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Enabling ultranarrow blue emission linewidths in colloidal alloy quantum dots by decreasing the exciton fine structure splitting and exciton–phonon coupling
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作者 Jinke Bai Linfeng Wang +9 位作者 Tingting Zhang Tianyi Hou Meilun Zhang Bing Xu Dongyu Li Xiao Jin Qinghua Li Yuxiao Wang Xueru Zhang Yinglin Song 《Nano Research》 SCIE EI CSCD 2023年第1期1576-1585,共10页
The realization of colloidal alloy quantum dots(QDs)with narrow spectral linewidths requires minimization of the contributions of inhomogeneous and homogeneous broadening to the ensemble spectrum.Recently,there has be... The realization of colloidal alloy quantum dots(QDs)with narrow spectral linewidths requires minimization of the contributions of inhomogeneous and homogeneous broadening to the ensemble spectrum.Recently,there has been remarkable progress in eliminating the inhomogeneous contribution by controlling the size distribution of the QDs.However,considerable challenges remain in suppressing the homogeneous broadening,in terms of both intrinsic principles and rational synthetic routes.We find that ground-state exciton fine structure splitting and exciton-phonon coupling play a pivotal role in the homogeneous broadening mechanism.Here we demonstrate that the elimination of the lattice mismatch strain by using a coherent strain structure can decrease the light-heavy hole splitting,thus suppressing the asymmetric broadening of the emission on the high energy side.Besides,the improvement of the uniformity of the alloy by using a stepwise ion exchange strategy can weaken the exciton-longitudinal optical(LO)-phonon interactions,further minimizing the homogeneous broadening.As a result,the final alloy QD products exhibit a widely tunable blue emission wavelength(445-470 nm)with the narrowest ensemble photoluminescence full width at half maximum(FWHM)of 10.1-13.5 nm(or 58.4-75.3 meV).Our study provides a potential strategy for other semiconductor nanocrystals with ultranarrow spectral linewidths. 展开更多
关键词 alloy quantum dots spectral linewidth light-heavy hole splitting exciton-phonon coupling homogeneous broadening
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Design of distributed feedback grating for QCL based on time-domain finite-difference method
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作者 CUI Jintao CHEN Guang +3 位作者 ZHANG Dongliang ZHANG Shiya LU Lidan ZHU Lianqing 《Optoelectronics Letters》 2025年第9期520-527,共8页
Quantum cascade lasers(QCLs) have broad application potentials in infrared countermeasure system,free-space optical communication and trace gas detection.Compared with traditional Fabry-Pérot(FP) cavity and exter... Quantum cascade lasers(QCLs) have broad application potentials in infrared countermeasure system,free-space optical communication and trace gas detection.Compared with traditional Fabry-Pérot(FP) cavity and external cavity,distributed feedback quantum cascade lasers(DFB-QCLs) can obtain narrower laser linewidth and higher integration.In this paper,the structure design,numerical simulation and optimization of the Bragg grating of DFB-QCLs are carried out to obtain the transmission spectrum with central wavelength at 4.6 μm.We analyze the relationship among the structure parameters,the central wavelength shift and transmission efficiency using coupled-wave theory and finite-difference time-domain(FDTD) method.It is shown that the increase in the number of grating periods enhances the capabilities of mode selectivity,while the grating length of a single period adjustment directly determines the Bragg wavelength.Additionally,variations in etching depth and duty cycle lead to blue and red shifts in the central wavelength,respectively.Based on the numerical simulation results,the optimized design parameters for the upper buffer layer and the upper cladding grating are proposed,which gives an optional scheme for component fabrication and performance improvement in the future. 展开更多
关键词 trace gas detectioncompared transmission spectrum central wavelen structure designnumerical simulation narrower laser linewidth quantum cascade lasers qcls quantum cascade lasers infrared countermeasure systemfree space feedback quantum cascade lasers dfb qcls
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Effect of DBR Geometry on Reflectivity and Spectral Linewidth of DBR Lasers 被引量:1
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作者 方达伟 张艺 +2 位作者 李晨霞 Manzaneda C 李波 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第12期2315-2319,共5页
The linewidths of InGaAs-GaAs-AlGaAs DBR lasers with varied DBR dimensional parameters are measured and analyzed. These lasers were built with different DBR grating lengths and depths in order to explore the effect of... The linewidths of InGaAs-GaAs-AlGaAs DBR lasers with varied DBR dimensional parameters are measured and analyzed. These lasers were built with different DBR grating lengths and depths in order to explore the effect of the size of the DBR on its coupling coefficient and reflectivity,and hence on the linewidth of the laser diodes. The linewidths were measured by employing a self heterodyne linewidth measurement system. The experimental and calculated data for DBR reflectivity and spectral linewidth are given. The relationship between these data and the dimensions of the DBR is analyzed. Based on this analysis,the effect of the DBR geometry on the linewidth of the lasers is explored. The results give useful information related to the design and fabrication of such DBR lasers. 展开更多
关键词 LINEWIDTH distributed Bragg reflector InGaAs-GaAs-AlGaAs semiconductor lasers
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An Exact Expression for Fractional Absorption in Mossbauer Spectroscopy
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作者 Chen Yi-long Lu Ning +1 位作者 Peng Li-li Zhao Lei 《Wuhan University Journal of Natural Sciences》 EI CAS 2001年第4期784-786,共3页
The fractional resonance absorption ε(0) in transmission Mossbauer spectroscopy is defined as a relative number of the absorbed γ-ray, and regarded as a measure of Mossbauer effect. The absorption linewidth Λ a , a... The fractional resonance absorption ε(0) in transmission Mossbauer spectroscopy is defined as a relative number of the absorbed γ-ray, and regarded as a measure of Mossbauer effect. The absorption linewidth Λ a , as it is usually suggested, is nearly equal to the emission linewidth, Λ s , and such an approximation leads to a extremely simplified expression ε(0), depending on neither Λ s nor Λ a . We consider the general case Λ s ≠Λ a , and obtain an exact expression for ε(0) which is given in the present paper. This expression ε(0), as a function oft a, Λ s , Λ a , is figured and discussed. 展开更多
关键词 Mossbauer effect fractional resonance absorption emission and absorption linewidths
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Influence of laser linewidth on performance of Brillouin optical time domain reflectometry 被引量:6
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作者 郝蕴琦 叶青 +2 位作者 潘政清 蔡海文 瞿荣辉 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第7期257-261,共5页
The effects of optical sources with different laser linewidths on Brillouin optical time domain reflectometry (BOTDR) are investigated numerically and experimentally. Simulation results show that the spectral linewi... The effects of optical sources with different laser linewidths on Brillouin optical time domain reflectometry (BOTDR) are investigated numerically and experimentally. Simulation results show that the spectral linewidth of spontaneous Brillouin scattering remains almost constant when the laser linewidth is less than 1 MHz at the same pulse width; otherwise, it increases sharply. A comparison between a fiber laser (FL) with 4-kHz linewidth at 3 dB and a distributed feedback (DFB) laser with 3-MHz linewidth is made experimentally. When a constant laser power is launched into the sensing fiber, the fitting linewidths of the beat signals (backscattered Brillouin light and local oscillator (LO)) is about 5 MHz wider for the DFB laser than for the FL and the intensity of the beat signal is about a half. Furthermore, the frequency fluctuation in the long sensing fiber is lower for the FL source, yielding about 2 MHz less than that of the DFB laser, indicating higher temperature/strain resolution. The experimental results are in good agreement with the numerical simulations. 展开更多
关键词 Brillouin optical time domain reflectometry (BOTDR) laser linewidth distributed feedback laser fiber laser
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Two-hertz-linewidth Nd:YAG lasers at 1064 nm stabilized to vertically mounted ultra-stable cavities 被引量:5
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作者 蒋燕义 毕志毅 +1 位作者 徐信业 马龙生 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第6期2152-2155,共4页
Two Nd:YAG lasers operating at 1064 nm are separately servo-locked to two vertically mounted ultra-stable cavities. The optical heterodyne beat between two cavity-stabilized lasers shows that the linewidth of each la... Two Nd:YAG lasers operating at 1064 nm are separately servo-locked to two vertically mounted ultra-stable cavities. The optical heterodyne beat between two cavity-stabilized lasers shows that the linewidth of each laser reaches 2 Hz and the average frequency drift reduces to less than 1 Hz/s. 展开更多
关键词 narrow linewidth laser laser frequency stabilization high finesse cavity optical clock
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Effect of Interconnect Linewidth on Evolution of Intragranular Microcracks Due to Electromigration Analyzed by Finite Element Method 被引量:3
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作者 HE Dingni HUANG Peizhen 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2019年第2期290-297,共8页
The effect of interconnect linewidth on the evolution of intragranular microcracks due to surface diffusion induced by electromigration is analyzed by finite element method.The numerical results indicate that there ex... The effect of interconnect linewidth on the evolution of intragranular microcracks due to surface diffusion induced by electromigration is analyzed by finite element method.The numerical results indicate that there exists critical values of the linewidth hc,the electric fieldχc and the aspect ratioβc.When h>hc,χ<χc orβ<βc,the microcrack will evolve into a stable shape as it migrates along the interconnect line.When h≤hc,χ≥χc orβ≥βc,the microcrack will split into two smaller microcracks.The critical electric field,the critical aspect ratio and the splitting time have a stronger dependence on the linewidth when h≤6.In addition,the decrease of the linewidth,the increase of the electric field or the aspect ratio is beneficial to accelerate microcrack splitting,which may delay the open failure of the interconnect line. 展开更多
关键词 finite element method surface diffusion ELECTROMIGRATION LINEWIDTH MICROCRACK EVOLUTION
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Waveguide external cavity narrow linewidth semiconductor lasers 被引量:4
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作者 Chanchan Luo Ruiying Zhang +1 位作者 Bocang Qiu Wei Wang 《Journal of Semiconductors》 EI CAS CSCD 2021年第4期90-97,共8页
Narrow linewidth light source is a prerequisite for high-performance coherent optical communication and sensing.Waveguide-based external cavity narrow linewidth semiconductor lasers(WEC-NLSLs)have become a competitive... Narrow linewidth light source is a prerequisite for high-performance coherent optical communication and sensing.Waveguide-based external cavity narrow linewidth semiconductor lasers(WEC-NLSLs)have become a competitive and attractive candidate for many coherent applications due to their small size,volume,low energy consumption,low cost and the ability to integrate with other optical components.In this paper,we present an overview of WEC-NLSLs from their required technologies to the state-of-the-art progress.Moreover,we highlight the common problems occurring to current WEC-NLSLs and show the possible approaches to resolving the issues.Finally,we present the possible development directions for the next phase and hope this review will be beneficial to the advancements of WEC-NLSLs. 展开更多
关键词 semiconductor laser narrow linewidth waveguide external cavity
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Broad bandwidth interference filter-stabilized external cavity diode laser with narrow linewidth below 100kHz 被引量:4
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作者 潘冠中 关宝璐 +3 位作者 徐晨 李鹏涛 杨嘉炜 刘振杨 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第1期381-384,共4页
Interference filter-stabilized external cavity diode lasers (ECDLs) have properties of simple configurations, high sta- bilities, and narrow linewidths. However, the interference filter used in common ECDL designs r... Interference filter-stabilized external cavity diode lasers (ECDLs) have properties of simple configurations, high sta- bilities, and narrow linewidths. However, the interference filter used in common ECDL designs requires an ultra-narrow bandwidth (about 0.3 nm) to achieve mode selection, that is considerably expensive and not yet available for a wide range of wavelengths. In this paper, a robust ECDL using an available broad bandwidth (about 4 nm) interference filter as the wavelength discriminator is constructed and tested. The ECDL demonstrated a narrow Lorentzian fitted linewidth of 95 kHz and a spectral purity of 2.9 MHz. The long-term frequency stability of the ECDL reaches 5.59 x 10 12. 展开更多
关键词 external cavity diode laser narrow linewidth high frequency stability
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Transverse relaxation determination based on light polarization modulation for spin-exchange relaxation free atomic magnetometer 被引量:4
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作者 Xue-Jing Liu Ming Ding +3 位作者 Yang Li Yan-Hui Hu Wei Jin Jian-Cheng Fang 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第7期276-280,共5页
A transverse relaxation determination of spin-exchange relaxation free (SERF) magnetometer based on polarization modulation technique is proposed. Compared with the radio-frequency (RF) excitation and light intens... A transverse relaxation determination of spin-exchange relaxation free (SERF) magnetometer based on polarization modulation technique is proposed. Compared with the radio-frequency (RF) excitation and light intensity excitation meth- ods used in SERF magnetometer, the light polarization modulation method has a high stability in low-frequency range, which indicates a more accurate transverse relaxation measurement. 展开更多
关键词 spin-exchange relaxation free (SERF) magnetometer LINEWIDTH optical polarization modulation
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Spectral feature with sub-natural linewidth due to quantum interference in a four-level system 被引量:2
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作者 杨丽君 张连水 +2 位作者 庄仲红 郭庆林 傅广生 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第6期2147-2151,共5页
This paper studies the narrow spectral feature appearing in a four-level system coupled by two strong coherent fields and probed by a weak laser field. The linewidth is examined as a function of the Rabi frequencies o... This paper studies the narrow spectral feature appearing in a four-level system coupled by two strong coherent fields and probed by a weak laser field. The linewidth is examined as a function of the Rabi frequencies of coupling fields, and the result is explained by using the dressed-state formalism. 展开更多
关键词 quantum interference LINEWIDTH dressed-state
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Ultra-high spectral purity laser derived from weak external distributed perturbation 被引量:2
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作者 Laiyang Dang Ligang Huang +7 位作者 Leilei Shi Fuhui Li Guolu Yin Lei Gao Tianyi Lan Yujia Li Lidan Jiang Tao Zhu 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2023年第2期39-48,共10页
Ultra-high spectral purity lasers are of considerable research interests in numerous fields such as coherent optical communication,microwave photonics,distributed optical fiber sensing,gravitational wave detection,opt... Ultra-high spectral purity lasers are of considerable research interests in numerous fields such as coherent optical communication,microwave photonics,distributed optical fiber sensing,gravitational wave detection,optical clock,and so on.Herein,to deeply purify laser spectrum with compact size under normal condition,we propose a novel and practical idea to effectively suppress the spontaneous radiation of the laser cavity through weak external distributed perturbation.Subsequently,a laser configuration consisting of a main lasing cavity and an external distributed feedback cavity is proposed.The feedback signal with continuous spatio-temporal phase transition controlled by a distributed feedback structure is injected into the main cavity,which can deeply suppress the coupling rate from the spontaneous radiation to the stimulated emission and extremely purify the laser spectrum.Eventually,an ultra-narrow linewidth on-chip laser system with a side mode suppression ratio greater than 80 dB,an output linewidth of 10 Hz,and a relative intensity noise less than-150 dB/Hz is successfully obtained under normal conditions.The proposed concept in this work provides a new perspective for extreme regulation of laser parameters by using weak external distributed perturbation,which can be valid for various gain-type lasers with wide wavelength bands. 展开更多
关键词 high-coherence weak external distributed perturbation narrow linewidth LASER
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Influences of semiconductor laser on fibre-optic distributed disturbance sensor based on Mach-Zehnder interferometer 被引量:2
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作者 梁生 张春熹 +4 位作者 蔺博 林文台 李勤 钟翔 李立京 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第12期339-346,共8页
This paper investigates the influences of a semiconductor laser with narrow linewidth on a fibre-optic distributed disturbance sensor based on Mach-Zehnder interferometer. It establishes an effective numerical model t... This paper investigates the influences of a semiconductor laser with narrow linewidth on a fibre-optic distributed disturbance sensor based on Mach-Zehnder interferometer. It establishes an effective numerical model to describe the noises and linewidth of a semiconductor laser, taking into account their correlations. Simulation shows that frequency noise has great influences on location errors and their relationship is numerically investigated. Accordingly, there is need to determine the linewidth of the laser less than a threshold and obtain the least location errors. Furthermore, experiments are performed by a sensor prototype using three semiconductor lasers with different linewidths, respectively, with polarization maintaining optical fibres and couplers to eliminate the polarization induced noises and fading. The agreement of simulation with experimental results means that the proposed numerical model can make a comprehensive description of the noise behaviour of a semiconductor laser. The conclusion is useful for choosing a laser source for fibre-optic distributed disturbance sensor to achieve optimized location accuracy. What is more, the proposed numerical model can be widely used for analysing influences of semiconductor lasers on other sensing, communication and optical signal processing systems. 展开更多
关键词 fibre-optic distributed sensor semiconductor laser narrow linewidth laser fibre-optic interferometric sensor
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Transportable 1555-nm Ultra-Stable Laser with Sub-0.185-Hz Linewidth 被引量:8
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作者 Zhao-Yang Tai Lu-Lu Yan +4 位作者 Yan-Yan Zhang Xiao-Fei Zhang Wen-Ge Guo Shou-Gang Zhang Hai-Feng Jiang 《Chinese Physics Letters》 SCIE CAS CSCD 2017年第9期33-36,共4页
We present two cavity-stabilized lasers at 1555 nm, which are built to be the frequency source for a transportable photonic microwave generation system. The frequency instability reaches the thermal noise limit (7 &#... We present two cavity-stabilized lasers at 1555 nm, which are built to be the frequency source for a transportable photonic microwave generation system. The frequency instability reaches the thermal noise limit (7 ×10-16) of the 10-cm ultra-low expansion glass cavity at 1-10s averaging time and the beat signal of the two lasers reveals a remarkable linewidth of 185mHz. 展开更多
关键词 Transportable 1555-nm Ultra-Stable Laser with Sub-0.185-Hz Linewidth
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Spectrum evolution of Rayleigh backscattering in one‐dimensional waveguide 被引量:2
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作者 Fuhui Li Tianyi Lan +3 位作者 Ligang Huang Iroegbu Paul Ikechukwu Wuming Liu Tao Zhu 《Opto-Electronic Advances》 2019年第8期2-8,共7页
Despite the tremendous awareness of Rayleigh scattering characteristics and its considerable research interest for numerous fields,no report has been documented on the dynamic characteristics of spectrum evolution(SpE... Despite the tremendous awareness of Rayleigh scattering characteristics and its considerable research interest for numerous fields,no report has been documented on the dynamic characteristics of spectrum evolution(SpE)and physical law for Rayleigh scattering from a micro perspective.Herein,the dynamic characteristics of the SpE of Rayleigh scattering in a one-dimensional waveguide(ODW)is investigated based on the quantum theory and a SpE-model of Rayleigh backscattering(RBS)source is established.By means of simulation,the evolution law which represents the dynamic process of the spectrum linewidth at a state of continuous scattering is revealed,which is consistent with our previous experimental observation.Moreover,an approximate theoretical prediction of the existing relationship between the spectrum linewidth of RBS source and the transmission length in ODW is proposed,which theoretically provides the feasibility of constructing functional devices suitable to ascertain laser linewidth compression.The designed experimental scheme can be implemented provided the assumptions are fulfilled.In addition,a theoretical model of the micro-cavity structure to realize the deep compression of laser linewidth is proposed. 展开更多
关键词 scattering RAYLEIGH SPECTRUM EVOLUTION LINEWIDTH functional device
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Molecular beam epitaxial growth of high quality InAs/GaAs quantum dots for 1.3-μm quantum dot lasers 被引量:1
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作者 Hui-Ming Hao Xiang-Bin Su +2 位作者 Jing Zhang Hai-Qiao Ni Zhi-Chuan Niu 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第7期495-498,共4页
Systematic investigation of InAs quantum dot(QD) growth using molecular beam epitaxy has been carried out, focusing mainly on the InAs growth rate and its effects on the quality of the InAs/GaAs quantum dots.By optimi... Systematic investigation of InAs quantum dot(QD) growth using molecular beam epitaxy has been carried out, focusing mainly on the InAs growth rate and its effects on the quality of the InAs/GaAs quantum dots.By optimizing the growth rate, high quality InAs/GaAs quantum dots have been achieved.The areal quantum dot density is 5.9× 1010 cm-2, almost double the conventional density(3.0 × 1010 cm-2).Meanwhile, the linewidth is reduced to 29 meV at room temperature without changing the areal dot density.These improved QDs are of great significance for fabricating high performance quantum dot lasers on various substrates. 展开更多
关键词 QUANTUM DOTS growth rate DOT density LINEWIDTH
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Combined effect of light intensity and temperature on the magnetic resonance linewidth in alkali vapor cell with buffer gas 被引量:1
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作者 高阳 董海峰 +2 位作者 王翔 王笑菲 尹凌霄 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第6期417-421,共5页
One of the peculiar phenomenons in non-zero magnetic resonance magnetometer is that, with the increase of the temperature, the magnetic resonance linewidth is narrowed at first instead of broadened due to the increasi... One of the peculiar phenomenons in non-zero magnetic resonance magnetometer is that, with the increase of the temperature, the magnetic resonance linewidth is narrowed at first instead of broadened due to the increasing collision rate. The magnetometer usually operates at the narrowest linewidth temperature to obtain the best sensitivity. Here, we explain this phenomenon quantitatively considering the nonlinear of the optical pumping in the cell and did experiments to verify this explanation. The magnetic resonance linewidth is measured using one amplitude-modulated pump laser and one continuous probe laser. The field is along the direction orthogonal to the plane of pump and probe beams. We change the temperature from 53℃ to 93℃ and the pumping light from 0.1 mW to 2 mW. The experimental results agree well with the theoretical calculations. 展开更多
关键词 atomic magnetometer magnetic resonance LINEWIDTH TEMPERATURE
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Pressure-broadened atomic Li(2s-2p) line perturbed by ground neon atoms in the spectral wings and core 被引量:1
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作者 Sabri Bouchoucha Kamel Alioua Moncef Bouledroua 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第7期67-74,共8页
Full quantum calculations are performed to investigate the broadening profiles of the atomic lithium Li(2s-2p) resonance line induced by interactions with ground Ne(2s^22p^6) perturbers in the spectral wings and c... Full quantum calculations are performed to investigate the broadening profiles of the atomic lithium Li(2s-2p) resonance line induced by interactions with ground Ne(2s^22p^6) perturbers in the spectral wings and core. The X^2Σ~+, A^2Π,and B^2Σ~+ potential-energy curves of the two first low lying Li Ne molecular states, as well as the corresponding transition dipole moments, are determined with ab initio methods based on the SA-CASSCF-MRCI calculations. The emission and absorption coefficients in the wavelength range 550-800 nm and the line-core width and shift are investigated theoretically for temperatures ranging from 130 K to 3000 K. Their temperature dependence is analyzed, and the obtained results are compared with the previous experimental measurements and theoretical works. 展开更多
关键词 pressure broadening emission and absorption coefficients LINEWIDTH lineshift
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Coherence transfer from 1064 nm to 578 nm using an optically referenced frequency comb 被引量:1
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作者 方苏 蒋燕义 +3 位作者 陈海琴 姚远 毕志毅 马龙生 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第7期240-243,共4页
A laser at 578 nm is phase-locked to an optical frequency comb(OFC) which is optically referenced to a subhertzlinewidth laser at 1064 nm. Coherence is transferred from 1064 nm to 578 nm via the OFC. By comparing wi... A laser at 578 nm is phase-locked to an optical frequency comb(OFC) which is optically referenced to a subhertzlinewidth laser at 1064 nm. Coherence is transferred from 1064 nm to 578 nm via the OFC. By comparing with a cavitystabilized laser at 578 nm, the absolute linewidth of 1.1 Hz and the fractional frequency instability of 1.3 × 10^-15 at an averaging time of 1 s for each laser at 578 nm have been determined, which is limited by the performance of the reference laser for the OFC. 展开更多
关键词 coherence transfer optical frequency comb narrow linewidth laser
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Absorption linewidth inversion with wavelength modulation spectroscopy 被引量:3
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作者 颜悦 杜振辉 +1 位作者 李金义 王瑞雪 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第2期368-373,共6页
For absorption linewidth inversion with wavelength modulation spectroscopy(WMS), an optimized WMS spectral line fitting method was demonstrated to infer absorption linewidth effectively, and the analytical expressio... For absorption linewidth inversion with wavelength modulation spectroscopy(WMS), an optimized WMS spectral line fitting method was demonstrated to infer absorption linewidth effectively, and the analytical expressions for relationships between Lorentzian linewidth and the separations of first harmonic peak-to-valley and second harmonic zero-crossing were deduced. The transition of CO_2 centered at 4991.25 cm^(-1) was used to verify the optimized spectral fitting method and the analytical expressions. Results showed that the optimized spectra fitting method was able to infer absorption accurately and compute more than 10 times faster than the commonly used numerical fitting procedure. The second harmonic zero-crossing separation method calculated an even 6 orders faster than the spectra fitting without losing any accuracy for Lorentzian dominated cases. Additionally, linewidth calculated through second harmonic zero-crossing was preferred for much smaller error than the first harmonic peak-to-valley separation method. The presented analytical expressions can also be used in on-line optical sensing applications, electron paramagnetic resonance, and further theoretical characterization of absorption lineshape. 展开更多
关键词 absorption linewidth wavelength modulation spectroscopy absorption spectroscopy spectral line fitting separation of harmonics
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