The stability control of surrounding rock for large or super-large section chamber is a difficult technical problem in deep mining condition.Based on the in-site geological conditions of Longgu coal mine,this paper us...The stability control of surrounding rock for large or super-large section chamber is a difficult technical problem in deep mining condition.Based on the in-site geological conditions of Longgu coal mine,this paper used the dynamic module of FLAC3D to study the response characteristics of deep super-large section chamber under dynamic and static combined loading condition.Results showed that under the static loading condition,the maximum vertical stress,deformation and failure range are large,where the stress concentration coefficient is 1.64.The maximum roof-to-floor and two-sides deformations are 54.6 mm and 53.1 mm,respectively.Then,under the dynamic and static combined loading condition:(1)The influence of dynamic load frequency on the two-sides is more obvious;(2)The dynamic load amplitude has the greatest influence on the stress concentration degree,and the plastic failure tends to develop to the deeper;(3)With the dynamic load source distance increase,the response of surrounding rock is gradually attenuated.On this basis,empirical equations for each dynamic load conditions were obtained by using regression analysis method,and all correlation coefficients are greater than 0.99.This research provided reference for the supporting design of deep super-large section chamber under same or similar conditions.展开更多
Based on the density functional theory(DFT),we investigate the friction properties of inevitable oxidized black phosphorus(o-BP).o-BP with the weaker interlayer adhesion exhibits their great potential as a solid lubri...Based on the density functional theory(DFT),we investigate the friction properties of inevitable oxidized black phosphorus(o-BP).o-BP with the weaker interlayer adhesion exhibits their great potential as a solid lubricant.At the zero load,the friction property of o-BP is adjusted by its oxidation degree.Expressly,ultra-low friction of P4O2(50%oxidation,O:P=2:4=50%)is obtained,which is attributed to the upper O atoms with lower sliding resistance in the O channel formed by lower layer O atoms.More attractive,we observe superlubricity behavior of o-BP at the critical load/distance due to the flattening potential energy surface(PES).The flattening PES is controlled by the electrostatic role for the high-load(P4O3,O:P=3:4=75%),and by the electrostatic and dispersion roles for the low-load(P4O2).Distinctly,the transform from ultra-low friction to superlubricity state of black phosphorus(BP)can be achieved by critical oxidation and load,which shows an important significance in engineering application.In addition,negative friction behavior of o-BP is a general phenomenon(Z>Z_(min),Z_(min)is the interlayer distances between the outermost P atoms of minimum load.),while its surface-surface model is different from the fold mechanism of the tip-surface model(Z_(0)<Z<Z_(min),Z_(0)is the interlayer distances between the outermost P atoms of equilibrium state.).Thus,this phenomenon cannot be captured due to the jump effect with instability of the atomic force microscopy(AFM)(Z>Z_(min)).In summary,o-BP improves the friction performance and reduces the application limitation,comparing to graphene(Gr),MoS2,and their oxides.展开更多
基金Project(2018YFC0604703)supported by the National Key R&D Program of ChinaProjects(51804181,51874190)supported by the National Natural Science Foundation of China+3 种基金Project(ZR2018QEE002)supported by the Shandong Province Natural Science Fund,ChinaProject(ZR2018ZA0603)supported by the Major Program of Shandong Province Natural Science Foundation,ChinaProject(2019GSF116003)supported by the Key R&D Project of Shandong Province,ChinaProject(SDKDYC190234)supported by the Shandong University of Science and Technology,Graduate Student Technology Innovation Project,China。
文摘The stability control of surrounding rock for large or super-large section chamber is a difficult technical problem in deep mining condition.Based on the in-site geological conditions of Longgu coal mine,this paper used the dynamic module of FLAC3D to study the response characteristics of deep super-large section chamber under dynamic and static combined loading condition.Results showed that under the static loading condition,the maximum vertical stress,deformation and failure range are large,where the stress concentration coefficient is 1.64.The maximum roof-to-floor and two-sides deformations are 54.6 mm and 53.1 mm,respectively.Then,under the dynamic and static combined loading condition:(1)The influence of dynamic load frequency on the two-sides is more obvious;(2)The dynamic load amplitude has the greatest influence on the stress concentration degree,and the plastic failure tends to develop to the deeper;(3)With the dynamic load source distance increase,the response of surrounding rock is gradually attenuated.On this basis,empirical equations for each dynamic load conditions were obtained by using regression analysis method,and all correlation coefficients are greater than 0.99.This research provided reference for the supporting design of deep super-large section chamber under same or similar conditions.
基金The authors were grateful to the financial support from the National Natural Science Foundation of China(52175168)the Natural Science Foundation of Guangdong Province(2021A1515012266),ChinaGuangdong Basic and Applied Basic Research Foundation(2022A1515010513),China.
文摘Based on the density functional theory(DFT),we investigate the friction properties of inevitable oxidized black phosphorus(o-BP).o-BP with the weaker interlayer adhesion exhibits their great potential as a solid lubricant.At the zero load,the friction property of o-BP is adjusted by its oxidation degree.Expressly,ultra-low friction of P4O2(50%oxidation,O:P=2:4=50%)is obtained,which is attributed to the upper O atoms with lower sliding resistance in the O channel formed by lower layer O atoms.More attractive,we observe superlubricity behavior of o-BP at the critical load/distance due to the flattening potential energy surface(PES).The flattening PES is controlled by the electrostatic role for the high-load(P4O3,O:P=3:4=75%),and by the electrostatic and dispersion roles for the low-load(P4O2).Distinctly,the transform from ultra-low friction to superlubricity state of black phosphorus(BP)can be achieved by critical oxidation and load,which shows an important significance in engineering application.In addition,negative friction behavior of o-BP is a general phenomenon(Z>Z_(min),Z_(min)is the interlayer distances between the outermost P atoms of minimum load.),while its surface-surface model is different from the fold mechanism of the tip-surface model(Z_(0)<Z<Z_(min),Z_(0)is the interlayer distances between the outermost P atoms of equilibrium state.).Thus,this phenomenon cannot be captured due to the jump effect with instability of the atomic force microscopy(AFM)(Z>Z_(min)).In summary,o-BP improves the friction performance and reduces the application limitation,comparing to graphene(Gr),MoS2,and their oxides.
