Composite slabs with profiled steel sheet are widely applied in practical structures now. Plenty of literatures can be available about simply supported composite slabs with single span. However, continuous slabs alway...Composite slabs with profiled steel sheet are widely applied in practical structures now. Plenty of literatures can be available about simply supported composite slabs with single span. However, continuous slabs always exist in high-rise building structures. In order to obtain the ultimate loading capacity of continuous composite slabs, the full scale test on slab specimens with high cost need to be carried out. This paper presented an analytical model for calculating the ultimate loading capacity of continuous composite slabs. Only the small-scale slide block test needed to be carried out for determining some mechanical parameters, resulting in less cost, compared with the conventional m-k test method. Various load conditions and parameters were considered in the analytical model. The comparison between test results and predicted results showed that the proposed method had enough precision. Furthermore, the simplified method was also proposed for practical design.展开更多
Ultra-high speed machining technology enables high efficiency, high precision and high integrity of machined surface. Previous researches of hybrid bearing rarely consider influences of solid particles in lubricant an...Ultra-high speed machining technology enables high efficiency, high precision and high integrity of machined surface. Previous researches of hybrid bearing rarely consider influences of solid particles in lubricant and ultra-high speed of hybrid bearing, which cannot be ignored under the high speed and micro-space conditions of ultra-high speed water-lubricated hybrid bearing. Considering the impact of solid particles in lubricant, turbulence and temperature viscosity effects of lubricant, the influences of particles on pressure distribution, loading capacity and the temperature rise of the lubricant film with four-step-cavity ultra-high speed water-lubricated hybrid bearing are presented in the paper. The results show that loading capacity of the hybrid bearing can be affected by changing the viscosity of the lubricant, and large particles can improve the bearing loading capacity higher. The impact of water film temperature rise produced by solid particles in lubricant is related with particle diameter and minimum film thickness. Compared with the soft particles, hard particles cause the more increasing of water film temperature rise and loading capacity. When the speed of hybrid bearing increases, the impact of solid particles on hybrid bearing becomes increasingly apparent, especially for ultra-high speed water-lubricated hybrid bearing. This research presents influences of solid particles on the loading capacity and the temperature rise of water film in ultra-high speed hybrid bearings, the research conclusions provide a new method to evaluate the influence of solid particles in lubricant of ultra-high speed water-lubricated hybrid bearing, which is important to performance calculation of ultra-high speed hybrid bearings, design of filtration system, and safe operation of ultra-high speed hybrid bearings.展开更多
The relationship between dialkylphosphinic acid structure and their loading capacity for HREEs and emulsification phenomena has rarely been studied.In this paper,we took Lu extraction as an example to study the effect...The relationship between dialkylphosphinic acid structure and their loading capacity for HREEs and emulsification phenomena has rarely been studied.In this paper,we took Lu extraction as an example to study the effect of β,γ,δ-substituents of dialkylphosphinic acids on their loading capacity and anti-emulsification performance for HREEs.To discuss conveniently,the dialkylphosphinic acids were classified into two groups:β-substituent group(P208,INET-1,P218,USTB-1 and P227)and γ,δ-substituent group(P218,P2132 and Cyanex 272).For β-substituent group extractants,their loading capacities are in the order P208(299.7 mg/L)≈INET-1(299.5 mg/L)>P218(270.8 mg/L)>>USTB-1(163.1 mg/L)>P227(151.4 mg/L),while their anti-emulsification/gelation performances are just in the opposite order P227>USTB-1>P218>P208≈INET-1 under the studied conditions.For γ,δ-substituent group extractants,their loading capacities are in the order P218(270.8 mg/L)>P2132(192.3 mg/L)>Cyanex272(131.7 mg/L),while the anti-emulsification performance of P218 is better than those of P2132 and Cyanex 272.The loading capacity data given in the parentheses are obtained through repeatedly extracting Lu from ~4×10^(-4)mol/L of Lu aqueous feed solution with initial pH of 2.40 by 0.01 mol/L extractant at phase ratio A/O of 1:1.展开更多
Surface modification of different functional molecules onto NaREF_(4)(RE=rare earth)upconversion nanoparticles(UCNPs)impart their multiple functionalities.Functional molecules can be loaded onto NaREF_(4) UCNPs throug...Surface modification of different functional molecules onto NaREF_(4)(RE=rare earth)upconversion nanoparticles(UCNPs)impart their multiple functionalities.Functional molecules can be loaded onto NaREF_(4) UCNPs through the formation of coordination bonds between the surface-exposed RE^(3+) ions and the appropriate chemical groups of functional molecules.The density of surface RE^(3+) ions directly determines the loading efficiency of Na REF4 UCNPs.However,NaREF_(4) is a binary cation system,rendering the surface-distributed Na;and RE^(3+) ions remains a mystery.Here,we develop an effective strategy to significantly enhance the density of surface RE^(3+) ions,thus maximizing the loading capacity of NaREF_(4) UCNPs.This strategy is based on a heterovalent cation exchange(HCE)reaction in the surface region in which Na^(+)ions are replaced by RE^(3+) ions.The density of surface ligands enhances from 3.6 to 8.8 molecules/nm^(2) after reaction,suggesting that the loading efficiency increases by approximately 150%.Benefiting from the improved loading capacity,we demonstrate such surface-RE-rich nanoparticles have the ability to offer higher colloidal stability and more desirable photodynamic therapy(PDT)efficacy.This work not only advances our understanding of cation exchange reactions in RE-based nanoparticles,but also provides significant value for considerable applications such as sensing,bioimaging,and therapy.展开更多
Trusses used for roof support in coal mines are constructed of two grouted bolts installed at opposing forty-five degree angles into the roof and a cross member that ties the angled bolts together. The load on the cro...Trusses used for roof support in coal mines are constructed of two grouted bolts installed at opposing forty-five degree angles into the roof and a cross member that ties the angled bolts together. The load on the cross member is vertical, which is transverse to the longitudinal axis, and therefore the cross member is loaded in the weakest direction. Laboratory tests were conducted to determine the vertical load capacity and deflection of three different types of cross members. Single-point load tests, with the load applied in the center of the specimen and double-point load tests, with a span of 2.4 m, were conducted. For the single-point load configuration, the yield of the 25 mm solid bar cross member was nominally 98 kN of vertical load, achieved at 42 cm of deflection. For cable cross members, yield was not achieved even after 45 cm of deflection. Peak vertical loads were about 89 kN for 17 mm cables and67 kN for the 15 mm cables. For the double-point load configurations, the 25 mm solid bar cross members yielded at 150 kN of vertical load and 25 cm of deflection. At 25 cm of deflection individual cable strands started breaking at 133 and 111 kN of vertical load for the 17 and 15 mm cable cross members respectively.展开更多
The intersection of economic development,energy dynamics,environmental policy,and environmental sustainability presents complex challenges for European Union(EU)countries.This study investigatedthe impact of environme...The intersection of economic development,energy dynamics,environmental policy,and environmental sustainability presents complex challenges for European Union(EU)countries.This study investigatedthe impact of environmental taxes,hydroelectricity consumption,economic globalization,and gross domestic product(GDP)on the load capacity factor(LCF)in the 10 EU member countries(including Austria,Finland,France,Germany,Italy,Poland,Portugal,Slovakia,Spain,and Sweden)using data from 1995 to 2020.To ensure the reliability and validity of the data,this study applied several advanced econometric tests,including the Pesaran and Yamagata slopeheterogeneitytest,Pesaran cross-sectional dependence(CSD)test,second-generation unit root test,and Westerlund cointegration test.The data showed important statistical issues such as slope heterogeneityacross panels,CSD,mixed-orderunit root structures,and long-run associations between variables.To address these issues,we applied an augmented mean group(AMG)model as the main regression approach,andusedthe pooled mean group-autoregressive distributed lag(PMG-ARDL)method to check the robustness.Specifically,the AMG results indicate that a 1.000%rise in hydroelectricity consumptionresults in a 0.048% rise in the LCF,while a 1.000% increase in environmental taxes leads toa 0.175% increase in the LCF.Contrary to this,a 1.000% increase in economic globalization results in a 0.370% decrease in the LCF,and a 1.000% increase in GDP leads toa 0.850% decrease in the LCF.Environmental taxes have a more beneficial impact on the environment,and GDP has the most detrimental effect.The findings provide empirical evidence on the role of environmental taxes,hydroelectricity consumption,economic globalization,and GDP in driving the LCF.Additionally,the findings provide valuable information to policy-makers,academicians,and stakeholders shaping energy and environmental policies in the 10 EU member countries.展开更多
Compared to single-layer networks,multilayer networks exhibit a more complex node degree composition,comprising both intra-layer and inter-layer degrees.However,the distinct impacts of these degree types on cascading ...Compared to single-layer networks,multilayer networks exhibit a more complex node degree composition,comprising both intra-layer and inter-layer degrees.However,the distinct impacts of these degree types on cascading failures remain underexplored.Distinguishing their effects is crucial for a deeper understanding of network structure,information propagation,and behavior prediction.This paper proposes a capacity-load model to influence and compare the influence of different degree types on cascading failures in multilayer networks.By designing three node removal strategies based on total degree,intra-layer degree,and inter-layer degree,simulation experiments are conducted on four types of networks.Network robustness is evaluated using the maximum number of removable nodes before collapse.The relationships between network robustness and the coupling coefficient,as well as load and capacity adjustment parameters,are also analyzed.The results indicate that the node removal strategy with the least impact on cascading failures varies across different types of networks,revealing the significance of different node degrees in failure propagation.Compared to other models,the proposed model enables networks to maintain a higher maximum number of removable nodes during cascading failures,demonstrating superior robustness.展开更多
Captive model tests are one of the most common methods to calculate the maneuvering hydrodynamic coefficients and characteristics of surface and underwater vehicles.Considerable attention must be paid to selecting and...Captive model tests are one of the most common methods to calculate the maneuvering hydrodynamic coefficients and characteristics of surface and underwater vehicles.Considerable attention must be paid to selecting and designing the most suitable laboratory equipment for towing tanks.A computational fluid dynamics(CFD)-based method is implemented to determine the loads acting on the towing facility of the submarine model.A reversed topology is also used to ensure the appropriateness of the load cells in the developed method.In this study,the numerical simulations were evaluated using the experimental results of the SUBOFF benchmark submarine model of the Defence Advanced Research Projects Agency.The maximum and minimum loads acting on the 2.5-meter submarine model were measured by determining the body’s lightest and heaviest maneuvering test scenarios.In addition to having sufficient endurance against high loads,the precision in measuring the light load was also investigated.The horizontal planar motion mechanism(HPMM)facilities in the National Iranian Marine Laboratory were developed by locating the load cells inside the submarine model.The results were presented as a case study.A numerical-based method was developed to obtain the appropriate load measurement facilities.Load cells of HPMM test basins can be selected by following the two-way procedure presented in this study.展开更多
In order to analyze the load carrying capacity of prestressed concrete box girders, failure behaviors of in-situ deteriorated continuous prestressed concrete box girders under loading are experimentally observed and a...In order to analyze the load carrying capacity of prestressed concrete box girders, failure behaviors of in-situ deteriorated continuous prestressed concrete box girders under loading are experimentally observed and a finite failure analysis method for predicting behaviors of box girders is developed. A degenerated solid shell element is used to simulate box girders and material nonlinearity is considered. Since pre-stressed concrete box girders usually have a large number of curve prestressed tendons, a type of combined element is presented to simulate the prestressed tendons of box girders, and then the number of elements can be significantly reduced. The analytical results are compared with full-scale failure test results. The comparison shows that the presented method can be effectively applied to the failure analysis of in-situ continuous prestressed concrete box girders, and it also shows that the studied old bridge still has enough load carrying capacity.展开更多
An engineered cementitious composite (ECC) is introduced to partially substitute concrete in the tension zone of a reinforced concrete beam to form an ECC/reinforced concrete (RC) composite beam, which can increas...An engineered cementitious composite (ECC) is introduced to partially substitute concrete in the tension zone of a reinforced concrete beam to form an ECC/reinforced concrete (RC) composite beam, which can increase the ductility and crack resisting ability of the beam. Based on the assumption of the plane remaining plane and the simplified constitutive models of materials, the stress and strain distributions along the depth of the composite beam in different loading stages are comprehensively investigated to obtain calculation methods of the load-carrying capacities for different stages. Also, a simplified formula for the ultimate load carrying capacity is proposed according to the Chinese code for the design of concrete structures. The relationship between the moment and curvature for the composite beam is also proposed together with a simplified calculation method for ductility of the ECC/RC composite beam. Finally, the calculation method is demonstrated with the test results of a composite beam. Comparison results show that the calculation results have good consistency with the test results, proving that the proposed calculation methods are reliable with a certain theoretical significance and reference value.展开更多
The prosperous post buckling load capacity of web plates of box girders can be used.In this article,the post buckling behaviour of web plates of box girders under different loading conditions is theoretically analyz...The prosperous post buckling load capacity of web plates of box girders can be used.In this article,the post buckling behaviour of web plates of box girders under different loading conditions is theoretically analyzed and on the basis of domestic and overseas design codes of steel structures,the corresponding simplified analysis methods are put forward for the engineering design or code revision.It is proved that the simplified methods are safe,efficient and practicable through the comparison between several results.展开更多
This paper investigated the stress evolution,displacement field,local deformation and its overall distribution,and failure characteristics of the anchorage structure of surrounding rock with different rockbolt spacing...This paper investigated the stress evolution,displacement field,local deformation and its overall distribution,and failure characteristics of the anchorage structure of surrounding rock with different rockbolt spacing through the model experiments.The influences of the pre-tightening force and spacing of rockbolt on the support strength of the anchorage structure of surrounding rock were analyzed by the simulation using FLAC3D numerical software.The support scheme of the excavated roadway was then designed,and the effectiveness of this support scheme was further verified by the displacement measurement of the roadway.The results showed that the maximum displacement between the roof and floor of the west wing track roadway in Kouzidong coal mine,China is about 42 mm,and the maximum displacement between its both sides is about 72 mm,indicating that the support scheme proposed in this study can ensure the stability and safety of the excavated roadway.展开更多
Effects of different lead compounds, PbCl2, Pb(NO3)2 and Pb(OAc)2, on the rice growth and uptake of lead and some microelements by wetland rice were studied. The results showed that the seed germination, rice seedling...Effects of different lead compounds, PbCl2, Pb(NO3)2 and Pb(OAc)2, on the rice growth and uptake of lead and some microelements by wetland rice were studied. The results showed that the seed germination, rice seedling growth, chlorophyl content, grain yield and uptake of Pb, Cu, Zn, Fe and Mn by rice plant were affected by the chemical forms of Pb compounds added in soil to a certain degree. The germination rate and the amount of chlorophyl decreased remarkably with increasing Pb concentration, the root extension was restrained obviously by the presence of Pb, and the effect of PbCl2 was more evident than that of Pb(NO3)2 or Pb(OAc)2. The pot incubation test with yellow brown soil and red soil showed that there was no significant regularity in effect of Pb on grain yield, but the difference in the influence of various Pb compounds on yield was clearer. The effect on the amount of Pb in straw and brown rice was in the sequence of Pb(NO3)2> Pb(OAc)2> PbCl2. In case the content of Pb in brown rice was 0.5 mg/ kg, the relative loading capacities of yellow brown soil for Pb added as PbCl2, Pb(OAc)2 and Pb(NO3)2 were 100, 90 and 60 respectively. Pb uptake by wetland rice was closely related to the chemical species of Pb in soil, but there was no comparability among chemical forms of different Pb compounds in the same soil. The uptake of Cu, Zn, Fe and Mn by wetland rice was markedly affected by the addition of Pb, and different Pb compounds varied in their impacts on the uptake of other metals by different organs of wetland rice, e.g. the concentration of Fe in root increased significantly (r = 0.92), while opposite was true for Fe in brown rice (r =-0.92) due to the application of Pb(OAc), in soil. These results demonstrate that the effect of accompanying anions of Pb on the physiological and biochemical processes of wetland rice was rather complex.展开更多
An experimental study on the compressive behavior of steel fiber reinforced concrete-filled steel tube columns is presented. Specimens were tested to investigate the effects of the concrete strength, the thickness of ...An experimental study on the compressive behavior of steel fiber reinforced concrete-filled steel tube columns is presented. Specimens were tested to investigate the effects of the concrete strength, the thickness of steel tube and the steel fiber volume fraction on the ultimate strength and the ductility. The experimental results indicate that the addition of steel fibers in concrete can significantly improve the ductility and the energy dissipation capacity of the concrete-filled steel tube columns and delay the local buckling of the steel tube, but has no obvious effect on the failure mode. It has also been found that the addition of steel fibers is a more effective method than using thicker steel tube in enhancing the ductility, and more advantageous in the case of higher strength concrete. An analytical model to estimate the load capacity is proposed for steel tube columns filled with both plain concrete and steel fiber reinforced concrete. The predicted results are in good agreement with the experimental ones obtained in this work and literatures.展开更多
The rectifier filter circuit is widely applied.However,it is difficult to gain a global solution for the optimization design.4-D visual analysis and design optimization of the single-phase uncontrolled bridge rectifie...The rectifier filter circuit is widely applied.However,it is difficult to gain a global solution for the optimization design.4-D visual analysis and design optimization of the single-phase uncontrolled bridge rectifier with an LC filter are presented in this paper.展开更多
By increasing the yield strengths of austenitic stainless steels for pressure vessels with strain hardening techniques,the elastic load bearing capacity of austenitic stainless steel pressure vessels can be significan...By increasing the yield strengths of austenitic stainless steels for pressure vessels with strain hardening techniques,the elastic load bearing capacity of austenitic stainless steel pressure vessels can be significantly improved.Two kinds of strain hardening methods are often used for austenitic stainless steel pressure vessels:Avesta model for ambient temperature applications and Ardeform model for cryogenic temperature applications.Both methods are obtained from conventional design rules based on the linear elastic theory,and only consider the hardening effect from materials.Consequently this limits the applications of strain hardening techniques for austenitic stainless steel pressure vessels because of safety concerns.This paper investigates the effect of strain hardening on the load bearing capacity of austenitic stainless steel pressure vessels under large deformation,based on the elastic-plastic theory.Firstly,to understand the effect of strain hardening on material behavior,the plastic instability loads of a round tensile bar specimen are derived under two different loading paths and validated by experiments.Secondly,to investigate the effect of strain hardening on pressure vessels strength, the plastic instability pressure under strain hardening is derived and further validated by finite element simulations.Further,the safety margin of pressure vessels after strain hardening is analyzed by comparing the safety factor values calculated from bursting tests,finite element analyses,and standards.The researching results show that the load bearing capacity of pressure vessels at ambient temperature is independent of the loading history when the effects of both material strain hardening and structural deformation are considered.Finite element simulations and bursting tests results show that the minimum safety factor of austenitic stainless steel pressure vessels with 5% strain hardening is close to the recommended value for common pressure vessels specified in the European pressure vessel standard.The proposed study also shows that in the strain hardening design of austenitic stainless steel pressure vessels,the calculation for plastic instability pressure could use theoretical formula or finite element analyses based on geometrical dimensions and material property parameters before strain hardening,but a 5%strain should be employed as a design limit.The proposed research can be used for the strain hardening design of austenitic stainless steel pressure vessels safely.展开更多
In order to find out the bearing behavior of super-long piles located in deep soft clay over stiff layers around Dongting Lake, China, a test pile was first designed with the field loading test finished afterward. Bas...In order to find out the bearing behavior of super-long piles located in deep soft clay over stiff layers around Dongting Lake, China, a test pile was first designed with the field loading test finished afterward. Based on the measured test results, load transfer mechanism and bearing behavior of the pile shaft were discussed in detail. Then, by introducing a bi-linear model for shaft friction and the tri-linear model for pile tip resistance, respectively, the governing differential equation of pile soil system was set up by the load transfer method with the analytical solutions derived as well, taking into account the effect by stratified feature and various bearing conditions of subsoil, material nonlinearity, and the sediment under pile tip. Furthermore, formulas to determine the axial capacity of super-long piles by the pile top settlement were advised and applied to analyze the test pile. Good agreement between the predicted load settlement variations and the measured data is obtained to verify the validity of the present method. The results also show that, the axial bearing capacity of super-long piles should be controlled by the allowable pile top settlement, and buckling stability of the pile shaft should be paid attention as well.展开更多
The mechanism of a hydro-viscous soft start is of great importance in the design of a hydro-viscous clutch and its control system. To explain the mechanism of a hydro-viscous soft start, the startup process of a belt ...The mechanism of a hydro-viscous soft start is of great importance in the design of a hydro-viscous clutch and its control system. To explain the mechanism of a hydro-viscous soft start, the startup process of a belt conveyor was numerically analyzed with the modified Reynolds equation, an energy equation and a temperature-viscosity equation. The effect of temperature and grooves of the friction disk surface on torque transfer and load capacity of the oil film have also been analyzed. The results show that 1) the grooves are the basis of forming dynamic pressure but they may reduce the capacity of torque transfer to a certain extent, 2) during the startup process, temperature has little effect on torque transfer and load capacity and the variation in load capacity of the oil film is very small, indicating that it is preferable to use the flow rate as a control object than the pressure of the feed cylinder. The results have been verified by an experiment.展开更多
An emulsion-congealing technique is used to prepare solid lipid microparticles (SLM) containing ibuprofen with glyceryl behenate, tripalmitin and beewax as excipients. The difference of the solubility parameters bet...An emulsion-congealing technique is used to prepare solid lipid microparticles (SLM) containing ibuprofen with glyceryl behenate, tripalmitin and beewax as excipients. The difference of the solubility parameters between the excipients and ibuprofen are used to analyze their compatibility. Both the solubility parameter analysis and the experimental results show that glyceryl behenate is the best among the three excipients. The solid particles disperse well in aqueous phase when the drug loading reaches 10% (relative to lipid only). Glycerides exhibit marked polymorphism and their rapid rates of crystallization accelerate the formation of metastable crystal modification. The metastable crystal modification characterizes high drug loading capacity but less stability. Increasing the content of lipophilic drug in a lipid matrix facilitates the transformation of excipients to more stable polymorphic forms.展开更多
文摘Composite slabs with profiled steel sheet are widely applied in practical structures now. Plenty of literatures can be available about simply supported composite slabs with single span. However, continuous slabs always exist in high-rise building structures. In order to obtain the ultimate loading capacity of continuous composite slabs, the full scale test on slab specimens with high cost need to be carried out. This paper presented an analytical model for calculating the ultimate loading capacity of continuous composite slabs. Only the small-scale slide block test needed to be carried out for determining some mechanical parameters, resulting in less cost, compared with the conventional m-k test method. Various load conditions and parameters were considered in the analytical model. The comparison between test results and predicted results showed that the proposed method had enough precision. Furthermore, the simplified method was also proposed for practical design.
基金Supported by National Natural Science Foundation of China(Grant No.51275395)Major National Basic Research Program of China(973 Program,Grant Nos.2009CB724304-2,2009CB724404)
文摘Ultra-high speed machining technology enables high efficiency, high precision and high integrity of machined surface. Previous researches of hybrid bearing rarely consider influences of solid particles in lubricant and ultra-high speed of hybrid bearing, which cannot be ignored under the high speed and micro-space conditions of ultra-high speed water-lubricated hybrid bearing. Considering the impact of solid particles in lubricant, turbulence and temperature viscosity effects of lubricant, the influences of particles on pressure distribution, loading capacity and the temperature rise of the lubricant film with four-step-cavity ultra-high speed water-lubricated hybrid bearing are presented in the paper. The results show that loading capacity of the hybrid bearing can be affected by changing the viscosity of the lubricant, and large particles can improve the bearing loading capacity higher. The impact of water film temperature rise produced by solid particles in lubricant is related with particle diameter and minimum film thickness. Compared with the soft particles, hard particles cause the more increasing of water film temperature rise and loading capacity. When the speed of hybrid bearing increases, the impact of solid particles on hybrid bearing becomes increasingly apparent, especially for ultra-high speed water-lubricated hybrid bearing. This research presents influences of solid particles on the loading capacity and the temperature rise of water film in ultra-high speed hybrid bearings, the research conclusions provide a new method to evaluate the influence of solid particles in lubricant of ultra-high speed water-lubricated hybrid bearing, which is important to performance calculation of ultra-high speed hybrid bearings, design of filtration system, and safe operation of ultra-high speed hybrid bearings.
基金Project supported by the National Natural Science Foundation of China(51974026,21301104)the State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization。
文摘The relationship between dialkylphosphinic acid structure and their loading capacity for HREEs and emulsification phenomena has rarely been studied.In this paper,we took Lu extraction as an example to study the effect of β,γ,δ-substituents of dialkylphosphinic acids on their loading capacity and anti-emulsification performance for HREEs.To discuss conveniently,the dialkylphosphinic acids were classified into two groups:β-substituent group(P208,INET-1,P218,USTB-1 and P227)and γ,δ-substituent group(P218,P2132 and Cyanex 272).For β-substituent group extractants,their loading capacities are in the order P208(299.7 mg/L)≈INET-1(299.5 mg/L)>P218(270.8 mg/L)>>USTB-1(163.1 mg/L)>P227(151.4 mg/L),while their anti-emulsification/gelation performances are just in the opposite order P227>USTB-1>P218>P208≈INET-1 under the studied conditions.For γ,δ-substituent group extractants,their loading capacities are in the order P218(270.8 mg/L)>P2132(192.3 mg/L)>Cyanex272(131.7 mg/L),while the anti-emulsification performance of P218 is better than those of P2132 and Cyanex 272.The loading capacity data given in the parentheses are obtained through repeatedly extracting Lu from ~4×10^(-4)mol/L of Lu aqueous feed solution with initial pH of 2.40 by 0.01 mol/L extractant at phase ratio A/O of 1:1.
基金financially supported by the National Natural Science Foundation of China(Nos.61805083,31801968,and 51802281)。
文摘Surface modification of different functional molecules onto NaREF_(4)(RE=rare earth)upconversion nanoparticles(UCNPs)impart their multiple functionalities.Functional molecules can be loaded onto NaREF_(4) UCNPs through the formation of coordination bonds between the surface-exposed RE^(3+) ions and the appropriate chemical groups of functional molecules.The density of surface RE^(3+) ions directly determines the loading efficiency of Na REF4 UCNPs.However,NaREF_(4) is a binary cation system,rendering the surface-distributed Na;and RE^(3+) ions remains a mystery.Here,we develop an effective strategy to significantly enhance the density of surface RE^(3+) ions,thus maximizing the loading capacity of NaREF_(4) UCNPs.This strategy is based on a heterovalent cation exchange(HCE)reaction in the surface region in which Na^(+)ions are replaced by RE^(3+) ions.The density of surface ligands enhances from 3.6 to 8.8 molecules/nm^(2) after reaction,suggesting that the loading efficiency increases by approximately 150%.Benefiting from the improved loading capacity,we demonstrate such surface-RE-rich nanoparticles have the ability to offer higher colloidal stability and more desirable photodynamic therapy(PDT)efficacy.This work not only advances our understanding of cation exchange reactions in RE-based nanoparticles,but also provides significant value for considerable applications such as sensing,bioimaging,and therapy.
基金the National Natural Science Foundation of China,the China Postdoctoral Science Special Foundation,UTC Exploration Project,the Harbin City Science and Technology Projects
文摘Trusses used for roof support in coal mines are constructed of two grouted bolts installed at opposing forty-five degree angles into the roof and a cross member that ties the angled bolts together. The load on the cross member is vertical, which is transverse to the longitudinal axis, and therefore the cross member is loaded in the weakest direction. Laboratory tests were conducted to determine the vertical load capacity and deflection of three different types of cross members. Single-point load tests, with the load applied in the center of the specimen and double-point load tests, with a span of 2.4 m, were conducted. For the single-point load configuration, the yield of the 25 mm solid bar cross member was nominally 98 kN of vertical load, achieved at 42 cm of deflection. For cable cross members, yield was not achieved even after 45 cm of deflection. Peak vertical loads were about 89 kN for 17 mm cables and67 kN for the 15 mm cables. For the double-point load configurations, the 25 mm solid bar cross members yielded at 150 kN of vertical load and 25 cm of deflection. At 25 cm of deflection individual cable strands started breaking at 133 and 111 kN of vertical load for the 17 and 15 mm cable cross members respectively.
文摘The intersection of economic development,energy dynamics,environmental policy,and environmental sustainability presents complex challenges for European Union(EU)countries.This study investigatedthe impact of environmental taxes,hydroelectricity consumption,economic globalization,and gross domestic product(GDP)on the load capacity factor(LCF)in the 10 EU member countries(including Austria,Finland,France,Germany,Italy,Poland,Portugal,Slovakia,Spain,and Sweden)using data from 1995 to 2020.To ensure the reliability and validity of the data,this study applied several advanced econometric tests,including the Pesaran and Yamagata slopeheterogeneitytest,Pesaran cross-sectional dependence(CSD)test,second-generation unit root test,and Westerlund cointegration test.The data showed important statistical issues such as slope heterogeneityacross panels,CSD,mixed-orderunit root structures,and long-run associations between variables.To address these issues,we applied an augmented mean group(AMG)model as the main regression approach,andusedthe pooled mean group-autoregressive distributed lag(PMG-ARDL)method to check the robustness.Specifically,the AMG results indicate that a 1.000%rise in hydroelectricity consumptionresults in a 0.048% rise in the LCF,while a 1.000% increase in environmental taxes leads toa 0.175% increase in the LCF.Contrary to this,a 1.000% increase in economic globalization results in a 0.370% decrease in the LCF,and a 1.000% increase in GDP leads toa 0.850% decrease in the LCF.Environmental taxes have a more beneficial impact on the environment,and GDP has the most detrimental effect.The findings provide empirical evidence on the role of environmental taxes,hydroelectricity consumption,economic globalization,and GDP in driving the LCF.Additionally,the findings provide valuable information to policy-makers,academicians,and stakeholders shaping energy and environmental policies in the 10 EU member countries.
基金supported by the National Social Science Fund Project(No.23&ZD115)the Graduate Student Research Innovation Project of the School of Mathematics and Statistics,Hubei Minzu University(No.STK2023011)。
文摘Compared to single-layer networks,multilayer networks exhibit a more complex node degree composition,comprising both intra-layer and inter-layer degrees.However,the distinct impacts of these degree types on cascading failures remain underexplored.Distinguishing their effects is crucial for a deeper understanding of network structure,information propagation,and behavior prediction.This paper proposes a capacity-load model to influence and compare the influence of different degree types on cascading failures in multilayer networks.By designing three node removal strategies based on total degree,intra-layer degree,and inter-layer degree,simulation experiments are conducted on four types of networks.Network robustness is evaluated using the maximum number of removable nodes before collapse.The relationships between network robustness and the coupling coefficient,as well as load and capacity adjustment parameters,are also analyzed.The results indicate that the node removal strategy with the least impact on cascading failures varies across different types of networks,revealing the significance of different node degrees in failure propagation.Compared to other models,the proposed model enables networks to maintain a higher maximum number of removable nodes during cascading failures,demonstrating superior robustness.
文摘Captive model tests are one of the most common methods to calculate the maneuvering hydrodynamic coefficients and characteristics of surface and underwater vehicles.Considerable attention must be paid to selecting and designing the most suitable laboratory equipment for towing tanks.A computational fluid dynamics(CFD)-based method is implemented to determine the loads acting on the towing facility of the submarine model.A reversed topology is also used to ensure the appropriateness of the load cells in the developed method.In this study,the numerical simulations were evaluated using the experimental results of the SUBOFF benchmark submarine model of the Defence Advanced Research Projects Agency.The maximum and minimum loads acting on the 2.5-meter submarine model were measured by determining the body’s lightest and heaviest maneuvering test scenarios.In addition to having sufficient endurance against high loads,the precision in measuring the light load was also investigated.The horizontal planar motion mechanism(HPMM)facilities in the National Iranian Marine Laboratory were developed by locating the load cells inside the submarine model.The results were presented as a case study.A numerical-based method was developed to obtain the appropriate load measurement facilities.Load cells of HPMM test basins can be selected by following the two-way procedure presented in this study.
基金Post-Doctoral Innovative Projects of Shandong Province(No.200703072)the National Natural Science Foundation of China(No.50574053)
文摘In order to analyze the load carrying capacity of prestressed concrete box girders, failure behaviors of in-situ deteriorated continuous prestressed concrete box girders under loading are experimentally observed and a finite failure analysis method for predicting behaviors of box girders is developed. A degenerated solid shell element is used to simulate box girders and material nonlinearity is considered. Since pre-stressed concrete box girders usually have a large number of curve prestressed tendons, a type of combined element is presented to simulate the prestressed tendons of box girders, and then the number of elements can be significantly reduced. The analytical results are compared with full-scale failure test results. The comparison shows that the presented method can be effectively applied to the failure analysis of in-situ continuous prestressed concrete box girders, and it also shows that the studied old bridge still has enough load carrying capacity.
基金The National Natural Science Foundation of China(No. 50808043)the National Basic Research Program of China (973 Program) (No. 2009CB623200)Foundation of Jiangsu Key Laboratory of Construction Materials,Program for Special Talents in Six Fields of Jiangsu Province(No. 2011-JZ-010)
文摘An engineered cementitious composite (ECC) is introduced to partially substitute concrete in the tension zone of a reinforced concrete beam to form an ECC/reinforced concrete (RC) composite beam, which can increase the ductility and crack resisting ability of the beam. Based on the assumption of the plane remaining plane and the simplified constitutive models of materials, the stress and strain distributions along the depth of the composite beam in different loading stages are comprehensively investigated to obtain calculation methods of the load-carrying capacities for different stages. Also, a simplified formula for the ultimate load carrying capacity is proposed according to the Chinese code for the design of concrete structures. The relationship between the moment and curvature for the composite beam is also proposed together with a simplified calculation method for ductility of the ECC/RC composite beam. Finally, the calculation method is demonstrated with the test results of a composite beam. Comparison results show that the calculation results have good consistency with the test results, proving that the proposed calculation methods are reliable with a certain theoretical significance and reference value.
基金Supported by Ministry of Metallurgical Industry of China
文摘The prosperous post buckling load capacity of web plates of box girders can be used.In this article,the post buckling behaviour of web plates of box girders under different loading conditions is theoretically analyzed and on the basis of domestic and overseas design codes of steel structures,the corresponding simplified analysis methods are put forward for the engineering design or code revision.It is proved that the simplified methods are safe,efficient and practicable through the comparison between several results.
基金supported by the National Natural Science Foundation of China(51734009)National Key Basic Research and Development Program of China(2017YFC0603001).
文摘This paper investigated the stress evolution,displacement field,local deformation and its overall distribution,and failure characteristics of the anchorage structure of surrounding rock with different rockbolt spacing through the model experiments.The influences of the pre-tightening force and spacing of rockbolt on the support strength of the anchorage structure of surrounding rock were analyzed by the simulation using FLAC3D numerical software.The support scheme of the excavated roadway was then designed,and the effectiveness of this support scheme was further verified by the displacement measurement of the roadway.The results showed that the maximum displacement between the roof and floor of the west wing track roadway in Kouzidong coal mine,China is about 42 mm,and the maximum displacement between its both sides is about 72 mm,indicating that the support scheme proposed in this study can ensure the stability and safety of the excavated roadway.
文摘Effects of different lead compounds, PbCl2, Pb(NO3)2 and Pb(OAc)2, on the rice growth and uptake of lead and some microelements by wetland rice were studied. The results showed that the seed germination, rice seedling growth, chlorophyl content, grain yield and uptake of Pb, Cu, Zn, Fe and Mn by rice plant were affected by the chemical forms of Pb compounds added in soil to a certain degree. The germination rate and the amount of chlorophyl decreased remarkably with increasing Pb concentration, the root extension was restrained obviously by the presence of Pb, and the effect of PbCl2 was more evident than that of Pb(NO3)2 or Pb(OAc)2. The pot incubation test with yellow brown soil and red soil showed that there was no significant regularity in effect of Pb on grain yield, but the difference in the influence of various Pb compounds on yield was clearer. The effect on the amount of Pb in straw and brown rice was in the sequence of Pb(NO3)2> Pb(OAc)2> PbCl2. In case the content of Pb in brown rice was 0.5 mg/ kg, the relative loading capacities of yellow brown soil for Pb added as PbCl2, Pb(OAc)2 and Pb(NO3)2 were 100, 90 and 60 respectively. Pb uptake by wetland rice was closely related to the chemical species of Pb in soil, but there was no comparability among chemical forms of different Pb compounds in the same soil. The uptake of Cu, Zn, Fe and Mn by wetland rice was markedly affected by the addition of Pb, and different Pb compounds varied in their impacts on the uptake of other metals by different organs of wetland rice, e.g. the concentration of Fe in root increased significantly (r = 0.92), while opposite was true for Fe in brown rice (r =-0.92) due to the application of Pb(OAc), in soil. These results demonstrate that the effect of accompanying anions of Pb on the physiological and biochemical processes of wetland rice was rather complex.
基金Project(51078294)supported by the National Natural Science Foundation of ChinaProject(201101411100025)supported by the Doctoral Fund of Ministry of Education of China
文摘An experimental study on the compressive behavior of steel fiber reinforced concrete-filled steel tube columns is presented. Specimens were tested to investigate the effects of the concrete strength, the thickness of steel tube and the steel fiber volume fraction on the ultimate strength and the ductility. The experimental results indicate that the addition of steel fibers in concrete can significantly improve the ductility and the energy dissipation capacity of the concrete-filled steel tube columns and delay the local buckling of the steel tube, but has no obvious effect on the failure mode. It has also been found that the addition of steel fibers is a more effective method than using thicker steel tube in enhancing the ductility, and more advantageous in the case of higher strength concrete. An analytical model to estimate the load capacity is proposed for steel tube columns filled with both plain concrete and steel fiber reinforced concrete. The predicted results are in good agreement with the experimental ones obtained in this work and literatures.
文摘The rectifier filter circuit is widely applied.However,it is difficult to gain a global solution for the optimization design.4-D visual analysis and design optimization of the single-phase uncontrolled bridge rectifier with an LC filter are presented in this paper.
基金supported by National Key Technology R&D Program of China under the 11th Five-year(Grant No.2006BAK02B02),and China Special Equipment Science & Technology Cooperation Platform
文摘By increasing the yield strengths of austenitic stainless steels for pressure vessels with strain hardening techniques,the elastic load bearing capacity of austenitic stainless steel pressure vessels can be significantly improved.Two kinds of strain hardening methods are often used for austenitic stainless steel pressure vessels:Avesta model for ambient temperature applications and Ardeform model for cryogenic temperature applications.Both methods are obtained from conventional design rules based on the linear elastic theory,and only consider the hardening effect from materials.Consequently this limits the applications of strain hardening techniques for austenitic stainless steel pressure vessels because of safety concerns.This paper investigates the effect of strain hardening on the load bearing capacity of austenitic stainless steel pressure vessels under large deformation,based on the elastic-plastic theory.Firstly,to understand the effect of strain hardening on material behavior,the plastic instability loads of a round tensile bar specimen are derived under two different loading paths and validated by experiments.Secondly,to investigate the effect of strain hardening on pressure vessels strength, the plastic instability pressure under strain hardening is derived and further validated by finite element simulations.Further,the safety margin of pressure vessels after strain hardening is analyzed by comparing the safety factor values calculated from bursting tests,finite element analyses,and standards.The researching results show that the load bearing capacity of pressure vessels at ambient temperature is independent of the loading history when the effects of both material strain hardening and structural deformation are considered.Finite element simulations and bursting tests results show that the minimum safety factor of austenitic stainless steel pressure vessels with 5% strain hardening is close to the recommended value for common pressure vessels specified in the European pressure vessel standard.The proposed study also shows that in the strain hardening design of austenitic stainless steel pressure vessels,the calculation for plastic instability pressure could use theoretical formula or finite element analyses based on geometrical dimensions and material property parameters before strain hardening,but a 5%strain should be employed as a design limit.The proposed research can be used for the strain hardening design of austenitic stainless steel pressure vessels safely.
基金Project(50908084)supported by the National Natural Science Foundation of ChinaProject(200815)supported by the Transportation Science and Technology Program of Hunan Province,ChinaProject(531107040620)supported by the Growth Plan for Young Teachers of Hunan University,China
文摘In order to find out the bearing behavior of super-long piles located in deep soft clay over stiff layers around Dongting Lake, China, a test pile was first designed with the field loading test finished afterward. Based on the measured test results, load transfer mechanism and bearing behavior of the pile shaft were discussed in detail. Then, by introducing a bi-linear model for shaft friction and the tri-linear model for pile tip resistance, respectively, the governing differential equation of pile soil system was set up by the load transfer method with the analytical solutions derived as well, taking into account the effect by stratified feature and various bearing conditions of subsoil, material nonlinearity, and the sediment under pile tip. Furthermore, formulas to determine the axial capacity of super-long piles by the pile top settlement were advised and applied to analyze the test pile. Good agreement between the predicted load settlement variations and the measured data is obtained to verify the validity of the present method. The results also show that, the axial bearing capacity of super-long piles should be controlled by the allowable pile top settlement, and buckling stability of the pile shaft should be paid attention as well.
文摘The mechanism of a hydro-viscous soft start is of great importance in the design of a hydro-viscous clutch and its control system. To explain the mechanism of a hydro-viscous soft start, the startup process of a belt conveyor was numerically analyzed with the modified Reynolds equation, an energy equation and a temperature-viscosity equation. The effect of temperature and grooves of the friction disk surface on torque transfer and load capacity of the oil film have also been analyzed. The results show that 1) the grooves are the basis of forming dynamic pressure but they may reduce the capacity of torque transfer to a certain extent, 2) during the startup process, temperature has little effect on torque transfer and load capacity and the variation in load capacity of the oil film is very small, indicating that it is preferable to use the flow rate as a control object than the pressure of the feed cylinder. The results have been verified by an experiment.
基金Supported by the National Natural Science Foundation of China (No.20536020, No.20476033), the China Distinguished Young Scientist Fund (No.20225620) and Guangdong Province Science Fund (No.04020121).
文摘An emulsion-congealing technique is used to prepare solid lipid microparticles (SLM) containing ibuprofen with glyceryl behenate, tripalmitin and beewax as excipients. The difference of the solubility parameters between the excipients and ibuprofen are used to analyze their compatibility. Both the solubility parameter analysis and the experimental results show that glyceryl behenate is the best among the three excipients. The solid particles disperse well in aqueous phase when the drug loading reaches 10% (relative to lipid only). Glycerides exhibit marked polymorphism and their rapid rates of crystallization accelerate the formation of metastable crystal modification. The metastable crystal modification characterizes high drug loading capacity but less stability. Increasing the content of lipophilic drug in a lipid matrix facilitates the transformation of excipients to more stable polymorphic forms.