Artificial neural networks (ANN), being a sophisticated type of information processing system by imitating the neural system of human brain, can be used to investigate the effects of concentration of flux solution, te...Artificial neural networks (ANN), being a sophisticated type of information processing system by imitating the neural system of human brain, can be used to investigate the effects of concentration of flux solution, temperature of liquid aluminium, temperture of tools and pressure on thickness of the intermetallic layer at the interface between steel and aluminium under solid-liquid pressure bonding of steel and aluminium perfectly. The optimum thickness has been determined according to the value of the optimum shearing strength.展开更多
A series of calcined carbonate layered double hydroxides （CLDHs） with various metal compositions and different M^2＋/M^3＋ ratios were prepared as adsorbents for perchlorate. Adsorption isotherms fit Langmuir model ...A series of calcined carbonate layered double hydroxides （CLDHs） with various metal compositions and different M^2＋/M^3＋ ratios were prepared as adsorbents for perchlorate. Adsorption isotherms fit Langmuir model well, and the adsorption amount followed the order of MgA1-CLDHs 1〉 MgFeCLDHs 〉〉 ZnA1-CLDHs. The isotherms of MgA1-CLDHs and MgFe-CLDHs displayed a two-step shape at low and high concentration ranges and increased with an increase in the M^2＋/M^3＋ ratio from 2 to 4. The two-step isotherm was not observed for ZnA1-CLDHs, and the adsorption was minimally affected by the M^2＋/M^3＋ ratio. The LDHs, CLDHs and the reconstructed samples were characterized by X-ray diffraction, SEM, FT-IR and Raman spectra to delineate the analysis of perchlorate adsorption mechanisms. The perchlorate adsorption of MgA1-CLDHs and MgFe-CLDHs was dominated by the structural memory effect and the hydrogen bonds between the free hydroxyl groups on the reconstructed-LDHs and the oxygen atoms of the perchlorates. For ZnAI-CLDHs, the perchlorate adsorption was controlled by the structural memory effect only, as the hydroxyl groups on the hydroxide layers preferred to form strong hydrogen bonds with carbonate over perchlorate, which locked the intercalated perchlorate into a more confined nano-interlayer. Several distinct binding mechanisms of perchlorate by CLDHs with unique M^2＋ ions were proposed.展开更多
A high performance composite membrane was prepared under the inspiration of bioadhesion principles for pervaporative dehydration of ethanol.Chitosan(CS)and polyacrylonitrile(PAN)ultrafiltration membranes were used as ...A high performance composite membrane was prepared under the inspiration of bioadhesion principles for pervaporative dehydration of ethanol.Chitosan(CS)and polyacrylonitrile(PAN)ultrafiltration membranes were used as the active layer and the support layer,respectively.Guar gum(GG),a natural bioadhesive,was introduced as the intermediate bonding layer to improve the separation performance and stability of the fabricated CS/GG/PAN composite membranes.The contact angle of the GG layer was just between those of the CS layer and the PAN layer,minimizing the difference of hydrophilicity between the active layer and the support layer.The peeling strength of the composite membrane was significantly enhanced after the introduction of the GG layer.The effects of preparation conditions and operation conditions including GG concentration,operating temperature and ethanol concentration in feed on the pervaporation performance were investigated.The as-fabricated CS/GG/PAN composite membrane showed the optimum performance with a permeation flux of up to804 g·m-2·h-1and a separation factor higher than 1900.Besides,the composite membranes exhibited a desirable long-term operational stability.展开更多
A new method was used to evaluate the fatigue properties of the bonding layer used in the bridge deck pavement. The shear fatigue test of three bonding layers was conducted on a dynamic shear rheometer（DSR）. The fat...A new method was used to evaluate the fatigue properties of the bonding layer used in the bridge deck pavement. The shear fatigue test of three bonding layers was conducted on a dynamic shear rheometer（DSR）. The fatigue formulas were gained for these layers. The experimental results indicate that, at the same torque level or at the same frequency, neoprene latex asphalt bonding layer exhibits excellent fatigue performance when compared to other two bonding layers.展开更多
The bonding layers in dissimilar alloy explosive bonding joints,γ/α stainless steels, copper/carbon steel and brass/γ-stainless steel have been studied by means of TEM tech- nique.The results show that the bonding ...The bonding layers in dissimilar alloy explosive bonding joints,γ/α stainless steels, copper/carbon steel and brass/γ-stainless steel have been studied by means of TEM tech- nique.The results show that the bonding is obtained by diffusion and local melting at the con- tact surface.The structure of bonding layer not only responds to the compositions of the bond- ing alloys,but also the difference between their thermal conductivities,melting points and recrystallization temperatures,Because of the small molten region and fast cooling rate,the structure of molten region could be amorphous or microcrystals,and both stable and metastable phases exsist.展开更多
Thin-walled structures are sensitive to vibrate under even very small disturbances. In order to design a suitable controller for vibration suppression of thin-walled smart structures, an electro-mechanically coupled f...Thin-walled structures are sensitive to vibrate under even very small disturbances. In order to design a suitable controller for vibration suppression of thin-walled smart structures, an electro-mechanically coupled finite element（FE） model of smart structures is developed based on first-order shear deformation（FOSD） hypothesis. Considering the vibrations generated by various disturbances, which include free and forced vibrations, a PID control is implemented to damp both the free and forced vibrations. Additionally, an LQR optimal control is applied for comparison.The implemented control strategies are validated by a piezoelectric layered smart plate under various excitations.展开更多
In this work, with the analysis on MO and electronic structure for a series of heteronuclear cluster with cubane type (Mo4S1 )xMn1(x=1.2. M = Cu, W, Ni, Sb, Mo, Sn, Cu2) we found that it is with the multiple center d-...In this work, with the analysis on MO and electronic structure for a series of heteronuclear cluster with cubane type (Mo4S1 )xMn1(x=1.2. M = Cu, W, Ni, Sb, Mo, Sn, Cu2) we found that it is with the multiple center d-pir orbitals that the ligand Mo3S44+ bonds to the M atom to form these class clusters. It is revealed that the charges transfer from the M atom to Mo atom of the ligand Mo3S44+ and its relationship with the MC (multiple center) d-pπ orbitals. Based on the charge transfer the electronic spectrum and the magnetic property of some cubane clusters have been discussed.展开更多
文摘Artificial neural networks (ANN), being a sophisticated type of information processing system by imitating the neural system of human brain, can be used to investigate the effects of concentration of flux solution, temperature of liquid aluminium, temperture of tools and pressure on thickness of the intermetallic layer at the interface between steel and aluminium under solid-liquid pressure bonding of steel and aluminium perfectly. The optimum thickness has been determined according to the value of the optimum shearing strength.
基金supported by the National Natural Science Foundation of China(No.41071210)the Zhejiang Provincial Natural Science Foundation of China(No.R5100105)the Doctoral Fund of Ministry of Education China(No.J20130039)
文摘A series of calcined carbonate layered double hydroxides （CLDHs） with various metal compositions and different M^2＋/M^3＋ ratios were prepared as adsorbents for perchlorate. Adsorption isotherms fit Langmuir model well, and the adsorption amount followed the order of MgA1-CLDHs 1〉 MgFeCLDHs 〉〉 ZnA1-CLDHs. The isotherms of MgA1-CLDHs and MgFe-CLDHs displayed a two-step shape at low and high concentration ranges and increased with an increase in the M^2＋/M^3＋ ratio from 2 to 4. The two-step isotherm was not observed for ZnA1-CLDHs, and the adsorption was minimally affected by the M^2＋/M^3＋ ratio. The LDHs, CLDHs and the reconstructed samples were characterized by X-ray diffraction, SEM, FT-IR and Raman spectra to delineate the analysis of perchlorate adsorption mechanisms. The perchlorate adsorption of MgA1-CLDHs and MgFe-CLDHs was dominated by the structural memory effect and the hydrogen bonds between the free hydroxyl groups on the reconstructed-LDHs and the oxygen atoms of the perchlorates. For ZnAI-CLDHs, the perchlorate adsorption was controlled by the structural memory effect only, as the hydroxyl groups on the hydroxide layers preferred to form strong hydrogen bonds with carbonate over perchlorate, which locked the intercalated perchlorate into a more confined nano-interlayer. Several distinct binding mechanisms of perchlorate by CLDHs with unique M^2＋ ions were proposed.
基金Supported by the New Century Excellent Talents in University(NCET-10-0623)the National Natural Science Foundation for Distinguished Young Scholars(21125627)+1 种基金the National Basic Research Program of China(2009CB623404)State Key Laboratory for Modification of Chemical Fibers and Polymer Materials(Dong Hua University)
文摘A high performance composite membrane was prepared under the inspiration of bioadhesion principles for pervaporative dehydration of ethanol.Chitosan(CS)and polyacrylonitrile(PAN)ultrafiltration membranes were used as the active layer and the support layer,respectively.Guar gum(GG),a natural bioadhesive,was introduced as the intermediate bonding layer to improve the separation performance and stability of the fabricated CS/GG/PAN composite membranes.The contact angle of the GG layer was just between those of the CS layer and the PAN layer,minimizing the difference of hydrophilicity between the active layer and the support layer.The peeling strength of the composite membrane was significantly enhanced after the introduction of the GG layer.The effects of preparation conditions and operation conditions including GG concentration,operating temperature and ethanol concentration in feed on the pervaporation performance were investigated.The as-fabricated CS/GG/PAN composite membrane showed the optimum performance with a permeation flux of up to804 g·m-2·h-1and a separation factor higher than 1900.Besides,the composite membranes exhibited a desirable long-term operational stability.
基金Funded by the National Natural Science Foundation of China (No. 50878171)
文摘A new method was used to evaluate the fatigue properties of the bonding layer used in the bridge deck pavement. The shear fatigue test of three bonding layers was conducted on a dynamic shear rheometer（DSR）. The fatigue formulas were gained for these layers. The experimental results indicate that, at the same torque level or at the same frequency, neoprene latex asphalt bonding layer exhibits excellent fatigue performance when compared to other two bonding layers.
文摘The bonding layers in dissimilar alloy explosive bonding joints,γ/α stainless steels, copper/carbon steel and brass/γ-stainless steel have been studied by means of TEM tech- nique.The results show that the bonding is obtained by diffusion and local melting at the con- tact surface.The structure of bonding layer not only responds to the compositions of the bond- ing alloys,but also the difference between their thermal conductivities,melting points and recrystallization temperatures,Because of the small molten region and fast cooling rate,the structure of molten region could be amorphous or microcrystals,and both stable and metastable phases exsist.
基金supported by the National Natural Science Foundation of China(No.51275413)financial support from the China Scholarship Council of China for the first author(No.2010629003)
文摘Thin-walled structures are sensitive to vibrate under even very small disturbances. In order to design a suitable controller for vibration suppression of thin-walled smart structures, an electro-mechanically coupled finite element（FE） model of smart structures is developed based on first-order shear deformation（FOSD） hypothesis. Considering the vibrations generated by various disturbances, which include free and forced vibrations, a PID control is implemented to damp both the free and forced vibrations. Additionally, an LQR optimal control is applied for comparison.The implemented control strategies are validated by a piezoelectric layered smart plate under various excitations.
文摘In this work, with the analysis on MO and electronic structure for a series of heteronuclear cluster with cubane type (Mo4S1 )xMn1(x=1.2. M = Cu, W, Ni, Sb, Mo, Sn, Cu2) we found that it is with the multiple center d-pir orbitals that the ligand Mo3S44+ bonds to the M atom to form these class clusters. It is revealed that the charges transfer from the M atom to Mo atom of the ligand Mo3S44+ and its relationship with the MC (multiple center) d-pπ orbitals. Based on the charge transfer the electronic spectrum and the magnetic property of some cubane clusters have been discussed.
