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Stereodirected Construction of Lemniscular Metallacycles via Linear d^(10) Ag^(I)/AuI-NHC Coordination Engineering
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作者 Meng-Zhi Han Hai-Ning Zhang +3 位作者 Le Zhang Xiang-Yang Li Can Chen Ying-Feng Han 《Chinese Journal of Chemistry》 2025年第21期2742-2748,共7页
Comprehensive Summary Helically twisted molecular architectures are critical motifs in both biology and synthetic supramolecular chemistry,with unique functional properties derived from their chiral geometries.Althoug... Comprehensive Summary Helically twisted molecular architectures are critical motifs in both biology and synthetic supramolecular chemistry,with unique functional properties derived from their chiral geometries.Although lemniscular(figure-eight)macrocycles with a noncontact crossover point have attracted increasing interest,their metallosupramolecular analogs remain underexplored,largely because of synthetic challenges that hinder precise control. 展开更多
关键词 Coordiantion-driven assembly Coordination engineering Helical structures Metal-N-heterocyclic carbene Metallosupramolecular lemniscular Weak intermolecular interactions Supramolecular chemistry Metal ion Ligand design NANOSTRUCTURES
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