Here we report on simultaneous lidar observations of sporadic Ni(Nis)layers and sporadic Na(Nas)layers in the atmosphere over Yanqing,Beijing(40.42°N,116.02°E)from April 2019 to October 2022.During 343 night...Here we report on simultaneous lidar observations of sporadic Ni(Nis)layers and sporadic Na(Nas)layers in the atmosphere over Yanqing,Beijing(40.42°N,116.02°E)from April 2019 to October 2022.During 343 nights of observation,68 Nis and 56 Nas were observed.The seasonal variation of Nis and Nas was also obtained,with the highest occurrence of Nis being in July(43%)and that of Nas being in June(61%).We found that the seasonal variation of Nis is similar to that of Nas and that both occur more frequently in summer than in winter.In addition,we found 23 events in which Nis and Nas occur simultaneously.The average peak altitude of Nas is approximately 1 km higher than that of Nis,and the peak density ratio of Nas to Nis is approximately 5,which is half the density ratio of the two main layers.Additionally,the strength factor for Nas is smaller than that for Nis.Through data analysis of sporadic E layers(Es),we found that Nis and Nas has a significant correlation with Es.The neutralization rates of Ni^(+)/Na^(+)were calculated according to the dissociative recombination reaction of Ni^(+)/Na^(+)and the WACCM-Ni(Whole Atmosphere Community Climate Model of Ni).The production rates of Ni and Na were estimated to be approximately 1:4.4,which is consistent with the density ratio of Nis to Nas.The results showed that the neutralization reaction of Ni+,Na+,and electrons in Es is the main reason for the formation of the Nis layer and the Nas layer.展开更多
A novel trace nickel(Ni)doped tungsten(W)matrix with coated Ni on W grains was prepared by powder metallurgy method.The introduction of Ni can inhibit the reaction between W and barium-calcium aluminates(Ba-Ca alumina...A novel trace nickel(Ni)doped tungsten(W)matrix with coated Ni on W grains was prepared by powder metallurgy method.The introduction of Ni can inhibit the reaction between W and barium-calcium aluminates(Ba-Ca aluminates)during the impregnation process of the matrix.After cathode activation,the surface Ba:O molar ratio is 0.88:1.00,much higher than the Ba dispenser cathode without Ni doping.The XPS results of the cathode surface showed that the metallic Ba appeared on the activated cathode surface,forming dipoles with oxygen,and effectively reducing the cathode surface work function.The pulse electron emission current density at 1100℃_(b)(brightness temperature)was 18.26 A/cm^(2),and the calculated work function was 1.97 eV.It has a low evaporation rate and the accelerated lifetime test predict a lifetime of over 160000 h.First-principles calculations showed that the charge transfer and dipole moment in the NiW-BaO system were both increased compared to the Ba dispenser cathode,thus improving the emission performance of the Ni-W mixed matrix cathode.展开更多
The effect of local polymer injection on a flat-plate turbulent boundary layer was investigated experimentally,with a particular focus on the distinct mechanisms of drag reduction in the low-drag reduction(LDR)and hig...The effect of local polymer injection on a flat-plate turbulent boundary layer was investigated experimentally,with a particular focus on the distinct mechanisms of drag reduction in the low-drag reduction(LDR)and high-drag reduction(HDR)states.High-resolution measurements of the near-wall flow field were achieved using particle tracking velocimetry(PTV),while large-field measurements covering the entire boundary layer were obtained through particle image velocimetry(PIV).It is found that in the LDR state,the mean shear and turbulence intensity in the near-wall region are mildly suppressed.The influence of polymer solution is limited to the near-wall region and does not affect the self-sustaining cycle of wall-bounded turbulence.Conversely,in the HDR state,the polymer solution effectively disrupts the self-sustaining process of wall-bounded turbulence by suppressing the lifting of the low-speed streaks.Consequently,the turbulence production is attenuated.The buffer layer is extended,and the slope of the log-law region also becomes larger when polymer concentration or the Weissenberg number increases.展开更多
Layered transition metal oxide cathode materials have garnered increasing attention for sodium-ion batteries(SIBs).However,they are plagued by the Jahn-Teller distortion of MnO6,Na^(+)/vacancy ordering,and irreversibl...Layered transition metal oxide cathode materials have garnered increasing attention for sodium-ion batteries(SIBs).However,they are plagued by the Jahn-Teller distortion of MnO6,Na^(+)/vacancy ordering,and irreversible lattice oxygen loss,which collectively lead to capacity fading and voltage decay.Herein,we report a P2-type material,Na_(0.67)Ni_(0.3)Mn_(0.6)Li_(0.09)Sn_(0.01)O_(2)(NNMO-Li0.09Sn0.01),modified with two closed-shell dopants(i.e.,Li^(+)and Sn^(4+)).Benefiting from the unique electronic configurations of closed-shell ions,NNMO-Li0.09Sn0.01 exhibits enhanced structural and electrochemical stability.Specifically,the incorporation of Li^(+)increases the Mn^(4+)/Mn3+ratio,thereby mitigating Jahn-Teller distortion during(de)sodiation process.In addition,Li^(+)disrupts the Ni/Mn ordering in the transition metal layer,suppressing Na^(+)/vacancy ordering.Meanwhile,the introduction of Sn^(4+)forms stronger Sn-O bonds(548 kJ mol-1),thereby enhancing the bonding strength between neighboring transition metal ions and surrounding oxygen atoms,effectively reducing oxygen loss during cycling.NNMO-Li0.09Sn0.01 exhibits significantly improved cycling stability,delivering a specific capacity of 90.3 mAh g^(-1)with 62.9%capacity retention after 50 cycles at 0.1 C(1 C=200 mA g^(-1)),along with 90.3%voltage retention.This substitution strategy based on closed-shell ions offers a viable approach for enhancing the structural stability of wide-voltage layered oxide cathodes.展开更多
Layered double hydroxides(LDHs)are promising electrocatalysts for the oxygen evolution reaction(OER),yet their practical application remains limited by poor electrical conductivity and sluggish reaction kinetics.In th...Layered double hydroxides(LDHs)are promising electrocatalysts for the oxygen evolution reaction(OER),yet their practical application remains limited by poor electrical conductivity and sluggish reaction kinetics.In this work,we synthesize three high-entropy LDHs(HELDHs)featuring a hierarchical architecture of microspheres assembled from ultrathin nanosheets,via a simple hydrothermal method using a combination of low-cost,catalytically active transition metals(Fe,Co,Ni,Mn,Zn,Cu,and Cr).Among them,the FeCoNiMnZn HELDH exhibits outstanding OER performance,requiring an overpotential of only 306 mV to reach a current density of 100 mA cm^(-2).Notably,during 200 h of continuous operation,the device exhibits a stable and,in some cases,increasing current output.This exceptional activity is attributed to the formation of abundant cation vacancies,induced by Zn leaching,which enhance the intrinsic catalytic properties by optimizing the adsorption energies of key OER intermediates.Density functional theory calculations further validate that these vacancies modulate the electronic structure and lower reaction barriers,underscoring the effectiveness of cation-vacancy engineering in high-entropy systems for efficient and durable water oxidation catalysis.The optimized catalyst was further evaluated as the air cathode in a zinc-air battery,demonstrating practical electrochemical performance.展开更多
Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage,but their commercialization is hindered by zinc anode challenges,notably parasitic reactions and dendrite growth.Herein,we...Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage,but their commercialization is hindered by zinc anode challenges,notably parasitic reactions and dendrite growth.Herein,we present a biodegradable biomass-derived protective layer,primarily composed of curcumin,as a zincophilic interface for AZMBs.The curcumin-based layer,fabricated via a homogeneous solution process,exhibits strong adhesion,uniform coverage,and robust mechanical integrity.Rich polar functional groups in curcumin facilitate homogeneous Zn~(2+)flux and suppress side reactions.The curcumin-based layer shows a favorable affinity for zinc trifluoromethanesulfonate(Zn(OTf)_(2))electrolyte,which is the representative of organic zinc salts,enabling optimal thickness for both protection and ion transport.The protected Zn anodes demonstrate an extended lifespan of 2500 h in symmetrical cells and a high Coulombic efficiency of 99.15%.Furthermore,Zn(OTf)_(2)-based system typically exhibits poor stability at high current densities.Fortunately,the lifespan of symmetrical cells was extended by 40-fold at the high current density.When paired with an Na V_(3)O_(8)·1.5H_(2)O(NVO)cathode,the system achieves 86.5%capacity retention after 3000 cycles at a large specific current density of 10 A g^(-1).These results underscore the efficacy of the curcumin-based protective layer in enhancing the reversibility and stability of metal electrodes,specifically relieving the instability of Zn(OTf)_(2)-based systems at high current densities,advancing its commercial viability.展开更多
The formation of Zn dendrites and the occurrence of the hydrogen evolution reaction(HER)at Zn anodes represent two major obstacles that significantly impede the widespread commercialization of aqueous Zn-ion batteries...The formation of Zn dendrites and the occurrence of the hydrogen evolution reaction(HER)at Zn anodes represent two major obstacles that significantly impede the widespread commercialization of aqueous Zn-ion batteries.In this work,we propose sorbitan oleate(Span 80)as a novel amphiphilic electrolyte additive for 2 mol/L ZnSO_(4),demonstrating multifunctional performance.The unique ultra-long hydrophobic carbon chains of Span 80 effectively reduce free water molecules at the Zn anode-electrolyte interface,forming a robust hydrophobic interfacial layer that significantly suppresses HER and corrosion reactions.Simultaneously,carbon chains can enhance the desolvation effect of[Zn(H_(2)O)_(6)]^(2+),leading to improve rate performance.Additionally,the hydrophilic sorbitan groups in Span 80 selectively adsorb onto active sites of the Zn anode,promoting uniform Zn^(2+)deposition and suppressing dendrite growth.The optimized Zn||Zn symmetric cell exhibits outstanding cycling stability,sustaining reversible plating/stripping for 570 h at 50 mA/cm^(2) and the Zn||V_(2)O_(5) full cell retains exceptional stability over 2000 cycles at 1 A/g.Our work presents a promising strategy for suppressing interfacial side reactions by constructing a hydrophobic protective layer through the use of ultra-long carbon chain surfactants.This approach offers new insights into enhancing the performance of aqueous Zn-ion batteries.展开更多
AIM:To investigate the changes of retinal vascular parameters and retinal layer thickness in patients with multiple sclerosis(MS).METHODS:This single-centered case-control study was performed on a MS group of 42 patie...AIM:To investigate the changes of retinal vascular parameters and retinal layer thickness in patients with multiple sclerosis(MS).METHODS:This single-centered case-control study was performed on a MS group of 42 patients diagnosed with MS and a control group of 43 healthy hospital staff matched in terms of age and sex at Iran University,department of neurology and ophthalmology from March 2020 to March 2021.The ophthalmic parameters of each patient were recorded,and optical coherence tomography was used to evaluate the retinal thickness in the layers.RESULTS:This study enrolled a total of 85 participants,with a mean age of 40.44±11.52 years,including 61 females(72%).The control group consisted of 43 individuals with a mean age of 39.49±11.07 years,while the MS group comprised 42 participants with a mean age of 41.40±12.01 years.The mean disease duration in the MS group was 8.45±6.04 a.The thickness of the ganglion cell layer in the right eye was significantly lower in the MS group compared to the control group(P=0.034).In addition,except for the left nasal sector(P=0.106),the mean peripapillary neurofibrillation in all examined sectors were significantly lower in the MS group than in the control group(P<0.05).The average vessel density in both the deep and superficial capillary plexuses across all regions of both eyes was lower in the MS group than in the control group,with all comparisons for the superficial capillary plexus showing statistical significance(P<0.05 for all except the left nasal sector).CONCLUSION:The thickness of the retina of patients with MS is significantly reduced.Therefore,optical coherence tomography results can be used as a reliable tool to evaluate disease progression and prognosis in MS patients.展开更多
This study introduces a new ocean surface friction velocity scheme and a modified Thompson cloud microphysics parameterization scheme into the CMA-TYM model.The impact of these two parameterization schemes on the pred...This study introduces a new ocean surface friction velocity scheme and a modified Thompson cloud microphysics parameterization scheme into the CMA-TYM model.The impact of these two parameterization schemes on the prediction of the movement track and intensity of Typhoon Kompasu in 2021 is examined.Additionally,the possible reasons for their effects on tropical cyclone(TC)intensity prediction are analyzed.Statistical results show that both parameterization schemes improve the predictions of Typhoon Kompasu’s track and intensity.The influence on track prediction becomes evident after 60 h of model integration,while the significant positive impact on intensity prediction is observed after 66 h.Further analysis reveals that these two schemes affect the timing and magnitude of extreme TC intensity values by influencing the evolution of the TC’s warm-core structure.展开更多
The atmospheric surface layer of the tropical coastal ocean is commonly very unstable and experiences weakwind conditions.How the latent(LE)and sensible(H)heat fluxes behave under such conditions are unclear because o...The atmospheric surface layer of the tropical coastal ocean is commonly very unstable and experiences weakwind conditions.How the latent(LE)and sensible(H)heat fluxes behave under such conditions are unclear because of the lack of observation stations in the tropics.Thus,this study aims to analyze LE and H and the microclimate parameters influencing them.The authors deployed an eddy covariance system in a tropical coastal region for seven months.The microclimate parameters investigated were wind speed(U),vapor pressure deficit(Δe),temperature difference(ΔT),wind-vapor pressure deficit(UΔe),wind-temperature difference(UΔT),and atmospheric stability(z/L),where z is height and L is the Monin–Obukhov length.On the daily time scale,the results show that LE was more associated with U thanΔe,while H was more related toΔT than U.Cross-wavelet analysis revealed the strong coherence in the LE-U relationship for periods between one and two days,and for H–ΔT,0.5 to 1 day.Correlation and regression analyses confirmed the time series analyses results,where strong positive correlation coefficients(r)were obtained between LE and U(r=0.494)and H andΔT(r=0.365).Compared to other water bodies,the transfer coefficient of moisture(CE N)was found to be small(=0.40×10^(-3))and independent of stability;conversely,the transfer coefficient of heat(CH N)was closer to literature values(=1.00×10^(-3))and a function of stability.展开更多
As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises s...As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises structural concerns,and the latter is of aerodynamic interest.Thus,panel aeroelasticity in shock-dominated flow represents a vital topic for the development and optimization of supersonic vehicles and propulsion systems.This review systematically summarizes recent advances in the methodologies applied to capture structural and fluid dynamics,including theoretical models,numerical simulations,and wind tunnel experiments.The application of data-driven modal decomposition,an advanced technique to extract physically crucial features,on the topic is introduced.From the perspective of FSIs,the distinctive aeroelastic behaviors in shock-dominated flow,including hysteresis phenomena and nonlinear responses,are highlighted.From the perspective of SBLIs,the modifications in their spatial and temporal characteristics imposed by the aeroelastic responses are emphasized.Motivated by the interaction between the shock waves and structural response,different strategies have been proposed to implement aeroelastic suppression and shock control,which have the potential to enhance structural safety and aerodynamic performance in the next generation of high-speed flight vehicles.展开更多
The deep coal reservoir in Linxing-Shenfu block of Ordos Basin is an important part of China’s coalbed methane resources.In the process of reservoir reconstruction,the artificial fracture morphology of coal seam with...The deep coal reservoir in Linxing-Shenfu block of Ordos Basin is an important part of China’s coalbed methane resources.In the process of reservoir reconstruction,the artificial fracture morphology of coal seam with gangue interaction is significantly different,which affects the efficient development of coalbed methane resources in this area.In this paper,the surface outcrop of Linxing-Shenfu block is selected,and three kinds of interaction modes between gangue and coal seam are set up,including single-component coal rock sample,coal rock sample with different thicknesses of gangue layer and coal rock sample with different numbers of gangue.Through true triaxial physical simulation and three-dimensional discrete element numerical simulation,the lawof artificial fracture initiation and propagation in multi-gangue interaction coal seam is analyzed in depth,and the hydraulic fracture initiation and propagation mode under different interaction modes of gangue layer in Linxing-Shenfu deep coal reservoir was clarified.The research shows that the initiation of artificial fractures in a single coal seam is affected by geologicalengineering factors.The maximum principal stress dominates the direction of fracture propagation,and the stress difference controls the fracture morphology.When the stress difference is 2 MPa,the fracture morphology is complex,which is easy to connect to the weak surface of coal and rock cleat,and the fracturemorphology of the stress difference is mainly a single main fracture.After the thickness of the gangue layer is increased from 2 to 5 cm,it is difficult for the artificial fracture to penetrate the layer vertically after the fracture initiation,and the effective transformation area of the reservoir is limited.The more the number of gangue layers,the greater the hydraulic energy consumption in the process of fracture propagation,and the more difficult the fracture propagation.展开更多
Layered oxides have attracted significant attention as cathodes for sodium-ion batteries(SIBs)due to their compositional versatility and tuneable electrochemical performance.However,these materials still face challeng...Layered oxides have attracted significant attention as cathodes for sodium-ion batteries(SIBs)due to their compositional versatility and tuneable electrochemical performance.However,these materials still face challenges such as structural phase transitions,Na^(+)/vacancy ordering,and Jahn–Teller distortion effect,resulting in severe capacity decay and sluggish ion kinetics.We develop a novel Cu/Y dual-doping strategy that leads to the formation of"Na–Y"interlayer aggregates,which act as structural pillars within alkali metal layers,enhancing structural stability and disrupting the ordered arrangement of Na^(+)/vacancies.This disruption leads to a unique coexistence of ordered and disordered Na^(+)/vacancy states with near-zero strain,which significantly improves Na^(+)diffusion kinetics.This structural innovation not only mitigates the unfavorable P2–O2 phase transition but also facilitates rapid ion transport.As a result,the doped material demonstrates exceptional electrochemical performance,including an ultra-long cycle life of 3000 cycles at 10 C and an outstanding high-rate capability of~70 mAh g^(−1)at 50 C.The discovery of this novel interlayer pillar,along with its role in modulating Na^(+)/vacancy arrangements,provides a fresh perspective on engineering layered oxides.It opens up promising new pathways for the structural design of advanced cathode materials toward efficient,stable,and high-rate SIBs.展开更多
The electric double layer(EDL)at the electrochemical interface is crucial for ion transport,charge transfer,and surface reactions in aqueous rechargeable zinc batteries(ARZBs).However,Zn anodes routinely encounter per...The electric double layer(EDL)at the electrochemical interface is crucial for ion transport,charge transfer,and surface reactions in aqueous rechargeable zinc batteries(ARZBs).However,Zn anodes routinely encounter persistent dendrite growth and parasitic reactions,driven by the inhomogeneous charge distribution and water-dominated environment within the EDL.Compounding this,classical EDL theory,rooted in meanfield approximations,further fails to resolve molecular-scale interfacial dynamics under battery-operating conditions,limiting mechanistic insights.Herein,we established a multiscale theoretical calculation framework from single molecular characteristics to interfacial ion distribution,revealing the EDL’s structure and interactions between different ions and molecules,which helps us understand the parasitic processes in depth.Simulations demonstrate that water dipole and sulfate ion adsorption at the inner Helmholtz plane drives severe hydrogen evolution and by-product formation.Guided by these insights,we engineered a“water-poor and anion-expelled”EDL using 4,1’,6’-trichlorogalactosucrose(TGS)as an electrolyte additive.As a result,Zn||Zn symmetric cells with TGS exhibited stable cycling for over 4700 h under a current density of 1 mA cm^(−2),while NaV_(3)O_(8)·1.5H_(2)O-based full cells kept 90.4%of the initial specific capacity after 800 cycles at 5 A g^(−1).This work highlights the power of multiscale theoretical frameworks to unravel EDL complexities and guide high-performance ARZB design through integrated theory-experiment approaches.展开更多
Aqueous zinc(Zn)-ion batteries hold great promise as renewable energy storage system for carbon-neutral energy transition.However,Zn anodes suffer from poor Zn plating/stripping reversibility due to Zn dendrite growth...Aqueous zinc(Zn)-ion batteries hold great promise as renewable energy storage system for carbon-neutral energy transition.However,Zn anodes suffer from poor Zn plating/stripping reversibility due to Zn dendrite growth and side reactions.Existing Zn interfacial modification strategies based on single-component or homogeneous structure are insufficient to address these issues comprehensively.Herein,we rationally designed an organic-inorganic hybrid interfacial layer with rigid-to-soft graded structure for dendrite-free and stable Zn anodes.A liquid plasma-assisted oxidation technology is developed to rapidly construct a porous ZnO inner framework in situ.This ZnO layer offers high interfacial energy,mechanical robustness,and an open structure that facilitates ion transport while firmly anchoring a subsequently coated soft polymer layer.The resulting architecture presents a structurally graded and functionally complementary interface,enabling effective dendrite suppression,continuous Zn ion transport,and enhanced corrosion resistance.As a result,a long cycling stability of more than 6000 h can be achieved at 1 mA cm^(-2)for 1 mAh cm^(-2)in symmetric cells.When used as anodes for zinc-iodine full battery,the hybrid interlayer can effectively prevent the Zn anodes from the corrosion by polyiodine,enabling stable cycling and negligible capacity decay(~0.02‰per cycle)for over 10,000 cycles at 2.0 A g^(-1).This work demonstrates a promising interfacial design strategy and introduces a novel liquid plasma-assisted oxidation route for fabricating high-performance Zn anodes towards next-generation aqueous batteries.展开更多
Molecular tailoring of self-assembled hole-transporting monolayers(SAMs)has been proven as an efficient approach for improving the device performance of inverted perovskite solar cells.Herein,a novel SAM with extended...Molecular tailoring of self-assembled hole-transporting monolayers(SAMs)has been proven as an efficient approach for improving the device performance of inverted perovskite solar cells.Herein,a novel SAM with extended conjugation is designed and synthesized,named NaPh-4PACz.Compared to Ph-4PACz,NaPh-4PACz exhibits a larger adsorption energy with the ITO substrate,enabling the formation of a more uniform and dense film,thereby preventing direct contact between the perovskite and ITO.Additionally,NaPh-4PACz also has a stronger interaction with the perovskite,which can reduce buried interface defects and suppress non-radiative recombination.Consequently,NaPh-4PACz-based devices achieved a power conversion efficiency of 25.48%due to their interfacial“adhesive”ability.Importantly,the stability of the NaPh-4PACz-based devices was significantly improved.展开更多
O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe ...O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe structural collapse and performance degradation.Herein,a series of high valence tantalum(Ta^(5+))doped Na(Ni_(0.4)Fe_(0.2)Mn_(0.4))_(1−x)Ta_(x)O_(2)(x=0/0.0025/0.005/0.01)secondary spherical particles are firstly developed,where Ta^(5+)doping enables the refined primary grain with a tightly stacked rod-like morphology.Comprehensive structural analysis via Neutron powder diffraction(NPD)and Synchrotron radiation X-ray diffraction(SXRD)reveals an expanded NaO_(2)slab and a reduction in Na site vacancy.The potential charge compensation mechanism is further illustrated by X-ray absorption spectroscopy(XAS)and X-ray photoelectron spectroscopy(XPS),unveiling a partial reduction from Ni^(3+)to Ni^(2+)with Ta^(5+)doping.In situ X-ray diffraction(in situ XRD)suggests that the decorated sample undergoes a volume change as low as 0.8%,in contrast with the pristine one(1.5%).Thus,the optimized sample with x=0.005 retains an enhanced capacity retention up to 70.4%at 1 C after 300 cycles in half-cell and delivers a high energy density of 251 Wh kg^(-1)(0.1 C)and with a good capacity retention of 81.0%at 1 C after 200 cycles in full-cell.Our findings provide new insights into the mechanism of high valence Ta^(5+)doping in stabilizing layered oxides cathode materials for SIBs.展开更多
Conventional Tb^(3+)-doped phosphors typically suffer from concentration quenching once the doping level exceeds a critical threshold.Consequently,the development of Tb^(3+)phosphors with intrinsic resistance to conce...Conventional Tb^(3+)-doped phosphors typically suffer from concentration quenching once the doping level exceeds a critical threshold.Consequently,the development of Tb^(3+)phosphors with intrinsic resistance to concentration quenching has become a key research focus.In this work,we successfully synthesized KBi(MoO_(4))_(2):x Tb^(3+)(x=0-100 at%)(denoted as KBM:x Tb^(3+))phosphors via a high-temperature solid-state reaction.Remarkably,no concentration quenching was observed across the entire doping range.This anti-quenching behavior originates from the large Tb^(3+)-Tb^(3+)interionic distance(>5Å)inherent to the quasi-layered crystal structure,which effectively suppresses multipole-interaction-mediated energy migration.At full Tb^(3+)substitution(x=100 at%),the material undergoes a structural phase transition from the monoclinic KBM phase to the triclinicα-KTb(MoO_(4))_(2)(α-KTM)phase.Theα-KTM phosphor exhibits excellent thermal stability(activation energy=0.6129 eV)and a single-exponential decay profile,whereas KBM:x Tb^(3+)(x<100%)display double-exponential decay behaviors,attributed to dual energy transfer pathways.These findings provide new insights into the luminescence mechanisms of high-concentration rare-earth-doped systems and offer guidance for designing nextgeneration anti-quenching phosphors.展开更多
Many hydropower projects have been constructed in Southwest China with the strategic goal of achieving carbon neutrality.Most of these hydropower projects utilize concrete face rockfilldams(CFRDs)built on a deep overb...Many hydropower projects have been constructed in Southwest China with the strategic goal of achieving carbon neutrality.Most of these hydropower projects utilize concrete face rockfilldams(CFRDs)built on a deep overburden layer.The deep overburden layer causes uneven settlement between the overburden layer and the dam,which poses a serious threat to the safety of both the construction and operation of the dam.In this study,microseismic(MS)monitoring technology was employed for the firsttime in the fieldof dam fillingengineering,allowing for the real-time monitoring of microfracture in the bedrock during dam construction.The time-frequency analysis method was used to summarize the MS waveform characteristics induced by dam filling.The fracture mechanism of bedrock was revealed,and the relationships among slope deformation,dam settlement,and MS activity were analyzed.The following research results have been obtained.The MS signal induced by dam fillinghas low energy and amplitude,short duration,and high frequency.The fracture of the bedrock was mainly shear failure.MS monitoring can predict deformation during blasting excavation and capture the large settlement that may occur during dam fillingin advance.Research findingshave demonstrated the significantapplication value of MS monitoring technology in predicting the risk of dam settlement and provide a reference for similar projects.展开更多
With the continuous development of the offshore wind industry,the design concept of composite foundation has been given attention in the past decade.This paper presents an accurate method for investigating the horizon...With the continuous development of the offshore wind industry,the design concept of composite foundation has been given attention in the past decade.This paper presents an accurate method for investigating the horizontal vibration of monopile-friction wheel composite foundations in layered saturated soil.Firstly,the three-dimensional continuum mechanics theory with the range of linear elasticity is introduced to calculate the frictional resistance distributed on the upper soil surface.Then,the resistances of multilayered soils and inviscid seawater to the pile shaft under horizontal harmonic excitation are obtained using Novak's plane strain model,Biot's porous media theory and radiationwave theory.Thirdly,the expressions for the deformation,bending moment and internal force of the Euler-Bernoulli pile are derived using the boundary conditions with definitephysical meaning and transfer matrix method.By comparing with the results of 1g laboratory test and the idealized formula reported by the literature,the rationality and accuracy of the developed dynamical model can be verified.Finally,this paper conducts a series of worked examples to investigate the influencesof the elastic modulus and thickness of three-layer saturated soil and the location of interlayer soil on the horizontal dynamic vibration of composite foundation.The results show that an increase in elastic modulus of the surface soil is an effective way to improve the dynamic stability of the composite foundation in service conditions.The conclusions drawn from the numerical examples can develop some guidelines for the current foundation design of offshore wind turbines.展开更多
基金supported by the Specialized Research Fund for State Key Laboratories,Chinese Meridian Project,the Specialized Research Fund for the State Key Laboratory of Solar Activity and Space Weather,postgraduate Education Reform and Quality Improvement Project of Henan Province(Grant No.YJS2024JD32)Natural Science Foundation Project of Henan Province(Grant No.242300420253)National Natural Science Foundation of China for Young Scientists(Grant No.42504156)funding.
文摘Here we report on simultaneous lidar observations of sporadic Ni(Nis)layers and sporadic Na(Nas)layers in the atmosphere over Yanqing,Beijing(40.42°N,116.02°E)from April 2019 to October 2022.During 343 nights of observation,68 Nis and 56 Nas were observed.The seasonal variation of Nis and Nas was also obtained,with the highest occurrence of Nis being in July(43%)and that of Nas being in June(61%).We found that the seasonal variation of Nis is similar to that of Nas and that both occur more frequently in summer than in winter.In addition,we found 23 events in which Nis and Nas occur simultaneously.The average peak altitude of Nas is approximately 1 km higher than that of Nis,and the peak density ratio of Nas to Nis is approximately 5,which is half the density ratio of the two main layers.Additionally,the strength factor for Nas is smaller than that for Nis.Through data analysis of sporadic E layers(Es),we found that Nis and Nas has a significant correlation with Es.The neutralization rates of Ni^(+)/Na^(+)were calculated according to the dissociative recombination reaction of Ni^(+)/Na^(+)and the WACCM-Ni(Whole Atmosphere Community Climate Model of Ni).The production rates of Ni and Na were estimated to be approximately 1:4.4,which is consistent with the density ratio of Nis to Nas.The results showed that the neutralization reaction of Ni+,Na+,and electrons in Es is the main reason for the formation of the Nis layer and the Nas layer.
基金supported by the National Natural Science Foundation of China(Nos.U2341209 and 52130407).
文摘A novel trace nickel(Ni)doped tungsten(W)matrix with coated Ni on W grains was prepared by powder metallurgy method.The introduction of Ni can inhibit the reaction between W and barium-calcium aluminates(Ba-Ca aluminates)during the impregnation process of the matrix.After cathode activation,the surface Ba:O molar ratio is 0.88:1.00,much higher than the Ba dispenser cathode without Ni doping.The XPS results of the cathode surface showed that the metallic Ba appeared on the activated cathode surface,forming dipoles with oxygen,and effectively reducing the cathode surface work function.The pulse electron emission current density at 1100℃_(b)(brightness temperature)was 18.26 A/cm^(2),and the calculated work function was 1.97 eV.It has a low evaporation rate and the accelerated lifetime test predict a lifetime of over 160000 h.First-principles calculations showed that the charge transfer and dipole moment in the NiW-BaO system were both increased compared to the Ba dispenser cathode,thus improving the emission performance of the Ni-W mixed matrix cathode.
基金supported by the National Natural Science Foundation of China(Grant Nos.12125204,12388101,12502257,12472227)the Project 111 of China(Grant No.B17037)。
文摘The effect of local polymer injection on a flat-plate turbulent boundary layer was investigated experimentally,with a particular focus on the distinct mechanisms of drag reduction in the low-drag reduction(LDR)and high-drag reduction(HDR)states.High-resolution measurements of the near-wall flow field were achieved using particle tracking velocimetry(PTV),while large-field measurements covering the entire boundary layer were obtained through particle image velocimetry(PIV).It is found that in the LDR state,the mean shear and turbulence intensity in the near-wall region are mildly suppressed.The influence of polymer solution is limited to the near-wall region and does not affect the self-sustaining cycle of wall-bounded turbulence.Conversely,in the HDR state,the polymer solution effectively disrupts the self-sustaining process of wall-bounded turbulence by suppressing the lifting of the low-speed streaks.Consequently,the turbulence production is attenuated.The buffer layer is extended,and the slope of the log-law region also becomes larger when polymer concentration or the Weissenberg number increases.
基金supported by the Ministry of Science and Technology of China(2025YFE0100200)the Natural Science Foundation of Tianjin(24JCJQJC00220 and 24ZXZSSS00310)+3 种基金the National Natural Science Foundation of China(22479080,92372203,and 92372001)the Open Foundation of Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Molecular Engineering(JDSX2023003)the Fundamental Research Funds for the Central Universities of Nankai University(020-63253167)the"111 Center"(B25010)。
文摘Layered transition metal oxide cathode materials have garnered increasing attention for sodium-ion batteries(SIBs).However,they are plagued by the Jahn-Teller distortion of MnO6,Na^(+)/vacancy ordering,and irreversible lattice oxygen loss,which collectively lead to capacity fading and voltage decay.Herein,we report a P2-type material,Na_(0.67)Ni_(0.3)Mn_(0.6)Li_(0.09)Sn_(0.01)O_(2)(NNMO-Li0.09Sn0.01),modified with two closed-shell dopants(i.e.,Li^(+)and Sn^(4+)).Benefiting from the unique electronic configurations of closed-shell ions,NNMO-Li0.09Sn0.01 exhibits enhanced structural and electrochemical stability.Specifically,the incorporation of Li^(+)increases the Mn^(4+)/Mn3+ratio,thereby mitigating Jahn-Teller distortion during(de)sodiation process.In addition,Li^(+)disrupts the Ni/Mn ordering in the transition metal layer,suppressing Na^(+)/vacancy ordering.Meanwhile,the introduction of Sn^(4+)forms stronger Sn-O bonds(548 kJ mol-1),thereby enhancing the bonding strength between neighboring transition metal ions and surrounding oxygen atoms,effectively reducing oxygen loss during cycling.NNMO-Li0.09Sn0.01 exhibits significantly improved cycling stability,delivering a specific capacity of 90.3 mAh g^(-1)with 62.9%capacity retention after 50 cycles at 0.1 C(1 C=200 mA g^(-1)),along with 90.3%voltage retention.This substitution strategy based on closed-shell ions offers a viable approach for enhancing the structural stability of wide-voltage layered oxide cathodes.
基金supported by the National Natural Science Foundation of China(NSFC)(22302151,52502312)Natural Science Foundation of Hubei Province(2024AFB755,2024AFB267)+1 种基金Key Project of Hubei Provincial Department of Education Scientific Research Plan(F2023007)Wuhan Institute of Technology Graduate Education Innovation Fund(CX2024285)。
文摘Layered double hydroxides(LDHs)are promising electrocatalysts for the oxygen evolution reaction(OER),yet their practical application remains limited by poor electrical conductivity and sluggish reaction kinetics.In this work,we synthesize three high-entropy LDHs(HELDHs)featuring a hierarchical architecture of microspheres assembled from ultrathin nanosheets,via a simple hydrothermal method using a combination of low-cost,catalytically active transition metals(Fe,Co,Ni,Mn,Zn,Cu,and Cr).Among them,the FeCoNiMnZn HELDH exhibits outstanding OER performance,requiring an overpotential of only 306 mV to reach a current density of 100 mA cm^(-2).Notably,during 200 h of continuous operation,the device exhibits a stable and,in some cases,increasing current output.This exceptional activity is attributed to the formation of abundant cation vacancies,induced by Zn leaching,which enhance the intrinsic catalytic properties by optimizing the adsorption energies of key OER intermediates.Density functional theory calculations further validate that these vacancies modulate the electronic structure and lower reaction barriers,underscoring the effectiveness of cation-vacancy engineering in high-entropy systems for efficient and durable water oxidation catalysis.The optimized catalyst was further evaluated as the air cathode in a zinc-air battery,demonstrating practical electrochemical performance.
基金the financial support from Research Institute for Smart Energy at the Hong Kong Polytechnic University(Grant No.CDB2)the support of the Hong Kong PhD Fellowship Scheme(Grant No.PF21-65328)。
文摘Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage,but their commercialization is hindered by zinc anode challenges,notably parasitic reactions and dendrite growth.Herein,we present a biodegradable biomass-derived protective layer,primarily composed of curcumin,as a zincophilic interface for AZMBs.The curcumin-based layer,fabricated via a homogeneous solution process,exhibits strong adhesion,uniform coverage,and robust mechanical integrity.Rich polar functional groups in curcumin facilitate homogeneous Zn~(2+)flux and suppress side reactions.The curcumin-based layer shows a favorable affinity for zinc trifluoromethanesulfonate(Zn(OTf)_(2))electrolyte,which is the representative of organic zinc salts,enabling optimal thickness for both protection and ion transport.The protected Zn anodes demonstrate an extended lifespan of 2500 h in symmetrical cells and a high Coulombic efficiency of 99.15%.Furthermore,Zn(OTf)_(2)-based system typically exhibits poor stability at high current densities.Fortunately,the lifespan of symmetrical cells was extended by 40-fold at the high current density.When paired with an Na V_(3)O_(8)·1.5H_(2)O(NVO)cathode,the system achieves 86.5%capacity retention after 3000 cycles at a large specific current density of 10 A g^(-1).These results underscore the efficacy of the curcumin-based protective layer in enhancing the reversibility and stability of metal electrodes,specifically relieving the instability of Zn(OTf)_(2)-based systems at high current densities,advancing its commercial viability.
基金supported by the financial support from the Guangdong Basic and Applied Basic Research Foundation(No.2023B1515120095)the National Natural Science Foundation of China(Nos.52471229 and 52171210)the Jilin Province Science and Technology Department Program(No.20240101004JJ).
文摘The formation of Zn dendrites and the occurrence of the hydrogen evolution reaction(HER)at Zn anodes represent two major obstacles that significantly impede the widespread commercialization of aqueous Zn-ion batteries.In this work,we propose sorbitan oleate(Span 80)as a novel amphiphilic electrolyte additive for 2 mol/L ZnSO_(4),demonstrating multifunctional performance.The unique ultra-long hydrophobic carbon chains of Span 80 effectively reduce free water molecules at the Zn anode-electrolyte interface,forming a robust hydrophobic interfacial layer that significantly suppresses HER and corrosion reactions.Simultaneously,carbon chains can enhance the desolvation effect of[Zn(H_(2)O)_(6)]^(2+),leading to improve rate performance.Additionally,the hydrophilic sorbitan groups in Span 80 selectively adsorb onto active sites of the Zn anode,promoting uniform Zn^(2+)deposition and suppressing dendrite growth.The optimized Zn||Zn symmetric cell exhibits outstanding cycling stability,sustaining reversible plating/stripping for 570 h at 50 mA/cm^(2) and the Zn||V_(2)O_(5) full cell retains exceptional stability over 2000 cycles at 1 A/g.Our work presents a promising strategy for suppressing interfacial side reactions by constructing a hydrophobic protective layer through the use of ultra-long carbon chain surfactants.This approach offers new insights into enhancing the performance of aqueous Zn-ion batteries.
文摘AIM:To investigate the changes of retinal vascular parameters and retinal layer thickness in patients with multiple sclerosis(MS).METHODS:This single-centered case-control study was performed on a MS group of 42 patients diagnosed with MS and a control group of 43 healthy hospital staff matched in terms of age and sex at Iran University,department of neurology and ophthalmology from March 2020 to March 2021.The ophthalmic parameters of each patient were recorded,and optical coherence tomography was used to evaluate the retinal thickness in the layers.RESULTS:This study enrolled a total of 85 participants,with a mean age of 40.44±11.52 years,including 61 females(72%).The control group consisted of 43 individuals with a mean age of 39.49±11.07 years,while the MS group comprised 42 participants with a mean age of 41.40±12.01 years.The mean disease duration in the MS group was 8.45±6.04 a.The thickness of the ganglion cell layer in the right eye was significantly lower in the MS group compared to the control group(P=0.034).In addition,except for the left nasal sector(P=0.106),the mean peripapillary neurofibrillation in all examined sectors were significantly lower in the MS group than in the control group(P<0.05).The average vessel density in both the deep and superficial capillary plexuses across all regions of both eyes was lower in the MS group than in the control group,with all comparisons for the superficial capillary plexus showing statistical significance(P<0.05 for all except the left nasal sector).CONCLUSION:The thickness of the retina of patients with MS is significantly reduced.Therefore,optical coherence tomography results can be used as a reliable tool to evaluate disease progression and prognosis in MS patients.
基金supported by the National Key R&D Program of China[grant number 2023YFC3008004]。
文摘This study introduces a new ocean surface friction velocity scheme and a modified Thompson cloud microphysics parameterization scheme into the CMA-TYM model.The impact of these two parameterization schemes on the prediction of the movement track and intensity of Typhoon Kompasu in 2021 is examined.Additionally,the possible reasons for their effects on tropical cyclone(TC)intensity prediction are analyzed.Statistical results show that both parameterization schemes improve the predictions of Typhoon Kompasu’s track and intensity.The influence on track prediction becomes evident after 60 h of model integration,while the significant positive impact on intensity prediction is observed after 66 h.Further analysis reveals that these two schemes affect the timing and magnitude of extreme TC intensity values by influencing the evolution of the TC’s warm-core structure.
基金supported by a PETRONAS-Academia Collabora-tion Dialogue 2022 Grant[Grant number PACD 2022]from PETRONAS Research Sdn.Bhd。
文摘The atmospheric surface layer of the tropical coastal ocean is commonly very unstable and experiences weakwind conditions.How the latent(LE)and sensible(H)heat fluxes behave under such conditions are unclear because of the lack of observation stations in the tropics.Thus,this study aims to analyze LE and H and the microclimate parameters influencing them.The authors deployed an eddy covariance system in a tropical coastal region for seven months.The microclimate parameters investigated were wind speed(U),vapor pressure deficit(Δe),temperature difference(ΔT),wind-vapor pressure deficit(UΔe),wind-temperature difference(UΔT),and atmospheric stability(z/L),where z is height and L is the Monin–Obukhov length.On the daily time scale,the results show that LE was more associated with U thanΔe,while H was more related toΔT than U.Cross-wavelet analysis revealed the strong coherence in the LE-U relationship for periods between one and two days,and for H–ΔT,0.5 to 1 day.Correlation and regression analyses confirmed the time series analyses results,where strong positive correlation coefficients(r)were obtained between LE and U(r=0.494)and H andΔT(r=0.365).Compared to other water bodies,the transfer coefficient of moisture(CE N)was found to be small(=0.40×10^(-3))and independent of stability;conversely,the transfer coefficient of heat(CH N)was closer to literature values(=1.00×10^(-3))and a function of stability.
基金supported by the National Natural Science Foundation of China(No.12372233)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University,China(No.25GH01020005)the“111 Project”of China(No.B17037)。
文摘As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises structural concerns,and the latter is of aerodynamic interest.Thus,panel aeroelasticity in shock-dominated flow represents a vital topic for the development and optimization of supersonic vehicles and propulsion systems.This review systematically summarizes recent advances in the methodologies applied to capture structural and fluid dynamics,including theoretical models,numerical simulations,and wind tunnel experiments.The application of data-driven modal decomposition,an advanced technique to extract physically crucial features,on the topic is introduced.From the perspective of FSIs,the distinctive aeroelastic behaviors in shock-dominated flow,including hysteresis phenomena and nonlinear responses,are highlighted.From the perspective of SBLIs,the modifications in their spatial and temporal characteristics imposed by the aeroelastic responses are emphasized.Motivated by the interaction between the shock waves and structural response,different strategies have been proposed to implement aeroelastic suppression and shock control,which have the potential to enhance structural safety and aerodynamic performance in the next generation of high-speed flight vehicles.
基金supported by National Key Laboratory of Petroleum Resources and Engineering,China University of Petroleum,Beijing(No.PRE/open-2307).
文摘The deep coal reservoir in Linxing-Shenfu block of Ordos Basin is an important part of China’s coalbed methane resources.In the process of reservoir reconstruction,the artificial fracture morphology of coal seam with gangue interaction is significantly different,which affects the efficient development of coalbed methane resources in this area.In this paper,the surface outcrop of Linxing-Shenfu block is selected,and three kinds of interaction modes between gangue and coal seam are set up,including single-component coal rock sample,coal rock sample with different thicknesses of gangue layer and coal rock sample with different numbers of gangue.Through true triaxial physical simulation and three-dimensional discrete element numerical simulation,the lawof artificial fracture initiation and propagation in multi-gangue interaction coal seam is analyzed in depth,and the hydraulic fracture initiation and propagation mode under different interaction modes of gangue layer in Linxing-Shenfu deep coal reservoir was clarified.The research shows that the initiation of artificial fractures in a single coal seam is affected by geologicalengineering factors.The maximum principal stress dominates the direction of fracture propagation,and the stress difference controls the fracture morphology.When the stress difference is 2 MPa,the fracture morphology is complex,which is easy to connect to the weak surface of coal and rock cleat,and the fracturemorphology of the stress difference is mainly a single main fracture.After the thickness of the gangue layer is increased from 2 to 5 cm,it is difficult for the artificial fracture to penetrate the layer vertically after the fracture initiation,and the effective transformation area of the reservoir is limited.The more the number of gangue layers,the greater the hydraulic energy consumption in the process of fracture propagation,and the more difficult the fracture propagation.
基金supported by the “Pioneer” and “Leading Goose” R&D Program of Zhejiang Province of China (No. 2024C01056)the support from London South Bank University
文摘Layered oxides have attracted significant attention as cathodes for sodium-ion batteries(SIBs)due to their compositional versatility and tuneable electrochemical performance.However,these materials still face challenges such as structural phase transitions,Na^(+)/vacancy ordering,and Jahn–Teller distortion effect,resulting in severe capacity decay and sluggish ion kinetics.We develop a novel Cu/Y dual-doping strategy that leads to the formation of"Na–Y"interlayer aggregates,which act as structural pillars within alkali metal layers,enhancing structural stability and disrupting the ordered arrangement of Na^(+)/vacancies.This disruption leads to a unique coexistence of ordered and disordered Na^(+)/vacancy states with near-zero strain,which significantly improves Na^(+)diffusion kinetics.This structural innovation not only mitigates the unfavorable P2–O2 phase transition but also facilitates rapid ion transport.As a result,the doped material demonstrates exceptional electrochemical performance,including an ultra-long cycle life of 3000 cycles at 10 C and an outstanding high-rate capability of~70 mAh g^(−1)at 50 C.The discovery of this novel interlayer pillar,along with its role in modulating Na^(+)/vacancy arrangements,provides a fresh perspective on engineering layered oxides.It opens up promising new pathways for the structural design of advanced cathode materials toward efficient,stable,and high-rate SIBs.
基金supported by the National Natural Science Foundation of China(52471240)the Natural Science Foundation of Zhejiang Province(LZ23B030003)+2 种基金the Fundamental Research Funds for the Central Universities(226-2024-00075)support from the Engineering and Physical Sciences Research Council(EPSRC,UK)RiR grant-RIR18221018-1EU COST CA23155。
文摘The electric double layer(EDL)at the electrochemical interface is crucial for ion transport,charge transfer,and surface reactions in aqueous rechargeable zinc batteries(ARZBs).However,Zn anodes routinely encounter persistent dendrite growth and parasitic reactions,driven by the inhomogeneous charge distribution and water-dominated environment within the EDL.Compounding this,classical EDL theory,rooted in meanfield approximations,further fails to resolve molecular-scale interfacial dynamics under battery-operating conditions,limiting mechanistic insights.Herein,we established a multiscale theoretical calculation framework from single molecular characteristics to interfacial ion distribution,revealing the EDL’s structure and interactions between different ions and molecules,which helps us understand the parasitic processes in depth.Simulations demonstrate that water dipole and sulfate ion adsorption at the inner Helmholtz plane drives severe hydrogen evolution and by-product formation.Guided by these insights,we engineered a“water-poor and anion-expelled”EDL using 4,1’,6’-trichlorogalactosucrose(TGS)as an electrolyte additive.As a result,Zn||Zn symmetric cells with TGS exhibited stable cycling for over 4700 h under a current density of 1 mA cm^(−2),while NaV_(3)O_(8)·1.5H_(2)O-based full cells kept 90.4%of the initial specific capacity after 800 cycles at 5 A g^(−1).This work highlights the power of multiscale theoretical frameworks to unravel EDL complexities and guide high-performance ARZB design through integrated theory-experiment approaches.
基金support from the Australian Research Council Discovery Program(DP220103416,DP240102177)Australian Research Council Future Fellowships(FT200100730,FT210100804).
文摘Aqueous zinc(Zn)-ion batteries hold great promise as renewable energy storage system for carbon-neutral energy transition.However,Zn anodes suffer from poor Zn plating/stripping reversibility due to Zn dendrite growth and side reactions.Existing Zn interfacial modification strategies based on single-component or homogeneous structure are insufficient to address these issues comprehensively.Herein,we rationally designed an organic-inorganic hybrid interfacial layer with rigid-to-soft graded structure for dendrite-free and stable Zn anodes.A liquid plasma-assisted oxidation technology is developed to rapidly construct a porous ZnO inner framework in situ.This ZnO layer offers high interfacial energy,mechanical robustness,and an open structure that facilitates ion transport while firmly anchoring a subsequently coated soft polymer layer.The resulting architecture presents a structurally graded and functionally complementary interface,enabling effective dendrite suppression,continuous Zn ion transport,and enhanced corrosion resistance.As a result,a long cycling stability of more than 6000 h can be achieved at 1 mA cm^(-2)for 1 mAh cm^(-2)in symmetric cells.When used as anodes for zinc-iodine full battery,the hybrid interlayer can effectively prevent the Zn anodes from the corrosion by polyiodine,enabling stable cycling and negligible capacity decay(~0.02‰per cycle)for over 10,000 cycles at 2.0 A g^(-1).This work demonstrates a promising interfacial design strategy and introduces a novel liquid plasma-assisted oxidation route for fabricating high-performance Zn anodes towards next-generation aqueous batteries.
基金supported by the National Natural Science Foundation of China(61904053,22279033)the National Key Research and Development Program of China(2023YFB4204502)+2 种基金the 111 Project(B16016)the Fundamental Research Funds for the Central Universities(2025MS043)the Special Foundation for Carbon Peak Carbon Neutralization Technology Innovation Program of Jiangsu Province(BE2022026).
文摘Molecular tailoring of self-assembled hole-transporting monolayers(SAMs)has been proven as an efficient approach for improving the device performance of inverted perovskite solar cells.Herein,a novel SAM with extended conjugation is designed and synthesized,named NaPh-4PACz.Compared to Ph-4PACz,NaPh-4PACz exhibits a larger adsorption energy with the ITO substrate,enabling the formation of a more uniform and dense film,thereby preventing direct contact between the perovskite and ITO.Additionally,NaPh-4PACz also has a stronger interaction with the perovskite,which can reduce buried interface defects and suppress non-radiative recombination.Consequently,NaPh-4PACz-based devices achieved a power conversion efficiency of 25.48%due to their interfacial“adhesive”ability.Importantly,the stability of the NaPh-4PACz-based devices was significantly improved.
基金supported by the National Natural Science Foundation of China (52402298, 52172224, 52202228, 22479112)the Science and Technology Correspondent Project of Tianjin(24YDTPJC00240)+3 种基金Science Research Project of Hebei Education Department (BJK2022011)Central Funds Guiding the Local Science and Technology Development of Hebei Province (236Z4404G)the Beijing Tianjin Hebei Basic Research Cooperation Special Project(E2024202273)Tianjin Sci.&Tech. Program (22YFYSHZ00220)
文摘O3-types layered cathode materials in sodium-ion batteries(SIBs)suffer from the obvious lattice distortion induced by the complex phase transitions during Na^(+)intercalation/deintercalation process,leading to severe structural collapse and performance degradation.Herein,a series of high valence tantalum(Ta^(5+))doped Na(Ni_(0.4)Fe_(0.2)Mn_(0.4))_(1−x)Ta_(x)O_(2)(x=0/0.0025/0.005/0.01)secondary spherical particles are firstly developed,where Ta^(5+)doping enables the refined primary grain with a tightly stacked rod-like morphology.Comprehensive structural analysis via Neutron powder diffraction(NPD)and Synchrotron radiation X-ray diffraction(SXRD)reveals an expanded NaO_(2)slab and a reduction in Na site vacancy.The potential charge compensation mechanism is further illustrated by X-ray absorption spectroscopy(XAS)and X-ray photoelectron spectroscopy(XPS),unveiling a partial reduction from Ni^(3+)to Ni^(2+)with Ta^(5+)doping.In situ X-ray diffraction(in situ XRD)suggests that the decorated sample undergoes a volume change as low as 0.8%,in contrast with the pristine one(1.5%).Thus,the optimized sample with x=0.005 retains an enhanced capacity retention up to 70.4%at 1 C after 300 cycles in half-cell and delivers a high energy density of 251 Wh kg^(-1)(0.1 C)and with a good capacity retention of 81.0%at 1 C after 200 cycles in full-cell.Our findings provide new insights into the mechanism of high valence Ta^(5+)doping in stabilizing layered oxides cathode materials for SIBs.
基金supported by the Natural Science Research Project of Anhui Province Education Department for Excellent Young Scholars(Grant No.2024AH030007)the National Natural Science Foundation of China(Grant No.52202001)。
文摘Conventional Tb^(3+)-doped phosphors typically suffer from concentration quenching once the doping level exceeds a critical threshold.Consequently,the development of Tb^(3+)phosphors with intrinsic resistance to concentration quenching has become a key research focus.In this work,we successfully synthesized KBi(MoO_(4))_(2):x Tb^(3+)(x=0-100 at%)(denoted as KBM:x Tb^(3+))phosphors via a high-temperature solid-state reaction.Remarkably,no concentration quenching was observed across the entire doping range.This anti-quenching behavior originates from the large Tb^(3+)-Tb^(3+)interionic distance(>5Å)inherent to the quasi-layered crystal structure,which effectively suppresses multipole-interaction-mediated energy migration.At full Tb^(3+)substitution(x=100 at%),the material undergoes a structural phase transition from the monoclinic KBM phase to the triclinicα-KTb(MoO_(4))_(2)(α-KTM)phase.Theα-KTM phosphor exhibits excellent thermal stability(activation energy=0.6129 eV)and a single-exponential decay profile,whereas KBM:x Tb^(3+)(x<100%)display double-exponential decay behaviors,attributed to dual energy transfer pathways.These findings provide new insights into the luminescence mechanisms of high-concentration rare-earth-doped systems and offer guidance for designing nextgeneration anti-quenching phosphors.
基金support from the Joint Funds of the National Natural Science Foundation of China(Grant No.42177143)the National Natural Science Foundation of China(Grant No.U23A2060).
文摘Many hydropower projects have been constructed in Southwest China with the strategic goal of achieving carbon neutrality.Most of these hydropower projects utilize concrete face rockfilldams(CFRDs)built on a deep overburden layer.The deep overburden layer causes uneven settlement between the overburden layer and the dam,which poses a serious threat to the safety of both the construction and operation of the dam.In this study,microseismic(MS)monitoring technology was employed for the firsttime in the fieldof dam fillingengineering,allowing for the real-time monitoring of microfracture in the bedrock during dam construction.The time-frequency analysis method was used to summarize the MS waveform characteristics induced by dam filling.The fracture mechanism of bedrock was revealed,and the relationships among slope deformation,dam settlement,and MS activity were analyzed.The following research results have been obtained.The MS signal induced by dam fillinghas low energy and amplitude,short duration,and high frequency.The fracture of the bedrock was mainly shear failure.MS monitoring can predict deformation during blasting excavation and capture the large settlement that may occur during dam fillingin advance.Research findingshave demonstrated the significantapplication value of MS monitoring technology in predicting the risk of dam settlement and provide a reference for similar projects.
基金supported by the National Natural Science Foundation of China(Grant No.52178329),the China Scholarship Council(Grant No.202306130155)the Postgraduate Scientific Research Innovation Project of Hunan Province,China(Grant No.CX20230442).
文摘With the continuous development of the offshore wind industry,the design concept of composite foundation has been given attention in the past decade.This paper presents an accurate method for investigating the horizontal vibration of monopile-friction wheel composite foundations in layered saturated soil.Firstly,the three-dimensional continuum mechanics theory with the range of linear elasticity is introduced to calculate the frictional resistance distributed on the upper soil surface.Then,the resistances of multilayered soils and inviscid seawater to the pile shaft under horizontal harmonic excitation are obtained using Novak's plane strain model,Biot's porous media theory and radiationwave theory.Thirdly,the expressions for the deformation,bending moment and internal force of the Euler-Bernoulli pile are derived using the boundary conditions with definitephysical meaning and transfer matrix method.By comparing with the results of 1g laboratory test and the idealized formula reported by the literature,the rationality and accuracy of the developed dynamical model can be verified.Finally,this paper conducts a series of worked examples to investigate the influencesof the elastic modulus and thickness of three-layer saturated soil and the location of interlayer soil on the horizontal dynamic vibration of composite foundation.The results show that an increase in elastic modulus of the surface soil is an effective way to improve the dynamic stability of the composite foundation in service conditions.The conclusions drawn from the numerical examples can develop some guidelines for the current foundation design of offshore wind turbines.
