Grid pattern was textured on Ti-6 Al-4 V alloy(TC4)substrate surface by nanosecond laser system.Laser joining of carbon fiber reinforced thermoplastic composite(CFRTP)to TC4 joints were performed,and the effect of tex...Grid pattern was textured on Ti-6 Al-4 V alloy(TC4)substrate surface by nanosecond laser system.Laser joining of carbon fiber reinforced thermoplastic composite(CFRTP)to TC4 joints were performed,and the effect of texture grid depth was investigated.The contact angle of molten CFRTP on textured TC4 surface was measured and the tensile-shear force was tested.The fracture surface and interface morphology were observed.The results indicated that the wettability of molten CFRTP on TC4 surface improved remarkably after laser textured TC4.Shear force of CFRTP/TC4 joints was increased by 156%after laser textured TC4 surface.When the depth of grid was deeper than 100μm,contact angle increased and incomplete filling of molten CFRTP in grid occurred,the shear force thus decreased gradually.Resin-carbon fibers mixture was adhered on the fracture surface of TC4,and the variation tendency of adhesion ratio was consistent with that of shear force.TC4 matrix was exfoliated from substrate and adhered at the fracture surface of CFRTP,indicating stronger mechanical interlocking occurred at the joining interface after laser textured TC4 surface.Beside mechanical interlocking,compound layer consisted of CTi_(0.42)V_(1.58)carburization phase was also confirmed at interface,suggesting that chemical bonding also occurred at the joining interface.展开更多
Although hydrofluoric acid(HF)surface treatment is known to enhance the joining of metals with polymers,there is limited information on its effect on the joining of AZ31 alloy and carbon-fiber-reinforced plastics(CFRP...Although hydrofluoric acid(HF)surface treatment is known to enhance the joining of metals with polymers,there is limited information on its effect on the joining of AZ31 alloy and carbon-fiber-reinforced plastics(CFRPs)through laser-assisted metal and plastic direct joining(LAMP).This study uses the LAMP technique to produce AZ31-CFRP joints.The joining process involves as-received AZ31,HFpretreated AZ31,and thermally oxidized HF-pretreated AZ31 alloy sheets.Furthermore,the bonding strength of joints prepared with thermally oxidized AZ31 alloy sheets is examined to ascertain the combined effect of HF treatment and thermal oxidation on bonding strength.The microstructures,surface chemical interactions,and mechanical performances of joints are investigated under tensile shear loading.Various factors,such as bubble formation,CFRP resin decomposition,and mechanical interlocking considerably affect joint strength.Additionally,surface chemical interactions between the active species on metal parts and the polar amide along with carbonyl groups of polymer play a significant role in improving joint strength.Joints prepared with surface-pretreated AZ31 alloy sheets show significant improvements in bonding strength.展开更多
基金financially supported by National Natural Science Foundation of China(No.51875129)。
文摘Grid pattern was textured on Ti-6 Al-4 V alloy(TC4)substrate surface by nanosecond laser system.Laser joining of carbon fiber reinforced thermoplastic composite(CFRTP)to TC4 joints were performed,and the effect of texture grid depth was investigated.The contact angle of molten CFRTP on textured TC4 surface was measured and the tensile-shear force was tested.The fracture surface and interface morphology were observed.The results indicated that the wettability of molten CFRTP on TC4 surface improved remarkably after laser textured TC4.Shear force of CFRTP/TC4 joints was increased by 156%after laser textured TC4 surface.When the depth of grid was deeper than 100μm,contact angle increased and incomplete filling of molten CFRTP in grid occurred,the shear force thus decreased gradually.Resin-carbon fibers mixture was adhered on the fracture surface of TC4,and the variation tendency of adhesion ratio was consistent with that of shear force.TC4 matrix was exfoliated from substrate and adhered at the fracture surface of CFRTP,indicating stronger mechanical interlocking occurred at the joining interface after laser textured TC4 surface.Beside mechanical interlocking,compound layer consisted of CTi_(0.42)V_(1.58)carburization phase was also confirmed at interface,suggesting that chemical bonding also occurred at the joining interface.
基金supported by the Nano&Material Technology Development Program through the National Research Foundation of Korea(NRF),funded by the Ministry of Science and ICT(RS-2023-00234757).
文摘Although hydrofluoric acid(HF)surface treatment is known to enhance the joining of metals with polymers,there is limited information on its effect on the joining of AZ31 alloy and carbon-fiber-reinforced plastics(CFRPs)through laser-assisted metal and plastic direct joining(LAMP).This study uses the LAMP technique to produce AZ31-CFRP joints.The joining process involves as-received AZ31,HFpretreated AZ31,and thermally oxidized HF-pretreated AZ31 alloy sheets.Furthermore,the bonding strength of joints prepared with thermally oxidized AZ31 alloy sheets is examined to ascertain the combined effect of HF treatment and thermal oxidation on bonding strength.The microstructures,surface chemical interactions,and mechanical performances of joints are investigated under tensile shear loading.Various factors,such as bubble formation,CFRP resin decomposition,and mechanical interlocking considerably affect joint strength.Additionally,surface chemical interactions between the active species on metal parts and the polar amide along with carbonyl groups of polymer play a significant role in improving joint strength.Joints prepared with surface-pretreated AZ31 alloy sheets show significant improvements in bonding strength.
