Cyanide is the most widely used reagent in gold production processes. However, cyanide is highly toxic and poses safety haz-ards during transportation and use. Therefore, it is necessary to develop gold leaching reage...Cyanide is the most widely used reagent in gold production processes. However, cyanide is highly toxic and poses safety haz-ards during transportation and use. Therefore, it is necessary to develop gold leaching reagents that can replace cyanide. This paper intro-duces a method for synthesizing a gold leaching reagent. Sodium cyanate is used as the main raw material, with sodium hydroxide and so-dium ferrocyanide used as additives. The gold leaching reagent can be obtained under the conditions of a mass ratio of sodium cyanate,sodium hydroxide, and sodium ferrocyanide of 15:3:1, synthesis temperature of 600℃, and synthesis time of 1 h. This reagent has a goodrecovery effect on gold concentrate and gold-containing electronic waste. The gold leaching rate of roasted desulfurized gold concentratecan reach 87.56%. For the extraction experiments of three types of gold-containing electronic waste, the gold leaching rate can reach over90% after 2 h. Furthermore, the reagent exhibits good selectivity towards gold. Component analysis indicates that the effective compon-ent in the reagent could be sodium isocyanate.展开更多
This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitroge...This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitrogen; to be specific, the concentration of nitrate nitrogen in soil planted with wheat was reduced from 692.19 mg/kg to lower than 100 mg/kg; when the mass ratio of amendment to soil reached 3:50 and the amendment particle size was 1-2 mm, the concentration of nitrate ni-trogen in soil planted with wheat was reduced to 43 mg/kg. The amendment type exhibited extremely significant effects on the concentration of ammonium nitrogen; to be specific, when the mass ratio of amendment to soil reached 10:50, the concen-tration of ammonium nitrogen in soil added with 2-3 mm zeolite was reduced from 23 593.75 to 3 300 mg/kg on day 15. Amendments and plants mainly exhibited desorption performance for sulfate radical in soil, and the amendment type extreme-ly significantly affected the concentration of sulfate radical; to be specific, the con-centration of sulfate radical in soil added with limestone increased from 370 mg/kg to 900 mg/kg on day 7.展开更多
基金financially supported by the National Natural Science Foundation of China (No.51974016)。
文摘Cyanide is the most widely used reagent in gold production processes. However, cyanide is highly toxic and poses safety haz-ards during transportation and use. Therefore, it is necessary to develop gold leaching reagents that can replace cyanide. This paper intro-duces a method for synthesizing a gold leaching reagent. Sodium cyanate is used as the main raw material, with sodium hydroxide and so-dium ferrocyanide used as additives. The gold leaching reagent can be obtained under the conditions of a mass ratio of sodium cyanate,sodium hydroxide, and sodium ferrocyanide of 15:3:1, synthesis temperature of 600℃, and synthesis time of 1 h. This reagent has a goodrecovery effect on gold concentrate and gold-containing electronic waste. The gold leaching rate of roasted desulfurized gold concentratecan reach 87.56%. For the extraction experiments of three types of gold-containing electronic waste, the gold leaching rate can reach over90% after 2 h. Furthermore, the reagent exhibits good selectivity towards gold. Component analysis indicates that the effective compon-ent in the reagent could be sodium isocyanate.
基金Supported by National Natural Science Foundation of China(Grant No.21067003,5136-4015)Natural Science Foundation of Jiangxi Province(Grant No.20114BAB203024)National High-Tech Research and Development Program of China(Grant No.2012BAC11B07)~~
文摘This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitrogen; to be specific, the concentration of nitrate nitrogen in soil planted with wheat was reduced from 692.19 mg/kg to lower than 100 mg/kg; when the mass ratio of amendment to soil reached 3:50 and the amendment particle size was 1-2 mm, the concentration of nitrate ni-trogen in soil planted with wheat was reduced to 43 mg/kg. The amendment type exhibited extremely significant effects on the concentration of ammonium nitrogen; to be specific, when the mass ratio of amendment to soil reached 10:50, the concen-tration of ammonium nitrogen in soil added with 2-3 mm zeolite was reduced from 23 593.75 to 3 300 mg/kg on day 15. Amendments and plants mainly exhibited desorption performance for sulfate radical in soil, and the amendment type extreme-ly significantly affected the concentration of sulfate radical; to be specific, the con-centration of sulfate radical in soil added with limestone increased from 370 mg/kg to 900 mg/kg on day 7.