A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5w...A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5wt%Er-1wt%TiB_(2)/Al-Mn-Mg-Sc-Zr nanocomposite were prepared using vacuum homogenization technique,and the density of samples prepared through the LPBF process reached 99.8%.The strengthening and toughening mechanisms of Er-TiB_(2)were investigated.The results show that Al_(3)Er diffraction peaks are detected by X-ray diffraction analysis,and texture strength decreases according to electron backscatter diffraction results.The added Er and TiB_(2)nano-reinforcing phases act as heterogeneous nucleation sites during the LPBF forming process,hindering grain growth and effectively refining the grains.After incorporating the Er-TiB_(2)dual-phase nano-reinforcing phases,the tensile strength and elongation at break of the LPBF-deposited samples reach 550 MPa and 18.7%,which are 13.4%and 26.4%higher than those of the matrix material,respectively.展开更多
To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0....To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0.27%to 0.22%,enabling the elements Mo and Ti to diffuse fully and to distribute more uniformly,and to forming a substantial number of low-angle grain boundaries.The tensile strength soars from 286±32 MPa to 598±22 MPa,while the elongation increases from 0.08%±0.02%to 0.18%±0.02%,without notable alterations in grain morphology during the tensile deformation.HIP treatment eliminates the molten pool boundaries,which are the primary source for premature failure in LPBFed Mo alloys.Consequently,HIP treatment emerges as a novel and effective approach for strengthening the mechanical properties of LPBFed Mo alloys,offering a fresh perspective on producing high-performance Mo-based alloys.展开更多
The characteristics of nonmetallic inclusions formed during steel production have a significant influence on steel performance.In this paper,studies on inclusions using confocal scanning laser microscopy(CSLM)are revi...The characteristics of nonmetallic inclusions formed during steel production have a significant influence on steel performance.In this paper,studies on inclusions using confocal scanning laser microscopy(CSLM)are reviewed and summarized,particularly the col-lision of various inclusions,dissolution of inclusions in liquid slag,and reactions between inclusions and steel.Solid inclusions exhibited a high collision tendency,whereas pure liquid inclusions exhibited minimal collisions because of the small attraction force induced by their<90°contact angle with molten steel.The collision of complex inclusions in molten steel was not included in the scope of this study and should be evaluated in future studies.Higher CaO/Al_(2)O_(3)and CaO/SiO_(2)ratios in liquid slag promoted the dissolution of Al_(2)O_(3)-based in-clusions.The formation of solid phases in the slag should be prevented to improve dissolution of inclusions.To accurately simulate the dissolution of inclusions in liquid slag,in-situ observation of the dissolution of inclusions at the steel-slag interface is necessary.Using a combination of CSLM and scanning electron microscopy-energy dispersive spectroscopy,the composition and morphological evolution of the inclusions during their modification by the dissolved elements in steel were observed and analyzed.Although the in-situ observa-tion of MnS and TiN precipitations has been widely studied,the in-situ observation of the evolution of oxide inclusions in steel during so-lidification and heating processes has rarely been reported.The effects of temperature,heating and cooling rates,and inclusion character-istics on the formation of acicular ferrites(AFs)have been widely studied.At a cooling rate of 3-5 K/s,the order of AF growth rate in-duced by different inclusions,as reported in literature,is Ti-O<Ti-Ca-Zr-Al-O<Mg-O<Ti-Zr-Al-O<Mn-Ti-Al-O<Ti-Al-O<Zr-Ti-Al-O.Further comprehensive experiments are required to investigate the quantitative relationship between the formation of AFs and inclusions.展开更多
The features of additive manufacturing(AM)have made commercially pure titanium(CP-Ti)an attractive candidate material for biomedical implants.However,achieving high strength and ductility is challenging because of the...The features of additive manufacturing(AM)have made commercially pure titanium(CP-Ti)an attractive candidate material for biomedical implants.However,achieving high strength and ductility is challenging because of the columnar structures and fine martensite formation.This study investigated the effect of carbon nanotubes(CNTs)addition on the microstructure and mechanical properties of grade 1 CP-Ti(Gr-1)during the laser powder bed fusion(L-PBF)process.A minute amount of 0.2%mass fraction(wt%)CNTs addition resulted in a high yield strength of approximately 700 MPa and exceptional ductility of 25.7%.Therein,a portion of the CNTs dissolved in the matrix as solute atoms,contributing to solution strengthening,while others were transformed into Ti C_(x)through an in situ reaction with the Ti matrix.Furthermore,the addition of CNTs resulted in the formation of a larger fraction of equiaxed grains and increased the activity of basal and prismatic slip systems.Hence,Gr-1 with CNTs exhibited significantly increased ductility while maintaining a high strength comparable to that of Gr-1 without CNTs.The insights gained from this study provide a novel approach for designing strong and ductile Ti alloys for AM.展开更多
This work investigated the anisotropy tensile properties of Inconel 625 alloy fabricated by laser powder bed fusion (LPBF) under various tests temperature, focusing the anisotropy evolution during the high temperature...This work investigated the anisotropy tensile properties of Inconel 625 alloy fabricated by laser powder bed fusion (LPBF) under various tests temperature, focusing the anisotropy evolution during the high temperature. The microstructure contained columnar grains with (111) texture in the vertical plane (90° sample), while a large equiaxed grain with (100) texture was produced in the horizontal plane (0° sample). As for 45° sample, a large number of equiaxed grains and a few columnar grains with (111) texture can be observed. The sample produced at a 0° orientation demonstrates the highest tensile strength, whereas the 90° sample exhibits the greatest elongation. Conversely, the 45° sample displays the least favorable overall performance. As the tests temperature increased from room temperature to 600℃, the anisotropy rate of ultimate tensile strength, yield strength and ductility between 0° and 45° samples, decreased from 8.98 to 6.96%, 2.36 to 1.28%, 19.93 to 12.23%, as well as between 0° and 90° samples decreased from 4.87 to 4.03%, 11.88 to 7.21% and 14.11 to 6.89%, respectively, because of the recovery of oriented columnar grains.展开更多
Laser additively manufactured(LAM)Ni-based superalloys commonly exhibit low strength and high residual stress in the as-built state,requiring post-heat treatment to improve mechanical properties.We propose a modified ...Laser additively manufactured(LAM)Ni-based superalloys commonly exhibit low strength and high residual stress in the as-built state,requiring post-heat treatment to improve mechanical properties.We propose a modified heat treatment(MHT)process that only involves a single-step aging at 650℃ for 4 h to achieve high strength,high ductility,and low residual stress simultaneously in a laser powder bed fusion(LPBF)-processed Inconel 718(IN718)alloy.The MHT treated alloy exhibits comparable tensile strength(1368 MPa)to the conventional solution plus two-step aging(SA)treated alloy(1398 MPa),while the tensile elongation(∼21.7%for MHT treated alloy and 13.4%for SA treated alloy)is 60%higher and the residual stress(∼195 MPa)is 20%lower than the SA treated alloy.The balanced high performance of the MHT IN718 alloy was mainly attributed to the precipitation of abundantγ’’phase with a size of∼5 nm,while the original nano-sized Laves precipitates and dislocation cells were mostly retained.The finer size and higher fraction ofγ”of the MHT sample mainly result from the dislocation structure and compositional variations in the as-built IN718,which promotes precipitation during aging.The retention of Laves phase,and cellular dislocation network in the MHT alloy also contributes to work hardening during tension and suspends the occurrence of necking.This study unveils a unique strengthening and toughening mechanism in the Ni-based superalloy produced by LAM with the presence of abundant Laves precipitates and provides a simple,low energy-consumption and cost-effective heat treatment route for achieving desirable mechanical properties.展开更多
To fully utilize the functionality of shape memory alloys(SMAs),laser powder bed fusion(LPBF)has gradually become the most dominant preparation method for NiTi SMAs owing to its high geometric adaptability.However,due...To fully utilize the functionality of shape memory alloys(SMAs),laser powder bed fusion(LPBF)has gradually become the most dominant preparation method for NiTi SMAs owing to its high geometric adaptability.However,due to the unique microstructure of LPBF parts,the shape memory effect(SME)of SMAs prepared by this method is significantly lower than that of other preparation processes.Improving SME has become a recognized difficult problem.This study investigates that dislocation slip and stable martensite during deformation are the main causes of irreversible strain.Furthermore,for the first time,it was found that the hindering effect of nanoprecipitates relative to dislocation movement in LPBF NiTi SMAs can inhibit the formation of slip bands.This hinders the formation of stable martensite and significantly improves SME(with a maximum tensile strength of 922 MPa,maximum elongation of 10.18%,and recoverable strain of 6.8%after applying 8%strain).These results provide a theoretical basis for enhancing the SME of LPBF-SMAs and offer the possibility for preparing NiTi SMAs smart actuators.展开更多
Control of the columnar to equiaxed transition(CET)is a major challenge in additively manufacturedβtitanium alloys.In this work,the promotion of CET was successfully achieved through in-situ fabrication of Ti-5Cu(wt....Control of the columnar to equiaxed transition(CET)is a major challenge in additively manufacturedβtitanium alloys.In this work,the promotion of CET was successfully achieved through in-situ fabrication of Ti-5Cu(wt.%)alloys with additions of 5,15,and 25 wt.%Nb using elemental Ti,Cu,and Nb powders by employing laser powder bed fusion(LPBF).The alloy containing 5 wt.%Nb consisted ofαlamellae,Ti2 Cu precipitates,and unmeltedβ-Nb inclusions,whereas the 25 wt.%Nb alloy consisted of equiaxedβgrains,ωprecipitates,and Ti2 Cu precipitates at the grain boundaries.In terms of mechanical proper-ties,despite the presence of Nb inclusions and liquation cracks in the 5 wt.%Nb alloy,it showed a yield strength of 1051±40 MPa and an elongation of 5.2%±1.3%.Both the strength and ductility decreased with increasing Nb content,e.g.,the 25 wt.%Nb alloy exhibited a yield strength of 808±53 MPa and an elongation of 1.6%±0.2%.As the Nb content increased from 5 to 25 wt.%,the Young’s modulus decreased from 110 to 65 GPa.The 25 wt.%Nb alloy showed a high ratio of hardness to Young’s mod-ulus(H/E)and yield pressure(H3/E2).However,due to its brittle nature,the material manifested high wear rates.These findings provide a basis for the future development of novel low-modulus isotropicβ-titanium alloys using LPBF.展开更多
Additive manufacturing (AM) of high-strength metallic alloys frequently encounters detrimental distortion and cracking, attributed to the accumulation of thermal stresses. These issues significantly impede the practic...Additive manufacturing (AM) of high-strength metallic alloys frequently encounters detrimental distortion and cracking, attributed to the accumulation of thermal stresses. These issues significantly impede the practical application of as-printed components. This study examines the Mg-15Gd-1Zn-0.4Zr (GZ151K, wt.%) alloy, a prototypical high-strength casting Mg-RE alloy, fabricated through laser powder bed fusion (LPBF). Despite achieving ultra-high strength, the GZ151K alloy concurrently exhibits a pronounced cold-cracking susceptibility. The as-printed GZ151K alloy consists of almost fully fine equiaxed grains with an average grain size of merely 2.87 µm. Subsequent direct aging (T5) heat treatment induces the formation of dense prismatic β' precipitates. Consequently, the LPBF-T5 GZ151K alloy manifests an ultra-high yield strength of 405 MPa, surpassing all previously reported yield strengths for Mg alloys fabricated via LPBF and even exceeding that of its extrusion-T5 counterpart. Interestingly, as-printed GZ151K samples with a build height of 2 mm exhibit no cracking, whereas samples with build heights ranging from 4 to 18 mm demonstrate severe cold cracking. Thermal stress simulation also suggests that the cold cracking susceptibility increases significantly with increasing build height. The combination of high thermal stress and low ductility in the as-printed GZ151K alloy culminates in a high cold cracking susceptibility. This study offers novel insights into the intricate issue of cold cracking in the LPBF process of high-strength Mg alloys, highlighting the critical balance between achieving high strength and mitigating cold cracking susceptibility.展开更多
To increase the strength of the laser powder-bed fusion (LPBF) Al-Si-based aluminum alloy, TiB_(2) ceramic particles were selected to be mixed with high-Mg content Al-Si-Mg-Zr powder, and then a novel TiB_(2)/Al-Si-Mg...To increase the strength of the laser powder-bed fusion (LPBF) Al-Si-based aluminum alloy, TiB_(2) ceramic particles were selected to be mixed with high-Mg content Al-Si-Mg-Zr powder, and then a novel TiB_(2)/Al-Si-Mg-Zr composite was fabricated using LPBF. The results indicated that a dense sample with a maximum relative density of 99.85% could be obtained by adjusting the LPBF process parameters. Incorporating TiB_(2) nanoparticles enhanced the powder's laser absorption rate, thereby raising the alloy's intrinsic heat treatment temperature and consequently facilitating the precipitation of Si and βʺ nanoparticles in the α-Al cells. Moreover, the rapid cooling process during LPBF resulted in numerous alloying elements with low-stacking fault energy dissolving in the α-Al matrix, thus promoting the formation of the 9R phase. After a 48 h direct aging treatment at 150℃, the strength of the alloy slightly increased due to the increase of nanoprecipitates. Both yield strength and ultimate tensile strength of the LPBF TiB_(2)/Al-Si-Mg-Zr alloy were significantly higher than that of other LPBF TiB_(2)-modified aluminum alloys with external addition.展开更多
Two-plasmon-decay instability(TPD)poses a critical target preheating risk in direct-drive inertial confinement fusion.In this paper,TPD collectively driven by dual laser beams consisting of a normal-incidence laser be...Two-plasmon-decay instability(TPD)poses a critical target preheating risk in direct-drive inertial confinement fusion.In this paper,TPD collectively driven by dual laser beams consisting of a normal-incidence laser beam(Beam-N)and a large-angle-incidence laser beam(Beam-L)is investigated via particle-in-cell simulations.It is found that significant TPD growth can develop in this regime at previously unexpected low laser intensities if the intensity of Beam-L exceeds the large-angle-incidence threshold.Both beams contribute to the growth of TPD in a“seed-amplification”manner in which the absolute instability driven by Beam-L provides the seeds that are convectively amplified by Beam-N,making TPD energetically important and causing significant pump depletion and hot-electron generation.展开更多
Driving of the nuclear fusion reaction p+^(11)B3α+8.7 MeV under laboratory conditions by interaction between high-power laser pulses and matter has become a popular field of research,owing to its numerous potential a...Driving of the nuclear fusion reaction p+^(11)B3α+8.7 MeV under laboratory conditions by interaction between high-power laser pulses and matter has become a popular field of research,owing to its numerous potential applications:as an alternative to deuterium-tritium for fusion energy production,astrophysics studies,and alpha-particle generation for medical treatment.One possible scheme for laser-driven p-^(11)B reactions is to direct a beam of laser-accelerated protons onto a boron(B)sample(the so-called“pitcher-catcher”scheme).This technique has been successfully implemented on large high-energy lasers,yielding hundreds of joules per shot at low repetition.We present here a complementary approach,exploiting the high repetition rate of the VEGA III petawatt laser at CLPU(Spain),aiming at accumulating results from many interactions at much lower energy,to provide better control of the parameters and the statistics of the measurements.Despite a moderate energy per pulse,our experiment allowed exploration of the laser-driven fusion process with tens(up to hundreds)of laser shots.The experiment provided a clear signature of the reactions involved and of the fusion products,accumulated over many shots,leading to an improved optimization of the diagnostics for experimental campaigns of this type.In this paper,we discuss the effectiveness of laser-driven p-11B fusion in the pitcher-catcher scheme,at a high repetition rate,addressing the challenges of this experimental scheme and highlighting its critical aspects.Our proposed methodology allows evaluation of the performance of this scheme for laser-driven alpha particle production and can be adapted to high-repetition-rate laser facilities with higher energy and intensity.展开更多
Laser powder bed fusion(LPBF)additive manufacturing of zinc(Zn)offers promising advantages for biodegradable metal bone implants,including tailorable microstructures,controllable porous structures,and appropriate degr...Laser powder bed fusion(LPBF)additive manufacturing of zinc(Zn)offers promising advantages for biodegradable metal bone implants,including tailorable microstructures,controllable porous structures,and appropriate degradation rates.However,the layer-by-layer construction during LPBF often leads to microstructural and performance anisotropy within metallic materials.In this work,the anisotropic mechanical and degradation properties of pure Zn processed using LPBF were comprehensively investigated for the first time.Specifically,the influence of microstructural characteristics on the mechanical and degradation properties of LPBF-processed Zn in both horizontal and vertical planes was revealed,while the underlying deformation mechanisms in different planes were illustrated.The results demonstrated that the horizontal plane exhibited higher mechanical strength compared to the vertical plane,with ulti-mate tensile strength of 123.6 and 107.86 MPa,respectively,significantly surpassing that of the tradition-ally cast counterpart(52.7 MPa).Importantly,abundant deformation twins coupled with infrequent microbands and pyramidal(c+a)slip systems activated during tensile loading along the vertical plane enabled multiple deformation modes,which sustained durable work hardening ability while delaying plastic instability,resulting in extraordinary plasticity(elongation of 14.2%).Additionally,synergistic effects between high-density grain boundaries including low-angle grain boundaries and pre-existing dislocations promoted the stable presence of a passive film along the horizontal plane,thus exhibiting relatively low corrosion sensitivity.Furthermore,the LPBF-processed Zn also demonstrated favorable biological activity and osteogenic potential.These findings provide valuable insights into multiple mechanisms underlying anisotropy in mechanical and degradation properties of laser additively manufactured Zn-based materials.展开更多
Laser powder bed fusion(LPBF)is a widely used and well-developed approach in additive manufacturing.To meet the high material performance requirements of fourth-generation nuclear power reactors,the combination of LPB...Laser powder bed fusion(LPBF)is a widely used and well-developed approach in additive manufacturing.To meet the high material performance requirements of fourth-generation nuclear power reactors,the combination of LPBF processing with oxide dispersion strengthening(ODS)is currently of interest for the design and development of new materials.In this approach,nanoscale Y_(2)O_(3)particles are dispersed into the feeding powders to produce LPBF-ODS materials.Oxygen exposure and the introduction of oxygen into the solvation cell during LPBF are usually considered as detrimental processes that are impossible to eliminate completely.However,our understanding of these unavoidable processes is still limited.In this study,we developed a new LPBF-ODS design approach based on in situ oxygen content regulation during the LPBF process.The oxygen content of the environmental chamber was artificially adjusted using an online monitoring system to activate reactions between oxygen and the metallic elements for the in situ formation of dispersed oxide particles.Four batches of LPBF 304 L stainless steel samples were successfully processed under different oxygen levels to investigate the reinforcement effect of in situ chemical alloying.The results show that dispersed oxide particles were formed with an average nanoscale size of approximately 46 nm through the LPBF in situ alloying approach.The increase in the number density of oxide particles to 11.4 particles∕μm^(2)as the oxygen content increased played a role in refining and stabilizing the cellular structure.The yield strength of the in situ alloyed ODS material was enhanced(to up to~675 MPa)while its ductility was not significantly degraded(elongation of up to~39%).These tensile properties are competitive within the ranges reported for ODS alloys prepared by mechanical alloying.The main mechanisms for yield strength enhancement through interactions between nanoscale oxide particles and dislocation entanglement cells were analyzed.This study provides a new approach for the future preparation of high-performance LPBF-ODS alloys.展开更多
This study presents new methods to effectively model the anisotropic yielding and hardening behavior of laser powder bed fusion fabricated aluminum alloy under both monotonic and cyclic loading conditions.The proposed...This study presents new methods to effectively model the anisotropic yielding and hardening behavior of laser powder bed fusion fabricated aluminum alloy under both monotonic and cyclic loading conditions.The proposed model combines the yield surface-interpolation method to accurately describe the anisotropic hardening rates in various directions,with the Chaboche kinematic hardening rule to precisely reflect the cyclic characteristics.For numerical implementation of the combined anisotropic and cyclic constitutive model,a fully implicit stress integration algorithm based on return mapping method is provided.Moreover,the multiple parameters associated with the model are categorized and identified in an uncoupled manner.The isotropic and cyclic hardening parameters are determined by an inverse method,and the stability of the optimization outcomes is validated by applying different starting points for the parameters.Particularly,the back-stress effect on the identification of anisotropic parameters associated with the stress invariant-based Hill48 yield function is considered for the first time.This consideration leads to an improved prediction accuracy compared to the identification of anisotropic parameters without considering back-stress effect.The combined anisotropic and cyclic constitutive model,along with the calibrated parameters,are proven capable of accurately reproducing the intricate deformation behavior of laser powder bed fusion fabricated AlSi10Mg.展开更多
After millions of years of natural evolution,horsetails have evolved unique stem structures that enable survival in harsh environments.Inspired by the cross-sectional characteristics of horsetail stems,a series of bio...After millions of years of natural evolution,horsetails have evolved unique stem structures that enable survival in harsh environments.Inspired by the cross-sectional characteristics of horsetail stems,a series of bioinspired sandwich structures were designed and fabricated using the laser powder bed fusion(LPBF)process.By combining experimental and finite element simulation methods,the formability,mechanical properties,deformation behavior,and thermal conduction performance of these structures were determined.Results show that the surface morphology of the bioinspired sandwich structures was smooth,with no cracks observed.The bioinspired sandwich structure with an inner tube diameter of 1.9 mm(D_(1.9))exhibited optimal comprehensive mechanical properties,with a specific strength of 64.2 MPa/(g/cm^(3)),and specific energy absorption of 3.3 J/g.Stress distribution results revealed that the D_(1.9)structures had the most uniform stress distribution.Furthermore,increasing the internal conduction paths improved heat transfer;therefore,the thermal conductivities of the D_(1.4),D_(1.9),and D_(2.4)structures were higher than that of the D0 structure.This study demonstrates that a bioinspired design approach,combined with additive manufacturing technology,enables the development of high-performance structures with both load-bearing and thermally insulating capabilities.展开更多
Transpiration cooling is crucial for the performance of aerospace engine components,relying heavily on the processing quality and accuracy of microchannels.Laser powder bed fusion(LPBF)offers the potential for integra...Transpiration cooling is crucial for the performance of aerospace engine components,relying heavily on the processing quality and accuracy of microchannels.Laser powder bed fusion(LPBF)offers the potential for integrated manufacturing of complex parts and precise microchannel fabrication,essential for engine cooling applications.However,optimizing LPBF’s extensive process parameters to control processing quality and microchannel accuracy effectively remains a significant challenge,especially given the time-consuming and labor-intensive nature of handling numerous variables and the need for thorough data analysis and correlation discovery.This study introduced a combined methodology of high-throughput experiments and Gaussian process algorithms to optimize the processing quality and accuracy of nickel-based high-temperature alloy with microchannel structures.250 parameter combinations,including laser power,scanning speed,channel diameter,and spot compensation,were designed across ten high-throughput specimens.This setup allowed for rapid and efficient evaluation of processing quality and microchannel accuracy.Employing Bayesian optimization,the Gaussian process model accurately predicted processing outcomes over a broad parameter range.The correlation between various processing parameters,processing quality and accuracy was revealed,and various optimized process combinations were summarized.Verification through computed Tomography testing of the specimens confirmed the effectiveness and precision of this approach.The approach introduced in this research provides a way for quickly and efficiently optimizing the process parameters and establishing process-property relationships for LPBF,which has broad application value.展开更多
The GH3536(Hastelloy-X)nickel-based superalloy is increasingly applied in the aerospace industry due to its exceptional combination of excellent oxidation resistance and high-temperature strength.Laser powder bed fusi...The GH3536(Hastelloy-X)nickel-based superalloy is increasingly applied in the aerospace industry due to its exceptional combination of excellent oxidation resistance and high-temperature strength.Laser powder bed fusion(LPBF)is an additive manufacturing(AM)technology for producing metallic components with complex shapes using layer-by-layer manufacture principle.The debate has long prevailed as to research on eliminating anisotropy in the forming of GH3536 alloy through LPBF technology.In this study,the anisotropy of microstructure and mechanical properties of GH3536 alloy formed by LPBF was investigated using different scanning strategies(0°,90°,67°,checkerboard,and contour).The scanning strategy was optimized to reduce the weaving differences between the horizontal and vertical directions of the microstructure of the LPBF formed GH3536 alloy,which in turn reduces the anisotropy of the properties in both directions.The results of the tensile specimens indicate that except for the horizontal specimens produced using the contour scanning strategy,the strength of all other specimens exceeds that of the vertical specimens.Additionally,differences in elongation are observed,demonstrating that the GH3536 alloy fabricated via laser powder bed fusion exhibits anisotropic properties.According to electron backscatter diffraction(EBSD)analysis,the grain boundary strengthening and geometrically necessary dislocations(GNDs)impede dislocation motion during tensile deformation along the horizontal direction.Consequently,this mechanism negatively affects both the tensile strength and ductility in that orientation.The anisotropy in tensile strength and plasticity is attributed to the different crack sensitivities in the two tensile directions.In addition,specimens molded using different scanning strategies exhibit varying degrees of anisotropy,strength,and elongation due to different degrees of texture strengthening,grain boundary strengthening,and dislocation strengthening effects.Regardless of the stretching direction,the combined tensile properties of the 0°and contoured specimens are the worst under the room temperature and 815℃ stretching conditions.The 67°specimens exhibit the best combined tensile properties.Therefore,the anisotropy of the mechanical properties of the LPBF formed GH3536 alloy can be positively mitigated by modulating the scanning strategy.展开更多
Laser powder-bed fusion(LPBF)of Zn-0.8Cu(wt.%)alloys exhibits significant advantages in the customization of biodegradable bone implants.However,the formability of LPBFed Zn alloy is not sufficient due to the spheroid...Laser powder-bed fusion(LPBF)of Zn-0.8Cu(wt.%)alloys exhibits significant advantages in the customization of biodegradable bone implants.However,the formability of LPBFed Zn alloy is not sufficient due to the spheroidization during the interaction of powder and laser beam,of which the mechanism is still not well understood.In this study,the evolution of morphology and grain structure of the LPBFed Zn-Cu alloy was investigated based on single-track deposition experiments.As the scanning speed increases,the grain structure of a single track of Zn-Cu alloy gradually refines,but the formability deteriorates,leading to the defect’s formation in the subsequent fabrication.The Zn-Cu alloys fabricated by optimum processing parameters exhibit a tensile strength of 157.13 MPa,yield strength of 106.48 MPa and elongation of 14.7%.This work provides a comprehensive understanding of the processing optimization of Zn-Cu alloy,achieving LPBFed Zn-Cu alloy with high density and excellent mechanical properties.展开更多
High-temperature confocal scanning laser microscopy(HT-CSLM)is a potent methodology for investigating various phenomena in the field of metallurgy.Initially applied to the observation of solid phase transformations an...High-temperature confocal scanning laser microscopy(HT-CSLM)is a potent methodology for investigating various phenomena in the field of metallurgy.Initially applied to the observation of solid phase transformations and solidification,this method has gained traction in the field of non-metallic inclusion in steels in recent years.An overview of the experimental capabilities of HT-CSLM and the most important results of recent investigations regarding the topics of clean steel production are provided.It includes the formation of intragranular acicular ferrite(IAF)from the surface of non-metallic inclusions during the continuous cooling and heat treatment,which can be especially beneficial in the toughness of heat-affected zones of welded pieces.Furthermore,the investigation of agglomeration mechanisms of non-metallic inclusions(NMIs)in liquid steel is discussed to improve the insight into attraction forces between particles and clogging phenomena during continuous casting.Also,the dissolution of NMIs in various steelmaking slags can be observed by HT-CSLM to compare dissolution rates and mechanisms of NMI,where significant influences of temperature and chemical composition of the slag were shown.Last but not least,the experimental work regarding the interface between steel and slag is discussed,where novel techniques are currently being developed.A comprehensive summary of experimental techniques using HT-CSLM equipment to investigate different interactions of NMIs with steel and slag phases is compiled.展开更多
基金Shaanxi Province Qin Chuangyuan“Scientist+Engineer”Team Construction Project(2022KXJ-071)2022 Qin Chuangyuan Achievement Transformation Incubation Capacity Improvement Project(2022JH-ZHFHTS-0012)+8 种基金Shaanxi Province Key Research and Development Plan-“Two Chains”Integration Key Project-Qin Chuangyuan General Window Industrial Cluster Project(2023QCY-LL-02)Xixian New Area Science and Technology Plan(2022-YXYJ-003,2022-XXCY-010)2024 Scientific Research Project of Shaanxi National Defense Industry Vocational and Technical College(Gfy24-07)Shaanxi Vocational and Technical Education Association 2024 Vocational Education Teaching Reform Research Topic(2024SZX354)National Natural Science Foundation of China(U24A20115)2024 Shaanxi Provincial Education Department Service Local Special Scientific Research Program Project-Industrialization Cultivation Project(24JC005,24JC063)Shaanxi Province“14th Five-Year Plan”Education Science Plan,2024 Project(SGH24Y3181)National Key Research and Development Program of China(2023YFB4606400)Longmen Laboratory Frontier Exploration Topics Project(LMQYTSKT003)。
文摘A dual-phase synergistic enhancement method was adopted to strengthen the Al-Mn-Mg-Sc-Zr alloy fabricated by laser powder bed fusion(LPBF)by leveraging the unique advantages of Er and TiB_(2).Spherical powders of 0.5wt%Er-1wt%TiB_(2)/Al-Mn-Mg-Sc-Zr nanocomposite were prepared using vacuum homogenization technique,and the density of samples prepared through the LPBF process reached 99.8%.The strengthening and toughening mechanisms of Er-TiB_(2)were investigated.The results show that Al_(3)Er diffraction peaks are detected by X-ray diffraction analysis,and texture strength decreases according to electron backscatter diffraction results.The added Er and TiB_(2)nano-reinforcing phases act as heterogeneous nucleation sites during the LPBF forming process,hindering grain growth and effectively refining the grains.After incorporating the Er-TiB_(2)dual-phase nano-reinforcing phases,the tensile strength and elongation at break of the LPBF-deposited samples reach 550 MPa and 18.7%,which are 13.4%and 26.4%higher than those of the matrix material,respectively.
基金National Natural Science Foundation of China(52105385)Stable Support Plan Program of Shenzhen Natural Science Fund(20220810132537001)+2 种基金Guangdong Basic and Applied Basic Research Foundation(2022A1515010781)Joint Fund of Henan Province Science and Technology R&D Program(225200810002)Fundamental Research Funds of Henan Academy of Sciences(240621041)。
文摘To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0.27%to 0.22%,enabling the elements Mo and Ti to diffuse fully and to distribute more uniformly,and to forming a substantial number of low-angle grain boundaries.The tensile strength soars from 286±32 MPa to 598±22 MPa,while the elongation increases from 0.08%±0.02%to 0.18%±0.02%,without notable alterations in grain morphology during the tensile deformation.HIP treatment eliminates the molten pool boundaries,which are the primary source for premature failure in LPBFed Mo alloys.Consequently,HIP treatment emerges as a novel and effective approach for strengthening the mechanical properties of LPBFed Mo alloys,offering a fresh perspective on producing high-performance Mo-based alloys.
基金supported by the National Key R&D Program(No.2023YFB3709900)the National Nature Science Foundation of China(No.U22A20171)+2 种基金China Baowu Low Carbon Metallurgy Innovation Foundation(No.BWLCF202315)the High Steel Center(HSC)at North China University of TechnologyUniversity of Science and Technology Beijing,China.
文摘The characteristics of nonmetallic inclusions formed during steel production have a significant influence on steel performance.In this paper,studies on inclusions using confocal scanning laser microscopy(CSLM)are reviewed and summarized,particularly the col-lision of various inclusions,dissolution of inclusions in liquid slag,and reactions between inclusions and steel.Solid inclusions exhibited a high collision tendency,whereas pure liquid inclusions exhibited minimal collisions because of the small attraction force induced by their<90°contact angle with molten steel.The collision of complex inclusions in molten steel was not included in the scope of this study and should be evaluated in future studies.Higher CaO/Al_(2)O_(3)and CaO/SiO_(2)ratios in liquid slag promoted the dissolution of Al_(2)O_(3)-based in-clusions.The formation of solid phases in the slag should be prevented to improve dissolution of inclusions.To accurately simulate the dissolution of inclusions in liquid slag,in-situ observation of the dissolution of inclusions at the steel-slag interface is necessary.Using a combination of CSLM and scanning electron microscopy-energy dispersive spectroscopy,the composition and morphological evolution of the inclusions during their modification by the dissolved elements in steel were observed and analyzed.Although the in-situ observa-tion of MnS and TiN precipitations has been widely studied,the in-situ observation of the evolution of oxide inclusions in steel during so-lidification and heating processes has rarely been reported.The effects of temperature,heating and cooling rates,and inclusion character-istics on the formation of acicular ferrites(AFs)have been widely studied.At a cooling rate of 3-5 K/s,the order of AF growth rate in-duced by different inclusions,as reported in literature,is Ti-O<Ti-Ca-Zr-Al-O<Mg-O<Ti-Zr-Al-O<Mn-Ti-Al-O<Ti-Al-O<Zr-Ti-Al-O.Further comprehensive experiments are required to investigate the quantitative relationship between the formation of AFs and inclusions.
基金financially supported by the National Key Research and Development Project of the Ministry of Science and Technology of China(No.2022YFB4601000)the Fundamental Research Funds for the Central Universities(No.2042023kf0103)the Ministry of Trade,Industry and Energy,Korea(No.20013095)。
文摘The features of additive manufacturing(AM)have made commercially pure titanium(CP-Ti)an attractive candidate material for biomedical implants.However,achieving high strength and ductility is challenging because of the columnar structures and fine martensite formation.This study investigated the effect of carbon nanotubes(CNTs)addition on the microstructure and mechanical properties of grade 1 CP-Ti(Gr-1)during the laser powder bed fusion(L-PBF)process.A minute amount of 0.2%mass fraction(wt%)CNTs addition resulted in a high yield strength of approximately 700 MPa and exceptional ductility of 25.7%.Therein,a portion of the CNTs dissolved in the matrix as solute atoms,contributing to solution strengthening,while others were transformed into Ti C_(x)through an in situ reaction with the Ti matrix.Furthermore,the addition of CNTs resulted in the formation of a larger fraction of equiaxed grains and increased the activity of basal and prismatic slip systems.Hence,Gr-1 with CNTs exhibited significantly increased ductility while maintaining a high strength comparable to that of Gr-1 without CNTs.The insights gained from this study provide a novel approach for designing strong and ductile Ti alloys for AM.
基金supported by the National Natural Science Foundation of China(Grant Nos.52205140,52175129)the Outstanding Youth Foundation of Hunan Province(Grant No.2023JJ20041)the Science and Technology Innovation Program of Hunan Province(2023RC3241).
文摘This work investigated the anisotropy tensile properties of Inconel 625 alloy fabricated by laser powder bed fusion (LPBF) under various tests temperature, focusing the anisotropy evolution during the high temperature. The microstructure contained columnar grains with (111) texture in the vertical plane (90° sample), while a large equiaxed grain with (100) texture was produced in the horizontal plane (0° sample). As for 45° sample, a large number of equiaxed grains and a few columnar grains with (111) texture can be observed. The sample produced at a 0° orientation demonstrates the highest tensile strength, whereas the 90° sample exhibits the greatest elongation. Conversely, the 45° sample displays the least favorable overall performance. As the tests temperature increased from room temperature to 600℃, the anisotropy rate of ultimate tensile strength, yield strength and ductility between 0° and 45° samples, decreased from 8.98 to 6.96%, 2.36 to 1.28%, 19.93 to 12.23%, as well as between 0° and 90° samples decreased from 4.87 to 4.03%, 11.88 to 7.21% and 14.11 to 6.89%, respectively, because of the recovery of oriented columnar grains.
基金financially supported by the Ministry of Science and Technology of China via the National Key Research&Development Plan(Nos.2022YFB3707105 and 2020YFA0405900)Jiangsu Department of Science and Technology via Provincial Key Research&Development(Industrial Foresight and Key Core Technology,No.BE2021037)+1 种基金Department of the National Science Foundation of China(No.52204390)the Natural Science Foundation of Jiangsu Province(No.BK20202010).
文摘Laser additively manufactured(LAM)Ni-based superalloys commonly exhibit low strength and high residual stress in the as-built state,requiring post-heat treatment to improve mechanical properties.We propose a modified heat treatment(MHT)process that only involves a single-step aging at 650℃ for 4 h to achieve high strength,high ductility,and low residual stress simultaneously in a laser powder bed fusion(LPBF)-processed Inconel 718(IN718)alloy.The MHT treated alloy exhibits comparable tensile strength(1368 MPa)to the conventional solution plus two-step aging(SA)treated alloy(1398 MPa),while the tensile elongation(∼21.7%for MHT treated alloy and 13.4%for SA treated alloy)is 60%higher and the residual stress(∼195 MPa)is 20%lower than the SA treated alloy.The balanced high performance of the MHT IN718 alloy was mainly attributed to the precipitation of abundantγ’’phase with a size of∼5 nm,while the original nano-sized Laves precipitates and dislocation cells were mostly retained.The finer size and higher fraction ofγ”of the MHT sample mainly result from the dislocation structure and compositional variations in the as-built IN718,which promotes precipitation during aging.The retention of Laves phase,and cellular dislocation network in the MHT alloy also contributes to work hardening during tension and suspends the occurrence of necking.This study unveils a unique strengthening and toughening mechanism in the Ni-based superalloy produced by LAM with the presence of abundant Laves precipitates and provides a simple,low energy-consumption and cost-effective heat treatment route for achieving desirable mechanical properties.
基金financially supported by the National Natural Science Foundation of China(No.52275365).
文摘To fully utilize the functionality of shape memory alloys(SMAs),laser powder bed fusion(LPBF)has gradually become the most dominant preparation method for NiTi SMAs owing to its high geometric adaptability.However,due to the unique microstructure of LPBF parts,the shape memory effect(SME)of SMAs prepared by this method is significantly lower than that of other preparation processes.Improving SME has become a recognized difficult problem.This study investigates that dislocation slip and stable martensite during deformation are the main causes of irreversible strain.Furthermore,for the first time,it was found that the hindering effect of nanoprecipitates relative to dislocation movement in LPBF NiTi SMAs can inhibit the formation of slip bands.This hinders the formation of stable martensite and significantly improves SME(with a maximum tensile strength of 922 MPa,maximum elongation of 10.18%,and recoverable strain of 6.8%after applying 8%strain).These results provide a theoretical basis for enhancing the SME of LPBF-SMAs and offer the possibility for preparing NiTi SMAs smart actuators.
基金the National Natural Science Foun-dation of China(Grant Nos.12374022,U23A20540)the Natu-ral Science Foundation of Hunan Province for Distinguished Young Scholars(Grant No.2023JJ10075)+3 种基金the China Postdoctoral Science Foundation(Grant Nos.GZC20241335,2024MD753962)the YueLuShan Center Industrial Innovation(Grant No.2024YCII0106)the Scientific and Technological Project of Yunnan Precious Met-als Laboratory(Grant No.YPML-2023050247)the Central South University Research Programme of Advanced Interdisci-plinary Studies(Grant No.2023QYJC039).
文摘Control of the columnar to equiaxed transition(CET)is a major challenge in additively manufacturedβtitanium alloys.In this work,the promotion of CET was successfully achieved through in-situ fabrication of Ti-5Cu(wt.%)alloys with additions of 5,15,and 25 wt.%Nb using elemental Ti,Cu,and Nb powders by employing laser powder bed fusion(LPBF).The alloy containing 5 wt.%Nb consisted ofαlamellae,Ti2 Cu precipitates,and unmeltedβ-Nb inclusions,whereas the 25 wt.%Nb alloy consisted of equiaxedβgrains,ωprecipitates,and Ti2 Cu precipitates at the grain boundaries.In terms of mechanical proper-ties,despite the presence of Nb inclusions and liquation cracks in the 5 wt.%Nb alloy,it showed a yield strength of 1051±40 MPa and an elongation of 5.2%±1.3%.Both the strength and ductility decreased with increasing Nb content,e.g.,the 25 wt.%Nb alloy exhibited a yield strength of 808±53 MPa and an elongation of 1.6%±0.2%.As the Nb content increased from 5 to 25 wt.%,the Young’s modulus decreased from 110 to 65 GPa.The 25 wt.%Nb alloy showed a high ratio of hardness to Young’s mod-ulus(H/E)and yield pressure(H3/E2).However,due to its brittle nature,the material manifested high wear rates.These findings provide a basis for the future development of novel low-modulus isotropicβ-titanium alloys using LPBF.
基金supported by the National Key Research and Development Program of China(No.2021YFB3701000)the National Natural Science Foundation of China(Nos.51971130,52201129,U21A2047,51821001,U2037601)+2 种基金support by the China Postdoctoral Science Foun-dation(2023M742219)the Postdoctoral Fellowship Program of CPSF under Grant Number GZB20240419support by the Ministry of Education,Singapore,under its Academic Research Fund Tier 2(MOE-T2EP50221-0013).
文摘Additive manufacturing (AM) of high-strength metallic alloys frequently encounters detrimental distortion and cracking, attributed to the accumulation of thermal stresses. These issues significantly impede the practical application of as-printed components. This study examines the Mg-15Gd-1Zn-0.4Zr (GZ151K, wt.%) alloy, a prototypical high-strength casting Mg-RE alloy, fabricated through laser powder bed fusion (LPBF). Despite achieving ultra-high strength, the GZ151K alloy concurrently exhibits a pronounced cold-cracking susceptibility. The as-printed GZ151K alloy consists of almost fully fine equiaxed grains with an average grain size of merely 2.87 µm. Subsequent direct aging (T5) heat treatment induces the formation of dense prismatic β' precipitates. Consequently, the LPBF-T5 GZ151K alloy manifests an ultra-high yield strength of 405 MPa, surpassing all previously reported yield strengths for Mg alloys fabricated via LPBF and even exceeding that of its extrusion-T5 counterpart. Interestingly, as-printed GZ151K samples with a build height of 2 mm exhibit no cracking, whereas samples with build heights ranging from 4 to 18 mm demonstrate severe cold cracking. Thermal stress simulation also suggests that the cold cracking susceptibility increases significantly with increasing build height. The combination of high thermal stress and low ductility in the as-printed GZ151K alloy culminates in a high cold cracking susceptibility. This study offers novel insights into the intricate issue of cold cracking in the LPBF process of high-strength Mg alloys, highlighting the critical balance between achieving high strength and mitigating cold cracking susceptibility.
基金supported by the National Natural Science Foundation of China(Nos.51801079 and 52001140)the National Science Centre,Poland(Narodowe Centrum Nauki)(No.UMO-2021/42/E/ST5/00339).
文摘To increase the strength of the laser powder-bed fusion (LPBF) Al-Si-based aluminum alloy, TiB_(2) ceramic particles were selected to be mixed with high-Mg content Al-Si-Mg-Zr powder, and then a novel TiB_(2)/Al-Si-Mg-Zr composite was fabricated using LPBF. The results indicated that a dense sample with a maximum relative density of 99.85% could be obtained by adjusting the LPBF process parameters. Incorporating TiB_(2) nanoparticles enhanced the powder's laser absorption rate, thereby raising the alloy's intrinsic heat treatment temperature and consequently facilitating the precipitation of Si and βʺ nanoparticles in the α-Al cells. Moreover, the rapid cooling process during LPBF resulted in numerous alloying elements with low-stacking fault energy dissolving in the α-Al matrix, thus promoting the formation of the 9R phase. After a 48 h direct aging treatment at 150℃, the strength of the alloy slightly increased due to the increase of nanoprecipitates. Both yield strength and ultimate tensile strength of the LPBF TiB_(2)/Al-Si-Mg-Zr alloy were significantly higher than that of other LPBF TiB_(2)-modified aluminum alloys with external addition.
基金supported by the National Natural Science Foundation of China (NSFC) under Grant Nos. 12375243 and 12388101the Strategic Priority Research Program of the Chinese Academy of Sciences under Grant Nos. XDA25050400, XDA25010200, and XDA25010100+1 种基金the Science Challenge Projectthe Fundamental Research Funds for the Central Universities。
文摘Two-plasmon-decay instability(TPD)poses a critical target preheating risk in direct-drive inertial confinement fusion.In this paper,TPD collectively driven by dual laser beams consisting of a normal-incidence laser beam(Beam-N)and a large-angle-incidence laser beam(Beam-L)is investigated via particle-in-cell simulations.It is found that significant TPD growth can develop in this regime at previously unexpected low laser intensities if the intensity of Beam-L exceeds the large-angle-incidence threshold.Both beams contribute to the growth of TPD in a“seed-amplification”manner in which the absolute instability driven by Beam-L provides the seeds that are convectively amplified by Beam-N,making TPD energetically important and causing significant pump depletion and hot-electron generation.
基金funded by the European Union via the Euratom Research and Training Program(Grant Agreement No.101052200-EUROfusion)funding from LASERLAB-EUROPE(Grant Agreement No.871124,European Union’s Horizon 2020 Research and Innovation Program)+5 种基金supported in part by the United States Department of Energy under Grant No.DE-FG02-93ER40773We also acknowledge support from Grant No.PID2021-125389OA-I00 funded by MCIN/AEI/10.13039/501100011033/FEDER,UEby“ERDF A Way of Making Europe”by the European Union and Unidad de Investigación Consolidada of Junta de Castilla y León UIC 167supported in part by the National Natural Science Foundation of China under Grant No.12375125the Fundamental Research Funds for the Central Universitiesthe support of the Czech Science Foundation through Grant No.GACR24-11398S.
文摘Driving of the nuclear fusion reaction p+^(11)B3α+8.7 MeV under laboratory conditions by interaction between high-power laser pulses and matter has become a popular field of research,owing to its numerous potential applications:as an alternative to deuterium-tritium for fusion energy production,astrophysics studies,and alpha-particle generation for medical treatment.One possible scheme for laser-driven p-^(11)B reactions is to direct a beam of laser-accelerated protons onto a boron(B)sample(the so-called“pitcher-catcher”scheme).This technique has been successfully implemented on large high-energy lasers,yielding hundreds of joules per shot at low repetition.We present here a complementary approach,exploiting the high repetition rate of the VEGA III petawatt laser at CLPU(Spain),aiming at accumulating results from many interactions at much lower energy,to provide better control of the parameters and the statistics of the measurements.Despite a moderate energy per pulse,our experiment allowed exploration of the laser-driven fusion process with tens(up to hundreds)of laser shots.The experiment provided a clear signature of the reactions involved and of the fusion products,accumulated over many shots,leading to an improved optimization of the diagnostics for experimental campaigns of this type.In this paper,we discuss the effectiveness of laser-driven p-11B fusion in the pitcher-catcher scheme,at a high repetition rate,addressing the challenges of this experimental scheme and highlighting its critical aspects.Our proposed methodology allows evaluation of the performance of this scheme for laser-driven alpha particle production and can be adapted to high-repetition-rate laser facilities with higher energy and intensity.
基金supported by the following funds:the National Natural Science Foundation of China(No.52305358)the Fundamental Research Funds for the Central Universities(No.2023ZYGXZR061)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2022A1515010304)the Young Elite Scientists Sponsorship Program by CAST(No.2023QNRC001)the Young Talent Support Project of Guangzhou(No.QT-2023-001).
文摘Laser powder bed fusion(LPBF)additive manufacturing of zinc(Zn)offers promising advantages for biodegradable metal bone implants,including tailorable microstructures,controllable porous structures,and appropriate degradation rates.However,the layer-by-layer construction during LPBF often leads to microstructural and performance anisotropy within metallic materials.In this work,the anisotropic mechanical and degradation properties of pure Zn processed using LPBF were comprehensively investigated for the first time.Specifically,the influence of microstructural characteristics on the mechanical and degradation properties of LPBF-processed Zn in both horizontal and vertical planes was revealed,while the underlying deformation mechanisms in different planes were illustrated.The results demonstrated that the horizontal plane exhibited higher mechanical strength compared to the vertical plane,with ulti-mate tensile strength of 123.6 and 107.86 MPa,respectively,significantly surpassing that of the tradition-ally cast counterpart(52.7 MPa).Importantly,abundant deformation twins coupled with infrequent microbands and pyramidal(c+a)slip systems activated during tensile loading along the vertical plane enabled multiple deformation modes,which sustained durable work hardening ability while delaying plastic instability,resulting in extraordinary plasticity(elongation of 14.2%).Additionally,synergistic effects between high-density grain boundaries including low-angle grain boundaries and pre-existing dislocations promoted the stable presence of a passive film along the horizontal plane,thus exhibiting relatively low corrosion sensitivity.Furthermore,the LPBF-processed Zn also demonstrated favorable biological activity and osteogenic potential.These findings provide valuable insights into multiple mechanisms underlying anisotropy in mechanical and degradation properties of laser additively manufactured Zn-based materials.
基金supported by the National Natural Science Foundation of China(Nos.U22B2067 and 52073176)。
文摘Laser powder bed fusion(LPBF)is a widely used and well-developed approach in additive manufacturing.To meet the high material performance requirements of fourth-generation nuclear power reactors,the combination of LPBF processing with oxide dispersion strengthening(ODS)is currently of interest for the design and development of new materials.In this approach,nanoscale Y_(2)O_(3)particles are dispersed into the feeding powders to produce LPBF-ODS materials.Oxygen exposure and the introduction of oxygen into the solvation cell during LPBF are usually considered as detrimental processes that are impossible to eliminate completely.However,our understanding of these unavoidable processes is still limited.In this study,we developed a new LPBF-ODS design approach based on in situ oxygen content regulation during the LPBF process.The oxygen content of the environmental chamber was artificially adjusted using an online monitoring system to activate reactions between oxygen and the metallic elements for the in situ formation of dispersed oxide particles.Four batches of LPBF 304 L stainless steel samples were successfully processed under different oxygen levels to investigate the reinforcement effect of in situ chemical alloying.The results show that dispersed oxide particles were formed with an average nanoscale size of approximately 46 nm through the LPBF in situ alloying approach.The increase in the number density of oxide particles to 11.4 particles∕μm^(2)as the oxygen content increased played a role in refining and stabilizing the cellular structure.The yield strength of the in situ alloyed ODS material was enhanced(to up to~675 MPa)while its ductility was not significantly degraded(elongation of up to~39%).These tensile properties are competitive within the ranges reported for ODS alloys prepared by mechanical alloying.The main mechanisms for yield strength enhancement through interactions between nanoscale oxide particles and dislocation entanglement cells were analyzed.This study provides a new approach for the future preparation of high-performance LPBF-ODS alloys.
基金co-supported by Basic and Applied Basic Research Foundation of Guangdong Province(No.2022A1515110622)Natural Science Basic Research Program of Shaanxi Province(No.2023-JC-QN-0548)+1 种基金National Key R&D Program of China(No.2022YFB3402200)the Fundamental Research Funds for the Central Universities。
文摘This study presents new methods to effectively model the anisotropic yielding and hardening behavior of laser powder bed fusion fabricated aluminum alloy under both monotonic and cyclic loading conditions.The proposed model combines the yield surface-interpolation method to accurately describe the anisotropic hardening rates in various directions,with the Chaboche kinematic hardening rule to precisely reflect the cyclic characteristics.For numerical implementation of the combined anisotropic and cyclic constitutive model,a fully implicit stress integration algorithm based on return mapping method is provided.Moreover,the multiple parameters associated with the model are categorized and identified in an uncoupled manner.The isotropic and cyclic hardening parameters are determined by an inverse method,and the stability of the optimization outcomes is validated by applying different starting points for the parameters.Particularly,the back-stress effect on the identification of anisotropic parameters associated with the stress invariant-based Hill48 yield function is considered for the first time.This consideration leads to an improved prediction accuracy compared to the identification of anisotropic parameters without considering back-stress effect.The combined anisotropic and cyclic constitutive model,along with the calibrated parameters,are proven capable of accurately reproducing the intricate deformation behavior of laser powder bed fusion fabricated AlSi10Mg.
基金supported by National Key Research and Development Program of China(Grant No.2021YFB1715400)National Natural Science Foundation of China(Grant No.52225503)+3 种基金Key Research and Development Program of Jiangsu Province(Grant Nos.BE2022069,BE2022069-1)Fundamental Research Funds for the Central Universities(Grant No.NI2024003)National Natural Science Foundation of China for Creative Research Groups(Grant No.51921003)the 15th Batch of“Six Talents Peaks”Innovative Talents Team Program(Grant No.TD-GDZB-001).
文摘After millions of years of natural evolution,horsetails have evolved unique stem structures that enable survival in harsh environments.Inspired by the cross-sectional characteristics of horsetail stems,a series of bioinspired sandwich structures were designed and fabricated using the laser powder bed fusion(LPBF)process.By combining experimental and finite element simulation methods,the formability,mechanical properties,deformation behavior,and thermal conduction performance of these structures were determined.Results show that the surface morphology of the bioinspired sandwich structures was smooth,with no cracks observed.The bioinspired sandwich structure with an inner tube diameter of 1.9 mm(D_(1.9))exhibited optimal comprehensive mechanical properties,with a specific strength of 64.2 MPa/(g/cm^(3)),and specific energy absorption of 3.3 J/g.Stress distribution results revealed that the D_(1.9)structures had the most uniform stress distribution.Furthermore,increasing the internal conduction paths improved heat transfer;therefore,the thermal conductivities of the D_(1.4),D_(1.9),and D_(2.4)structures were higher than that of the D0 structure.This study demonstrates that a bioinspired design approach,combined with additive manufacturing technology,enables the development of high-performance structures with both load-bearing and thermally insulating capabilities.
基金project supported by the National Natural Science Foundation of China(Grant Nos.52225503 and 52405380)National Key Research and Development Program(Grant Nos.2023YFB4603303 and 2023YFB4603304)+4 种基金Key Research and Development Program of Jiangsu Province(Grant Nos.BE2022069 and BE2022069-3)National Natural Science Foundation of China for Creative Research Groups(Grant No.51921003)The 15th Batch of“Six Talents Peaks”Innovative Talents Team Program of Jiangsu province(Grant Nos.TD-GDZB-001)Shanghai Aerospace Science and Technology Innovation Fund Project(Grant No.SAST2023-066)The Fundamental Research Funds for the Central Universities(Grant Nos.NS2023035 and NP2024128)。
文摘Transpiration cooling is crucial for the performance of aerospace engine components,relying heavily on the processing quality and accuracy of microchannels.Laser powder bed fusion(LPBF)offers the potential for integrated manufacturing of complex parts and precise microchannel fabrication,essential for engine cooling applications.However,optimizing LPBF’s extensive process parameters to control processing quality and microchannel accuracy effectively remains a significant challenge,especially given the time-consuming and labor-intensive nature of handling numerous variables and the need for thorough data analysis and correlation discovery.This study introduced a combined methodology of high-throughput experiments and Gaussian process algorithms to optimize the processing quality and accuracy of nickel-based high-temperature alloy with microchannel structures.250 parameter combinations,including laser power,scanning speed,channel diameter,and spot compensation,were designed across ten high-throughput specimens.This setup allowed for rapid and efficient evaluation of processing quality and microchannel accuracy.Employing Bayesian optimization,the Gaussian process model accurately predicted processing outcomes over a broad parameter range.The correlation between various processing parameters,processing quality and accuracy was revealed,and various optimized process combinations were summarized.Verification through computed Tomography testing of the specimens confirmed the effectiveness and precision of this approach.The approach introduced in this research provides a way for quickly and efficiently optimizing the process parameters and establishing process-property relationships for LPBF,which has broad application value.
基金the financial support by Yunnan Provincial Materials Fund Project Ⅱ(Grant No.202302AB080020)the National Natural Science Foundation of China(Grant No.U24A2037)the Liaoning Science and Technology Program(2024JH1/11700038).
文摘The GH3536(Hastelloy-X)nickel-based superalloy is increasingly applied in the aerospace industry due to its exceptional combination of excellent oxidation resistance and high-temperature strength.Laser powder bed fusion(LPBF)is an additive manufacturing(AM)technology for producing metallic components with complex shapes using layer-by-layer manufacture principle.The debate has long prevailed as to research on eliminating anisotropy in the forming of GH3536 alloy through LPBF technology.In this study,the anisotropy of microstructure and mechanical properties of GH3536 alloy formed by LPBF was investigated using different scanning strategies(0°,90°,67°,checkerboard,and contour).The scanning strategy was optimized to reduce the weaving differences between the horizontal and vertical directions of the microstructure of the LPBF formed GH3536 alloy,which in turn reduces the anisotropy of the properties in both directions.The results of the tensile specimens indicate that except for the horizontal specimens produced using the contour scanning strategy,the strength of all other specimens exceeds that of the vertical specimens.Additionally,differences in elongation are observed,demonstrating that the GH3536 alloy fabricated via laser powder bed fusion exhibits anisotropic properties.According to electron backscatter diffraction(EBSD)analysis,the grain boundary strengthening and geometrically necessary dislocations(GNDs)impede dislocation motion during tensile deformation along the horizontal direction.Consequently,this mechanism negatively affects both the tensile strength and ductility in that orientation.The anisotropy in tensile strength and plasticity is attributed to the different crack sensitivities in the two tensile directions.In addition,specimens molded using different scanning strategies exhibit varying degrees of anisotropy,strength,and elongation due to different degrees of texture strengthening,grain boundary strengthening,and dislocation strengthening effects.Regardless of the stretching direction,the combined tensile properties of the 0°and contoured specimens are the worst under the room temperature and 815℃ stretching conditions.The 67°specimens exhibit the best combined tensile properties.Therefore,the anisotropy of the mechanical properties of the LPBF formed GH3536 alloy can be positively mitigated by modulating the scanning strategy.
基金Project(2022YFC2406000)supported by the National Key R&D Program,ChinaProject(2022GDASZH-2022010107)supported by the Guangdong Academy of Science,China+4 种基金Project(2019BT02C629)supported by the Guangdong Special Support Program,ChinaProject(2022GDASZH-2022010203-003)supported by the GDAS’project of Science and Technology Development,ChinaProjects(2023B1212120008,2023B1212060045)supported by the Guangdong Province Science and Technology Plan Projects,ChinaProject(2023TQ07Z559)supported by the Special Support Foundation of Guangdong Province,ChinaProject(52105293)supported by the National Natural Science Foundation of China。
文摘Laser powder-bed fusion(LPBF)of Zn-0.8Cu(wt.%)alloys exhibits significant advantages in the customization of biodegradable bone implants.However,the formability of LPBFed Zn alloy is not sufficient due to the spheroidization during the interaction of powder and laser beam,of which the mechanism is still not well understood.In this study,the evolution of morphology and grain structure of the LPBFed Zn-Cu alloy was investigated based on single-track deposition experiments.As the scanning speed increases,the grain structure of a single track of Zn-Cu alloy gradually refines,but the formability deteriorates,leading to the defect’s formation in the subsequent fabrication.The Zn-Cu alloys fabricated by optimum processing parameters exhibit a tensile strength of 157.13 MPa,yield strength of 106.48 MPa and elongation of 14.7%.This work provides a comprehensive understanding of the processing optimization of Zn-Cu alloy,achieving LPBFed Zn-Cu alloy with high density and excellent mechanical properties.
基金the Association SSF Strategic Mobility Grant(No.SM22-0039)theÅForsk Foundation(No.23-540)for supporting the research regarding inclusion engineering.
文摘High-temperature confocal scanning laser microscopy(HT-CSLM)is a potent methodology for investigating various phenomena in the field of metallurgy.Initially applied to the observation of solid phase transformations and solidification,this method has gained traction in the field of non-metallic inclusion in steels in recent years.An overview of the experimental capabilities of HT-CSLM and the most important results of recent investigations regarding the topics of clean steel production are provided.It includes the formation of intragranular acicular ferrite(IAF)from the surface of non-metallic inclusions during the continuous cooling and heat treatment,which can be especially beneficial in the toughness of heat-affected zones of welded pieces.Furthermore,the investigation of agglomeration mechanisms of non-metallic inclusions(NMIs)in liquid steel is discussed to improve the insight into attraction forces between particles and clogging phenomena during continuous casting.Also,the dissolution of NMIs in various steelmaking slags can be observed by HT-CSLM to compare dissolution rates and mechanisms of NMI,where significant influences of temperature and chemical composition of the slag were shown.Last but not least,the experimental work regarding the interface between steel and slag is discussed,where novel techniques are currently being developed.A comprehensive summary of experimental techniques using HT-CSLM equipment to investigate different interactions of NMIs with steel and slag phases is compiled.
