolution,and load-displacement characteristics.This study develops a robust microstructure-aware hyperelastic framework to describe the mechanical behaviors of granular materials,providing multiscale insights for geotechnical engineering applications.展开更多
This paper provides a systematic review of the histochemical localization,content characteristics,and influencing factors of saponins in Pseudostellaria heterophylla based on an extensive literature survey.It provides...This paper provides a systematic review of the histochemical localization,content characteristics,and influencing factors of saponins in Pseudostellaria heterophylla based on an extensive literature survey.It provides an in-depth analysis and summary of the effects of biological factors,environmental conditions,agronomic practices,processing methods,and continuous cropping obstacles on the synthesis of P.heterophylla saponins,as well as their underlying mechanisms.Based on identified gaps in the current literature,future research directions and prospects are proposed.The findings of this review offer valuable insights for advancing the understanding of the saponin biosynthesis mechanisms in P.heterophylla and for enhancing its quality.展开更多
Summary Pain is not pain because people interpret symptoms differently.Neck pain is one of the most common pains and should not be missing from a study on the effects of pain.Depression does not arise solely from pain...Summary Pain is not pain because people interpret symptoms differently.Neck pain is one of the most common pains and should not be missing from a study on the effects of pain.Depression does not arise solely from pain but is multicausal and often caused by this cumulative effect.展开更多
This paper investigates the following mixed local and nonlocal elliptic problem fea-turing concave-convex nonlinearities and a discontinuous right-hand side:{L(u)=H(u−μ)|u|^(p−2)u+λ|u|^(q−2)u,x∈Ω,u≥0,x∈Ω,u=0,x...This paper investigates the following mixed local and nonlocal elliptic problem fea-turing concave-convex nonlinearities and a discontinuous right-hand side:{L(u)=H(u−μ)|u|^(p−2)u+λ|u|^(q−2)u,x∈Ω,u≥0,x∈Ω,u=0,x∈R^(N)\Ω,where Ω ⊂R^(N)(N>2)is a bounded domain,μ≥0 and λ>0 are real parameters,H denotes the Heaviside function(H(t)=0 for t<0,H(t)=1 for t>0),and the mixed local and nolocal operator is defined as L(u)=−Δu+(−Δ)^(s)u with(−Δ)^(s) being the restricted fractional Laplace(0<s<1).The exponents satisfy 1<q<2<p.By employing a novel non-smooth variational principle,we establish the existence of an M-solution for this problem and identify a range for the exponent p.展开更多
A multi-stage stress relaxation test was performed on a granodiorite sample to understand the deformation process prior to the macroscopic failure of brittle rocks,as well as the transient response during stress relax...A multi-stage stress relaxation test was performed on a granodiorite sample to understand the deformation process prior to the macroscopic failure of brittle rocks,as well as the transient response during stress relaxation.Distributed optical fiber sensing was used to measure strains across the sample surface by helically wrapping the single-mode fiber around the cylindrical sample.Close agreement was observed between the circumferential strains obtained from the optical fibers and the extensometer.The reconstructed full-field strain contours show strain heterogeneity from the crack closure phase,and the strains in the later deformation phase are dominantly localized within the former high-strain zone.The Gini coefficient was used to quantify the degree of strain localization and shows an initial increase during the crack closure phase,a decrease during the linear elastic phase,and a subsequent increase during the post-yielding phase.This behavior corresponds to a process of initial localization from an imperfect boundary condition,homogenization,and eventual relocalization prior to the macroscopic failure of the sample.The transient strain rate decay during the stress relaxation phase was quantified using the p-value in the“Omori-like"power law function.A higher initial stress at the onset of relaxation results in a lower p-value,indicating a slower strain rate decay.As the sample approaches macroscopic failure,the lowest p-value shifts from the most damaged zone to adjacent areas,suggesting stress redistribution or crack propagation in deformed crystalline rocks under stress relaxation conditions.展开更多
Despite remarkable advances in nanomedicine,localized delivery of advanced cancer therapeutics remains underexploited.Advanced therapies based on biopharmaceuticals,immunotherapy,or gene therapy have revolutionized on...Despite remarkable advances in nanomedicine,localized delivery of advanced cancer therapeutics remains underexploited.Advanced therapies based on biopharmaceuticals,immunotherapy,or gene therapy have revolutionized oncology.Yet,their systemic administration is often associated with limitations such as poor sitespecific accumulation,instability,and systemic toxicity.Hydrogels/macrogels offer the ability to encapsulate,protect,and release biomolecules in situ with sustained and stimulus-responsive profiles,addressing key translational gaps.This review provides a focused synthesis of the last five years of hydrogel-based research for cancer therapy,with emphasis on peptides,antibodies,immunotherapeutic agents,and gene delivery systems.We discuss design principles,release mechanisms,and clinical translation challenges,highlighting structure-function relationships and comparative performance across therapeutic classes.By integrating mechanistic insights with recent breakthroughs,we outline how next-generation hydrogels can synergize with personalized medicine and combination therapies to redefine localized cancer treatment.This work explores the fundamental aspects and provides examples of hydrogel-based delivery for the advanced treatment of cancer.The review summarizes the dynamic landscape of hydrogel research of the last 5 years,showcasing their potential systems for the precise delivery of biomolecules.Specifically,we explore the multidimensional role of hydrogels in the sustained and localized release of antibodies,immunotherapeutic agents,and genes as next-generation platforms for localized cancer treatment.This review aims to critically evaluate the mechanisms and applications of these systems in order to assess their potential to transform medical interventions and advance patient care.展开更多
The multi-pass intermittent local loading process,which features a more flexible processing path,can further enhance the second material distribution during local loading,improve the formability of components,and redu...The multi-pass intermittent local loading process,which features a more flexible processing path,can further enhance the second material distribution during local loading,improve the formability of components,and reduce forming loads.However,the absence of compatible forming equipment makes it difficult to control the constraint in the unloaded zones during the forming process.This difficulty complicates coordination and control of deformation,particularly for asymmetric rib-web components.Additionally,the current implementation involves multi-fire heating,a long process flow,and high energy consumption,which limits the popularization and application of the local loading process.In this study,a new multi-pass local loading hydraulic forming apparatus that can quickly and reliably switch between heavy-load deformation and low-load constraint for different local loading sub-dies was developed.A 10-tonne laboratory prototype was developed,and the forming characteristics during the forming process as well as the response characteristics of the hydraulic system during the multi-pass intermittent local loading of rib-web component were investigated using numerical simulations and physical experiments.Results indicated that,compared to a whole loading process with the same initial geometry of billet,the total forming load(i.e.,the sum of loaded and restrained loads)is reduced by more than 40%with the local loading process,and by nearly 50%with multi-pass local loading.The multi-pass local loading process allows for more effective control of material flow compared to single-pass local loading,leading to improved cavity filling and reduced flow line disturbance.For a large-scale,complex titanium alloy bulkhead,the cavity filling problem was addressed by optimizing the multi-pass local loading path with an unequal thickness billet.The dynamic performance of the multi-pass local loading hydraulic system was found to be robust,with stable pressure transitions during motion and load switching for the sub-die(s).The dynamic characteristic of the hydraulic cylinder when switching from non-moving/unloaded state to a moving/loading state are consistent whether a load is present or not.However,the dynamic characteristics differ when switching from a moving/loading state to non-moving/unloaded state,showing opposite behavior.The developed hydraulic drive mechanism provides a way for implementation of multi-pass local loading without auxiliary operation and extra heating.The results of the study provide a foundation for the industrial production of large-scale,complex components with reduced force requirement and low-energy consumption.展开更多
The laboratory established an efficient reversed-phase ultra-high-performance liquid chromatographyquadrupole time-of-flight mass spectrometry(UPLC-Q-TOF-MS)qualitative method for screening more than 2000 kinds of ris...The laboratory established an efficient reversed-phase ultra-high-performance liquid chromatographyquadrupole time-of-flight mass spectrometry(UPLC-Q-TOF-MS)qualitative method for screening more than 2000 kinds of risk substances(including local anesthetics,LAs)in cosmetics,which has been successfully applied in the analysis of actual samples.This work aims to develop a more convenient high performance liquid chromatography triple quadrupole mass spectrometry(HPLC-QQQ-MS/MS)method for the quantitative determination of LAs.Samples were ultrasonically extracted with methanol,separated on an Agilent Poroshell 120 EC-C18 column(2.1 mm×100 mm,2.7μm),and eluted with a gradient mobile phase consisting of 0.1%formic acid aqueous solution and methanol.Quantification was performed using the external standard method.The results show that all 23 LAs are effectively separated within 12 minutes,with good linearity in the corresponding concentration ranges and the correlation coefficients all greater than 0.99.The limits of detection(LOD)range from 0.0025 to 0.05μg/g,and the limits of quantification(LOQ)range from 0.01 to 0.1μg/g.The average recoveries of the 23 LAs in 5 blank cosmetic matrices are 80.68%-117.57%,with the relative standard deviations(RSDs)less than 5.98%.This method has good precision and high accuracy,and is suitable for the determination of LAs in 5 cosmetic matrices.展开更多
The P2-type Fe/Mn-based layered oxides,with cost advantages and high theoretical capacity,are considered one of the promising cathode materials for sodium-ion batteries(SIBs).However,the commercial development of thes...The P2-type Fe/Mn-based layered oxides,with cost advantages and high theoretical capacity,are considered one of the promising cathode materials for sodium-ion batteries(SIBs).However,the commercial development of these materials is impeded by two main factors:the MnO_(6) structure distortion induced by the Jahn-Teller(J-T)effect of Mn^(3+),and the unfavorable phase transitions that occur during the insertion and extraction of Na^(+).Here,we present a strategy to improve structural stability by incorporating cost-effective,robust Al-O bonds.This approach induces localized adjustments in the electronic structu re and a pinning effect,which limits the deformation of the transition metal(TM)layers,strengthens the electrostatic bonding within the TM layers,and expands the Na layer spacing.Consequently,the Na_(0.67)Fe_(0.4)Mn_(0.54)Al_(0.06)O_(2) cathode demonstrates a capacity of 168.8 mAh g^(-1) at 0.1 C,maintaining89.2%of its original capacity after 200 cycles at 1 C.Through in situ electrochemical impedance spectroscopy(EIS)with dynamic resistance transformation(DRT)analysis,ex situ X-ray absorption spectroscopy(XAS),and in situ X-ray diffraction(XRD),the study demonstrates a reduction in the J-T effect,enhanced kinetic performance,and the inhibition of detrimental phase transitions.This study offers new avenues to the development and design of future low-cost Fe/Mn-based cathodes.展开更多
基金supported by the National Natural Science Foundation of China(No.62276204)the Fundamental Research Funds for the Central Universities,China(No.YJSJ24011)+1 种基金the Natural Science Basic Research Program of Shaanxi,China(Nos.2022JM-340 and 2023-JC-QN-0710)the China Postdoctoral Science Foundation(Nos.2020T130494 and 2018M633470)。
文摘Visible and infrared(RGB-IR)fusion object detection plays an important role in security,disaster relief,etc.In recent years,deep-learning-based RGB-IR fusion detection methods have been developing rapidly,but still struggle to deal with the complex and changing scenarios captured by drones,mainly due to two reasons:(A)RGB-IR fusion detectors are susceptible to inferior inputs that degrade performance and stability.(B)RGB-IR fusion detectors are susceptible to redundant features that reduce accuracy and efficiency.In this paper,an innovative RGB-IR fusion detection framework based on global-local feature optimization,named GLFDet,is proposed to improve the detection performance and efficiency of drone-captured objects.The key components of GLFDet include a Global Feature Optimization(GFO)module,a Local Feature Optimization(LFO)module and a Channel Separation Fusion(CSF)module.Specifically,GFO calculates the information content of the input image from the frequency domain and optimizes the features holistically.Then,LFO dynamically selects high-value features and filters out low-value features before fusion,which significantly improves the efficiency of fusion.Finally,CSF fuses the RGB and IR features across the corresponding channels,which avoids the rearrangement of the channel relationships and enhances the model stability.Extensive experimental results show that the proposed method achieves the best performance on three popular RGB-IR datasets Drone Vehicle,VEDAI,and LLVIP.In addition,GLFDet is more lightweight than other comparable models,making it more appealing to edge devices such as drones.The code is available at https://github.com/lao chen330/GLFDet.
文摘Background and Objectives:The perception of sound in the vertical plane supports spatial hearing by enabling listeners to detect sources located above and below.Sounds originating from both the front and back elevations along the mid-sagittal plane further contribute to a three-dimensional auditory experience.This study aimed to characterize the variability in vertical sound localization abilities among normal-hearing(NH)individuals using spatialized audio.Materials and Methods:Fifty-one NH participants(aged 18 to 35 years)completed three vertical localization tasks under headphones as part of a single-group,within-subject experimental study.These tasks included two-plane identification:(1)top-down localization,(2)front-back localization,and one discrimination task in the front plane.Hierarchical Cluster Analysis(HCA)was employed to identify distinct patterns in spatial localization profiles specific to the vertical-median plane.Fisher's Discriminant Function Analysis(FDA)was used to validate the accuracy of HCA and estimate classification error.Results:HCA revealed three distinct listener clusters:(1)cluster 1 with good performance across all three tasks,(2)cluster 2 with selective impairment in top-bottom identification,and(3)cluster 3 with selective deficits in front-back identification.FDA validated group membership of the clusters identified by the HCA,with a prediction accuracy of 98%.Conclusions:Individuals with clinically NH exhibited three distinct vertical localization profiles:uniform performers,those impaired in top-bottom identification,and those impaired in front-back identification.These profiles may be linked to the interplay between acoustic and non-acoustic perceptual factors.
基金financial supports of the National Natural Science Foundation of China(52222512)。
文摘The application potential of tuning two-dimensional materials(2DMs)characteristics through strain engineering for wearable and flexible devices has been widely recognized.However,the challenges lie in achieving accurate deterministic positioning,spatial modulation,controllable magnitude,and permanent nanostrains.Herein,motivated by the skin swelling caused by mosquito bites,a technique utilizing the heated nanotip in atomic force microscopy for thermomechanical nanoindentation is demonstrated.This method enables precise positioning of localized nanostrain and regulation of bandgap in tungsten diselenide(WSe_(2))/molybdenum disulfide(MoS_(2))heterobilayer transferred onto a flexible polymethyl methacrylate film.The magnitude of strain in the WSe_(2)/MoS_(2) heterobilayer can be controlled by adjusting the parameters of nanoindentation,leading to a spatially modulated average strain of up to 2.5%on the ring-shaped expansion structure(RES).The local bandgap of the WSe_(2)/MoS_(2) heterobilayer is spatially regulated through three distinct regions.In particular,the RES exhibits the largest extent of bandgap modulation,accompanied by a significant change of~12 meV.The nanostrain significantly enhances the photoresponse speed of the photodetector device.For instance,under illumination from a 405 nm wavelength-laser,the rise time and fall time are reduced by 75%and 87.52%,respectively,compared to the device without strain.Similarly,under illumination from a 532 nm wavelength-laser,the rise time and fall time are reduced by 66.67%and 80.60%,respectively.These findings demonstrate that the proposed method serves as a versatile way for improving the photoresponse of optoelectronic devices based on 2DMs.
基金funded by Ministry of Higher Education Malaysia through Universiti Malaysia Pahang Al-Sultan Abdullah under Internal Research Grant(RDU233003).
文摘This paper proposes a tamper detection technique for semi-fragile watermarking using Quantizationbased Discrete Cosine Transform(DCT)for tamper localization.In this study,the proposed embedding strategy is investigated by experimental tests over the diagonal order of the DCT coefficients.The cover image is divided into non-overlapping blocks of size 8×8 pixels.The DCT is applied to each block,and the coefficients are arranged using a zig-zag pattern within the block.In this study,the low-frequency coefficients are selected to examine the impact of the imperceptibility score and tamper detection accuracy.High accuracy of tamper detection can be achieved by checking the surrounding blocks to determine whether the corresponding block has been tampered with.The proposed tamper detection is tested under various malicious,incidental,and hybrid attacks(both incidental and malicious attacks).The experimental results demonstrate that the proposed technique achieves a Peak-Signal-to-Noise Ratio(PSNR)value of 41.2318 dB,an average Structural Similarity Index Measure(SSIM)value of 0.9768.The proposed scheme is also evaluated against malicious attacks such as copy-move,object deletion,object manipulation,and collage attacks.The proposed scheme can detect the malicious attack localization under various tampering rates.In addition,the proposed scheme can still detect tampered pixels under a hybrid attack,such as a combination ofmalicious and incidental attacks,with an average accuracy of 96.44%.
基金Project supported by the National Natural Science Foundation of China(No.12472062)。
文摘In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally resonant effect,which contains two parts:the first part is induced by translation coupling,and the second part is induced by rotation coupling.The second part cannot be reflected by most existing theoretical models.The analytical solutions of the dynamic response are compared with the direct numerical simulation(DNS)results for two locally resonant plates with different resonator types,thereby validating the general applicability of the present model.The rotation coupling effect leads to the frequency-dependent effective rotational inertia density and anisotropic dispersion relation of the locally resonant plate,as well as the enhancement of the structural vibration suppression ability.
基金National Key R&D Program of China under Grants 2021YFB2900404the National Natural Science Foundation of China under Grants 62371098。
文摘The acquisition of position information of legitimate users and jammers plays an important role in the emerging non-geostationary synchronous orbit(NGSO)satellite communications.In this paper,we study the multi-signal localization problem in an uplink NGSO satellite communication system.We propose an onboard localization scheme based on multiple observations from the satellite,together with the geometric constraints of the satellite postions,the signal positions,the attitude of the satellite,and the angle-of-arrival(AoAs)of the signals.We develop a massage-passing algorithm,termed the Bayesian blind multi-signal localization(BMSL),to jointly estimate the AoAs and the signal positions.The Cramér-Rao lower bound(CRLB)is derived to characterize the fundamental performance limit of the considered localization problem.Simulation results show that the proposed BMSL algorithm can perform close to the derived CRLB and significantly outperforms its counterpart algorithms.
基金financially supported by the National Research Foundation of Korea(NRF)grant funded by the Korean government(MSIT)(No.NRF-2020R1A3B2079803 and No.RS-2024-00453815),Republic of Korea。
文摘Localized high-concentration electrolytes(LHCEs)are considered as promising electrolyte candidates to resolve technical issues of metal batteries owing to their unique interfacial properties and solvation structures.Herein,we propose a self-assembly chemical strategy into the LCHEs induced by ordered nanostructure of zwitterionic co-solutes for highly efficient and ultrastable zinc(Zn)metal batteries.Through the systematic screening of six zwitterionic compounds,3-(decyldimethylammonio)propanesulfonate salt(C_(10))with the decyl chain and zwitterions was determined as an optimum to construct quasi-spherical aggregates with a periodic length of 3.77 nm,as confirmed by comprehensive synchronous small-angle X-ray scattering,Guinier,pair distance distribution function,Porod,and other spectroscopic characterizations and molecular dynamic simulation.In particularly,this self-assembled structure in electrolyte environments was attributed to increasing the proportion of both contact and aggregated ion pairs for the formation of LHCEs as well as to providing fast and selective Zn^(2+)conducting channels and uniform solid electrolyte interfaces for facilitated charge transfer kinetics.Moreover,the preferential adsorption of the self-assembled C_(10)on the Zn(002)surface modulated the electrical double layer to suppress hydrogen evolution and corrosion reactions.Consequently,the Zn‖Zn symmetric cells in Zn(OTf)_(2)/C_(10)electrolytes showed long-term plating/stripping behaviors over 2800 h at 1 mA cm^(-2)and 1 mAh cm^(-2)as well as over 1200 h even at 5 mA cm^(-2)and 5 mAh cm^(-2)with a very high depth of discharge of 42.7%.Furthermore,the ZnllVO_(2)/CNT full cells in Zn(OTf)_(2)/C_(10)electrolytes delivered a record-high capacity of 8.10 mAh cm^(-2)at an ultrahigh cathode mass loading of 50 mg cm^(-2)after 150 cycles.
基金supported in part by the National Natural Science Foundation of China under Grant 52432012in part by the Shanghai Science and Technology Project with 25ZR1402508。
文摘The stator of the maglev track plays a crucial role in the operation of the maglev system.Currently,the efficiency of maglev track inspection is limited by several factors,including the large span of elevated structures,manual visual inspection,short inspection window times,and limited GPS positioning accuracy.To address these issues,this paper proposes a deep learning-based method for detecting and locating stator surface damage.This study establishes a maglev track stator surface image dataset,trains different object detection models,and compares their performance.Ultimately,YOLO and ByteTrack object tracking algorithms were chosen as the basic framework and enhanced to achieve automatic identification of high-speed maglev track stator surface damage images and track and count stator surface localization feature images.By matching the identified damaged images with their corresponding stator segment and beam segment sequence numbers,the location of the damage is pinpointed to the corresponding stator segment,enabling rapid and accurate identification and localization of complex damage to the maglev track stator surface.
基金Princess Nourah bint Abdulrahman University Researchers Supporting Project number(PNURSP2025R8)。
文摘In this article,we introduce a new theoretical approach to improve the accuracy of twodimensional(2D)atomic localization within a tripod-type,four-level atomic system by analyzing its transmission spectrum.In this method,the atom interacts with two orthogonal standing-wave fields and a weak probe field.By examining how the weak probe field passes through the system,we can determine the atom position.Our analysis reveals the presence of both double and sharply defined single localized peaks in the transmission spectrum,which correspond to specific positions of the atom.Importantly,we achieve ultra-high-resolution atomic localization with accuracy confined to a region smaller thanλ/32×λ/32.This level of precision is a significant improvement compared to earlier methods,which had lower localization accuracy.The increased precision is due to the complex interaction between the atom and the carefully controlled standing-wave and probe fields,which allows for precise control over the atom's position.The implications of this work are significant,especially for applications like nano-lithography,where precise atomic placement is essential,and for laser cooling technologies,where better atomic localization could lead to more effective cooling processes and improved manipulation of atomic states.
基金supported by the National Natural Science Foundation of China under Grant 62206083.
文摘Binary segmentation tasks in computer vision exhibit diverse appearance distributions and complex boundary characteristics.To address the limited generalization and adaptability of existing models across heterogeneous tasks,we propose Abel-Net,an Aggregated Bilateral Edge Localization Network designed as a universal framework formulti-task binary segmentation.Abel-Net integrates global and local contextual cues to enhance feature learning and edge precision.Specifically,amulti-scale feature pyramid fusion strategy is implemented via anAggregated Skip Connection(ASC)module to strengthen feature adaptability,while the Edge Dual Localization(EDL)mechanism performs coarse-to-fine refinement through edge-aware supervision.Additionally,Edge Attention(EA)and Edge Fusion Attention(EFA)modules prioritize edge-critical regions and facilitate accurate boundary alignment.Extensive experiments on nine diverse binary segmentation tasks demonstrate thatAbel-Net performs comparably to or surpasses state-of-the-art task-specific networks,exhibiting strong adaptability to a wide range of visual perception challenges.
基金supported by the National Natural Science Foundation of China through grant numbers 12002245 and 12172263the Science and Technology Research Program of Chongqing Municipal Education Commission through grant number KJQN202300742+1 种基金the National Natural Science Foundation of ChongqingMunicipality through grant number CSTB2025NSCQ-GPX0841Chongqing Jiaotong University through grant number F1220038.
文摘Granular materials exhibit complex macroscopic mechanical behaviors closely related to their microscalemicrostructural features.Traditional macroscopic phenomenological elasto-plastic models,however,usually have complex formulations and lack explicit relations to these microstructural features.To avoid these limitations,this study proposes a micromechanics-based softening hyperelastic model for granular materials,integrating softening hyperelasticity withmicrostructural insights to capture strain softening,critical state,and strain localization behaviors.The model has two key advantages:(1)a clear conceptualization,straightforward formulation,and ease of numerical implementation(via Abaqus UMAT subroutine in this study);(2)explicit incorporation of micro-scale features(e.g.,contact stiffness,particle size,porosity)to reveal their influences on macroscopic responses.An isotropic directional distribution density of contacts and three specific microstructures are considered,and their softening hyperelastic constitutive modulus tensors are explicitly derived.By introducing a softening factor and critical failure energy density,the model can describe geomaterial behaviors,simulating residual strength,X-shaped shear bands,and strain localization evolution.Numerical validations in comparison with themacro-scale hyperelastic model,Abaqus Drucker-Prager model,and the experiment confirm its accuracy.Parametric studies reveal critical dependencies:a normal to tangential contact stiffness ratio of 2-8(depending on stiffness magnitude),an internal length of 2-4 mm to ensure shear band formation,and a critical failure energy density(≤10 kJ/m^(3))to trigger strain softening and localization.Influences of the specific microstructures on strain localization and softening are investigated.The model also shows mesh independence due to the introduction of an internal length.The model’s applicability is further demonstrated by slope stability analysis,capturing slip surface evolution,and load-displacement characteristics.This study develops a robust microstructure-aware hyperelastic framework to describe the mechanical behaviors of granular materials,providing multiscale insights for geotechnical engineering applications.
基金Supported by Open Fund Project of the Engineering Technology Research Center of Characteristic Medicinal Plants of Fujian(PP202003).
文摘This paper provides a systematic review of the histochemical localization,content characteristics,and influencing factors of saponins in Pseudostellaria heterophylla based on an extensive literature survey.It provides an in-depth analysis and summary of the effects of biological factors,environmental conditions,agronomic practices,processing methods,and continuous cropping obstacles on the synthesis of P.heterophylla saponins,as well as their underlying mechanisms.Based on identified gaps in the current literature,future research directions and prospects are proposed.The findings of this review offer valuable insights for advancing the understanding of the saponin biosynthesis mechanisms in P.heterophylla and for enhancing its quality.
文摘Summary Pain is not pain because people interpret symptoms differently.Neck pain is one of the most common pains and should not be missing from a study on the effects of pain.Depression does not arise solely from pain but is multicausal and often caused by this cumulative effect.
基金Supported by the National Natural Science Foundation of China(Grant No.12361026)the Discipline Construction Fund Project of Northwest Minzu University.
文摘This paper investigates the following mixed local and nonlocal elliptic problem fea-turing concave-convex nonlinearities and a discontinuous right-hand side:{L(u)=H(u−μ)|u|^(p−2)u+λ|u|^(q−2)u,x∈Ω,u≥0,x∈Ω,u=0,x∈R^(N)\Ω,where Ω ⊂R^(N)(N>2)is a bounded domain,μ≥0 and λ>0 are real parameters,H denotes the Heaviside function(H(t)=0 for t<0,H(t)=1 for t>0),and the mixed local and nolocal operator is defined as L(u)=−Δu+(−Δ)^(s)u with(−Δ)^(s) being the restricted fractional Laplace(0<s<1).The exponents satisfy 1<q<2<p.By employing a novel non-smooth variational principle,we establish the existence of an M-solution for this problem and identify a range for the exponent p.
基金support of her postdoctoral research at the GFZ Helmholtz Centre for Geosciences.P.Pan acknowledges the financial support of the National Natural Science Foundation of China(Grant No.52339001)H.Hofmann and Y.Ji acknowledge the financial support of the Helmholtz Association's Initiative and Networking Fund for the Helmholtz Young Investigator Group ARES(contract number VH-NG-1516).
文摘A multi-stage stress relaxation test was performed on a granodiorite sample to understand the deformation process prior to the macroscopic failure of brittle rocks,as well as the transient response during stress relaxation.Distributed optical fiber sensing was used to measure strains across the sample surface by helically wrapping the single-mode fiber around the cylindrical sample.Close agreement was observed between the circumferential strains obtained from the optical fibers and the extensometer.The reconstructed full-field strain contours show strain heterogeneity from the crack closure phase,and the strains in the later deformation phase are dominantly localized within the former high-strain zone.The Gini coefficient was used to quantify the degree of strain localization and shows an initial increase during the crack closure phase,a decrease during the linear elastic phase,and a subsequent increase during the post-yielding phase.This behavior corresponds to a process of initial localization from an imperfect boundary condition,homogenization,and eventual relocalization prior to the macroscopic failure of the sample.The transient strain rate decay during the stress relaxation phase was quantified using the p-value in the“Omori-like"power law function.A higher initial stress at the onset of relaxation results in a lower p-value,indicating a slower strain rate decay.As the sample approaches macroscopic failure,the lowest p-value shifts from the most damaged zone to adjacent areas,suggesting stress redistribution or crack propagation in deformed crystalline rocks under stress relaxation conditions.
基金supported by the Vall d’Hebron Research Institute(PI23/01345)the Networking Research Centre on Bioengineering,Biomaterials,and Nanomedicine(CIBER-BBN),which is financed by the Instituto de Salud Carlos III(ISCIII)with assistance from the European Regional Development Fund(ERDF)+4 种基金supported by ANID FONDECYT REGULAR(Chile)through project No.1250634,and FOVI230019 granted to Esteban Duran-LaraDiana Rafael was supported by Marie Skłodowska-Curie Actions(MSCA-PF ID 101107735),“La Caixa Foundation”(LCF/BQ/PR24/12050008),and ISCIII(PI24/00745)Fernanda Andrade was granted by the Fundación Científica de la Asociación Española Contra el Cáncer(FCAECC Refs.INVES211530DASI and SNRGS247164DASI)“La Caixa Foundation”(HR24-00927).Júlia German-Cortés was granted by the 791 FAECC(PRDBA258393GERM)The authors also thank the denomination of Consolidated group from Generalitat de Catalunya(2021 SGR 01173)granted to the CB-DDT group。
文摘Despite remarkable advances in nanomedicine,localized delivery of advanced cancer therapeutics remains underexploited.Advanced therapies based on biopharmaceuticals,immunotherapy,or gene therapy have revolutionized oncology.Yet,their systemic administration is often associated with limitations such as poor sitespecific accumulation,instability,and systemic toxicity.Hydrogels/macrogels offer the ability to encapsulate,protect,and release biomolecules in situ with sustained and stimulus-responsive profiles,addressing key translational gaps.This review provides a focused synthesis of the last five years of hydrogel-based research for cancer therapy,with emphasis on peptides,antibodies,immunotherapeutic agents,and gene delivery systems.We discuss design principles,release mechanisms,and clinical translation challenges,highlighting structure-function relationships and comparative performance across therapeutic classes.By integrating mechanistic insights with recent breakthroughs,we outline how next-generation hydrogels can synergize with personalized medicine and combination therapies to redefine localized cancer treatment.This work explores the fundamental aspects and provides examples of hydrogel-based delivery for the advanced treatment of cancer.The review summarizes the dynamic landscape of hydrogel research of the last 5 years,showcasing their potential systems for the precise delivery of biomolecules.Specifically,we explore the multidimensional role of hydrogels in the sustained and localized release of antibodies,immunotherapeutic agents,and genes as next-generation platforms for localized cancer treatment.This review aims to critically evaluate the mechanisms and applications of these systems in order to assess their potential to transform medical interventions and advance patient care.
基金the supports of the National Natural Science Foundation of China(Grant No.52375378)。
文摘The multi-pass intermittent local loading process,which features a more flexible processing path,can further enhance the second material distribution during local loading,improve the formability of components,and reduce forming loads.However,the absence of compatible forming equipment makes it difficult to control the constraint in the unloaded zones during the forming process.This difficulty complicates coordination and control of deformation,particularly for asymmetric rib-web components.Additionally,the current implementation involves multi-fire heating,a long process flow,and high energy consumption,which limits the popularization and application of the local loading process.In this study,a new multi-pass local loading hydraulic forming apparatus that can quickly and reliably switch between heavy-load deformation and low-load constraint for different local loading sub-dies was developed.A 10-tonne laboratory prototype was developed,and the forming characteristics during the forming process as well as the response characteristics of the hydraulic system during the multi-pass intermittent local loading of rib-web component were investigated using numerical simulations and physical experiments.Results indicated that,compared to a whole loading process with the same initial geometry of billet,the total forming load(i.e.,the sum of loaded and restrained loads)is reduced by more than 40%with the local loading process,and by nearly 50%with multi-pass local loading.The multi-pass local loading process allows for more effective control of material flow compared to single-pass local loading,leading to improved cavity filling and reduced flow line disturbance.For a large-scale,complex titanium alloy bulkhead,the cavity filling problem was addressed by optimizing the multi-pass local loading path with an unequal thickness billet.The dynamic performance of the multi-pass local loading hydraulic system was found to be robust,with stable pressure transitions during motion and load switching for the sub-die(s).The dynamic characteristic of the hydraulic cylinder when switching from non-moving/unloaded state to a moving/loading state are consistent whether a load is present or not.However,the dynamic characteristics differ when switching from a moving/loading state to non-moving/unloaded state,showing opposite behavior.The developed hydraulic drive mechanism provides a way for implementation of multi-pass local loading without auxiliary operation and extra heating.The results of the study provide a foundation for the industrial production of large-scale,complex components with reduced force requirement and low-energy consumption.
文摘The laboratory established an efficient reversed-phase ultra-high-performance liquid chromatographyquadrupole time-of-flight mass spectrometry(UPLC-Q-TOF-MS)qualitative method for screening more than 2000 kinds of risk substances(including local anesthetics,LAs)in cosmetics,which has been successfully applied in the analysis of actual samples.This work aims to develop a more convenient high performance liquid chromatography triple quadrupole mass spectrometry(HPLC-QQQ-MS/MS)method for the quantitative determination of LAs.Samples were ultrasonically extracted with methanol,separated on an Agilent Poroshell 120 EC-C18 column(2.1 mm×100 mm,2.7μm),and eluted with a gradient mobile phase consisting of 0.1%formic acid aqueous solution and methanol.Quantification was performed using the external standard method.The results show that all 23 LAs are effectively separated within 12 minutes,with good linearity in the corresponding concentration ranges and the correlation coefficients all greater than 0.99.The limits of detection(LOD)range from 0.0025 to 0.05μg/g,and the limits of quantification(LOQ)range from 0.01 to 0.1μg/g.The average recoveries of the 23 LAs in 5 blank cosmetic matrices are 80.68%-117.57%,with the relative standard deviations(RSDs)less than 5.98%.This method has good precision and high accuracy,and is suitable for the determination of LAs in 5 cosmetic matrices.
基金financially supported by the National Natural Science Foundation of China(52274295)the Natural Science Foundation of Hebei Province(E2025501032,E2025501028)+3 种基金the Fundamental Research Funds for the Central Universities(N2523045,N2423051,N2423005,N2423019)the Science and Technology Project of Hebei Education Department(QN2024238)the Central Guided Local Science and Technology Development Fund Project of Hebei Province(254Z1102G)the Basic Research Program Project of Shijiazhuang City for Universities Stationed in Hebei Province(241790937A)。
文摘The P2-type Fe/Mn-based layered oxides,with cost advantages and high theoretical capacity,are considered one of the promising cathode materials for sodium-ion batteries(SIBs).However,the commercial development of these materials is impeded by two main factors:the MnO_(6) structure distortion induced by the Jahn-Teller(J-T)effect of Mn^(3+),and the unfavorable phase transitions that occur during the insertion and extraction of Na^(+).Here,we present a strategy to improve structural stability by incorporating cost-effective,robust Al-O bonds.This approach induces localized adjustments in the electronic structu re and a pinning effect,which limits the deformation of the transition metal(TM)layers,strengthens the electrostatic bonding within the TM layers,and expands the Na layer spacing.Consequently,the Na_(0.67)Fe_(0.4)Mn_(0.54)Al_(0.06)O_(2) cathode demonstrates a capacity of 168.8 mAh g^(-1) at 0.1 C,maintaining89.2%of its original capacity after 200 cycles at 1 C.Through in situ electrochemical impedance spectroscopy(EIS)with dynamic resistance transformation(DRT)analysis,ex situ X-ray absorption spectroscopy(XAS),and in situ X-ray diffraction(XRD),the study demonstrates a reduction in the J-T effect,enhanced kinetic performance,and the inhibition of detrimental phase transitions.This study offers new avenues to the development and design of future low-cost Fe/Mn-based cathodes.
