At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systema...At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systematically and quantitatively evaluated,which limits the effective implementation of environmental monitoring.In response to this key technical gap,this study aimed to establish a standardized method for determining antimony in groundwater using Hydride Generation–Atomic Fluorescence Spectrometry(HG-AFS).Ten laboratories participated in inter-laboratory collaborative tests,and the statistical analysis of the test data was carried out in strict accordance with the technical specifications of GB/T 6379.2—2004 and GB/T 6379.4—2006.The consistency and outliers of the data were tested by Mandel's h and k statistics,the Grubbs test and the Cochran test,and the outliers were removed to optimize the data,thereby significantly improving the reliability and accuracy.Based on the optimized data,parameters such as the repeatability limit(r),reproducibility limit(R),and method bias value(δ)were determined,and the trueness of the method was statistically evaluated.At the same time,precision-function relationships were established,and all results met the requirements.The results show that the lower the antimony content,the lower the repeatability limit(r)and reproducibility limit(R),indicating that the measurement error mainly originates from the detection limit of the method and instrument sensitivity.Therefore,improving the instrument sensitivity and reducing the detection limit are the keys to controlling the analytical error and improving precision.This study provides reliable data support and a solid technical foundation for the establishment and evaluation of standardized methods for the determination of antimony content in groundwater.展开更多
To achieve the potential performance gain of massive multiple-input multiple-output(MIMO)systems,base stations(BS)require downlink channel state information(CSI)fed back by users to execute beamforming design,especial...To achieve the potential performance gain of massive multiple-input multiple-output(MIMO)systems,base stations(BS)require downlink channel state information(CSI)fed back by users to execute beamforming design,especially in the frequency division duplex(FDD)systems.However,due to the enormous number of antennas in massive MIMO systems,the feedback overhead of downlink CSI acquisition is extremely large.To address this issue,deep learning(DL)techniques have been introduced to de velop high-accuracy feedback strategies under limited backhaul constraints.In this paper,we provide an overview of DL-based CSI compression and feedback approaches in massive MIMO systems.Specifically,we introduce the conventional CSI compression and feedback schemes and the existing problems.Besides,we elaborate on various DL techniques employed in CSI compression from the perspective of network architecture and analyze the advantages of different techniques.We also enumerate the applications of DL-based methods for solving practical challenges in CSI compression and feedback.In addition,we brief the remaining issues in deep CSI compression and indicate potential directions in future wireless networks.展开更多
Liver transplantation(LT)remains the optimal life-saving intervention for patients with end-stage liver disease.Despite the recent advances in LT several barriers,including organ allocation,donor-recipient matching,an...Liver transplantation(LT)remains the optimal life-saving intervention for patients with end-stage liver disease.Despite the recent advances in LT several barriers,including organ allocation,donor-recipient matching,and patient education,persist.With the growing progress of artificial intelligence,particularly large language models(LLMs)like ChatGPT,new applications have emerged in the field of LT.Current studies demonstrating usage of ChatGPT in LT include various areas of application,from clinical settings to research and education.ChatGPT usage can benefit both healthcare professionals,by decreasing the time spent on non-clinical work,but also LT recipients by providing accurate information.Future potential applications include the expanding usage of ChatGPT and other LLMs in the field of LT pathology and radiology as well as the automated creation of discharge summaries or other related paperwork.Additionally,the next models of ChatGPT might have the potential to provide more accurate patient education material with increased readability.Although ChatGPT usage presents promising applications,there are certain ethical and practical limitations.Key concerns include patient data privacy,information accuracy,misinformation possibility and lack of legal framework.Healthcare providers and policymakers should collaborate for the establishment of a controlled framework for the safe use of ChatGPT.The aim of this minireview is to summarize current literature on ChatGPT in LT,highlighting both opportunities and limitations,while also providing future possible applications.展开更多
Pelagic appendicularians,known for their rapid bloom capability,are important secondary producers and play essential roles in marine ecosystems.To assess the environmental adaptation of the most common appendicularian...Pelagic appendicularians,known for their rapid bloom capability,are important secondary producers and play essential roles in marine ecosystems.To assess the environmental adaptation of the most common appendicularian species Oikopleura dioica in Jiaozhou Bay,Shandong,China,its annual variations in abundance and body size were investigated monthly at 12 stations in 2011,and the relationship between somatic growth and gonadal development was compared with previously published laboratory data.Oikopleura dioica exhibited distinct seasonal abundance patterns,peaking in summer and autumn,particularly in the inner bay,reflecting its adaptation to the eutrophic conditions and high food availability.Compared to laboratory results,O.dioica in Jiaozhou Bay exhibited shorter body lengths,smaller gonad volumes,and earlier maturation at reduced body sizes,despite high natural chlorophyll-a concentration,suggesting that factors beyond food availability,such as resource competition and environmental stressors,may limit its growth in natural settings.Correlation analysis indicated that the somatic growth of natural O.dioica was primarily influenced by temperature,while gonadal development was related to chlorophyll-a concentration,and its population abundance was linked to food availability and the abundance of other zooplankton,such as copepods and jellyfish.It was suggested that the growth and recruitment of O.dioica were constrained by resource limitations in natural environments,further exacerbated by interactions with other zooplankton,including predation and competition.This study provides valuable data on the mechanisms underlying bio-environmental interactions and their spatiotemporal variations,offering critical insights into the ecological roles of appendicularians in marine ecosystems.展开更多
In order to enable wing morphing(e.g.change in camber or folds)without incurring additional weight to the aircraft,lightweight flexible materials such as membrane are needed.However,the research on fluid-structure cou...In order to enable wing morphing(e.g.change in camber or folds)without incurring additional weight to the aircraft,lightweight flexible materials such as membrane are needed.However,the research on fluid-structure coupling of membranes has mainly focused on parachutes in low-speed conditions,while that in supersonic flow conditions is lacking.Here,the degraded shell method is proposed to study membrane deformation by using shell element,which is more effective than using membrane elements directly.A fluid-structure interaction computational framework is proposed,whereby the aerodynamic module is composed of either the piston theory or computational fluid dynamics.A rectangular membrane of length 0.4 m and width 0.6 m is investigated in supersonic conditions.The characteristics of the limit cycle and steady deformation are analyzed,considering the effects of angle of attack and dynamic pressure.It is found that the structural response exhibits significant differences under various angles of attack.Furthermore,initial relaxation of membrane has significant influence on the structural deformation.Finally,the aeroelastic scaling method for membrane structures is derived,providing guidance for the design of wind tunnel models.This study provides a theoretical foundation for the analysis and application of membrane structures under supersonic conditions in future research.展开更多
Construction of electron donor-acceptor(D-A)conjugated system is an established strategy for achieving reverse saturable absorption(RSA)and broadband optical limiting(OL).Nevertheless,organic materials exhibit OL abil...Construction of electron donor-acceptor(D-A)conjugated system is an established strategy for achieving reverse saturable absorption(RSA)and broadband optical limiting(OL).Nevertheless,organic materials exhibit OL ability across the visible to near-infrared-II spectra range remain scarce.Herein,a series of D-A typeπ-conjugated copolymers with ultra-narrow bandgaps(0.62-0.76 e V)and strong ICT absorption were synthesized by coupling electron-withdrawing block[1,2,5]thiadiazolo[3,4-g]quinoxaline(TQ)with various electron-donating groups(thiophene,selenophene,bithiophene,di(thiophen-2-yl)ethene,and thienothiophene for P1-P5,respectively).Z-scan experiments reveal that all copolymers exhibit RSA behaviours at both 532 and 1064 nm,while P1,P3 and P4 maintain RSA performance extending to 1600 nm.Among all copolymers,P5 exhibits the strongest RSA performance upon both 532 and 1064 nm laser pulses,with the highest nonlinear absorption coefficient(β_(eff))of 51.5 and 49.4 cm·GW^(-1),respectively,and the lowest OL onset fluence(Fon)of 0.31 and 0.38 J·cm^(-2),respectively.In contrast,P4 shows optimal RSA property at 1600 nm laser pulse,withβeff of 13.1 cm·GW^(-1)and Fon of 1.43 J·cm^(-2),respectively.Combining the results of Z-scan and UV-Vis-NIR experiments,it can be speculated that moderate ground-state absorption,rather than excessively strong absorption,favors superior RSA properties.This work offers valuable insights for designing copolymers with excellent RSA behavior,as well as presents a class of candidate material systems for ultrabroadband optical limiting.展开更多
In data communication,limited communication resources often lead to measurement bias,which adversely affects subsequent system estimation if not effectively handled.This paper proposes a novel bias calibration algorit...In data communication,limited communication resources often lead to measurement bias,which adversely affects subsequent system estimation if not effectively handled.This paper proposes a novel bias calibration algorithm under communication constraints to achieve accurate system states of the interested system.An output-based event-triggered scheme is first employed to alleviate transmission burden.Accounting for the limited-communication-induced measurement bias,a novel bias calibration algorithm following the Kalman filtering line is developed to restrain the effect of the measurement bias on system estimation,thereby achieving accurate system state estimates.Subsequently,the Field Programmable Gate Array(FPGA)implementation of the proposed algorithm is also realized with the hope of providing fast bias calibration in practical scenarios.A simulation about a numerical example and a practical example(for gyroscope’s angular velocity bias calibration)on MATLAB is provided to demonstrate the feasibility and effectiveness of the proposed algorithm.展开更多
The transient synchronization stability of grid-forming converters(GFMCs)is significantly challenged under grid voltage sags.Continuous efforts have been devoted to analyzing the GFMC transient stability,with limited ...The transient synchronization stability of grid-forming converters(GFMCs)is significantly challenged under grid voltage sags.Continuous efforts have been devoted to analyzing the GFMC transient stability,with limited attention paid to the impacts of control loop dynamics.However,the complex control dynamics,especially the interactions between the active/reactive power control loops and the current saturation process(CSP),are crucial for accurately describing the transient behavior and evaluating the stability.Thus,in this study,a new large-signal GFMC model is established,considering the reactive power control(RPC)with different kinds of controllers and the CSP simultaneously.It is revealed that GFMC does not switch to the current-limited mode immediately,and the dynamics of RPC further affect the transient behavior before the current limiting significantly.Hence,the complex control dynamics can alter the mode switching point of current saturation,thereby increasing the risk of loss of synchronization(LOS).Based on the above findings,comprehensive comparisons of typical RPC controllers are presented to facilitate practical engineering applications.A unified stability enhancement method is proposed for solving the problem of LOS.Finally,experiments validate the correctness of the analysis and the effectiveness of the proposed control strategy.展开更多
In this paper,we derive the sub-Riemannian version of the Kastler-Kalau-Walze type theorem and the Dabrowski-Sitarz-Zalecki type theorem for the twisted BCV spaces.We also compute the Connes conformal invariants for t...In this paper,we derive the sub-Riemannian version of the Kastler-Kalau-Walze type theorem and the Dabrowski-Sitarz-Zalecki type theorem for the twisted BCV spaces.We also compute the Connes conformal invariants for the twisted product,as well as the sub-Riemannian limits of the Connes conformal invariants for the twisted BCV spaces.展开更多
Plants encounter dynamic light environments in natural field conditions,and species differ in their physiological and biochemical mechanisms for acclimating to fluctuating light(FL).The manner in which soybean(Glycine...Plants encounter dynamic light environments in natural field conditions,and species differ in their physiological and biochemical mechanisms for acclimating to fluctuating light(FL).The manner in which soybean(Glycine max(L.) Merr.) coordinates multiple physiological adjustments to FL remains poorly understood.This study assessed the effects of FL on soybean morphology and photosynthetic traits by examining changes in photosynthetic gas exchange parameters and chlorophyll(Chl) a fluorescence under alternating high-and low-light conditions.Results indicated that soybeans exposed to FL exhibited reduced dry matter accumulation,smaller and thinner leaves,and a lower Chl a/Chl b levels-characteristics typically associated with plants grown under continuous low-light.Despite these morphological similarities,their photosynthetic gas exchange rates and photosynthetic capacity were maintained at levels comparable to those under steady high light,unlike plants grown under constant low-light.Thus,acclimation to FL is distinct from adaptation to sustained low-light conditions.Correlation analyses revealed that the decline in carbon assimilation under FL primarily stemmed from two factors:the slow recovery of stomatal conductance upon transition to high light and the delayed relaxation of nonphotochemical quenching when light intensity decreased.Therefore,the reduction in carbon assimilation under FL cannot be attributed to low-light phase adjustments but rather reflects a lag in photosynthetic responsiveness to changing light conditions.展开更多
Agricultural ecosystems play a pivotal role in global carbon(C)sequestration efforts.Microbial C use efficiency(CUE)serves as a comprehensive metric that reflects the balance between microbial contributions to the acc...Agricultural ecosystems play a pivotal role in global carbon(C)sequestration efforts.Microbial C use efficiency(CUE)serves as a comprehensive metric that reflects the balance between microbial contributions to the accumulation and decomposition of soil organic C.However,the overall distribution patterns and underlying drivers of microbial CUE at the national scale remain unclear.Herein,data from 209 paired samples from 55 studies were analyzed to assess the distribution patterns and influencing factors of microbial CUE based on enzyme stoichiometry(CUE_(ST))in agricultural ecosystems across China.Results revealed that farmlands exhibited the highest CUE_(ST)value(mean=0.51),exceeding those of grasslands(0.46)and forests(0.44).Contrasting patterns of CUE_(ST)regulation were observed across land-use types,with farmlands showing significant(P<0.001)positive relationships of CUE_(ST)with phosphorus vs.nitrogen(N/P)limitation index,while grasslands and forests demonstrated inverse(P<0.05)relationships of CUE_(ST)with C limitation index.Nutrient stoichiometry emerged as the dominant driver of CUE_(ST),with enzyme ratios and mean annual precipitation playing secondary roles.Moreover,land management practices,including fertilization,grazing,and tillage,as well as land-use transition,significantly influenced microbial CUE_(ST)by potentially altering nutrient availability and soil properties;notably,water addition in grasslands had particularly positive effects.These findings provide a critical foundation for harnessing microbial CUE in agriculture and may inform scalable strategies to enhance soil C sequestration and climate-smart land management.展开更多
Urban tunnels are often built in multiples,yet the influence of surface structures on their support demands is frequently overlooked,highlighting the need for refined design under realistic loading.This study addresse...Urban tunnels are often built in multiples,yet the influence of surface structures on their support demands is frequently overlooked,highlighting the need for refined design under realistic loading.This study addresses this gap by examining the response of a uniformly loaded strip footing above twin horseshoe tunnels with structural linings.A non-dimensional Footing Stability Improvement Factor(I_(f)),defined as the ratio of ultimate bearing capacity with and without lining to that of a footing on intact rock—is evaluated using adaptive finite element limit analysis.The effects of normalized vertical depth of tunnel,normalised horizontal spacing of tunnel,and lining-thickness factor are examined,providing key insights into foundation-tunnel interaction and support optimization.This study finds that,for unlined twin tunnels,footing-tunnel interaction becomes negligible when embedment exceeds four times of footing widths and tunnel spacing surpasses eleven times of footing widths,beyond which additional support is unnecessary.For lined tunnels,the tunnel-lining thickness required to maintain footing stability equivalent to that on intact rock decreases rapidly with embedment depth.At a tunnel spacing equal to onehalf of the footing width,the critical lining-thickness ratio is about six percent of the footing width at a tunnel depth of half the footing width,reducing to approximately five,four,and three percent at depths of one,one-and-a-half,and two footing widths,and asymptotically approaching nearly one percent for embedment depths exceeding two-and-a-half footing widths.Additionally,rock mass parameters exhibit minimal impact(±2%)on I_(f).The results show that failure mechanisms in footing-tunnel systems are primarily governed by tunnels-positional parmeters,and lining thickness.The study presents a mechanistic framework that delineates the critical depth-spacing-thickness regimes controlling twin-tunnel behavior,providing engineers with clear design boundaries and performance-based lining guidelines to improve the stability of both tunnels and overlying foundations.展开更多
The deep tunnels are prone to mud and water inrush disasters when crossing water-rich weak zones.A good understanding the hydromechanical behavior of the water-rich weak zone in deep tunnels is the prerequisite for de...The deep tunnels are prone to mud and water inrush disasters when crossing water-rich weak zones.A good understanding the hydromechanical behavior of the water-rich weak zone in deep tunnels is the prerequisite for determining the limit support pressure on the tunnel face.However,the seepage forces within the water-rich weak zone are not well estimated in existing models.To overcome this,an analytical model is proposed in this study to determine the limit support pressure of a deep tunnel crossing the water-rich weak zone.The seepage force in the water-rich weak zone is obtained by solving a group of Laplace equations about the hydraulic head,avoiding complex physical and mathematical approximation in existing models.Besides,the seepage boundary conditions in the water-rich weak zone are considered at the nodes on the Neumann boundary and the Dirichlet boundary.The effectiveness of the proposed model is then validated by numerical simulations and engineering practice.It shows that the proposed model has higher accuracy and wider applicability in estimating the hydraulic head.The proposed model can be used for stability analysis of tunnel faces.展开更多
The interdependence of electrical parameters has long inhibited the progress of bismuth telluride(Bi_(2)Te3),limiting its widespread application in thermoelectric cooling and power generation.This work investigates th...The interdependence of electrical parameters has long inhibited the progress of bismuth telluride(Bi_(2)Te3),limiting its widespread application in thermoelectric cooling and power generation.This work investigates the n-type Bi_(2)Te_(2.79)Se_(0.21)I_(0.004)(Bi_(2)(Te,Se)_(3),BTS)system with light Zn doping,revealing that Zn addition simultaneously enhances the Seebeck coefficient(S)and electrical conductivity(σ)through the modulation of defect composition and multi-level band regulation.The substitution of Zn atoms at Bi sites enhances S via bandgap(E_(g))widening,band flattening,and band splitting effects,contributing to a competitive power factor(PF)of∼60μW⋅cm^(−1)⋅K^(−2).Additionally,thermal conductivity is maintained at a low level,leading to an extraordinary figure-of-merit(ZT)value of∼1.3 at room temperature.Furthermore,the Bi_(2)Zn_(0.01)Te_(2.79)Se_(0.21)I_(0.004) system demonstrates impressive thermoelectric device performance,with a maximum cooling temperature difference(ΔT_(max))of∼70.0 K at 300 K,rising to∼78.0 K at 323 K and∼85.7 K at 343 K,as well as a maximum conversion efficiency(η_(max))of∼6.2%under aΔT of 200 K.This study clarifies the mechanism of Zn doping and presents a cost-effective strategy for enhancing the performance of n-type BTS thermoelectrics and their devices.展开更多
To address the issues of high costs and low component utilization caused by the independent configuration of hybrid DC circuit breakers(HCBs)and DC power flow controllers(DCPFCs)at each port in existing DC distributio...To address the issues of high costs and low component utilization caused by the independent configuration of hybrid DC circuit breakers(HCBs)and DC power flow controllers(DCPFCs)at each port in existing DC distribution networks,this paper adopts a component sharing mechanism to propose a composite multi-port hybrid DC circuit breaker(CM-HCB)with DC power flow and fault current limitation abilities,as well as reduced component costs.The proposed CM-HCB topology enables the sharing of the main breaker branch(MB)and the energy dissipation branch,while the load commutation switches(LCSs)in the main branch are reused as power flow control components,enabling flexible regulation of power flow in multiple lines.Meanwhile,by reconstructing the current path during the fault process,the proposed CM-HCB can utilize the internal coupled inductor to limit the current rise rate at the initial stage of the fault,significantly reducing the requirement for breaking current.A detailed study on the topological structure,steady-state power flow regulation mechanism,transient fault isolation mechanism,control strategy and characteristic analysis of the proposed CM-HCB is presented.Then,a Matlab/Simulink-based meshed three-terminal DC grid simulation platform with the proposed CM-HCB is built.The results indicate that the proposed CM-HCB can not only achieve flexible power flow control during steady-state operation,but also obtain current rise limitation and fault isolation abilities under short-circuit fault conditions,verifying its correctness and effectiveness.Finally,a comparative economic analysis is conducted between the proposed CM-HCB and the other two existing solutions,confirming that its component sharing mechanism can significantly reduce the number of components,lower system costs,and improve component utilization.展开更多
A scheme is proposed based on a Mach-Zehnder interferometer with high phase sensitivity,utilizing a two-mode squeezed coherent state,generated by four-wave mixing,as input.The phase sensitivity of this scheme easily s...A scheme is proposed based on a Mach-Zehnder interferometer with high phase sensitivity,utilizing a two-mode squeezed coherent state,generated by four-wave mixing,as input.The phase sensitivity of this scheme easily surpasses the Heisenberg limit when intensity difference detection is applied.Under phase-matching conditions,the quantum Cramér-Rao bound significantly exceeds the Heisenberg limit.Additionally,the scheme exhibits robustness against photon loss.When compared with the modified SU(1,1)interferometer with two coherent state inputs,this approach demonstrates superior measurement sensitivity,evaluated through various detection methods and the quantum Cramér-Rao bound.This work holds potential applications in quantum metrology.展开更多
The quality of cardiopulmonary resuscitation(CPR) significantly influences survival and neurological outcomes in patients with cardiac arrest(CA).Although mechanical chest compression devices and extracorporeal cardio...The quality of cardiopulmonary resuscitation(CPR) significantly influences survival and neurological outcomes in patients with cardiac arrest(CA).Although mechanical chest compression devices and extracorporeal cardiopulmonary resuscitation(ECPR) have demonstrated some benefits,high-quality manual CPR remained the essential first step,particularly in resource-limited settings.In this study,we examined whether opportunities existed to improve manual CPR performance using preliminary data from our recent survey conducted in a province in western China.We aim to emphasize the importance of improving manual CPR quality before implementing advanced interventions.展开更多
The porous NiO nanoplates modified with rGO nanosheets and SnO_(2)nanoparticles are developed for accurate and rapid ppb-level NO_(2)detection.The developed SnO_(2)/NiO/rGO sensor towards 50 ppm NO_(2)gas demonstrates...The porous NiO nanoplates modified with rGO nanosheets and SnO_(2)nanoparticles are developed for accurate and rapid ppb-level NO_(2)detection.The developed SnO_(2)/NiO/rGO sensor towards 50 ppm NO_(2)gas demonstrates an excellent gas-sensing response of 14.8 at 23℃,which is 3.03 times that of Ni O/rGO sensor(4.89)and 6.49 times that of NiO sensor(2.28),respectively.The developed SnO_(2)/NiO/rGO sensor exhibits faster response/recovery speed(12.7/32.8 s@5 ppm),with extra-low theoretical detection limit of 0.15 ppb at room temperature.More fascinatingly,our sensors indicate great sensitivity,outstanding repeatability and long-term stability for longer than 7 weeks.Additionally,it also suggests that 1℃and 1%relative humidity have the same effect on the SnO_(2)/NiO/rGO sensor signal as approximately 13 ppb and 7.0 ppb NO_(2)gas change,respectively.Such excellent properties are mainly attributed to the large surface-to-volume ratio,which provides active sites to NO_(2)gas spread,adsorption and diffusion on material surface in redox reaction.Moreover,the ternary heterojunctions formed by NiO,rGO and SnO_(2)may serve as highly conductive channels to accelerate carrier transfer and abundant oxygen vacancies to reduce the adsorption energy for O_(2)and NO_(2)gas,thus further improving performance of the sensors.展开更多
Low-cost and high-safety aqueous Zn-I_(2) batteries attract extensive attention for large-scale energy storage systems.However,polyiodide shuttling and sluggish iodine conversion reactions lead to inferior rate capabi...Low-cost and high-safety aqueous Zn-I_(2) batteries attract extensive attention for large-scale energy storage systems.However,polyiodide shuttling and sluggish iodine conversion reactions lead to inferior rate capability and severe capacity decay.Herein,a three-dimensional polyaniline is wrapped by carboxylcarbon nanotubes(denoted as C-PANI)which is designed as a catalytic cathode to effectively boost iodine conversion with suppressed polyiodide shuttling,thereby improving Zn-I_(2) batteries.Specifically,carboxyl-carbon nanotubes serve as a proton reservoir for more protonated-NH+=sites in PANI chains,achieving a direct I0/I−reaction for suppressed polyiodide generation and Zn corrosion.Attributing to this“proton-iodine”regulation,catalytic protonated C-PANI strongly fixes electrolytic iodine species and stores proton ions simultaneously through reversible-N=/-NH^(+)-reaction.Therefore,the electrolytic Zn-I_(2) battery with C-PANI cathode exhibits an impressive capacity of 420 mAh g^(−1) and ultra-long lifespan over 40,000 cycles.Additionally,a 60 mAh pouch cell was assembled with excellent cycling stability after 100 cycles,providing new insights into exploring effective organocatalysts for superb Zn-halogen batteries.展开更多
In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to character...In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.展开更多
基金supported by the National Natural Science Foundation of China(Project No.42307555).
文摘At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systematically and quantitatively evaluated,which limits the effective implementation of environmental monitoring.In response to this key technical gap,this study aimed to establish a standardized method for determining antimony in groundwater using Hydride Generation–Atomic Fluorescence Spectrometry(HG-AFS).Ten laboratories participated in inter-laboratory collaborative tests,and the statistical analysis of the test data was carried out in strict accordance with the technical specifications of GB/T 6379.2—2004 and GB/T 6379.4—2006.The consistency and outliers of the data were tested by Mandel's h and k statistics,the Grubbs test and the Cochran test,and the outliers were removed to optimize the data,thereby significantly improving the reliability and accuracy.Based on the optimized data,parameters such as the repeatability limit(r),reproducibility limit(R),and method bias value(δ)were determined,and the trueness of the method was statistically evaluated.At the same time,precision-function relationships were established,and all results met the requirements.The results show that the lower the antimony content,the lower the repeatability limit(r)and reproducibility limit(R),indicating that the measurement error mainly originates from the detection limit of the method and instrument sensitivity.Therefore,improving the instrument sensitivity and reducing the detection limit are the keys to controlling the analytical error and improving precision.This study provides reliable data support and a solid technical foundation for the establishment and evaluation of standardized methods for the determination of antimony content in groundwater.
基金supported by ZTE Industry-University-Institute Cooperation Funds under Grant No.IA20240319003the NSFC under Grant No.62571112。
文摘To achieve the potential performance gain of massive multiple-input multiple-output(MIMO)systems,base stations(BS)require downlink channel state information(CSI)fed back by users to execute beamforming design,especially in the frequency division duplex(FDD)systems.However,due to the enormous number of antennas in massive MIMO systems,the feedback overhead of downlink CSI acquisition is extremely large.To address this issue,deep learning(DL)techniques have been introduced to de velop high-accuracy feedback strategies under limited backhaul constraints.In this paper,we provide an overview of DL-based CSI compression and feedback approaches in massive MIMO systems.Specifically,we introduce the conventional CSI compression and feedback schemes and the existing problems.Besides,we elaborate on various DL techniques employed in CSI compression from the perspective of network architecture and analyze the advantages of different techniques.We also enumerate the applications of DL-based methods for solving practical challenges in CSI compression and feedback.In addition,we brief the remaining issues in deep CSI compression and indicate potential directions in future wireless networks.
文摘Liver transplantation(LT)remains the optimal life-saving intervention for patients with end-stage liver disease.Despite the recent advances in LT several barriers,including organ allocation,donor-recipient matching,and patient education,persist.With the growing progress of artificial intelligence,particularly large language models(LLMs)like ChatGPT,new applications have emerged in the field of LT.Current studies demonstrating usage of ChatGPT in LT include various areas of application,from clinical settings to research and education.ChatGPT usage can benefit both healthcare professionals,by decreasing the time spent on non-clinical work,but also LT recipients by providing accurate information.Future potential applications include the expanding usage of ChatGPT and other LLMs in the field of LT pathology and radiology as well as the automated creation of discharge summaries or other related paperwork.Additionally,the next models of ChatGPT might have the potential to provide more accurate patient education material with increased readability.Although ChatGPT usage presents promising applications,there are certain ethical and practical limitations.Key concerns include patient data privacy,information accuracy,misinformation possibility and lack of legal framework.Healthcare providers and policymakers should collaborate for the establishment of a controlled framework for the safe use of ChatGPT.The aim of this minireview is to summarize current literature on ChatGPT in LT,highlighting both opportunities and limitations,while also providing future possible applications.
基金Supported by the National Key Research and Development Program of China(Nos.2023YFC3108205,2023YFC3108201)the National Natural Science Foundation of China(No.42306153)。
文摘Pelagic appendicularians,known for their rapid bloom capability,are important secondary producers and play essential roles in marine ecosystems.To assess the environmental adaptation of the most common appendicularian species Oikopleura dioica in Jiaozhou Bay,Shandong,China,its annual variations in abundance and body size were investigated monthly at 12 stations in 2011,and the relationship between somatic growth and gonadal development was compared with previously published laboratory data.Oikopleura dioica exhibited distinct seasonal abundance patterns,peaking in summer and autumn,particularly in the inner bay,reflecting its adaptation to the eutrophic conditions and high food availability.Compared to laboratory results,O.dioica in Jiaozhou Bay exhibited shorter body lengths,smaller gonad volumes,and earlier maturation at reduced body sizes,despite high natural chlorophyll-a concentration,suggesting that factors beyond food availability,such as resource competition and environmental stressors,may limit its growth in natural settings.Correlation analysis indicated that the somatic growth of natural O.dioica was primarily influenced by temperature,while gonadal development was related to chlorophyll-a concentration,and its population abundance was linked to food availability and the abundance of other zooplankton,such as copepods and jellyfish.It was suggested that the growth and recruitment of O.dioica were constrained by resource limitations in natural environments,further exacerbated by interactions with other zooplankton,including predation and competition.This study provides valuable data on the mechanisms underlying bio-environmental interactions and their spatiotemporal variations,offering critical insights into the ecological roles of appendicularians in marine ecosystems.
文摘In order to enable wing morphing(e.g.change in camber or folds)without incurring additional weight to the aircraft,lightweight flexible materials such as membrane are needed.However,the research on fluid-structure coupling of membranes has mainly focused on parachutes in low-speed conditions,while that in supersonic flow conditions is lacking.Here,the degraded shell method is proposed to study membrane deformation by using shell element,which is more effective than using membrane elements directly.A fluid-structure interaction computational framework is proposed,whereby the aerodynamic module is composed of either the piston theory or computational fluid dynamics.A rectangular membrane of length 0.4 m and width 0.6 m is investigated in supersonic conditions.The characteristics of the limit cycle and steady deformation are analyzed,considering the effects of angle of attack and dynamic pressure.It is found that the structural response exhibits significant differences under various angles of attack.Furthermore,initial relaxation of membrane has significant influence on the structural deformation.Finally,the aeroelastic scaling method for membrane structures is derived,providing guidance for the design of wind tunnel models.This study provides a theoretical foundation for the analysis and application of membrane structures under supersonic conditions in future research.
基金supported by the National Natural Science Foundation of China(No.52102013)。
文摘Construction of electron donor-acceptor(D-A)conjugated system is an established strategy for achieving reverse saturable absorption(RSA)and broadband optical limiting(OL).Nevertheless,organic materials exhibit OL ability across the visible to near-infrared-II spectra range remain scarce.Herein,a series of D-A typeπ-conjugated copolymers with ultra-narrow bandgaps(0.62-0.76 e V)and strong ICT absorption were synthesized by coupling electron-withdrawing block[1,2,5]thiadiazolo[3,4-g]quinoxaline(TQ)with various electron-donating groups(thiophene,selenophene,bithiophene,di(thiophen-2-yl)ethene,and thienothiophene for P1-P5,respectively).Z-scan experiments reveal that all copolymers exhibit RSA behaviours at both 532 and 1064 nm,while P1,P3 and P4 maintain RSA performance extending to 1600 nm.Among all copolymers,P5 exhibits the strongest RSA performance upon both 532 and 1064 nm laser pulses,with the highest nonlinear absorption coefficient(β_(eff))of 51.5 and 49.4 cm·GW^(-1),respectively,and the lowest OL onset fluence(Fon)of 0.31 and 0.38 J·cm^(-2),respectively.In contrast,P4 shows optimal RSA property at 1600 nm laser pulse,withβeff of 13.1 cm·GW^(-1)and Fon of 1.43 J·cm^(-2),respectively.Combining the results of Z-scan and UV-Vis-NIR experiments,it can be speculated that moderate ground-state absorption,rather than excessively strong absorption,favors superior RSA properties.This work offers valuable insights for designing copolymers with excellent RSA behavior,as well as presents a class of candidate material systems for ultrabroadband optical limiting.
基金support from the National Natural Science Foundation of China(Grant Nos.U2330206,U2230206,62173068)Sichuan Science and Technology Program(Grants Nos.2024NSFSC1483,2024ZYD0156,2023NSFC1962,DQ202412).
文摘In data communication,limited communication resources often lead to measurement bias,which adversely affects subsequent system estimation if not effectively handled.This paper proposes a novel bias calibration algorithm under communication constraints to achieve accurate system states of the interested system.An output-based event-triggered scheme is first employed to alleviate transmission burden.Accounting for the limited-communication-induced measurement bias,a novel bias calibration algorithm following the Kalman filtering line is developed to restrain the effect of the measurement bias on system estimation,thereby achieving accurate system state estimates.Subsequently,the Field Programmable Gate Array(FPGA)implementation of the proposed algorithm is also realized with the hope of providing fast bias calibration in practical scenarios.A simulation about a numerical example and a practical example(for gyroscope’s angular velocity bias calibration)on MATLAB is provided to demonstrate the feasibility and effectiveness of the proposed algorithm.
基金supported by the National Natural Science Foundation of China under Grant 52277184 and Grant 52277183.
文摘The transient synchronization stability of grid-forming converters(GFMCs)is significantly challenged under grid voltage sags.Continuous efforts have been devoted to analyzing the GFMC transient stability,with limited attention paid to the impacts of control loop dynamics.However,the complex control dynamics,especially the interactions between the active/reactive power control loops and the current saturation process(CSP),are crucial for accurately describing the transient behavior and evaluating the stability.Thus,in this study,a new large-signal GFMC model is established,considering the reactive power control(RPC)with different kinds of controllers and the CSP simultaneously.It is revealed that GFMC does not switch to the current-limited mode immediately,and the dynamics of RPC further affect the transient behavior before the current limiting significantly.Hence,the complex control dynamics can alter the mode switching point of current saturation,thereby increasing the risk of loss of synchronization(LOS).Based on the above findings,comprehensive comparisons of typical RPC controllers are presented to facilitate practical engineering applications.A unified stability enhancement method is proposed for solving the problem of LOS.Finally,experiments validate the correctness of the analysis and the effectiveness of the proposed control strategy.
基金Supported by Science and Technology Development Plan Project of Jilin Province China(Grant No.20260102245JC)Supported by National Natural Science Foundation of China(Grant No.11771070).
文摘In this paper,we derive the sub-Riemannian version of the Kastler-Kalau-Walze type theorem and the Dabrowski-Sitarz-Zalecki type theorem for the twisted BCV spaces.We also compute the Connes conformal invariants for the twisted product,as well as the sub-Riemannian limits of the Connes conformal invariants for the twisted BCV spaces.
基金supported by the National Key Research and Development Program of China (2023YFF1001504)the National Natural Science Foundation of China (32071963)+2 种基金the National Key Research and Development Program of China (2022YFD2300902)the Guangxi Key Research and Development Program of China (GuikeAB23026107)the Chengdu Science and Technology Project,China (2023-YF08-00003-SN)。
文摘Plants encounter dynamic light environments in natural field conditions,and species differ in their physiological and biochemical mechanisms for acclimating to fluctuating light(FL).The manner in which soybean(Glycine max(L.) Merr.) coordinates multiple physiological adjustments to FL remains poorly understood.This study assessed the effects of FL on soybean morphology and photosynthetic traits by examining changes in photosynthetic gas exchange parameters and chlorophyll(Chl) a fluorescence under alternating high-and low-light conditions.Results indicated that soybeans exposed to FL exhibited reduced dry matter accumulation,smaller and thinner leaves,and a lower Chl a/Chl b levels-characteristics typically associated with plants grown under continuous low-light.Despite these morphological similarities,their photosynthetic gas exchange rates and photosynthetic capacity were maintained at levels comparable to those under steady high light,unlike plants grown under constant low-light.Thus,acclimation to FL is distinct from adaptation to sustained low-light conditions.Correlation analyses revealed that the decline in carbon assimilation under FL primarily stemmed from two factors:the slow recovery of stomatal conductance upon transition to high light and the delayed relaxation of nonphotochemical quenching when light intensity decreased.Therefore,the reduction in carbon assimilation under FL cannot be attributed to low-light phase adjustments but rather reflects a lag in photosynthetic responsiveness to changing light conditions.
基金financially supported by the National Natural Science Foundation of China(Nos.42225706,42377297,42407408,42177283)the Fundamental Research Funds for the Central Universities of China(No.2662023PY010)the support from the Postdoctoral Fellowship Program of the China Postdoctoral Science Foundation(No.GZB20230246)。
文摘Agricultural ecosystems play a pivotal role in global carbon(C)sequestration efforts.Microbial C use efficiency(CUE)serves as a comprehensive metric that reflects the balance between microbial contributions to the accumulation and decomposition of soil organic C.However,the overall distribution patterns and underlying drivers of microbial CUE at the national scale remain unclear.Herein,data from 209 paired samples from 55 studies were analyzed to assess the distribution patterns and influencing factors of microbial CUE based on enzyme stoichiometry(CUE_(ST))in agricultural ecosystems across China.Results revealed that farmlands exhibited the highest CUE_(ST)value(mean=0.51),exceeding those of grasslands(0.46)and forests(0.44).Contrasting patterns of CUE_(ST)regulation were observed across land-use types,with farmlands showing significant(P<0.001)positive relationships of CUE_(ST)with phosphorus vs.nitrogen(N/P)limitation index,while grasslands and forests demonstrated inverse(P<0.05)relationships of CUE_(ST)with C limitation index.Nutrient stoichiometry emerged as the dominant driver of CUE_(ST),with enzyme ratios and mean annual precipitation playing secondary roles.Moreover,land management practices,including fertilization,grazing,and tillage,as well as land-use transition,significantly influenced microbial CUE_(ST)by potentially altering nutrient availability and soil properties;notably,water addition in grasslands had particularly positive effects.These findings provide a critical foundation for harnessing microbial CUE in agriculture and may inform scalable strategies to enhance soil C sequestration and climate-smart land management.
文摘Urban tunnels are often built in multiples,yet the influence of surface structures on their support demands is frequently overlooked,highlighting the need for refined design under realistic loading.This study addresses this gap by examining the response of a uniformly loaded strip footing above twin horseshoe tunnels with structural linings.A non-dimensional Footing Stability Improvement Factor(I_(f)),defined as the ratio of ultimate bearing capacity with and without lining to that of a footing on intact rock—is evaluated using adaptive finite element limit analysis.The effects of normalized vertical depth of tunnel,normalised horizontal spacing of tunnel,and lining-thickness factor are examined,providing key insights into foundation-tunnel interaction and support optimization.This study finds that,for unlined twin tunnels,footing-tunnel interaction becomes negligible when embedment exceeds four times of footing widths and tunnel spacing surpasses eleven times of footing widths,beyond which additional support is unnecessary.For lined tunnels,the tunnel-lining thickness required to maintain footing stability equivalent to that on intact rock decreases rapidly with embedment depth.At a tunnel spacing equal to onehalf of the footing width,the critical lining-thickness ratio is about six percent of the footing width at a tunnel depth of half the footing width,reducing to approximately five,four,and three percent at depths of one,one-and-a-half,and two footing widths,and asymptotically approaching nearly one percent for embedment depths exceeding two-and-a-half footing widths.Additionally,rock mass parameters exhibit minimal impact(±2%)on I_(f).The results show that failure mechanisms in footing-tunnel systems are primarily governed by tunnels-positional parmeters,and lining thickness.The study presents a mechanistic framework that delineates the critical depth-spacing-thickness regimes controlling twin-tunnel behavior,providing engineers with clear design boundaries and performance-based lining guidelines to improve the stability of both tunnels and overlying foundations.
基金support from the National Natural Science Foun-dation of China(Grant Nos.U24A20599 and 42277173)the National Science and Technology Major Project of China(Grant No.2024ZD1004300)is gratefully acknowledged.
文摘The deep tunnels are prone to mud and water inrush disasters when crossing water-rich weak zones.A good understanding the hydromechanical behavior of the water-rich weak zone in deep tunnels is the prerequisite for determining the limit support pressure on the tunnel face.However,the seepage forces within the water-rich weak zone are not well estimated in existing models.To overcome this,an analytical model is proposed in this study to determine the limit support pressure of a deep tunnel crossing the water-rich weak zone.The seepage force in the water-rich weak zone is obtained by solving a group of Laplace equations about the hydraulic head,avoiding complex physical and mathematical approximation in existing models.Besides,the seepage boundary conditions in the water-rich weak zone are considered at the nodes on the Neumann boundary and the Dirichlet boundary.The effectiveness of the proposed model is then validated by numerical simulations and engineering practice.It shows that the proposed model has higher accuracy and wider applicability in estimating the hydraulic head.The proposed model can be used for stability analysis of tunnel faces.
基金supported by the National Key Research and Development Program of China (Grant No.2024YFA1210400)the National Science Fund for Distinguished Young Scholars (Grant No.52525101)+3 种基金the National Natural Science Foundation of China (Grant Nos.52450001 and 22409014)the International Cooperation and Exchange of the National Natural Science Foundation of China (Grant No.52411540237)the Tencent Xplorer Prizethe support of the National High-Level Talent Special Support Programs—Young Talents。
文摘The interdependence of electrical parameters has long inhibited the progress of bismuth telluride(Bi_(2)Te3),limiting its widespread application in thermoelectric cooling and power generation.This work investigates the n-type Bi_(2)Te_(2.79)Se_(0.21)I_(0.004)(Bi_(2)(Te,Se)_(3),BTS)system with light Zn doping,revealing that Zn addition simultaneously enhances the Seebeck coefficient(S)and electrical conductivity(σ)through the modulation of defect composition and multi-level band regulation.The substitution of Zn atoms at Bi sites enhances S via bandgap(E_(g))widening,band flattening,and band splitting effects,contributing to a competitive power factor(PF)of∼60μW⋅cm^(−1)⋅K^(−2).Additionally,thermal conductivity is maintained at a low level,leading to an extraordinary figure-of-merit(ZT)value of∼1.3 at room temperature.Furthermore,the Bi_(2)Zn_(0.01)Te_(2.79)Se_(0.21)I_(0.004) system demonstrates impressive thermoelectric device performance,with a maximum cooling temperature difference(ΔT_(max))of∼70.0 K at 300 K,rising to∼78.0 K at 323 K and∼85.7 K at 343 K,as well as a maximum conversion efficiency(η_(max))of∼6.2%under aΔT of 200 K.This study clarifies the mechanism of Zn doping and presents a cost-effective strategy for enhancing the performance of n-type BTS thermoelectrics and their devices.
基金funded by Youth Talent Growth Project of Guizhou Provincial Department of Education(No.Qianjiaoji[2024]21)National Natural Science Foundation of China(No.62461008 and No.52507211)Guizhou Provincial Key Technology R&D Program(No.[2024]General 049).
文摘To address the issues of high costs and low component utilization caused by the independent configuration of hybrid DC circuit breakers(HCBs)and DC power flow controllers(DCPFCs)at each port in existing DC distribution networks,this paper adopts a component sharing mechanism to propose a composite multi-port hybrid DC circuit breaker(CM-HCB)with DC power flow and fault current limitation abilities,as well as reduced component costs.The proposed CM-HCB topology enables the sharing of the main breaker branch(MB)and the energy dissipation branch,while the load commutation switches(LCSs)in the main branch are reused as power flow control components,enabling flexible regulation of power flow in multiple lines.Meanwhile,by reconstructing the current path during the fault process,the proposed CM-HCB can utilize the internal coupled inductor to limit the current rise rate at the initial stage of the fault,significantly reducing the requirement for breaking current.A detailed study on the topological structure,steady-state power flow regulation mechanism,transient fault isolation mechanism,control strategy and characteristic analysis of the proposed CM-HCB is presented.Then,a Matlab/Simulink-based meshed three-terminal DC grid simulation platform with the proposed CM-HCB is built.The results indicate that the proposed CM-HCB can not only achieve flexible power flow control during steady-state operation,but also obtain current rise limitation and fault isolation abilities under short-circuit fault conditions,verifying its correctness and effectiveness.Finally,a comparative economic analysis is conducted between the proposed CM-HCB and the other two existing solutions,confirming that its component sharing mechanism can significantly reduce the number of components,lower system costs,and improve component utilization.
基金supported by the National Natural Science Foundation of China(Grant Nos.12104190,12104189,12204312)the Natural Science Foundation of Jiangsu Province(Grant No.BK20210874)+2 种基金General project of Natural Science Research in Colleges And Universities of Jiangsu Province(Grant No.20KJB140008)the Jiangxi Provincial Natural Science Foundation(Grant Nos.20224BAB211014 and 20232BAB201042)Key Laboratory of Tian Qin Project(Sun Yat-sen University)。
文摘A scheme is proposed based on a Mach-Zehnder interferometer with high phase sensitivity,utilizing a two-mode squeezed coherent state,generated by four-wave mixing,as input.The phase sensitivity of this scheme easily surpasses the Heisenberg limit when intensity difference detection is applied.Under phase-matching conditions,the quantum Cramér-Rao bound significantly exceeds the Heisenberg limit.Additionally,the scheme exhibits robustness against photon loss.When compared with the modified SU(1,1)interferometer with two coherent state inputs,this approach demonstrates superior measurement sensitivity,evaluated through various detection methods and the quantum Cramér-Rao bound.This work holds potential applications in quantum metrology.
文摘The quality of cardiopulmonary resuscitation(CPR) significantly influences survival and neurological outcomes in patients with cardiac arrest(CA).Although mechanical chest compression devices and extracorporeal cardiopulmonary resuscitation(ECPR) have demonstrated some benefits,high-quality manual CPR remained the essential first step,particularly in resource-limited settings.In this study,we examined whether opportunities existed to improve manual CPR performance using preliminary data from our recent survey conducted in a province in western China.We aim to emphasize the importance of improving manual CPR quality before implementing advanced interventions.
基金funded by the National Natural Science Foundation of China(No.62364002)Key Scientific Research Projects of Universities in Henan Province(No.24A510014)+5 种基金Xinjiang-Changji Vocational Education Alliance Special Project(No.2050305)National Laboratory of Solid State Microstructures,Nanjing University(No.M36001)Jiangsu Key Laboratory of Optoelectronic Information Functional Materials,Nanjing University(No.ndgd2024005)Henan Province Higher Education College Student Innovation Training Program Project(No.202410478019)the Doctoral Research Initiation Fund Project,Zhoukou Normal University(No.ZKNUC2022018)the Natural Science Foundation Project of Xinjiang Uygur Autonomous Region(No.2022D01C006)。
文摘The porous NiO nanoplates modified with rGO nanosheets and SnO_(2)nanoparticles are developed for accurate and rapid ppb-level NO_(2)detection.The developed SnO_(2)/NiO/rGO sensor towards 50 ppm NO_(2)gas demonstrates an excellent gas-sensing response of 14.8 at 23℃,which is 3.03 times that of Ni O/rGO sensor(4.89)and 6.49 times that of NiO sensor(2.28),respectively.The developed SnO_(2)/NiO/rGO sensor exhibits faster response/recovery speed(12.7/32.8 s@5 ppm),with extra-low theoretical detection limit of 0.15 ppb at room temperature.More fascinatingly,our sensors indicate great sensitivity,outstanding repeatability and long-term stability for longer than 7 weeks.Additionally,it also suggests that 1℃and 1%relative humidity have the same effect on the SnO_(2)/NiO/rGO sensor signal as approximately 13 ppb and 7.0 ppb NO_(2)gas change,respectively.Such excellent properties are mainly attributed to the large surface-to-volume ratio,which provides active sites to NO_(2)gas spread,adsorption and diffusion on material surface in redox reaction.Moreover,the ternary heterojunctions formed by NiO,rGO and SnO_(2)may serve as highly conductive channels to accelerate carrier transfer and abundant oxygen vacancies to reduce the adsorption energy for O_(2)and NO_(2)gas,thus further improving performance of the sensors.
基金supported by the National Natural Science Foundation of China(22209006,21935001)the Natural Science Foundation of Shandong Province(ZR2022QE009)+1 种基金Fundamental Research Funds for the Central Universities(buctrc202307)the Beijing Natural Science Foundation(Z210016).
文摘Low-cost and high-safety aqueous Zn-I_(2) batteries attract extensive attention for large-scale energy storage systems.However,polyiodide shuttling and sluggish iodine conversion reactions lead to inferior rate capability and severe capacity decay.Herein,a three-dimensional polyaniline is wrapped by carboxylcarbon nanotubes(denoted as C-PANI)which is designed as a catalytic cathode to effectively boost iodine conversion with suppressed polyiodide shuttling,thereby improving Zn-I_(2) batteries.Specifically,carboxyl-carbon nanotubes serve as a proton reservoir for more protonated-NH+=sites in PANI chains,achieving a direct I0/I−reaction for suppressed polyiodide generation and Zn corrosion.Attributing to this“proton-iodine”regulation,catalytic protonated C-PANI strongly fixes electrolytic iodine species and stores proton ions simultaneously through reversible-N=/-NH^(+)-reaction.Therefore,the electrolytic Zn-I_(2) battery with C-PANI cathode exhibits an impressive capacity of 420 mAh g^(−1) and ultra-long lifespan over 40,000 cycles.Additionally,a 60 mAh pouch cell was assembled with excellent cycling stability after 100 cycles,providing new insights into exploring effective organocatalysts for superb Zn-halogen batteries.
基金Project(51378510) supported by the National Natural Science Foundation of China。
文摘In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.
