Comprehensive Summary Helically twisted molecular architectures are critical motifs in both biology and synthetic supramolecular chemistry,with unique functional properties derived from their chiral geometries.Althoug...Comprehensive Summary Helically twisted molecular architectures are critical motifs in both biology and synthetic supramolecular chemistry,with unique functional properties derived from their chiral geometries.Although lemniscular(figure-eight)macrocycles with a noncontact crossover point have attracted increasing interest,their metallosupramolecular analogs remain underexplored,largely because of synthetic challenges that hinder precise control.展开更多
基金support from the National Natural Science Foundation of China(22025107,92461302,22301040)the National Youth Top-notch Talent Support Program of China,the Shaanxi Postdoctoral Science Foundation Project(2023BSHYDZZ128)+1 种基金the Xi'an Key Laboratory of Functional Supramolecular Structure and Materialsthe FM&EM International Joint Laboratory of Northwest University.
文摘Comprehensive Summary Helically twisted molecular architectures are critical motifs in both biology and synthetic supramolecular chemistry,with unique functional properties derived from their chiral geometries.Although lemniscular(figure-eight)macrocycles with a noncontact crossover point have attracted increasing interest,their metallosupramolecular analogs remain underexplored,largely because of synthetic challenges that hinder precise control.