The mechanical properties,such as hardness and modulus of elasticity of coatings and the part of thin walls of Ni-based and Co-based alloy prepared by LENS were measured by nanoindentation testing,scanning electron mi...The mechanical properties,such as hardness and modulus of elasticity of coatings and the part of thin walls of Ni-based and Co-based alloy prepared by LENS were measured by nanoindentation testing,scanning electron microscopy and energy dispersive spectroscopy were used to analyze their microstructure,the affect of parameters on structure and mechanical properties were studied.The results showed that the mechanical properties were basically identical with the whole coating;the hardness and modulus of elasticity of nanoindentation were evenly distributed in the defect field.The average hardness and modulus of elasticity of coating of Ni-based alloy are 8.29GPa and 235GPa.The average hardness and modulus of elasticity of coating of Co-based alloy are 7.08GPa and 243GPa.The modulus of elasticity of part of thin walls has relationship with the grain orientation.展开更多
We present a vectorial optical field(VOF) framework that surpasses the diffraction limit in both long-range imaging and energy delivery. By jointly engineering spatial and temporal dimensions, reflective Fourier ptych...We present a vectorial optical field(VOF) framework that surpasses the diffraction limit in both long-range imaging and energy delivery. By jointly engineering spatial and temporal dimensions, reflective Fourier ptychography is extended to 3.2 km with 0.37× the classical diffraction limit, while a single-photon Li DAR tomography system achieves centimeter-scale, sub-diffraction imaging at 3.3 km using superconducting nanowire single-photon detectors. These advances demonstrate super-resolution, turbulence-resilient imaging over kilometer-range distances. Beyond super-resolution optical, high power VOFs are able to counteract thermal blooming during atmospheric laser propagation, enhancing on-target power density by a factor larger than 2. Together, these results may outline a cross-scale paradigm that links highpower vector-field structuring, single-photon detection, and adaptive control-offering a pathway toward next-generation optical systems that integrate imaging, sensing, communication and directed energy within a common physical framework.展开更多
Laser engineered net shaping(LENS) process was investigated using Co-based superalloy powder with a high power continuous wave CO2 laser. Thin wall part with smooth surface was obtained by LENS of layer-by-layer depos...Laser engineered net shaping(LENS) process was investigated using Co-based superalloy powder with a high power continuous wave CO2 laser. Thin wall part with smooth surface was obtained by LENS of layer-by-layer deposition of the powder materials. This thin wall sample was tested for metallographic examinations, micro-hardness, X-ray diffraction and mechanical property test. Microstructural results show that the layers possess rapid solidification microstructural feature, fine dendritic crystal and M7C3-type carbides (essentially chromium-rich carbide) dispersed in theγ(Co,Cr) phase matrix. Dendrite spacing as well as the solidification mode can be controlled through control process parameters. In addition, this microstructural feature of the as-formed Co-base sample leads to an evident hardening and a superior tensile strength and toughness.展开更多
In this work,the evolution of melt pool under single-point and single-line printing in the laser engineered net shaping(LENS)process is analyzed.Firstly,the basic structure of the melt pool model of the LENS process i...In this work,the evolution of melt pool under single-point and single-line printing in the laser engineered net shaping(LENS)process is analyzed.Firstly,the basic structure of the melt pool model of the LENS process is established and the necessary assumptions are made.Then,the establishment process of the multi-physical field model of the melt pool is introduced in detail.It is concluded that the simulation model results are highly consistent with the online measurement experiment results in terms of melt pool profile,space temperature gradient,and time temperature gradient.Meanwhile,some parameters,such as the 3D morphology and surface fluid field of the melt pool,which are not obtained in the online measurement experiment,are analyzed.Finally,the influence of changing the scanning speed on the profile,peak temperature,and temperature gradient of the single-line melt pool is also analyzed,and the following conclusions are obtained:With the increase in scanning speed,the profile of the melt pool gradually becomes slender;The relationship between peak temperature and scanning speed is approximately linear in a certain speed range;The space temperature gradient at the tail of the melt pool under different scanning speeds hardly changes with the scanning speed,and the time temperature gradient at the tail of the melt pool is in direct proportion to the scanning speed.展开更多
Tellurene,a chiral chain semiconductor with a narrow bandgap and exceptional strain sensitivity,emerges as a pivotal material for tailoring electronic and optoelectronic properties via strain engineering.This study el...Tellurene,a chiral chain semiconductor with a narrow bandgap and exceptional strain sensitivity,emerges as a pivotal material for tailoring electronic and optoelectronic properties via strain engineering.This study elucidates the fundamental mechanisms of ultrafast laser shock imprinting(LSI)in two-dimensional tellurium(Te),establishing a direct relationship between strain field orientation,mold topology,and anisotropic structural evolution.This is the first demonstration of ultrafast LSI on chiral chain Te unveiling orientation-sensitive dislocation networks.By applying controlled strain fields parallel or transverse to Te’s helical chains,we uncover two distinct deformation regimes.Strain aligned parallel to the chain’s direction induces gliding and rotation governed by weak interchain interactions,preserving covalent intrachain bonds and vibrational modes.In contrast,transverse strain drives shear-mediated multimodal deformations—tensile stretching,compression,and bending—resulting in significant lattice distortions and electronic property modulation.We discovered the critical role of mold topology on deformation:sharp-edged gratings generate localized shear forces surpassing those from homogeneous strain fields via smooth CD molds,triggering dislocation tangle formation,lattice reorientation,and inhomogeneous plastic deformation.Asymmetrical strain configurations enable localized structural transformations while retaining single-crystal integrity in adjacent regions—a balance essential for functional device integration.These insights position LSI as a precision tool for nanoscale strain engineering,capable of sculpting 2D material morphologies without compromising crystallinity.By bridging ultrafast mechanics with chiral chain material science,this work advances the design of strain-tunable devices for next-generation electronics and optoelectronics,while establishing a universal framework for manipulating anisotropic 2D systems under extreme strain rates.This work discovered crystallographic orientation-dependent deformation mechanisms in 2D Te,linking parallel strain to chain gliding and transverse strain to shear-driven multimodal distortion.It demonstrates mold geometry as a critical lever for strain localization and dislocation dynamics,with sharp-edged gratings enabling unprecedented control over lattice reorientation.Crucially,the identification of strain field conditions that reconcile severe plastic deformation with single-crystal retention offers a pathway to functional nanostructure fabrication,redefining LSI’s potential in ultrafast strain engineering of chiral chain materials.展开更多
Laser anti-drone technology is entering the sequence of actual combat,and it is necessary to consider the vulnerability of typical functional parts of UAVs.Since the concept of"vulnerability"was proposed,a v...Laser anti-drone technology is entering the sequence of actual combat,and it is necessary to consider the vulnerability of typical functional parts of UAVs.Since the concept of"vulnerability"was proposed,a variety of analysis programs for battlefield targets to traditional weapons have been developed,but a comprehensive assessment methodology for targets'vulnerability to laser is still missing.Based on the shotline method,this paper proposes a method that equates laser beam to shotline array,an efficient vulnerability analysis program of target to laser is established by this method,and the program includes the circuit board and the wire into the vulnerability analysis category,which improves the precision of the vulnerability analysis.Taking the UAV engine part as the target of vulnerability analysis,combine with the"life-death unit method"to calculate the laser penetration rate of various materials of the UAV,and the influence of laser weapon system parameters and striking orientation on the killing probability is quantified after introducing the penetration rate into the vulnerability analysis program.The quantitative analysis method proposed in this paper has certain general expansibility,which can provide a fresh idea for the vulnerability analysis of other targets to laser.展开更多
The concepts of “confining structure” and structure light are illuminated in this paper.A laser theodolite with three freedoms of rotation,which is aimed at “confining structure”,is developed.Various scanning mode...The concepts of “confining structure” and structure light are illuminated in this paper.A laser theodolite with three freedoms of rotation,which is aimed at “confining structure”,is developed.Various scanning modes and their mathematical models based on laser theodolite with three freedoms of rotation are discussed.According to the features of a huge object,,the structure light engineering surveying based on laser theodolite with three freedoms of rotation is determined as the main method in an actual application.The observation of four sound concrete posts and forced centering plates.Subsequently,it is transformed into the huge object coordinate system.The scanning mode with plumb plane is selected as the main mode in the whole work.And other assistant methods,such as close range photogrammetry and the method of using reflection sheet,are applied to the work of “scanning dead angle”.At last,a surveying accuracy estimation of this method is done and a surveying accuracy test is finished.It can be concluded that the structure light engineering surveying based on laser theodolite with three freedoms of rotation is considered to be an effective and applied method,and has many superiority to some other surveying methods in the work of surveying “confining structure”.展开更多
Purpose: Selective laser sintering (SLS) is a rapid pro- totyping technique applied to produce tissue-engineer- ing scaffolds from powder materials. The standard scanning technique, however, often produces struts of e...Purpose: Selective laser sintering (SLS) is a rapid pro- totyping technique applied to produce tissue-engineer- ing scaffolds from powder materials. The standard scanning technique, however, often produces struts of extensive thickness, which means fabrication of high- ly porous scaffolds with small overall dimensions is quite difficult. Nevertheless, this study aims to overcome this shortfall. Design/methodology/approach: To this end, three scanning methods were evaluated in terms of minimum feature size and freedom of design, using a test polyamide (PA) material. Polycaprolactone (PCL) was then employed to create highly porous 3D scaffolds using the preferred scanning me- thod to produce thin struts. Findings: While in normal scanning mode some features were well above the laser spot diameter, strut thicknesses below the laser spot diameter were achieved when using the “outline scan” function for PA material. Those achieved for PCL were slightly higher and in the 500-800 ?m range, with an average pore size of 400 μm. Investigations on the properties of the scaffolds revealed an effective compression modulus of the PCL scaffold of 6.5 MPa. Furthermore, there was no change in physical or che- mical properties when the scaffolds were stored in a physiological environment for 7 weeks. Originality/ value: Though SLS is considered as a fabrication te- chnique for tissue engineering scaffolds, actually pro- duced scaffolds did not comply with porosity requirements and limitations of the SLS process in produ- cing features at the size of the laser beam spot have not been discussed. The present paper shows the capabilities of the SLS process based on two materials and presents a method to minimize feature size in scaffolds.展开更多
MALDI-TOF-MS technology was used for identification of lipopeptide antibiotics producedby GEB3 strain, a derivative of Bacillus subtilis 168 which was transformed by lpaB3gene. The result showed GEB3 only produced lip...MALDI-TOF-MS technology was used for identification of lipopeptide antibiotics producedby GEB3 strain, a derivative of Bacillus subtilis 168 which was transformed by lpaB3gene. The result showed GEB3 only produced lipopeptide antibiotic surfactin. The analysisby LC-MS demonstrated that GEB3 produced standard surfactin isoforms with side chainlengths of 13,14 and 15 carbon atoms. The bioactivity detection of surfactin indicatedthat the surfactin produced by GEB3 had inhibition effect on plant pathogens Rhizoctoniasolani and Pyricularia oryzae.展开更多
In this paper,a series of new techniques are used to optimize typical laser scanning sensor.The integrated prototype is compared with traditional approach to demonstrate the much improved performance.In the research a...In this paper,a series of new techniques are used to optimize typical laser scanning sensor.The integrated prototype is compared with traditional approach to demonstrate the much improved performance.In the research and development,camera calibration is achieved by extracting characteristic points of the laser plane,so that the calibra- tion efficiency is improved significantly.With feedback control of its intensity,the laser is automatically adjusted for different material.A modified algorithm is presented to improve the accuracy of laser stripe extraction.The fusion of data extracted from left and right camera is completed with re-sampling technique.The scanner is integrated with a robot arm and some other machinery for on-line measurement and inspection,which provides a flexible measurement tool for reverse engineering.展开更多
5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and ...5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and safety risks.In this study,we have developed a simple and safe synthetic route for CL-18.It was synthesized from 3,5-dihaloanisole in a four-step reaction with an overall yield exceeding 60%,surpassing all reported yields in the literature.Subsequently,recrystallization of CL-18 was successfully achieved by carefully selecting appropriate solvents and antisolvents to reduce its mechanical sensitivity.Ultimately,when DMF-ethanol was employed as the recrystallization solvent system,satisfactory product yield(>90%)and reduced mechanical sensitivity(IS=15 J;FS=216 N)were obtained.Additionally,CL-18 is derived from the rearrangement of oxygen atoms on i-CL-18 furoxan,and a comparative analysis of their physicochemical properties was conducted.The thermal stability of both compounds is similar,with onset decomposition temperatures recorded at 186 and 182℃respectively.Similarly,they exhibit 5 s breaking point temperatures of 236 and 237℃.Additionally,we present novel insights into the positional-isomerization-laser-ignition performance of CL-18 and its isomer i-CL-18 using laser irradiation for the first time.Remarkably,our findings demonstrate that i-CL-18 exhibits enhanced laser sensitivity,as it can be directly ignited by a 1064 nm wavelength laser,whereas CL-18 lacks this characteristic.展开更多
A PVA-GAG-COL composite scaffold is fabricated by polyvinyl alcohol （PVA）, glyeosaminoglycan （GAG） and collagen （COL）. Laser surface modification technology is used to make holes on the surface of the scaffolds....A PVA-GAG-COL composite scaffold is fabricated by polyvinyl alcohol （PVA）, glyeosaminoglycan （GAG） and collagen （COL）. Laser surface modification technology is used to make holes on the surface of the scaffolds. Inside and outside interconnection micro-porous structure is obtained. Bioeompatibility test of the scaffolds shows that PVA-GAG-COL scaffold can promote the adhesion and proliferation of the fibroblast. Also, fibroblast can grow normally on the scaffolds with pore diameter from 115 um to 255 um and pore distance from 500 um to 2000 um. PVA-GAG-COL scaffolds possess excellent cell biocompatibility. The porous structure is suitable for cell culture in tissue engineering.展开更多
All-solid-state batteries(ASSBs)with Li or Si anodes promise enhanced safety and high energy densities but face challenges with complex fabrication,stringent storage requirements,and pressure-dependent operation.Polye...All-solid-state batteries(ASSBs)with Li or Si anodes promise enhanced safety and high energy densities but face challenges with complex fabrication,stringent storage requirements,and pressure-dependent operation.Polyethylene oxide(PEO)-based composite solid electrolytes(CSEs)enable easy processing and flexible interfaces,supporting pressure-free operation and reducing costs.However,their low ionic conductivity remains a key limitation.Here,we present a rapid(~5 min)and eco-friendly laser modification strategy for post-synthesized PEO CSEs,achieving enhanced ionic conductivity while retaining the attributes of simple fabrication and compatibility with Li and Si anodes under pressure-free operation.Laser engineering reduces PEO crystallinity,introduces additional Li^(+)coordination sites,and improves interfacial stability through tailored solid electrolyte interphases.The laser-modified electrolyte enables LiFePO_(4)//Li cells to retain 142.4 mAh g^(-1)after 800 cycles with 99.8%Coulombic efficiency at 1 C and 60℃.Moreover,without stack pressure,a Si anode paired with the laser-modified electrolyte delivers a high capacity of 1710.3 mAh g^(-1)with 56%retention at 0.5 A g^(-1)after 50 cycles at 60℃.Beyond performance enhancements,this work establishes a link between fluorescence emission and Li^(+)transport in CSEs.Specifically,fluorescence shifts to shorter wavelengths correspond to shorter molecular chain lengths and lower coordination bonds,supported by time-dependent density functional theory calculations.These factors give rise to improved Li^(+)transport.This optical probe offers a non-destructive approach for rapidly assessing electrolyte properties and enriching electrolyte design.Overall,this work demonstrates laser engineering as a practical post-synthetic strategy and highlights fluorescence as a practical indicator for advancing next-generation ASSBs.展开更多
An integration processing system of three-dimensional laser scanning information visualization in goaf was developed. It is provided with multiple functions, such as laser scanning information management for goaf, clo...An integration processing system of three-dimensional laser scanning information visualization in goaf was developed. It is provided with multiple functions, such as laser scanning information management for goaf, cloud data de-noising optimization, construction, display and operation of three-dimensional model, model editing, profile generation, calculation of goaf volume and roof area, Boolean calculation among models and interaction with the third party soft ware. Concerning this system with a concise interface, plentiful data input/output interfaces, it is featured with high integration, simple and convenient operations of applications. According to practice, in addition to being well-adapted, this system is favorably reliable and stable.展开更多
基金supported by the National Key Laboratory Foundation(No.51461010101JB3501)
文摘The mechanical properties,such as hardness and modulus of elasticity of coatings and the part of thin walls of Ni-based and Co-based alloy prepared by LENS were measured by nanoindentation testing,scanning electron microscopy and energy dispersive spectroscopy were used to analyze their microstructure,the affect of parameters on structure and mechanical properties were studied.The results showed that the mechanical properties were basically identical with the whole coating;the hardness and modulus of elasticity of nanoindentation were evenly distributed in the defect field.The average hardness and modulus of elasticity of coating of Ni-based alloy are 8.29GPa and 235GPa.The average hardness and modulus of elasticity of coating of Co-based alloy are 7.08GPa and 243GPa.The modulus of elasticity of part of thin walls has relationship with the grain orientation.
基金supported by Temporal-spatial manipulation Infrastructure for vector Fields in Optics-Test Facility(TIFO-TF)the National Natural Science Foundation of China(U24A6010,62222513)。
文摘We present a vectorial optical field(VOF) framework that surpasses the diffraction limit in both long-range imaging and energy delivery. By jointly engineering spatial and temporal dimensions, reflective Fourier ptychography is extended to 3.2 km with 0.37× the classical diffraction limit, while a single-photon Li DAR tomography system achieves centimeter-scale, sub-diffraction imaging at 3.3 km using superconducting nanowire single-photon detectors. These advances demonstrate super-resolution, turbulence-resilient imaging over kilometer-range distances. Beyond super-resolution optical, high power VOFs are able to counteract thermal blooming during atmospheric laser propagation, enhancing on-target power density by a factor larger than 2. Together, these results may outline a cross-scale paradigm that links highpower vector-field structuring, single-photon detection, and adaptive control-offering a pathway toward next-generation optical systems that integrate imaging, sensing, communication and directed energy within a common physical framework.
基金Project(51461010101JB3501) supported by National Key Laboratory for High Energy Density Beam Processing Technology Foundation of China
文摘Laser engineered net shaping(LENS) process was investigated using Co-based superalloy powder with a high power continuous wave CO2 laser. Thin wall part with smooth surface was obtained by LENS of layer-by-layer deposition of the powder materials. This thin wall sample was tested for metallographic examinations, micro-hardness, X-ray diffraction and mechanical property test. Microstructural results show that the layers possess rapid solidification microstructural feature, fine dendritic crystal and M7C3-type carbides (essentially chromium-rich carbide) dispersed in theγ(Co,Cr) phase matrix. Dendrite spacing as well as the solidification mode can be controlled through control process parameters. In addition, this microstructural feature of the as-formed Co-base sample leads to an evident hardening and a superior tensile strength and toughness.
基金This work was financially supported by the National Key R&D Program of China(Grant No.2017YFB1103900)National Natural Science Foundation of China(Grant No.11972084)+1 种基金National Science and Technology Major Project(2017-VI-0003-0073)Beijing National Science Foundation(1192014).
文摘In this work,the evolution of melt pool under single-point and single-line printing in the laser engineered net shaping(LENS)process is analyzed.Firstly,the basic structure of the melt pool model of the LENS process is established and the necessary assumptions are made.Then,the establishment process of the multi-physical field model of the melt pool is introduced in detail.It is concluded that the simulation model results are highly consistent with the online measurement experiment results in terms of melt pool profile,space temperature gradient,and time temperature gradient.Meanwhile,some parameters,such as the 3D morphology and surface fluid field of the melt pool,which are not obtained in the online measurement experiment,are analyzed.Finally,the influence of changing the scanning speed on the profile,peak temperature,and temperature gradient of the single-line melt pool is also analyzed,and the following conclusions are obtained:With the increase in scanning speed,the profile of the melt pool gradually becomes slender;The relationship between peak temperature and scanning speed is approximately linear in a certain speed range;The space temperature gradient at the tail of the melt pool under different scanning speeds hardly changes with the scanning speed,and the time temperature gradient at the tail of the melt pool is in direct proportion to the scanning speed.
基金financial support from NSF ExpandQISE program.The synthesis of tellurene was supported by NSF under grant no.CMMI-2046936supports from Purdue Research Foundation.
文摘Tellurene,a chiral chain semiconductor with a narrow bandgap and exceptional strain sensitivity,emerges as a pivotal material for tailoring electronic and optoelectronic properties via strain engineering.This study elucidates the fundamental mechanisms of ultrafast laser shock imprinting(LSI)in two-dimensional tellurium(Te),establishing a direct relationship between strain field orientation,mold topology,and anisotropic structural evolution.This is the first demonstration of ultrafast LSI on chiral chain Te unveiling orientation-sensitive dislocation networks.By applying controlled strain fields parallel or transverse to Te’s helical chains,we uncover two distinct deformation regimes.Strain aligned parallel to the chain’s direction induces gliding and rotation governed by weak interchain interactions,preserving covalent intrachain bonds and vibrational modes.In contrast,transverse strain drives shear-mediated multimodal deformations—tensile stretching,compression,and bending—resulting in significant lattice distortions and electronic property modulation.We discovered the critical role of mold topology on deformation:sharp-edged gratings generate localized shear forces surpassing those from homogeneous strain fields via smooth CD molds,triggering dislocation tangle formation,lattice reorientation,and inhomogeneous plastic deformation.Asymmetrical strain configurations enable localized structural transformations while retaining single-crystal integrity in adjacent regions—a balance essential for functional device integration.These insights position LSI as a precision tool for nanoscale strain engineering,capable of sculpting 2D material morphologies without compromising crystallinity.By bridging ultrafast mechanics with chiral chain material science,this work advances the design of strain-tunable devices for next-generation electronics and optoelectronics,while establishing a universal framework for manipulating anisotropic 2D systems under extreme strain rates.This work discovered crystallographic orientation-dependent deformation mechanisms in 2D Te,linking parallel strain to chain gliding and transverse strain to shear-driven multimodal distortion.It demonstrates mold geometry as a critical lever for strain localization and dislocation dynamics,with sharp-edged gratings enabling unprecedented control over lattice reorientation.Crucially,the identification of strain field conditions that reconcile severe plastic deformation with single-crystal retention offers a pathway to functional nanostructure fabrication,redefining LSI’s potential in ultrafast strain engineering of chiral chain materials.
基金National Natural Science Foundation of China(Grant Nos.62005276,62175234)the Scientific and Technological Development Program of Jilin,China(Grant No.20230508111RC)to provide fund for this research。
文摘Laser anti-drone technology is entering the sequence of actual combat,and it is necessary to consider the vulnerability of typical functional parts of UAVs.Since the concept of"vulnerability"was proposed,a variety of analysis programs for battlefield targets to traditional weapons have been developed,but a comprehensive assessment methodology for targets'vulnerability to laser is still missing.Based on the shotline method,this paper proposes a method that equates laser beam to shotline array,an efficient vulnerability analysis program of target to laser is established by this method,and the program includes the circuit board and the wire into the vulnerability analysis category,which improves the precision of the vulnerability analysis.Taking the UAV engine part as the target of vulnerability analysis,combine with the"life-death unit method"to calculate the laser penetration rate of various materials of the UAV,and the influence of laser weapon system parameters and striking orientation on the killing probability is quantified after introducing the penetration rate into the vulnerability analysis program.The quantitative analysis method proposed in this paper has certain general expansibility,which can provide a fresh idea for the vulnerability analysis of other targets to laser.
文摘The concepts of “confining structure” and structure light are illuminated in this paper.A laser theodolite with three freedoms of rotation,which is aimed at “confining structure”,is developed.Various scanning modes and their mathematical models based on laser theodolite with three freedoms of rotation are discussed.According to the features of a huge object,,the structure light engineering surveying based on laser theodolite with three freedoms of rotation is determined as the main method in an actual application.The observation of four sound concrete posts and forced centering plates.Subsequently,it is transformed into the huge object coordinate system.The scanning mode with plumb plane is selected as the main mode in the whole work.And other assistant methods,such as close range photogrammetry and the method of using reflection sheet,are applied to the work of “scanning dead angle”.At last,a surveying accuracy estimation of this method is done and a surveying accuracy test is finished.It can be concluded that the structure light engineering surveying based on laser theodolite with three freedoms of rotation is considered to be an effective and applied method,and has many superiority to some other surveying methods in the work of surveying “confining structure”.
文摘Purpose: Selective laser sintering (SLS) is a rapid pro- totyping technique applied to produce tissue-engineer- ing scaffolds from powder materials. The standard scanning technique, however, often produces struts of extensive thickness, which means fabrication of high- ly porous scaffolds with small overall dimensions is quite difficult. Nevertheless, this study aims to overcome this shortfall. Design/methodology/approach: To this end, three scanning methods were evaluated in terms of minimum feature size and freedom of design, using a test polyamide (PA) material. Polycaprolactone (PCL) was then employed to create highly porous 3D scaffolds using the preferred scanning me- thod to produce thin struts. Findings: While in normal scanning mode some features were well above the laser spot diameter, strut thicknesses below the laser spot diameter were achieved when using the “outline scan” function for PA material. Those achieved for PCL were slightly higher and in the 500-800 ?m range, with an average pore size of 400 μm. Investigations on the properties of the scaffolds revealed an effective compression modulus of the PCL scaffold of 6.5 MPa. Furthermore, there was no change in physical or che- mical properties when the scaffolds were stored in a physiological environment for 7 weeks. Originality/ value: Though SLS is considered as a fabrication te- chnique for tissue engineering scaffolds, actually pro- duced scaffolds did not comply with porosity requirements and limitations of the SLS process in produ- cing features at the size of the laser beam spot have not been discussed. The present paper shows the capabilities of the SLS process based on two materials and presents a method to minimize feature size in scaffolds.
基金supported by the National Nature1 Science Foundation of China(30170623)the National 863 Program of China(2001AA246013).
文摘MALDI-TOF-MS technology was used for identification of lipopeptide antibiotics producedby GEB3 strain, a derivative of Bacillus subtilis 168 which was transformed by lpaB3gene. The result showed GEB3 only produced lipopeptide antibiotic surfactin. The analysisby LC-MS demonstrated that GEB3 produced standard surfactin isoforms with side chainlengths of 13,14 and 15 carbon atoms. The bioactivity detection of surfactin indicatedthat the surfactin produced by GEB3 had inhibition effect on plant pathogens Rhizoctoniasolani and Pyricularia oryzae.
文摘In this paper,a series of new techniques are used to optimize typical laser scanning sensor.The integrated prototype is compared with traditional approach to demonstrate the much improved performance.In the research and development,camera calibration is achieved by extracting characteristic points of the laser plane,so that the calibra- tion efficiency is improved significantly.With feedback control of its intensity,the laser is automatically adjusted for different material.A modified algorithm is presented to improve the accuracy of laser stripe extraction.The fusion of data extracted from left and right camera is completed with re-sampling technique.The scanner is integrated with a robot arm and some other machinery for on-line measurement and inspection,which provides a flexible measurement tool for reverse engineering.
基金support from the National Natural Science Foundation of China(Grant No.22175160)the Science Challenge Project(Grant No.TZ2018004)。
文摘5-amino-4-nitrobenzo[1,2-c:3,4-c']bis([1,2,5]oxadiazole)1,6-dioxide(CL-18)exhibits significant potential as an initiating explosive.However,its current synthesis process remains non-scalable due to low yields and safety risks.In this study,we have developed a simple and safe synthetic route for CL-18.It was synthesized from 3,5-dihaloanisole in a four-step reaction with an overall yield exceeding 60%,surpassing all reported yields in the literature.Subsequently,recrystallization of CL-18 was successfully achieved by carefully selecting appropriate solvents and antisolvents to reduce its mechanical sensitivity.Ultimately,when DMF-ethanol was employed as the recrystallization solvent system,satisfactory product yield(>90%)and reduced mechanical sensitivity(IS=15 J;FS=216 N)were obtained.Additionally,CL-18 is derived from the rearrangement of oxygen atoms on i-CL-18 furoxan,and a comparative analysis of their physicochemical properties was conducted.The thermal stability of both compounds is similar,with onset decomposition temperatures recorded at 186 and 182℃respectively.Similarly,they exhibit 5 s breaking point temperatures of 236 and 237℃.Additionally,we present novel insights into the positional-isomerization-laser-ignition performance of CL-18 and its isomer i-CL-18 using laser irradiation for the first time.Remarkably,our findings demonstrate that i-CL-18 exhibits enhanced laser sensitivity,as it can be directly ignited by a 1064 nm wavelength laser,whereas CL-18 lacks this characteristic.
基金863 Program grant number: 2077AA09Z436+1 种基金Guangdong Province '211' Fund for Biomaterials and Tissue Engineering grantnumber: 50621030
文摘A PVA-GAG-COL composite scaffold is fabricated by polyvinyl alcohol （PVA）, glyeosaminoglycan （GAG） and collagen （COL）. Laser surface modification technology is used to make holes on the surface of the scaffolds. Inside and outside interconnection micro-porous structure is obtained. Bioeompatibility test of the scaffolds shows that PVA-GAG-COL scaffold can promote the adhesion and proliferation of the fibroblast. Also, fibroblast can grow normally on the scaffolds with pore diameter from 115 um to 255 um and pore distance from 500 um to 2000 um. PVA-GAG-COL scaffolds possess excellent cell biocompatibility. The porous structure is suitable for cell culture in tissue engineering.
基金the generous support from the Singapore MOE-ARC grant(A-8001494-00-00)supported by the Ministry of Education,Singapore,under its Research Centre of Excellence award to the Institute for Functional Intelligent Materials(EDUNC-33-18-279-V12)。
文摘All-solid-state batteries(ASSBs)with Li or Si anodes promise enhanced safety and high energy densities but face challenges with complex fabrication,stringent storage requirements,and pressure-dependent operation.Polyethylene oxide(PEO)-based composite solid electrolytes(CSEs)enable easy processing and flexible interfaces,supporting pressure-free operation and reducing costs.However,their low ionic conductivity remains a key limitation.Here,we present a rapid(~5 min)and eco-friendly laser modification strategy for post-synthesized PEO CSEs,achieving enhanced ionic conductivity while retaining the attributes of simple fabrication and compatibility with Li and Si anodes under pressure-free operation.Laser engineering reduces PEO crystallinity,introduces additional Li^(+)coordination sites,and improves interfacial stability through tailored solid electrolyte interphases.The laser-modified electrolyte enables LiFePO_(4)//Li cells to retain 142.4 mAh g^(-1)after 800 cycles with 99.8%Coulombic efficiency at 1 C and 60℃.Moreover,without stack pressure,a Si anode paired with the laser-modified electrolyte delivers a high capacity of 1710.3 mAh g^(-1)with 56%retention at 0.5 A g^(-1)after 50 cycles at 60℃.Beyond performance enhancements,this work establishes a link between fluorescence emission and Li^(+)transport in CSEs.Specifically,fluorescence shifts to shorter wavelengths correspond to shorter molecular chain lengths and lower coordination bonds,supported by time-dependent density functional theory calculations.These factors give rise to improved Li^(+)transport.This optical probe offers a non-destructive approach for rapidly assessing electrolyte properties and enriching electrolyte design.Overall,this work demonstrates laser engineering as a practical post-synthetic strategy and highlights fluorescence as a practical indicator for advancing next-generation ASSBs.
基金Project(51274250)supported by the National Natural Science Foundation of ChinaProject(2012BAK09B02-05)supported by the National Key Technology R&D Program during the 12th Five-year Plan of China
文摘An integration processing system of three-dimensional laser scanning information visualization in goaf was developed. It is provided with multiple functions, such as laser scanning information management for goaf, cloud data de-noising optimization, construction, display and operation of three-dimensional model, model editing, profile generation, calculation of goaf volume and roof area, Boolean calculation among models and interaction with the third party soft ware. Concerning this system with a concise interface, plentiful data input/output interfaces, it is featured with high integration, simple and convenient operations of applications. According to practice, in addition to being well-adapted, this system is favorably reliable and stable.
