In 2011,the Chinese Academy of Sciences launched an engineering project to develop an acceleratordriven subcritical system(ADS)for nuclear waste transmutation.The China Lead-based Reactor(CLEAR),proposed by the Instit...In 2011,the Chinese Academy of Sciences launched an engineering project to develop an acceleratordriven subcritical system(ADS)for nuclear waste transmutation.The China Lead-based Reactor(CLEAR),proposed by the Institute of Nuclear Energy Safety Technology,was selected as the reference reactor for ADS development,as well as for the technology development of the Generation IV lead-cooled fast reactor.The conceptual design of CLEAR-I with 10 MW thermal power has been completed.KYLIN series lead-bismuth eutectic experimental loops have been constructed to investigate the technologies of the coolant,key components,structural materials,fuel assembly,operation,and control.In order to validate and test the key components and integrated operating technology of the lead-based reactor,the lead alloy-cooled non-nuclear reactor CLEAR-S,the lead-based zero-power nuclear reactor CLEAR-0,and the lead-based virtual reactor CLEAR-V are under realization.展开更多
An attempt was made to build up a thick and compact oxide layer rapidly by pre-treating the Pb-Ag-Nd anode in fluoride-containing H2SO4 solution. The passivation reaction of Pb-Ag-Nd anode during pre-treatment process...An attempt was made to build up a thick and compact oxide layer rapidly by pre-treating the Pb-Ag-Nd anode in fluoride-containing H2SO4 solution. The passivation reaction of Pb-Ag-Nd anode during pre-treatment process was investigated using cyclic voltammetry, linear scanning voltammetry, environmental scanning electron microscopy and X-ray diffraction analysis. The results show that Pb F2 and PbSO4 are formed near the potential of Pb/PbSO4 couple. The pre-treatment in fluoride-containing H2SO4 solution contributes to the formation of a thick, compact and adherent passive film. Furthermore, pre-treatment in fluoride-containing H2SO4 solution also facilitates the formation of PbO2 on the anodic layer, and the reason could be attributed to the formation of more PbF2 and PbSO4 during the pre-treatment which tend to transform to PbO2 during the following electrowinning process. In addition, the anodic layer on anode with pre-treatment in fluoride-containing H2SO4 solution is thick and compact, and its predominant composition is β-PbO2. In summary, the pre-treatment in fluoride-containing H2SO4 solution benefits the formation of a desirable protective layer in a short time.展开更多
Online reactivity monitoring plays an important role in operation and safety analyses of fission reactor systems. The inverse kinetics method, which is based on a point kinetics model, is the most widely used method f...Online reactivity monitoring plays an important role in operation and safety analyses of fission reactor systems. The inverse kinetics method, which is based on a point kinetics model, is the most widely used method for reactivity reconstruction of critical water reactors. However, this method is seldom applied to the reactivity reconstruction of subcritical reactors. In this study, an inverse kinetics method was employed for the reactivity reconstruction of a lead-based reactor under different initial reactivity states(ρ_0= 0,-2786,-5486,-8367, and-12,371 pcm). The results showed that the deviation in the reactivity of the lead-based subcritical reactor was greater when ρ_0 became smaller. The reactivity reconstructed using the inverse kinetics method was globally underestimated. At a given reactivity perturbation, the relative and absolute errors increased with the decrease in the initial reactivity. At a given initial reactivity, with the increase in the reactivity perturbation, the absolute error increased, whereas the relative error remained the same.This deviation is due to the variation in the external neutron source, spatial-spectral effects, and sub-diffusive effects, which require further study.展开更多
The solid solution characteristics of Pb（B1/3Nb2/3）O3-based （B=Zn^2＋, Mg^2＋, Ni^2＋） composite ceramics prepared by two-phase mixed-sintering method were developed based on dielectric measurements. Results show ...The solid solution characteristics of Pb（B1/3Nb2/3）O3-based （B=Zn^2＋, Mg^2＋, Ni^2＋） composite ceramics prepared by two-phase mixed-sintering method were developed based on dielectric measurements. Results show that there are double dielectric peaks for PZN-based composite ceramic, implying two phases coexist. However single dielectric peak was presented in PMN- and PNN-based composite ceramics, respectively. It is indicated that obvious solid solution reaction exists during the sintering process of these two systems. The effects of B-site ion difference on the solid solution characteristics were discussed by crystal chemistry. SEM was employed to investigated the microstructures of composite ceramics. The influences of solid solution reaction on grain growth were discussed.展开更多
Utilizing efficient and eco-friendly electrochemical techniques for the synthesis of valuable chemicals represents an optimal strategy for enhancing energy utilization.Electrochemical ozone production(EOP),recognized ...Utilizing efficient and eco-friendly electrochemical techniques for the synthesis of valuable chemicals represents an optimal strategy for enhancing energy utilization.Electrochemical ozone production(EOP),recognized for its cleanliness and adaptability,emerges as a promising energy conversion technology for the synthesis of high-value chemicals.However,the selection of anode materials poses a significant challenge to the widespread commercial deployment of EOP,and a thorough investigation into this area is crucial for improving both the performance and durability.In this review,we delve into the fundamental principle of ozone generation,explore the advantages and constraints associated with various EOP systems,and discuss how the utilization of advanced membrane electrode assembly(MEA)electrolysis cells can sustain an overall efficiency of 20%or higher.This review offers objective evaluations of various anode materials and summarizes recent advancements in EOP,highlighting laboratory-measured current efficiencies that surpass 50%.Lastly,this review delineates the myriad challenges encountered within the current EOP research and proposes potential avenues for future development,all in an effort to furnish indispensable insights for the industrial implementation of EOP.展开更多
Optoelectronic devices,including light sensors and light-emitting diodes,are indispensable for our daily lives.Lead-based optoelectronic materials,including colloidal quantum dots and lead-halide perovskites,have emer...Optoelectronic devices,including light sensors and light-emitting diodes,are indispensable for our daily lives.Lead-based optoelectronic materials,including colloidal quantum dots and lead-halide perovskites,have emerged as promising candidates for the next-generation optoelectronic devices.This is primarily attributed to their tailorable optoelectronic properties,industrialization-compatible manufacturing techniques,seamless integration with silicon technology and excellent device performance.In this perspective,we review recent advancements in lead-based optoelectronic devices,specifically focusing on photodetectors and active displays.By discussing the current challenges and limitations of lead-based optoelectronics,we find the exciting potential of on-chip,in-situ fabrication methods for realizing high-performance optoelectronic systems.展开更多
Alloying strategies provide a high degree of freedom for reducing lead toxicity,improving thermodynamic stability, tuning the optoelectronic properties of ABX3 halide perovskites by varying the alloying element specie...Alloying strategies provide a high degree of freedom for reducing lead toxicity,improving thermodynamic stability, tuning the optoelectronic properties of ABX3 halide perovskites by varying the alloying element species and their contents.Given the key role of B-site cations in contributing band edge states and modulating structure factors in halide perovskites,the partial replacement of Pb2+with different B-site metal ions has been proposed.Although several experimental attempts have been made to date,the effect of B-site alloying on the stability and electronic properties of halide perovskites has not been fully explored.Herein,we take cubic CsPbBr3 perovskite as the prototype material and systematically explore the effects of B-site alloying on Pb-containing perovskites.According to the presence or absence of the corresponding perovskite phase,the ten alloying elements investigated are classified into three types(i.e.,Type Ⅰ:Sn Ge,Ca,Sr;Type Ⅱ:Cd,Mg,Mn;Type Ⅲ:Ba,Zn,Cu).Based on the first-principles calculations,we obtain the following conclusions.First,these B-site alloys will exist as disordered solid solutions rather than ordered structures at room temperature throughout the composition space.Second,the alloying of Sn and Ge enhances the thermodynamic stability of the cubic perovskite host,whereas the alloying of the other elements has no remarkable effect on the thermodynamic stability of the cubic perovskite host.Third,the underlying physical mechanism for bandgap tuning can be attributed to the atomic orbital energy mismatch or quantum confinement effect.Fourth,the alloying of different elements demonstrates the diversity in the regulation of crystal structure and electronic properties,indicating potential applications in photovoltaic s and self-trapped exciton-based light-emitting applications.Our work provides theoretical guidance for using alloying strategies to reduce lead toxicity,enhance stability,and optimize the electronic properties of halide perovskites to meet the needs of optoelectronic applications.展开更多
文摘In 2011,the Chinese Academy of Sciences launched an engineering project to develop an acceleratordriven subcritical system(ADS)for nuclear waste transmutation.The China Lead-based Reactor(CLEAR),proposed by the Institute of Nuclear Energy Safety Technology,was selected as the reference reactor for ADS development,as well as for the technology development of the Generation IV lead-cooled fast reactor.The conceptual design of CLEAR-I with 10 MW thermal power has been completed.KYLIN series lead-bismuth eutectic experimental loops have been constructed to investigate the technologies of the coolant,key components,structural materials,fuel assembly,operation,and control.In order to validate and test the key components and integrated operating technology of the lead-based reactor,the lead alloy-cooled non-nuclear reactor CLEAR-S,the lead-based zero-power nuclear reactor CLEAR-0,and the lead-based virtual reactor CLEAR-V are under realization.
基金Projects(51204208,51374240)supported by the National Natural Science Foundation of ChinaProject(2014zzts028)supported by the Fundamental Research Funds for the Central Universities of Central South University,China
文摘An attempt was made to build up a thick and compact oxide layer rapidly by pre-treating the Pb-Ag-Nd anode in fluoride-containing H2SO4 solution. The passivation reaction of Pb-Ag-Nd anode during pre-treatment process was investigated using cyclic voltammetry, linear scanning voltammetry, environmental scanning electron microscopy and X-ray diffraction analysis. The results show that Pb F2 and PbSO4 are formed near the potential of Pb/PbSO4 couple. The pre-treatment in fluoride-containing H2SO4 solution contributes to the formation of a thick, compact and adherent passive film. Furthermore, pre-treatment in fluoride-containing H2SO4 solution also facilitates the formation of PbO2 on the anodic layer, and the reason could be attributed to the formation of more PbF2 and PbSO4 during the pre-treatment which tend to transform to PbO2 during the following electrowinning process. In addition, the anodic layer on anode with pre-treatment in fluoride-containing H2SO4 solution is thick and compact, and its predominant composition is β-PbO2. In summary, the pre-treatment in fluoride-containing H2SO4 solution benefits the formation of a desirable protective layer in a short time.
基金supported by the Strategic Priority Science and Technology Program of the Chinese Academy of Sciences(No.XDA03040000)the National Natural Science Foundation of China(NSFC)(Nos.11305205,11305203,and 11405204)+3 种基金the Special Program for Informatization of the Chinese Academy of Sciences(No.XXH12504-1-09)the Anhui Provincial Special project for High Technology Industrythe Special Project of Youth Innovation Promotion Association of Chinese Academy of Sciencesthe Industrialization Fund
文摘Online reactivity monitoring plays an important role in operation and safety analyses of fission reactor systems. The inverse kinetics method, which is based on a point kinetics model, is the most widely used method for reactivity reconstruction of critical water reactors. However, this method is seldom applied to the reactivity reconstruction of subcritical reactors. In this study, an inverse kinetics method was employed for the reactivity reconstruction of a lead-based reactor under different initial reactivity states(ρ_0= 0,-2786,-5486,-8367, and-12,371 pcm). The results showed that the deviation in the reactivity of the lead-based subcritical reactor was greater when ρ_0 became smaller. The reactivity reconstructed using the inverse kinetics method was globally underestimated. At a given reactivity perturbation, the relative and absolute errors increased with the decrease in the initial reactivity. At a given initial reactivity, with the increase in the reactivity perturbation, the absolute error increased, whereas the relative error remained the same.This deviation is due to the variation in the external neutron source, spatial-spectral effects, and sub-diffusive effects, which require further study.
基金the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry(2005)
文摘The solid solution characteristics of Pb（B1/3Nb2/3）O3-based （B=Zn^2＋, Mg^2＋, Ni^2＋） composite ceramics prepared by two-phase mixed-sintering method were developed based on dielectric measurements. Results show that there are double dielectric peaks for PZN-based composite ceramic, implying two phases coexist. However single dielectric peak was presented in PMN- and PNN-based composite ceramics, respectively. It is indicated that obvious solid solution reaction exists during the sintering process of these two systems. The effects of B-site ion difference on the solid solution characteristics were discussed by crystal chemistry. SEM was employed to investigated the microstructures of composite ceramics. The influences of solid solution reaction on grain growth were discussed.
基金supported by the National Natural Science Foundation of China(No.22208376)Qingdao New Energy Shandong Laboratory Open Project(QNESL OP 202303)+2 种基金Shandong Provincial Natural Science Foundation(No.ZR2024QB175,No.ZR2023LFG005)Taishan Scholar Project(ts201712020)support from Science and Technology Innovation Teams of Shanxi Province(202304051001023).
文摘Utilizing efficient and eco-friendly electrochemical techniques for the synthesis of valuable chemicals represents an optimal strategy for enhancing energy utilization.Electrochemical ozone production(EOP),recognized for its cleanliness and adaptability,emerges as a promising energy conversion technology for the synthesis of high-value chemicals.However,the selection of anode materials poses a significant challenge to the widespread commercial deployment of EOP,and a thorough investigation into this area is crucial for improving both the performance and durability.In this review,we delve into the fundamental principle of ozone generation,explore the advantages and constraints associated with various EOP systems,and discuss how the utilization of advanced membrane electrode assembly(MEA)electrolysis cells can sustain an overall efficiency of 20%or higher.This review offers objective evaluations of various anode materials and summarizes recent advancements in EOP,highlighting laboratory-measured current efficiencies that surpass 50%.Lastly,this review delineates the myriad challenges encountered within the current EOP research and proposes potential avenues for future development,all in an effort to furnish indispensable insights for the industrial implementation of EOP.
基金supported by the National Key Research and Development Program of China(Nos.2024YFA1209503 and 2021YFB3501800)the National Natural Science Foundation of China(Grant Nos.62322505 and 62374069)the Innovation Project of Optics Valley Laboratory(No.OVL2023ZD002).
文摘Optoelectronic devices,including light sensors and light-emitting diodes,are indispensable for our daily lives.Lead-based optoelectronic materials,including colloidal quantum dots and lead-halide perovskites,have emerged as promising candidates for the next-generation optoelectronic devices.This is primarily attributed to their tailorable optoelectronic properties,industrialization-compatible manufacturing techniques,seamless integration with silicon technology and excellent device performance.In this perspective,we review recent advancements in lead-based optoelectronic devices,specifically focusing on photodetectors and active displays.By discussing the current challenges and limitations of lead-based optoelectronics,we find the exciting potential of on-chip,in-situ fabrication methods for realizing high-performance optoelectronic systems.
基金supported by the National Natural Science Foundation of China(Grant Nos.12004131,and 22090044)the Jilin Province Science and Technology Development Program(Grant No.20210508044RQ)。
文摘Alloying strategies provide a high degree of freedom for reducing lead toxicity,improving thermodynamic stability, tuning the optoelectronic properties of ABX3 halide perovskites by varying the alloying element species and their contents.Given the key role of B-site cations in contributing band edge states and modulating structure factors in halide perovskites,the partial replacement of Pb2+with different B-site metal ions has been proposed.Although several experimental attempts have been made to date,the effect of B-site alloying on the stability and electronic properties of halide perovskites has not been fully explored.Herein,we take cubic CsPbBr3 perovskite as the prototype material and systematically explore the effects of B-site alloying on Pb-containing perovskites.According to the presence or absence of the corresponding perovskite phase,the ten alloying elements investigated are classified into three types(i.e.,Type Ⅰ:Sn Ge,Ca,Sr;Type Ⅱ:Cd,Mg,Mn;Type Ⅲ:Ba,Zn,Cu).Based on the first-principles calculations,we obtain the following conclusions.First,these B-site alloys will exist as disordered solid solutions rather than ordered structures at room temperature throughout the composition space.Second,the alloying of Sn and Ge enhances the thermodynamic stability of the cubic perovskite host,whereas the alloying of the other elements has no remarkable effect on the thermodynamic stability of the cubic perovskite host.Third,the underlying physical mechanism for bandgap tuning can be attributed to the atomic orbital energy mismatch or quantum confinement effect.Fourth,the alloying of different elements demonstrates the diversity in the regulation of crystal structure and electronic properties,indicating potential applications in photovoltaic s and self-trapped exciton-based light-emitting applications.Our work provides theoretical guidance for using alloying strategies to reduce lead toxicity,enhance stability,and optimize the electronic properties of halide perovskites to meet the needs of optoelectronic applications.
