The effect of hydrogen on the dezincification layer-induced stress and the susceptibility to SCC was investigated. Experimental results showed that the dezincification layer-induced stress increased with increasing hy...The effect of hydrogen on the dezincification layer-induced stress and the susceptibility to SCC was investigated. Experimental results showed that the dezincification layer-induced stress increased with increasing hydrogen concentration, and 3x10-6 hydrogen could increase the susceptibility to SCC of brass in ammonia solution by 10%.展开更多
During stress corrosion cracking of Cu3Au alloy, there is a dealloyed layer on its surface because of preferential dissolution of Cu, and there is a linear distribution of Cu vacancy concentration in the dealloyed lay...During stress corrosion cracking of Cu3Au alloy, there is a dealloyed layer on its surface because of preferential dissolution of Cu, and there is a linear distribution of Cu vacancy concentration in the dealloyed layer. Molecular dynamics simulation has been done on the three-dimensional crystal (about 148 000 atoms) by employing the embedded-atom method (EAM) potential. Simulation shows that Cu3Au crystal in which there is a dealloyed layer on one surface and one end is fixed will be deflected after relaxing for a long time because of a tensile stress generated at or near the dealloyed layer interface. The deflection and then the tensile stress increase with increasing the depth of dealloyed layer and the vacancy concentration in the dealloyed layer.展开更多
基金This project was supported by the Special Fund for the Major State Basic Research Project(G19990650)the NSFC(No.50071010)
文摘The effect of hydrogen on the dezincification layer-induced stress and the susceptibility to SCC was investigated. Experimental results showed that the dezincification layer-induced stress increased with increasing hydrogen concentration, and 3x10-6 hydrogen could increase the susceptibility to SCC of brass in ammonia solution by 10%.
基金This work was financially supported by the NNSF(No.59872004)the Special Funds for the Major State Basic Research Projects(No
文摘During stress corrosion cracking of Cu3Au alloy, there is a dealloyed layer on its surface because of preferential dissolution of Cu, and there is a linear distribution of Cu vacancy concentration in the dealloyed layer. Molecular dynamics simulation has been done on the three-dimensional crystal (about 148 000 atoms) by employing the embedded-atom method (EAM) potential. Simulation shows that Cu3Au crystal in which there is a dealloyed layer on one surface and one end is fixed will be deflected after relaxing for a long time because of a tensile stress generated at or near the dealloyed layer interface. The deflection and then the tensile stress increase with increasing the depth of dealloyed layer and the vacancy concentration in the dealloyed layer.
