Laser multi\|layer cladding experiments were performed on the substrate of DD3 single crystal with FGH95 powder as cladding material.The solidification microstructure in the sample was investigated.It was found that t...Laser multi\|layer cladding experiments were performed on the substrate of DD3 single crystal with FGH95 powder as cladding material.The solidification microstructure in the sample was investigated.It was found that the solidification microstructure was greatly influenced by the crystallography orientation of the substrate and the local solidification conditions.When the angle between the preferred orientation of the single crystal and the direction of heat flow in the cladding layer is less than 30°,single crystal cladding layers were acquired.Otherwise the crystallography orientation of the cladding layer will deviate from the orientation of the substrate and the microstructure with polycrystalline appears.Meanwhile,even when the experiments were performed on the same preferred crystal surface,the solidification microstructures will be different distinctly resulting from the variation of the local solidification conditions.The secondary arms were degenerated and the primary arm spacing was about 10\|20μm.Further investigation shows that the phases of the cladding layer are mainly made up ofγ,γ′,the flower\|likeγ/γ′eutectic and carbide.The morphology ofγ′was cubical and the size is less than 0.1μm.展开更多
By laser multi-layer cladding using a pulsed Nd-YAG irradiation the thickness of the cladding zone Mg-based alloys(ZM2 and ZM5) can reach about 1.0 mm.The microstructure of the substrate and the cladding zone was stud...By laser multi-layer cladding using a pulsed Nd-YAG irradiation the thickness of the cladding zone Mg-based alloys(ZM2 and ZM5) can reach about 1.0 mm.The microstructure of the substrate and the cladding zone was studied using optical microscope, scanning electron microscopy(SEM), X-ray diffractometry(XRD) and micro hardness analysis. It is observed that constituent of ZM5 alloy is δ+Mg 17Al 12, that of ZM2 alloy is α+MgZn+Mg 9Ce. That of cladding layer ZM2 alloy(L-ZM2) is Mg+Mg 2Zn 11+MgCe; while that of the cladding layer ZM5 alloy(L-ZM5) is Mg+Mg 32(Al, Zn) 49. The hardness of the cladding area can be increased to values above HV127. Very fine uniform microstructure and the produced new phases of nanometer/sub-micrometer order were obtained. Now, many repaired Mg-based alloy components have been passed by flying test in outside field.展开更多
Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,a...Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,as well as the wear resistance of the coatings.Besides,the effect of changing the laser melting process on the coatings was also investigated.The oxidation mass gain at 800–1200℃and the high-temperature oxidation behavior during high-temperature treatment for 1 h of two coated Zr alloy samples were studied.Results show that the Co coating and the Co-T800 coating have better resistance against high-temperature oxidation.After oxidizing at 1000℃for 1 h,the thickness of the oxide layer of the uncoated sample was 241.0μm,whereas that of the sample with Co-based coating is only 11.8–35.5μm.The friction wear test shows that the depth of the abrasion mark of the coated sample is only 1/2 of that of the substrate,indicating that the hardness and wear resistance of the Zr substrate are greatly improved.The disadvantage of Co-based coatings is the inferior corrosion resistance in 3.5wt%NaCl solution.展开更多
Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and...Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and tribological properties were investigated by laser cladding technique.Additionally,the effect of Si on the glass forming ability(GFA)of the layers was understood.Results show that an appropriate Si content can refine the microstructure of the FeCoNiBSiNb laser cladding layers and improve the mechanical and tribological properties.The hardness of the coating layer increases monotonically with the Si content.At the Si content of 4.8at%(x=0),the coating layer exhibits a relatively low hardness(734.2HV 0.1).Conversely,at the silicon content of 13.44at%(x=3),the coating layer exhibits the highest hardness(1106HV 0.1).The non-crystalline content and tensile strength exhibit an initial increase,followed by a subsequent decrease.At x=2,the coating exhibits its maximum fracture strength(2880 MPa).However,when x>2,the fracture strength of the coating decreases with an increase in x.Conversely,with an increase in Si content,the wear volume loss initially decreases and then increases.At a Si content of 10.56at%(x=2),the coating exhibits the highest non-crystalline content(42%),the highest tensile strength(2880 MPa),and the most favorable dry friction performance.展开更多
In order to enhance the wear resistance of 45 steel,a WC/Stellite 6 composite layer with 30%WC which with different morphologies(spherical and irregular)was prepared on the surface of 45 steel by laser cladding techno...In order to enhance the wear resistance of 45 steel,a WC/Stellite 6 composite layer with 30%WC which with different morphologies(spherical and irregular)was prepared on the surface of 45 steel by laser cladding technology.The effects of WC morphology on the phase composition,microstructure,microhardness,and wear resistance of the cladding layer were compared and analyzed.The res-ults show that the surface of the cladding layer was well formed.M_(23)C_(6),M_(7)C_(3),WC,and W_(2)C exist in both cladding layers.With the ad-dition of spherical WC,the diffraction peaks of γ-Co appear on the left side of the main peak of Co6W6C.The area of intergranular carbides accounts for a large proportion in the surface layer which with the fine grains.During the process of laser cladding the spherical WC particles with loose structure are prone to melting,including their interior.However,the melting amount of irregular WC particles is finite,which only occurs on the periphery of the particles,and the particle interior is relatively intact.The microhard-ness of two cladding layers gradient increases from the substrate to the surface layer.The surface layer added spherical WC has high-er microhardness,which reaches 790.6 HV1.Nevertheless,the wear resistance of the cladding layer added irregular WC is better than that of the cladding layer added spherical WC.The reason is because that the incompletely melted irregular WC particles are uni-formly distributed in the cladding layer which provided the support points for the cladding layer matrix during the wear process,the wear of the cladding layer by the grinding pair is reduced consequently.展开更多
Conventional Fe-C alloy parts used in mechanical transmission and braking systems exposed to the external environment often suffer from wear and corrosion failures.Surface coating strengthening technologies have been ...Conventional Fe-C alloy parts used in mechanical transmission and braking systems exposed to the external environment often suffer from wear and corrosion failures.Surface coating strengthening technologies have been explored to improve the surface performance and prolong service life of these parts.Among these technologies,laser cladding has shown promise in producing Fe-based alloy coatings with superior interfacial bonding properties to the Fe-C alloy substrate.Additionally,the microstructure of the Fe-based alloy coating is more uniform and the grain size is finer than that of surfacing welding,thermal spraying,and plasma cladding,and the oxide film of alloying elements on the coating surface can improve the coating performance.However,Fe-based alloy coatings produced by laser cladding typically exhibit lower hardness,lower wear resistance,corrosion resistance,and oxidation resistance compared to coatings based on Co and Ni alloys.Moreover,these coatings are susceptible to defects such as pores and cracks.To address these limitations,the incorporation of rare-earth oxides through doping in the laser cladding process has garnered significant attention.This approach has demonstrated substantial improvements in the microstructure and properties of Fe-based alloy coatings.This paper reviewed recent research on the structure and properties of laser-cladded Fe-based alloy coatings doped with various rare earth oxides,including La_(2)O_(3),CeO_(2),and Y_(2)O_(3).Specifically,it discussed the effects of rare earth oxides and their concentrations on the structure,hardness,friction,wear,corrosion,and oxidation characteristics of these coatings.Furthermore,the mechanisms by which rare earth oxides influence the coating’s structure and properties were summarized.This review aimed to serve as a valuable reference for the application and advancement of laser cladding technology for rare earth modified Fe-based alloy coatings.展开更多
The Multi layer coating of Ni60 alloy was got by multi layer laser cladding. The height of the coating was about 12mm and the wall of the coating was perpendicular to the base. The microstructure of the coating was ...The Multi layer coating of Ni60 alloy was got by multi layer laser cladding. The height of the coating was about 12mm and the wall of the coating was perpendicular to the base. The microstructure of the coating was made up of fine dendrite. The conjunction between layers was good.展开更多
Multi-layer laser cladding manufacturing is a newly developed rapid manufacturing technology. It is a powerful tool for direct fabrication of three-dimensional fully dense metal components and part repairing. In this ...Multi-layer laser cladding manufacturing is a newly developed rapid manufacturing technology. It is a powerful tool for direct fabrication of three-dimensional fully dense metal components and part repairing. In this paper, the microstructure evolution and properties of 316L stainless steel deposited with this technology was investigated, compact components with properties similar to the as-cast and wrought annealed material was obtained. Cracking was eliminated by introducing of supersonic vibration and application of parameter adjustment technologies.展开更多
The effects of Y_(2)O_(3) on the microstructure, microhardness, wear resistance, high-temperature oxidation resistance, hot corrosion resistance, and electrochemical corrosion behaviour of CoCrFeNiTiNb high entropy al...The effects of Y_(2)O_(3) on the microstructure, microhardness, wear resistance, high-temperature oxidation resistance, hot corrosion resistance, and electrochemical corrosion behaviour of CoCrFeNiTiNb high entropy alloy coatings formed on Ti-6Al-4V alloy surfaces were studied. The results show that the addition of Y_(2)O_(3) changes the proportion of the phase but does not change its type. The average grain size is only 1/4.7 of that of the high entropy alloy(HEA) coating, and the fine-grained strengthening leads to increases in the microhardness and wear resistance of 21.8% and 26.9%, respectively. The addition of Y_(2)O_(3) enhances the denseness and bonding properties of the oxide and corrosion product layers, reducing the oxidation and hot corrosion rates by 60.3% and 40.3%, respectively. The addition of Y_(2)O_(3) doubles the corrosion resistance which is attributed to the refinement of the grains, the increased proportion of HCP and TiN, and the weakening of galvanic coupling corrosion.展开更多
WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content o...WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content on microstructure and wear property of the composite coatings was studied in detail.Large numbers of carbides with four main types:primary carbide crystals,eutectic structures,massive crystals growing along the periphery of the remaining WC particles and incompletely fused WC particles,were found to exist in the WC/CoCrFeNiMo composite coatings.With increasing WC content,the microhardness of coatings is gradually improved while the average friction coefficients follow the opposite trend due to solid solution strengthening and second phase strengthening effect.The maximum microhardness and minimum friction coefficient are HV_(0.2)689.7 and 0.72,respectively,for the composite coating with 30 wt.%WC,the wear resistance of the substrate is improved significantly,the wear mechanisms are spalling wear and abrasive wear due to their high microhardness.展开更多
Four kinds of Ni-xCr alloy laser cladding layers(x=20,40,60 and 80,wt%)were prepared by high-speed laser cladding technique,and the relationship between microstructure and wear resistance of Ni-Cr alloy laser cladding...Four kinds of Ni-xCr alloy laser cladding layers(x=20,40,60 and 80,wt%)were prepared by high-speed laser cladding technique,and the relationship between microstructure and wear resistance of Ni-Cr alloy laser cladding layers with different Cr contents was investigated.The results show that the four Ni-Cr alloy laser cladding layers all have reticulated dendritic structures.Among them,Ni-20Cr and Ni-40Cr are single-phaseγ-(Ni,Cr)solid solutions,and their wear mechanisms are adhesive wear and abrasive wear.With the increase in Cr content,Ni-60Cr and Ni-80Cr areγ-(Ni,Cr)phase and Cr phase,as well as Cr-rich precipitates,and their wear mechanisms are adhesive wear,abrasive wear and fatigue wear.A moderate increase in Cr content can enhance the hardness and wear resistance of Ni-Cr alloy laser cladding layer.However,excessive addition of Cr results in the precipitation of Cr-rich precipitates.The hardness of these precipitates is 2430.4 MPa,which is lower than the hardness of the Ni-60Cr matrix(4024.86 MPa)and Ni-80Cr matrix(7022.68 MPa).A hardness transition zone exists between the Cr-rich precipitates and the matrix.Cracks are likely to initiate and expand in this zone,leading to deep spalling,which is not conducive to the wear-resistant properties of the laser cladding layer.Ni-80Cr has the highest hardness,but its high Cr content leads to a large number of penetrating cracks and Cr-rich precipitates on the surface,ultimately resulting in the worst wear resistance.Ni-60Cr exhibits the best wear resistance due to its high hardness and dense microstructure.展开更多
(Zr_(0.53)Al_(0.1)Ni_(0.05)Cu_(0.3)Ti_(0.02))_(99)Y_1(at%)coating with amorphous layer of about 180μm thick was prepared on a steel substrate by using laser cladding method.The coating is compact and shows good metal...(Zr_(0.53)Al_(0.1)Ni_(0.05)Cu_(0.3)Ti_(0.02))_(99)Y_1(at%)coating with amorphous layer of about 180μm thick was prepared on a steel substrate by using laser cladding method.The coating is compact and shows good metallurgical bonding with substrate.The microstructure,microhardness and corrosion behavior along the depth from the coating surface to the substrate were investigated.It is found that a gradient structure consisted of amorphous surface layer,amorphous-crystalline transitional layer and substrate is formed after the laser cladding.The microhardness and corrosion behavior exhibit variation with the microstructural evolution at different depths from the coating surface.The microhardness and corrosion resistance in 3.5 wt%NaCl solution of the amorphous surface layer are comparable to those of the as-cast Zr-based BMG with the same composition,and higher than those of the steel substrate.展开更多
The effect of the gradient content of Co element on the solidification process of Cu-based alloy under deep under cooling conditions was explored.The non-equilibrium solidification structure of the under cooled alloy ...The effect of the gradient content of Co element on the solidification process of Cu-based alloy under deep under cooling conditions was explored.The non-equilibrium solidification structure of the under cooled alloy samples were analyzed.It is found that the rapidly solidified alloy has undergone twice grain refinement during the undercooling process.Characterization and significance of the maximum undercooling refinement structure of Cu60Ni35Co5 at T=253 K were analyzed.High-density defects were observed,such as dislocations,stacking faults networks,and twinning structures.The standard FCC diffraction pattern represents that it is still a single-phase structure.Based on the metallographic diagram,EBSD and TEM data analysis,it is illustrated that the occurrence of grain refinement under high undercooling is due to stress induced recrystallization.In addition,the laser cladding technology is used to coat Co-based alloy(Stellite12) coating on 304 stainless steel substrate;the microstructure of the coating cross-section was analyzed.It was found that the microstructure of the cross-section is presented as columnar crystals,planar crystals,and disordered growth direction,so that the coating has better hardness and wear resistance.By electrochemical corrosion of the substrate and coating,it can be seen that the Co and Cr elements present in the coating are more likely to form a dense passivation film,which improved the corrosion resistance of the coating.展开更多
21-4N(5Cr21Mn9Ni4N)is extensively employed in the production of engine valves,operating under severe conditions.Apart from withstanding high-temperature gas corrosion,it must also endure the impact of cylinder explosi...21-4N(5Cr21Mn9Ni4N)is extensively employed in the production of engine valves,operating under severe conditions.Apart from withstanding high-temperature gas corrosion,it must also endure the impact of cylinder explosion pressure.The predominant failure mode of 21-4N valves is abrasive wear.Surface coatings serve as an effective approach to prevent such failures.In this investigation,Laser cladding technology was utilized to fabricate AlCoCrFeNiTi high entropy alloy coatings onto the surfaces of 21-4N valves.According to the findings,the cladding zone has a normal dendritic microstructure,a good substrate-to-cladding layer interaction,and no obvious flaws.In terms of hardness,the cladding demonstrates an average hardness of 620 HV.The hardness has increased by 140%compared to the substrate.The average hardness of the cladding remains at approximately 520 HV even at elevated temperatures.Regarding frictional wear performance,between 400℃and 800℃,the cladding layer exhibits an average friction coefficient of 0.4,with the primary wear mechanisms being abrasive wear,adhesive wear,and a minor degree of plastic deformation.展开更多
The mathematical model between laser cladding parameters and coating properties was established by the response surface method(RSM).Ni–WC-reinforced CoCrNiFeAl high-entropy alloy(HEA)composite coatings were prepared ...The mathematical model between laser cladding parameters and coating properties was established by the response surface method(RSM).Ni–WC-reinforced CoCrNiFeAl high-entropy alloy(HEA)composite coatings were prepared on the surface of 0Cr13Ni5Mo steel by laser cladding to study the addition of Ni–WC on slurry erosion resistance of coatings.The optimal parameters obtained by RSM are laser power of 1450 W,scanning speed of 4.3 mm/s,powder feeding speed of 1.3 r/min and overlap rate of 60%,respectively.The grains of CoCrNiFeAl composite coatings are refined by adding Ni–WC-reinforced powder.15 wt.%Ni–WC composite coating presents the maximum microhardness with the value of 655 HV_(0.3).The cumulative mass loss of the composite coatings at different erosion angles is lower than that of the pure CoCrNiFeAl coating.In addition,at low erosion angles,the cumulative mass loss of the composite coatings gradually decreases with the increase in the mass fraction of Ni–WC.Ploughing and microcutting are the primary erosion mechanisms of CoCrNiFeAl composite coatings at low erosion angles.When erosion damage occurs at high erosion angle,the erosion mechanisms of composite coating material loss are dominated by lip formation and craters.The proposed high-entropy alloy composite coatings can be applied to improve the erosion resistance of components in contact with high-speed fluids,such as ship propellers and centrifugal pump blades.展开更多
In order to investigate the process of laser cladding(LC)Inconel 625 alloy powder on Q235 steel plate,this paper focuses on analyzing the effects of different process parameters on the temperature field,stress field a...In order to investigate the process of laser cladding(LC)Inconel 625 alloy powder on Q235 steel plate,this paper focuses on analyzing the effects of different process parameters on the temperature field,stress field and flow behavior of the molten pool through a combination of finite element simulation and experiment.The simulation part established a geometric model,applied the Goldak double el-lipsoid heat source model,and simulated the LC process by varying the laser power and scanning speed.For the experimental part,LC equipment was used,parameters such as laser power and scanning speed were adjusted,and the molten pool dynamics were observed by in-frared temperature measurement and high-speed photography.The results show that the laser power and scanning speed are the key factors affecting the quality of cladding,and the experimental observation coincides with the simulation results,which verifies the validity of the simulation method and provides theoretical basis and experimental support for the optimization of the LC process.展开更多
In order to improve the sealing surface performance of gray cast iron gas gate valves and achieve precise molding control of the cladding layer,as well as to reveal the influence of laser cladding process parameters o...In order to improve the sealing surface performance of gray cast iron gas gate valves and achieve precise molding control of the cladding layer,as well as to reveal the influence of laser cladding process parameters on the morphology and structure of the cladding layer,we prepared the 316L coating on HT 200 by using Design-Expert software central composite design(CCD)based on response surface analysis.We built a regression prediction model and analyzed the ANOVA with the inspection results.With a target cladding layer width of 3.5 mm and height of 1.3 mm,the process parameters were optimized to obtain the best combination of process parameters.The microstructure,phases,and hardness variations of the cladding layer from experiments with optimal parameters were analyzed by the metallographic microscope,confocal microscope,and microhardness instrument.The experimental results indicate that laser power has a significant impact on the cladding layer width,followed by powder feed rate;scan speed has a significant impact on the cladding layer height,followed by powder feed rate.The HT200 substrate and 316L can metallurgically bond well,and the cladding layer structure consists of dendritic crystals,columnar crystals,and equiaxed crystals in sequence.The optimal process parameter combination satisfying the morphology requirements is laser power(A)of 1993 W,scan speed(B)of 8.949 mm/s,powder feed rate(C)of 1.408 r/min,with a maximum hardness of 1564.3 HV0.5,significantly higher than the hardness of the HT200 substrate.展开更多
The crack-free Ni60 A coating was fabricated on 45 steel substrate by laser cladding and the microstructure including solidification characteristics, phases constitution and phase distribution was systematically inves...The crack-free Ni60 A coating was fabricated on 45 steel substrate by laser cladding and the microstructure including solidification characteristics, phases constitution and phase distribution was systematically investigated. The high temperature friction and wear behavior of the cladding coating and substrate sliding against GCr15 ball under different loads was systematically evaluated. It was found that the coating has homogenous and fine microstructure consisting of γ（Ni） solid solution, a considerable amount of network Ni-Ni3 B eutectics, m^23C6 with the floret-shape structure and Cr B with the dark spot-shape structure uniformly distributing in interdendritic eutectics. The microhardness of the coating is about 2.6 times as much as that of the substrate. The coating produces higher friction values than the substrate under the same load condition, but the friction process on the coating keeps relatively stable. Wear rates of the coating are about 1/6.2 of that of the substrate under the higher load（300 g）. Wear mechanism of the substrate includes adhesion wear, abrasive wear, severe plastic deformation and oxidation wear, while that of the coating is merely a combination of mild abrasive wear and moderate oxidation wear.展开更多
Fe-based coating was produced on pure Ti substrate by the laser cladding technology. The composition and microstructure of the fabricated coating were analyzed by scanning electron microscopy （SEM）, X-ray diffracti...Fe-based coating was produced on pure Ti substrate by the laser cladding technology. The composition and microstructure of the fabricated coating were analyzed by scanning electron microscopy （SEM）, X-ray diffraction （XRD） and transmission electron microscopy （TEM） technique. The tribological properties were tested through sliding against AISI52100 steel ball at different normal loads and sliding speeds. Besides, the morphologies of the worn surfaces and wear debris were analyzed by scanning electron microscopy （SEM） and three dimensional （3D） non-contact surface mapping. The results show that the prepared Fe-based coating has a high hardness of about 860 HV0.2 and exhibits an average wear rate of （0.70-2.32）×10-6 mm3/（N-m）, showing that the Fe-based coating can greatly improve the wear resistance of pure Ti substrate. The wear mechanism of the coating involves moderate adhesive and abrasive wear.展开更多
A Y2O3 particle enhanced Ni/TiC composite coating was fabricated in-situ on a TC4 Ti alloy by laser surface cladding. The phase component, microstructure, composition distribution and properties of the composite layer...A Y2O3 particle enhanced Ni/TiC composite coating was fabricated in-situ on a TC4 Ti alloy by laser surface cladding. The phase component, microstructure, composition distribution and properties of the composite layer were investigated. The composite layer has graded microstructures and compositions, due to the fast melting followed by rapid solidification and cooling during laser cladding. The TiC powders are completely dissolved into the melted layer during melting and segregated as fine dendrites when solidified. The size of TiC dendrites decreases with increasing depth. Y2O3 fine particles distribute in the whole clad layer. The Y2O3 particle enhanced Ni/TiC composite layer has a quite uniform hardness along depth with a maximum value of HV1380, which is 4 times higher than the initial hardness. The wear resistance of the Ti alloy is significantly improved after laser cladding due to the high hardness of the composite coating.展开更多
基金National Key Basic Research Development Program me of china(No.G2000067205-3)
文摘Laser multi\|layer cladding experiments were performed on the substrate of DD3 single crystal with FGH95 powder as cladding material.The solidification microstructure in the sample was investigated.It was found that the solidification microstructure was greatly influenced by the crystallography orientation of the substrate and the local solidification conditions.When the angle between the preferred orientation of the single crystal and the direction of heat flow in the cladding layer is less than 30°,single crystal cladding layers were acquired.Otherwise the crystallography orientation of the cladding layer will deviate from the orientation of the substrate and the microstructure with polycrystalline appears.Meanwhile,even when the experiments were performed on the same preferred crystal surface,the solidification microstructures will be different distinctly resulting from the variation of the local solidification conditions.The secondary arms were degenerated and the primary arm spacing was about 10\|20μm.Further investigation shows that the phases of the cladding layer are mainly made up ofγ,γ′,the flower\|likeγ/γ′eutectic and carbide.The morphology ofγ′was cubical and the size is less than 0.1μm.
文摘By laser multi-layer cladding using a pulsed Nd-YAG irradiation the thickness of the cladding zone Mg-based alloys(ZM2 and ZM5) can reach about 1.0 mm.The microstructure of the substrate and the cladding zone was studied using optical microscope, scanning electron microscopy(SEM), X-ray diffractometry(XRD) and micro hardness analysis. It is observed that constituent of ZM5 alloy is δ+Mg 17Al 12, that of ZM2 alloy is α+MgZn+Mg 9Ce. That of cladding layer ZM2 alloy(L-ZM2) is Mg+Mg 2Zn 11+MgCe; while that of the cladding layer ZM5 alloy(L-ZM5) is Mg+Mg 32(Al, Zn) 49. The hardness of the cladding area can be increased to values above HV127. Very fine uniform microstructure and the produced new phases of nanometer/sub-micrometer order were obtained. Now, many repaired Mg-based alloy components have been passed by flying test in outside field.
基金National Natural Science Foundation of China(52071126)Natural Science Foundation of Tianjin City,China(22JCQNJC01240)+2 种基金Central Guidance on Local Science and Technology Development Fund of Hebei Province(226Z1009G)Special Funds for Science and Technology Innovation in Hebei(2022X19)Anhui Provincial Natural Science Foundation(2308085ME135)。
文摘Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,as well as the wear resistance of the coatings.Besides,the effect of changing the laser melting process on the coatings was also investigated.The oxidation mass gain at 800–1200℃and the high-temperature oxidation behavior during high-temperature treatment for 1 h of two coated Zr alloy samples were studied.Results show that the Co coating and the Co-T800 coating have better resistance against high-temperature oxidation.After oxidizing at 1000℃for 1 h,the thickness of the oxide layer of the uncoated sample was 241.0μm,whereas that of the sample with Co-based coating is only 11.8–35.5μm.The friction wear test shows that the depth of the abrasion mark of the coated sample is only 1/2 of that of the substrate,indicating that the hardness and wear resistance of the Zr substrate are greatly improved.The disadvantage of Co-based coatings is the inferior corrosion resistance in 3.5wt%NaCl solution.
文摘Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and tribological properties were investigated by laser cladding technique.Additionally,the effect of Si on the glass forming ability(GFA)of the layers was understood.Results show that an appropriate Si content can refine the microstructure of the FeCoNiBSiNb laser cladding layers and improve the mechanical and tribological properties.The hardness of the coating layer increases monotonically with the Si content.At the Si content of 4.8at%(x=0),the coating layer exhibits a relatively low hardness(734.2HV 0.1).Conversely,at the silicon content of 13.44at%(x=3),the coating layer exhibits the highest hardness(1106HV 0.1).The non-crystalline content and tensile strength exhibit an initial increase,followed by a subsequent decrease.At x=2,the coating exhibits its maximum fracture strength(2880 MPa).However,when x>2,the fracture strength of the coating decreases with an increase in x.Conversely,with an increase in Si content,the wear volume loss initially decreases and then increases.At a Si content of 10.56at%(x=2),the coating exhibits the highest non-crystalline content(42%),the highest tensile strength(2880 MPa),and the most favorable dry friction performance.
基金supported by the National Natural Science Foundation of China(52161007)Science and Technology Planning Project of Guangdong Province of China(20170902,20180902)+1 种基金Science and Technology Planning Project of Yangjiang City of Guangdong Province(SDZX2020009)Research project of Shenzhen city(JSGG20210420091802007).
文摘In order to enhance the wear resistance of 45 steel,a WC/Stellite 6 composite layer with 30%WC which with different morphologies(spherical and irregular)was prepared on the surface of 45 steel by laser cladding technology.The effects of WC morphology on the phase composition,microstructure,microhardness,and wear resistance of the cladding layer were compared and analyzed.The res-ults show that the surface of the cladding layer was well formed.M_(23)C_(6),M_(7)C_(3),WC,and W_(2)C exist in both cladding layers.With the ad-dition of spherical WC,the diffraction peaks of γ-Co appear on the left side of the main peak of Co6W6C.The area of intergranular carbides accounts for a large proportion in the surface layer which with the fine grains.During the process of laser cladding the spherical WC particles with loose structure are prone to melting,including their interior.However,the melting amount of irregular WC particles is finite,which only occurs on the periphery of the particles,and the particle interior is relatively intact.The microhard-ness of two cladding layers gradient increases from the substrate to the surface layer.The surface layer added spherical WC has high-er microhardness,which reaches 790.6 HV1.Nevertheless,the wear resistance of the cladding layer added irregular WC is better than that of the cladding layer added spherical WC.The reason is because that the incompletely melted irregular WC particles are uni-formly distributed in the cladding layer which provided the support points for the cladding layer matrix during the wear process,the wear of the cladding layer by the grinding pair is reduced consequently.
基金supported by the Jiangxi Provincial Natural Science Foundation of China(Grant number 20224BAB204049)the National Natural Science Foundation of China(Grant number 52205194)the Fund Project of Jiangxi Provincial Department of Education(Grant number GJJ2200602)。
文摘Conventional Fe-C alloy parts used in mechanical transmission and braking systems exposed to the external environment often suffer from wear and corrosion failures.Surface coating strengthening technologies have been explored to improve the surface performance and prolong service life of these parts.Among these technologies,laser cladding has shown promise in producing Fe-based alloy coatings with superior interfacial bonding properties to the Fe-C alloy substrate.Additionally,the microstructure of the Fe-based alloy coating is more uniform and the grain size is finer than that of surfacing welding,thermal spraying,and plasma cladding,and the oxide film of alloying elements on the coating surface can improve the coating performance.However,Fe-based alloy coatings produced by laser cladding typically exhibit lower hardness,lower wear resistance,corrosion resistance,and oxidation resistance compared to coatings based on Co and Ni alloys.Moreover,these coatings are susceptible to defects such as pores and cracks.To address these limitations,the incorporation of rare-earth oxides through doping in the laser cladding process has garnered significant attention.This approach has demonstrated substantial improvements in the microstructure and properties of Fe-based alloy coatings.This paper reviewed recent research on the structure and properties of laser-cladded Fe-based alloy coatings doped with various rare earth oxides,including La_(2)O_(3),CeO_(2),and Y_(2)O_(3).Specifically,it discussed the effects of rare earth oxides and their concentrations on the structure,hardness,friction,wear,corrosion,and oxidation characteristics of these coatings.Furthermore,the mechanisms by which rare earth oxides influence the coating’s structure and properties were summarized.This review aimed to serve as a valuable reference for the application and advancement of laser cladding technology for rare earth modified Fe-based alloy coatings.
文摘The Multi layer coating of Ni60 alloy was got by multi layer laser cladding. The height of the coating was about 12mm and the wall of the coating was perpendicular to the base. The microstructure of the coating was made up of fine dendrite. The conjunction between layers was good.
基金supported by the National Natural Science Foundation of China under the Grant No.50375096
文摘Multi-layer laser cladding manufacturing is a newly developed rapid manufacturing technology. It is a powerful tool for direct fabrication of three-dimensional fully dense metal components and part repairing. In this paper, the microstructure evolution and properties of 316L stainless steel deposited with this technology was investigated, compact components with properties similar to the as-cast and wrought annealed material was obtained. Cracking was eliminated by introducing of supersonic vibration and application of parameter adjustment technologies.
基金Project supported by the National Natural Science Foundation of China(51805285,51605237)the projects of Shandong Province"Youth Innovation Science and Technology Support Plan"(2021KJ026)+1 种基金the Key Research and Development Project of Shandong Province(2018GGX103031)the Natural Science Foundation of Shandong Province(ZR2021ME023)。
文摘The effects of Y_(2)O_(3) on the microstructure, microhardness, wear resistance, high-temperature oxidation resistance, hot corrosion resistance, and electrochemical corrosion behaviour of CoCrFeNiTiNb high entropy alloy coatings formed on Ti-6Al-4V alloy surfaces were studied. The results show that the addition of Y_(2)O_(3) changes the proportion of the phase but does not change its type. The average grain size is only 1/4.7 of that of the high entropy alloy(HEA) coating, and the fine-grained strengthening leads to increases in the microhardness and wear resistance of 21.8% and 26.9%, respectively. The addition of Y_(2)O_(3) enhances the denseness and bonding properties of the oxide and corrosion product layers, reducing the oxidation and hot corrosion rates by 60.3% and 40.3%, respectively. The addition of Y_(2)O_(3) doubles the corrosion resistance which is attributed to the refinement of the grains, the increased proportion of HCP and TiN, and the weakening of galvanic coupling corrosion.
基金Project(2021YFC2801904)supported by the National Key R&D Program of ChinaProject(KY10100230067)supported by the Basic Product Innovation Research Project,China+3 种基金Projects(52271130,52305344)supported by the National Natural Science Foundation of ChinaProjects(ZR2020ME017,ZR2020QE186)supported by the Natural Science Foundation of Shandong Province,ChinaProjects(AMGM2024F11,AMGM2021F10,AMGM2023F06)supported by the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai,ChinaProject(KY90200210015)supported by Leading Scientific Research Project of China National Nuclear Corporation(CNNC),China。
文摘WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content on microstructure and wear property of the composite coatings was studied in detail.Large numbers of carbides with four main types:primary carbide crystals,eutectic structures,massive crystals growing along the periphery of the remaining WC particles and incompletely fused WC particles,were found to exist in the WC/CoCrFeNiMo composite coatings.With increasing WC content,the microhardness of coatings is gradually improved while the average friction coefficients follow the opposite trend due to solid solution strengthening and second phase strengthening effect.The maximum microhardness and minimum friction coefficient are HV_(0.2)689.7 and 0.72,respectively,for the composite coating with 30 wt.%WC,the wear resistance of the substrate is improved significantly,the wear mechanisms are spalling wear and abrasive wear due to their high microhardness.
文摘Four kinds of Ni-xCr alloy laser cladding layers(x=20,40,60 and 80,wt%)were prepared by high-speed laser cladding technique,and the relationship between microstructure and wear resistance of Ni-Cr alloy laser cladding layers with different Cr contents was investigated.The results show that the four Ni-Cr alloy laser cladding layers all have reticulated dendritic structures.Among them,Ni-20Cr and Ni-40Cr are single-phaseγ-(Ni,Cr)solid solutions,and their wear mechanisms are adhesive wear and abrasive wear.With the increase in Cr content,Ni-60Cr and Ni-80Cr areγ-(Ni,Cr)phase and Cr phase,as well as Cr-rich precipitates,and their wear mechanisms are adhesive wear,abrasive wear and fatigue wear.A moderate increase in Cr content can enhance the hardness and wear resistance of Ni-Cr alloy laser cladding layer.However,excessive addition of Cr results in the precipitation of Cr-rich precipitates.The hardness of these precipitates is 2430.4 MPa,which is lower than the hardness of the Ni-60Cr matrix(4024.86 MPa)and Ni-80Cr matrix(7022.68 MPa).A hardness transition zone exists between the Cr-rich precipitates and the matrix.Cracks are likely to initiate and expand in this zone,leading to deep spalling,which is not conducive to the wear-resistant properties of the laser cladding layer.Ni-80Cr has the highest hardness,but its high Cr content leads to a large number of penetrating cracks and Cr-rich precipitates on the surface,ultimately resulting in the worst wear resistance.Ni-60Cr exhibits the best wear resistance due to its high hardness and dense microstructure.
基金financially supported by the National Natural Science Foundation of China(No.51271008)。
文摘(Zr_(0.53)Al_(0.1)Ni_(0.05)Cu_(0.3)Ti_(0.02))_(99)Y_1(at%)coating with amorphous layer of about 180μm thick was prepared on a steel substrate by using laser cladding method.The coating is compact and shows good metallurgical bonding with substrate.The microstructure,microhardness and corrosion behavior along the depth from the coating surface to the substrate were investigated.It is found that a gradient structure consisted of amorphous surface layer,amorphous-crystalline transitional layer and substrate is formed after the laser cladding.The microhardness and corrosion behavior exhibit variation with the microstructural evolution at different depths from the coating surface.The microhardness and corrosion resistance in 3.5 wt%NaCl solution of the amorphous surface layer are comparable to those of the as-cast Zr-based BMG with the same composition,and higher than those of the steel substrate.
基金Funded by the Basic Research Projects in Shanxi Province(No.202103021224183)。
文摘The effect of the gradient content of Co element on the solidification process of Cu-based alloy under deep under cooling conditions was explored.The non-equilibrium solidification structure of the under cooled alloy samples were analyzed.It is found that the rapidly solidified alloy has undergone twice grain refinement during the undercooling process.Characterization and significance of the maximum undercooling refinement structure of Cu60Ni35Co5 at T=253 K were analyzed.High-density defects were observed,such as dislocations,stacking faults networks,and twinning structures.The standard FCC diffraction pattern represents that it is still a single-phase structure.Based on the metallographic diagram,EBSD and TEM data analysis,it is illustrated that the occurrence of grain refinement under high undercooling is due to stress induced recrystallization.In addition,the laser cladding technology is used to coat Co-based alloy(Stellite12) coating on 304 stainless steel substrate;the microstructure of the coating cross-section was analyzed.It was found that the microstructure of the cross-section is presented as columnar crystals,planar crystals,and disordered growth direction,so that the coating has better hardness and wear resistance.By electrochemical corrosion of the substrate and coating,it can be seen that the Co and Cr elements present in the coating are more likely to form a dense passivation film,which improved the corrosion resistance of the coating.
基金Sponsored by the Project to Enhance the Innovative Capabilities of Science and Technology SMEs of Shandong Province(Grant No.2023TSGC0531).
文摘21-4N(5Cr21Mn9Ni4N)is extensively employed in the production of engine valves,operating under severe conditions.Apart from withstanding high-temperature gas corrosion,it must also endure the impact of cylinder explosion pressure.The predominant failure mode of 21-4N valves is abrasive wear.Surface coatings serve as an effective approach to prevent such failures.In this investigation,Laser cladding technology was utilized to fabricate AlCoCrFeNiTi high entropy alloy coatings onto the surfaces of 21-4N valves.According to the findings,the cladding zone has a normal dendritic microstructure,a good substrate-to-cladding layer interaction,and no obvious flaws.In terms of hardness,the cladding demonstrates an average hardness of 620 HV.The hardness has increased by 140%compared to the substrate.The average hardness of the cladding remains at approximately 520 HV even at elevated temperatures.Regarding frictional wear performance,between 400℃and 800℃,the cladding layer exhibits an average friction coefficient of 0.4,with the primary wear mechanisms being abrasive wear,adhesive wear,and a minor degree of plastic deformation.
基金supported by the National Natural Science Foundation of China(Grant Nos.52375210 and 52375209)Yangzhou City and Yangzhou University Cooperation Foundation(Grant No.YZ2022182)+2 种基金Yangzhou Science and Technology Plan Project(Grant No.YZ2023246)Postgraduate Research and Practice Innovation Program of Jiangsu Province(Grant No.SJCX23_1902)Qing Lan Project of Yangzhou University.
文摘The mathematical model between laser cladding parameters and coating properties was established by the response surface method(RSM).Ni–WC-reinforced CoCrNiFeAl high-entropy alloy(HEA)composite coatings were prepared on the surface of 0Cr13Ni5Mo steel by laser cladding to study the addition of Ni–WC on slurry erosion resistance of coatings.The optimal parameters obtained by RSM are laser power of 1450 W,scanning speed of 4.3 mm/s,powder feeding speed of 1.3 r/min and overlap rate of 60%,respectively.The grains of CoCrNiFeAl composite coatings are refined by adding Ni–WC-reinforced powder.15 wt.%Ni–WC composite coating presents the maximum microhardness with the value of 655 HV_(0.3).The cumulative mass loss of the composite coatings at different erosion angles is lower than that of the pure CoCrNiFeAl coating.In addition,at low erosion angles,the cumulative mass loss of the composite coatings gradually decreases with the increase in the mass fraction of Ni–WC.Ploughing and microcutting are the primary erosion mechanisms of CoCrNiFeAl composite coatings at low erosion angles.When erosion damage occurs at high erosion angle,the erosion mechanisms of composite coating material loss are dominated by lip formation and craters.The proposed high-entropy alloy composite coatings can be applied to improve the erosion resistance of components in contact with high-speed fluids,such as ship propellers and centrifugal pump blades.
基金supported by Natural Science Foundation of Shandong Province of China(Grant No.ZR2023ME201)Qingdao Key Technology Research and Industrialization Demonstration Project(23-1-2-qljh-17-gx).
文摘In order to investigate the process of laser cladding(LC)Inconel 625 alloy powder on Q235 steel plate,this paper focuses on analyzing the effects of different process parameters on the temperature field,stress field and flow behavior of the molten pool through a combination of finite element simulation and experiment.The simulation part established a geometric model,applied the Goldak double el-lipsoid heat source model,and simulated the LC process by varying the laser power and scanning speed.For the experimental part,LC equipment was used,parameters such as laser power and scanning speed were adjusted,and the molten pool dynamics were observed by in-frared temperature measurement and high-speed photography.The results show that the laser power and scanning speed are the key factors affecting the quality of cladding,and the experimental observation coincides with the simulation results,which verifies the validity of the simulation method and provides theoretical basis and experimental support for the optimization of the LC process.
基金Funded by the National Natural Science Foundation of China(No.51975540)。
文摘In order to improve the sealing surface performance of gray cast iron gas gate valves and achieve precise molding control of the cladding layer,as well as to reveal the influence of laser cladding process parameters on the morphology and structure of the cladding layer,we prepared the 316L coating on HT 200 by using Design-Expert software central composite design(CCD)based on response surface analysis.We built a regression prediction model and analyzed the ANOVA with the inspection results.With a target cladding layer width of 3.5 mm and height of 1.3 mm,the process parameters were optimized to obtain the best combination of process parameters.The microstructure,phases,and hardness variations of the cladding layer from experiments with optimal parameters were analyzed by the metallographic microscope,confocal microscope,and microhardness instrument.The experimental results indicate that laser power has a significant impact on the cladding layer width,followed by powder feed rate;scan speed has a significant impact on the cladding layer height,followed by powder feed rate.The HT200 substrate and 316L can metallurgically bond well,and the cladding layer structure consists of dendritic crystals,columnar crystals,and equiaxed crystals in sequence.The optimal process parameter combination satisfying the morphology requirements is laser power(A)of 1993 W,scan speed(B)of 8.949 mm/s,powder feed rate(C)of 1.408 r/min,with a maximum hardness of 1564.3 HV0.5,significantly higher than the hardness of the HT200 substrate.
基金Project(2012AA040210)supported by the National High-Tech Research and Development Program of ChinaProject(510-C10293)supported by the Central Finance Special Fund to Support the Local University,ChinaProject(2010A090200048)supported by the Key Project of Industry,Education,Research of Guangdong Province and Ministry of Education,China
文摘The crack-free Ni60 A coating was fabricated on 45 steel substrate by laser cladding and the microstructure including solidification characteristics, phases constitution and phase distribution was systematically investigated. The high temperature friction and wear behavior of the cladding coating and substrate sliding against GCr15 ball under different loads was systematically evaluated. It was found that the coating has homogenous and fine microstructure consisting of γ（Ni） solid solution, a considerable amount of network Ni-Ni3 B eutectics, m^23C6 with the floret-shape structure and Cr B with the dark spot-shape structure uniformly distributing in interdendritic eutectics. The microhardness of the coating is about 2.6 times as much as that of the substrate. The coating produces higher friction values than the substrate under the same load condition, but the friction process on the coating keeps relatively stable. Wear rates of the coating are about 1/6.2 of that of the substrate under the higher load（300 g）. Wear mechanism of the substrate includes adhesion wear, abrasive wear, severe plastic deformation and oxidation wear, while that of the coating is merely a combination of mild abrasive wear and moderate oxidation wear.
基金Project (51045004) supported by the National Natural Science Foundation of ChinaProject (2006AA03A219) supported by Hi-tech Research and Development Program of ChinaProject (YYYJ-0913) supported by Knowledge Innovation Project in Chinese Academy of Sciences
文摘Fe-based coating was produced on pure Ti substrate by the laser cladding technology. The composition and microstructure of the fabricated coating were analyzed by scanning electron microscopy （SEM）, X-ray diffraction （XRD） and transmission electron microscopy （TEM） technique. The tribological properties were tested through sliding against AISI52100 steel ball at different normal loads and sliding speeds. Besides, the morphologies of the worn surfaces and wear debris were analyzed by scanning electron microscopy （SEM） and three dimensional （3D） non-contact surface mapping. The results show that the prepared Fe-based coating has a high hardness of about 860 HV0.2 and exhibits an average wear rate of （0.70-2.32）×10-6 mm3/（N-m）, showing that the Fe-based coating can greatly improve the wear resistance of pure Ti substrate. The wear mechanism of the coating involves moderate adhesive and abrasive wear.
基金Projects (51101096, 51002093) supported by the National Natural Science Foundation of ChinaProject (1052nm05000) supported by Special Foundation of the Shanghai Science and Technology Commission for Nano-Materials ResearchProject (J51042) supported by Leading Academic Discipline Project of the Shanghai Education Commission, China
文摘A Y2O3 particle enhanced Ni/TiC composite coating was fabricated in-situ on a TC4 Ti alloy by laser surface cladding. The phase component, microstructure, composition distribution and properties of the composite layer were investigated. The composite layer has graded microstructures and compositions, due to the fast melting followed by rapid solidification and cooling during laser cladding. The TiC powders are completely dissolved into the melted layer during melting and segregated as fine dendrites when solidified. The size of TiC dendrites decreases with increasing depth. Y2O3 fine particles distribute in the whole clad layer. The Y2O3 particle enhanced Ni/TiC composite layer has a quite uniform hardness along depth with a maximum value of HV1380, which is 4 times higher than the initial hardness. The wear resistance of the Ti alloy is significantly improved after laser cladding due to the high hardness of the composite coating.
